Materials Science and Engineering Handbook Part 3 doc

H EAT OF F USION F OR E LEMENTS AND I NORGANIC C OMPOUNDS SHEET 1 OF 16 Melting point ˚C Heat of fusion cal/g cal/g mole For heat of fusion in J/kg, multiply values in cal/g by 4184.. H

Thermodynamic and Kinetic Data

Thermodynamic and Kinetic Data

Thermodynamic and Kinetic Data

Thermodynamic and Kinetic Data

Table 73 H EAT OF F USION F OR E LEMENTS AND

I NORGANIC C OMPOUNDS (SHEET 1 OF 16)

Melting point

˚C

Heat of fusion cal/g cal/g mole

For heat of fusion in J/kg, multiply values in cal/g by 4184.

For heat of fusion in J/mol, multiply values in cal/g-mol (=cal/mol) by 4.184.

For melting point in K, add 273.15 to values in ˚C.

Values in parentheses are of uncertain reliability

Source: data from Weast, R C., Ed., Handbook of Chemistry and Physics, 55th ed., CRC Press, Cleveland, (1974); and Bolz, R E and Tuve, G L., Eds., Handbook of Tables for Applied Engineering Science, 2nd ed., CRC Press, Cleveland, (1973)

6.3 Thermodynamics Page 240 Wednesday, December 31, 1969 17:00

Thermodynamic and Kinetic Data

Barium nitrate Ba(NO3)2 594.8 (22.6) (5900)

Barium phosphate Ba3(PO4)2 1727 30.9 18600

Table 73 H EAT OF F USION F OR E LEMENTS AND

I NORGANIC C OMPOUNDS (SHEET 2 OF 16)

Melting point

˚C

Heat of fusion cal/g cal/g mole

For heat of fusion in J/kg, multiply values in cal/g by 4184.

For heat of fusion in J/mol, multiply values in cal/g-mol (=cal/mol) by 4.184.

For melting point in K, add 273.15 to values in ˚C.

Values in parentheses are of uncertain reliability

Source: data from Weast, R C., Ed., Handbook of Chemistry and Physics, 55th ed., CRC Press,

Cleveland, (1974); and Bolz, R E and Tuve, G L., Eds., Handbook of Tables for Applied

Engineering Science, 2nd ed., CRC Press, Cleveland, (1973)

6.3 Thermodynamics Page 241 Wednesday, December 31, 1969 17:00

Thermodynamic and Kinetic Data

Table 73 H EAT OF F USION F OR E LEMENTS AND

I NORGANIC C OMPOUNDS (SHEET 3 OF 16)

Melting point

˚C

Heat of fusion cal/g cal/g mole

For heat of fusion in J/kg, multiply values in cal/g by 4184.

For heat of fusion in J/mol, multiply values in cal/g-mol (=cal/mol) by 4.184.

For melting point in K, add 273.15 to values in ˚C.

Values in parentheses are of uncertain reliability

Source: data from Weast, R C., Ed., Handbook of Chemistry and Physics, 55th ed., CRC Press, Cleveland, (1974); and Bolz, R E and Tuve, G L., Eds., Handbook of Tables for Applied Engineering Science, 2nd ed., CRC Press, Cleveland, (1973)

6.3 Thermodynamics Page 242 Wednesday, December 31, 1969 17:00

Thermodynamic and Kinetic Data

Chromium (III) sequioxide Cr2O3 2279 27.6 4200

Copper(l) cyanide Cu2(CN)2 473 (30.1) (5400)

Table 73 H EAT OF F USION F OR E LEMENTS AND

I NORGANIC C OMPOUNDS (SHEET 4 OF 16)

Melting point

˚C

Heat of fusion cal/g cal/g mole

For heat of fusion in J/kg, multiply values in cal/g by 4184.

For heat of fusion in J/mol, multiply values in cal/g-mol (=cal/mol) by 4.184.

For melting point in K, add 273.15 to values in ˚C.

Values in parentheses are of uncertain reliability

Source: data from Weast, R C., Ed., Handbook of Chemistry and Physics, 55th ed., CRC Press,

Cleveland, (1974); and Bolz, R E and Tuve, G L., Eds., Handbook of Tables for Applied

Engineering Science, 2nd ed., CRC Press, Cleveland, (1973)

6.3 Thermodynamics Page 243 Wednesday, December 31, 1969 17:00

Thermodynamic and Kinetic Data

Table 73 H EAT OF F USION F OR E LEMENTS AND

I NORGANIC C OMPOUNDS (SHEET 5 OF 16)

Melting point

˚C

Heat of fusion cal/g cal/g mole

For heat of fusion in J/kg, multiply values in cal/g by 4184.

For heat of fusion in J/mol, multiply values in cal/g-mol (=cal/mol) by 4.184.

For melting point in K, add 273.15 to values in ˚C.

Values in parentheses are of uncertain reliability

Source: data from Weast, R C., Ed., Handbook of Chemistry and Physics, 55th ed., CRC Press, Cleveland, (1974); and Bolz, R E and Tuve, G L., Eds., Handbook of Tables for Applied Engineering Science, 2nd ed., CRC Press, Cleveland, (1973)

6.3 Thermodynamics Page 244 Wednesday, December 31, 1969 17:00

Thermodynamic and Kinetic Data

Iron (III) chloride Fe2Cl6 303.8 63.2 20500

Table 73 H EAT OF F USION F OR E LEMENTS AND

I NORGANIC C OMPOUNDS (SHEET 6 OF 16)

Melting point

˚C

Heat of fusion cal/g cal/g mole

For heat of fusion in J/kg, multiply values in cal/g by 4184.

For heat of fusion in J/mol, multiply values in cal/g-mol (=cal/mol) by 4.184.

For melting point in K, add 273.15 to values in ˚C.

Values in parentheses are of uncertain reliability

Source: data from Weast, R C., Ed., Handbook of Chemistry and Physics, 55th ed., CRC Press,

Cleveland, (1974); and Bolz, R E and Tuve, G L., Eds., Handbook of Tables for Applied

Engineering Science, 2nd ed., CRC Press, Cleveland, (1973)

6.3 Thermodynamics Page 245 Wednesday, December 31, 1969 17:00

Thermodynamic and Kinetic Data

Lithium metasilicate Li2SiO3 1177 80.2 7210

Lithium orthosilicate Li4SiO4 1249 60.5 7430

Table 73 H EAT OF F USION F OR E LEMENTS AND

I NORGANIC C OMPOUNDS (SHEET 7 OF 16)

Melting point

˚C

Heat of fusion cal/g cal/g mole

For heat of fusion in J/kg, multiply values in cal/g by 4184.

For heat of fusion in J/mol, multiply values in cal/g-mol (=cal/mol) by 4.184.

For melting point in K, add 273.15 to values in ˚C.

Values in parentheses are of uncertain reliability

Source: data from Weast, R C., Ed., Handbook of Chemistry and Physics, 55th ed., CRC Press, Cleveland, (1974); and Bolz, R E and Tuve, G L., Eds., Handbook of Tables for Applied Engineering Science, 2nd ed., CRC Press, Cleveland, (1973)

6.3 Thermodynamics Page 246 Wednesday, December 31, 1969 17:00

Thermodynamic and Kinetic Data

Manganese metasilicate MnSiO3 1274 (62.6) (8200)

Table 73 H EAT OF F USION F OR E LEMENTS AND

I NORGANIC C OMPOUNDS (SHEET 8 OF 16)

Melting point

˚C

Heat of fusion cal/g cal/g mole

For heat of fusion in J/kg, multiply values in cal/g by 4184.

For heat of fusion in J/mol, multiply values in cal/g-mol (=cal/mol) by 4.184.

For melting point in K, add 273.15 to values in ˚C.

Values in parentheses are of uncertain reliability

Source: data from Weast, R C., Ed., Handbook of Chemistry and Physics, 55th ed., CRC Press,

Cleveland, (1974); and Bolz, R E and Tuve, G L., Eds., Handbook of Tables for Applied

Engineering Science, 2nd ed., CRC Press, Cleveland, (1973)

6.3 Thermodynamics Page 247 Wednesday, December 31, 1969 17:00

Thermodynamic and Kinetic Data

Table 73 H EAT OF F USION F OR E LEMENTS AND

I NORGANIC C OMPOUNDS (SHEET 9 OF 16)

Melting point

˚C

Heat of fusion cal/g cal/g mole

For heat of fusion in J/kg, multiply values in cal/g by 4184.

For heat of fusion in J/mol, multiply values in cal/g-mol (=cal/mol) by 4.184.

For melting point in K, add 273.15 to values in ˚C.

Values in parentheses are of uncertain reliability

Source: data from Weast, R C., Ed., Handbook of Chemistry and Physics, 55th ed., CRC Press, Cleveland, (1974); and Bolz, R E and Tuve, G L., Eds., Handbook of Tables for Applied Engineering Science, 2nd ed., CRC Press, Cleveland, (1973)

6.3 Thermodynamics Page 248 Wednesday, December 31, 1969 17:00

Thermodynamic and Kinetic Data

Phosphoric acid hypo– H4P2O6 54.8 51.2 8300

Phosphorus acid, ortho– H3PO3 73.8 37.4 3070

Table 73 H EAT OF F USION F OR E LEMENTS AND

I NORGANIC C OMPOUNDS (SHEET 10 OF 16)

Melting point

˚C

Heat of fusion cal/g cal/g mole

For heat of fusion in J/kg, multiply values in cal/g by 4184.

For heat of fusion in J/mol, multiply values in cal/g-mol (=cal/mol) by 4.184.

For melting point in K, add 273.15 to values in ˚C.

Values in parentheses are of uncertain reliability

Source: data from Weast, R C., Ed., Handbook of Chemistry and Physics, 55th ed., CRC Press,

Cleveland, (1974); and Bolz, R E and Tuve, G L., Eds., Handbook of Tables for Applied

Engineering Science, 2nd ed., CRC Press, Cleveland, (1973)

6.3 Thermodynamics Page 249 Wednesday, December 31, 1969 17:00

Thermodynamic and Kinetic Data

Potassium pyro– phosphate K4P2O7 1092 42.4 14000

Table 73 H EAT OF F USION F OR E LEMENTS AND

I NORGANIC C OMPOUNDS (SHEET 11 OF 16)

Melting point

˚C

Heat of fusion cal/g cal/g mole

For heat of fusion in J/kg, multiply values in cal/g by 4184.

For heat of fusion in J/mol, multiply values in cal/g-mol (=cal/mol) by 4.184.

For melting point in K, add 273.15 to values in ˚C.

Values in parentheses are of uncertain reliability

Source: data from Weast, R C., Ed., Handbook of Chemistry and Physics, 55th ed., CRC Press, Cleveland, (1974); and Bolz, R E and Tuve, G L., Eds., Handbook of Tables for Applied Engineering Science, 2nd ed., CRC Press, Cleveland, (1973)

6.3 Thermodynamics Page 250 Wednesday, December 31, 1969 17:00

Thermodynamic and Kinetic Data

Table 73 H EAT OF F USION F OR E LEMENTS AND

I NORGANIC C OMPOUNDS (SHEET 12 OF 16)

Melting point

˚C

Heat of fusion cal/g cal/g mole

For heat of fusion in J/kg, multiply values in cal/g by 4184.

For heat of fusion in J/mol, multiply values in cal/g-mol (=cal/mol) by 4.184.

For melting point in K, add 273.15 to values in ˚C.

Values in parentheses are of uncertain reliability

Source: data from Weast, R C., Ed., Handbook of Chemistry and Physics, 55th ed., CRC Press,

Cleveland, (1974); and Bolz, R E and Tuve, G L., Eds., Handbook of Tables for Applied

Engineering Science, 2nd ed., CRC Press, Cleveland, (1973)

6.3 Thermodynamics Page 251 Wednesday, December 31, 1969 17:00

Thermodynamic and Kinetic Data

Sodium phosphate, meta– NaPO3 988 (48.6) (4960)

Sodium pyrophosphate Na4P2O7 970 (51.5) (13700)

Sodiumsilicate,aluminum– NaAlSi3O8 1107 50.1 13150

Sodium silicate, di– Na2Si2O5 884 46.4 8460

Sodium silicate, meta– Na2SiO3 1087 84.4 10300

Table 73 H EAT OF F USION F OR E LEMENTS AND

I NORGANIC C OMPOUNDS (SHEET 13 OF 16)

Melting point

˚C

Heat of fusion cal/g cal/g mole

For heat of fusion in J/kg, multiply values in cal/g by 4184.

For heat of fusion in J/mol, multiply values in cal/g-mol (=cal/mol) by 4.184.

For melting point in K, add 273.15 to values in ˚C.

Values in parentheses are of uncertain reliability

Source: data from Weast, R C., Ed., Handbook of Chemistry and Physics, 55th ed., CRC Press, Cleveland, (1974); and Bolz, R E and Tuve, G L., Eds., Handbook of Tables for Applied Engineering Science, 2nd ed., CRC Press, Cleveland, (1973)

6.3 Thermodynamics Page 252 Wednesday, December 31, 1969 17:00

Thermodynamic and Kinetic Data

Table 73 H EAT OF F USION F OR E LEMENTS AND

I NORGANIC C OMPOUNDS (SHEET 14 OF 16)

Melting point

˚C

Heat of fusion cal/g cal/g mole

For heat of fusion in J/kg, multiply values in cal/g by 4184.

For heat of fusion in J/mol, multiply values in cal/g-mol (=cal/mol) by 4.184.

For melting point in K, add 273.15 to values in ˚C.

Values in parentheses are of uncertain reliability

Source: data from Weast, R C., Ed., Handbook of Chemistry and Physics, 55th ed., CRC Press,

Cleveland, (1974); and Bolz, R E and Tuve, G L., Eds., Handbook of Tables for Applied

Engineering Science, 2nd ed., CRC Press, Cleveland, (1973)

6.3 Thermodynamics Page 253 Wednesday, December 31, 1969 17:00

Thermodynamic and Kinetic Data

Titanium chloride, tetra– TiCl4 –23.2 11.9 2240

Table 73 H EAT OF F USION F OR E LEMENTS AND

I NORGANIC C OMPOUNDS (SHEET 15 OF 16)

Melting point

˚C

Heat of fusion cal/g cal/g mole

For heat of fusion in J/kg, multiply values in cal/g by 4184.

For heat of fusion in J/mol, multiply values in cal/g-mol (=cal/mol) by 4.184.

For melting point in K, add 273.15 to values in ˚C.

Values in parentheses are of uncertain reliability

Source: data from Weast, R C., Ed., Handbook of Chemistry and Physics, 55th ed., CRC Press, Cleveland, (1974); and Bolz, R E and Tuve, G L., Eds., Handbook of Tables for Applied Engineering Science, 2nd ed., CRC Press, Cleveland, (1973)

6.3 Thermodynamics Page 254 Wednesday, December 31, 1969 17:00

Thermodynamic and Kinetic Data

Table 73 H EAT OF F USION F OR E LEMENTS AND

I NORGANIC C OMPOUNDS (SHEET 16 OF 16)

Melting point

˚C

Heat of fusion cal/g cal/g mole

For heat of fusion in J/kg, multiply values in cal/g by 4184.

For heat of fusion in J/mol, multiply values in cal/g-mol (=cal/mol) by 4.184.

For melting point in K, add 273.15 to values in ˚C.

Values in parentheses are of uncertain reliability

Source: data from Weast, R C., Ed., Handbook of Chemistry and Physics, 55th ed., CRC Press,

Cleveland, (1974); and Bolz, R E and Tuve, G L., Eds., Handbook of Tables for Applied

Engineering Science, 2nd ed., CRC Press, Cleveland, (1973)

6.3 Thermodynamics Page 255 Wednesday, December 31, 1969 17:00

Thermodynamic and Kinetic Data

Table 74 H EATS OF S UBLIMATION OF M ETALS

AND T HEIR O XIDES

Metal

kcal/mole (25˚C)

kJ/mole (25˚C)

Since both forms are used in the following, let

The constants a, b, c, and d are to be determined either experimentally or by some theoretical or semi-empirical approach The heat content, or enthalpy (H), is determined from the heat capacity by a simple integration of the range of temperatures for which the for- mula for cp is valid Thus, if 298K is taken as a reference temperature,

where all the constants on the right-hand side of the equation have been incorporated in the term –A.

In general, the enthalpy is given by a sum of terms for each phase of the substance involved in the temperature range considered plus terms that represent the heats of transitions:

In a similar manner, the entropy S is obtained by performing the integration

Table 75 K EY TO T ABLES OF T HERMODYNAMIC C OEFFICIENTS

(SHEET 2 OF 4)

may be written as:

and also the free energy function

Values of these thermodynamic coefficients are given in the following tables The first column in each table lists the material The ond column gives the phase to which the coefficients are applicable The remaining columns list the values of the constants a, b, c, d, A, and B required in the thermodynamic equations All values that represent estimates are enclosed in parentheses The heat capacities at temperatures beyond the range of experimental determination were estimated by extrapolation Where no experimental values were found, analogy with compounds of neighboring elements in the periodic table was used

sec-Table 75 K EY TO T ABLES OF T HERMODYNAMIC C OEFFICIENTS

(SHEET 4 OF 4)

b –

c (cal • g mole -1 )

b –

c (cal • g mole -1 )

b –

c (cal • g mole -1 )

b –

c (cal • g mole -1 )

b –

c (cal • g mole -1 )

b –

c (cal • g mole -1 )

b –

c (cal • g mole -1 )

b –

c (cal • g mole -1 )

b –

c (cal • g mole -1 )

b –

c (cal • g mole -1 )

b –

c (cal • g mole -1 )

b –

c (cal • g mole -1 )

b –

c (cal • g mole -1 )

b –

c (cal • g mole -1 )

b (cal • g mole -1 )

c –

For discussion of these coefficients, please see Table 75, Key to Tables of Thermodynamic Coefficients on page 257

Source: data from Weast, R C., Ed., Handbook of Chemistry and Physics, 55th ed., CRC Press, Cleveland, 1974, D-58.

b (cal • g mole -1 )

c –

For discussion of these coefficients, please see Table 75, Key to Tables of Thermodynamic Coefficients on page 257

Source: data from Weast, R C., Ed., Handbook of Chemistry and Physics, 55th ed., CRC Press, Cleveland, 1974, D-58.