The major tec nical c an es with resp ct to the previou edition are: – the order of the An exes was c an ed to the order in whic they a p ar in the doc ment an a ca tion was ad ed to in
Trang 2THIS PUBLICATION IS COPYRIGHT PROTECTED
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Trang 3INT ERNAT IONAL
ELECT ROT ECHNICAL
Trang 4FOREWORD 5
INTRODUCTION 7
1 Sco e 8
2 Normative ref eren es 8
3 Terms an def i ition 8
4 Req irements 1
4.1 General 1
4.1.1 Desig 1
4.1.2 Bat ery dimen ion 1
4.1.3 Terminals 1
4.1.4 Clas ification (electroc emical s stem) 1
3 4.1.5 Desig ation 14 4.1.6 Markin 14 4.1.7 Interc ange bi ty: b t ery voltage 15 4.2 Per orman e 16 4.2.1 Dis harge p rf orman e 16 4.2.2 Dimen ional sta i ty 16 4.2.3 L akage 16 4.2.4 Op n-circ it voltage l mits 16 4.2.5 Service output 16 4.2.6 Saf ety 16 5 Perorman e – Testin 17 5.1 General 17 5.2 Dis harge testin 17 5.2.1 General 17 5.2.2 Ap l cation tests 17 5.2.3 Service output tests 1
8 5.3 Conforman e c ec to a sp cified minimum average d ration 18 5.4 Calc lation method of the sp cified value of a minimum average d ration 19 5.5 OCV testin 19 5.6 Bat ery dimen ion 19 5.7 L akage an deformation 19 6 Perorman e – Test con ition 19 6.1 Storage an dis harge con ition 19 6.2 Commen ement of dis harge tests af ter storage 2
6.3 Dis harge test con ition 2
6.3.1 General 2
6.3.2 Compl an e 2
6.4 L ad resistan e 2
6.5 Time p riod 2
6.6 Test con ition toleran es 21
6.7 Activation of ‘P’-s stem b teries 21
6.8 Me s rin eq ipment 21
6.8.1 Voltage me s rement 21
6.8.2 Mec anical me s rement 21
7 Samplng an q alty as uran e 21
Trang 58 Batery p c agin 21
An ex A (normative) Criteria for the stan ardization of b teries 2
An ex B (informative) Recommen ation for eq ipment desig 2
B.1 Tec nical l aison 2
B.2 Bat ery comp rtment 2
B.2.1 General 2
B.2.2 Limitin ac es by c i dren 2
B.3 Voltage c t-of f 2
An ex C (normative) Desig ation s stem (nomen lature) 2
C.1 General 2
C.2 Desig ation s stem in u e up to Octo er 19 0 2
C.2.1 General 2
C.2.2 Cel s 2
C.2.3 Electroc emical s stem 2
C.2.4 Bat eries 2
C.2.5 Modifiers 2
C.2.6 Examples 2
C.3 Desig ation s stem in u e sin e Octo er 19 0 2
C.3.1 General 2
C.3.2 Rou d b teries 2
C.3.3 Non- ou d b t eries 3
C.3.4 Ambig ity 3
An ex D (inf ormative) Stan ard dis harge voltage U s – Def i ition an method of determination 3
D.1 Definition 3
D.2 Determination 3
D.2.1 General con ideration : the C/R-plot 3
D.2.2 Determination of the stan ard dis harge resistor R s 3
D.2.3 Determination of the stan ard dis harge ca acity C s an stan ard dis harge time t s 3
D.3 Exp rimental con ition to b o served and test res lts 3
An ex E (informative) Pre aration of stan ard method of me s rin p rorman e (SMMP) of con umer go d 41
E.1 General 41
E.2 Per orman e c aracteristic 41
E.3 Criteria f or the develo ment of test method 41
An ex F (informative) Calc lation method for the sp cified value of minimum average d ration 4
An ex G (normative) Code of practice for p c agin , s ipment, storage, u e an disp sal of primary b teries 4
G.1 General 4
G.2 Pac agin 4
G.3 Tran p rt an han l n 4
G.4 Storage an stoc rotation 4
G.5 Display at sales p ints 4
G.6 Selection, u e an disp sal 4
G.6.1 Purc ase 4
G.6.2 In tal ation 4
G.6.3 Use 4
Trang 6G.6.4 Re lacement 4
G.6.5 Disp sal 4
Biblogra h 4
Fig re 1 – In estion gau e 1
Fig re C.1 – Desig ation s stem f or rou d b t eries: d 1 < 10 mm; heig t h 1 < 10 mm 2
Fig re C.2 – Diameter code for non- ecommen ed diameters 3
Fig re C.3 – Heig t code f or denotin the h n redth of a mi imetre of heig t 31
Fig re C.4 – Desig ation s stem for rou d b t eries: d 1 ≥ 10 mm; heig t h 1 ≥ 10 mm 3
Fig re C.5 – Desig ation s stem f or non- ou d b teries, dimen ion < 10 mm 3
Fig re C.6 – Desig ation s stem f or non- ou d b teries, dimen ion ≥ 10 mm 3
Fig re C.7 – Heig t code f or dis rimination p r tenth of a mi imetre 3
Fig re D.1 – Normalzed C/R-plot (s hematic) 3
Fig re D.2 – Stan ard dis harge voltage (s hematic) 3
Ta le 1 – Stan ardized electroc emical s stems 13 Ta le 2 – Markin req irements 15 Ta le 3 – Con ition for storage b fore an d rin dis harge testin 19 Ta le 4 – Resistive lo d for new tests 2
Ta le 5 – Time p riod for new tests 2
Ta le 6 – Test con ition toleran es 21
Ta le A.1 – Items neces ary to stan ardize 2
Ta le C.1 – Ph sical desig ation an dimen ion of ou d cel s an b t eries 2
Ta le C.2 – Ph sical desig ation an nominal overal dimen ion of f lat cel s 2
Ta le C.3 – Ph sical desig ation an dimen ion of s uare cel s an b teries 2
Ta le C.4 – Diameter code for recommen ed diameter 3
Ta le C.5 – Ph sical desig ation an dimen ion of rou d cel s an b t eries b sed on Clau e C.2 3
Ta le C.6 – Ph sical desig ation an dimen ion of non- ou d b teries b sed on Clau e C.2 3
Ta le D.1 – Stan ard dis harge voltage by s stem 4
Trang 7INTERNATIONAL ELECTROTECHNICAL COMMISSION
_
PRIMA RY BA TTERIES –
Part 1: General
1 Th Intern tio al Ele trote h ic l Commis io (IEC) is a worldwid org niz tio for sta d rdiz tio c mprisin
al n tio al ele trote h ic l c mmite s (IEC Natio al Commite s) Th o je t of IEC is to promote
intern tio al c -o eratio o al q e tio s c n ernin sta d rdiz tio in th ele tric l a d ele tro ic f i ld To
this e d a d in a ditio to oth r a tivitie , IEC p bls e Intern tio al Sta d rd , Te h ic l Sp cific tio s,
Te h ic l Re orts, Pu lcly Av ia le Sp cif i atio s (P S) a d Guid s (h re fter ref er e to a “IEC
Pu lc tio (s)”) Th ir pre aratio is e tru te to te h ic l c mmite s; a y IEC Natio al Commite intere te
in th s bje t d alt with ma p rticip te in this pre aratory work Intern tio al g v rnme tal a d n n
-g v rnme tal org niz tio s laisin with th IEC als p rticip te in this pre aratio IEC c la orate clo ely
with th Intern tio al Org niz tio f or Sta d rdiz tio (ISO) in a c rd n e with c n itio s d termin d b
a re me t b twe n th two org niz tio s
2) Th f ormal d cisio s or a re me ts of IEC o te h ic l maters e pre s, a n arly a p s ible, a intern tio al
c n e s s of o inio o th rele a t s bje ts sin e e c te h ic l c mmite h s re re e tatio fom al
intere te IEC Natio al Commite s
3) IEC Pu lc tio s h v th form of re omme d tio s f or intern tio al u e a d are a c pte b IEC Natio al
Commite s in th t s n e Whie al re s n ble ef forts are ma e to e s re th t th te h ic l c nte t of IEC
Pu lc tio s is a c rate, IEC c n ot b h ld re p n ible f or th wa in whic th y are u e or for a y
misinterpretatio b a y e d u er
4) In ord r to promote intern tio al u if ormity, IEC Natio al Commite s u d rta e to a ply IEC Pu lc tio s
tra s are tly to th ma imum e te t p s ible in th ir n tio al a d re io al p blc tio s An div rg n e
b twe n a y IEC Pu lc tio a d th c re p n in n tio al or re io al p blc tio s al b cle rly in ic te in
th later
5) IEC its lf d e n t pro id a y ate tatio of c nf ormity In e e d nt c rtif i atio b die pro id c nformity
a s s me t s rvic s a d, in s me are s, a c s to IEC mark of c nf ormity IEC is n t re p n ible f or a y
s rvic s c rie o t b in e e d nt c rtific tio b die
6) Al u ers s o ld e s re th t th y h v th late t e itio of this p blc tio
7) No la i ty s al ata h to IEC or its dire tors, emplo e s, s rv nts or a e ts in lu in in ivid al e p rts a d
memb rs of its te h ic l c mmite s a d IEC Natio al Commite s f or a y p rs n l injury, pro erty d ma e or
oth r d ma e of a y n ture wh ts e er, wh th r dire t or in ire t, or for c sts (in lu in le al f ee ) a d
e p n e arisin o t of th p blc tio , u e of, or rela c u o , this IEC Pu lc tio or a y oth r IEC
Pu lc tio s
8) Ate tio is drawn to th Normativ refere c s cite in this p blc tio Us of th refere c d p blc tio s is
in is e s ble for th c r e t a plc tio of this p blc tio
9) Ate tio is drawn to th p s ibi ty th t s me of th eleme ts of this IEC Pu lc tio ma b th s bje t of
p te t rig ts IEC s al n t b h ld re p n ible f or id ntifyin a y or al s c p te t rig ts
International Stan ard IEC 6 0 6-1 has b en pre ared by IEC tec nical commit e 3 :
Primary cels an b teries
This twelfth edition can els an re laces the eleventh edition (2 1 ) an con titutes a
tec nical revision
The major tec nical c an es with resp ct to the previou edition are:
– the order of the An exes was c an ed to the order in whic they a p ar in the doc ment
an a ca tion was ad ed to in icate where the An ex inf ormation first a p ars in the
doc ment;
– the h midity con ition f or non P-s stem bat eries in Ta le 3 was modified;
– the stan ard dis harge voltage for the Y an W c emistries was determined to b at 3,5 V
and 2,8 V resp ctively;
– detai s on ca acity me s rement were moved f rom Annex E to Subclau e 5.1
Trang 8– the coin/but on cel an b t ery definition was clarif ied in order to b t er ad res is ues
with the swal owin of coin cel s
The text of this stan ard is b sed on the fol owin doc ments:
Ful inf ormation on the votin f or the a proval of this stan ard can b foun in the re ort on
votin in icated in the a ove ta le
This publ cation has b en draf ted in ac ordan e with the ISO/IEC Directives, Part 2
A lst of al p rts in the IEC 6 0 6 series, u der the general title P rimary b t teries, can b
f ou d on the IEC we site
The commit e has decided that the contents of this publ cation wi remain u c an ed u ti
the sta i ty date in icated on the IEC we site u der "htp:/we store.iec.c " in the data
related to the sp cific publ cation At this date, the publ cation wi b
Trang 9The tec nical content of this p rt of IEC 6 0 6 provides fu damental req irements an
information on primary cels an b teries Al b t eries within the IEC 6 0 6 series are
con idered dry cel b t eries In this sen e, IEC 6 0 6-1 is the main comp nent of the
IEC 6 0 6 series an f orms the b sis f or the s bseq ent p rts For example, this p rt
in lu es elementary information on def i ition , nomen lature, dimen ion an markin Whie
sp cific req irements are in lu ed, the content of this p rt ten s to explain methodolog (how)
an ju tification (why)
Over the ye rs, this p rt has b en c an ed to improve its content an remain u der
contin al s rutin to en ure that the publ cation is ke t up to date with the ad an es in b th
b tery an b t ery-p wered device tec nologies
NOT Safety informatio is a aia le in IEC 6 0 6-4, IEC 6 0 6-5 a d IEC 6 2 1
Trang 10PRIMA RY BA TTERIES –
Part 1: General
This p rt of IEC 6 0 6 is inten ed to stan ardize primary b teries with resp ct to dimen ion ,
nomen lature, terminal config ration , markin s, test method , typical p r orman e, safety
an en ironmental asp cts
As a primary b t ery clas if i ation tool, electroc emical s stems are also stan ardized with
resp ct to s stem let er, electrodes, electrolyte, nominal an maximum o en circ it voltage
NOT Th re uireme ts ju tif yin th in lu io or th o g in rete tio of b terie in th IEC 6 0 6 s rie are
giv n in An e A
The o ject of this p rt of IEC 6 0 6 is to b nefit primary b t ery u ers, device desig ers an
b tery man facturers by en urin that b teries f rom diff erent man facturers are
interc an e ble ac ordin to stan ard f orm, f it an f un tion Furthermore, to en ure
compl an e with the a ove, this p rt sp cifies stan ard test method for testin primary cel s
an b t eries
The f ol owin doc ments, in whole or in p rt, are normatively ref eren ed in this doc ment an
are in isp n a le f or its a pl cation For dated ref eren es, only the edition cited a ples For
u dated referen es, the latest edition of the referen ed doc ment (in lu in an
amen ments) a pl es
IEC 6 0 6-2:−
1
, P rimary b tt eries – P art 2: P hysic l a d electric l sp cific tio s
IEC 6 08 -3:2 11, Primary b tt eries – P art 3: Watch b t teries
IEC 6 08 -4:2 14, P rimary b t teries – P art 4: Safety of lithium b tt eries
IEC 6 08 -5:2 11, Primary b tt eries – P art 5: Safety of b tteries with a u o s electrolyte
one or more cel s electrical y con ected an fit ed in a case, with terminals, markin s an
protective devices etc as neces ary for u e
_ _ _ _ _ _ _
1
Tob p bls e
Trang 11[SOURCE: EC 6 0 0-4 2:2 0 , 4 2-01-0 , modif ied def i ition]
3.3
but on (cel or b tery)
smal rou d cel or b tery where the overal heig t is les than the diameter
Note 1 to e try: In En ls , th term “b to (c l or b tery)” is o ly u e f or n n-lthium b terie whie th term
“c in (c l or b tery)” is u e for lthium b terie o ly In la g a e oth r th n En ls , th terms “c in” a d
“b to ” are ofte u e interc a g a ly, re ardle s of th ele tro h mic l s stem
3.4
c l
b sic f un tional u it, con istin of an as embly of electrodes, electrolyte, container, terminals
an u ual y se arators, that is a source of electric energ o tained by direct con ersion of
c emical energ
[SOURCE: EC 6 0 0-4 2:2 0 , 4 2-01-01]
3.5
clos d-circ it volta e
CCV (a breviation)
voltage acros the terminals of a b t ery when it is on dis harge
[SOURCE: EC 6 0 0-4 2:2 0 , 4 2-0 -2 , modified ("voltage b twe n the terminals of a cel
or b t ery" re laced by "voltage acros the terminals of a b t ery")]
dis harg (of a primary b tery)
o eration d rin whic a b tery del vers c r ent to an external circ it
3.9
dry (primary) bat ery
primary b t ery in whic the l q id electrolyte is es ential y immo i zed
[SOURCE: EC 6 0 0-4 2:2 0 , 4 2-0 -14, modified]
3.10
ef fe tiv internal re ista c – DC method
the internal d.c resistan e of an electroc emical cel is defined by the f ol owin relation:
)(
)(
)(
AV
i
iU
R
∆
∆
=Ω
Trang 12minimum average time on dis harge whic is met by a sample of b t eries
Note 1 to e try: Th dis h rg te t is c rie o t a c rdin to th s e if i d meth d or sta d rd a d d sig e
to s ow c nformity with th sta d rd a plc ble to th b tery ty e
s ita le a proximate value of the voltage u ed to desig ate or identify a cel , a b tery or an
electroc emical s stem
[SOURCE: EC 6 0 0-4 2:2 0 , 4 2-0 -31, modif ied (ad ition of "(of a primary b tery)" an
n)]
3.15
ope -circ it volta e
OCV (a breviation)
voltage acros the terminals of a cel or b t ery when it is of f dis harge
3.16
primary (cel or b tery)
cel or b tery that is not desig ed to b electrical y rec arged
3.17
round (cel or b tery)
cel or b tery with circ lar cros section
3.18
s rvic output (of a primary b t ery)
service lfe, or ca acity, or energ output of a b tery u der sp cified con ition of dis harge
3.19
s rvic output te t
test desig ed to me s re the service output of a b t ery
Note 1 to e try: A s rvic o tp t te t ma b pre crib d, f or e ample, wh n
Trang 13termin ls (of a primary b t ery)
con u tive p rts of a b tery that provide con ection to an external circ it
Primary b teries are sold mainly in con umer markets In recent ye rs, they have b come
more so histicated in b th c emistry an con tru tion, for example b th ca acity an rate
ca a i ty have in re sed to me t the growin deman s f rom new, b t ery-p wered eq ipment
tec nolog
When desig in primary b teries, the aforementioned con ideration s al b taken into
ac ou t Sp cifical y, their dimen ional conf ormity an sta i ty, their ph sical an electrical
p rorman e an their saf e o eration u der normal u e an forese a le mis-u e con ition
Trang 14Their ph sical s a e s al b desig ed in s c a way that they en ure that the b t eries make
an maintain go d electrical contact at al times
They s al b made of materials that provide go d electrical con u tivity an resistan e to
cor osion
4.1.3.2 Conta t pre s re re ista c
Where stated in the b tery sp cif i ation ta les or the in ivid al sp cification s e ts in
IEC 6 0 6-2, the folowin a pl es:
– a force of 10 N a pled throu h a ste l b l of 1 mm diameter at the centre of e c contact
are f or a p riod of 10 s s al not cau e an a p rent deformation whic mig t prevent
satisfactory o eration of the b tery
NOT Se als IEC 6 0 6-3 f or e c ptio s
4.1.3.3 Cap a d ba e
This typ of terminal is u ed f or b teries whic have their dimen ion sp cified ac ordin to
Fig res 1 to 7 of IEC 6 0 6-2:− an whic have the c l n rical side of the b t ery in ulated
These are es ential y flat metal s r aces ada ted to make electrical contact by s ita le
contact mec anisms b arin again t them
4.1.3.7 Flat or spiral springs
These contacts comprise flat metal strips or spiral y wou d wires whic are in a f orm that
provides pres ure contact
4.1.3.8 Plug-in-soc ets
These are made up of a s ita le as embly of metal contacts, mou ted in an in ulated hou in
or holdin device an ada ted to receive cor esp n in pin of a matin plu
4.1.3.9 Snap f aste ers
These contacts are comp sed of a combination comprisin a stu (non- esi ent f or the
p sitive terminal an a soc et (resi ent for the negative terminal
They s al b of s ita le metal so as to provide eff i ient electrical con ection when joined to
the cor esp n in p rts of an external circ it
Trang 154.1.3.9.2 Sn p f aste er
This typ of terminal con ists of a stu for the p sitive terminal an a soc et for the negative
terminal These s al b made f om nic el plated ste l or other s ita le material They s al
b desig ed to provide a sec re ph sical an electrical con ection, when fit ed with simi ar
cor esp n in p rts for con ection to an electrical circ it
4.1.3.10 Wire
Wire le d may b sin le or multi-stran flexible in ulated tin ed co p r The p sitive
terminal wire coverin s al b red an the negative blac
4.1.3.1 Oth r spring conta ts or cl ps
These contacts are general y u ed on b teries when the cor esp n in p rts of the external
circ it are not precisely k own They s al b of sprin bras or of other material havin
simi ar pro erties
4.1.4 Cla sif ic tion (ele troc emic l s stem)
Primary b teries are clas ified ac ordin to their electroc emical s stem
Eac s stem, with the ex e tion of the zin -ammonium c loride, zin c loride-man anese
dioxide s stem, has b en al ocated a let er denotin the p rtic lar s stem
The electroc emical s stems that have b en stan ardized up to now are given in Ta le 1
Table 1 – Sta dardize ele troc emic l s stems
C Lithium (Li) Org nic ele trolyte Ma g n s dio id (MnO
G Lithium (Li) Org nic ele trolyte Co p r (I ) o id (CuO) 1,5 2,3
L Zin (Zn) Alk l metal h dro id Ma g n s dio id (MnO
2
Z Zin (Zn) Alk l metal h dro id Nic el o y y ro id (NiOOH) 1,5 1,7
NOT 1 Th v lu of th n min l v lta e is n t v rif i ble; th refore it is o ly giv na aref ere c
NOT 2 Th ma imum o e -circ it v lta e (3.15) is me s re a d fin d in 5.5 a d 6.8.1
NOT 3 Wh n referin to a ele tro h mic l s stem, c mmo proto ol is to lst n g tiv ele tro e first,
f olowe b p sitiv ele tro e, ie lthium-iro dis lf i e
Trang 164.1.5 De ig ation
The desig ation of primary b t eries is b sed on their ph sical p rameters, their
electroc emical s stem as wel as modifiers, if ne ded
A comprehen ive explanation of the desig ation s stem (nomen lature) can b f ou d in
a) desig ation, IEC or common;
b) expiration of a recommen ed u age p riod or ye r an month or we k of man f acture
The ye r an month or we k of man facture may b in code;
c) p larity of the p sitive (+) terminal;
d) nominal voltage;
e) name or trade mark of the man facturer or s p l er;
f ) cautionary ad ice
NOT Ex mple of th c mmo d sig atio s c n b fo n in An e D of IEC 6 0 6-2:−
4.1.6.2 Marking of smal bat erie (s e Table 2)
a) Bat eries desig ated in the IEC as smal , mainly category 3 an category 4 b t eries have
a s race to smal to ac ommodate al markin s s own in 4.1.6.1 For these b teries the
desig ation 4.1.6.1a) an the p larity 4.1.6.1c) s al b marked on the b tery Al other
markin s s own in 4.1.6.1 may b given on the immediate p c in in te d of on the
b tery
b) F r P-s stem b teries, 4.1.6.1a) may b on the b t ery, the se l n ta or the
p c age.4.1.6.1c) may b marked on the se l n ta an /or on the b tery 4.1.6.1b),
4.1.6.1d) an 4.1.6.1e) may b given on the immediate p c in in te d of on the b tery
c) Caution f or in estion of swal owa le b t eries s al b given Refer to IEC 6 0 6-4:2 14
(7.2 a) an 9.2) an IEC 6 0 6-5:2 1 (7.1 l) and 9.2) for detais
Trang 17Table 2 – Marking re uireme ts
4.1.6.3 Marking of bat erie re arding method of dispos l
Markin of b t eries with resp ct to the method of disp sal s al b in ac ordan e with local
legal req irements
4.1.7 Interc a ge bi ty: bat ery volta e
Primary b teries as presently stan ardized in the IEC 6 0 6 series can b categorized by
their stan ard dis harge voltage U
s F r a new b tery s stem, its interc an e bi ty by
voltage is as es ed for compl an e with the f ol owin f ormula:
Cur ently, two voltage ran es that conform to the a ove formula have b en identif ied They
are identified by referen e voltage U
r, whic is the midp int of the relevant voltage ran e
Voltage ran e 1, U
The term stan ard dis harge voltage an related q antities, as wel as the method of their
determination, are given in An ex D
_ _ _ _ _ _ _
2
Th sta d rd dis h rg v lta e U
s
wa intro u e to c mply with th prin iple of e p rime tal v rif i bi ty
Neith r th n min l v lta e n r th ma imum of lo d v lta e c mple with this re uireme t
Trang 18n wi b id ntic l m a d n wi b dif fere t f or multi-c l b terie if a s mble with c ls f rom a diff ere t v lta e
ra g th n th s of a alre d sta d rdiz db tery
Voltage ran e 1 en omp s es al presently stan ardized b teries with a nominal voltage of
1,5 V, i.e "no-let er s stem, s stems A, F, G, L, P, S an Z
Voltage ran e 2 en omp s es al presently stan ardized b t eries with a nominal voltage of 3
V, i.e s stems B, C, E, W an Y
Becau e b t eries f om voltage ran e 1 an voltage ran e 2 s ow sig ificantly dif ferent
dis harge voltages, they s al b desig ed to b ph sical y non-interc an e ble Before
stan ardizin a new electroc emical s stem, its stan ard dis harge voltage s al b
determined in ac ordan e with the proced re given in An ex D to resolve its
interc an e bi ty by voltage
WARNING Faiure to c mply with this re uireme t c n pre e t s fety h z rd to th u er, s c a fire, e plo io ,
le k g a d/or d vic d ma e This re uireme t is n c s ary for s fety a d o eratio al re s n
4.2.1 Dis h rge perf orma c
Dis harge p r orman e of primary b t eries is sp cif ied in IEC 6 0 6-2
4.2.2 Dime sional stabi ity
The dimen ion of b teries s al conform with the relevant sp cified dimen ion as given in
IEC 6 0 6-2 an IEC 6 0 6-3 at al times d rin dis harge testin u der the stan ard
con ition given in this sp cification
NOT 1 An in re s in b tery h ig t of 0,2 mm c n o c r with b to c ls of th B, C, G, L, P a d S s stems,
4.2.4 Ope -circ it volta e l mits
The maximum o en-circ it voltage of b teries s al not ex e d the values given in Ta le 1
Dis harge d ration , initial and delayed, of b teries s al me t the req irements given in
IEC 6 0 6-2
When desig in primary b teries, safety u der con ition of inten ed u e an forese a le
mis-u e as pres rib d in IEC 6 0 6-4 an IEC 6 0 6-5 s al b con idered
Trang 195 Perf ormanc – Testing
For the pre aration of stan ard method of me s rin p rf orman e (SMMP) of con umer
go d , refer to An ex E
A ca acity of a primary b t ery may b esta ls ed by electrical dis harge tests as detai ed in
D.2.3 However, u der con umer u age con ition , the ca acities re l sed f om electrical
dis harge test method can vary
The fol owin factors/varia les dramatical y imp ct on o timum ca acity re lsation
a) The c r ent deman fom the external electrical circ itdevice
b) The f eq en y of c r ent deman (Contin ou or intermit ent u age)
c) The minimum voltage at whic the device wi satisf actori y o erate (Cut of f voltage)
d) The temp rature of o eration
From the varia les l sted in a) to d), hig c r ent deman f or prolon ed p riod coupled with a
hig c t of f voltage an low temp rature re resent the worst case condition res ltin in
sig ificant ca acity los
Becau e the electrical y or c emical y derived ca acity of a primary bat ery can ot b rel a ly
u ed in any calc lation of ultimate b tery p r orman e it is nevertheles es ential to con ey
to the u er some ide of b t ery p rf orman e/l fe when u ed in typical b t ery p wered
devices It s ould however b noted that s c desig ated ‘a pl cation tests’ (defined in
6 0 6-2) may not entirely re lcate a device/a plcation there b in man variation e c with
dif ferin electrical req irements in the marketplace Furthermore b tery p rf orman e may b
f urther aff ected by one or more of the con ition in a) to d) a ove
The f ol owin has therefore b en derived fom ISO/IEC Guide 3 :19 2
5.2 Dis harge te tin
The dis harge tests in this stan ard fal into two categories:
– a pl cation tests;
– service output tests
In both categories of tests, dis harge lo d are sp cif ied in ac ordan e with 6.4
The test method of determinin the lo d an test con ition are as given in 5.2.2
a) The eq ivalent resistan e is calc lated f rom the average c r ent an average o eratin
voltage of the eq ipment u der lo d Con tant c r ent or con tant p wer lo d are also
p rmited f or a plcation ex ibitin these typ s of p wer deman p t ern
b) The fu ctional en -p int voltage an the eq ivalent resistan e lo d, c r ent lo d, or
con tant p wer values are o tained f rom typical a pl cation eq ipment me s rements
c) The median clas defines the lo d value an the en -p int voltage to b u ed f or the
dis harge test
d) If the data are con entrated in two or more widely se arated groups, more than one test
may b req ired
Trang 20Ap lcation tests may b ac elerated by dis harge lo d, dai y p riod d ty c cle, or b th The
sp cified values f or lo d an time intermit en y s ould take the fol owin f actors into
con ideration:
– dis harge eff i ien y of the b tery relative to the a pl cation
– typical d ty c cle u e p t ern for the a pl cation
– total time to con u t the test not to ex e d 3 day
Some fixed resistan e tests have b en c osen to permit simpl city of desig an en ure
rela i ty of the test eq ipment, despite the f act that, in sp cif i in tan es, con tant c r ent or
con tant watage tests may b a b t er re resentation of the a pl cation
In the f uture, alternative or ad itional lo d con ition may b neces ary to eff ectively
re resent the ran e of a pl cation in u e It is l kely that the lo d c aracteristic of a
p rtic lar category of eq ipment wi c an e with time in a develo in tec nolog
The precise determination of the fu ctional en -p int voltage of the eq ipment is not alway
p s ible The dis harge con ition are at b st a compromise selected to re resent a category
of eq ipment whic may have widely divergent c aracteristic
Nevertheles , in spite of these l mitation , the derived ap l cation test is the b st a pro c
k own for the estimation of b t ery ca a i ty for a p rtic lar category of eq ipment
NOT In ord r to minimiz th prolferatio of a plc tio te ts, th te ts s e if i d targ t to b th s a c u tin
f or 8 % of th mark t b b tery d sig atio
5.2.2.2 Appl c tion te ts with multiple loa s
For a pl cation test with multiple lo d , the lo d order d rin a c cle s al start with the
he viest lo d an move to the l g test lo d u les otherwise sp cified
For service output tests, the value of the lo d resistor s ould b selected s c that the
service output a proximates 3 day
When ful ca acity is not re l zed within the req ired time s ale, the service output may b
exten ed to the s ortest s ita le d ration there f ter by selectin a dis harge lo d of hig er
ohmic value, as def i ed in 6.4
5.3 Conf orma c c e k to a spe ifie minimum a era e duration
In order to c ec the conf orman e of a b tery to an dis harge tests sp cified in
IEC 6 0 6-2 an 6 0 6-3, the test s al b car ied out as folows:
a) Test eig t b teries
b) Calc late the average without the ex lu ion of an res lt
c) If this average is eq al to or gre ter than the sp cified fig re an no more than one
b tery has a service output of les than 8 % of the sp cified fig re, the b teries are
con idered to conform to service output
d) If this average is les than the sp cified f i ure an /or more than one b t ery has a service
output of les than 8 % of the sp cified fig re, re e t the test on another sample of eig t
b teries an calc late the average as previou ly
e) If the average of this secon test is eq al to or gre ter than the sp cified f i ure an no
more than one b tery has a service output of les than 8 % of the sp cif ied fig re, the
b teries are con idered to conf orm to service output
Trang 21f ) If the average of the secon test is les than the sp cified fig re an /or more than one
b tery has a service output of les than 8 % of the sp cified fig re, the b teries are
con idered not to conform an no f urther testin is p rmit ed
g) For the purp ses of verifyin compl an e with this stan ard, con itional ac e tan e may
b given after completion of the initial dis harge tests
NOT Dis h rg p rf orma c of primary b terie is s e ifie in IEC 6 0 6-2
5.4 Calc lation method of the spe ifie v lue of a minimum a era e duration
Af ter the service output has b en determined u der the sp cif ied en ironmental con ition ,
the dis harge s al b contin ed in the same way u ti the closed circ it voltage dro s for the
f irst time b low 4 % of the nominal voltage of the b tery The req irements of 4.1.3, 4.2.2
an 4.2.3 s al b met
NOT For watc b terie , th vis al e amin tio f or le k g is c rie o t in a c rd n e with Cla s 8 of
IEC 6 0 6-3:2 1
6 Perf ormanc – Test conditions
6.1 Stora e a d dis h rg conditions
Storage b f ore dis harge testin an the actual dis harge test is car ied out u der wel
-defined con ition Unles otherwise sp cified, the con ition given in Ta le 3 s al a ply
Dis harge con ition s own are f urther refer ed to as stan ard con ition
Table 3 – Con itions f or stora e bef ore a d d ring dis harge te tin
a
Durin s ort p rio s th stora e temp rature ma d viate fom th s lmits with ut e c e in (2 ± 5) °C
b
This te t is c rie o t wh n a stora e te t at hig temp rature is re uire Perorma c re uireme ts are th
s bje t of a re me t b twe n th ma ufa turer a d th c stomer
c
Baterie to b store u p c e
d
Ex e t “P” s stem: (5 ± 10) % RH
Trang 226.2 Comme c me t of dis harge te ts af ter stora e
The p riod b twe n the completion of storage an the start of a delayed dis harge test s al
not ex e d 14 day
Durin this p riod the b t eries s al b ke t at (2 ± 2) °C an (5 + 2 / -4 ) % RH (ex e t
f or P-s stem b t eries where the relative h midity s al b (5 ± 10) % RH)
At le st one day in these condition s al b al owed f or normal zation b fore startin a
dis harge test af ter storage at hig temp rature
6.3 Dis harge te t condition
In order to test a b tery it s al b dis harged as sp cified in IEC 6 0 6-2 or IEC 6 0 6-3
u ti the voltage on lo d drops f or the f irst time b low the sp cif ied en -p int The service
output may b expres ed as pulses, d ration, ca acity, or energ
When IEC 6 0 6-2 or IEC 6 0 6-3 sp cify service outputs for more than one dis harge test,
b teries s al me t al of these req irements in order to comply with this sp cification
The value of the resistive lo d (whic in lu es al p rts of the external circ it s al b as
sp cified in the relevant sp cification s e t an s al b ac urate to ± 0,5 %
When formulatin new tests, the resistive lo d s al , whenever p s ible, b as s own in Ta le
4 together with their decimal multiples or s b-multiples
Table 4 – Re istiv loa s for new te ts
The p riod on-dis harge an of f-dis harge s al b as sp cified in IEC 6 0 6-2
When f ormulatin new tests, whenever p s ible, one of the fol owin dai y p riod s ould b
Trang 236.6 Te t condition tolera c s
Unles otherwise sp cified, the toleran es given in Ta le 6 s al a ply
Table 6 – Te t condition tolera c s
6.7 Activ tion of ‘P’-s stem bat erie
A p riod of at le st 10 min s al ela se b twe n activation an the commen ement of
electrical me s rement
The ac urac of the me s rin eq ipment s al b ≤ 0,2 % an the precision s al b ≤ 5 %
of the value of the last sig ificant digit
The u e of sampl n plan or prod ct q al ty in ices s ould b agre d b twe n the
man f acturer an the purc aser
Where no agre ment is sp cified, ref er to ISO 2 5 an ISO 217 7 for sampl n an q alty
compl an e as es ment ad ice
A code of practice f or b t ery p c agin , s ipment, storage, u e an disp sal can b fou d in
An ex G
Trang 24Annex A
(nor mative)
Criteria for the standardization of bat eries
Bateries an electroc emical s stems s al me t the fol owin req irements to ju tify their
initial in lu ion or on oin retention in the IEC 6 0 6 series:
a) The b t ery or b t eries of this electroc emical s stem are in mas prod ction
b) The b t ery or b t eries of this electroc emical s stem are avai a le in several market
places of the world
c) The b tery is prod ced by at le st two in e en ent man facturers, the p tent holder(s)
of whic s al conf orm to the req irements contained in 2.14 of the ISO/IEC Directives,
Part 1, Referen e to p tented items
d) The b tery is prod ced in at le st two dif ferent cou tries or, alternatively, the b tery is
purc ased by other international an in e en ent b tery man facturers an sold u der
their comp n la el
The items of Ta le A.1 s al b in lu ed in an new work pro osal to stan ardize a new
in ivid al b t ery or electroc emical s stem
Table A.1 – Items ne e s ry to sta dardize
Co forma c stateme t to items a) to d) a o e Co forma c stateme t to items a) a d b) a o e
De ig atio a d ele tro h mic l s stem Re omme d d d sig atio leter
Ma imum o e circ it v lta e
Ele trolyte
Trang 25Annex B
(inf or mative)
Recommendations f or equipment design
B.1 Te hnic l l aison
It is recommen ed that comp nies prod cin b tery-p wered eq ipment maintain close
l aison with the b tery in u try The ca a i ties of existin b teries s ould b taken into
ac ou t at desig in e tion Whenever p s ible, the b t ery typ selected s ould b one
in lu ed in IEC 6 0 6-2 The eq ipment s ould b p rmanently marked with the IEC
desig ation, grade an size of b tery whic wi give o timum p rf orman e
Desig comp rtments so that b t eries are e si y in erted an do not fal out The dimen ion
an desig of comp rtments an contacts s ould b s c that b teries complyin with this
stan ard wi b ac e ted In p rtic lar, the eq ipment desig er s ould not ig ore the
toleran es given in this stan ard, even if a national stan ard or a b tery man facturer cal s
f or smal er b t ery toleran es
The desig of the negative contact s ould make al owan e for an reces of the b t ery
terminal
Cle rly in icate the typ of b tery to u e, the cor ect p larity al g ment an direction f or
in ertion
Use the s a e an /or the dimen ion of the p sitive (+) an negative (–) b tery terminals in
comp rtment desig s to prevent the reverse con ection of b teries Positive (+) an negative
(–) b tery contacts s ould b visibly dif ferent in form to avoid conf usion when in ertin
b teries
Batery comp rtments s ould b electrical y in ulated f rom the electric circ it an p sitioned
so as to minimize p s ible damage an /or ris of injury Only the b tery terminals s ould
ph sical y contact the electric circ it Care s ould b taken in the c oice of materials an the
desig of contacts to en ure that eff ective electrical contact is made an maintained u der
con ition of u e even with b t eries at the extremes of dimen ion p rmit ed by this stan ard
Batery an eq ipment terminals s ould b of comp tible material an low electrical
resistan e
Batery comp rtments with p ral el con ection are not recommen ed sin e a wron ly placed
b tery wi res lt in c argin con ition
Eq ipment desig ed to b p wered by air de olarized b t eries of either the "A" or "P" s stem
s al provide for adeq ate air ac es For the "A" s stem, the b tery s ould prefera ly b in
an uprig t p sition d rin normal o eration For "P" s stem b t eries conformin to Fig re 9
of IEC 6 0 6-2:−, p sitive contact s ould b made on the side of the b tery, so that air
ac es is not imp ded
Althou h b t eries are very mu h improved regardin their resistan e to le kage, it can sti
oc ur oc asional y When the b tery comp rtment can ot b completely isolated f rom the
eq ipment, it s ould b p sitioned so as to minimize p s ible damage