Most com-mon uses of asbestos—applications such as pipeline insulation, clothing, and roofing felt—were banned in the United States in 1990, and virtually all asbestos products were bann
Trang 1with other fibers and spun or milled into cloth The
shorter, or “nonspinning,” fibers are generally made
into compressed, molded, or cast products, such as
as-bestos pipe and sheet, in which the fibers are added to
a binder such as portland cement or plastic Such
products account for most of the asbestos produced
each year Of the six different minerals that have been
produced as asbestos, only crocidolite and amosite
have been produced in important quantities
Produc-tion of anthophyllite, tremolite, and actinolite has
been extremely limited and was nonexistent by the
end of the twentieth century
Uses of Asbestos
Although the individual properties of asbestos
miner-als differ from one another, they share to varying
de-grees several properties that make them useful and
cost-effective These include nonflammability, great
resistance to heat and acid attack, high tensile strength
and flexibility, low electrical conductivity, resistance
to friction, and a fibrous habit
Over a span of only a few years, the public’s view of
asbestos changed dramatically: Once considered a
useful commodity, asbestos became known as an
ex-tremely dangerous material The change began with
passage of the Clean Air Act (1972), which classified asbestos as a carcinogenic material because studies of workers exposed to high concentrations of asbestos dust for many years showed a high incidence of asbes-tosis, a lung disease that decreases the ability to breathe, and mesothelioma, a cancer of the lungs Then, in 1973, a lawsuit against a number of asbestos manufacturers on behalf of an asbestos worker was decided against the companies Litigation mounted, and, in 1982, manufacturer Johns-Manville filed for bankruptcy in the face of overwhelming litigation; eventually, as a compromise measure, the company established a $2.5 billion fund to pay future asbestos claims
Widespread publicity concerning asbestos hazards led to a near hysteria among the general public; many people were afraid to send their children to a school unless asbestos insulation had been removed People brought lawsuits demanding that asbestos be re-moved from public buildings The courts awarded large damage rewards based on the argument that low-level exposure to asbestos should be considered dangerous because a safe level of exposure had not been scientifically established This led to the “single fiber” concept—that exposure to only one fiber of as-bestos may be deadly—in keeping with a widely held public perception that there should be no exposure
to carcinogenic materials in the environment The
“asbestos scare” was largely the result of mass media sensationalism and resultant political and legal pres-sure rather than the result of scientific investigation For example, very few people realized that, according
to scientific estimates, a person breathing normal out-door air inhales nearly 4,000 asbestos fibers per day,
or more than 100 million over a lifetime
Asbestos can be a health hazard, but the serious-ness depends on the length of exposure, the amount
of asbestos in the air, and the type of asbestos involved The danger to miners and others working with asbes-tos in unprotected conditions is demonstrable, but the danger to the general public from minimal expo-sure has been greatly exaggerated Some researchers believe that the danger is so small as to be virtually
nonexistent Melvin Benarde in Asbestos: The Hazard-ous Fiber (1990) outlined the statistical risks (the
num-ber of deaths expected per 100,000 people) for a number of potential hazards The risk of dying from nonoccupational exposure to asbestos is one-third the risk of being killed by lightning and nearly five thousand times less than the chance of dying in a car
U.S End Uses of Asbestos,
1977 vs 2003
Metric Tons
Coatings & compounds 32,500 1,170
Insulation: electrical 3,360 —
Packing & gaskets 25,100 —
Source: Data from the U.S Geological Survey.
Note: U.S mining of asbestos ended in 2002.
Trang 2accident Nevertheless, by the mid-1990’s more than
$35 billion had been spent on asbestos abatement in
rental, commercial, and public buildings Most
com-mon uses of asbestos—applications such as pipeline
insulation, clothing, and roofing felt—were banned
in the United States in 1990, and virtually all asbestos
products were banned in the country by 1996
It has been estimated that in the time period from
1965 to 2029 there will be 432,465 asbestos-related
cancers in the United States Although this figure has
been disputed by some epidemiologists and other
ex-perts, it is enough to indicate the misery that many
will suffer because of their exposure to asbestos
Nev-ertheless, the litigation-centered approach to
asbes-tos issues in the United States has been criticized In a
2003 report, the Manhattan Institute’s Center for
Le-gal Policy described asbestos litigation as the
longest-running mass tort in the history of the nation and
arguably the most unjust Some critics have claimed
that the massive asbestos tort litigation is more likely
to enrich lawyers than relieve victims The Manhattan
Institute estimated that of the $70 billion paid out by
companies for asbestos claims, $40 billion has gone to
plaintiffs and defense lawyers Numerous companies
have been driven into bankruptcy by asbestos lawsuits,
some of which had only a tangential connection to the original asbestos exposure Of the twenty-nine com-panies that filed for bankruptcy in the years from 2000
to 2002 because of asbestos litigation, six were valued
at more than $1 billion These included such indus-trial giants as Owens Corning, W R Grace, and U.S Gypsum As the companies that directly produced as-bestos have gone under, plaintiffs’ lawyers have in-creasingly sued companies outside the asbestos and building products industry Companies in more than one-half of all industries in the United States have been sued over asbestos With the total eventual cost
of asbestos litigation estimated at $200 billion, Con-gress has considered several proposals to establish a compensation fund in place of litigation In 2004, in-dustrial states such as Michigan and Ohio enacted measures to implement some form of asbestos tort re-form
Although asbestos use has become rare in devel-oped countries, the same cannot be said of develop-ing economies In most of Europe and North Amer-ica, use of asbestos is strictly limited or banned by law However, emerging nations have continued and even increased the use of asbestos in manufacturing and building Countries such as China, India, Brazil, Iran,
Data from the U.S Geological Survey, U.S Government Printing Office, 2009.
220,000
175,000
380,000
300,000
925,000
100,000
Metric Tons
1,050,000 900,000
750,000 600,000
450,000 300,000
150,000 Zimbabwe
China
Canada
Brazil
Kazakhstan
Russia
Other countries 75,000
World Mine Production of Asbestos, 2008
Trang 3and South Korea are major consumers of asbestos
As-bestos mining is widespread in Africa Many
develop-ing nations consider the low cost and the effectiveness
of asbestos as an industrial material to outweigh the
health risks The adverse effects of asbestos as an
in-dustrial pollutant are below the surface and
long-term Many of these nations face a more obvious
health risk from such epidemics as HIV/AIDS,
chol-era, tuberculosis, and malaria, which have been
linked to poverty or inadequate infrastructure
Like-wise, many developing nations have accepted a great
deal of air, water, and ground pollution as the price of
accelerating the growth of fragile economies
Asbes-tos has apparently been accepted as another
pollut-ant Certainly these countries lack the extensive and
ubiquitous legal and regulatory system of the United
States that has focused attention on asbestos
How-ever, in some African nations, such as South Africa
and Swaziland, compensation for workers suffering
the effects of asbestos has been provided
China is perhaps the most dynamic and
fastest-growing of all emerging markets Many have
specu-lated that China will emerge as the most important
economy of the twenty-first century It is worth noting,
therefore, some facts about asbestos consumption in
China China continues to make extensive use of
as-bestos Production of asbestos in China has remained
steady since 1995 China is one of the five leading
pro-ducers of asbestos but is perhaps its leading consumer
Imports of asbestos to China rose from 1,083 metric
tons in 1990 to 145,425 metric tons in 2003, an
in-crease nearly 150-fold Estimates indicate that more
than 100,000 workers in China are exposed to asbestos
Although the Chinese government has official
poli-cies against pollutants, they are often not enforced
With the United States and China taking such
dif-ferent approaches to the use of asbestos, it is not yet
possible to speak of a unified world approach to this
industrial product Certainly its use, associated health
risks, and remediation represent one of the most
im-portant confluences of industry, medical concerns,
and law in the world economy
Gene D Robinson, updated by Howard Bromberg
Further Reading
Carroll, Stephen, et al Asbestos Litigation Santa
Monica, Calif.: Rand Corporation, 2005
Castleman, Barry Asbestos: Medical and Legal Aspects.
5th ed New York: Aspen, 2005
Chatterjee, Kaulir Kisor “Asbestos.” In Uses of
Indus-trial Minerals, Rocks, and Freshwater New York: Nova
Science, 2009
Craighead, John E., and Allen R Gibbs, ed Asbestos and Its Diseases New York: Oxford University Press,
2008
Deffeyes, Kenneth S “Asbestos.” In Nanoscale: Visual-izing an Invisible World Illustrations by Stephen E.
Deffeyes Cambridge: Massachusetts Institute of Technology Press, 2009
Dodson, Ronald, and Samuel Hammar, eds Asbestos: Assessment, Epidemiology, and Health Effects Boca
Raton, Fla.: CRC Press, 2005
Guthrie, George D., Jr., and Brooke T Mossman, eds
Health Effects of Mineral Dusts Washington, D.C.:
Mineralogical Society of America, 1993
Harben, Peter W., and Robert L Bates Industrial Min-erals: Geology and World Deposits London: Industrial
Minerals Division, Metal Bulletin, 1990
Kogel, Jessica Elzea, et al., eds “Asbestos.” In Indus-trial Minerals and Rocks: Commodities, Markets, and Uses 7th ed Littleton, Colo.: Society for Mining,
Metallurgy, and Exploration, 2006
McCulloch, Jock, and Geoffrey Tweedale Defending the Indefensible: The Global Asbestos Industry and Its Fight for Survival New York: Oxford University
Press, 2008
McDonald, J C., et al “The Health of Chrysotile
As-bestos Mine and Mill Workers of Quebec.” Archives
of Environmental Health 28 (1974).
Maines, Rachel Asbestos and Fire: Technological Trade-offs and the Body at Risk New Brunswick, N.J.:
Rutgers University Press, 2005
Skinner, H Catherine W., Malcolm Ross, and Clifford
Frondel Asbestos and Other Fibrous Materials: Miner-alogy, Crystal Chemistry, and Health Effects New York:
Oxford University Press, 1988
Web Sites Manhattan Institute Center for Legal Policy Trial Lawyers Inc.: Asbestos
http://www.triallawyersinc.com/asbestos/asb01.html U.S Geological Survey
Asbestos: Statistics and Information http://minerals.usgs.gov/minerals/pubs/
commodity/asbestos U.S Geological Survey Mineral Commodities Profiles—Asbestos http://pubs.usgs.gov/circ/2005/1255/kk
Trang 4See also: Clean Air Act; Health, resource
exploita-tion and; Hydrothermal soluexploita-tions and
mineraliza-tion; Metamorphic processes, rocks, and mineral
de-posits; Silicates
Asphalt
Category: Products from resources
Where Found
Before the growth of the petroleum industry in the
early twentieth century, when asphalt began to be
mass-produced, naturally occurring asphalt was
found in pools of petroleum-heavy deposits, most
no-tably Trinidad’s 46-hectare Pitch Lake (off the coast
of Venezuela), the 4,000-hectare Bermudez Lake in
Venezuela, and areas around the Dead Sea basin in
Is-rael and Jordan
Primary Uses
Asphalt is most associated with road-surface paving
Apart from highway construction and repairs, asphalt
is used for airport runways, running tracks, and
drive-ways In addition, asphalt is a waterproofing agent in
fabrics, irrigation systems, roofing shingles, jetties
and sea walls designed to combat beach erosion, and
insulation More than 60 billion metric tons of
manu-factured asphalt are used annually in the United
States alone
Technical Definition
Asphalt is a by-product of petroleum refining, either
occurring naturally over geologic eras or processed
industrially in the controlled refining process called
fractional distillation that occurs once naphtha,
gaso-line, and kerosene have all been extracted from the
crude It is difficult to define a single chemical profile
because asphalt varies depending on the grade of
crude petroleum and the type of refining production
used Generally, asphalts contain saturated and
unsat-urated aliphatic compounds (organic compounds
whose carbon atoms configure in open branches
rather than closed rings) and aromatic compounds
(organic compounds whose carbon atoms configure
in closed rings) with up to 150 carbon atoms Asphalt
contains about 80 percent carbon, 10 percent
hydro-gen, and 6 percent sulfur with trace amounts of
oxy-gen and nitrooxy-gen Molecular weight varies These
compounds are further classified by their solubility— more insoluble compounds are called asphaltenes and less soluble compounds maltenes
Description, Distribution, and Forms Asphalt is a dark (brown or black), cementitious (highly adhesive) material Its predominant elements are bitumens, solid and/or semisolid high-molecular-weight hydrocarbons Because more than 80 percent
of commercially produced asphalt is used for paving, the properties of asphalt are graded according to its performance as a pavement adhesive, particularly how well it holds up over time, specifically in the areas
of aging, stiffening, and cracking
Only 5 percent of the asphalt used today is natu-rally occurring Its most prominent natunatu-rally occur-ring site is Pitch Lake in the petroleum-rich southwest corner of the island of Trinidad, near the town of La Brea Although difficult to determine dimensions with any accuracy because it grows and shrinks, this
“lake”—it is more accurately a sludgy 40-plus-hectare mineral deposit created by a slow underground seep-age of asphalt, or pitch—is estimated to be more than
35 meters across and 107 meters deep at its deepest point (the edges of the lake are crusty and support weight, but toward the center of the lake, the pitch becomes characteristically sticky and far more hazard-ous, easily swallowing entire objects) Given its dimen-sions, the lake has provided an apparently inexhaust-ible supply of asphalt for centuries—large holes left
by removing asphalt are quickly filled in as the lake maintains a kind of fluid dynamic Western explorers were fascinated by the phenomena of this vast tar lake, not merely for the usefulness of the asphalt (they im-mediately used it to upgrade the waterproofing on their ships) but because the lake also preserved the re-mains of prehistoric mammals and birds
Commercially produced asphalt is primarily a taffylike binder known as asphaltic concrete Asphal-tic concrete, a tacky, ductile resin suspended in an oily medium, maintains the integrity of aggregate parti-cles Because asphaltic concrete is highly sticky, it must be heated into liquid to be used for pavement construction It is most often sprayed on a graded roadbed It is then compacted into the proper density, usually 25 to 30 centimeters Because it solidifies into
a tough and flexible surface able to maintain its integ-rity against both the weight and frequency of traffic and the deformations from weather conditions (nota-bly ice and extreme heat), asphalt remains the
Trang 5mary roadway surface Given the diminishing supply
of fossil fuel and concerns over the depletion of that
resource, asphaltic concrete is attractive because more
than 80 percent of removed asphalt can be recycled
for new road projects
History
Asphalt was used as early at 3600 b.c.e by the
Sumer-ians as a mortar adhesive for paving and building and
as a waterproofing agent in canal construction and
public pools (records indicate it also was used for
medical treatments, statuar y enhancement, and
mummification throughout the Middle East) Pitch is
mentioned early in the Bible: It binds Noah’s ark and
later makes waterproof the bulrush basket in which
the baby Moses is set adrift on the Nile
Following the discovery of huge natural deposits of
pitch in South America in the fifteenth and sixteenth
centuries (notably by Sir Walter Ralegh), asphalt
be-came a commercially viable waterproofing agent for
the burgeoning shipbuilding industry Not until 1870,
however, was asphalt first tested for paving The idea
came from accounts discovered among Incan archives
dating back to the twelfth century A stretch of streets
in Newark, New Jersey, was made of Trinidad asphalt Its appeal was evident—it was cheap to import, easy to apply, flexible, and once hardened made for a smooth ride Within six years, asphalt was selected for a most ambitious—and prestigious—paving project: Penn-sylvania Avenue in Washington, D.C By the turn of the century, more than 35 million square meters of streets in America were asphalt With the rise of the oil industry, however, commercially produced asphalt became more profitable
Obtaining Asphalt Asphalt may be obtained directly from sludgy beds near petroleum fields However, far more asphalt is obtained as a small fraction of residue distilled during the refining process of crude oil Heavy crude oil is heated to nearly 370° Celsius in large furnaces As the crude is processed, lighter components vaporize and are released into the atmosphere through refinery towers (in the early 1980’s, facing pressure from envi-ronmental groups, the petroleum industry over-hauled the distillation towers to minimize pollution)
To render the remaining asphalt into asphaltic ce-ment, the residue is distilled further through a
Russian workers repave an asphalt road on the outskirts of Abakan (Kolbasov Alexander/ITAR-TASS/Landov)
Trang 6uum process designed to prevent the residue from
cracking, and then it is mixed with the appropriate
ag-gregate materials, most commonly crushed rock, slag,
sand, and/or cement stone In turn, the asphalt must
be stored (and transported) at a constant 65.55°
Cel-sius to ensure liquidity If the asphalt must be
trans-ported a considerable way, kerosene or diesel oil can
be temporarily added and then separated before the
asphalt is applied to the roadbed
Uses of Asphalt
Long before the automobile made highway
construc-tion a pressing concern, as thousands of kilometers of
roadway needed to be laid quickly and economically,
asphalt was valued because it was waterproof It
revo-lutionized the shipping industry because of its
caulk-ing ability Even in modern society, asphalt helps
so-lidify sea walls to protect against the effects of tides,
waves, and harsh weather In addition, asphalt lines
the retaining tanks in industrial fish hatcheries,
pre-serves the integrity of irrigation systems (before
as-phalt, up to one-third of water transported would be
lost in transit), and maintains holdings by providing
underlining for reservoirs Furthermore, asphalt has
become a primary liner for the disposal of hazardous
waste and a liner at landfill sites
In addition, because it is waterproof and fire
retar-dant, asphalt can be used, when combined with felt
and mineral granules, to produce the familiar
rectan-gular roofing shingles This asphalt is slightly harder
than paving asphalt (it is typically heated at a much
higher temperature to make it less flexible) Asphalt
shingles are remarkably adaptable to a variety of
roof-ing needs and styles; shroof-ingles can be adjusted for the
slope of the roof, climate conditions, and even house
design
However, asphalt is best known as a paving agent It
is durable, tough, and flexible enough to provide a
comfortable riding surface Industry standards
mea-sure durability of standard asphalt roadways at fifteen
to twenty years That longevity is most often
compro-mised by cracks from water seeping into the surface
during the winter, freezing, and then cracking the
up-per layers or by ruts that appear during hot summers
when the asphalt softens However, asphalt provides
for relatively easy repairs The durability of asphalt,
particularly its capacity to hold up under constant
traffic and enormous weights, has made it the
pri-mary coating for airplane runways For much the
same reason, asphalt is also used for railroad beds and
even subway system track beds Finally, asphalt is used for smaller, high-volume traffic surfaces such as walk-ing trails, tennis courts, bikwalk-ing paths, runnwalk-ing tracks, basketball courts, golf-cart paths, and playgrounds Users of these recreational surfaces appreciate the give in asphalt, as compared to concrete surfaces In
1986, the National Center for Asphalt Technology (NCAT) was established at Auburn University to de-velop asphalt production quality
Joseph Dewey
Further Reading
Karnes, Thomas L Asphalt Politics: A History of the Amer-ican Highway System Jefferson, N.C.: McFarland,
2009
Lavin, Patrick Asphalt Pavements: A Practical Guide to Design, Production, and Maintenance for Engineers and Architects London: Spon Press, 2003.
Nicholls, Cliff Asphalt Surfacing: A Guide to Asphalt Surfacings and Treatments Used for the Surface Course of Road Pavements London: Spon Press, 1998 O’Flaherty, C A Highways: The Location, Design, Con-struction, and Maintenance of Road Pavements 4th ed.
Oxford: Butterworth-Heinemann, 2002
Web Site National Center for Asphalt Technology http://www.eng.auburn.edu/center/ncat See also: Petroleum refining and processing; Renew-able and nonrenewRenew-able resources; Transportation, energy use in
Aspinall, Wayne
Category: People Born: April 3, 1896; Middleburg, Ohio Died: October 9, 1983; Palisade, Colorado
Aspinall, a Colorado Democrat, served in the U.S Congress from 1948 to 1972 From 1958 to 1972, he chaired the House Interior and Insular Affairs Com-mittee, shaping some of the most important natural re-source legislation in American history.
Biographical Background Wayne Norviel Aspinall’s shadow looms large over the modern American West After growing up near
Trang 7sade, Colorado, on the Grand (now Colorado) River,
Aspinall attended Denver University, served in World
War I, became a schoolteacher, obtained a law degree,
and ran a peach orchard business Always active in
lo-cal Democratic Party politics, he served as a state
rep-resentative and senator for sixteen years before he was
elected to Congress in 1948
Aspinall quickly made a name for himself as an
ex-pert on public land and federal reclamation issues In
1958, he began chairing the House Interior and
Insu-lar Affairs Committee, a post he did not relinquish
un-til after his defeat in the 1972 Colorado primary
Dur-ing Aspinall’s twenty-four-year congressional career,
his name became synonymous with some of the most
notable legislation that shaped the landscape of the
American West, including the Upper Colorado River
Storage Act (1956), the Wilderness Act (1964), and
the Colorado River Basin Act (1968) From 1964 until
1970, he chaired the Public Land Law Review
Com-mission, which made dozens of recommendations for
reforming the management of the nation’s federal
lands
Impact on Resource Use
By the mid-1960’s, Aspinall’s strict adherence to a
multiple-use philosophy of resource management
had made him a target for environmentalist criticism
In 1970, political columnist Jack Anderson labeled
Aspinall the environmentalists’ “most durable foe”
and accused him of defending timber, oil, cattle, and
chemical interests “against the beauty of American
nature.” To Aspinall, nature had been placed in the
stewardship of humankind, and while he appreciated
the American West’s beauty, he always favored the
controlled use of its resources over what he saw as the
program of “extreme” environmentalists who, in his
view, wanted to “lock up” the region’s resources
Steven C Schulte
See also: Bureau of Reclamation, U.S.; Dams; Energy
politics; Irrigation; Public lands; Wilderness Act
Astor, John Jacob
Category: People
Born: July 17, 1763; Waldorf, near Heidelberg,
Germany
Died: March 29, 1848; New York, New York
Astor, a leader in early American capitalism, founded the American Fur Company, considered the first Amer-ican business monopoly Astor’s astounding financial success, although atypical, pointed to the fortunes that could be made from the exploitation of resources in the young and resource-rich United States.
Biographical Background
As a young man aboard a ship from Germany, John Ja-cob Astor learned about the lucrative fur trade in North America In 1786, three years after arriving in New York City, he opened a fur-goods store and began dealing directly with American Indians to secure his furs In 1796, as his area of activity expanded, Astor se-cured a charter from the British East India Company This charter opened foreign markets, especially the rich fur market of China
John Jacob Astor earned most of his multimillion-dollar fortune in the fur trade (Library of Congress)
Trang 8Impact on Resource Use
Astor established the American Fur Company in 1808
In 1811, in an attempt to gain control of fur trade in
the Northwest, he founded the town of Astoria in
Ore-gon However, this plan failed when the British
cap-tured Astoria during the War of 1812 The setback was
temporary, and by 1827, Astor had obtained his
mo-nopoly of the American fur trade
Astor’s trading empire benefited from his
friend-ship with U.S presidents such as Thomas Jefferson,
who appointed Astor executive agent in the
North-west An Astor ship was also allowed to go to China
during the Embargo Act of 1807, producing a profit
of $200,000 Exploitation of human and natural
re-sources was the inevitable result of Astor’s activities
American Indians, to whom the profit motive was
hitherto unknown, were exploited because of their
skill in obtaining animal furs The tremendous
popu-larity of furs led to exploitation of the animals from
which furs were obtained
In 1834, Astor retired from the fur-trading business
to concentrate on investments in New York City His
estate, worth $20 million when he died, made him
the wealthiest person in the United States He left
$400,000 to establish the Astor Library, now part of
New York City Public Library
Glenn L Swygart
See also: Capitalism and resource exploitation;
En-dangered Species Act; Forests; United States;
Wild-life
Athabasca oil sands
Category: Energy resources
Where Found
The Athabasca oil sands are located in the Athabascan
basin of northeastern Alberta, Canada, near the
Sas-katchewan border The Athabasca River runs through
the region—hence its name With two smaller oil sand
deposits located elsewhere in the province, Alberta
has a total of about 140,200 square kilometers of oil
sands, the largest quantity in the world There are also
oil sands located outside Canada, primarily in
Vene-zuela
Primary Uses With industrial processes, bitumen can be extracted from the oil sands and upgraded into light crude oil Although the First Nations (Canadian aborigines) used the tarlike substance to waterproof and patch their boats, in modern times the oil sands have one commercial use: the production of crude oil To pro-duce crude oil, an energy-intensive process is re-quired to extract the bitumen from the thick, sludgy, sandy substance Bitumen is a heavy, viscous oil that can be industrially upgraded into synthetic crude oil, which in turn is refined into gasoline and diesel fuels
Technical Definition The Athabasca oil sands consist of a tarlike mixture of about 80 to 85 percent sand and rich mineral clays, 10
to 12 percent bitumen, and 4 to 6 percent water The valuable resource in this mixture is the bitumen Bitu-men is a heavy, black, asphaltlike substance that has been pressurized underground for millions of years but not long enough to be concentrated into coal or light sweet crude oil Nonetheless, it is a form of crude oil that can be processed for commercial use Tech-nically, bitumen is a mix of petroleum hydrocarbons with a density greater than 960 kilograms per cubic meter
Description, Distribution, and Forms Oil sands are a viscous mix of hydrocarbons and can
be found throughout the world but most prevalently
in Alberta, Canada While the Athabasca region has the largest quantity of oil sands, and the only surface quantities, there are also deposits buried in the Peace River and Cold Lake regions of Alberta (Although the United States has some oil sand deposits, it also has massive quantities of oil shale, rocklike forma-tions containing crude oil that can also be refined at high industrial cost.) The oil sands contain a mix of sands, clays, water, and bitumen, but the bitumen, a form of heavy crude oil, is what gives oil sands their distinctive properties Many ancient cultures made use of bitumen for its sticky, adhesive qualities It was used as a sealant for boats, a building mortar, and an ingredient for mummification In modern times, bi-tumen is valuable as a crude oil that can be refined into commercial petroleum The Athabasca basin has the largest reserves of naturally occurring bitumen in the world Semisolid at normal temperatures, the bi-tumen must be heated or diluted with hydrocarbons
to make it flow through supply pipelines The
Trang 9men is extracted through a steam separation process.
Hot water is injected into the mined oil sands, causing
the bitumen to float to the surface, where it can be
re-covered The bitumen is then upgraded into synthetic
oil and petroleum products
History
The First Nations knew about the oil sands deposits
from ancient times and used the tarlike material to
bind their canoes Early Canadian explorers such as
Peter Pond and Alexander Mackenzie wrote of the
fluid bitumen pooling near the Athabasca River In
1882, geologist Robert Bell surveyed the basin and oil
fields However, oil production did not become
possi-ble until Karl Clark first developed a process for
sepa-rating the bitumen from the sands Clark’s process,
developed between 1922 and 1929, relied on hot
water and steam to turn the sand into a soupy
sub-stance from which the bitumen could be extracted
In 1930, the Canadian government leased a large
portion of the Athabasca basin for development to
petroleum engineer Max Ball and his Abasand Oils
company Abasand’s separation process was primitive,
however, and even by the 1940’s Abasand processed
less than 20,000 metric tons of sand per year
The technological challenges of extraction
re-mained daunting, but in the 1960’s the Great
Canadian Oil Sands (GCOS) company built the first
large-scale oil sands production plant, capable of
pro-ducing about 24,000 barrels of synthetic crude oil per
day GCOS eventually became the Suncor Oil
Com-pany, which remains the leading oil producer in the
Athabasca region In 1978, prompted by the oil
em-bargoes of the 1970’s, the Syncrude consortium of oil
companies built a second major oil sands plant,
fol-lowed by Imperial Oil’s Cold Lake plant in 1987,
Alsands Project Group’s facility in 1988, and Shell’s
Albian Sands mine in 2003 In the twenty-first century,
oil production increased, with new technologies
re-ducing the cost of bitumen extraction Dozens of oil
companies and industrial consortiums opened plants
and increased supply The proven feasibility of oil
sands production led the U.S Department of Energy
to tabulate 32 trillion liters of oil reserves in the basin,
second only to the reserves of Saudi Arabia
Obtaining Oil Sands
The bulk of the oil sands are located near the surface
and can be obtained through massive open-pit
min-ing operations Because of the heavy mineral clays
that make up most of the sand, the operations use the largest shovels and trucks in the world to dig up and move the sands Deposits that are located deeper— below 75 meters—are recovered by in situ methods, which include cyclic steam stimulation and steam-assisted gravity drainage About 75 percent of the valuable resource, the bitumen, is obtained during the recovery After the sand is processed and the bitu-men removed, Canadian environbitu-mental laws require the processed sand to be returned to the pit and the site restored to its original condition
Uses of Oil Sands The Athabasca oil sands represent one of the great oil reservoirs in the world Containing a potential 300 bil-lion barrels of crude oil, the oil sands of Alberta, rep-resenting 15 percent of the world’s oil, are second only to Saudi Arabia as potential oil reserves There are currently four thousand agreements in Alberta between Canadian governments and oil companies for production of oil More than 1 million barrels of oil are produced a day Because of the thickness of the oil sands, it takes a tremendous amount of energy to produce oil flow In the winter, temperatures in the Athabasca region fall to as low as−40° Celsius and the extraction machinery can easily freeze up and break down Massive amounts of surface material are moved, sifted, and heated Thus, two major issues must be ad-dressed for the world to exploit this resource: first, the high cost of extraction and, second, the impact on the environment
The profitability of the oil sands depends directly
on the price of oil While light crude oil flows easily from conventional oil wells, oil sand producers must expend fixed costs for mining and extracting the bitu-men and converting it to liquid crude Thus the oil sands may be profitable if the price of oil is more than fifty dollars per barrel, for example, but noncompeti-tive below fifty dollars per barrel and completely un-feasible below thirty dollars With new technology, production costs have been lowered to about thirty-three to thirty-seven dollars per barrel, spurring an oil sands boom As to the environment, the massive pro-cessing of oil sands is bound to leave a certain scarring
of the earth, despite Canadian restoration legislation Oil sands production releases carbon dioxide, which
is believed to contribute to the greenhouse effect The recovery of bitumen itself requires the consump-tion of tremendous amounts of resources, mostly in the form of natural gas and water
Trang 10In 2003, with the rise of oil prices, the oil sands
op-eration became consistently profitable for the first
time, and the three major mines—Suncor, Syncrude
Consortium, and Shell Canada—began producing
about 1.2 million barrels of synthetic crude oil per
day It was estimated that production could grow
within a decade to more than 3 million barrels per
day, making Canada one of the world’s leading
oil-producing countries in the world The oil companies
engaged in the major production of oil from the
Athabasca region include Suncor, Imperial Oil, Petro
Canada, Marathon, Chevron, Occidental Petroleum,
Canadian Natural Resources, Shell Canada, EnCana,
British Petroleum, Husky, Total, UTS, Teck, Conoco
Philips, Japan Canada Oil, Devon Energy, and various
joint ventures Cumulative investment in oil sands
production in the first decade of the twenty-first
cen-tury was estimated to be about $70 billion, resulting in
about 275,000 jobs As of 2009, royalties to the
Cana-dian government were close to $3 billion a year and
oil sands production accounted for about 44 percent
of Canada’s total output of crude oil
Howard Bromberg
Further Reading
Breen, David Alberta’s Petroleum Industry and the
Con-servation Board Edmonton: University of Alberta
Press, 1993
Chastko, Paul Developing Alberta’s Oil Sands: From Karl
Clark to Kyoto Calgary: University of Calgary Press,
2004
Comfort, Darlene The Abasand Fiasco: The Rise and Fall
of a Brave Pioneer Oil Sands Extraction Plant Fort
McMurray, Alta.: Jubilee Committee, 1980
Ferguson, Barry Glen Athabasca Oil Sands: Northern
Resource Exploration, 1875-1951 Edmonton: Alberta
Culture, 1985
Hicks, Brian, and Chris Nelder Profit from the Peak: The
End of Oil and the Greatest Investment Event of the
Cen-tury New York: John Wiley & Sons, 2008.
Nikiforuk, Andrew The Tar Sands: Dirty Oil and the
Fu-ture of a Continent Vancouver: Greystone, 2009.
Tertzakian, Peter A Thousand Barrels a Second: The
Com-ing Oil Break Point and the Challenges FacCom-ing an Energy
Dependent World New York: McGraw-Hill, 2006.
Web Site
Athabasca Oil Sands Corp
http://www.aosc.com/
See also: Canada; Oil and natural gas distribution; Oil and natural gas drilling and wells; Oil shale and tar sands; Petroleum refining and processing
Atmosphere
Category: Ecological resources
The atmosphere is the envelope of gases that surrounds Earth Held in place by the attractive force of gravity, Earth’s atmosphere pervades all facets of the environ-ment Almost every aspect of Earth’s system is depen-dent upon or markedly influenced by the behavior of weather systems spawned within the atmosphere The atmosphere provides resources in the form of individ-ual gases, which can be separated industrially; it also directly affects other resources, most notably food re-sources.
Background The composition of the atmosphere (excluding water vapor) below 80 kilometers is about 78 percent nitro-gen and 21 percent oxynitro-gen by volume (76 percent ni-trogen, 23 percent oxygen by mass) The remaining 1 percent includes all other dry gases, chiefly argon, carbon dioxide, neon, helium, krypton, hydrogen, and ozone Water vapor, the most variable constituent
of the atmosphere, typically occupies between 0 per-cent and 4 perper-cent of the atmospheric volume This mixture of gases is commonly referred to as “air.” The two principal constituents of air are greatly dis-similar in their chemical properties While oxygen is
an extremely active chemical, reacting with many sub-stances, nitrogen reacts only under limited condi-tions The inert nature of nitrogen is believed to be the reason it came to be the atmosphere’s most abun-dant constituent Volcanic outgassing in Earth’s early history is the likely source of its present atmosphere Though nitrogen is a minor component of volcanic emissions, the lack of chemical reactions able to re-move it from the atmosphere allowed its concentra-tion to grow dramatically over time Photosynthesis and, to a lesser degree, photodissociation of water
by sunlight are believed to account for atmospheric oxygen
Carbon dioxide, a principal constituent of volcanic emissions, is also released into the atmosphere by the oceans, respiration, and fossil fuel combustion