3 ebook qui ve danh phap quoc te IUPAC Ebook 2

The entries in the table of section 2 display changes applied to the 2005/JUL/93 draft of the Green Book which has been distributed at the Beijing Meeting 2005 (IUPAC GA).. Only those ch[r]

Trang 1

For Peer Review Only

Quantities, Units and Symbols in Physical Chemistry,3rd Edition

Journal: Pure and Applied Chemistry

Manuscript ID: PAC-REC-05-11-10

Manuscript Type: Recommendation

Date Submitted by the

Author: 10-Nov-2005 Complete List of Authors: Quack, Martin; Eidgenössische Technische Hochschule Zürich,

Laboratorium für Physikalische Chemie Frey, Jeremy; University of Southampton, School of Chemistry Keywords: recommendation, symbols, units, green book, quantities

Trang 2

Trang 3

Trang 4

Trang 5

Trang 6

+ - 1 , 4 - +6 1,1-,! - -, 1++1 !

Trang 7

Trang 8

!! @2 *'& J !K3 4 7 , - , 1+ N

1M,O < - 3 66 =3 1 1+ /!

Trang 9

Trang 10

;,1 =P *&"− *' !! F < I=P *("− ** !! < I=P *&"− *&'

! < =P *&'− *'" !! , < =P ** − *** < =P *&"− *&' I!B!1 < 7=P *&'− *'% ! Q?V <+=P *('− **' 1 #))#−#))% ! A,7

Trang 11

Trang 12

Trang 13

Trang 14

W )

−9

;, - 4 .+ - λ ;, <#= -4 4 4 , 6 , - /6 1 /Q 1 - 1 )

−9

;, <"=! 4/ ;,4 6 .+1 -

Trang 15

Trang 16

Trang 17

Trang 18

7 +1 1 a/bc +1 a/(bc) 1 (a/b)cP

Trang 19

<"1=1

< 61=1

3 X 3

>13 1 .<#1=

2

< 62=2

<"1=2

Trang 20

Trang 21

Trang 22

,3 ++ 6 11/ 1-/,6+ ,++3 6 , ,++ 4 ! @ 1 ,65 6 +6 +- 3- .+ 6 / ;,-/,6+ ,++34, 1,/ 6/,!

Trang 23

Trang 24

Trang 25

Trang 26

Trang 27

−2

32U

Trang 28

Trang 29

Trang 30

Trang 31

Trang 32

IUPAC GB3C 2005/OCT/26

$$ ('2'%%;-56; 27((& 27%-'. *+3&> /-)%5*)(' -'032()+%?@(&=%= (+

)3&%(' 5-/03&(23-&+ -, (2-/35 -'032() 0(+3+ ,*&523-&+ 8 ; 27%-'.9

Trang 33

Trang 34

Trang 35

Trang 36

,,! 6 c 10 E/hc - +1 - / ,,! >,94,6: ,6 ,//,-++44,6J%3&K!

Trang 37

Trang 38

Trang 39

Trang 40

Trang 41

ψ = J (J + 1) ψ, J Z ψ = M J ψ, 1 J z ψ = Kψ,4 + ;,, ,6 M J 1 K 7 / -?11 , /

Trang 42

-+3 ,/-,- - + +Y<,/1=

-/+−</ /=,1E ∗ .

66,11/,41/+ -16 ?1,6/ <1/ = l?1,6/<

2K+

−

1,6 1/+4+ +,3/ +3 J#

2K

−

+

1 +1/ +4+ +,3 + +3J#3

2K+

−

1 +1/ +4+ +,3 / +3J#3

2K

Trang 43

◦ 1/2

+

Trang 44

Trang 45

Trang 46

Trang 47

Trang 48

+ - ;, +66 1,164#!'! ! 6

Trang 49

Trang 50

Trang 51

Trang 52

V m ,3 1 α m + +Q6 < #!"3 '3 +! &=! / + α

C j = N A

4 ν 0 g(|M ji | 2 ) ++,?4/1,6,/-4,?6 ;,- 1+ - <g / +,1+1-,4,12-/,61,,=! 1

Trang 53

Trang 54

Trang 55

#Pa

"Pa

$Pa

Trang 56

Trang 57

Trang 58

<&= 3 4 ,1 41 9:3 ,-, , - 1+- ! 3 4 ++ 6 11!

Trang 59

+, p − ◦

W 6 W )

5 < #! ! <=3+!& 3 '!#3 +! "( 1

Trang 60

Trang 61

Trang 62

OH

C H H

H

C OH O

Trang 63

Trang 64

;, ,1 - , <-4 4,1 , L,6 - M - L/M=!

Trang 65

Trang 66

Trang 67

μ − μ − ◦ RT

Trang 68

Trang 69

Trang 70

Trang 71

Trang 72

Trang 73

Trang 74

Trang 75

Trang 76

+0 k uni (E, J ) k uni (E, J ) = − d(ln c A (E, J ))

Trang 77

Trang 78

Trang 79

Trang 80

Trang 81

φ − φ

Trang 82

, + 743 6, ! , 1+1 + -

,! 3 c i 13 6/ Q1 ,/16 11 c − ◦

Trang 83

Trang 84

Trang 85

Trang 86

3+-,-+131-,6;,?

,3 + , - +1, 671 +116 ,67 -+!

Trang 87

$01

Trang 88

Trang 89

Trang 90

Trang 91

Trang 92

Trang 93

Trang 94

Trang 95

Trang 96

Trang 97

Trang 98

Trang 99

Trang 100

2

27/

Trang 101

2

Trang 102

)2

)3

)6

)9

)12

)15

)18

)21

)24

Trang 103

31

Trang 104

&

11 11 , 101 +1, - +4 - 6 , 4,

, -3 ,/ - , 161 6/ ! .+3 7 / T - + -m / 4 +1 v 101 6 ;,

Trang 105

Trang 106

64 01 , 6.+16 - ;,

E h = 2 /m e a 2 0 = e 2 /4ε 0 a 0 = m e e 4 /(4ε 0 ) 2 2

-,+1/ ,,--,1+ 3 1 - .! , , 6 -

Trang 107

Trang 108

Trang 109

Trang 110

63 >3 1 -;, ,1,6,+ 163 1>3 ,14 011+4 ,1 ,/11 / 1/

Trang 111

Trang 112

Trang 113

Trang 114

++ /0 1/- a! 11 6 1- / b + σ 01/- a!

Trang 115

Trang 116

Trang 117

Trang 118

Trang 119

Trang 120

Trang 121

Trang 122

Trang 123

Trang 124

Trang 125

Trang 126

, G# ) !))( &&$ * % &)<%%= *"*!%&% "&)<( =1, 1 #!) " %%" # # ')<"%= ('%!& # (#< &=

Trang 127

Trang 128

Trang 129

Trang 130

Trang 131

Trang 132

Trang 133

Trang 134

68 / 88 8=?@;<7=@;*28+ 277 8>6− M;?=:<B2@7*@+ M;;?7*27+K

8B 8:?@;8;@<;*28+ 6?22@*27+ 2>6− M7?7@7:6;77*@+K8< 8B?@;;6<72*28+ 7?6<6*=+ 7M 7

6< 4 8< 8B?@;8;=BB*2:+ :<?7B:@*<@+ 7M 7

:2 :7?@;27:72*28+ 2?2;@@*:+ ;>6− −7?B8776*=+ M2:?6*28+:6 :2?@6<;=<=*28+ ;?:;=8*2B+ 7M 7

Trang 135

Trang 136

26= 26;?@76<2<<*2:+ =?B=*2=+ 7M 7

268 26=?@7==6=2*67+ B?7B*28+ 2>6M −7?<<<8782;*=;+K26: 268?@7;;7=@*67+ 2<?<=*68+ 7M 7

26< 26B?@7==:28*2@+ ;2?B=*<+ 7M 72;7 26@?@7:666@*62+ ;=?7<*:6+ 7M 7

8; 3 26B 26:?@7==:<*=+ 277 8>6M M6?<2;6B;*<=+ −B2?7*27+

26: 268?@7=6:<*B+ 7?7<@7*6+ 7M 726< 26B?@7;8;78*28+ 2?@276*<+ 7M 726@ 26<?@7=BB@@*@+ 6:?=77:*<6+ 2>6M −7?BBB@B:;*<=+

2;7 26@?@7;87<@*22+ =?7B27*2;+ 7M 72;2 2;7?@787<6<*2<+ 62?6;6=*;7+ ;>6M M7?:@2<:2@*;@+ −22?=*2+2;6 2;2?@7=28=:*28+ 6:?@7<:*;;+ 7M 7

Trang 137

Trang 138

2B; 2B6?@;<67B*;+ 2:?2;*6B+ 8>6− −7?:B@<@*;+K M6<7?7*=7+2B= 2B;?@;<<8<*;+ ;2?<;*@6+ 7M 7

2B@ 2B<?@=8<28=*6B+ 2;?:6*6+ @>6M −7?:=7@*2;+ M;B@?;*;;+K2<7 2B@?@=:8=<<*6B+ ;8?7<*2:+ 7M 7

2<2 2<7?@=B@@:*;+ @@?@<<*6+ B>6M M6?;B78*B+ M;2B?7*67+K

2<6 2<2?@=<678*;+ 6:?87*2:+ 7M 72<; 2<6?@8766=6*;7+ 2=?;2*=+ 2>6− M7?22BB<=B:*@+

2<= 2<;?@87@;6;*;7+ ;7?:=*6+ 7M 72<: 2<8?@8=;:6*;+ 6<?=;*2@+ 7M 7

B8 2<8 2<=?@86@88*;+ ;B?=7*6+ 8>6M M;?2<B2*;+ M62<?7*67+K

2<BF 2<:?@88B878*;7+ :6?:7*6+ 8>6M M;?62@B*;+ M67B?7*67+K

2<: 2<8?@8;<;<*;+ 2?8@*;+ 7M 72<B 2<:?@88B=B:*;7+ 2?@:*6+ 2>6− M7?7:=:82<@*:+K2<< 2<B?@88<;8B*;7+ 2;?6=*<+ 7M 7

2<@ 2<<?@8<2=8*;+ 2:?28*8+ ;>6− M7?:8@@;;*=+ M<8?:*6<+2@7 2<@?@8<==8*;+ 6:?6:*6+ 7M 7

Trang 139

Trang 140

/ ,! - -- / 1 /?1 , <+3 4,63-;,3+,1/=31-+,,3+161

Trang 141

Trang 142

Trang 143

Trang 144

Trang 145

−2

W < )5

Trang 146

Trang 147

3/ < I= /< I= W$!%$& )*# 1

3

α

1 < ,= 11/

7/ < ,= 7/

Trang 148

;, "&%!#% 1P '%>-'3(& ;, "&%!#$#% 1P (.(& ;,

Trang 149

Trang 150

Trang 151

2

Trang 152

2M3;,1,+ e

2 ≈ !&)# '& %"< $=× )

−23

2

α

2

)L

3M3+Q6, 4ε 0

L[

Trang 153

27/

Trang 154

em = (μ 0 /4) I 1 11 × (I 2 12 ×)/r 3

4 + 11, +1 6 <4 || = r=! +

Trang 155

Trang 156

1 ;, 10/ es 1 1

2

em 6P 4 ++

11;,3 !!3 .4;,! @--$1,1 43 3 ;, 1LQ1M!

Trang 157

k 2

I 1 d1 × (I 2 d2 ×)

2 = μ 0

I 111 × (I 212 ×)

2 = I 111 × (I 21 2 ×)

Trang 158

Trang 159

Trang 160

Trang 161

Trang 162

,= - u c W )!"% /! 6 ,1 +6 1 ,

-11 ++. 16,14 ++. 11 1 u c3,74 ,- 11 61 m s ± u c 4 - 01

Trang 163

Trang 164

Trang 165

Trang 166

Trang 167

Trang 168

Trang 169

Trang 170

Trang 171

Trang 172

Trang 173

Trang 174

Trang 175

Trang 176

Trang 177

Trang 178

Trang 179

Trang 180

B& & &3 *D ##(\ #$)3 #))"!

J#"K ! B7! - +- ,! B& & &3$"D$#%\

Trang 181

Trang 182

Trang 183

Trang 184

,3 6 <10 5 =! B& & "&- 3#*D )%\ 3 *($!

J()K ! ! ! - 11 1 4 11?,! B& & &#D&( \&(&3 *(%!

Trang 185

Trang 186

J )*K ! ??/! ,1/ D / +1 &3&&D &&'\ '"(3 **$!

Trang 187

Trang 188

J "(K B!!!1!U! ,;,1,+

-115

-,1! B& & &3 'D" )"\" )(3 #))#!

Trang 189

Trang 190

Trang 191

Trang 192

Trang 193

Trang 194

Trang 195

Trang 196

Trang 197

Trang 198

Trang 199

Trang 200

Changes made to the draft of the Green Book (GB) dated 2005/JUL/03

Please note that a line numbering has been introduced to facilitate your work For technical reasons, tables etc are not line-numbered; however, lines in tables can easily be named by the proper keyword An empty page can show a single numbered line, but this is for technical reasons and will not appear in print.

The Subject Index is missing Indexing will make the electronic version of the manuscript almost unreadable The index will be prepared when all points raised by the reviewers are discussed and settled This will be the very last step of editing the GB manuscript.

1 Reference to the Notes in the Tables is now consequently written as ‘see note x’ instead of ‘see

footnote x’ The term footnote is reserved for real footnotes to running text, as for example

in section 7.1

2 Nucle¨ı has been replaced by nuclei in the whole manuscript.

3 A consistent writing of sums with the lower index

has been introduced for entries in the tables of the whole manuscript (where applicable).

4 After receiving the new IUPAC periodic table (now dated 3 October 2005), the Secretary of Commission II.1 was contacted about the new atomic weights The minutes of Commission II.1 from the Beijing Meeting were received and the few corrected atomic weights have been considered in section 6.2 After completion of the II.1 manuscript we will receive a copy to complete the now incomplete citation [123] in the submitted draft The atomic weights in section 6.2 are now consistent with those appearing in the new IUPAC periodic table.

5 Please note an error in the Commission I.1 Beijing Minutes: Based on a misunderstanding, it

was stated that the GB draft dated 2005/JUL/03 needs an update of the fundamental constants

and the atomic masses or weights (chapters 5 and 6) By the time of the Beijing meeting, both chapters in the distributed draft were up-to-date (which can be seen by inspecting the list of references cited) The year of publication of ref [107] in the draft is misprinted and should read 2005 and the fundamental constants are therefore the most recent (also currently

3 X 3< /h3>

>13 1 .<#1=

2< /h3>

< 62< /h3>=2< /h3>

<& #34 ;1=2< /h3>

)2< /h3>

)3< /h3>

)6

)9

) 12< /h3>

)15

)18

)21

Định dạng
Số trang	203
Dung lượng	5,85 MB