Environmental Health and Safety Concerns of Nano Silver • Potential to be released into environment • May be toxic to beneficial microbes • Impact on aquatic species 6... Nano Material
Trang 1Nano Silver
Neena Sahasrabudhe
DTSC
1
Trang 2Nano Material Applications
• CONSUMER PRODUCTS
• PESTICIDES AND ANTIMICROBIALS
• MEDICAL DIAGNOSTICS AND
PHARMACEUTICALS
• BIOTECHNOLOGY
• AUTOMOTIVE
• PAINTS AND COATINGS
• COSMETICS AND PERSONAL CARE
• ENERGY AND ELECTRONICS
Trang 3Nano silver uses
• Medical Products—wound dressings,
surgical gauze, bandages
• Textiles and Clothing
• Sporting Goods
• Aerospace and Electronics
3
Trang 4Why are nano materials popular?
• Different Physical and Chemical
Trang 5Nano materials also used in
• Environmental Remediation
• Decontamination of Pollutants
5
Trang 6Environmental Health and Safety
Concerns of Nano Silver
• Potential to be released into environment
• May be toxic to beneficial microbes
• Impact on aquatic species
6
Trang 7Nano Material Lifecycle
Manufacture Transportation Storage
Consumers / Public
Materials
Workers Waste
Soil/
Sediment Water
Plant Animal
Food
Environment
Integration
Consumer Products
Devices Processes
Facility
Systems
Release Disposal
7
Trang 8‘I-on’ concern
• Ag (metal) Ag + e-
• Silver ions (Ag+) were considered the
culprit behind the toxicity
of silver nano particles (AgNP*)
* AgNP- Silver nano particles 8
Trang 9Wastewater treatment concerns
“Considering the current extensive production of Ag NPs and
their widespread use in consumer products, it is likely that they
are entering wastewater streams and the treatment facilities
that process this water”**
• nano silver in products can affect the good bacteria in
treatment plants
• Treatment plants may not function to its capacity
** Discovery and Characterization of Silver Sulfide Nanoparticles in Final Sewage Sludge Products
Kim , Park, Murayama and Hochella, The Center for NanoBioEarth, Department of
Geosciences,Virginia Tech, Department of Materials Science and Engineering 9
Trang 11Other Concerns
• Other consumer products lined with antibacterial nano silver
• Food containers, baby bottles
• Band aids
• Medicinal supplements
• FDA nanotechnology section
Trang 12Is human population affected?
• Silver metal in colloidal form has been used as
anti-bacterial from ancient times
• Engineered nano silver differs from silver metal
• Definitive research on nano silver and in vivo
studies for mammals is unknown
• Research at UCLA plans to find out IF silver nano
plates are toxic to mammalian lungs if inhaled
12
Trang 13What we know
and do not know
• Nano material obtained by the
manufacturer
• Manufacturer may know the modification
of nanomaterial into the product
• What is coming out of product into the
environment IS UNKNOWN
13
Trang 14Data gaps
Fate, Transport, Toxicity and ANALYTICAL
METHODS unknown
14
Trang 15Nano Silver in Environment
• Lake Ecosystem Nano Silver ( LENS) Project*
• Effect of nano silver on aquatic environment
• Will monitor changes in lake’s ecosystem
• Track effects through entire food web
• Determine how resulting changes alter ecosystem
function
* Trent University- Natural Sciences and Engineering
Research Council of Canada, Environmental Canada
Support- Fisheries and Oceans Canada
15
Trang 16Measurement Techniques
Transmission Electron Microscopy (TEM)
Scanning Electron Microscopy (SEM)
X- Ray Diffraction (XRD)
Atomic Force Microscopy (AFM)
Measurement*** of silver nano particles also depends
on
Agglomeration/ thickness of initial capping agents
Dispersion conditions/thickness of natural organic
Trang 17Shape affects Toxicity
• Silver nano plates are toxic in direct
contact with cells of some fish*
• Silver nano spheres are toxic in high
concentration
• Silver nano wires are much less toxic
• * Rainbow Trout and Zebra fish**
• ** nanotechweb- research at UCLA, DR.A Nel, S George et al 17
Trang 18DTSC and Nanosilver
Round Two call-in dataset –identified:
Twelve (12) nano silver
manufacturers or importers
Requested information from
manufacturers and importers on
analytical methods of their chemical 18
Trang 20Outcomes
1.Cooperation and communications with
creators and user's of the material
2.MOU with other state agency (DPR*)
3 Collaboration with Federal agencies,
Universities, research agencies
4 Other participations
5 Nano toolkit
Trang 21Thank you
Neena Sahasrabudhe, Ph.D
916/324 8660