Thermodynamic Data of Copolymer Solutions Part 5 pdf

HIGH-PRESSURE PHASE EQUILIBRIUM HPPE DATAType of data: cloud-points T/K 308.15... copolymer B: E-AA/06w 92WINType of data: coexistence data Type of data: cloud-points... copolymer B: E-B

4 HIGH-PRESSURE PHASE EQUILIBRIUM (HPPE) DATA

Type of data: cloud-points

T/K 308.15

Ethylene/acrylic acid copolymer

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Characterization:

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Copolymer (B) Mn/ Mw/ Mη/ Further information

g/mol g/mol g/mol

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Experimental HPPE data:

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Type of data: cloud-points

Type of data: coexistence data

T/K = 403.15

Total feed concentration of the copolymer in the homogeneous system: wB = 0.155

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Demixing wA Fractionation during demixing

pressure bottom phase top phase bottom phase top phase

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Type of data: coexistence data

T/K = 433.15

continue

The total feed concentration of the copolymer in the homogeneous system is: wB = 0.164

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Demixing wA Fractionation during demixing

pressure bottom phase top phase bottom phase top phase

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Type of data: cloud-points

copolymer (B): E-AA/06w 92WIN

Type of data: coexistence data

Type of data: cloud-points

Ethylene/butyl acrylate copolymer

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Characterization:

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Copolymer (B) Mn/ Mw/ Mη/ Further information

g/mol g/mol g/mol

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E-BA/15w 6980 34900 sample from BASF AG, Ger.E-BA/19w 7740 38700 sample from BASF AG, Ger.E-BA/35w 7960 39800 sample from BASF AG, Ger.E-BA/67w 11500 37000 synthesized in the laboratoryE-BA/75w 13900 35200 synthesized in the laboratory

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Experimental HPPE data:

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Type of data: cloud-points

wB 0.025 0.025 0.025 0.025 0.025 0.050 0.050 0.050 0.050

T/K 522.85 498.05 473.05 448.55 423.85 524.05 498.35 473.85 449.15

continue

Type of data: cloud-points

Type of data: cloud-points

Type of data: cloud-points

T/K 522.35 498.15 473.65 448.35 424.65

copolymer (B): E-BA/75w 96MUE

Type of data: cloud-points

Copolymer (B) Mn/ Mw/ Mη/ Further information

g/mol g/mol g/mol

Experimental HPPE data:

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Type of data: cloud-points

wB 0.148 0.148 0.148 0.148

T/K 393.25 413.15 433.25 453.15

Type of data: cloud-points

wB 0.150 0.150 0.150 0.150 0.150 0.150

T/K 393.15 413.15 433.15 453.15 473.15 493.15

Type of data: cloud-points

Type of data: cloud-points

copolymer (B): E-H/21w 2000CH2

Type of data: cloud-points

Type of data: cloud-points

wB 0.150 0.150 0.150 0.150 0.150 0.150

T/K 313.15 343.15 363.05 373.05 413.15 453.15

Type of data: cloud-points

Ethylene/methyl acrylate copolymer

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Copolymer (B) Mn/ Mw/ Mη/ Further information

g/mol g/mol g/mol

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E-MA/25w 17000 75400 synthesized in the laboratoryE-MA/58w 33000 108900 synthesized in the laboratoryE-MA/68w 42000 110000 synthesized in the laboratory

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Experimental HPPE data:

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Type of data: cloud-points

Type of data: cloud-points

copolymer (B): E-MA/68w 96MUE

Type of data: cloud-points

Copolymer (B) Mn/ Mw/ Mη/ Further information

g/mol g/mol g/mol

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E-O/14w 51200 83000 4 hexyl branches/100 ethyl unitsE-O/26w 54800 115000 8 hexyl branches/100 ethyl unitsE-O/39w 83300 120000 13.6 hexyl branches/100 ethyl units

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Experimental HPPE data:

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Type of data: cloud-points

wB 0.050 0.050 0.050 0.050 0.050 0.050

T/K 453.15 413.15 393.15 373.15 368.15 363.15

Type of data: cloud-points

wB 0.049 0.049 0.049

T/K 453.15 413.15 373.15

Type of data: cloud-points

Ethylene/propylene/isoprene terpolymer

28.2 mol% propene, 43.6 mol% isoprene E-P-IP/28x 96ALB

36.7 mol% propene, 26.6 mol% isoprene E-P-IP/37x 96ALB

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Characterization:

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Copolymer (B) Mn/ Mw/ Mη/ Further information

g/mol g/mol g/mol

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E-P/50x(1) 782 790 alternating ethylene/propylene units from

complete hydrogenation of polyisopreneE-P/50x(2) 5460 5900 alternating ethylene/propylene units from

complete hydrogenation of polyisopreneE-P/50x(3) 25200 26000 alternating ethylene/propylene units from

complete hydrogenation of polyisopreneE-P/50x(4) 87700 96400 alternating ethylene/propylene units from

complete hydrogenation of polyisopreneE-P-IP/28x 7650 13620 alternating ethylene/propylene units from

partial hydrogenation of polyisopreneE-P-IP/37x 7690 13690 alternating ethylene/propylene units from

partial hydrogenation of polyisoprene

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Experimental HPPE data:

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Type of data: cloud-points

Type of data: cloud-points

Type of data: cloud-points

copolymer (B): E-P/50x(4) 92CH1

Type of data: cloud-points

Comments: a lower critical endpoint is found at 333.15 K

Type of data: cloud-points

T/K 293.15 323.15 363.15 423.15 475.15

Type of data: cloud-points

wB 0.156 0.156 0.156 0.158 0.158 0.157 0.158 0.158 0.158

T/K 308.15 323.15 325.65 348.15 373.15 398.15 448.15 468.15 473.15

Type of data: cloud-points

T/K 353.15 373.15 398.15 423.15 473.15

Type of data: cloud-points

continue

wB = 0.160

T/K 427.15 447.95 467.85 473.15 477.95 478.65 473.15 477.95 478.55

Comments: a lower critical endpoint is found at 472.15 K

Type of data: cloud-points

wB = 0.150

T/K 416.95 453.15 459.35 454.95 474.45 463.95

Comments: a lower critical endpoint is found at 457.15 K

Type of data: cloud-points

Comments: a lower critical endpoint is found at 351.1 K

Type of data: cloud-points

copolymer (B): E-P/50x(2) 93GRE, 94GR1, 94GR2

Type of data: cloud-points

Type of data: cloud-points

wB = 0.151

T/K 323.55 355.55 373.55 398.05 423.55 448.15

Type of data: cloud-points

Type of data: cloud-points

copolymer (B): E-P-IP/28x 96ALB

Type of data: cloud-points

wB = 0.0536

T/K 424.75 383.25 347.55 329.95

Comments: a lower critical endpoint is found at 329.95 K

Type of data: cloud-points

wB = 0.0524

T/K 423.45 411.95 410.65 384.35 362.35 348.65 328.15

Comments: a lower critical endpoint is found at 328.15 K

Type of data: cloud-points

wB = 0.0722

T/K 423.65 414.15 393.75 392.85 383.05 382.25 373.75 364.85 362.25

Type of data: cloud-points

wB = 0.0843

T/K 423.75 423.15 421.65 409.15 394.35

copolymer (B): E-P-IP/37x 96ALB

Type of data: cloud-points

Type of data: cloud-points

Ethylene/vinyl acetate copolymer

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continue

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Characterization:

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Copolymer (B) Mn/ Mw/ Mη/ Further information

g/mol g/mol g/mol _

E-VA/28w(1) 35000 126500 Exxon Chemical CompanyE-VA/28w(2) 61900 167000

E-VA/32w(1) 16200 45800 Leuna-Werke, Germany

E-VA/32w(2) 21800 46400 Leuna-Werke, Germany

E-VA/32w(3) 15500 40800 Leuna-Werke, Germany

E-VA/33w(1) 13000 22100 Exxon Chemical CompanyE-VA/33w(2) 5430 8220 Leuna-Werke, Germany

E-VA/33w(3) 15000 28300 Leuna-Werke, Germany

E-VA/33w(4) 9590 16900 Leuna-Werke, Germany

E-VA/58w 35000 Exxon Chemical Company

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Experimental HPPE data:

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Type of data: cloud-points

T/K = 433.15

Type of data: cloud-points

Type of data: coexistence data

copolymer (B): E-VA/11w 91NIE

Type of data: coexistence data

Type of data: cloud-points

T/K = 433.15

Type of data: cloud-points

copolymer (B): E-VA/18w 91NIE

Type of data: cloud-points

Type of data: coexistence data

T/K = 403.15

The total feed concentration of the copolymer in the homogeneous system is: wB = 0.145

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Demixing wA Fractionation during demixing

pressure bottom phase top phase bottom phase top phase

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Type of data: coexistence data

T/K = 433.15

continue

Type of data: coexistence data

Type of data: cloud-points

wB 0.040 0.040 0.040 0.067 0.067 0.101 0.101 0.101 0.157

T/K 373.15 403.15 463.15 393.15 433.15 393.15 433.15 453.15 373.15

continue

Type of data: cloud-points

T/K = 433.15

Type of data: cloud-points

Type of data: coexistence data

T/K = 433.15

The total feed concentration of the copolymer in the homogeneous system is: wB = 0.138

continue

Type of data: cloud-points

Type of data: gas solubility

Type of data: coexistence data

copolymer (B): E-VA/29w 91FIN

Type of data: gas solubility

Type of data: gas solubility

Type of data: gas solubility

T/K = 473.15

wA 0.024 0.037 0.039 0.055 0.056 0.086 0.122 0.155

Type of data: cloud-points

copolymer (B): E-VA/31w 84WAG

Type of data: cloud-points

Type of data: cloud-points

T/K = 433.15

Type of data: cloud-points

copolymer (B): E-VA/32w(2) 84WAG

Type of data: cloud-points

Type of data: cloud-points

Type of data: cloud-points

copolymer (B): E-VA/33w(1) 91NIE

Type of data: cloud-points

Type of data: cloud-points

Type of data: cloud-points

copolymer (B): E-VA/33w(3) 83RAE

Type of data: cloud-points

T/K 433.15 433.15 433.15 433.15

Type of data: cloud-points

Type of data: cloud-points

Type of data: gas solubility

Type of data: cloud-points

T/K 433.15 433.15 433.15 433.15 433.15

Type of data: cloud-points

copolymer (B): E-VA/58w 91NIE

Type of data: coexistence data

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continue

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Poly(ethylene b-poly(propylene

oxide)-b-poly(ethylene oxide) triblock copolymer

Poly(propylene b-poly(ethylene

oxide)-b-poly(propylene oxide) triblock copolymer

NH2 terminated POEO-PO-EO/11x 1050 (= 50 + 950 + 50) Pluronic L31, hydroxyl terminatedEO-PO-EO/13x 2944 (= 147 + 2650 + 147) Pluronic L81, hydroxyl terminatedEO-PO-EO/14x 2210 (= 120 + 1970 + 120) Pluronic L61, hydroxyl terminatedEO-PO-EO/25x(1) 2460 (= 245 + 1970 + 245) Pluronic L62, hydroxyl terminatedEO-PO-EO/25x(2) 3738 (= 374 + 2990 + 374) Pluronic L92, hydroxyl terminatedEO-PO-EO/36x 1844 (= 277 + 1290 + 277) Pluronic L43, hydroxyl terminatedPO-EO-PO/25x(1) 3125 (= 1250 + 625 + 1250) Pluronic 25R2, hydroxyl terminatedPO-EO-PO/25x(2) 2125 (= 850 + 425 + 850) Pluronic 17R2, hydroxyl terminatedPO-EO-PO/47x 2833 (= 850 + 1133 + 850) Pluronic 17R4, hydroxyl terminatedPO-EO-PO/57x 2000 (= 500 + 1000 + 500) Pluronic 10R5, hydroxyl terminated

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Experimental HPPE data:

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Type of data: cloud-points

T/K 308.15

Type of data: cloud-points

T/K 308.15

Type of data: cloud-points

T/K 308.15

Type of data: cloud-points

T/K 308.15

Type of data: cloud-points

T/K 308.15

copolymer (B): EO-PO-EO/25x(1) 98ONE

Type of data: cloud-points

T/K 308.15

Type of data: cloud-points

T/K 308.15

Type of data: cloud-points

T/K 308.15

Type of data: cloud-points

T/K 308.15

Type of data: cloud-points

T/K 308.15

copolymer (B): PO-EO-PO/47x 98ONE

Type of data: cloud-points

T/K 308.15

Type of data: cloud-points

T/K 308.15

4.2 Table of systems where binary HPPE data were published only

in graphical form as phase diagrams or related figures

Copolymer (B) Solvent/gas (A) Ref _

Copolymer (B) Solvent/gas (A) Ref _

Ethylene/methyl acrylate copolymer

Copolymer (B) Solvent/gas (A) Ref _

Poly(ethylene b-poly(propylene

oxide)-b-poly(ethylene oxide) triblock copolymer

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Tetrafluoroethylene/hexafluoropropylene copolymer

carbon dioxide 96MERcarbon dioxide 96RINcarbon dioxide 98MCHcarbon dioxide 99MERchlorotrifluoromethane 96MERhexafluoroethane 96MERhexafluoropropene 96MERoctafluoropropane 96MERsulfur hexafluoride 96MERsulfur hexafluoride 98MCHsulfur hexafluoride 99MERtetrafluoromethane 96MERtetrafluoromethane 98MCHtrifluoromethane 99MER

Vinylidene fluoride/hexafluoropropylene copolymer

carbon dioxide 96RINcarbon dioxide 97MERcarbon dioxide 2000DIN1-chloro-1,1-difluoroethane 2000DINchlorodifluoromethane 2000DINchlorotrifluoromethane 97MERchlorotrifluoromethane 2000DIN1,1-difluoroethane 2000DINdifluoromethane 2000DINhexafluoropropene 97MERpentafluoroethane 2000DIN1,1,1,2-tetrafluoroethane 2000DINtrifluoromethane 97MERtrifluoromethane 2000DIN

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