Thermodynamic Data of Copolymer Solutions Part 7 doc

and Griskey, R.G., An equation of state for molten polymers, J.. K., and Simha, R., Equation of state of copolymer melts: The polyvinyl acetate-polyethylene pair, J.. experimental data b

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6 PVT DATA OF MOLTEN COPOLYMERS

6.1 Experimental data and/or Tait equation parameters

_

Characterization:

_

Copolymer (B) Mn/ Mw/ Mη/ Further information

g/mol g/mol g/mol

_

S-AN/70wMonsanto Co

_

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Tait equation parameter functions:

g/mol g/mol g/mol

_

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_

g/mol g/mol g/mol

_

S-BR/10w112000 650000 35% 1,4-cis, 52% 1,4-trans, 13% 1,2-vinylS-BR/23w126000 720000 30% 1,4-cis, 47% 1,4-trans, 23% 1,2-vinylS-BR/25 239000 481000 Europrene R130, ANIC Mailand

S-BR/60w128000 820000 30% 1,4-cis, 47% 1,4-trans, 23% 1,2-vinylS-BR/85w121000 730000 30% 1,4-cis, 47% 1,4-trans, 23% 1,2-vinylS-?-B/48 61800 76100 Europrene S141, ANIC Mailand

(32% styrene in blocks)S-?-B/70 97600 126400 Europrene S142, ANIC Mailand

Copolymer V(P/MPa, T/K) = V(0, T/K){1 − C(T/K) ln[1 + (P/MPa)/B(T/K)]}

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Ethylene/acrylic acid copolymer

_

Characterization:

_

g/mol g/mol g/mol

_

E-AA/03w 37500 183000 synthesized in the laboratory

E-AA/09wunspecified commercial product

E-AA/20wSci Polym Prod., No 10

_

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P/ Vspez/ P/ Vspez/ P/ Vspez/ P/ Vspez/ P/ Vspez/

MPa cm3g−1 MPa cm3g−1 MPa cm3g−1 MPa cm3g−1 MPa cm3g−1

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copolymer (B): E-AA/07w 92WIN _

T/K 393.2 413.2 433.2 453.2 473.2

_

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copolymer (B): E-AA/20w 95ZOL _

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Characterization:

_

g/mol g/mol g/mol

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copolymer (B): E-B/82w 99MAI _

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Ethylene/methacrylic acid copolymer

4.0 wt% methacrylic acid E-MAA/04w 418-524 0.1-200 95ZOL 9.0 wt% methacrylic acid E-MAA/09w 410-524 0.1-200 95ZOL 11.5 wt% methacrylic acid E-MAA/11w 409-524 0.1-200 95ZOL

_

continue

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Characterization:

_

g/mol g/mol g/mol

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_

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_

g/mol g/mol g/mol

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copolymer (B): E-O/08w 98SUH, 99MAI _

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continue

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Characterization:

_

g/mol g/mol g/mol

_

E-P/11w 143600 273000 synthesized in the laboratory,

ρB = 0.9007 g/cm3E-P/17w 152000 258000 synthesized in the laboratory,

ρB = 0.9008 g/cm3E-P/23w 53300 160000 random, most probable distributionE-P/32w 104500 178000 synthesized in the laboratory,

ρB = 0.8871 g/cm3E-P/57w 51500 134000 random, most probable distributionE-P/61w 91900 138000 synthesized in the laboratory,

ρB = 0.8582 g/cm3E-P/76w(1) 40200 84400 random, most probable distributionE-P/76w(2) 77800 117000 synthesized in the laboratory,

ρB = 0.8600 g/cm3

E-P/84w(1) 49600 94200 synthesized in the laboratory,

ρB = 0.8783 g/cm3E-P/84w(2) 35700 75000 random, most probable distributionE-P/96w 96900 145400 synthesized in the laboratory,

ρB = 0.8889 g/cm3

_

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copolymer (B): E-P/61w 99MAI _

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copolymer (B): E-P/84w(2) 95ZOL _

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copolymer (B): E-P/96w 99MAI _

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Characterization:

_

g/mol g/mol g/mol

_

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copolymer (B): E-S/14x 96XUY _

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copolymer (B): E-S/29x 96XUY _

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Ethylene/vinyl acetate copolymer

9 wt% vinyl acetate E-VA/09w 393-473 10-80 90BU1

14 wt% vinyl acetate E-VA/14w 393-535 0.1-200 95ZOL

18 wt% vinyl acetate E-VA/18w(1) 385-517 0.1-177 86ZOL

28 wt% vinyl acetate E-VA/28w(B) 373-473 10-80 90BU1

28 wt% vinyl acetate E-VA/28w(B) 373-473 10-80 90BU2

28 wt% vinyl acetate E-VA/28w(Z1) 367-517 0.1-177 86ZOL

28 wt% vinyl acetate E-VA/28w(Z2) 377-519 0.1-200 95ZOL

33 wt% vinyl acetate E-VA/33w 385-526 0.1-200 95ZOL

65 wt% vinyl acetate E-VA/65w 343-502 0.1-200 95ZOL 87.1 wt% vinyl acetate E-VA/87w 303-443 0.1 90CIM

_

Characterization:

_

g/mol g/mol g/mol

_

E-VA/14wSci Polym Products

E-VA/20wC-Elvax 210, DSM, Netherlands

E-VA/33wSci Polym Products

_

continue

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_

g/mol g/mol g/mol

_

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copolymer (B): E-VA/14w 95ZOL _

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copolymer (B): E-VA/18w(2) 95ZOL _

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copolymer (B): E-VA/33w 95ZOL _

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Tait equation parameter functions:

E-VA/18w(1) 1.02391 exp(2.173 10−5T 1.5) 188.2 exp(−4.537 10−3θ )

E-VA/25w(1) 1.00416 exp(2.244 10−5T 1.5) 184.4 exp(−4.734 10−3θ )

E-VA/28w(Z1) 1.00832 exp(2.241 10−5T 1.5) 183.5 exp(−4.457 10−3θ )

E-VA/40w(1) 1.06332 exp(2.288 10−5T 1.5) 205.1 exp(−4.989 10−3θ )

Ethylene/vinyl alcohol copolymer

_

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_

g/mol g/mol g/mol

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43 mol% perfluorooxymethylene PF(OE-OM)/43x 253-333 0.1 95DAN

49 mol% perfluorooxymethylene PF(OE-OM)/49x(1) 253-333 0.1 95DAN

_

Characterization:

_

g/mol g/mol g/mol

_

PF(OE-OM)/43x 465 500 endgroup −CH2-OH on each side of the

chain, i.e., = 12.4 wt% in this samplePF(OE-OM)/44x 850 1045 endgroup −CH2-OH on each side of the

chain, i.e., = 8.3 wt% in this samplePF(OE-OM)/49x(1) 2550 3290 endgroup −CH2-OH on each side of the

chain, i.e., = 1.2 wt% in this sample

_

continue

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_

g/mol g/mol g/mol

_

PF(OE-OM)/51x(1) 9400 10900 endgroup −CH2-OH on each side of the

chain, i.e., = 5.6 wt% in this sample

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copolymer (B): PF(OE-OM)/48x 95DAN

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copolymer (B): PF(OE-OM)/51x(2) 95DAN

Styrene/methyl methacrylate copolymer

20.5 wt% methyl methacrylate S-MMA/21w 383-543 0.1-200 92KIM 58.5 wt% methyl methacrylate S-MMA/59w 383-543 0.1-200 92KIM

_

Characterization:

_

g/mol g/mol g/mol

_

S-MMA/59wRichardson Polymer RPC 100

_

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20 mol% 4-hexylstyrene VCZ-HS/20x 473-523 30-100 94PRI

80 mol% 4-hexylstyrene VCZ-HS/80x 313-423 30-100 94PRIN-Vinylcarbazole/4-octylstyrene copolymer

50 mol% 4-octylstyrene VCZ-OS/50x 403-453 30-100 94PRIN-Vinylcarbazole/4-pentylstyrene copolymer

50 mol% 4-pentylstyrene VCZ-PS/50x 383-443 30-100 94PRI

_

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_

g/mol g/mol g/mol

_

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6.2 References

73RAO Rao, K and Griskey, R.G., An equation of state for molten polymers, J Appl Polym Sci.,

17, 3293, 1973

77REN Renuncio, J.A.R and Prausnitz, J.M., Volumetric properties of block and random

ers of butadiene and styrene at pressures to 1 kilobar, J Appl Polym Sci., 21, 2867,

1977

86ZOL Zoller, P., Jain, R K., and Simha, R., Equation of state of copolymer melts: The poly(vinyl

acetate)-polyethylene pair, J Polym Sci., Part B: Polym Phys., 24, 687, 1986.

(experimental data by private communication with P Zoller)

90BU1 Busch, B., Das spezifische Volumen geschmolzener Polymere und Copolymere in

Abhängigkeit von Druck und Temperatur, PhD-Thesis, Univ Osnabrück, 1990.

90BU2 Busch, B., Lechner, M.D., and Kleintjens, L.A., The specific volume of polymer melts as a

function of temperature and pressure, Thermochim Acta, 160, 131, 1990.

90CIM Cimmino, S., Martuscelli, E., Saviano, M., and Silvestre, C., A comparison of theoretical

predictions and experimental evidences of miscibility for poly(ethylene oxide)-basedblends, Makromol Chem., Macromol Symp., 38, 61,1990.

92KIM Kim, C.K and Paul, D.R., Interaction parameters for blends containing polycarbonates 2

Tetramethyl bisphenol-A polycarbonate - styrene copolymers, Polymer, 33, 2089, 1992.

(experimental data by private communication with D R Paul)

92WIN Wind, R.W., Untersuchungen zum Phasenverhalten von Mischungen aus Ethylen,

Acrylsäu-re und Ethylen-AcrylsäuAcrylsäu-re-CopolymeAcrylsäu-ren unter hohem Druck, PhD-Thesis, TH Darmstadt,

1992

93ROD Rodgers, P.A., Pressure-volume-temperature relationships for polymeric liquids: A review

of equations of state and their characteristic parameters for 56 polymers, J Appl Polym Sci., 48, 1061, 1993.

94PRI Privalko, V.P., Arbuzova, A.P., Korskanov, V.V., and Zagdanskaya, N.E.,

Thermodyna-mics of random copolymers of N-vinylcarbazole and 4-alkylstyrenes, Polym Intern., 35,

161, 1994

94WAN Wang, Y.Z., Hsieh, K.H., Chen, L.W., and Tseng, H.C., Effect of compatibility on specific

volume of molten polyblends, J Appl Polym Sci., 53, 1191, 1994.

95DAN Danusso, F., Levi, M., Gianotti, G., and Turri, S., Thermovolumetric properties versus glass

transition temperature of diolic perfluoro-poly(oxyethylene-ran-oxymethylene) oligomers,

Macromol Chem Phys., 196, 2855, 1995.

95ZOL Zoller, P and Walsh, D.J., Standard Pressure-Volume-Temperature Data for Polymers,

Technomic Publishing, Lancaster, 1995

96XUY Xu, Y., Charakterisierung von Styrol-Ethylen-Copolymeren und deren Mischungen mit

Poly(2,6-dimethyl-1,4-phenylen ether), Diploma paper, Albert-Ludwigs-Univ., Freiburg i.

Br., 1996

(experimental data by personal communication with Y Thomann)

98SUH Suhm, J., Maier, R.-D., Kressler, J., and Mühlhaupt, R., Microstructure and

pressure-volume-temperature properties of ethene/1-octene random copolymers, Acta Polym., 49, 80,

1998

(experimental data by personal communication with R.-D Maier)

99MAI Maier, R.-D., Thermodynamik und Kristallisation von Metallocen-Polyolefinen,

PhD-Thesis, Albert-Ludwigs-Univ., Freiburg i Br., 1999.

(experimental data by personal communication with R.-D Maier)

Tiêu đề	PVT Data of Molten Copolymers Part 7
Trường học	University of CRC Press LLC
Chuyên ngành	Thermodynamics and Polymer Solutions
Thể loại	Thesis
Năm xuất bản	2001
Thành phố	Unknown

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