Volume 03 - Alloy Phase Diagrams Part 8 ppsx

Nafziger, 1992 Fe-N phase diagram Fe-N crystallographic data... Fe-Nb phase diagram Fe-Nb crystallographic data Fe-Nd Iron - Neodymium W... Fe-Nd phase diagram Fe-Nd crystallographic d

Fe-N (Iron - Nitrogen)

H.A Wriedt, N.A Gokcen, and R.H Nafziger, 1992

Fe-N phase diagram

Fe-N crystallographic data

Fe-Nb (Iron - Niobium)

E Paul and L.J Swartzendruber, 1992

Fe-Nb phase diagram

Fe-Nb crystallographic data

Fe-Nd (Iron - Neodymium)

W Zhang, G Liu, and K Han, 1992

Fe-Nd phase diagram

Fe-Nd crystallographic data

Fe-Ni (Iron - Nickel)

L.J Swartzendruber, V.P Itkin, and C.B Alcock, 1992

Fe-Ni phase diagram

Fe-Ni crystallographic data

Fe-O phase diagram

Fe-O phase diagram from 22 to 31 wt% O

Fe-O crystallographic data

(a) Stable at pressures >13 GPa

(b) Incommensurate or orthorhombic

(c) Magnetic reflections might indicate linear cell dimensions are doubled,

corresponding to hR16

(d) Stable at pressures >25 GPa

Fe-P (Iron - Phosphorus)

H Okamoto, 1992

Fe-P phase diagram

Fe-P crystallographic data

Fe-Pd phase diagram

Fe-Pd crystallographic data

Fe-Pu phase diagram

Fe-Pu crystallographic data

( 'Pu) 100 tI2 I4/mmm

Fe-Rh phase diagram

Fe-Rh crystallographic data

Fe-rich region of the Fe-S system

Fe-S crystallographic data

Reference cited in this section

9 [Kubaschewski]: O Kubaschewski, Iron Binary Phase Diagrams, Springer-Verlag, New York (1982)

Fe-Sb (Iron - Antimony)

H Okamoto, 1992

Fe-Sb phase diagram

Fe-Sb crystallographic data

Metastable phase

Fe-Sc (Iron - Scandium)

H Okamoto, 1992

Fe-Sc phase diagram

Fe-Sc crystallographic data

Fe-Se phase diagram

Fe-Se crystallographic data

Fe-Si (Iron - Silicon)

From [Kubaschewski] 9

Fe-Si phase diagram

Fe-Si crystallographic data

FeSi 2 53.4 to 58.2 tP3 P4/mmm

FeSi 2 50.2 oC48 Cmca

(Si) 100 cF8 Fd m

Reference cited in this section

9 [Kubaschewski]: O Kubaschewski, Iron Binary Phase Diagrams, Springer-Verlag, New York (1982)

Fe-Sm (Iron - Samarium)

H Okamoto, 1992

Fe-Sm phase diagram

Fe-Sm crystallographic data

Fe-Sn (Iron - Tin)

H Okamoto, 1992

Fe-Sn phase diagram

Fe-Sn crystallographic data

Fe-Tb phase diagram

Fe-Tb crystallographic data

Fe-Te (Iron - Tellurium)

H Okamoto and L.E Tanner, 1992

Fe-Te phase diagram

Fe-Te crystallographic data

1

(a)

66 to 68 mP* P21/m

73.0

Fe-Th phase diagram

Fe-Th crystallographic data

Fe-Ti (Iron - Titanium)

J.L Murray, 1992

Fe-Ti phase diagram

Fe-Ti crystallographic data

(a) Metastable phase

Fe-Tm (Iron - Thulium)

H Okamoto, 1992

Fe-Tm phase diagram

Fe-Tm crystallographic data

Fe-U phase diagram

Fe-U crystallographic data

Fe-V phase diagram

Fe-V crystallographic data

Fe-W (Iron - Tungsten)

S.V Nagender Naidu, A.M Sriramamurthy, and P Rama Rao, 1992

Fe-W phase diagram

Fe-W crystallographic data

Fe-Zn (Iron - Zinc)

B.P Burton and P Perrot, 1992

Fe-Zn phase diagram

Fe-Zn crystallographic data

Fe-Zr (Iron - Zirconium)

D Arias and J.P Abriata, 1992

Fe-Zr phase diagram

Fe-Zr crystallographic data

• “Ag-Ga (Silver - Gallium)” in the article “Ag (Silver) Binary Alloy Phase Diagrams.”

• “Al-Ga (Aluminum - Gallium)” in the article “Al (Aluminum) Binary Alloy Phase Diagrams.”

• “As-Ga (Arsenic - Gallium)” in the article “As (Arsenic) Binary Alloy Phase Diagrams.”

• “Au-Ga (Gold - Gallium)” in the article “Au (Gold) Binary Alloy Phase Diagrams.”

• “Ba-Ga (Barium - Gallium)” in the article “Ba (Barium) Binary Alloy Phase Diagrams.”

• “Bi-Ga (Bismuth - Gallium)” in the article “Bi (Bismuth) Binary Alloy Phase Diagrams.”

• “Ca-Ga (Calcium - Gallium)” in the article “Ca (Calcium) Binary Alloy Phase Diagrams.”

• “Cd-Ga (Cadmium - Gallium)” in the article “Cd (Cadmium) Binary Alloy Phase Diagrams.”

• “Ce-Ga (Cerium - Gallium)” in the article “Ce (Cerium) Binary Alloy Phase Diagrams.”

• “Cl-Ga (Chlorine - Gallium)” in the article “Cl (Chlorine) Binary Alloy Phase Diagrams.”

• “Co-Ga (Cobalt - Gallium)” in the article “Co (Cobalt) Binary Alloy Phase Diagrams.”

• “Cr-Ga (Chromium - Gallium)” in the article “Cr (Chromium) Binary Alloy Phase Diagrams.”

• “Cu-Ga (Copper - Gallium)” in the article “Cu (Copper) Binary Alloy Phase Diagrams.”

• “Dy-Ga (Dysprosium - Gallium)” in the article “Dy (Dysprosium) Binary Alloy Phase Diagrams.”

• “Er-Ga (Erbium - Gallium)” in the article “Er (Erbium) Binary Alloy Phase Diagrams.”

• “Eu-Ga (Europium - Gallium)” in the article “Eu (Europium) Binary Alloy Phase Diagrams.”

• “Fe-Ga (Iron - Gallium)” in the article “Fe (Iron) Binary Alloy Phase Diagrams.”

Ga-Gd (Gallium - Gadolinium)

A Palenzona and S Cirafici, 1990

Ga-Gd phase diagram

Ga-Gd crystallographic data

Ga-Ho (Gallium - Holmium)

H Okamoto, 1990

Ga-Ho phase diagram

Ga-Ho crystallographic data

(Ho) 100 hP2 P63/mmc

Ga-In (Gallium - Indium)

T.J Anderson and I Ansara, 1992

Ga-In phase diagram

Ga-In crystallographic data

(In) 98.6 to 100 tI2 I4/mmm

Ga-La (Gallium - Lanthanum)

A Palenzona and S Cirafici, 1990

Ga-La phase diagram

Ga-La crystallographic data

( La) 100 cF4 Fm m

( La) 100 hP4 P63/mmc

(a) Not shown on diagram; needs further

confirmation

Ga-Li (Gallium - Lithium)

J Sangster and A.D Pelton, 1991

Ga-Li phase diagram

Ga-Li crystallographic data

Ga-Lu (Gallium - Lutetium)

S.P Yatsenko, A.A Semyannikov, B.G Semenov, and K.A Chuntonov, 1979

Ga-Lu phase diagram

Ga-Lu crystallographic data

Ga-Mg phase diagram

Ga-Mg crystallographic data

(Ga) 100 oC8 Cmca

(a) The structure is closely related to the Fe2P (hP9) type

with a small deviation

Ga-Mn (Gallium - Manganese)

X.S Lu, J.K Liang, and M.G Zhou, 1980

Ga-Mn phase diagram

Ga-Mn crystallographic data

Ga-Mo phase diagram

Ga-Mo crystallographic data

(Ga) 100 oC8 Cmca

Reference cited in this section

12 [Molybdenum]: L Brewer, Molybdenum: Physico-Chemical Properties of Its Compounds and Alloys, O

Kubaschewski, Ed., Atomic Energy Review Special Issue No.7, International Atomic Energy Agency, Vienna (1980)

Ga-Na (Gallium - Sodium)

A.D Pelton and S Larose, 1990

Ga-Na phase diagram

Ga-Na crystallographic data

(b) Structure observed when compound prepared with excess Na

(c) Same compound with same diffractogram, although different

stoichiometries have been reported

Ga-Nb (Gallium - Niobium)

H Okamoto, 1990

Ga-Nb phase diagram

Ga-Nb crystallographic data

(a) Not in phase diagram

Ga-Nd (Gallium - Neodymium)

From [Moffatt] 11

Ga-Nd phase diagram

Ga-Nd crystallographic data

Reference cited in this section

11 [Moffatt]: W.G Moffatt, Ed., Handbook of Binary Phase Diagrams, Business Growth Services, General

Electric Co., Schenectady, NY (1976)

Ga-Ni (Gallium - Nickel)

S.Y Lee and P Nash, 1991

Ga-Ni phase diagram

Ga-Ni crystallographic data

'(Ni 2 Ga 3 ) 64 hP5 P m1

(NiGa 4 ) 83 cI52 I 3m

Ga-Pb (Gallium - Lead)

I Ansara and F Ajersch, 1991

Ga-Pb phase diagram

Ga-Pb crystallographic data

Ga-Pd (Gallium - Palladium)

H Okamoto, 1990

Ga-Pd phase diagram

Ga-Pd crystallographic data

Ga-Pr phase diagram

Ga-Pr crystallographic data

Ga-Pt phase diagram

Ga-Pt crystallographic data

Ga-Pu (Gallium - Plutonium)

D.E Peterson and M.E Kassner, 1988

Ga-Pu phase diagram

Ga-Pu crystallographic data

(Ga) 100 oC8 Cmca

(a) Partially ordered

(b) Face-centered cubic

(c) Tetragonal

(d) Body-centered tetragonal

(e) Hexagonal

Ga-S (Gallium - Sulfur)

P.G Rustamov, B.N Mardakhaev, and M.G Safarov, 1967

Ga-S phase diagram

Ga-S crystallographic data

Ga-Sb (Gallium - Antimony)

T.I Ngai, R.C Sharma, and Y.A Chang, 1988

Ga-Sb phase diagram

Ga-Sb crystallographic data

GaSb 63.6 cF8 F4 m

GaSb (a) 63.6 tI4 I41/amd

(Sb) 100 hR2 R m

(a) At high pressure

Ga-Sc (Gallium - Scandium)

S.P Yatsenko, A.A Semyannikov, G.B Semenov, and K.A Chuntonov, 1979

Ga-Sc phase diagram

Ga-Sc crystallographic data

Ga-Se crystallographic data

R m

P P63mc

Ga 2 Se 3 63 c**

Ga 2 Se 3 63 mC20 Cc

(Se) 100 hP3 P3121

Reference cited in this section

11 [Moffatt]: W.G Moffatt, Ed., Handbook of Binary Phase Diagrams, Business Growth Services, General

Electric Co., Schenectady, NY (1976)

Ga-Sm (Gallium - Samarium)

From [Moffatt] 11

Ga-Sm phase diagram

Ga-Sm crystallographic data

( Sm) ? to 100 cI2 Im m

( Sm) ? to 100 hP2 P63/mmc

( Sm) 100 hR3 R m

Reference cited in this section

11 [Moffatt]: W.G Moffatt, Ed., Handbook of Binary Phase Diagrams, Business Growth Services, General

Electric Co., Schenectady, NY (1976)

Ga-Sn (Gallium - Tin)

T.J Anderson and I Ansara, 1992

Ga-Sn phase diagram

Ga-Sn crystallographic data

( Ga) (a) 0 to 0.03 tI2 I4/mmm

( Sn) 96.1 to 100 tI4 I41/amd

(a) Above 1.2 GPa

Ga-Sr (Gallium - Strontium)

V.P Itkin and C.B Alcock, 1992

Ga-Sr phase diagram

Ga-Sr crystallographic data

Ga 7 Sr 8 58.9 cP60 P213

( Sr) 100 cF4 Fm m

( Sr) 100 cI2 Im m

(a) After annealing at 900 °C

Ga-Tb (Gallium - Terbium)

From [Moffatt] 11

Ga-Tb phase diagram

Ga-Tb crystallographic data

Reference cited in this section

11 [Moffatt]: W.G Moffatt, Ed., Handbook of Binary Phase Diagrams, Business Growth Services, General

Electric Co., Schenectady, NY (1976)

Ga-Te (Gallium - Tellurium)

U.R Kattner, unpublished

Ga-Te phase diagram

Ga-Te crystallographic data

Ga-Tl (Gallium - Thallium)

J Klingbeil and R Schmid-Fetzer, 1991

Ga-Tl phase diagram

Ga-Tl crystallographic data

Ga-Tm (Gallium - Thulium)

From [Moffatt] 11

Ga-Tm phase diagram

Ga-Tm crystallographic data

(Tm) 100 hP2 P63/mmc

Reference cited in this section

11 [Moffatt]: W.G Moffatt, Ed., Handbook of Binary Phase Diagrams, Business Growth Services, General

Electric Co., Schenectady, NY (1976)

Ga-U (Gallium - Uranium)

K.H.J Buschow, 1973

Ga-U phase diagram

Ga-U crystallographic data

Ga-V phase diagram

Ga-V crystallographic data

(Ga) 100 oC8 Cmca

Ga-Y (Gallium - Yttrium)

S.P Yatsenko, 1977

Ga-Y phase diagram

Ga-Y crystallographic data

Ga-Yb (Gallium - Ytterbium)

A Palenzona and S Cirafici, 1992

Ga-Yb phase diagram

Ga-Yb crystallographic data

Ga-Zn (Gallium - Zinc)

J Dutkiewicz, Z Moser, L Zabdyr, D.D Gohil, T.G Chart, I Ansara, and C Girard, 1990

Ga-Zn phase diagram

Ga-Zn crystallographic data

Ga-Zr (Gallium - Zirconium)

From [Shunk] 17

Ga-Zr phase diagram

Ga-Zr crystallographic data

Reference cited in this section

17 [Shunk]: F.A Shunk, Constitution of Binary Alloys, Second Supplement, McGraw-Hill, New York or

General Electric Co., Business Growth Services, Schenectady, New York (1969)

Gd (Gadolinium) Binary Alloy Phase Diagrams

Introduction

THIS ARTICLE includes systems where gadolinium is the first-named element in the binary pair Additional binary systems that include gadolinium are provided in the following locations in this Volume:

• “Ag-Gd (Silver - Gadolinium)” in the article “Ag (Silver) Binary Alloy Phase Diagrams.”

• “Al-Gd (Aluminum - Gadolinium)” in the article “Al (Aluminum) Binary Alloy Phase Diagrams.”

• “Cd-Gd (Cadmium - Gadolinium)” in the article “Cd (Cadmium) Binary Alloy Phase Diagrams.”

• “Cu-Gd (Copper - Gadolinium)” in the article “Cu (Copper) Binary Alloy Phase Diagrams.”

• “Fe-Gd (Iron - Gadolinium)” in the article “Fe (Iron) Binary Alloy Phase Diagrams.”

• “Ga-Gd (Gallium - Gadolinium)” in the article “Ga (Gallium) Binary Alloy Phase Diagrams.”

Gd-Ge (Gadolinium - Germanium)

A.B Gokhale and G.J Abbaschian, 1989

Gd-Ge phase diagram

Gd-Ge crystallographic data

Gd-In (Gadolinium - Indium)

A Palenzona and S Cirafici, 1992

Gd-In phase diagram

Gd-In crystallographic data

(In) 100 tI2 I4/mmm

Gd-Ni (Gadolinium - Nickel)

Y.Y Pan and P Nash, 1991

Gd-Ni phase diagram

Gd-Ni crystallographic data

Gd-Te phase diagram

Gd-Te crystallographic data

Gd-Ti phase diagram

Gd-Ti crystallographic data

GdTl 3 80 cP4 Pm m

( Tl) 100 cI2 Im m

( Tl) 100 hP2 P63/mmc

(a) Cubic structure presumed to be room- and higher-temperature phases

(b) Tetragonal structure presumed to be lower-temperature phase

Ge (Germanium) Binary Alloy Phase Diagrams

Introduction

THIS ARTICLE includes systems where germanium is the first-named element in the binary pair Additional binary systems that include germanium are provided in the following locations in this Volume:

• “Ag-Ge (Silver - Germanium)” in the article “Ag (Silver) Binary Alloy Phase Diagrams.”

• “Al-Ge (Aluminum - Germanium)” in the article “Al (Aluminum) Binary Alloy Phase Diagrams.”

• “As-Ge (Arsenic - Germanium)” in the article “As (Arsenic) Binary Alloy Phase Diagrams.”

• “Au-Ge (Gold - Germanium)” in the article “Au (Gold) Binary Alloy Phase Diagrams.”

• “Ba-Ge (Barium - Germanium)” in the article “Ba (Barium) Binary Alloy Phase Diagrams.”

• “Bi-Ge (Bismuth - Germanium)” in the article “Bi (Bismuth) Binary Alloy Phase Diagrams.”

• “Ca-Ge (Calcium - Germanium)” in the article “Ca (Calcium) Binary Alloy Phase Diagrams.”

• “Cd-Ge (Cadmium - Germanium)” in the article “Cd (Cadmium) Binary Alloy Phase Diagrams.”

• “Ce-Ge (Cerium - Germanium)” in the article “Ce (Cerium) Binary Alloy Phase Diagrams.”

• “Co-Ge (Cobalt - Germanium)” in the article “Co (Cobalt) Binary Alloy Phase Diagrams.”

• “Cr-Ge (Chromium - Germanium)” in the article “Cr (Chromium) Binary Alloy Phase Diagrams.”

• “Cs-Ge (Cesium - Germanium)” in the article “Cs (Cesium) Binary Alloy Phase Diagrams.”

• “Cu-Ge (Copper - Germanium)” in the article “Cu (Copper) Binary Alloy Phase Diagrams.”

• “Dy-Ge (Dysprosium - Germanium)” in the article “Dy (Dysprosium) Binary Alloy Phase Diagrams.”

• “Er-Ge (Erbium - Germanium)” in the article “Er (Erbium) Binary Alloy Phase Diagrams.”

• “Eu-Ge (Europium - Germanium)” in the article “Eu (Europium) Binary Alloy Phase Diagrams.”

• “Fe-Ge (Iron - Germanium)” in the article “Fe (Iron) Binary Alloy Phase Diagrams.”

• “Gd-Ge (Gadolinium - Germanium)” in the article “Gd (Gadolinium) Binary Alloy Phase Diagrams.”

Ge-Ho (Germanium - Holmium)

V.N Eremenko, I.M Obushenko, and Yu.I Buyanov, 1980

Ge-Ho phase diagram

Ge-Ho crystallographic data

Ge-In (Germanium - Indium)

R.W Olesinski, N Kanani, and G.J Abbaschian, 1992

Ge-In phase diagram

Ge-In crystallographic data

(Ge) 0 cF8 Fd m

(In) 100 tI2 I4/mmm

Ge-K (Germanium - Potassium)

H Okamoto, 1990

Ge-K phase diagram

Ge-K crystallographic data

GeK 3 62

(K) 100 cI2 Im m

(a) Not shown in the phase diagram

Ge-La (Germanium - Lanthanum)

A.B Gokhale and G.J Abbaschian, 1989

Ge-La phase diagram

Ge-La crystallographic data

La 3 Ge 15 t**

La 5 Ge 3 23.9 hP16 P63/mcm

La 4 Ge 3 28.2 cI28 I 3d

La 5 Ge 4 29.5 oP* Pnma

LaGe 33 to 35 oP8 Pnma

LaGe2-x 45.5 to 46.4 oI* Imma

LaGe2-x 45.5 to 46.4 tI12 I41/amd

Ge-Li crystallographic data

(a) Not shown in the diagram

Ge-Lu (Germanium - Lutetium)

H Okamoto, 1990

Ge-Lu phase diagram

Ge-Lu crystallographic data

Ge-Mg (Germanium - Magnesium)

A.A Nayeb-Hashemi, R.W Olesinski, G.J Abbaschian, and J.B Clark, 1988

Ge-Mg phase diagram

Ge-Mg crystallographic data

Ge-Mn (Germanium - Manganese)

A.B Gokhale and G.J Abbaschian, 1990