Volume 03 - Alloy Phase Diagrams Part 7 pdf

• “Ag-Cu Silver - Copper” in the article “Ag Silver Binary Alloy Phase Diagrams.” • “Al-Cu Aluminum - Copper” in the article “Al Aluminum Binary Alloy Phase Diagrams.” • “As-Cu Arsenic

Cs-O (Cesium - Oxygen)

P.R Subramanian, 1990

Cs-O phase diagram

Cs-O crystallographic data

Reference cited in this section

19 [Smithells]: C.J Smithells and E.A Brandes, Metals Reference Book, 5th ed., Butterworths, Wobum, MA

(1976)

Cs-Se phase diagram

Cs-Se crystallographic data

Cs-Te (Cesium - Tellurium)

J Sangster and A.D Pelton, unpublished

Cs-Te phase diagram

Cs-Te crystallographic data

CsTe 4 79 mP20 P21/c

(Te) 100 hP3 P3121

(a) Might not exist

(b) Three allotropic forms have been reported to exist If so, this is the structure of a metastable temperature allotrope

• “Ag-Cu (Silver - Copper)” in the article “Ag (Silver) Binary Alloy Phase Diagrams.”

• “Al-Cu (Aluminum - Copper)” in the article “Al (Aluminum) Binary Alloy Phase Diagrams.”

• “As-Cu (Arsenic - Copper)” in the article “As (Arsenic) Binary Alloy Phase Diagrams.”

• “Au-Cu (Gold - Copper)” in the article “Au (Gold) Binary Alloy Phase Diagrams.”

• “B-Cu (Boron - Copper)” in the article “B (Boron) Binary Alloy Phase Diagrams.”

• “Ba-Cu (Barium - Copper)” in the article “Ba (Barium) Binary Alloy Phase Diagrams.”

• “Be-Cu (Beryllium - Copper)” in the article “Be (Beryllium) Binary Alloy Phase Diagrams.”

• “Bi-Cu (Bismuth - Copper)” in the article “Bi (Bismuth) Binary Alloy Phase Diagrams.”

• “C-Cu (Carbon - Copper)” in the article “C (Carbon) Binary Alloy Phase Diagrams.”

• “Ca-Cu (Calcium - Copper)” in the article “Ca (Calcium) Binary Alloy Phase Diagrams.”

• “Cd-Cu (Cadmium - Copper)” in the article “Cd (Cadmium) Binary Alloy Phase Diagrams.”

• “Ce-Cu (Cerium - Copper)” in the article “Ce (Cerium) Binary Alloy Phase Diagrams.”

• “Co-Cu (Cobalt - Copper)” in the article “Co (Cobalt) Binary Alloy Phase Diagrams.”

• “Cr-Cu (Chromium - Copper)” in the article “Cr (Chromium) Binary Alloy Phase Diagrams.”

Cu-Dy (Copper - Dysprosium)

P.R Subramanian and D.E Laughlin, 1988

Cu-Dy phase diagram

Cu-Dy crystallographic data

( 'Dy) 100 oC4 Cmcm

( Dy) 100 hP2 P63/mmc

( Dy) 100 cI2 Im m

Cu-Er (Copper - Erbium)

P.R Subramanian and D.E Laughlin, 1988

Cu-Er phase diagram

Cu-Er crystallographic data

CuEr 73 cP2 Pm m

(Er) 100 hP2 P63/mmc

Cu-Eu (Copper - Europium)

P.R Subramanian and D.E Laughlin, 1988

Cu-Eu phase diagram

Cu-Eu crystallographic data

CuEu 2 84.48 oP12 Pnma

(Eu) 100 cI2 Im m

Cu-Fe (Copper - Iron)

L.J Swartzendruber, 1992

Cu-Fe phase diagram

Cu-Fe crystallographic data

(Cu) 95.9 to 100 cF4 Fm m

Cu-Ga (Copper - Gallium)

P.R Subramanian and D.E Laughlin, unpublished

Cu-Ga phase diagram

Cu-Ga crystallographic data

(Ga) 100 oC8 Cmca

(a) The number of atoms/cell decreases from 52 to 47, as the Ga contents decrease from 32.0 to 44.6 wt%

Cu-Gd (Copper - Gadolinium)

P.R Subramanian and D.E Laughlin, 1988

Cu-Gd phase diagram

Cu-Gd crystallographic data

Cu-Ge (Copper - Germanium)

R.W Olesinski and G.J Abbaschian, 1986

Cu-Ge phase diagram

Cu-Ge crystallographic data

Other reported phase

''' 75.6

(d)

(a) Also denoted as Cu3Ge

(b) Rhombohedral

(c) Also denoted as Cu5Ge

(d) Cubic

Cu-H (Copper - Hydrogen)

O.M Barabash and Yu.N Koval, 1986

Cu-H phase diagram

Cu-H crystallographic data

Cu-Hf (Copper - Hafnium)

P.R Subramanian and D.E Laughlin, 1988

Cu-Hf phase diagram

Cu-Hf crystallographic data

Cu-Hg (Copper - Mercury)

D.J Chakrabarti and D.E Laughlin, 1985

Cu-Hg phase diagram

Cu-Hg crystallographic data

(b) Formed from Hg by strain-induced (martensitic) transformation at 4.2 K, reverting to Hg at 50 K

Cu-In (Copper - Indium)

H Okamoto, 1991

Cu-In phase diagram

Cu-In crystallographic data

Cu 11 In 9 59 mC20 C2/m

(In) 100 tI2 I4/mmm

Cu-Ir (Copper - Iridium)

D.J Chakrabarti and D.E Laughlin, 1987

Cu-Ir phase diagram

Cu-Ir crystallographic data

Cu-La phase diagram

Cu-La crystallographic data

Cu-Li phase diagram

Cu-Li crystallographic data

( Li) 100 hP2 P63/mmc

(a) Below 193 °C

Cu-Mg (Copper - Magnesium)

H Okamoto, 1992

Cu-Mg phase diagram

Cu-Mg crystallographic data

Cu-Mn (Copper - Manganese)

N.A Gokcen, unpublished

Cu-Mn phase diagram

Cu-Mn crystallographic data

H Okamoto, 1991

Cu-Nb phase diagram

Enlargement of the Cu-rich portion of the Cu-Nb system

Cu-Nb crystallographic data

Cu-Nd (Copper - Neodymium)

P.R Subramanian and D.E Laughlin, 1988

Cu-Nd phase diagram

Cu-Nd crystallographic data

Cu-Ni (Copper - Nickel)

D.J Chakrabarti, D.E Laughlin, S.W Chen, and Y.A Chang, 1991

Cu-Ni phase diagram

Cu-Ni crystallographic data

(a) Above 354.5 °C

Cu-O (Copper - Oxygen)

J.P Neumann, T Zhong, and Y.A Chang, 1984

Cu-O phase diagram

Cu-O stability diagram

Solubility of O in (Cu)

Cu-O crystallographic data

Phase Composition, Pearson Space

Cu-P phase diagram

Cu-P crystallographic data

(a) Not shown in the diagram

Cu-Pb (Copper - Lead)

D.J Chakrabarti and D.E Laughlin, 1984

Cu-Pb phase diagram

Cu-Pb crystallographic data

Cu-Pd (Copper - Palladium)

P.R Subramanian and D.E Laughlin, 1991

Cu-Pd phase diagram

Cu-Pd crystallographic data

Cu-Pt (Copper - Platinum)

P.R Subramanian and D.E Laughlin, unpublished

Cu-Pt phase diagram

Cu-Pt crystallographic data

Cu-Pu (Copper - Plutonium)

V.I Kutaitsev, N.T Chebotarev, I.G Lebedev, M.A Andrianov, V.N Konev, and T.S Menshikova, 1967

Cu-Pu phase diagram

Cu-Pu crystallographic data

Cu-Rh (Copper - Rhodium)

D.J Chakrabarti and D.E Laughlin, 1982

Cu-Rh phase diagram

Cu-Rh crystallographic data

Cu-S (Copper - Sulfur)

D.J Chakrabarti and D.E Laughlin, 1983

Cu-S phase diagram

Enlargement of the Cu-S diagram from 0 to 160 °C

Cu-saturated boundary of digenite phase diagram

Cu-S crystallographic data

Fddd P21/a

Cu-Sb phase diagram

Cu-Sb crystallographic data

Cu-Se (Copper - Selenium)

D.J Chakrabarti and D.E Laughlin, 1981

Cu-Se phase diagram

Cu-Se crystallographic data

(Se) 100 hP3 P3121

(a) Monoclinic

(b) Homogeneity range at room temperature, 0.18 x 0.22, and at

500 °C, x = 0 to 0.26

Cu-Si (Copper - Silicon)

R.W Olesinski and G.J Abbaschian, 1986

Cu-Si phase diagram

Cu-Si crystallographic data

Cu-Sn (Copper - Tin)

N Saunders and A.P Miodownik, 1990

Cu-Sn phase diagram

Cu-Sn crystallographic data

( Sn) 100 tI4 I41/amd

( Sn) 100 cF8 Fd m

Note: Lattice parameter data can be found in [Pearson3] 14

(a) Hexagonal; superlattice based on NiAs-type structure

Reference cited in this section

14 [Pearson3]: P Villars and L.D Calvert, Pearson's Handbook of Crystallographic Data for Intermetallic

Phases, Vol.1, 2, and 3, American Society for Metals, Metals Park, OH (1985)

Cu-Sr (Copper - Strontium)

D.J Chakrabarti and D.E Laughlin, 1984

Cu-Sr phase diagram

Cu-Sr crystallographic data

Cu-Te phase diagram

Details of the Cu-Te phase diagram from 49.7 to 53.6 wt% Te

Cu-Te crystallographic data

High-pressure phase

CuTe 2 50.1 cP12 Pa3

Cu-Th (Copper - Thorium)

D.J Chakrabarti, D.E Laughlin, and D.E Peterson, 1986

Cu-Th phase diagram

Cu-Th crystallographic data

Transformation of TiCu4 TiCu4

Cu-Ti crystallographic data

TiCu 2 72.7 oC12 Amm2

TiCu 4 83 to 84.9 oP20 Pnma

TiCu 4 83 to 84.9 tI10 I4/m

(Cu) 94 to 100 cF4 Fm m

Metastable phases

TiCu 3 oP8 Pmnm

'' tP2 P4/mmm

Cu-Tl (Copper - Thallium)

D.J Chakrabarti and D.E Laughlin, 1984

Cu-Tl phase diagram

Cu-Tl crystallographic data

( Tl) 100 hP2 P63/mmc

( Tl) 100 cI2 Im m

Pressure-stabilized phase

Tl 100 cF?

Cu-V (Copper - Vanadium)

J.F Smith and O.N Carlson, 1989

Cu-V phase diagram

Cu-V crystallographic data

Cu-Yb (Copper - Ytterbium)

P.R Subramanian and D.E Laughlin, 1988

Cu-Yb phase diagram

Cu-Yb crystallographic data

Cu-Zn (Copper - Zinc)

A.P Miodownik, unpublished

Cu-Zn phase diagram

Cu-Zn crystallographic data

Cu-Zr (Copper - Zirconium)

D Arias and J.P Abriata, 1990

Cu-Zr phase diagram

Cu-Zr crystallographic data

( Zr) 97.8 to 100 cI2 Im m

( Zr) 99.86 to 100 hP2 P63/mmc

(a) Tetragonal long-period superlattice derived from the

AuBe5-type structure

Dy (Dysprosium) Binary Alloy Phase Diagrams

Introduction

THIS ARTICLE includes systems where dysprosium is the first-named element in the binary pair Additional binary systems that include dysprosium are provided in the following locations in this Volume:

• “Ag-Dy (Silver - Dysprosium)” in the article “Ag (Silver) Binary Alloy Phase Diagrams.”

• “Au-Dy (Gold - Dysprosium)” in the article “Au (Gold) Binary Alloy Phase Diagrams.”

• “Co-Dy (Cobalt - Dysprosium)” in the article “Co (Cobalt) Binary Alloy Phase Diagrams.”

• “Cu-Dy (Copper - Dysprosium)” in the article “Cu (Copper) Binary Alloy Phase Diagrams.”

Dy-Fe (Dysprosium - Iron)

H Okamoto, 1992

Dy-Fe phase diagram

Dy-Fe crystallographic data

Dy-Ga phase diagram

Dy-Ga crystallographic data

(Ga) 0 oC8 Cmca

Reference cited in this section

11 [Moffatt]: W.G Moffatt, Ed., Handbook of Binary Phase Diagrams, Business Growth Services, General

Electric Co., Schenectady, NY (1976)

Dy-Ge (Dysprosium - Germanium)

V.N Eremenko, V.G Batalin, Yu.I Buyanov, and I.M Obushenko, 1977

Dy-Ge phase diagram

Dy-Ge crystallographic data

(a) High-temperature (>750 °C) phase?

Dy-In (Dysprosium - Indium)

H Okamoto, 1992

Dy-In phase diagram

Dy-In crystallographic data

(In) 100 tI2 I4/mmm

(a) Not accepted in the assessed

diagram

Dy-Mn (Dysprosium - Manganese)

H.R Kirchmayr and W Lugscheider, 1967

Dy-Mn phase diagram

Dy-Mn crystallographic data

( Mn) 100 cP20 P4132

( Mn) 100 cI58 I 3m

Dy-Ni (Dysprosium - Nickel)

Y.Y Pan and P Nash, 1991

Dy-Ni phase diagram

Dy-Ni crystallographic data

Dy-Pb (Dysprosium - Lead)

O.D McMasters, T.J O'Keefe, and K.A Gschneidner, Jr., 1968

Dy-Pb phase diagram

Dy-Pb crystallographic data

(Pb) 100 cF4 Fm m

Dy-Pd (Dysprosium - Palladium)

H Okamoto, 1990

Dy-Pd phase diagram

Dy-Pd crystallographic data

DyPd 39.6 oP8 Pnma

Dy-S crystallographic data

Dy-Sb (Dysprosium - Antimony)

H Okamoto, 1990

Dy-Sb phase diagram

Dy-Sb crystallographic data

'DySb 42.8 tI4 I4/mmm

Dy-Sn phase diagram

Dy-Sn crystallographic data

Dy-Tl (Dysprosium - Thallium)

S Delfino, A Saccone, A Palenzona, and R Ferro, unpublished

Dy-Tl phase diagram

Dy-Tl crystallographic data

Dy-Zr (Dysprosium - Zirconium)

J Croni, C.E Armantrout, and H Kato, 1960

Dy-Cr phase diagram

Dy-Zr crystallographic data

Phase Composition, Pearson Space

• “Ag-Er (Silver - Erbium)” in the article “Ag (Silver) Binary Alloy Phase Diagrams.”

• “Al-Er (Aluminum - Erbium)” in the article “Al (Aluminum) Binary Alloy Phase Diagrams.”

• “Co-Er (Cobalt - Erbium)” in the article “Co (Cobalt) Binary Alloy Phase Diagrams.”

• “Cu-Er (Copper - Erbium)” in the article “Cu (Copper) Binary Alloy Phase Diagrams.”

Er-Fe (Erbium - Iron)

H Okamoto, 1992

Er-Fe phase diagram

Er-Fe crystallographic data

Er-Ga (Erbium - Gallium)

H Okamoto, 1990

Er-Ga phase diagram

Er-Ga crystallographic data

(Er) 100 hP2 P63/mmc

Er-Ge (Erbium - Germanium)

H Okamoto, 1990

Er-Ge phase diagram

Er-Ge crystallographic data

Er-In crystallographic data

Er-Mn (Erbium - Manganese)

H.R Kirchmayr and W Lugscheider, 1967

Er-Mn phase diagram

Er-Mn crystallographic data

( Mn) 100 cI58 I 3m

Er-Ni (Erbium - Nickel)

Y.Y Pan and P Nash, 1991

Er-Ni phase diagram

Er-Ni crystallographic data

Er-Pd crystallographic data

Er-Pt (Erbium - Platinum)

H Okamoto, 1990

Er-Pt phase diagram

Er-Pt crystallographic data

Er-Se phase diagram

Er-Se crystallographic data

Er 2 Se 3 38.6 to 42 oF80 Fddd

ErSe 2 48.6 oC132 Cmma

ErSe 2 48.6 oI12 Immm

(Se) 100 hP3 P3121

Er-Te (Erbium - Tellurium)

H Okamoto, 1990

Er-Te phase diagram

Er-Te crystallographic data

Er-Ti phase diagram

Er-Ti crystallographic data

( Ti) 0 to 1.0 hP2 P63/mmc

(Er) 99.7 to 100 hP2 P63/mmc

Er-Tl (Erbium - Thallium)

S Delfino, A Saccone, A Palenzona, and R Ferro, unpublished

Er-Tl phase diagram

Er-Tl crystallographic data

(b) Tetragonal structure presumed to be lower temperature phase

Eu (Europium) Binary Alloy Phase Diagrams

Introduction

THIS ARTICLE includes systems where europium is the first-named element in the binary pair Additional binary systems that include europium are provided in the following locations in this Volume:

• “Ag-Eu (Silver - Europium)” in the article “Ag (Silver) Binary Alloy Phase Diagrams.”

• “Au-Eu (Gold - Europium)” in the article “Au (Gold) Binary Alloy Phase Diagrams.”

• “Cd-Eu (Cadmium - Europium)” in the article “Cd (Cadmium) Binary Alloy Phase Diagrams.”

• “Cu-Eu (Copper - Europium)” in the article “Cu (Copper) Binary Alloy Phase Diagrams.”

Eu-Ga (Europium - Gallium)

S.P Yatsenko, B.G Semenov, and K.A Chuntonov, 1978

Eu-Ga phase diagram

Eu-Ga crystallographic data

EuGa 4 65 tI10 I4/mmm

(Ga) 100 oC8 Cmca

(a) Hexagonal structure presumed to be lower

temperature phase

(b) Cubic structure presumed to be higher

temperature phase

Eu-Ge (Europium - Germanium)

A.B Gokhale and G.J Abbaschian, 1991

Eu-Ge phase diagram

Eu-Ge crystallographic data

(a) Hexagonal structure

Eu-In (Europium - Indium)

H Okamoto, 1990

Eu-In phase diagram

Eu-In crystallographic data

Eu-Mg (Europium - Magnesium)

H Okamoto, 1992

Eu-Mg phase diagram

Eu-Mg crystallographic data

Eu-Pb (Europium - Lead)

O.D McMasters and K.A Gschneidner, Jr., 1967

Eu-Pb phase diagram

Eu-Pb crystallographic data

(a) Crystal structure data might be for EuPb

Eu-Pd (Europium - Palladium)

H Okamoto, 1990

Eu-Pd phase diagram

Eu-Pd crystallographic data

EuPd 3 68 cP4 Pm m

EuPd 5 77.7 o*72

EuPd 7 83.1 c**

(Pd) 86 to 100 cF4 Fm m

Eu-Pt (Europium - Platinum)

A Iandelli and A Palenzona, 1981

Eu-Pt phase diagram

Eu-Pt crystallographic data

Eu-Te (Europium - Tellurium)

O.A Sadovskaya and E.I Yarembash, 1970

Eu-Te Phase-Diagram

Eu-Te crystallographic data

• “Ag-Fe (Silver - Iron)” in the article “Ag (Silver) Binary Alloy Phase Diagrams.”

• “Al-Fe (Aluminum - Iron)” in the article “Al (Aluminum) Binary Alloy Phase Diagrams.”

• “As-Fe (Arsenic - Iron)” in the article “As (Arsenic) Binary Alloy Phase Diagrams.”

• “Au-Fe (Gold - Iron)” in the article “Au (Gold) Binary Alloy Phase Diagrams.”

• “B-Fe (Boron - Iron)” in the article “B (Boron) Binary Alloy Phase Diagrams.”

• “Be-Fe (Beryllium - Iron)” in the article “Be (Beryllium) Binary Alloy Phase Diagrams.”

• “C-Fe (Carbon - Iron)” in the article “C (Carbon) Binary Alloy Phase Diagrams.”

• “Ce-Fe (Cerium - Iron)” in the article “Ce (Cerium) Binary Alloy Phase Diagrams.”

• “Co-Fe (Cobalt - Iron)” in the article “Co (Cobalt) Binary Alloy Phase Diagrams.”

• “Cr-Fe (Chromium - Iron)” in the article “Cr (Chromium) Binary Alloy Phase Diagrams.”

• “Cu-Fe (Copper - Iron)” in the article “Cu (Copper) Binary Alloy Phase Diagrams.”

• “Dy-Fe (Dysprosium - Iron)” in the article “Dy (Dysprosium) Binary Alloy Phase Diagrams.”

• “Er-Fe (Erbium - Iron)” in the article “Er (Erbium) Binary Alloy Phase Diagrams.”