Volume 03 - Alloy Phase Diagrams Part 3 potx

Calderwood, 1985 Ag-Eu phase diagram Ag-Eu crystallographic data Phase Composition, wt% Eu Pearson symbol Space group... Calderwood, 1985 Ag-Gd phase diagram Ag-Gd crystallographic

Ag-Eu (Silver - Europium)

K.A Gschneidner, Jr and F.W Calderwood, 1985

Ag-Eu phase diagram

Ag-Eu crystallographic data

Phase Composition,

wt% Eu

Pearson symbol

Space group

Ag-Fe (Silver - Iron)

L.J Swartzendruber, 1984

Ag-Fe phase diagram

Ag-Fe crystallographic data

Phase Composition,

wt% Ag

Pearson symbol

Space group

δor (δFe) 0 to 0.033 cI2 Im3m

γor (γFe) 0 to 0.042 cF4 Fm3m

αor (αFe) 0 to 0.0004 cI2 Im3m

(Ag) 99.99663 to 100 cF4 Fm3m

Ag-Ga (Silver - Gallium)

H Okamoto, 1992

Ag-Ga phase diagram

Ag-Ga crystallographic data

Phase Composition,

wt% Ga

Pearson symbol

Space group

Ag-Gd (Silver - Gadolinium)

K.A Gschneidner, Jr and F.W Calderwood, 1985

Ag-Gd phase diagram

Ag-Gd crystallographic data

Phase Composition,

wt% Gd

Pearson symbol

Space group

Ag-Ge (Silver - Germanium)

R.W Olesinski and G.J Abbaschian, 1988

Ag-Ge phase diagram

Ag-Ge crystallographic data

Phase Composition,

wt% Ag

Pearson symbol

Space group

Ag-Hg (Silver - Mercury)

M.R Baren, unpublished

Ag-Hg phase diagram

Ag-Hg crystallographic data

Phase Composition,

wt% Hg

Pearson symbol

Space group

(Ag) 0 to 52.5 cF4 Fm3m

58.9 to 61.3 hP2 P63/mmc

γ 70.0 to 71.0 cI* I23

(αHg) 100 hR1 R3m

Ag-Ho (Silver - Holmium)

K.A Gschneidner, Jr and F.W Calderwood, 1985

Ag-Ho phase diagram

Ag-Ho crystallographic data

Phase Composition,

wt% Ho

Pearson symbol

Space group

Ag-In (Silver - Indium)

M.R Baren, 1992

Ag-In phase diagram

Ag-In crystallographic data

Phase Composition,

wt% In

Pearson symbol

Space group

(AgIn2) 68.1 tI12 I4/mcm

Metastable phases

19.4 hP2 P63/mmc

71 to 81 cF4 Fm3m

Ag-La (Silver - Lanthanum)

K.A Gschneidner, Jr and F.W Calderwood, 1983

Ag-La phase diagram

Ag-La crystallographic data

Phase Composition,

wt% La

Pearson symbol

Space group

Ag-Li phase diagram

Ag-Li crystallographic data

Phase Composition,

wt% Li

Pearson symbol

Space group

Ag-Mg (Silver - Magnesium)

A.A Nayeb-Hashemi and J.B Clark, 1988, with modifications

Ag-Mg phase diagram

Ag-Mg crystallographic data

Phase Composition,

wt% Mg

Pearson symbol

Space group

Ag-Mo (Silver - Molybdenum)

M.R Baren, 1990

Ag-Mo phase diagram

Ag-Mo crystallographic data

Phase Composition,

wt% Mo

Pearson symbol

Space group

(Ag) 0 to 0.13 cF4 Fm3m

(Mo) 100 cI2 Im3m

Ag-Na (Silver - Sodium)

A.D Pelton, 1986

Ag-Na phase diagram

Ag-Na crystallographic data

Phase Composition,

wt% Na

Pearson symbol

Space group

Ag2Na 9.6 cF24 Fd3m

(βNa) 100 cI2 Im3m

Ag-Nd (Silver - Neodymium)

K.A Gschneidner, Jr and F.W Calderwood, 1985

Ag-Nd phase diagram

Ag-Nd crystallographic data

Phase Composition,

wt% Nd

Pearson symbol

Space group

Ag-Ni (Silver - Nickel)

M Singleton and P Nash, 1991

Ag-Ni phase diagram

Ag-Ni crystallographic data

Phase Composition,

wt% Ag

Pearson symbol

Space group

(Ni) 0 to 1.8 cF4 Fm3m

(Ag) 99.3 to 100 cF4 Fm3m

Ag-P (Silver - Phosphorus)

I Karakaya and W.T Thompson, 1988

Ag-P phase diagram

Ag-P crystallographic data

Phase Composition,

wt% P

Pearson symbol

Space group

(b) Monoclinic structure with β= 118.84°

(c) At high pressures black P transforms to a

rhombohedral structure

(d) Cubic below -35 °C

(e) Cubic with 66 atoms per unit cell

Ag-Pb (Silver - Lead)

I Karakaya and W.T Thompson, 1987

Ag-Pb phase diagram

Ag-Pb crystallographic data

Phase Composition,

wt% Pb

Pearson symbol

Space group

(Ag) 0 to 5.2 cF4 Fm3m

(Pb) 99.9 to 100 cF4 Fm3m

Ag-Pd (Silver - Palladium)

I Karakaya and W.T Thompson, 1988

Ag-Pd phase diagram

Ag-Pd crystallographic data

Phase Composition,

wt% Pd

Pearson symbol

Space group

(Ag,Pd) 0 to 100 cF4 Fm3m

Ag-Pr (Silver - Praseodymium)

K.A Gschneidner, Jr and F.W Calderwood, 1985

Ag-Pr phase diagram

Ag-Pr crystallographic data

Phase Composition,

wt% Pr

Pearson symbol

Space group

(α Pr) 99.0 to 100 hP4 P63/mmc

Ag-Pt (Silver - Platinum)

I Karakaya and W.T Thompson, 1987

Ag-Pt phase diagram

Ag-Pt crystallographic data

Phase Composition (a) ,

wt% Pt

Pearson symbol

Space group

β' 57 to 60

γ 80 to 89 cP4 Pm3m

γ' 83 to 85 cF*

Note: α', α'', β, β', γ, and γ' phases are questionable

(a) Rough composition from phase diagram

(b) Rhombohedrally distorted cubic structure

Ag-S (Silver - Sulfur)

R.C Sharma and Y.A Chang, 1986

Ag-S phase diagram

Ag-S crystallographic data

Phase Composition,

wt% S

Pearson symbol

Space group

(a) High-pressure phase

Ag-Sb (Silver - Antimony)

From [Hansen] 6

Ag-Sb phase diagram

Ag-Sb crystallographic data

Phase Composition,

wt% Sb

Pearson symbol

Space group

(a) Ordered orthorhombic, L60 related

Reference cited in this section

6 [Hansen]: M Hansen and K Anderko, Constitution of Binary Alloys, McGraw-Hill, New York or General

Electric Co., Business Growth Services, Schenectady, New York (1958)

Ag-Sc (Silver - Scandium)

K.A Gschneidner, Jr and F.W Calderwood, 1983

Ag-Sc phase diagram

Ag-Sc crystallographic data

Phase Composition,

wt% Sc

Pearson symbol

Space group

Ag-Se (Silver - Selenium)

I Karakaya and W.T Thompson, 1990

Ag-Se phase diagram

Ag-Se crystallographic data

Phase Composition,

wt% Se

Pearson symbol

Space group

β Ag2Se 26.8 cI*

Ag2Se 26.8 o**

(Se) 100 hP3 P3121

Ag-Si (Silver - Silicon)

R.W Olesinski and G.J Abbaschian, 1989

Ag-Si phase diagram

Ag-Si crystallographic data

Phase Composition,

wt% Ag

Pearson symbol

Space group

(b) cph

Ag-Sm (Silver - Samarium)

K.A Gschneidner, Jr and F.W Calderwood, 1985

Ag-Sm phase diagram

Ag-Sm crystallographic data

Phase Composition,

wt% Sm

Pearson symbol

Space group

(γSm) 100

(βSm) 100 hP2 P63/mmc

Ag-Sn (Silver - Tin)

I Karakaya and W.T Thompson, 1987

Ag-Sn phase diagram

Ag-Sn crystallographic data

Phase Composition,

wt% Sn

Pearson symbol

Space group

(Ag) 0 to 12.5 cF4 Fm3m

12.8 to 24.58 hP2 P63/mmc

ε 25.5 to 27 oP8 Pmmn

(βSn) 99.92 to 100 tI4 I41/amd

(αSn) 100 cF8 Fd3m

Ag-Sr (Silver - Strontium)

M.R Baren, 1990

Ag-Sr phase diagram

Ag-Sr crystallographic data

Phase Composition,

wt% Sr

Pearson symbol

Space group

Ag5Sr 12.9 to 14.1 hP6 P6/mmm

Ag4Sr 17

AgSr 28.9 Imma

AgSr 44.8 oP8 Pnma

Ag-Te (Silver - Tellurium)

I Karakaya and W.T Thompson, 1991

Ag-Te phase diagram

Ag-Te crystallographic data

Phase Composition ,

wt% Te

Pearson symbol

Space group

(e) Mineral empressite (regarded as metastable)

(f) Tetragonal structure stable at pressures 2200 to 2500 kPa Lattice parameters were measured at 2400 kPa pressure

(g) Tetragonal structure stable at pressures over 2500 kPa Lattice parameters were measured at 4000 kPa pressure

(h) Simple cubic structure (metastable)

(i) Stable at temperatures higher than 358 °C and pressures over 4.0 GPa

Reference cited in this section

13 [Pearson2]: W.B Pearson, Handbook of Lattice Spacings and Structures of Metals and Alloys, Vol 2,

Pergamon Press, New York (1967)

Ag-Ti (Silver - Titanium)

J.L Murray and K.J Bhansali, 1987

Ag-Ti phase diagram

Ag-Ti crystallographic data

Phase Composition,

wt% Ag

Pearson symbol

Space group

(αTi) 0 to ~1.0 hP2 P6 /mmc

Ag-Tl phase diagram

Ag-Tl crystallographic data

Phase Composition,

wt% Tl

Pearson symbol

Space group

(Ag) 0 to ~13.8 cF4 Fm3m

(αTl) 100 hP2 P6 /mmc

(βTl) ? to 100 cI2 Im3m

(a) Above 230 °C

Ag-Y (Silver - Yttrium)

K.A Gschneidner, Jr and F.W Calderwood, 1983

Ag-Y phase diagram

Ag-Y crystallographic data

Phase Composition,

wt% Y

Pearson symbol

Space group

(Ag) 0 to 1.08 cF4 Fm3m

Ag51Y14 18.4 hP65

Ag2Y 29.2 tI6 I4/mmm

(βY) 100 cI2 Im3m

(αY) 100 hP2 P63/mmc

Ag-Yb (Silver - Ytterbium)

K.A Gschneidner, Jr and F.W Calderwood, 1985

Ag-Yb phase diagram

Ag-Yb crystallographic data

Phase Composition,

wt% Yb

Pearson symbol

Space group

(Ag) 0 to 3.04 cF4 Fm3m

Ag9Yb2

Ag7Yb2 31.4 hP18

Ag2Yb 44.5 oI2 Imma

Ag-Zn (Silver - Zinc)

K.W Andrews, H.E Davies, W Hume-Rothery, and C.R Oswin, 1940

Ag-Zn phase diagram

Ag-Zn crystallographic data

Phase Composition,

wt% Zn

Pearson symbol

Space group

(a) Ordered hexagonal

Ag-Zr (Silver - Zirconium)

I Karakaya and W.T Thompson, 1992

Ag-Zr phase diagram

Ag-Zr crystallographic data

Phase Composition,

wt% Zr

Pearson symbol

Space group

• “Ag-Al (Silver - Aluminum)” in the article “Ag (Silver) Binary Alloy Phase Diagrams.”

Al-As (Aluminum - Arsenic)

A J McAIister, 1984

Al-As phase diagram

Al-As crystallographic data

Phase Composition,

wt% As

Pearson symbol

Space group

(As) 100 hR2 R3m

Al-Au (Aluminum - Gold)

H Okamoto, 1991

Al-Au phase diagram

Al-Au crystallographic data

Phase Composition,

wt% Au

Pearson symbol

Space group

Al-Ba phase diagram

Al-Ba crystallographic data

Phase Composition,

wt% Ba

Pearson symbol

Space group

Al13Ba7 73 hP20 P3m1

Al5Ba4 80.3 hP18 P63/mmc

Other phases

Al5Ba3 75.3 hP16 P63/mmc

Al-Be (Aluminum - Beryllium)

J L Murray and D J Kahan, 1988

Al-Be (calculated) phase diagram

Al-Be crystallographic data

Phase Composition,

wt% Be

Pearson symbol

Space group

(Al) 0 to 0.10 cF4 Fm3m

(βBe) 99.979 to 100 cI2 Im3m

(αBe) 99.979 to 100 hP2 P63/mmc

Al-Bi (Aluminum - Bismuth)

A J McAllister, 1984

Al-Bi phase diagram

Al-Bi crystallographic data

Phase Composition,

wt% Bi

Pearson symbol

Space group

(Al) 0 to ~0.23 cF4 Fm3m

(Bi) 100 hR2 R3m

Al-Ca (Aluminum - Calcium)

V P Itkin, C B Alcock, P J van Ekeren, and H A J Oonk, 1988

Al-Ca phase diagram

Al-Ca crystallographic data

Phase Composition,

wt% Ca

Pearson symbol

Space group

Al-Cd (Aluminum - Cadmium)

A J McAlister, 1982

Al-Cd phase diagram

Al-Cd crystallographic data

Phase Composition,

wt% Cd

Pearson symbol

Space group

(Cd) 100 hP2 P63/mmc

Al-Ce (Aluminum - Cerium)

K.A Gschneidner, Jr and F.W Calderwood, 1988

Al-Ce phase diagram

Al-Ce crystallographic data

Phase Composition,

wt% Ce

Pearson symbol

Space group

Al-Co phase diagram

Al-Co crystallographic data

Phase Composition,

wt% Co

Pearson symbol

Space group

Al-Cr (Aluminum - Chromium)

J.L Murray, unpublished

Al-Cr phase diagram

Al-Cr crystallographic data

Phase Composition,

wt% Cr

Pearson symbol

Space group

Al-Cu phase diagram

Al-Cu crystallographic data

Phase Composition,

wt% Cu

Pearson symbol

Space group

(Al) 0 to 5.65 cF4 Fm3m

η 70.0 to 72.2 oP16 or oC16 Pban or Cmmm

(d) Unknown

(e) D022-type long-period superlattice

Al-Er (Aluminum - Erbium)

K.A Gschneidner, Jr and F.W Calderwood, 1988

Al-Er phase diagram

Al-Er crystallographic data

Phase Composition,

wt% Er

Pearson symbol

Space group

Al2Er3 90 tP20 P42/mnm

AlEr2 92.6 oP12 Pnma

(Er) 100 hP2 P63/mmc

Al-Fe (Aluminum - Iron)

U.R Kattner and B.P Burton, 1992

Al-Fe phase diagram

Al-Fe crystallographic data

Phase Composition,

wt% Al

Pearson symbol

Space group

(α Fe) 0 to ~28 cI2 Im3m

(γFe) 0 to 0.6 cF4 Fm3m

FeAl 12.8 to ~37 cP8 Pm3m

Al-Ga phase diagram

Al-Ga crystallographic data

Phase Composition,

wt% Ga

Pearson symbol

Space group

Al-Gd (Aluminum - Gadolinium)

K.A Gschneidner, Jr and F.W Calderwood, 1988

Al-Gd phase diagram

Al-Gd crystallographic data

Phase Composition,

wt% Gd

Pearson symbol

Space group

( Gd) 100 hP2 P63/mmc

Al-Ge (Aluminum - Germanium)

A.J McAlister and J.L Murray, 1984

Al-Ge phase diagram

Al-Ge crystallographic data

Phase Composition,

wt% Ge

Pearson symbol

mC*

t**

3 cP*

hP*

Al-H (Aluminum - Hydrogen)

A San-Martin and F.D Manchester, 1992

Al-H phase diagram

Al-H crystallographic data

Phase Composition,

wt% H

Pearson symbol

Space

group

(Al) 0 to 4.48 × 10-6(a) cF4 Fm3m

AlH3 (b) 10.1 R3c

(a) At 660 °C and 0.1 MPa

(b) Produced by chemical reaction of organic solvents at atmospheric pressure

Al-Hg (Aluminum - Mercury)

A.J McAlister, 1985

Al-Hg phase diagram

Al-Hg crystallographic data

Phase Composition,

wt% Hg

Pearson symbol

Space

group

(Hg) 100 hR1 R3m

Al-Ho (Aluminum - Holmium)

K.A Gschneidner, Jr and F.W Calderwood, 1988

Al-Ho phase diagram

Al-Ho crystallographic data

Phase Composition,

wt% Ho

Pearson symbol

Al-In (Aluminum - Indium)

J L Murray, 1983

Al-In phase diagram

Al-In crystallographic data

Phase Composition,

wt% In

Pearson symbol

Al-La (Aluminum - Lanthanum)

K.A Gschneidner, Jr and F.W Calderwood, 1988

Al-La phase diagram

Al-La crystallographic data

Phase Composition,

wt% La

Pearson symbol

Al-Li phase diagram

Al-Li crystallographic data

Phase Composition,

wt% Li

Pearson symbol

Space

group

(Al) 0 to 4 cF4 Fm3m

β 17 to 24 cF16 Fd3m

Al-Mg phase diagram

Al-Mg crystallographic data

Phase Composition,

wt% Mg

Pearson symbol

Al-Mn (Aluminum - Manganese)

A.J McAlister and J.L Murray, 1987

Al-Mn phase diagram

Al-Mn crystallographic data

Phase Composition,

wt% Mn

Pearson symbol

Al-Nb (Aluminum - Niobium)

U.R Kattner, unpublished

Al-Nb phase diagram

Al-Nb crystallographic data

Phase Composition,

wt% Al

Pearson symbol

Al-Nd (Aluminum - Neodymium)

H Okamoto, 1991

Al-Nd phase diagram

Al-Nd crystallographic data

Phase Composition,

wt% Nd

Pearson symbol

Space

group

(Al) 0 to 0.05 cF4 Fm3m

αAl11Nd3 59.3 oI28 Immm

βAl11Nd3 59.3 tI10 I4/mmm

Al2Nd 72.7 cF24 Fd3m

AlNd3 94 hP8 P63/mmc

( Nd) 100 cI2 Im3m

Al-Ni (Aluminum - Nickel)

P Nash, M.F Singleton, and J.L Murray, 1991

Al-Ni phase diagram

Al-Ni crystallographic data

Phase Composition,

wt% Ni

Pearson symbol

Al-Pb phase diagram

Al-Pb crystallographic data

Phase Composition,

wt% Pb

Pearson symbol

Space

group

(Pb) 99.7 to 100 cF4 Fm3m

Al-Pd (Aluminum - Palladium)

A.J McAlister, 1986

Al-Pd phase diagram

Al-Pd crystallographic data

Phase Composition,

wt% Pd

Pearson symbol

Al-Pr (Aluminum - Praseodymium)

K.A Gschneidner, Jr and F.W Calderwood, 1989

Al-Pr phase diagram

Al-Pr crystallographic data

Phase Composition,

wt% Pr

Pearson symbol

Space

group

Al-Pt (Aluminum - Platinum)

A.J McAlister and D.J Kahan, 1986

Al-Pt phase diagram

Al-Pt crystallographic data

Phase Composition,

wt% Pt

Pearson symbol

Al3Pt5 92.0 to 92.5 oP16 Pbam

AlPt2 93 to 94 oP12 Pnma

AlPt2(LT) 93 to 94 oP24 Pmma