The frequency depends on the energy of each photon and the number of photons per second depends on the power output of the source... c There is no energy level 8 eV above the ground stat
Trang 138.1: 5.77 10 Hz
m105.20
sm103.00λ
14 7
103.84)
sm10(3.00s)mkg10(1.28
smkg101.28m
105.20
sJ106.63λ
19 8
27
27 7
eV)J10(1.60eV)10
34
19 6
Hz105.91
sm103.00
P hf
P dN dE
dt dE dt
)(
eVJ10(1.60eV)(5.1m
102.35s
J10(6.63
20
19 7
34
) )
J)10
101.45
15 0
c h
hc hf hf
2.3010 19 J1.44 eV
Trang 238.7: a) f c λ5.01014 Hz
b) Each photon has energy E hf 3.3110 19 J
Source emits 75J sso(75J s) (3.3110 19 photons/s)2.31020photons s
c) No, they are different The frequency depends on the energy of each photon and the number of photons per second depends on the power output of the source
38.8: For red light λ700nm
eV1.77
J101.6
1eVJ
102.84
m)10(700
)sm10(3.00s)J10(6.626λ
19 19
9
8 34
38.9: a) For a particle with mass, K p2 2m.p2 2p1 meansK2 4K1
b) For a photon, E pc p2 2p1 meansE2 2E1
38.10: Kmax hf
Use the information given for λ400nmtofind:
J10
3.204
eV)J10(1.602eV)
(1.10m
10400
)sm10(2.998s)
J10(6.626
19
19 9
8 34
103.418
J103.204m
10300
)sm10(2.998s)J10(6.626
19
19 9
8 34
Trang 338.11: a) The work function 0 eV0
V)(0.181C)
10(1.60m
102.54
s)m10(3.00s)J10(6.63
19
19 7
8 34
107.53
)sm10(3.00s)J10(6.63
19
8 34
10(2.50
s)m10(3.00s)eV10(4.136λ
1
7
8 15
V)(2.7C)102(1.602
J102.47J
s)J10(6.63λ
λ
7 28
p
This is infrared radiation
38.14: a) The threshold frequency is found by setting V = 0 in Eq (40.4), f0 h
m1072.3λ
19 7
hf
Trang 438.15: a) 2.31 10 J 1.44eV.
m108.60
)sm10(3.00s)J10(6.63λ
19 7
8 34
s)m10(3.00s)J10(6.63λ
19 7
8 34
2.96eV
E
38.16: a) E1 20eV b) The system starts in the n = 4 state If we look at all paths
to n = 1 we find the 4-3, 4-2, 4-1, 3-2, 3-1, and 2-1 transitions are possible (the last three
are possible in combination with the others), with energies 3 eV, 8 eV, 18 eV, 5 eV, 15
eV, and 10 eV, respectively c) There is no energy level 8 eV above the ground state energy, so the photon will not be absorbed d) The work function must be more than 3
eV, but not larger than
1
n
R (Balmer series implies final state is n = 2)
nm433m104.33m
)1021(1.10
10021
100λ
100
2125
14
1λ
1:5
n
H
m104.33
sm103.00λ
14 7
)34()
34(λ,
7144
Trang 5m105.890
)sm10(3.000s)J10(6.626
8 34
.eV2.107J
103.371
m105.896
)sm10(3.000s)J10(6.626λ
eV
2.109J
103.375
3 19
7
8 34
J10(4.78
C)10(1.60(184)4
1
)2()92(4
1
14 6
b) The above result may be substituted into Coulomb’s law, or, the relation between the magnitude of the force and the magnitude of the potential energy in a Coulombic field is
N
13.8m)
10(5.54
)evJ10(1.6eV)10(4.78
14
19 6
C)1060.1(1644
)82()2(
0
2 19
0 0
2 1
ε
e e r ε
q q U
103.63J
K
kg106.64
J)102(5.812
mv
K
λandnm97.0λ
so,)4(
11λ
Trang 638.23: a) Following the derivation for the hydrogen atom we see that for Be all we 3
need do is replace e2 by4e2.Then
.eV13.6016
)(Be)
H(168
)4(1)
2 2
2 2 2
E h
n
e m ε
So for the ground state, (Be3 ) 218eV
E
b) The ionization energy is the energy difference between the nandn1 levels
So it is just 218 eV for Be , which is 16 times that of hydrogen.3
8
)4
(
λ
1
2 2
2 1
1 8 2
2
2 1 3 2 0
2 2
n c h
e m
4
11)m10(1.74λ
1,1to
2 2 0 3
n
e m
h n ε
38.24: a), b) For either atom, the magnitude of the angular momentum is
2
h
s
mkg
L so for this state L33.1610 34kgm2 s
38.26: a) We can find the photon’s energy from Eq 38.8
1)m10(1.097)
sm10(3.00s)J10(6.63
12
1
19
2 2 1 7 8
34 2
E
The corresponding wavelength is λ hc E 434nm
b) In the Bohr model, the angular momentum of an electron with principal quantum
number n is given by Eq 38.10
2
h n
L
Thus, when an electron makes a transition from n = 5 to n = 2 orbital, there is the
following loss in angular momentum (which we would assume is transferred to the photon):
s
J103.172
s)J103(6.632
)52
However, this prediction of the Bohr model is wrong (as shown in Chapter 41)
Trang 738.27: a) 2.18 10 m/s
)sJ1063.6(2
C)1060.1(1
:2
34 0
2 19 1
sm1009.122
5 1
3
6 1
v v h
3 3 2 0 2
0
2 2 2
21
22
me
h n ε nh e
me h n v
3
s1022.1)2(:
2
s1053.1C)1060.1(kg)1011.9(
)sJ1063.6(41
15 3
1 3
15 3
1 2
16 4
19 31
3 34 2
0 1
T T n
T
c) number of orbits 8.2 10
s1022.1
s100
b) Using the eight-figure value for 2.1798741 10 18
λgivesE hc hcR
,m100967758
R
Trang 819
18 3
m10890.5
s)m10000.3(J10626.6(λ
19 7
8 34
1 2
/ 3
.J10371.3m
10896.5
s)m10000.3(J10626.6(λ
22 19
19 2
8 34
2 2
s)m1000.3(sJ1063.6(λ
20 5
8 34
J1050
38.32: 20.66 eV18.70eV1.96eV3.1410 19J,andλ 632nm,
E
hc f
c
in good agreement
Trang 9min
hc hf
m1011.3)
V4000)(
C1060.1(
)sm10s)(3.00J
1063.6(
19
8 34
This is the same answer as would be obtained if electrons of this energy were used Electron beams are much more easily produced and accelerated than proton beams
b) The shortest wavelength would correspond
to the maximum electron energy, eV, and so λ 0.0414nm
eV hc
38.35: An electron’s energy after being accelerated by a voltage V is just E eV The most energetic photon able to be produced by the electron is just:
V
λ
e
hc E
hc
.nm0829.0m1029.8V)105.1)(
C1060.1(
)sm1000.3)(
sJ1063.6(
4 19
8 34
λ1
cos
mc h
,731.0nm002426
0
nm0042.0
1
nm002426
0
nm0021.01cos.nm0500.0nm0521
.)λmaximizeto
is180))(
1(1(λ
1065.6
Trang 1038.38: a) λ 0.0691nm.b)λλ(h mc)(1cos)(2.42610 12 m)
eV hc
.nm0698.0λsom,1011.7)
mc
h
λ, 180 ; λ 2λ
λ
6
1070.9λ
2λ
mc
h Δ
38.40: The change in wavelength of the scattered photon is given by Eq 38.23
(1 cos ).
λ)cos1(λλ
h
Thus,
.m1065.2)11()100.0)(
m/s1000.3)(
kg1067.1
(
)sJ1063.6(
8 27
38.41: The derivation of Eq (38.23) is explicitly shown in Equations (38.24) through
(38.27) with the final substitution of
)
cos1(λ
λyieldingλ
p h
p
m10400
Km1090.2m
1090
9
3 3
K728.2
Km1090.2Km1090.2
λand,mm966.0K
00.3
Km10898
2
Note that a more precise value of the Wien displacement law constant has been used b)
A factor of 100 increase in the temperature lowers λ by a factor of 100 to 9.66 m and mraises the frequency by the same factor, to 3.101013 Hz c) Similarly,λm 966nm
.Hz1010
3
and f 14
Trang 1138.45: a) H Aeσ T4;Ar2l
4
4 2 8
2 3
4
)KmW10671.5)(
26.0)(
m30.0(m)10(0.20
W100
K1006
Much of the emitted radiation is in the ultraviolet
38.46: (a) Wien’s law: T k
m λ
nm97m107.9K
30,000
mK1090.2
m
This peak is in the ultraviolet region, which is not visible The star is blue because the
largest part of the visible light radiated is in the blue violetpart of the visible spectrum (b) PσAT4 (Stefan-Boltzmann law)
m102.8
)K000,30)(
4(Km
W105.67W)
1086.3)(
2 8 26
m108.2
8
9 sun
(c) The visual luminosity is proportional to the power radiated at visible wavelengths Much of the power is radiated nonvisible wavelengths, which does not contribute to the visible luminosity
21
but)1(
λ
2)
(
2 5
2
x
x x e
e
hc λ
2)λ(λ
2)
(
kT hc
hc λ
I
(38.31), which is Rayleigh’s distribution.
Trang 1238.48: a) As in Example 38.10, using four-place values for the physical constants,
b) With T 2000 K and the same values for λ andλ,
37.14
λ
kT hc
and so
.1054.7λ)
c) With 4.790and (λ) λ 1.36 10
λ,K
hc T
d) For these temperatures, the intensity varies strongly with temperature, although for even higher temperatures the intensity in this wavelength interval would decrease From the Wien displacement law, the temperature that has the peak of the corresponding distribution in this wavelength interval is 5800 K (see Example 38.10), close to that used
in part (c)
38.49: a) To find the maximum in the Planck distribution:
2 5
2 2
5
2 5
2
)1(
λ
)(
2)1(
λ
)2(50)1(
λ
2λ
e
hc e
hc d
d d
5Solve
λ55
λ)1(
5
λ λ
kT
hc x
e x e e
)sm1000.3)(
sJ1063.6()965.4(
23
8 34
38.50: Combining Equations (38.28) and (38.30),
nm
872m1072
8
)KmW1067.5W/m10(6.94
K)m1090.2((
Km1090.2
λ
7
1/4 4 2 8
2 6
3 1/4
3 m
Trang 1338.51: a) Energy to dissociate an AgBrmolecule is just
J1000.1mole1
)mole(
E E
.eV04.1eV)J
10
(1.60
J10
)sm1000.3)(
sJ1063.6(
19
8 34
m/s1000.3λ
14 6
J1063.6)Hz1000.1)(
sJ1063.6
19
26 8
38.52: a) Assume a non-relativistic velocity and conserve momentum
λ2λ2
12
1
m
h m
h m mv
λλ
2 2
2
mc
h hc m
(10.2
)sm1000.3)(
sJ1063.6(λ
.neglectedbe
canrecoilsosmallquiteisThis.1042.5eV
2.10
eV1053.5
eV
105.53J
1084.8)m1022.1)(
kg1067.1(2
)sJ1063.6(
9 8
8 27
2 7 27
2 34
38.53: Given a source of spontaneous emission photons we can imagine we have a
uniform source of photons over a long period of time (any one direction as likely as any other for emission) If a certain number of photons pass out though an area A, a distance
D from the source, then at a distance 2D, those photons are spread out over an area
Trang 1438.55: a) Plot: Below is the graph of frequency versus stopping potential.
Threshold frequency is when the stopping potential is zero
Hz104.60Hz
1011.4
89
)sm1000.3(
c) The work function is just hf th (6.6310 34 Js)(4.601014Hz)3.0510 19 JeV
V
sJ1058.6
)C1060.1)(
HzV1011.4(
34
19 15
)10.0)(
W200()
(
)(
14
h hf
P dN dE
dt dE dt
So.cmsecphotons10
00.14
6930)
cmsecphotons10
(1.00
4
secphotons10
03
2 11
Trang 1538.57: a) Recall
λ
0
hc eV
0 1
2 01
1λ
1λ
λ)(
e
hc V hc hc V
V
e
b)
.V477.0m1095.2
1m
1065.2
1C)
10(1.60
)sm10s)(3.00J
1063
6
(
7 7
11
8 34
So the change in the stopping potential is an increase of 0.739 V
38.58: From Eq (38.13), the speed in the ground state is (2.19 106 m s)
v gives Z = 13.7, or 14 as an integer b) The ionization energy is EZ2 (13.6
eV), and the rest mass energy of an electron is 0.511 MeV, and setting
smkg1099.6λ
m09485.0
2λλso
1λ
(9.11
s)J10(6.63m)
100830
0
(
)cos1(λ
λ)cos1(λ
λ
8 31
h
b) Since the collision is one-dimensional, the magnitude of the electron’s momentum must be equal to the magnitude of the change in the photon’s momentum Thus,
.smkg102smkg1065
1
)m10(0830.0
10781.0
1)sJ1063.6(λ
1λ1
23 23
1 9 34
16 16
2 e e
Trang 1638.61: a) 1.69 10 kg.
207
2 1
p e r
m m
m m m
m
m m m
b) The new energy levels are given by Eq (38.18) with m e replaced by m r
.keV53.2eV
1
1 2
3
2 31
kg 28
2 2
2
4 2
n
n m
m h
n
e m E
e
r r
n
c)
)sm10(3.00s)J1063.6(
))eVJ10(1.60eV))1053.2(4Ve1053.2()(
1
λ
1
8 34
19 3
3 2
eV,0.8eV,
0.5eV,
1055.8
)sm1000.3(s)J1063.6(λ
18 8
8 34
would expect a maximum kinetic energy of 14.5eV3.4eV11.1eV, which is exactly 10.2 eV above that measured in part (a), explaining the anomoly
Trang 1738.64: a) In terms of the satellite’s mass M , orbital radius Rand orbital period T,
MR h
L h n
2 2
V and its centripetal acceleration is 2 22 3
R M
L R
L R
R M
ML R
GM
earth
2 3
2
2 2
2 2
h n
R
c) R2knn, and for the next orbit, n1,andRn(h2 42GMearthM)
Insertion of numerical values from Appendix F and using n from part (a) gives
m,10
h n mvr L
2But
2
2 2 2
2 2
4
h n r
D mr
h n D
mv r
r
mv Dr
b) The energy E KU mv Dr ,sinceF Dr
2
12
to
2 2 2
2
2
12
1So.2
1
Dr Dr r
m
D m E kx U
nh m
D mD
nh D
h m
D n n E E
22
)(
Trang 1838.66: a) (1 ( )) 1,
d e e
d e
d e d r,
m m
values gives mr,d 0.999728me b) Let R
R m
m R
e
d r, e
p r,
,3)4(λand,Then
nm
033.0λ
13
4λ
d r,
e p r,
m R
R R
R R
38.67: a) The H line is emitted by an electron in the n3 energy level,
eV
51.1)
i
n n hc
E E
658 nm, 103 nm, and 122 nm for the respective photons above
Trang 1938.68:
kln
)(
1 2
g ex kT
) (
E E T
e n
J
101.63eV2.10
eV
6.13
eV
4.34
eV6.13
18 g
ex
g
2 ex
E
E E
ln(10)KJ10(1.38
J)1063.1(
12 23
ln(10)KJ10(1.38
J)1063.1(
8 23
ln(10)KJ10(1.38
J)1063.1(
4 23
absorption lines
Trang 2038.69: The transition energy equals the sum of the recoiling atom’s kinetic energy and
the photon’s energy
.λ
k tr
E E
hc E
E
hc E
E E E
2 2
)λ(λ
11
11
11
1λ
E hc E
E hc
E
E E
hc
E E E
hc E
E E hc
k k
tr k tr
k tr
tr k tr
tr k tr
Conservation of momentum, assuming atom initially at rest, yields:
mc
h mhcλ
h
m
h m
P E P
h
k k
2
λ2
λ
λ22λ
2 2 2
2
2 2
34
106.6)sm10kg)(3.0010
2(1.67
s)J1063.6(
K m v
Trang 2138.71: a) Largest wavelength shift:
s)m10kg)(3.0010
(9.11
s)J1063.6(2))
1(1
(
8 31
Smallest energy implies largest so,
2
eV1011.52λ
2λ1
dE mcdT
mc
pIV dt
dE mc
.0(
)V10A)(18.010
0.60)(
01.0
d) A high melting point and heat capacity—tungsten and copper, for example
2
λ
1λ
1)
(f f hc h
E
319.5J
10111.5m10100.1
1m
101.132
1)
sm10s)(3.00J
which is a loss for the photon, but which is a gain for the electron So, the kinetic energy
of the electron is 5.11110 17 J319.5eV
.sm1006.1kg1011.9
J)1011.5(2
b) If all the energy of the electron is lost in the emission of a photon, then
J105.111
)sm10s)(3.00J
1063.6(
nm
3.89m
10892
Trang 2238.74: a) λ1 (h mc)(1cosθ1),λ2 (h mc)(1cosθ2), and so the overall wavelength shift is λ(h mc)(2cosθ1cosθ2).
(b) For a single scattering through angle θ,λs (h mc)(1cosθ)
For two successive scatterings through an angle of 2, for each scattering, λt 2(h mc)(1cos 2)
t s 2
2 s
2
λλand))2cos(
1()2(cos1so1)
2
cos(
))2(cos1(2)(λand))2(cos1(2
h θ
θ
Equality holds only when 180
c) (h mc)2(1cos30.0)0.268(h mc).d)(h mc (1cos60)0.500(h mc),which is indeed greater than the shift found in part (c)
38.75: a) The wavelength of the gamma rays is
m101.24eV)
J10(1.60eV)10(1.00
)sm10(3.00s)J10(6.63
19 6
8 34
m101.24m
cos1(
mc
h mc
h mc
10
6.42
s)J10(6.63
m)10(5.00)sm10(3.00Kg)10
2(9.11λ
2
So
9 11
34
33 8
collisions10
sec103.15ears
13
26 13
6 y
.collisionsec
0.0945m
10
45
Trang 23
38.76: a) The final energy of the photon is ,and ,
(
1λ
1
λ
)1()λ()
λ(λ
2 2 2
mc
mc hc
hc K
hc
hc K
E
hc
)1(
(K mc2 since the relativistic expression must be used for three-figure accuracy) b) arccos(1λ (h mc))
3.801
(0.250))
sm10(3.00kg)10(9.11m)10(5.101
mm105.10λ
34
8 31
102.43
m)103.34m10(5.101
arccos
nm
103.34
12
12 12
λ
2)
λ( 5 λ 2
)1(
2)
1(
)(
2)
hf e
f c
hc f
f
c df f I d
3 2
4 4 5 2
3
4 5 4
3 2 4
0
3 3
2 4
3
15
2240
)()2()2(240
1)(2
1
)(2)1(
2
h c
T k c
h
kT h
c kT
dx e
x h
c
kT e
c
df hf
x kT
T k
as shown in Eq (38.36) Plugging in the values for the constants we get σ 5.6710 8 W m2 K4
Trang 2438.78: I σT4,PIA,andE Pt;combining,
hrs
2.45s
10
8.81
K)(473)KmW10(5.67)m10(4.00
J)(100
3
4 4
2 8 2
6 4
4
me
h n ε
T and frequency is just
.4
1
3 3 2
0
4
h n
me f
2
)1(
11
11then,1and
n n
n
.4
large
for
2
211
1)
11(
11
1
3 3 2 0
4 3
2 2 2
h n
me f
n n
n n
n n
(
λ
(h dN dt A The intensity is
,)λ((
)((dN dt E A dN dt hc A
and comparison of the two expressions gives the pressure as ( c I )
Trang 2538.81: Momentum:
)( p P P
p
P p P
)(
2)(
(2)(
)(pc pc 2 E2 E2 pc pc 2 Pc2 p p Ec p p pc2 Ec p
0 )
hc Pc E
Pc E
hc Pc
E
Pc E Pc
E
Pc E hc
Pc E pc
Pc E p Pc Ec pc
Pc Ec p
p
Pc Ec p Ec pc Pc
λ(λ
2λ
)(
λ2λλ
)(
22
)(
)2
(
2 2
2
2 2
2
If
2 2 2
2 2
mc E
Pc mc E
c2
11
E
m E
E
mc Pc
2 1
)m10(10.6kg)
1011.9(1J1060.1
6 4
2 31
c hc
(1.2410 16 m)(156.0)7.0810 15 m
c) These photons are gamma rays We have taken infrared radiation and converted it into gamma rays! Perhaps useful in nuclear medicine, nuclear spectroscopy, or high energy physics: wherever controlled gamma ray sources might be useful