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A2 GROUP4 Answer Key Functional Groups Organic Chemistry

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benzyl phenyl methyl methyl methyl phenyl methyl phenyl ester amine methyl phenyl methyl V phenyl methyl V phenyl benzyl carboxyl O methyl V phenyl methyl V phenyl sulfid

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Group Number: 4

Names: Lobetaña, Manalo, Mansilongan, Mariano, Mendez, Mendoza, Nacu, Nang, Olarte Yr/Blk: 1st Year – Block 3

Faculty: Prof Nemia T Dacumos

1 Identify the functional groups in each molecule

a

b

c

benzyl

phenyl

methyl

methyl

methyl

phenyl

methyl

phenyl

ester

amine

methyl

phenyl

methyl

V

phenyl

methyl

V

phenyl

benzyl carboxyl

O

methyl

V

phenyl

methyl

V

phenyl

sulfide

carboxyl benzyl amide

amide

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2 What types of intermolecular forces are exhibited by each compound?

a b

c d

3 Rank the following compounds in order of increasing strength of intermolecular

forces:

a b

c

d

4 Intramolecular forces of attraction are often important in holding large molecules

together For example, some proteins fold into compact shapes, held together by

attractive forces between nearby functional groups A schematic of a folded protein is

drawn here, with the protein backbone indicated by a blue-green ribbon, and various

appendages drawn dangling from the chain What types of intramolecular forces occur

at each labeled site (A–F)?

hydrogen bond dipole-dipole interactions

dipole-dipole interactions van der Waals forces

3 1 2 2 3 1

1 3 2

3 2 1

* 1 being the lowest *

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a van der Waals

b hydrogen bonding

c ion-ion

d hydrogen bonding

e hydrogen bonding

f van der Waals

a

b

a

b

1 3 2 4

* 1 being the lowest *

3 2 1

* 1 being the lowest *

1 3 2 4

3 2 1

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7 Which of the following molecules can hydrogen bond to another molecule of

itself? Which can hydrogen bond with water?

Can Hydrogen bond to itself

Can hydrogen bond to water

8 Predict the water solubility of each of the following organic molecules

a b

c

insoluble in water

insoluble in water

soluble in water

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