Application of origin software to research infrared absorption spectrum data

In this paper, Origin is applyed to analyze samples and give some results about the fluorescence spectrum of SiO2-Al2O3 glass material, which is produced by Sol-Gel method.

APPLICATION OF ORIGIN SOFTWARE TO RESEARCH INFRARED

ABSORPTION SPECTRUM DATA ABSORPTION SPECTRUM DATA

Ho Xuan Huy

An Giang University

Abstract:

Abstract: In studying materials science, the instruments used for measuring fabrication

are: Micro-Raman oscillator, infrared absorption spectrum, absorption spectrum, fluorescence emission spectrum The received data from measurement systems is data files Researchers must process these empirical datas; and, show them through graphs to determine the structure and characteristic properties of the material Origin software is used to graph, process data, match functions, find errors, calculate quantities

In this paper, Origin is applyed to analyze samples and give some results about the fluorescence spectrum of SiO2-Al2O3 glass material, which is produced by Sol-Gel method The result show that the infrared absorption spectra of samples with different composition were similar The characteris spectral peaks of silica glass and multi-component one are represented through vibrating the groups such as Si-0-, Si-O-Si,

Al-O, Al-O-, Si-O-Al and the presence of the OH groups exists in the samples

Keywords:

Keywords: Origin, infrared absorption, ion Er3+, ion Al3+

Email: hoxuanhuy69@gmail.com

Received 8 November 2018

Accepted for publication 15 December 2018

1 INTRODUCTION

Materials science is an interdisciplinary field involving the properties of matter It is interested in electrical materials, electronic materials, nanomaterials, optical fiber materials The devices used for measuring fabrication are: Micro-Raman oscillator, infrared absorption spectrum, absorption spectrum, fluorescence emission spectrum The results allow for studying the lattice structure, basal energy levels and the energy levels in the ground state and the corresponding excited states of rare-earth ions

During the implementation of scientific projects, researchers must process these empirical datas; and, show them through diagrams to determine the structure and characteristic properties of the material There are many softwares available in researching and teaching such as Origin, Matlab, Excel These software can process the statistical datas, show the empirical results by diagram, extract the report of analysis results

Matlab is a program for complex computation and result display, which is controlled

by programmed scripts Variables created inside a function are only in the workspace of that function and are released when the one terminates so it is not possible to use the information of the previous time for the next time

Excel is one of the most popular software for analyzing statistical data, analyzing results, calculating quantities according to formulas, demonstrating diagram results The disadvantage of Excel is that in each calculation, it is necessary to write mathematical formulas and data expressions that are limited to fonts when used for large units and the number of drawings is difficult to modify

Origin software has spreadsheets like Excel so you can import data from Excel or Word tables by copy, paste; or you can import the digital data files of the measurement system with the Import command This software has the advantage that after importing data and selecting the quantities to be calculated, the software will automatically output the specified statistics, whereas if using Matlab or Excel we must write or program the calculational functions

Application of Origin software to process the datas of aluminosilicate glass samples

2 RESEARCH METHODS

2.1 The Nexus 670 FT-IR infrared spectrophotometer [1]

Figure 1.

Figure 1 Diagram principle infrared spectrometry system Fourier transform

Fourier Transformation Infrared Spectrophotometer (FTIR), a fixed mirror, a moving mirror and a beam diffuser Infrared radiation passes out of the interferometer and passes

through the detector The detector records the variation in the intensity of the radiation in the direction d that the moving mirror performs and then converts it into an electrical signal It receives the signal as a function of the voltage V in the distance, This is a

The intensity of the radiation depends on the number of waves Because of computer use, the spectra are highly automated

2.2 Processed data from the Nexus 670 FT-IR Infrared Spectrophotometer with Origin

Origin is a powerful and full featured data analysis software Powerful visualization tools with accompanying descriptive statistics to assist with hypothesis testing, model development and modeling, and data analysis [5]

The main interface of Origin is the Menus bar, toolbars, active windows such as tables, graphs

Figure 2 Figure 2 The main interface of Origin

The Origin menu provides commands to perform operations during data processing In each submenu, the tags also change to correspond to each specific window: Analysis for the Worksheet window or Analysis for the Graph window

The worksheet viewer uses data organizers and provides tools for using, analyzing, analyzing, and graphing data from worksheet data The columns in the worksheet are relative to each other by the axis specified as the X axis, the Y axis, and their location

The Graph window is where the graphs are displayed and edited Each graph window contains a single edit page You can annotate different objects such as axes, annotations, and drawing data

Graphs in the Origin software include 2D graphs and some 3D graphs To create a graph we perform the following operations: select the file containing the data; select the data on the worksheet, in the menu bar appears Plot tab; Select Plot and choose plot style

or Click on a graphic type icon on the drawing toolbar

Origin handles data from the measurement system through the following steps:

Figure 3.

Figure 3 Origin procedures for processing experimental data

3 RESULTS AND DISCUSSION

3.1 Processing manipulation on the Nexus 670 FT-IR infrared spectrophotometer

The sample was smoothed and blended well with KBr in powdered state 10-100 times,

transparent and the powders studied were dispersed evenly

Infrared Spectrum Analyzer is used under the brand name Nexus 670 FT-IR, manufactured by Nicolet (USA), located at the Institute of Tropical Technology of the Vietnam Academy of Science and Technology The working spectrum of the device is

3.2 Analysis of infrared absorption spectra (FT-IR)

5 0 0 1 0 0 0 1 5 0 0 2 0 0 0 2 5 0 0 3 0 0 0 3 5 0 0 4 0 0 0 0

1 0

2 0

3 0

4 0

3 2 1

4 6 9

8 0 5

1 1 0 6

1 6 3 0

3 4 4 2

W a v e n u m b e r ( c m - 1 )

1 : S iO2 E r3 + ( 1 % w t)

2 : S iO2 E r3 + ( 3 % w t)

3 : S iO2 E r3 + ( 5 % w t)

T = 3 0 0 K

Figure 4.

with different concentrations

Structural information was determined by the vibrating of the formed links contained

Peaks of 469 cm-1, 805 cm-1, 1106 cm-1 are thought to be vibrating of the Si-O-Si

absorbed form These observations are similar to those published in the literature [3, 4]

In addition, it can be seen that in these samples, the OH- group remains, as their

sample, we see that the spectrum is approximately 590 cm-1 for the vibrating of the Al-O

molecules absorbed into the sample

5 0 0 1 0 0 0 1 5 0 0 2 0 0 0 2 5 0 0 3 0 0 0 3 5 0 0 4 0 0 0 0

1 0

2 0

3 0

4 0

1 0 9 5

1 0 7 5

5 9 0

4 6 9

8 0 6

1 1 0 6

1 6 3 8

3 4 4 2

3 2 1

W a v e n u m b e r (c m -1 )

1 :S iO

2

2 :S iO

2 E r 3+ (1 % w t)

3 :9 9 ,3 3 S iO

2 0 ,5 A l

2 O

3 0 ,1 7 E r

2 O

3

Figure 5.

Figure 5 Infrared absorption spectrum of SiO 2 samples (line 1), SiO 2 1% Er 3+ (line 2), 99.33 SiO 2 0.5Al 2 O 3 0,17Er 2 O 3 (line 3), the same is heated at 1000 o C for 1 hour

5 0 0 1 0 0 0 1 5 0 0 2 0 0 0 2 5 0 0 3 0 0 0 3 5 0 0 4 0 0 0 0

5

1 0

1 5

2 0

2 5

3 0

3 5

4 0

4 5

6 8 6

9 0 7

1 2 0 0

2 1

5 9 0

8 0 5

4 6 9

1 0 9 2

1 6 3 8

3 4 4 2

W a v e n u m b e r ( c m - 1 )

1 :9 8 S iO

2 1 ,5 A l

2 O

3 0 ,5 E r

2 O

3

2 :9 7 ,4 S iO

2 1 ,9 5 A l

2 O

3 0 ,6 5 E r

2 O

3

Figure 6.

Figure 6 Infrared absorption spectra of 98SiO 2 1.5Al 2 O 3 0.5Er 2 O 3 samples (line 1),

97.4SiO 1,95Al O 0.65E O (line 2) and the incubation temperature of 850 o C for 0.5 hour

In Figure 6, the spectrum bands are similar to Figure 4 and Figure 5 These two

peak of 907 cm-1 is attributable to the oscillation of the Si-O-Al or Si-O- groups Strips

increase in Al2O3 content

The infrared absorption spectra of samples with different composition concentrations were similar The vertices characteristic for silica glass and multi-component glass are

OH groups in the samples Infrared absorption spectra of the samples gave consistent results for the works of some authors [2,3,4]

4 CONCLUSION

Efficient application of Origin software to demonstrate the infrared spectrum diagram The characteris spectral peaks of silica glass and multi-component one

(FTIR) results show about: the information of the background of the glass network; the

linking vibration of Si-O-Al; and vibration of the groups such as Si-OH group Si-O-Er,

Al-O-Si-O, Al-O, along with the existence of the OH groups in the sample

These results may be necessary in the manufacture of silica glass and multi-component one with the high concentrations of the rare-earth ions doped, to apply the spectral properties in optical communication with the most effective way

REFERENCES

1 Nguyen Huu Dinh, Tran Thi Da (1999), Some common methods to study the structure of molecules, - Publishing Education

2 C.Hernandez, A.C Pierre (2000), “E volution of the texture abd structure of SiO2.Al2O3 xerogeels and Aerogels as a Function of Si to Al Molar Reatio”, - Journal of Sol-gel and technology, 20(2000), pp.227-243

3 Ian M.Thomas, Stephen A Payne and Gary D.Wilke (1992), “Optical properties and laser demonstration of Nd-doped sol-gel silica glasses”, - Journal of Non-crystalline solids, 151(1992), pp.183-194

4 Masayyuki Nogami, Yoshihiro Abe (1995), “Properties of sol-gel derived SiO2.Al2O3 glass using Eu3+ fluorescence spectra”, - Journal of Non-crystalline solids, 197(1995), pp.73-78

5 Https://www.originlab.com

ỨNG DỤNG PHẦN MỀM ORIGIN TRONG NGHIÊN CỨU

SỐ LIỆU PHỔ HẤP THỤ HỒNG NGOẠI

Tóm t ắắắắt: t: t: Trong quá trình nghiên c ứu khoa học vật liệu, các thiết bị được sử dụng để nghiên cứu đo các mẫu chế tạo là các hệ đo như: phổ dao động Micro-Raman, phổ hấp thụ hồng ngoại, phổ hấp thụ, phổ phát xạ huỳnh quang Dữ liệu nhận từ các hệ đo là các tập tin số liệu Nhà nghiên cứu khoa học thường phải xử lý số liệu thực nghiệm và biễu diễn qua đồ thị để xác định các cấu trúc, tính chất của vật liệu Origin là một phần mềm được dùng để vẽ đồ thị, xử lý số liệu, khớp hàm, tìm sai số, tính toán các đại lượng Trong báo cáo đã ứng dụng Origin để phân tích các mẫu và thu được một số kết quả về phổ hồng ngoại của vật liệu thủy tinh SiO2-Al2O3 được chế tạo bẳng phương pháp Sol - Gel Phổ hấp thụ hồng ngoại ghi được của các mẫu có thành phần khác nhau là tương tự Các đỉnh phổ đặc trưng cho thuỷ tinh silica và thuỷ tinh nhiều thành phần thể hiện qua các nhóm dao động Si-0-, Si-O-Si, Al-O, Al-O-, Si-O-Al và sự có mặt của nhóm OH còn tồn tại trong các mẫu

T ừ ừừ ừ khóa: khóa: khóa: Origin, h ấp thụ hồng ngoại, ion Er3+, ion Al3+