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Trang 1Frosio 07 Ambient conditions slide # 1
AMBIENT CONDITIONS
Humidity Air Temperature Substrate Temperature
Frosio 07 Ambient conditions slide # 2
Parameters influencing the corrosion speed
Atmospheric corrosion
Humidity Temperature
Concentration of salts Amount of air pollution, including acid rain, soot and dust particles
Trang 2Frosio 07 Ambient conditions slide # 3
3 °C above the dew point
of the surrounding atmosphere
Atmospheric conditions.
Requirement during blasting and painting
Trang 3Frosio 07 Ambient conditions slide # 5
B-24/2-4
4847-693
Estimating probability of condensation
• Cold liquid inside hull and warm air outside causes condensation
• See how frames inside keeps the cold longer
Why Temperature & Humidity are important
Frozen overnight condensation, follows the frames of the ship
Condensation follows the contours
of the double-bottom tank
Trang 4Frosio 07 Ambient conditions slide # 7
Purpose of climatic evaluation
Evaluate the likelihood of the moisture in the air to form condensation on a substrate
Moisture / Absolute Humidity
• When water evaporates, it forms water vapour or moisture in the air
• We may measure this moisture as gram water per
• The maximum amount of moisture that can be contained in the air depends on the temperature of the air
• Warm air can contain larger amounts of moisture than cold air
• The maximum moisture that can be contained in air
at the various temperatures is called the Absolute
Humidity
Trang 5Frosio 07 Ambient conditions slide # 9
maximum moisture content in the air is
Trang 6Frosio 07 Ambient conditions slide # 11
Moisture / Relative Humidity
• The Relative Humidity is a measure of how much of the
Absolute Humidity (maximum moisture) that the air contains, expressed as percent
• If the air contains the maximum amount of moisture, it will have a Relative Humidity of 100%
• If the air contain half of the maximum amount of moisture, it will have a Relative Humidity (RH) of 50%
• If the air contain a quarter of the maximum amount of moisture, it will have a Relative Humidity of 25%
Trang 7Frosio 07 Ambient conditions slide # 13
% R.H.:
Water vapour in the air as percentage of the total amount water vapour the air can contain at the same temperature
Example
Air at 20oC can contain 17.31 g water/m3, but the actual content is measured to 15 g/m3 What is the R.H ?
15g x 100%
17.31g
Humidity / Dew Point
as percentage of Absolute Humidity 17.31)
g/m3, but the RH will increase to 92.69% (12.64 as percentage of Absolute Humidity 13.65)
Humidity) is 10.62 g/m3 This means the moisture content
of 12.64 g/m3 is 2.02 g/m3 more than it can hold at this temperature
• The consequence is that the excessive moisture will leave the air through condensation, ending up as dew on available surfaces or as rain or fog
• The temperature at which a given moisture content will
start to condensate is called Dew Point.
Trang 8Frosio 07 Ambient conditions slide # 15
Dew Point / Substrate Temperature
• On an early morning inspection we measure the air
• Due to cold over-night temperature, the steel temperature
• Would this cause any problem?
to the steel surface will be cooled by the steel and perhaps
• This means that although we may not see it clearly, there will be condensation on the steel
Dew Point!
Trang 9Frosio 07 Ambient conditions slide # 17
Temperature of substrate should
be at a temperature of
min 3oC
above dew point of the air in the
vicinity
and paint application:
Measuring ambient conditions
• Electronic multi-function gauge
• Electronic humidity gauge
• Sling Psychrometer (Sling Hygrometer, “Dry and Wet bulb”)
• (Hair hygrometer, not suitable!)
• Dew point calculator
• Steel thermometer
Trang 10Frosio 07 Ambient conditions slide # 19
• Needs frequent calibration
• Dependent on batteries
• Multi-function models will measure air temperature, surface temperature, relative humidity, and calculate dew point and T(*)
( * ) difference between dew point and surface temperature)
Electronic humidity gauge
A dry and a wet thermometer put together in
one unit.
• The difference in the measured temperatures indicate the amount of humidity:
• Large difference = low RH%
• Small or none = high RH%
Sling Psycrometer
Trang 11Frosio 07 Ambient conditions slide # 21
ISO 8502-4 Measuring the relative humidity
• Photo: Sling Psychrometer for measuring:
- Dry temperature
- Wet temperature
• Measure the temperature in the vicinity
• Calculate the relative humidity
• Use together with dew point calculator
Cd-4932-88
ISO 8502-4 Dew point calculator
• For calculation of dew point
• To be used together with surface temperature thermometer and sling psychrometer
• Use this frequently during pre-treatment, application and drying of the paint
• Recommendation: Every 6 hours and when weather conditions are changing
Cd-4932-89
Trang 12Frosio 07 Ambient conditions slide # 23
Guidance on the estimation of the probability
of condensation prior to paint application
Steel temperature min 3 oC above the dew point
Trang 13Frosio 07 Ambient conditions slide # 25
determination of relative humidity (%RH)
Example:
Measured valuesAir dry temp.: 14.0 °CWet bulb temp.: 10.5 °CRead
Relative humidity: 65 %Dew point: 7 °CAir-water content: 6.3 g/kg
Trang 14Frosio 07 Ambient conditions slide # 27
Using the IX diagram
• Draw a horizontal line at the appropriate dry bulb temperature
• Draw a 45o line at the appropriate wet bulb temperature
• At the intersection you will determine the RH
• Draw a vertical line from the intersection point all the way to the 100% line
• This is the dew point
Ambient conditions, general
Painting should not be started when:
• The relative humidity exceeds 85% (unless the paint manufacturer consider it safe)
• The substrate temperature is less than 3o
C above the dew point
Trang 15Frosio 07 Ambient conditions slide # 29
• Dehumidifier, reduces the actual humidity
in the surroundings
• Heather, heat the objects (surfaces) prior
to application in order to reduce the danger for condensation.
• Forced ventilation is a must in order to secure a proper evaporation of the solvents from the paint film.
• Ambient
temperature will influence:
– shelf life (storage) – potlife (two-pack paints: time between mixing and no longer useable)
– induction time reaction before application) – viscosity/sprayability – Steel Temperature
(pre-Ambient Temperature and Steel Temperature
• Steel temperature
will affect:
– probability for condensation – solvent evaporation – speed of cure (drying time)
– degree of cure – recoating interval – service life of the coating
Trang 16Frosio 07 Ambient conditions slide # 31
Ventilation Good practice
Solvent vapours are heavier than air
Suction from lowest points
in enclosed areas
Ventilation Bad practice
Solvent vapour Solvent vapour
Using an inlet fan Using an exhaust fan
Air out
Solvent vapours
Inlet fan, air through pipe
Trang 17Frosio 07 Ambient conditions slide # 33
Control of relative humidity and temperature
• Check the atmospheric conditions before the work starts
• If required: Install proper ventilation
• Check the atmospheric conditions while the work is ongoing and during drying / curing
Paint technology: Humidity_control1
Temperature and humidity
of air used for drying.
• Supply of heated air immediately after application may lead to skin drying and entrapped solvents
• Cold air will keep the film open longer and ensure proper evaporation
• Avoid high air temperature (especially epoxy)
• High humidity will slow down the drying time
• Exhaust from heating equipment using propane or paraffin oil contain water and Carbon dioxide and may create Amine sweating
Trang 18Frosio 07 Ambient conditions slide # 35
Blisters inside a tank due to poor ventilation
Entrapped solvents
• Blisters sometime contain water
• Rust will not be formed inside intact blisters, due
to the high pH
• As soon as the blisters break corrosion will start
• Use cathodic protection
to back up the paint system
Cd-4934-68
Trang 19Frosio 12 Special coatings slide # 1
SPECIAL COATINGS
Other coatings than paint
Frosio 12 Special coatings slide # 2
Powder coatings
Trang 20Frosio 12 Special coatings slide # 3
• The powder contains resin, curing agent, pigments, additives, etc., all in solid form
• Surface preparation:
Sa 2½
• Applied by electrostatic spray
or dipping in a fluidized bed
• The object is baked in an oven at 160 –
250o C for 5 – 20 minutes
• The powder melts, forms a film and cures
• Typically used as part of production line (conveyor belt), for pipes (fusion bonded epoxy), cladding sheet, or for reinforcing bars in concrete
Powder coating (2)
Trang 21Frosio 12 Special coatings slide # 5
Glass fibre lining
• Types of glass:
– Woven mats– Non-woven mats– Chop-strand– Flakes
• Can be combined with both epoxy, polyester and vinyl-ester resins
• Used inside tanks, usually at the bottom / lower sides
• High requirement to surface preparation
• Resin is usually applied directly on the prepared steel surface, the glass fibre mat is pressed into the wet film and more resin applied on top
• Chop-strand application may also be used
• System may be built up be several coats
• High labour cost
• High material cost
Glass fibre lining (2)
Trang 22Frosio 12 Special coatings slide # 7
Rubber lining
• Used for tanks and pipelines
• Considered as the ultimate acid protection
• Natural rubber lining is typically used in storage tanks for concentrated
• Requires curing
in autoclave at
110 – 180o C:
Vulcanization
Trang 23Frosio 12 Special coatings slide # 9
Anti-corrosion tapes & foils
• Mostly used on pipes
• No solvents
• Require special application equipment
• Limited size of items to
be coated
• Applied by wrapping over a primer
• Thickness from 1 mm upwards
• No curing
• Many varieties available:
– Polyethylene tapes – Petrolatum (greasy) tapes – Elastomerised Bitumen tapes – PE-Butyl Rubber tapes – High temperature tapes
Trang 24Frosio 12 Special coatings slide # 11
Soft coatings
• Coatings that do not dry or cure, but stay soft all the time
• Protect against corrosion by forming a barrier
• Usually very good penetrating properties
• Applied by spraying
• Very difficult to change to a drying type of coating (cleaning / adhesion)
• Wax (warm applied)
• Grease (Lanolin / Wool fat / Sheep grease), very messy!
• Bitumen (hot applied)
• Used in cofferdams, void spaces, ballast tanks, under-carriage of cars & trucks, etc
Trang 25Frosio 09 Application slide # 2
Good work practise
Trang 26Frosio 09 Application slide # 3
Application
Cleanliness and good housekeeping before, during and after application are one of the most important factors to have a good result
Frosio 09 Application slide # 4
Good access is as important for a satisfactory application as the quality of the equipment!
Trang 27Frosio 09 Application slide # 5
Personal protection is a necessity
• Make sure to use adequate
protection while using paint
• Application on an offshore
installation
Cd-4934-30
Frosio 09 Application slide # 6
Important to open the tin correctly !
• Remove all loose particles from the lid
• Loosen the lid
• Lift the lid away from the tin in such a manner that the
contaminants do not fall into the paint Application: Open_dirtytin1
Trang 28Frosio 09 Application slide # 7
Mixing of two-pack paints
• Component B is poured into the component A (base)
• Component B may have a high viscosity Make sure to add all of it
Empty the tin !
• Ensure correct mixing ratio
• Use mechanical agitator
• The applicator is well protected
Think of your health !
Cd-4930-58
Frosio 09 Application slide # 8
Tools for mixing of paints
• Always use mechanical agitator to ensure proper mixing
• Proper mixing will not be achieved by a stick
• A wooden stick may also contain dirt and loose parts that may contaminate the paint and clog the spray equipment
Cd-4930-57
Trang 29Frosio 09 Application slide # 9
• Mixing of a two-pack paint: Light coloured component A (base) and dark coloured component B
• Visual mixing control improves the mixing and thereby the performance of the paint
Cd-4930-59
Frosio 09 Application slide # 10
Hand-tools for application of paint
• Stirrer: Only to
be used for small tins
• Round paint brush
• Flat, short paint brush
• Radiator brush
• Small back roller
• Tape for masking
Cd-4934-04
Trang 30Frosio 09 Application slide # 11
Methods for paint application
Frosio 09 Application slide # 12
Alternative 3.
1 Coat: Brush
2 Coat: Roller
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Application of paint
Use of roller for application
on bare steel is not recommended.
Roller application will not ensure good wetting of the substrate.
Frosio 09 Application slide # 14
Rollers and paint brushes left in a tin after the job is finished.
• The paint will dry / cure and the equipment is unsuitable for application of paint
• Waste of money !
Cd-4930-68
Trang 32Frosio 09 Application slide # 15
Poor coating performance
• To the right: Correct mixing and mixing ratio
• To the left: Insufficient mixing and / or incorrect mixing ratio
Cd-4930-60
Frosio 09 Application slide # 16
Mixing of a two-pack paint Visual mixing control
• The dark base makes it easy to see when the mixing is complete
• This is not easy to see with a clear base
• Poor mixing results
in poor protective properties of the paint
Application: Mixingcontrol1
Trang 33Frosio 09 Application slide # 17
Heating of paint in hot water bath
• Particularly applicable under cold climatic conditions
• Unnecessary thinning of the paint can be avoided
• Unnecessary thinning: Increased drying period
Cd-4930-61
Frosio 09 Application slide # 18
Ready to start?
Trang 34Frosio 09 Application slide # 19
Working with a Brush
Frosio 09 Application slide # 20
Application by paint brush
Benefits
Good wetting of the substrate Forces the paint into the surface Better than roller on the first coat Good on areas with poor accessibility
Limitations
Gives low film thickness, many coats required Creates an uneven film Application speed is slow
Trang 35Frosio 09 Application slide # 21
different surfaces
• Large, flat surfaces:
Squared end brush with long bristles
• Narrow surfaces:
Angular cut brush
• Irregular surfaces and edges:
Round or oval brushes
Note:
High quality brushes give an improved paint film
Frosio 09 Application slide # 22
A round (or an oval) paint brush is in many cases recommended.
• Paint brush “works” the paint well into the substrate
• Can be used on 1 coat as well as subsequent coats
• Limitation: The production rate
Cd-4934-05
Trang 36Frosio 09 Application slide # 23
Application by paint brush
• Application of the 1st coat
• Here, a round paint brush is used
• The paint brush works the paint well into the substrate
• Limitation:
Production rate
Frosio 09 Application slide # 24
Angled, flat paint brush (radiator brush)
• For areas being difficult to access
• Long handle is not recommended
• With long extension: Not permitted offshore
Cd-4934-07
Trang 37Frosio 09 Application slide # 25
Good quality paint brushes must be cleaned properly to maintain its properties
• Often the paint brushes are left without any kind of cleaning
• If properly cleaned and stored they can be reused
• Use suitable thinner or cleaner
• Final cleaning with water and soap before storing it properly
(not shown on video) Application: Cleaning_brush1
Frosio 09 Application slide # 26
Working with Rollers
Trang 38Frosio 09 Application slide # 27
in the paint filmGives low film thickness, many coats required
Application by roller
Frosio 09 Application slide # 28
Roller application
• Roller application will not force the paint into the profile of the substrate, but rather deposit it over the peaks
Trang 39Frosio 09 Application slide # 29
Application tool Small back roller
• Type of roller to use must be selected on what
to paint and the type of paint to use
• Thin naps for glossy top coats
to paint and the type of paint to use
• Well protected painter
Trang 40Frosio 09 Application slide # 31
Application by roller
• Type of roller to use must be selected on what to paint and the type of paint to use
• Not recommended to use roller on the 1st coat.
Cd-4934-11
Frosio 09 Application slide # 32
Superstructure Application by roller Two men working from a dock arm
This is often seen where it is environmental restrictions Spray dust may contaminate near by objects (Overspray / wind)
Cd-4934-12