Hazardous wastes, as defined by Federal and State regulation, generally are managed outside the munici-pal solid waste stream.. Exceptions are household hazardous wastes and hazardous wa
Trang 1INTEGRATED WASTE MANAGEMENT
The most recent comprehensive document produced by the
federal government characterizes the materials commonly
referred to as “municipal solid waste” (“MSW”) as follows:
“ residential solid waste, with some contribution
from commercial, institutional and industrial sources In
some areas, nonresidential wastes are managed separately,
largely because industrial and some commercial sources
produce relatively uniform waste in large quantities, which
makes them more suitable for alternate disposal techniques
or recycling Hazardous wastes, as defined by Federal and
State regulation, generally are managed outside the
munici-pal solid waste stream Exceptions are household hazardous
wastes and hazardous wastes generated in very small
quan-tities, which are often placed in the municipal solid waste
stream by the generator.” 1
One of the most significant developments in municipal
solid waste is the growing acceptance by citizens, all levels
of government, and industries of a new overall philosophy
concerning the management options available to address the
problem of increased waste generation in the face of
ever-decreasing land disposal sites This philosophy is commonly
known as “integrated waste management” and involves the
reliance upon a hierarchy of options from most desirable to
least desirable The options are as follows:
Source reduction, limitation of the amount and/or
toxicity of waste produced
Recycling, reuse of materials
Incineration, thermal reduction
Sanitary landfill, land disposal
While this hierarchy is little more than a common sense
approach to municipal solid waste problems and the unit
operations represented are not new, emphasis on the source
reduction and recycling options as preferred represents a
pro-found shift in attitudes toward municipal waste management
The traditional perspective that generators could produce
dis-cards without limit and depend on technological approaches
to mitigate such wastes and any associated effects of
treat-ment is no longer acceptable This approach is not unique
to the solid waste area but is a part of federal and state
“pol-lution prevention” strategies, which emphasize avoidance of
all types of pollution as preferable to “end of pipe” and other
traditional methods of environmental regulation
LEGISLATION
In 1984, amendments were made to the Resource Conservation and Recovery Act of 1976 (“RCRA”), the existing federal legislation covering solid waste management Although the majority of these amendments were concerned with the regulation of hazardous waste as were the original RCRA mandates, some changes and additions were made to those provisions which were directed at nonhazardous waste
The U.S Environmental Protection Agency (“EPA”) was directed to determine whether the existing criteria for land disposal of waste previously promulgated pursuant to Sections 1008(a) and 4004 of RCRA are adequate to protect human health and the environment from groundwater con-tamination and whether additional authorities are needed to enforce them In addition, EPA must revise the criteria for those facilities which may receive hazardous household or small quantity generator waste Furthermore, States were given three years to develop a program to ensure that munici-pal facilities met the existing criteria and the revised crite-ria when they are promulgated Although enforcement is still largely a state matter, EPA is empowered, though not required, to enforce the criteria if states fail to comply with their obligations As of this writing, revised criteria have been proposed but not yet adopted. 2
Perhaps the most significant aspects of the federal law and its implementation involve initiatives with legislative roots in the original RCRA legislation which had historically received less attention than the Act’s mandate to establish a hazardous waste management regulatory system EPA has begun pursuing a number of activities such as conservation
of virgin materials through guidelines establishing revised product specifications and similar initiatives
State legislation has also witnessed a marked shift toward more conservation-oriented management schemes as well as stricter standards for processing and land disposal facilities
For example, at least twenty-four states have laws mandating the use of recovered materials in procurement processes As
of this writing, nine states had legislation requiring deposits
on beverage containers and four states had mandatory cling laws covering a wide range of materials The scope of these new legislative initiatives and the myriad of options and alternatives they entail is beyond the purview of this analysis What is apparent, however, is that source reduction and recycling represent an important part of modern waste management systems
Trang 23) Disposal (or, hopefully, reuse)
Another natural division, resulting in part from the current
reg-ulatory states, is between hazardous and nonhazardous wastes
This section will deal primarily with nonhazardous wastes;
specifically, with their source and composition and disposal
However, a brief discussion of hazardous wastes is included
because of their importance in understanding the management
of urban waste More detailed discussion of hazardous waste
is found in another section The important problem of
collec-tion is also left to a special seccollec-tion on that subject
Solid waste used to be considered any solid matter which
was discarded as no longer being useful in the economy
During the last decade, this definition has been considerably
broadened For regulatory, and usually disposal purposes,
solid waste is now defined as “any garbage or refuse, sludge
from a waste treatment plant, water supply treatment plant,
or air pollution control facility, and other discarded
mate-rial, including solid, liquid, semi-solid, or contained gaseous
material resulting from industrial, commercial, mining, and
agricultural operations, and from community activities, but
does not include solid or dissolved materials in domestic
sewage, or solid or dissolved materials in irrigation return
flows or industrial discharges which are point sources.” 3 This
definition is important because it indicates that all matter
which is disposed of onto the land in any form is considered
“solid waste.” In addition that material which causes or
sig-nificantly contributes to an increase in mortality or serious
illness or poses a substantial hazard to human health or the
environment, is considered a “hazardous waste.” Hazardous
wastes have been further defined by rulemaking to a limited
set of materials and criteria such as toxicity, flammability,
reactivity, or corrosivity. 4 The handling of hazardous waste
requires special care and special permitting Contrary to the
management of normal refuse or solid waste, the generators,
transporters, and disposers of hazardous wastes must meet
stringent federal and state criteria and have considerable
potential liability exposure The disposers of solid waste
which is not hazardous must meet state criteria that are not
nearly as stringent as those for hazardous materials Thus,
while hazardous material in the past has been often disposed
of along with all other refuse, today this is no longer the case
Industrial waste generators segregate their hazardous from
their industrial waste so as to minimize their problems
Solid wastes are one of the three major interacting waste
vectors; the others are air and water pollutants Solid wastes,
if improperly handled, can be a source of land, air and water
pollution They are, also, at this writing, one of the most
vol-atile public issues and a problem which is presenting many
communities with significant institutional challenges
Significant progress has been made in regulating the posal of solid waste over the last decade Open dumps which presented aesthetic as well as environmental challenges are for the most part closed Regulations are in place for managing solid wastes in an acceptable manner However, dumping into the ocean, which can create “dead” zones, hopefully will be eliminated Nor have we eliminated the potential problems of leachate from landfills Perhaps the most significant problem is the one of locating new landfills or substituting resource recov-ery, reuse and recycling capacity for landfill disposal The technologies are available, but the economics still favor land disposal In the early ’70s there was great hope for massive resource recovery and recycle projects Some of those, dis-cussed later in this section, have not come to fruition because
dis-of economic and institutional barriers Others have succeeded but the technology has not been spread, primarily because of economic barriers Individual and community action to reduce the amount of wastes generated and collected has, in many areas of the country, been successful For example, solid waste contains significant amounts of valuable material; 40% to 50%
of urban waste is paper and, if recycled, can replace virgin stock equivalent to about 9 trees per person per year In addi-tion, the community and thus the taxpayer also saves in terms
of lower collection and disposal costs However, this is still
of limited application because it is usually limited to pers, aluminum cans and perhaps glass Both technology and institutional methodologies for recycling solid waste are still in their infancy and must gain momentum if we are to meet the challenge of solid waste management in the years to come
REGULATION OF SOLID WASTE MANAGEMENT
Regulation of solid waste management has been scattered
The federal government, contrary to its prior policies in air and water, did not take a strong posture in solid waste management
It left regulatory initiative to the states and localities These dealt with the solid waste management primarily through the licensing of collectors, through the “Utility Commissions”
and adding to zoning ordinances regarding local landfills
Public health regulations also played a role with respect to reduction of rodents and pests at landfills Air emissions from incinerators were regulated as were wastewater discharges
In the last several years a number of states have enacted and implemented legislation to regulate landfills Probably the earliest and still among the most comprehensive is the regu-latory effort of the State of California which has classified landfills which respect to underlying geological conditions in terms of what a landfill can and cannot accept
A comprehensive solid waste law at the federal level was passed in 1976 as the “Resource Conservation and Recovery Act of 1976.” 5 This act provides for federal assis-tance to states and regions developing and encouraging environmental sound disposal of solid waste and the maxi-mum utilization of resources It calls for state and regional plans and for federal assistance to develop these plans It requires that each plan shall prohibit the establishment
of open dumps and provides for the upgrading of open
Trang 3dumps that are currently in use It also requires that
crite-ria for sanitary landfills be established However, it leaves
enforcement to the states At the same time, the Act under
Subtitle C provides for federal regulation of the
manage-ment of Hazardous Wastes Many of these regulations have
been issued but the critical ones covering treatment,
stor-age and disposal facilities are still under review
SOURCES OF WASTE
Solid waste differs from air and water pollutants in that it
comes in discrete quanta and is very heterogeneous in nature
Both composition and rate vary significantly from day to day
and from season to season as well as from otherwise similar
sources
The solid waste production in the United States is in excess
of four billion tons/year and was expected to increase to five
billion tons by 1980. 6 Table 1 breaks this down for the year
1967 by major source However, waste generation appears to
have stabilized despite increased loads from air and water
pol-lution control facilities How long this will last remains to be
seen, if and when significant conversions to “coal as fuel” and
more stringent air and water pollution control take place
Urban Waste
Urban waste collected is between 4 and 8 lbs per person per
day, with typical values lying between 4.5 and 5.5 lbs per day
This differs from the amount generated because of self and
private disposal The major wastes included in this category
are tabulated in Table 2, which includes a summary of disposal
trends One should be careful in the terminology because often
domestic and municipal are used interchangeably to indicate
the total refuse picked up from residential (domestic),
institu-tional, small business and light industrial sources
Some further definition of terms may be useful at this
point In general usage many of the terms have been used
interchangeably However, an effort to standardize the
ter-minology was made by the Institute for Solid Waste of
the American Public Works Association and the Office of
Solid Waste Management of the Environmental Protection
Agency. 7 The standard usage of terms detailed by these
groups is summarized here:
Refuse All solid waste matter
Garbage The animal and vegetable waste resulting
from the preparation of food
Rubbish The waste from homes, small businesses,
and so on excluding garbage
Trash Used equivalent to rubbish
Litter Street refuse
Industrial Waste Specialized refuse from
manufactur-ing plants, and usually excludes rubbish
Domestic waste composition will vary seasonally, as well as
with locale and economic status Typical analyses for
domes-tic plus municipal refuse are shown in Table 3 As can be
seen in a comparison of the data, the composition has not
changed drastically with time except for a significant tion in ash because of the change from coal as a home heat-ing fuel Location variations noted are as great or greater A study of seasonal variations made in 1939 for New York City also showed greater variations: the ranges were garbage, 44 to 3.5%; and metal, 11.6 to 3.1%. 8 Base data have been difficult
reduc-to obtain because of the many variabilities in the base The most significant variables include the economic level of the area, the ratio of commercial to residential property, the type
of commercial establishments and the housing density and age The entire picture on obtaining accurate data on urban and/or domestic refuse is further complicated by the sampling problem A discussion of this problem is beyond the scope of this work; the reader is referred to some basic work in this area
by Carruth. 9 An excellent review of sampling and testing has been prepared by the Institute of Solid Wastes. 10 Further work
is being done in this area by ASTM’s D-34 Committee
The ultimate chemical composition of municipal refuse has been examined by a number of investigators Table 4 gives the range of values to be expected Recently 0.3 to 0.5% chloride has been found in refuse independent of the presence of poly-vinyl chloride; this is due to the presence of salt primarily. 11
Density of municipal refuse varies with the load applied to
it Typically household refuse has a density of 350–400 pounds per cubic yard Transfer stations and/or landfill operations can compact it to between 500 and 800 lbs per cubic yard depend-ing upon the material and conditions The effect of compres-sion on density for the Chandler, Arizona refuse is shown in
Figure 1 High pressure compaction (see Compaction) can increase the density to 1200 to 1400 lbs per cubic yard
Industrial Wastes
Industrial wastes amount to about 115 million tons annually
They include any discarded solid materials resulting from an
TABLE 1 Major sources of waste matter United States 1967 5
Source
Solids generated lab/cap/day Million tons/yr Urban
Trang 4industrial operation or establishment with the exception of
dissolved or suspended solids in domestic or industrial waste
waters The composition and quantity of industrial solid
wastes vary significantly from location to location, as well
TABLE 2 Composition of wastes from urban sources 6
Urban sources Waste Composition Disposal, present
Domestic Garbage Wastes from preparation, handling and sale of
food Rubbish, trash Paper, wool, excelsior, rags, yard trimmings,
metals, dirt, glass, crockery, minerals Landfill Ashes Residue from fuel and combustion of solid wastes Incineration Bulky wastes Furniture, appliances, rubber tires Dumping Commercial Garbage Same as domestic Landfill
Institutional Rubbish, trash Same as domestic Incineration
Ashes Same as domestic Demolition wastes, urban
renewal, expressway
Lumber, pipes, brick masonry, asphaltic material and other construction materials
Dumping Landfill Construction wastes Scrap lumber, pipe, concrete, other construction
materials
Dumping Landfill Open burning Special wastes Hazardous solids and semiliquids, explosives,
pathological wastes, radioactive wastes
Burial, incineration Special
Municipal streets, incinerators, sewage
treatment plants, septic tanks
Street refuse Dead animals Abandoned vehicles Fly ash, incinerator residue, boiler slag Sewage treatment residue
Sweepings, dirt, leaves Cats, dogs, horses, etc.
Unwanted cars and trucks Boiler house cinders, metal scarps, shavings, minerals
Solids and sludge
Fill Bury or incinerate Reclaim Landfill or dump Landfill
—
0 20 40 60 80 100 100
300 500 700 900 1100 1300
APPLIED LOAD, LBS./SQ IN.
FIGURE 1 Refuse density Household refuse, Chandler,
Ariz., 1954 Credit: APWA, Municipal Refuse Disposal; 1966
as between industries and within a given industry Table 5
lists the type of wastes to be expected from the various SIC Industrial Groups A large fraction of the wastes are generally common to most industries and are listed on Table 6 Data on the amounts of waste generated by or collected from various industries is very limited Industry, quite natu-rally, has considered this type of data confidential in that it often reveals significant process and economic information
Average data, even if available, are of limited value because wide variations can result from process differences, process efficiencies and direct recycle, as shown in a study based on detailed interviews The results of this study giving total waste
by industry are summarized in Table 7 Industry waste duction on a unit per employee basis vary widely and are sum-marized for large and small companies in Tables 8 and 9 Increased efficiency as well as new uses for present indus-trial waste streams will alter both the quantity and composition
pro-of the material for disposal in the next decade For example, saw mill waste is being reprocessed into composition board and this utilization could essentially eliminate this waste stream Only limited projections can and have been made and these show only a reduction in saw mill wastes. 12 Conversely, enforcement of air pollution statutes will increase the amount
of potential solid wastes significantly Greater purification of industrial wastewater will also affect the solid waste load
Agricultural Wastes
Agricultural wastes are principally organic as indicated in
Table 10 The exceptions are chemicals used in various facets
of farming such as pesticides, containers, and small amounts
Trang 5Material Paper and paper prod 56.01 53.5 32.71 53.33 56.5 42.7 50 69.0 c 69.7 c 38
a Included in glass and leads.
b Glass averaged 6.4% range 3.5–9.3%.
Trang 6of miscellaneous waste matter resulting from maintenance
and general housekeeping
Most crop waste is either plowed back into the soil or
composted Some open burning takes place In some special
cases such as bagasse (sugar cane stalks) industries have been
established to utilize the waste material Essentially none of
this material finds it way into the usual disposal facilities
Animal wastes pose a different problem because much
is produced in very concentrated areas such as feed lots
or poultry farms The disposal of these wastes is posing a
greater problem than crop waste, but may be more easily
solved because it is concentrated and therefore susceptible
to processing without collection Average waste yields for a
variety of domestic animals are summarized on Table 11
Mineral Wastes
Mineral wastes including solids generated in mining, milling
and processing industries are expected to reach between two
and four billion tons per year in 1990 In 1965 this waste
amounted to 1.4 billion tons, as summarized in Table 12
Hazardous Wastes
Hazardous wastes as defined by the federal government and
in many cases similarly by the states, must be receiving
spe-cial handling These wastes generally include materials that are
injurious to human health, toxic, can cause irreversible
environ-mental damage, such as high concentrations of pesticides, are
corrosive, reactive (form toxic gases), or highly inflammable
These wastes are defined in Federal Regulations (40CFR261)
They require special management from generation through
treatment and disposal as defined again by Federal Regulations
A detailed discussion of Hazardous Waste Management is
cov-ered in a section on Hazardous Waste
Processing Methods
A variety of processing methods, as summarized in Table 13, are available at present for handling solid wastes Most have been in use in some modification for at least the last 50 years
The choice of processing method will depend not only on the type of waste but also on location, sources, quantity of waste, method of collection, public opinion, and ultimately economics
Solid waste management was a 4.5 billion dollar try in 1968 It is only in recent years that the public has begun to worry about disposal of solids Prior to that it was
indus-“out-of-sight, out-of-mind.” With ever growing amounts of solid waste as detailed in the discussion on sources, and con-cerns about pollution of ground and drinking water as well
as release of hazardous materials, public pressure is ing a major factor in any decision on waste management
The major disposal methods in use are landfill and eration Of potential interest in the United States are high pres-sure compaction and reclamation by recycling Recycling is being used, but requires solution of institutional and techno-logical barriers before becoming a major factor Compaction
incin-is utilized in at least one major facility in the Meadowlands in New Jersey Composting is practiced in Europe, but also has not been successfully applied in the United States although it does have potential There are new processes and techniques appearing for waste disposal and for the first time an organized research and development effort was mounted in the early ’70s
to look at solid waste disposal; it has slowed down but there is ample opportunity for further progress
Disposal methods could be discussed from the point
of view of source: a brief summary of the most used ods for a variety of sources may be found in Table 14 This discussion will instead focus on the disposal methods most commonly in use today, landfill and incineration, followed
meth-by discussion of compaction, composting, and some of the newer disposal techniques
The oldest method of disposal is dumping either on land
or sea Here dumping in distinguished from Sanitary Landfill (see below) Dumping costs between $6 and $10 per ton and has been used for all waste materials It is totally unsatisfac-tory for putrescible materials such as food wastes and unsatis-factory from a public health as well as aesthetic and land use viewpoint, even for inert material such as demolition waste
Open burning is often used for demolition waste, tree branches and stumps, and similar items; it is unacceptable because of the air pollution it creates Neither dumping nor open burning have a place in the modern waste disposal scheme and are illegal
Sanitary Landfi ll
Landfill is the most widely used method of waste disposal
There are 8900 authorized sites (about half publicly ated) used by the 6300 communities surveyed in 1968. 14 There appeared to be an equal number of unauthorized dumps Unfor-tunately only 6% of the sites were considered to be “truly”
oper-sanitary The remainder fell either into Category B or C on the
US Public Health Service Classification Scale, summarized in
TABLE 4 Municipal refuse B ultimate chemical analysis Constituents % by weight (as received) Proximate Analysis —
Moisture 15–35 Volatile matter 50–65 Fixed carbon 3–9 Noncombustibles 15–25 Ultimate analysis — Moisture 15–35
Nitrogen 0.2–1.0 Sulfur 0.02–0.1 Chloride 0.3–0.5 (16) Noncombustibles 15–25 Heating values, Gross 3000–6000 Btu/1b
Trang 7TABLE 5 Sources and types of industrial wastes SIC group classification Waste generating process Expected specific wastes
Plumbing, heating, air conditioning
Special trade contractors
Manufacture and installation in homes, buildings, and factories
Scrap metal from piping and duct work; rubber, paper, and insulating materials, miscellaneous construction and demolition debris
Ordnance and accessories Manufacturing and assembling Metals, plastic, rubber, paper, wood, cloth, and
chemical residues Food and kindred products Processing, packaging, and shipping Meats, fats, oils, bones, offal, vegetables, nuts and
shells, and cereals Textile mill products Weaving, processing, dyeing, and shipping Cloth and fiber residues
Apparel and other finished products Cutting, sewing, sizing, and pressing Cloth and fibers, metals, plastics, and rubber
Lumber and wood products Sawmills, mill work plants, wooden container,
miscellaneous wood products, manufacturing
Scrap wood, shavings, sawdust; in some instances metals, plastics, fibers, glues, sealers, paints, and solvents
Furniture, wood Manufacture of household and office furniture,
partitions, office and store fixtures, and mattresses
Those listed under Code 24, and in addition cloth and padding residues
Furniture, metal Manufacture of household and office furniture,
lockers, bedsprings, and frames
Metals, plastics, resins, glass, wood, rubber, adhesives, cloth, and paper
Paper and allied products Paper manufacture, conversion of paper and
paperboard, manufacture of paperboard boxes and containers
Paper and fiber residues, chemicals, paper coatings and fillers, inks, glues, and fasteners
Printing and publishing Newspaper publishing, printing, lithography,
engraving, and bookbinding
Paper, newsprint, cardboard, metals, chemicals, cloth, inks, and glues
Chemicals and related products Manufacture and preparation of organic chemicals
(ranges from drugs and soups to paints and varnishes, and explosives)
Organic and inorganic chemicals, metals, plastics, rubber, glass, oils, paints, solvents and pigments Petroleum refining and related
industries
Manufacture of paving and roofing materials Asphalt and tars, felts, asbestos, paper, cloth, and
fiber Rubber and miscellaneous plastic
products
Manufacture of fabricated rubber and plastic products Scrap rubber and plastics, lampblack, curing
compounds, and dyes Leather and leather products Leather tanning and finishing: manufacture of leather
belting and packing
Scrap leather, thread, dyes, oils, processing and curing compounds
Electrical Manufacture of electric equipment, appliances, and
communication apparatus, machining, drawing, forming, welding, stamping, winding, painting, plating, baking, and firing operations
Metal scrap, carbon, glass, exotic metals, rubber, plastics, resins, fibers, cloth residues
Transportation equipment Manufacture of motor vehicles, truck and bus bodies,
motor vehicle parts and accessories, aircraft and parts, ship and boat building and repairing, motorcycles and bicycles and parts, etc.
Metal scrap, glass, fiber, wood, rubber, plastics, cloth, paints, solvents, petroleum products
Professional, scientific controlling
Miscellaneous manufacturing Manufacture of jewelry, silverware, plated ware, toys,
amusement, sporting and athletic goods, costume novelties, buttons, brooms, brushes, signs, and advertising displays
Metals, glass, plastics, resins, leather, rubber, composition, bone, cloth, straw, adhesives, paints, solvent
Stone, clay, and glass products Manufacture of flat glass, fabrication or forming of
glass: manufacturer of concrete, gypsum, and plaster products; forming and processing of stone and stone products, abrasives, asbestos,and miscellaneous nonmineral products.
Glass, cement, clay, ceramics, gypsum, asbestos, stone, paper, and abrasives
Primary metal industries Melting, casting, forging, drawing, rolling, forming,
and extruding operations
Ferrous and nonferrous metals scrap, slag, cores, patterns, bonding agents
Fabricated metal products Manufacture of metal cans, hand tools, general
hardware, nonelectric heating apparatus, plumbing fixtures, fabricated structural products, wire, farm machinery and equipment, coating and engraving
of metal
Metals, ceramics, sand, slag, scale, coatings, solvents, lubricants, pickling liquors
Machinery (except electrical) Manufacture of equipment for construction, mining,
elevators, moving stairways, conveyors, industrial trucks, trailers, stackers, machine tools, etc.
Slag, sand, cores, metal scrap, wood, plastics, resins, rubber, cloth, paint solvents, petroleum products
Trang 8Table 15 There are additional classifications with respect to
use in force in California and suggested in the new Federal
Regulations. 15 There is an increase in “Sanitary Fills” and an
elimination of “Dumps.”
Sanitary landfill is an acceptable method of disposal of
solids and provides for the ultimate disposal of many types of
waste; exceptions are non-degradable materials such as plastic
or aluminum which are placed in landfills Other items
mate-rial, toxic chemicals, and hazardous materials, are not allowed
in landfills for safety Where land is plentiful, or marginal areas
are available for reclamation, sanitary landfills offer a number
of advantages over other disposal methods including low
ini-tial and operating costs Other advantages and disadvantages
are summarized in Table 16 Sanitary landfill is basically the
dumping of wastes followed by compaction and the daily
application of an earth cover This situation has improved in
the last decade and by the mid-1980s—all landfills will be sanitary Several techniques are available, some of which are depicted in Figure 2, depending on the type of site available
The one constant in all operations is the daily earth cover, erably a sandy loam, amounting to, usually, one part earth for every four parts refuse Another, which is being required in new landfills, is leachate collection and treatment In addition these types of waste disposal are limited to “non-hazardous”
pref-materials unless the landfill is especially constructed, licensed and managed
Proper site selection is as critical to a satisfactory fill as is sound operation Selection criteria include proper ground and surface water drainage and isolation as well as leachate collection and treatment, to prevent pollution of the ground water table Location in a drainage basin near streams or lakes and in or close to the ground water table present special problems and should be avoided, where pos-sible Placement in the 100 year flood plain is prohibited
land-Accessibility of cover material is an important consideration
The use of tidal areas and marshes is prohibited Dry pits, abandoned quarries and certain types of canyons of depres-sions are often satisfactory landfill sites
The size of landfills is often restricted by the amount
of land available The capacity can be estimated with a fair degree of accuracy Refuse on arrival may vary in density from
300 to 800 pounds per cubic yard, depending on the delivery method Typically the density in the “fill,” of the initial com-paction with a typical crawler tractor will be 1000 lbs/yd for
a single lift (layer) with a depth of 20 feet of less For tiple lifts the initial density can reach 1250 lbs/yd This initial loading increases by as much as 50% over a period of time as further compaction and decomposition takes place. 16
Much of the material in the sanitary landfill decomposes over a period of between three and ten years depending on climate, permeability of the cover, composition of the refuse and degree of compaction The decomposition in sanitary landfills is anaerobic as compared to aerobic degradation often found in other types of fill Temperatures typically reach 120°F in the fill as a result of the degradation The principal gas products are carbon dioxide and methane The greatest gas production takes place in the first two years, according
to a study made at the University of Washington Ammonia and hydrogen sulfide are not problems in sanitary landfills although small amounts of these gases are produced Odors resulting from the decomposition of putrescible material can
be controlled by observing good operating practice; that is, covering the fill continuously and sealing surface cracks Fire hazard and insects and vermin are not a problem, as compared
to dumps, in a properly operated sanitary landfill although chemical control of the latter two is sometimes required
Completed landfills are suitable for use as recreational facilities, airfields and parking areas; light industrial build-ings may be erected on landfill Building of residential structures on fill requires special precautions because of the potential hazards associated with the evolution of methane and other decomposition gases
The cost of operating a sanitary landfill makes it an tive means of disposal where land is available Costs for a
attrac-TABLE 6 Solid wastes common Packing materials fiber
metal paper plastic wood Maintenance materials paints
metal grease plastic rags General housekeeping waste paper
fires glass solvents industrial chemicals
TABLE 7 Industry Waste for disposal thousand tons/yr
Trang 9sanitary fill will vary between $3 and $10 per ton, depending
on location and size of the fill Small fills, handling less than
50,000 tons per year, will have a unit cost of $5 to $10 per
ton A large urban fill more typically shows costs of $3 to
$6 per ton The wide variation is a result of location differences,
which include differences in land acquisition costs, labor costs
and operating differences due to local surface conditions and
requirements
The use of landfill will continue; however, its future,
par-ticularly in densely populated urban areas, is in doubt Land is
at a premium for this type of application close to urban centers
What land is available must be preserved for non-combustible
material and ashes For examples, one urban county in New
Jersey has less than three years landfill capacity available and
in portions of Long Island no more land for landfill is available
Hauling costs too, as well as public resistance in more rural
areas is making landfill less attractive for urban areas such as
metropolitan New York Finally, landfill does not provide for
maximizing the value of refuse as a source of raw materials
Recent studies to find alternatives to traditional landfill practices include a demonstration of shredding prior to fill-ing Only domestic refuse was shredded; the product was a superior fill compared to “raw” refuse It could be left uncov-ered with satisfactory sanitary and aesthetic results and was easier to dump and compact Flies and rats did not breed on the shredded refuse
The compacted, uncovered fill also had better weathering and load bearing characteristics This can be achieved at a cost
of about $5.00 per ton in a 65,000 ton per year operation. 17
The method has some attractive features, and some cial facilities including one in Monmouth Country, NJ, which incorporates some recycle, use this principle However, oper-ating and investment costs do appear to be higher than the more traditional method of filling “raw,” as collected, refuse
Baling of refuse may be particularly attractive where landfill sites are not locally available A feasibility study was carried out in Chicago which showed that this method overcomes many of the present objections to landfill The
TABLE 8 Waste generation for large fi rms 13
Industrial classification
Employment 1 a Annual wastes vol Cu yd 2 b Annual wastes per employee cu yd 3 c
Title Ordnance and accessories 29,356 131,404 4,476
Other food processing (except 203) 2,012 17,545 8,720
Apparel 601 1,248 2,077
Paper and allied products 250 9,360 37,440
Printing, publishing and allied 968 7,020 7,252
a Column 1: Data on employment were obtained for those large firms which were surveyed and included in the wastes calculation from the research
department of the Association of Metropolitan San Jose (Greater San Jose Chamber of Commerce).
b Column 2: FMC report, Solid Waste Disposal System Analysis (Preliminary Report), Tables 10 and 11, 1968 [5]
c Column 3: Column 2/Column 1.
d For Canning and Preserving (SIC 203), no individual firm data were available The industry total developed for the county as a whole was divided by the
total employment in the industry (specially tabulated) to arrive at the multiplier See text for further explanation.
e Data not available.
Trang 10Japanese have been leaders in this area using high pressure
presses to provide solid cubes suitable for use in building new
land in tidal areas A facility is being successfully operated
in New Jersey More details may be found in the discussion
of compaction
Incineration
Incineration is essentially a method for reducing waste volume
and at the same time producing an inert, essentially
inor-ganic, solid effluent from material which is largely organic
Typical feed analyses are shown in Table 4 In addition to the
solid product a gas is produced consisting mainly of CO 2 , H 2 ,
O 2 and N 2 but containing other gaseous components in tract
quantities depending on the type of material burned and the
operating conditions Incineration is not an ultimate disposal
method in that the solid residue which is primarily an ash
containing some metal must still be disposed of, usually as
landfill The primary advantage is that it reduces the volume
to be disposed of and results in a “clean” inert fill For every
100 tons of material fed to the incinerator approximately
20 tons of residue result The volume reduction is even more
significant, often resulting in a 90% lower solids volume for
organic materials
The theory of incinerator operation is very simple A unit
is designed to expose combustible material to sufficient air at
high temperature to achieve complete combustion Combustion
is usually carried out in fuel beds to ensure good contact of air and refuse Several types of configurations are used to achieve contact; these include concurrent flow of fuel and air-underfire, countercurrent flow of fuel and air-overfire, flow of fuel and air at an angle to each other—crossfeed; and combinations of these The combustion is basically the same for all methods
in that at the ignition front oxygen is rapidly consumed in the reaction O 2 ⫹ C → CO 2 and if oxygen is depleted CO 2 ⫹ C →
2CO Therefore, sufficient oxygen must be available to obtain complete combustion; usually this is provided by adding addi-tional air in the chamber above the fuel Incinerators are typi-cally operated with about 50 to 150% excess air in order that the gas temperatures do not drop below that required for good odor-free combustion; this is usually in the 1700–2300°F range
Recent trends have been to go to the higher part of this range while old units often operate at 1600°F or below The effect of excess air on gas composition is summarized in Table 17 for
a typical refuse A detailed discussion of typical air ments and their effect on the thermal balance may be found in Principles and Practices of Incineration. 18
Trace components in the incinerator-start gas include some SO 2 and NOx The former depends on the sulfur in the refuse and is typically around 0.01 to 0.02% Nitrogen oxide
is generally formed in combustion processes and depends on the amount of excess air and to some degree the operating temperature of the incinerator Typical values of two pounds
of equivalent NO 2 per ton of refuse have been reported. 19,20
Trang 11TABLE 9 Waste generation typical for small fi rms 14
Industrial classification
Weekly wastes vol per firm cu/yd 1 a
Annual wastes vol per firm cu/yd 2 b
Average employment per firm 3 c
Annual wastes vol per employee cu/yd 4 d
Title
Canning and preserving 4 — (not surveyed) —
Other food processing (except
Paper and allied products 44.650 2,321.80 35.479 65.442
Printing, publishing and allied 6.448 335.29 13.289 25.230
a Column 1: Data obtained and calculated for each SIC on the basis of small firm questionnaire response supplied by FMC.
b Column 2: Weekly average in Column 1 multiplied by 52.
c Column 3: Average size of small firm estimated from the distribution of firms by employment size, supplied by the California
Department of Employment (Research and Statistics), San Francisco Office.
d Column 4: Column 2/Column 3.
e Data not available.
TABLE 10 12
Agricultural waste (1966)
Amount (million tons/yr) Crop residue Corn stalks, grain stubble, cull, fruit and vegetable, vines, rice hulls, bagasse,
tree prunings, etc.
552 Animal manure (paunch manure) Organic matter, protein, fat, carbohydrates, nitrogen, phosphorus etc 1.532 a
Trang 12This is equivalent to 500 to 1000 ppm of NOx in the
off-gas depending on the refuse composition and the amount
of excess air Other trace components can be found in the
off-gas and air summarized in Table 18 Their presence or
absence is very much dependent on the type of refuse
incin-erated and the operating conditions
Particulate matter is also present in the stack gas and is
removed by the usual techniques discussed in the section on
Air Pollution Particulate loadings of 3 to 25 pounds per tonne
of refuse burned have been reported 21,22 Typically, particles
range from 5 to 350 microns in size with 30% by weight
under 10 microns and 75% less than 200 microns in size
Solids residue from incinerators will vary widely with the
type of feed and incinerator operating conditions Typical
resi-dues have been examined by the Bureau of Mines The results
of this work are summarized in Table 19 A typical ash and
slag chemical analysis may be found in Table 20 This residue
can be utilized in road fill or separated (see Reclamation)
Incineration can effectively be divided into local, onsite
and central methods The basic principles are the same but
the applications vary considerably Central incineration
facil-ities handle refuse from many sources and a wide variety of
feeds Local incinerators handle either special feeds, onsite,
such as industrial or hospital wastes, or serve a particular
small location such as an apartment house Size is not essarily a criterion although generally central incineration facilities have capacities in excess of 100 tons per day
At the present time there are about 200 central eration facilities in use (making this type of waste reduction facility the most prevalent one) Central incineration handled about 15 million tons of waste annually and is concentrated
incin-in the northeastern part of the United States It is also widely practiced in Europe The practice of incineration of wastes was growing as land for fill, particularly in urban areas, becomes scarcer and technological improvements provide more efficient and cleaner systems
A typical incineration facility will have a capacity ing from 100 to 1200 tons per day with individual furnaces usually limited to a 300 ton per day rating Most large incin-erators today are continuous-feed rather than batch design because operation is more controlled and easier In addition the absence of the heating and cooling cycle results in lower maintenance and a higher capacity per investment dollar Air pollution control is improved significantly in continuous-feed incinerators are compared to batch plants
A large central incineration facility is schematically shown in Figure 3.It can be divided into five areas: (1) the receiving section which includes the weight station, storage hopper and bucket crane; (2) the furnace—which includes the charging hopper, stokers, furnace chamber and air feed system; (3) the effluent gas treating facilities; (4) the ash handling system; and (5) the cooling water system The par-ticular system shown does not have provision for waste-heat recovery; only a few systems incorporate this at present
For mixed refuse, a typical refractory-wall incinerator will have 12.7 cubic feet in the primary furnace chamber and 18.5 cubic feet in the secondary chamber per ton of refuse per
24 hours with a grate loading of 77 pounds per square foot per hour Volume and loading requirements will vary with the type of feed as well as furnace configuration Typically the values quoted correspond to a 12,500 Btu per hour per cubic foot heat release A detailed discussion of furnace design is
TABLE 12 Generation by type of solid wastes from the mineral and fossil and fuel industries (1965)
Industry Mine waste Mill tailings
Washing plant rejects Slag
Processing plant wastes
Total (thousands
of tons) Copper 286,600 170,500 — 5,200 — 466,700 Iron and steel 117,599 100,579 — 14,689 1,000 233,877 Bituminous coal 12,800 — 86,800 — — 99,600 Phosphate rock 72 — 54,823 4,030 9,383 68,308 Lead-zinc 2,500 17,811 970 — — 20,311 Aluminum — — — — 5,350 2,350 Anthracite coal — — 2,000 — — 2,000 Coal ash — — — — 24,500 24,500 Other — — — — — 229,284 Total 419,571 288,900 144,593 23,919 40,233 1,146,500
TABLE 11 Unit generation rates Animal Waste (tons unit yr)
Trang 13TABLE 13 Solid waste management methods Type Present usage Relative cost Items disposed of Principal benefits Sanitary landfill Most used (80%)
second largest method (4%)
High All burnable except
special items and over-sized items
Reduces volume, clean product can produce by- product items Open burning Illegal Low Construction
wastes, leaves, agricultural waste Compaction, high
pressure
Two plants in operation
Medium-high All except
hazardous materials
Produces dense, essentially inert blocks for fill Composting Very few Medium-high Organic only
No tires, large pieces
Provides soil conditioner Garbage grinding Large number home
units
High Organic only Reduces domestic
collections Dumping Not legal Lowest Non-putrescibles
Recycling Only for selected
materials and areas, increasing
High Selected
Depends
on process
Reduces quantity for ultimate disposal
a Many landfills are not sanitary but are included in this classification
b Low under $10/ton; Medium $10 to $30/ton; High $30 ⫹ ton
1
2
3 4
7) — final burning and settling chamber volume 8) — high-pressure opposed spray curtain 9) — fly-ash sluiceways
10) — sequential cyclone collectors 11) — induced-draft fan
12) — bypass flue 13) — provision for added filters or precipitators
beyond the scope of this work and the reader is referred to an
excellent work by Richard C Corey. 22
Incineration in the past has received a bad reputation
because of poor control of gaseous effluents and sloppy
han-dling of solid and liquid effluents With proper design and
operation an incinerator can meet or exceed requirements
on all effluent discharges A modern central incinerator is
a more complex operation than a large commercial steam boiler It therefore requires skilled operating, maintenance and supervisory personnel to ensure efficient operation
At the present time control of particulate matter in the effluent gas is the most critical problem in incinerator design