Category: Mineral and other nonliving resources Where Found Zinc is widely distributed in the Earth’s crust, with an average crustal abundance of 70 parts per million 0.007 percent.. The
Trang 1Web Site
U.S Geological Survey
Mineral Information: Zeolites Statistics and
Information
http://minerals.usgs.gov/minerals/pubs/
commodity/zeolites/
See also: Volcanoes; Water; Water pollution and water
pollution control
Zimbabwe
Categories: Countries; government and resources
Zimbabwe has the second largest reserve of gold on the
African continent and the second largest reserve of
platinum in the world The country also boasts the
largest elephant herd in the world as well as a sizable
impala herd; safari tours have historically been an
im-portant means of support for the local population.
The Country
Zimbabwe is in the southeastern corner of Africa,
bor-dered to the north by Zambia, to the east by
Mozam-bique, to the west by Botswana, and to the south by
South Africa In 2008, the country’s gross domestic
product was estimated at $2.3 billion Of this amount,
agriculture accounted for 18.1 percent, industry
counted for 22.6 percent, and the services sector
ac-counted for 59.3 percent The total value of mineral
production in Zimbabwe exceeds $500 million per
year The mining sector of the economy employs at
least sixty thousand people and accounts for more
than 40 percent of the total export revenues of the
country
Of the total land area, 49.2 percent is forest, and
this consists of mopane and dry Miombo woodland
Grasslands, both low- and high-altitude types,
consti-tute another important ecosystem The Zambezi River,
which forms the border between Zimbabwe and
Zam-bia, is an important waterway of the country
Gold
Africa has about 30 percent of the Earth’s mineral
re-serves, including 40 percent of the world’s gold Gold
is the most important mineral commodity of
Zimba-bwe and the second-leading export commodity,
pro-viding an annual output of $194 million In 2007, 5.7
metric tons of gold were produced by the country’s mines Zimbabwe possesses the second largest gold re-serves in Africa
The Freda Rebecca Mine, located close to Bindura, north of the capital city of Harare, is said to be the richest in the country Ninety thousand metric tons of ore are processed at this mine each month Freda Rebecca is owned by AngloGols Ashanti, a large ming firm Other important gold-minming companies in-clude Falcon Gold, one of the oldest in Zimbabwe; Anglo American; Rio Tinto Zimbabwe; Consolidated Trillion Resources; Independence Gold; Delta Gold; and Reedbuck Gold Central Rand Gold is a holding company for a number of smaller gold-mining and exploration firms
In addition to traditional, large-scale gold-mining operations, nearly everyone in Zimbabwe pans for gold and seeks the mineral in tailings left from closed mines
Diamonds
In Zimbabwe, diamonds, among the world’s most precious minerals, were first discovered in 1997 at Murowa, about 40 kilometers from the town of Zvisha-vane in the south-central portion of the country Three kimberlite pipes containing diamond ore were located at the site The Rio Tinto Group, which is the third largest producer of rough diamonds in the world and also owns gold mines in Zimbabwe, has worked only two of these kimberlite pipes Full-scale production is expected to process 181,400 metric tons
of ore per year Another important diamond mine in the country is the River Ranch mine, a combination open-pit and underground operation De Beers owns
75 percent of River Ranch
As of late 2008, diamond production in Zimbabwe totaled approximately fourteen million carats How-ever, a tremendous amount of illegal mining has oc-curred and contributes to a sizable black market prob-lem The government is attempting to control the diamond situation and the accompanying violence as-sociated with the black market
Platinum Among the world’s scarcest minerals, found at a con-centration of only 0.003 part per billion in the Earth’s crust, platinum is a highly prized metal that is thirty times rarer than gold Its properties of malleability, ductility, and corrosion resistance make it a valuable component used in many industries Platinum is
Trang 2some-Zimbabwe: Resources at a Glance
Official name: Republic of Zimbabwe Government: Parliamentary democracy Capital city: Harare
Area: 150,883 mi2; 390,757 km2
Population (2009 est.): 11,392,629 Language: English
Monetary unit: Zimbabwean dollar
Economic summary:
GDP composition by sector (2008 est.): agriculture, 18.1%; industry, 22.6%; services, 59.3%
Natural resources: coal, chromium ore, asbestos, gold, diamonds, nickel, copper, iron ore, vanadium, lithium, tin,
platinum group metals
Land use (2005): arable land, 8.24%; permanent crops, 0.33%; other, 91.43%
Industries: mining (coal, gold, platinum, copper, nickel, tin, clay, numerous metallic and nonmetallic ores), steel,
wood products, cement, chemicals, fertilizer, clothing and footwear, foodstuffs, beverages
Agricultural products: corn, cotton, tobacco, wheat, coffee, sugarcane, peanuts, sheep, goats, pigs
Exports (2008 est.): $1.321 billion
Commodities exported: platinum, cotton, tobacco, gold, ferroalloys, textiles/clothing
Imports (2008 est.): $1.915 billion
Commodities imported: machinery and transport equipment, other manufactures, chemicals, fuels
Labor force (2008 est.): 4.039 million
Labor force by occupation (1996): agriculture, 66%; industry, 10%; services, 24%
Energy resources:
Electricity production (2006 est.): 9.467 billion kWh
Electricity consumption (2006 est.): 11.59 billion kWh
Electricity exports (2006 est.): 34 million kWh
Electricity imports (2006 est.): 2.867 billion kWh
Natural gas production (2007 est.): 0 m3
Natural gas consumption (2007 est.): 0 m3
Natural gas exports (2007 est.): 0 m3
Natural gas imports (2007 est.): 0 m3
Oil production (2007 est.): 0 bbl/day Oil imports (2005 est.): 15,800 bbl/day Oil proved reserves ( Jan 2006 est.): 0 bbl Source: Data from The World Factbook 2009 Washington, D.C.: Central Intelligence Agency, 2009.
Notes: Data are the most recent tracked by the CIA Values are given in U.S dollars Abbreviations: bbl/day = barrels per day;
GDP = gross domestic product; km 2 = square kilometers; kWh = kilowatt-hours; m 3 = cubic meters; mi 2 = square miles.
Harare
Namibia
South Africa
Angola
Mo zam bique
Botswana
Zambia
Ma la wi
Zimbabwe
I n d i a n
O c e a n
Swaziland
Trang 3times used as a component of dental fillings and as a
catalyst in the catalytic converters of automobiles It
also serves a number of important functions in the
manufacture of laboratory equipment such as
cruci-bles, tongs, funnels, and combustion instruments
Additionally, platinum is valued by many people for
jewelry
Leading world producers of platinum are South
Af-rica (with 80 percent of the planet’s share of
produc-tion), Russia, and Canada Although Zimbabwe
pro-duces approximately only 2 percent of the world’s
platinum group metals, this product is an important
export for the country Found in nickel and copper
ores, platinum is also found in native deposits,
includ-ing those along Zimbabwe’s Great Dyke, a geological
feature that runs north to south for about 550
kilome-ters through the central portion of the country
Plati-num deposits were found in this area in 1925, but only
in more recent times has mining become profitable
Union Carbide began trial mining between 1966
and 1975 at the Mimosa Mine, now Zimbabwe’s
old-est Obtained by Zimasco Ltd in 1992, Mimosa
pro-cesses approximately 27,000 metric tons of ore per
month for a production total of 2,400 kilograms of
platinum each year The mine also supplies palladium
and rhodium, other platinum group metals In 2007,
1,850 kilograms of palladium and 190 kilograms of
rhodium were produced
The Zimplats Mine, also a large producer of
num group metals, produced 3,000 kilograms of
plati-num, 2,440 kilograms of palladium, and 264
kilo-grams of rhodium in 2007 Other important mines
along the Great Dyke include Hartley Platinum, Ngezi,
and Unki Ngezi’s production totaled 2,550 kilograms
in 2006, and Unki was expected to generate about
1,644 kilograms by 2010
Lithium
Although Zimbabwe is not one of the world’s leading
producers of lithium, the country is still important as
a lithium exporter because reserves of this alkali
metal are rare Chile is the leading producer of
lith-ium, followed by Argentina Australia, Brazil, Canada,
Portugal, and Zimbabwe are the other nations for
which lithium is a vital export
Lithium has many uses in industry It has been
used in glass manufacturing for many years because it
lowers the melting point of glass and allows for
con-tainers to be made with thinner walls as well as with
lighter weight Thermal and shock-resistant cookware
is manufactured using lithium, and the metal acts as a catalyst in synthetic rubber and plastic production Lithium carbonate in a pharmaceutical formulation provides a valuable drug for treating manic depres-sion
Probably the most important modern use of lith-ium has been as a component of rechargeable batter-ies Lithium batteries are used as the power sources for 60 percent of all cell phones and 90 percent of all laptop computers
In 2000, Zimbabwe produced 38,000 metric tons of lithium; production increased by 110 percent be-tween 2003 and 2004 Subsequent figures are difficult
to obtain because of the continuing instability of Zim-babwe’s political and economic situation The Glen Cove Mine, operated by Bikita Minerals Ltd., contin-ues production and is considered to have a remark-ably high-quality grade of lithium This particular mine has provided the United States Atomic Energy Commission with about 30 percent of its lithium hy-droxide stockpile
Chromium Zimbabwe boasts more than 50 percent of the world’s reserves of chromite, and together South Africa and Zimbabwe possess 90 percent of Earth’s supply of this valuable ore Chromium is vital in the production of stainless steel, nonferrous (non-iron) alloys, metal-plating processes, and the manufacture of refrac-tories Like lithium and platinum, chromium is im-portant as a catalyst for manufacturing processes For the United States, the only domestic source of chro-mium is through recycling, so the country imports much of its needed supply from South Africa and Zim-babwe
The two major Zimbabwean chromite mines are Mutorashanga and the Torwood and Valley Mine The large companies of Zimasco and Zimbabwe Al-loys International own both the ore-mining and ferrochromium production components, allowing for the vertical integration of this industry
Tobacco Zimbabwe is one of the world’s major tobacco export-ers, ranking seventh, as of 2009, after Brazil, the United States, India, Malawi, Italy, and China For many years, the country ranked as one of the top four tobacco producers in the world Tobacco accounts for more than 50 percent of Zimbabwe’s total agricul-tural exports and represents 30 percent of the
Trang 4coun-try’s total exports Sales of the crop earn about seven
times more than sales of corn, about twenty-two times
more than cotton, and sixty times more than
soy-beans Virtually all the tobacco crop (98 percent) is
exported because there is little domestic production
of cigarettes
Tobacco production provides employment for
ap-proximately 5 percent of the country’s labor force
and also contributes to employment for those in the
coal-mining, transportation, hospitality, and service
sectors of the economy Most tobacco farming is done
by about two thousand large-scale, commercial
grow-ers who utilize modern farming techniques,
includ-ing irrigation These large growers account for 95
per-cent of total crop production and plant on about 87
percent of the available land About sixteen thousand
small-scale dryland farmers raise the remaining 5
per-cent of the country’s tobacco
Three types of tobacco are grown in Zimbabwe
Flue-cured tobacco is raised in the parts of the
coun-try with better rainfall totals, and this encompasses
areas north and east of the capital of Harare Burley
tobacco is grown in the northeastern and eastern
highland regions, where there is both good rainfall
and high humidity, which is necessary for the curing
of this particular type of tobacco Oriental tobacco is
grown primarily by small-scale farmers in Masvingo
Province
Most tobacco farmers practice a five-year rotation
schedule and grow other crops within the rotation
cycle Soybeans, wheat, corn, and livestock are all
pro-duced on tobacco land, and some farmers have turned
to less traditional crops such as export roses,
vegeta-bles for sale to grocery stores, coffee, and paprika
The change to a greater diversity of crops became
nec-essary because of the worldwide campaign to reduce
the use of tobacco products such as cigarettes
For most of the 2000’s, Zimbabwe produced an
av-erage of 181,000 metric tons of tobacco per year, but
in the later years of the decade, production totals
dropped steeply Fewer than 54,000 metric tons were
produced in 2008 As mentioned, the global health
campaign against tobacco use has contributed
signifi-cantly to a drop in production, but severe drought
and shortages of diesel fuel and fertilizer have also
affected this agricultural sector adversely
Cotton
Cotton is Zimbabwe’s second most important
agricul-tural export Approximately 200,000 small farms
pro-duce 98 percent of the cotton crop in the country The amount of cotton produced has been steadily in-creasing In 2007, production totaled 99,700 metric tons; in 2008, 370,000 hectares were planted and har-vested, with seed cotton production reaching 300,000 metric tons and lint production 123,000 metric tons Average yield was 0.81 metric ton per hectare Since 1994, the small-scale cotton growers in Zim-babwe have sold their seed cotton to the Cotton Com-pany of Zimbabwe (Cottco) This comCom-pany is the larg-est buying, processing, and marketing operation in the country, although Cargill and Romsdal also have a share of the cotton market The ginners and mer-chants of these companies provide seed, fertilizer, and pesticides to the growers on credit In turn, the growers sign contracts promising to sell all of their cotton back to the contractors
Large-scale cotton farming takes place in the cen-tral, northern, and eastern sections of Mashonaland, while most small-scale production is in the Gokwe, Gwanda, and Kezi areas of Zimbabwe Alber and long staple varieties of cotton are grown on all farms, and the quality of this cotton is ranked as “high” because there are not many contaminants and not much dam-age to the cotton
Although the textile and garment industries have been well established since the 1930’s in Zimbabwe, these industries and the accompanying cotton pro-duction that supports them have experienced a num-ber of problems Foreign currency problems and the extreme political instability of Zimbabwe have af-fected all of the country’s industries adversely, and the cotton business is no exception Farmers who have been “resettled” by forced government intervention
on former commercial farms are unskilled and have little experience in cotton production There are also
no gins for small farms other than the ones owned by the national companies such as Cottco and Cargill Extreme drought in the region during recent years has also negatively affected cotton as well as many other crops
Some farmers have begun to break a law that states that all cotton stalks must be destroyed at least fifty days before the next season’s planting These farmers have been growing cotton by using the previous year’s stalks, a practice that has led to increased infestation
of pink bollworm, one of the primary cotton pests In spite of these problems, cotton continues to be an im-portant export crop for Zimbabwe and may surpass tobacco as the number one crop of the country
Trang 5Other Resources
One of Zimbabwe’s most important resources is its
wildlife and ecology: Tourism is the third largest
income-producing industry in Zimbabwe, employing
about 200,000 people The country has a variety of
na-tional parks, all of which host an astonishing variety of
flora and fauna Various licenses for tourists, park
fees, and concessions within the parks provide
in-come opportunities for local residents
The national parks include Chimanimani,
Chizar-ira, Gonarezhou, Hwange, Kazuma Pan, Mana Pools,
Matusadona, Matelo, Nyanga, Victoria Falls, and
Zam-bezi Most of the parks host large numbers of the
more common species of savanna wildlife, including
roan, sable, impala, eland, cape buffalo, zebra, and
elephant Lions, leopards, and cheetahs are among
the large predators that may also be seen in a few of
the parks, including Gonarezhou and Kazuma Pan
Chizarira National Park also supports herds of the ex-tremely rare black rhinoceroses The tsessebe, a sa-vanna antelope, and white rhinoceroses are found in Zambezi National Park Hwange, the largest game re-serve in Zimbabwe, located close to the Kalahari Desert, is home to hippopotamuses, crocodiles, brown hyenas, gemsboks, and African wild dogs as well as a large elephant herd
Victoria Falls and Zambezi national parks are lo-cated along Zimbabwe’s border with Zambia and are visited as much for the spectacular natural wonder of waterfalls as for the diversity of wildlife Victoria Falls actually consists of five separate falls, four within babwe and one (Eastern Cataract) in Zambia In Zim-babwe, the Devil’s Cataract, Main Falls, Rainbow Falls, and Horseshoe Falls provide awe-inspiring views for the tourist
Since its inception in 1989, the Communal Areas Management Program for Indigenous Resources, better known as CAMPFIRE, has provided money-making opportunities for local people by leasing land
to tour companies However, in order for ecotourism
to continue to provide a means of support for Zim-babweans, the political situation in the country must stabilize
Lenela Glass-Godwin
Further Reading
Bartholomew, D S Base Metal and Industrial Mineral Deposits of Zimbabwe Reprint Harare: Zimbabwe
Geological Survey, 1992
Coakley, George J The Mineral Industry of Zimbabwe.
Washington, D.C.: U.S Geological Survey, 2000
Duffy, Rosaleen Killing for Conservation: Wildlife Policy
in Zimbabwe London: International African
Insti-tute, 2000
Ebensperger, Arlene, P Maxwell, and C Moscoso
“The Lithium Industry: Its Recent Evolution and
Future Prospects.” Resources Policy 30, no 3 (2005):
218-231
George, M W Platinum Group Metals Washington,
D.C.: U.S Geological Survey, 2007
Hulme, David, and Marshall Murphree, eds African Wildlife and Livelihoods: The Promise and Performance
of Community Conser vation Portsmouth, N.H.:
James Currey, 2001
See also: Chromium; Cotton; Diamond; Gold; Lith-ium; Platinum and the platinum group metals; South Africa
Victoria Falls is one of the many natural wonders found in
Zim-babwe (©Lucian Coman/Dreamstime.com)
Trang 6Category: Mineral and other nonliving resources
Where Found
Zinc is widely distributed in the Earth’s crust, with an
average crustal abundance of 70 parts per million
(0.007 percent) It has been concentrated into several
types of ore deposits from which it is mined as the
principal metal or as a by-product The principal ore
mineral is sphalerite (ZnS), also known as zinc blende
or marmatite China, Japan, Australia, and Canada
are the world’s largest suppliers of zinc
Primary Uses
Zinc is a widely used metal, but its presence is
gener-ally not obvious to the public The largest single use is
in galvanizing, a process in which iron or carbon steel
is covered with a thin coating of zinc to prevent
rust-ing Zinc is also widely used in brass alloys and other
compounds ranging from pharmaceuticals to rubber
tires to paints
Technical Definition
Zinc (symbol Zn), atomic number 30, belongs to
Group IIB of the periodic table of the elements and
exhibits some chemical and physical similarities to
cadmium It has five naturally occurring stable
iso-topes, with masses of 64, 66, 67, 68, and 70, and it has
an average atomic weight of 65.38 Pure zinc is a
mal-leable, bluish-white metal that crystallizes in a
hexago-nal structure and that has a density of 7.13 grams per
cubic centimeter It has a melting point of 419.6°
Cel-sius and a boiling point of 907° CelCel-sius
Description, Distribution, and Forms
Zinc is one of the most widely used metals; however,
throughout much of its history it was not recognized
as a distinct metal Zinc is nearly ubiquitous in trace
amounts and is essential for the normal growth and
development of plants and animals It occurs in more
than twenty metalloenzymes and promotes healing of
wounds and burns; furthermore, zinc deficiency has
been shown to have severe effects on reproduction
and tissue growth in laboratory animals Zinc
defi-ciency in soils leads to reduced productivity but can be
remedied by the application of trace amounts of zinc
in fertilizers
Numerous studies of zinc in the environment have
demonstrated that severe zinc pollution is extremely rare and that zinc contamination rarely becomes a problem for plants or animals In general, the only time that zinc concentrations can rise to harmful lev-els is if the pH is very low and the sources of zinc are very large Zinc is readily adsorbed onto clays or pre-cipitates from solutions at neutral and high pH values Zinc and its compounds are relatively nontoxic to hu-mans when taken in normal dosages Very large dos-ages can cause gastroenteritis; however, reports of such poisoning are limited to a few rare cases of the consumption of acidic beverages having been kept in galvanized containers Workplace poisoning has been only rarely reported as the result of inhaling zinc dust
or fumes; the human body is quite efficient in the elimination of excess zinc
Zinc has been mobilized by fluids in the Earth’s crust and precipitated into many types of ore deposits Although there are many zinc-bearing minerals, the only mineral that serves as an economic source of zinc
in mining is sphalerite (ZnS) The principal types of ores are carbonate-hosted lead-zinc ores (Mississippi Valley-type ores, so called because of their abundance
in parts of the Mississippi Valley drainage system, es-pecially Missouri), hydrothermal vein deposits, and polymetallic massive sulfide ores formed where hy-drothermal fluids have deposited complex ores in sedimentary basins or in masses of volcanic rocks The Mississippi Valley-type ores occur in limestone and do-lomite beds where there has been infiltration of rela-tively low-temperature (75° to 150° Celsius) fluids that have already leached zinc (and commonly lead) from thick sequences of sedimentary rocks The zinc is de-posited as the mineral sphalerite, most often as light yellow coatings on, and as fracture fillings in, the car-bonate rocks This sphalerite typically contains small amounts (0.5 percent) of cadmium and iron and trace amounts (less than 0.1 percent) of germanium, gallium, and indium in solid solution Consequently, the zinc ores serve as the world’s major sources of these rare elements, which are recovered during re-fining
Zinc-bearing hydrothermal deposits commonly oc-cur as veins from centimeters to meters in thickness associated with granitic to intermediate igneous rocks The sphalerite in these ores is typically very dark brown to black and contains 5 to 10 percent iron sub-stituting for the zinc; it has commonly been called
“blackjack” or marmatite The zinc ores of the volca-nic and sedimentary deposits are similar
Trang 7mineralogi-cally to those of the vein deposits with the sphalerite
intermixed with pyrite (FeS2), chalcopyrite (CuFeS2),
and galena (PbS) These deposits occur where
frac-tures and faults have allowed deeply circulating
groundwaters, containing small amounts of dissolved
metals, to discharge and precipitate complex masses
of sulfides In recent years modern examples of these
types of deposit have been observed forming at
oce-anic spreading centers such as the East Pacific Rise
At these sites, hydrothermal fluids issuing from the
seafloor fractures are depositing polymetallic sulfide
mounds that are rich in zinc Although all the zinc in
ore deposits occurs as sphalerite, much of the zinc
forming in modern seafloor deposits is wurtzite,
an-other form of ZnS; the wurtzite gradually is converted
into sphalerite after deposition
In 2008, world zinc production was about 11
mil-lion metric tons World reserves are thought to be
about 180 million metric tons The world reserve
base, which includes zinc that will likely become
eco-nomic to mine, is about 480 million metric tons
United States production is dominated by Alaska,
Tennessee, New York, Missouri, and Colorado and has been in the range of 800,000 metric tons per year; total U.S reserves are about 14 million metric tons, and the U.S reserve base is about 90 million metric tons Accordingly, U.S mines will be able to continue
to produce zinc at about the same rates for several de-cades
History Zinc has been found in some bronze and brass arti-facts made five thousand years ago, and a few early ex-amples of nearly pure zinc metal date back to about
500 b.c.e Significant zinc production appears to have begun in China in the sixth century c.e Subsequent large-scale production is known from India about
1000 c.e., but zinc appears in European usage only around the sixteenth century The technology of zinc smelting is thought to have been developed in China and brought to Europe about 1730
The use of zinc in the United States began in 1835, when it was desired to produce alloys for the manufac-ture of the U.S standard units of weights and
mea-Data from the U.S Geological Survey, U.S Government Printing Office, 2009.
Source: Mineral Commodity Summaries, 2009
1,510,000 660,000
3,200,000 420,000
460,000
1,450,000 770,000
2,840,000
Metric Tons
3,500,000 3,000,000
2,500,000 2,000,000
1,500,000 1,000,000
500,000 United States
Kazakhstan
China
Canada
Australia
Mexico
Peru
Other countries
Zinc: World Mine Production, 2008
Trang 8sures Mining in the United States began about 1850
in rich ores in New Jersey and Pennsylvania A smelter
was built in 1859 By 1900 mines had been developed
in a number of other states, especially along the
Mis-sissippi Valley
Obtaining Zinc
Zinc ores are mined by underground and surface
mining methods, depending upon the depth of the
deposit below the surface Generally ores must
con-tain 2.5 to 3.0 percent zinc or about 4 to 5 percent
sphalerite to be economic; this percentage is
equiva-lent to a concentration factor of about four hundred
times the average abundance of zinc in the Earth’s
crust In order to recover the zinc, the ores are crushed
finely enough that the individual mineral grains may
be separated by the froth flotation process This
pro-cess selectively removes the sphalerite grains as they
attach themselves to small bubbles and float off the
surface of a suspension that contains many kinds of
minerals The separation yields a concentrate that
contains about 55 to 65 percent zinc, depending
upon the purity of the sphalerite Other valuable
metals—such as cadmium, germanium, gallium, and
indium—that are present in small amounts in the
sphalerite are separated during selective smelting and
refining In most smelters, the zinc sulfide is roasted
to remove the sulfur and to produce zinc oxide, which
is then leached with sulfuric acid to form a zinc sulfate
solution After the solution is purified, the zinc is
removed in electrolytic cells and precipitates on large
aluminum cathodes Further refining is accomplished
by distilling the zinc in a vapor form, which is then
recondensed Zinc recycling accounts for a relatively
insignificant percentage of demand because so much
of the zinc is used in forms for which recycling is
diffi-cult or inefficient
Uses of Zinc
Zinc metal and zinc compounds have broad uses, but
many applications are not easily visible or known to
those who benefit from them About 90 percent of
zinc is used in the metallic form; the remainder is
used as zinc oxide and a variety of other compounds
More that half of metallic zinc usage is for the
galva-nizing of iron and steel for construction,
transporta-tion, electrical, and machinery purposes The
appli-cation of the zinc, either by dipping the iron and steel
into molten zinc or by electrolytic plating, provides a
coating that greatly reduces the rusting of iron and
steel Much of the use of such galvanized materials is
on the body parts of motor vehicles Many construc-tion materials, from nails to bridge parts, are also gal-vanized to reduce corrosion
Die-cast zinc materials are also widely used in han-dles, grills, gauges, housings, and assorted hardware, much of it in vehicles The modern American auto-mobile can contain as much as 18 kilograms of zinc Zinc is also used as a sacrificial anode on ships, oil rigs, and other structures exposed to seawater These an-odes corrode as the result of natural electrical cells that develop, and in the process they prevent the cor-rosion of other metals Beginning in 1983, zinc was used in the minting of United States one-cent coins; the penny is composed of 95 percent zinc
Zinc is a basic component of the copper-based alloy brass, which has served humankind for thousands of years Brass is widely used in shell casings for ammuni-tion, in tubing, in motors, in refrigeration equipment, and in communication and electronic devices Zinc dust and zinc oxide have been used in corrosion-inhibiting primer paints for application on metals Zinc dust is also used in the manufacture of alkaline dry-cell batteries Zinc oxide and other compounds
Commodity Summaries, 2009
Data from the U.S Geological Survey,
U.S Government Printing Office, 2009.
Galvanizing 55%
Alloys 21%
Brass &
bronze 16%
Other 8%
U.S End Uses of Zinc
Trang 9such as chlorides, sulfates, and sulfides are widely
used in chemical catalysts, welding and soldering
fluxes, paints, fungicides and pharmaceuticals, and
phosphors for cathode tubes and radar scopes; they
are also used as additives in lubricating oils and greases
and in agricultural products
James R Craig
Further Reading
Adriano, Domy C “Zinc.” In Trace Elements in
Terres-trial Environments: Biogeochemistry, Bioavailability,
and Risks of Metals 2d ed New York: Springer, 2001.
Greenwood, N N., and A Earnshaw “Zinc,
Cad-mium, and Mercury.” In Chemistry of the Elements 2d
ed Boston: Butterworth-Heinemann, 1997
Guilbert, John M., and Charles F Park, Jr The Geology
of Ore Deposits Long Grove, Ill.: Waveland Press,
2007
Krebs, Robert E The History and Use of Our Earth’s
Chemical Elements: A Reference Guide 2d ed
Illustra-tions by Rae Déjur Westport, Conn.: Greenwood
Press, 2006
Massey, A G “Group 12: Zinc, Cadmium, and
Mer-cury.” In Main Group Chemistry 2d ed New York:
Wiley, 2000
Nriagu, Jerome O., ed Zinc in the Environment New
York: Wiley-Interscience, 1980
Rainsford, K D., et al., eds Copper and Zinc in
Inflam-matory and Degenerative Diseases Boston: Kluwer
Ac-ademic, 1998
Silva, J J R Fraústo da, and R J P Williams “Zinc:
Lewis Acid Catalysis and Regulation.” In The
Biolog-ical Chemistry of the Elements: The Inorganic Chemistry
of Life 2d ed New York: Oxford University Press,
2001
Web Sites
Natural Resources Canada
Canadian Minerals Yearbook, Mineral and Metal
Commodity Reviews
http://www.nrcan-rncan.gc.ca/mms-smm/busi-indu/cmy-amc/com-eng.htm
U.S Geological Survey
Zinc: Statistics and Information
http://minerals.usgs.gov/minerals/pubs/
commodity/zinc
See also: Brass; Cadmium; Open-pit mining;
Under-ground mining
Zirconium
Category: Mineral and other nonliving resources
Where Found The known deposits of zirconium constitute 0.028 percent of the Earth’s crust, which is greater than the combined total of all known copper, nickel, lead, tin, zinc, and mercury deposits Reserves of zirconium minerals are found in Australia, Brazil, China, India, South Africa, Ukraine, Sri Lanka, Russia, and Canada Deposits in the United States are located in Florida, North Carolina, California, Oregon, Colorado, and Idaho The largest deposits are in Australia and South Africa
Primary Uses Zirconium is used mainly in ceramics, foundry appli-cations, opacifiers, and refractories, as well as in abra-sives, chemicals alloys, welding rod coatings, and sand-blasting
Technical Definition Zirconium (symbol Zr) is a grayish-white, lustrous metal It is a member of the second series of transition metals in Group IVB in the periodic table of elements Zirconium’s atomic number is 40, and its atomic weight is 91.22; it has five stable isotopes and three un-stable isotopes Zirconium has a melting point of 1,852° Celsius, a boiling point of 4,377° Celsius, and a density of 6.506 grams per cubic centimeter
Description, Distribution, and Forms Zirconium occurs in abundance in S-type stars and has been identified in the Sun and meteorites Zirco-nium is found in many minerals, such as zircon (nium silicate) and baddeleyite (almost pure zirco-nium dioxide), and it is typically found in igneous rocks (mainly granite and diorite)
History Zirconium was discovered by German chemist M H Klaproth in 1789, while he was studying some semi-precious stones from Sri Lanka The name comes
from the Arabic word zargun, which means gold color,
describing the gemstone now known as zircon Im-pure zirconium was first isolated by Jöns Jacob Ber-zelius by heating a mixture of potassium zirconium fluoride with potassium in an iron tube
Trang 10Obtaining Zirconium
Metallic zirconium is produced commercially by the
purification of zirconium tetrachloride by
sublima-tion and reducsublima-tion of the tetrachloride vapor with
molten magnesium (the Kroll process) Unless
spe-cial separation methods, such as column
chromatog-raphy, are used in this process, the zirconium
pro-duced contains between 0.5 and 3 percent hafnium,
chemical element number 72
Uses of Zirconium
Because zirconium has a low tendency to absorb slow
neutrons and a remarkable resistance to the
corro-sive environments in nuclear reactors, it finds many
uses in the field of nuclear energy Zirconium and its
tin-iron-nickel-chromium alloy (zircaloy) are used as
coatings for pipes and fuel element jackets in fission
reactor cores Zirconium is also used in deodorants,
surgical instruments, pins, screws for bone repairs,
spinnerets for the spinning of rayon fibers, alloys, and
powder metallurgy In powdered form, zirconium is
used as an ammunition primer, in smokeless flash
pow-ders, in blasting caps, and in the manufacture of
vac-uum tubes Various zirconium compounds are used as
catalysts for ammonia synthesis, for organic oxidations, for polymerizations, and in the conversion of sulfur di-oxide to sulfur tridi-oxide Along with niobium (colum-bium), zirconium is a superconductor (it can conduct electricity without any resistance) at low temperatures and is used in the construction of superconducting magnets with potential applications to the generation
of electrical power Baddeleyite, a compound of zirco-nium and oxygen, can withstand extremely high tem-peratures It is used for laboratory crucibles (melting pots for metals) and the linings for certain furnaces
Alvin K Benson
Web Site U.S Geological Survey Mineral Information: Zirconium and Hafnium Statistics and Information
http://minerals.usgs.gov/minerals/pubs/
commodity/zirconium/
See also: Alloys; Australia; Brazil; Igneous processes, rocks, and mineral deposits; India; Isotopes, radioac-tive; Minerals, structure and physical properties of; Niobium; Nuclear energy
Data from the U.S Geological Survey, U.S Government Printing Office, 2009.
Source: Mineral Commodity Summaries, 2009
575,000 31,000
160,000 29,000
405,000 35,000
Withheld 120,000
Metric Tons
600,000 500,000
400,000 300,000
200,000 100,000
United States
India
China
Brazil
Australia
South Africa
Ukraine
Other countries
Zirconium: World Mine Production, 2007