The most widely produced cement is portland cement used in con-crete, which is generally made from limestone and silica- and alumina-bearing material such as clay or shale.. Magnesite is
Trang 1CNa2CO3C2H2O), hydromagnesite (Mg5(CO3)4(OH)2
C4H2O), and artinite (Mg2(CO3)(OH)2C3H2O)
The most abundant carbonate mineral is calcite
(CaCO3), which comprises limestone, chalk,
traver-tine, tufa (sedimentary rocks), and marble
(meta-morphic rock) Most limestone forms in warm,
shal-low seas, far from sources of land-derived sediment
Chalk is made of the shells of microscopic floating
or-ganisms which once lived in the sea Spring deposits
are travertine or tufa, and cave deposits (stalactites
and stalagmites) are travertine These deposits form
from the evaporation of groundwater carrying
dis-solved calcium carbonate Marble is limestone which
has been changed by heat and pressure Malachite
and azurite are associated with the oxidized portions
of copper deposits and with copper veins through
limestone deposits
Sodium carbonate minerals are present in
associa-tion with dry salt lake deposits in some parts of the
world These include trona, natron (Na2CO3C10H2O),
thermonatrite (NaCO3CH2O), nahcolite (NaHCO3),
gaylussite (CaCO3CNa2CO3C5H2O), pirssonite (CaCO3
CNa2CO3C2H2O), and shortite (2CaCO3CNa2CO3)
History
Calcite, because of its abundance, has a rich history
Because calcite can preserve fossil records, its
pres-ence helps date cultural artifacts Chalk has been used
for writing for thousands of years
Obtaining Carbonate Minerals
The most important use of calcite is in the production
of cements and lime When limestone is heated to
about 900° Celsius, it loses CO2and is converted to
quicklime or lime (CaO) Mixed with sand, quicklime
forms mortar When mixed with water, it hardens
or “sets,” swelling and releasing heat The most widely
produced cement is portland cement (used in
con-crete), which is generally made from limestone and
silica- and alumina-bearing material such as clay or
shale The raw materials are ground together, and
the mixture is heated in a kiln until it fuses into a
“clinker,” which is then crushed to a powder
Uses of Carbonate Minerals
Lime (CaO) is also used in agriculture to neutralize
acid in soils, in the manufacture of paper, glass, and
whitewash, and in tanning leather It is used in
refin-ing sugar, as a water softener, and as a flux for smeltrefin-ing
various types of ores Fine-grained limestone has been
used in lithography (printing) Blocks of cut lime-stone and marble are used as building lime-stone and orna-mental stone and may be polished Crushed lime-stone is used as aggregate in concrete and as road metal Dolomite has uses similar to those of calcite Several carbonates are metal ores: dolomite and magnesite (ores of magnesium), rhodochrosite (man-ganese), siderite (iron), smithsonite (zinc), strontian-ite (strontium), witherstrontian-ite (barium), cerrusstrontian-ite (lead), malachite and azurite (copper), and trona (sodium) Magnesite is used in the manufacture of refractory materials capable of withstanding high temperatures, for special types of cements, and in the paper, rubber, and pharmaceutical industries Strontianite is also used in the manufacture of fireworks, producing a purplish-red flame Malachite (green) and azurite (blue) are used as pigments Sodium carbonate and sodium bicarbonate are important in the manufac-ture of washing soda (or sal soda) and are used as cleaning agents and water softeners They are used in the manufacture of glass, ceramics, paper, soap, and sodium-containing compounds (such as sodium hy-droxide) as well as in petroleum refining Sodium bi-carbonate, also known as baking soda, is an important part of baking powder, is a source of carbon dioxide in fire extinguishers and is used medicinally to neutral-ize excess stomach acid Several carbonates are used
as ornamental stone and in jewelry, including mala-chite, azurite, aragonite (alabaster), rhodochrosite, and smithsonite
Pamela J W Gore
Further Reading
Klein, Cornelis, and Barbara Dutrow The Twenty-third Edition of the Manual of Mineral Science 23d ed.
Hoboken, N.J.: J Wiley, 2008
Pellant, Chris Rocks and Minerals 2d American ed.
New York: Dorling Kindersley, 2002
Pough, Frederick H A Field Guide to Rocks and Min-erals Photographs by Jeffrey Scovil 5th ed Boston:
Houghton Mifflin, 1996
Tegethoff, F Wolfgang, Johannes Rohleder, and
Evelyn Kroker, eds Calcium Carbonate: From the Cre-taceous Period into the Twenty-first Century Boston:
Birkhäuser Verlag, 2001
Tucker, Maurice E., and V Paul Wright Carbonate Sedimentology Boston: Blackwell Scientific, 1990 Warren, John K Evaporite Sedimentology: Importance in Hydrocarbon Accumulation Englewood Cliffs, N.J.:
Prentice Hall, 1989
Trang 2Web Site
Carbonate-hydroxylapatite Mineral Data
http://webmineral.com/data/Carbonate-hydroxylapatite.shtml
See also: Carbon cycle; Crystals; Evaporites; Lime;
Limestone; Minerals, structure and physical
proper-ties of; Sedimentary processes, rocks, and mineral
de-posits
Carnegie, Andrew
Category: People
Born: November 25, 1835; Dunfermline, Scotland
Died: August 11, 1919; Lenox, Massachusetts
Carnegie established the Carnegie Steel Company,
which he eventually sold for $250 million The
explo-sive growth of the steel industry that Carnegie’s success
exemplified initiated the final phase of the Industrial
Revolution; it ultimately led, for example, to the mass
production of automobiles and the exploitation of a
va-riety of resources worldwide.
Biographical Background
In 1848, Andrew Carnegie moved from Scotland to
the United States He began working in an Allegheny,
Pennsylvania, cotton mill for $1.20 per week Later, he
moved to Pittsburgh, becoming involved in the
rap-idly growing railroad business Carnegie soon became
the superintendent of the Pittsburgh division of the
Pennsylvania Railroad By investing wisely in what
be-came the Pullman Company and in oil lands,
Carne-gie established the foundation for his fortune
Impact on Resource Use
Following service in the War Department during the
Civil War, Carnegie left the Pennsylvania Railroad and
formed a company to build iron railroad bridges This
led to the next step: the production of steel He
founded a steel mill and began using the new
Besse-mer process of making steel The extensive use of steel
that resulted from Carnegie’s work led to a greater
ex-ploitation of iron ore deposits in the United States
and abroad The need for oil and rubber, which grew
alongside the booming steel industry, also
acceler-ated resource exploitation and had profound effects
on succeeding generations
By 1899, the Carnegie Steel Company controlled
25 percent of steel production in the United States Two years later, Carnegie sold the company to J P Morgan, who organized it into the U.S Steel Corpora-tion, the first billion-dollar corporation in the United States
When Carnegie was thirty-three years old, with an annual income of fifty thousand dollars, he declared that a person should never seek to build a fortune un-less intending to give the surplus for benevolent pur-poses Although he did not always follow his own ad-vice, he did eventually give more than $350 million to philanthropic projects, including the endowment of seventeen hundred libraries, the Tuskegee Institute, and the Peace Palace at The Hague in the Nether-lands
Glenn L Swygart
See also: Bessemer process; Capitalism and resource exploitation; Iron; Steel; Steel industry
Andrew Carnegie was the leading figure in the steel industry at the end of the nineteenth century (Library of Congress)
Trang 3Carson, Rachel
Category: People
Born: May 27, 1907; Springdale, Pennsylvania
Died: April 14, 1964; Silver Spring, Maryland
Carson made a major contribution to the
environmen-tal movement in the United States by educating the
public about the natural geological evolution of the
Earth and the dangers associated with the widespread
use of chemicals Her book Silent Spring was
pub-lished in 1962.
Biographical Background
Rachel Carson was educated at the Pennsylvania
Col-lege for Women in Pittsburgh and Johns Hopkins
University in Baltimore, Maryland She did research
at the Woods Hole Marine Biological Laboratory and
subsequently worked for the U.S Fish and Wildlife
Service in Washington, D.C
Impact on Resource Use
Carson published Under the Sea-Wind (1941); The Sea Around Us (1951), which received the National Book Award for nonfiction; The Edge of the Sea (1955); and her most famous work, Silent Spring (1962) Her
writ-ings took a naturalist’s approach to explaining the ocean environment and the origin of the Earth, and they were praised for their clear explanations in lay
terms The Edge of the Sea revealed Carson’s growing
in-terests in the interrelationships of Earth’s systems and
a holistic approach to human interaction with nature
In Silent Spring Carson warned of the environmental
contamination that results from widespread use of pes-ticides, particularly dichloro-diphenyl-trichloroethane (DDT) She described how the ecology of the soil had been largely ignored in the rush to apply chemicals, drew attention to the effects on wildlife where chemi-cal mixing in runoff channels turned streams into le-thal cauldrons of chemical soup, and accused the chemical companies of aggressive marketing policies that ignored the impact on the environment The first Earth Day (April 22, 1970) and the creation of the En-vironmental Protection Agency in 1970 can both be attributed in part to Carson’s role in changing the way Americans thought about their surroundings
Pat Dasch
See also: Environmental movement; Food chain; Pesticides and pest control
Carter, Jimmy
Category: People Born: October 1, 1924; Plains, Georgia
As the thirty-ninth president of the United States, James Earl “Jimmy” Carter deregulated domestic crude oil prices and established the Department of Energy.
Biographical Background Jimmy Carter graduated from the United States Naval Academy and served in the Navy until his father’s death Assuming his father’s business responsibilities, Carter expanded the family business and ran for politi-cal offices He was elected governor of Georgia in 1970
At the end of his term as governor, Carter began a cam-paign for the presidency He ran against incumbent Gerald Ford in 1976 and won by a narrow margin
Rachel Carson’s seminal text Silent Spring helped spearhead the
modern environmental movement (Library of Congress)
Trang 4Impact on Resource Use
The years before and during President Carter’s term
were times of instability in the world economy World
petroleum demand was increasing, and Congress had
capped domestic crude oil prices, discouraging
do-mestic petroleum exploration In 1979, the
Organiza-tion of Petroleum Exporting Countries (OPEC) raised
crude oil prices by 50 percent Because most goods
were moved to market by gasoline- or diesel-powered
transport, the increase in world petroleum prices
con-tributed significantly to inflation, which reached an
annual rate of 12 percent Interest rates tracked
infla-tion and rose 20 percent, a level unprecedented in the
twentieth century
In response to these problems, President Carter
proposed an energy program that included creation
of a Department of Energy, deregulation of domestic
crude oil prices, and promotion of conservation and
alternative energy sources An advocate of
environ-mentalism, President Carter was also successful in
obtaining congressional action that preserved vast wilderness areas in Alaska
Robert E Carver
See also: Department of Energy, U.S.; Energy eco-nomics; Oil embargo and energy crises of 1973 and 1979; Synthetic Fuels Corporation
Carver, George Washington
Category: People Born: July 12, 1861?; near Diamond Grove (now Diamond), Missouri
Died: January 5, 1943; Tuskegee, Alabama
A pioneering African American agricultural scientist, Carver is best known for popularizing and promoting the economic potential of peanuts and sweet potatoes as alternative crops for southern farmers.
Biographical Background George Washington Carver was born into slavery near the end of the Civil War near Diamond Grove (now Diamond), Missouri His early education was spo-radic, though he did attend high school in Minneapo-lis, Kansas He was briefly a homesteader in Ness County, Kansas, before he returned to school, first at Simpson College in Indianola, Iowa, where he studied fine arts, then at Iowa State University in Ames, Iowa, where he studied agriculture After Carver completed his bachelor of agriculture degree in 1894, he was ap-pointed to the faculty at Iowa State and received a master of agriculture degree in 1896
Impact on Resource Use Carver immediately began working as director of agri-culture and director of the agricultural experiment station at Tuskegee University in Alabama Carver won international acclaim for the educational efforts
he began in the early 1900’s to promote sound conser-vation practices and sustainable agricultural activity
in the rural South, which had previously been depen-dent on cotton production He is best known, how-ever, for popularizing and promoting the economic potential of peanuts and sweet potatoes as alternative crops for southern farmers He was instrumental in persuading Congress to protect the peanut industry from foreign competition shortly after World War I
Jimmy Carter, the thirty-ninth president of the United States, was an
early advocate of alternative energy use (Library of Congress)
Trang 5In the later stages of his career, he investigated the
po-tential uses of peanuts and sweet potatoes, which
in-cluded uses in dyes, milk substitutes, and cosmetics
Mark S Coyne
See also: Agricultural products; Agriculture
indus-try; Agronomy
Cement and concrete
Category: Products from resources
Cement and concrete have played crucial roles in
shap-ing humankind’s physical environment Of all
manu-factured construction materials worldwide, concrete is
the most widely used.
Background
Cement is an important construction material
be-cause of the ready availability of its raw materials, its
capacity to be shaped prior to setting, and its durabil-ity after hardening When combined with an aggre-gate (such as sand, gravel, or crushed rock), cement becomes concrete—a durable, load-bearing construc-tion material
Cements with the ability to set and harden under-water are called hydraulic cements The most mon of these is portland cement, consisting of com-pounds of lime mixed with silica, alumina, and iron oxide Gypsum is also added to retard the setting time When water is added, these ingredients react to form hydrated calcium silicates that will set into a hardened product
History Cement has been used for construction purposes for the past six thousand years The Egyptians are known
to have used a simple cement, and the Greeks and Ro-mans advanced the technology by creating hydraulic cements from various volcanic materials and lime Many examples of their concrete structures remain today—some underwater, where they were used in harbors
The quality of cementing materials declined greatly during the Middle Ages but began to improve again in the late eighteenth century In 1756, the famed Brit-ish engineer John Smeaton was commissioned to re-build the Eddystone Lighthouse near Cornwall, En-gland He undertook a search for lime mortars that would resist the action of the water and discovered that the best limestone contains a high proportion of clayey material For his project he used lime mixed with pozzolana from Italy (the same volcanic material the Romans had used) Smeaton was followed by a number of researchers, including Joseph Aspdin, a Leeds builder, who patented “portland” cement, named for the high-quality building stone quarried at Portland, England
Manufacturing Cement Cement is a manufactured product, made from raw materials that are found relatively easily in nature Ce-ment manufacturers have a number of sources for lime, but the most common are limestone and chalk Coral and marine shell deposits are also used as sources of lime, when available Silica, alumina, and iron oxide are found in clays, shales, slates, and cer-tain muds Some raw materials concer-tain almost all the ingredients of cement, especially marl (a compact clay), cement rock, and blast-furnace slag Industrial
Scientist George Washington Carver is best known for his work with
agricultural crops such as peanuts (National Archives)
Trang 6Global Resources Cement and concrete • 185
Data from the U.S Geological Survey, U.S Government Printing Office, 2009.
40,000,000 37,000,000 36,000,000 35,000,000 35,000,000 33,000,000 30,000,000 30,000,000 22,000,000
Metric Tons
1,500,000,000 1,250,000,000
1,000,000,000 750,000,000
500,000,000 250,000,000
Saudi Arabia
Thailand
Iran
Indonesia
Vietnam
Mexico
Germany
Pakistan
France
Egypt
Italy
Turkey
Brazil
Spain
South Korea
Russia
Japan
United States
India
China
40,000,000 47,000,000 48,000,000 48,000,000 55,000,000 56,000,000 61,000,000 67,000,000 89,100,000 175,000,000
1,450,000,000
Cement: Top Producers, 2008
Trang 7wastes such as fly ash and calcium carbonate are also
used as raw materials for cement, but not on a large
scale
Raw materials in the form of hard rock—such as
limestone, slate, and some shales—are usually
quar-ried, but they may also be mined If the limestone is of
low quality, it may need to go through a concentrating
process Softer materials such as chalk, clay, and mud
can be dug by various types of machinery, depending
on the physical setting and type of material Once
ex-tracted, the raw materials are transported to the
ce-ment manufacturing plant by truck, rail, conveyor
belt, or pipeline (when in a slurry)
At the plant, the raw materials are ground into a
fine powder and then mixed in predetermined ratios
The mixing can be done wet, semidry, or dry In the
wet process the materials are ground wet and mixed
into a slurry In the semidry process they are ground
dry, then moistened for adhesion; and in the dry
pro-cess the raw materials remain dry throughout
After mixing, the raw materials are burned in a large
rotating kiln Kilns are usually from four to eight
me-ters in diameter and from 90 to 200 meme-ters long, and
they consist of a steel cylindrical shell inclined slightly
from the horizontal The mixture is introduced at the
upper end of the kiln, and as it flows
down the incline (with the help of
gravity and the kiln’s steady rotation),
it reaches a maximum temperature
between 1,300° Celsius and 1,500°
Celsius, at which point the raw
mate-rials interact to form calcium
sili-cates The heated material exits the
kiln in the form of rough lumps or
pellets—called clinker—no larger
than 5 centimeters in diameter After
the clinker cools, the manufacturer
adds gypsum and grinds the mixture
into the fine powder known as
port-land cement
Uses of Concrete
Concrete is generally used in four
common forms: ready-mixed,
pre-cast, reinforced, and prestressed
Ready-mixed concrete is transported
to a construction site as a cement
paste and is then poured into forms
to make roadways, foundations,
driveways, floor slabs, and much
more Precast concrete—cast at a plant and then transported to the site—is used for everything from lawn ornaments to major structural elements Rein-forced concrete is created by adding steel mesh, rein-forcing bars, or any other stiffening member to the concrete before it sets Prestressed concrete, the most recently developed form, increases the strength of a beam by using reinforcing steel to keep the entire beam under compression Concrete is much stronger under compression (pushed in on itself) than under tension (pulled apart)
Brian J Nichelson
Further Reading
Gani, M S J Cement and Concrete New York: Chapman
& Hall, 1997
Lea, F M Lea’s Chemistry of Cement and Concrete 4th ed.
Edited by Peter C Hewlett New York: J Wiley, 1998
Mehta, P K., and Paulo J M Monteiro Concrete: Microstructure, Properties, and Materials 3d ed New
York: McGraw-Hill, 2005
Mindess, Sidney, J Francis Young, and David Darwin
Concrete 2d ed Upper Saddle River, N.J.: Prentice
Hall, 2003
2009
Data from the U.S Geological Survey, U.S Government Printing Office, 2009.
Ready-mix concrete 75%
Concrete products 13%
Contractors (road paving) 6%
U.S End Uses of Cement
Trang 8Neville, A M Properties of Concrete 4th ed Harlow,
Essex, England: Longman Group, 1995
Web Sites
Natural Resources Canada
Canadian Minerals Yearbook, Mineral and Metal
Commodity Reviews
http://www.nrcan-rncan.gc.ca/mms-smm/busi-indu/cmy-amc/com-eng.htm
Portland Cement Association
Cement and Concrete Basics
http://www.cement.org/basics
U.S Geological Survey
Cement: Statistics and Information
http://minerals.usgs.gov/minerals/pubs/
commodity/cement/index.html#mcs
See also: Clays; Gypsum; Lime; Limestone; Sand and
gravel; Shale; Silicates; Slate
Central Arizona Project
Category: Organizations, agencies, and programs
Date: Established September 30, 1968; substantially
completed 1993
The Central Arizona Project (CAP), a series of
pump-ing plants, dams, aqueducts, and pipelines stretchpump-ing
more than 540 kilometers, is the largest water transfer
project in the United States Drawing water from Lake
Havasu has supported agriculture in southwest
Ari-zona and made possible the growth of major cities,
while harming several species of fish and animals
downstream.
Background
As the area that makes up the southwestern United
States was settled and populated by Europeans in the
nineteenth century, the need for more water became
apparent In the early 1900’s, the Southwest looked to
the Colorado River basin as a source of water, and a
se-ries of laws and court decisions called the “Law of the
River” were established to ensure that each state was
treated equitably Decades of court cases attempted to
determine the amount of the water to which Arizona
was entitled Through the 1950’s Arizona lobbied for
authorization of a Central Arizona Project, and the
U.S secretary of the interior called for a comprehen-sive Colorado River plan to address the future water needs of seventeen Western states Passed on
Septem-ber 30, 1968, Public Law 90-537, 82 Stat 885 created
the Colorado River Basin Project and the Lower Colo-rado River Basin Development Fund, which autho-rized in turn the development of the Dixie Project in Utah and the Central Arizona Project in Arizona and New Mexico
Provisions The Central Arizona Project was designed to move 4,000 square kilometers of water from Lake Havasu, fed by the Colorado River, to agricultural lands in Maricopa, Pima, and Pinel Counties in Arizona, and
to Catron, Grant, and Hidalgo Counties in New Mex-ico Because of high costs and lower-than-expected demand, however, the New Mexico portion of the project was never built During the years of construc-tion, the economy of Arizona began to shift from agri-culture to industry, and the metropolitan areas of Phoenix, Scottsdale, and Tucson experienced rapid growth As a result, CAP waters were reallocated, so that over time more water would be designated for municipal and industrial use, and less for agriculture
Impact on Resource Use The purpose of CAP, as it was conceived in the late 1940’s, was to keep agriculture thriving without de-pleting groundwater supplies By most accounts, this goal was not realized In addition, the diversion of water from its natural course has created environmen-tal problems downstream from Lake Havasu, includ-ing the extinction of fish and wildlife, in spite of sev-eral successful conservation efforts along the project itself Dams along the project provide hydroelectric power, reducing the region’s dependence on other forms of power generation
Cynthia A Bily
Web Sites Central Arizona Project http://www.cap-az.com/
U.S Department of the Interior Bureau of Reclamation
Colorado River Basin Project: Central Arizona Project
http://www.usbr.gov/dataweb/html/crbpcap.html
Trang 9See also: Hydroenergy; Los Angeles Aqueduct; Three
Gorges Dam
Ceramics
Category: Products from resources
Ceramics are inorganic, nonmetallic materials—such
as naturally occurring silicates, oxides, nitrates,
car-bonates, chlorides, and sulfates—that are subjected to
high temperatures during their manufacture and
pro-cessing Ceramic materials are high strength but
brit-tle As a result of modern research and development,
they have multiple and varied uses.
Background
Paradoxically, ceramic science is one of the oldest yet
one of the newest technologies Much of what is
known of prehistoric humans and of the earliest
civili-zations has been learned from the pottery that was left
behind This longevity illustrates one of the greatest
assets of ceramic materials, their durability The fact
that most of the surviving pieces are fragments gives
evidence of the greatest weakness, their brittleness
The term “ceramics” is derived from the Greek
term keramos, which means “potter’s clay.” Ceramics is
defined in some dictionaries as “the art of making
things from baked clay.” “Clay” is used in describing
ceramics because it was an essential material in
tradi-tional ceramic compositions The term “baked” is
im-portant, since high temperatures are used in most
processing of ceramics Although simple, this
descrip-tion of ceramics was an accurate one until the time of
World War II In the early 1940’s, the field of materials
science, of which ceramics is a part, experienced a
push to develop new materials and processing
meth-ods Today, a more accurate present-day description
of ceramics might be “the art and science of making
and using implements and other articles that are
es-sentially composed of inorganic and nonmetallic
compounds.”
Traditional Ceramics
The ceramic industries may be grouped into several
divisions according to the products produced
Tradi-tional divisions include whitewares, refractories,
abra-sives, structural clay products, glass, cement, and
por-celain enamels Developments in the second half of
the twentieth century in the fields of nuclear physics and electronics resulted in many new ceramic prod-ucts, collectively known as technical ceramics Whitewares are materials such as clay, feldspar, whiting, and potter’s flint that fire to a white color The mineral mixtures are shaped and then partially melted at high temperatures to produce a dense hard material The term whiteware is misleading, since products in this class are produced in a wide variety of colors, depending on the amounts of impurities in the raw materials Common whitewares include earth-enware, porcelain or other tableware products as well
as casseroles and bowls, floor and wall tile, and decora-tive products such as vases and lamp bases Important commercial whitewares include laboratory ware such
as porcelain crucibles, combustion tubes, and grind-ing balls for the chemist as well as electrical porcelains such as spark plugs and insulators
A worker carries ceramic cylinders in Jungdezhen City, China, home
to what is believed to be the oldest egg-shaped ceramics kiln in the world (Zhang Wu/Xinhua/Landov)
Trang 10Refractories are structural materials manufactured
for the purpose of withstanding corrosive
high-tem-perature conditions in furnaces and process vessels
Refractories have high melting temperatures, good
hot strength, and resistance to chemical attack and
abrasion They are made from the refractory clays,
ka-olin, magnesite, chrome ore, olivine, and bauxite For
more special services, refractory products are made
from synthetic compositions such as carbides and
bor-ides Among the most important users of refractories
are the metallurgical industries, including the steel
industry
Glasses are ceramics that do not return to
crystal-line form after being melted and cooled These
noncrystalline ceramics behave as high viscosity
liq-uids They are essentially rigid at room temperature
but gradually soften and flow as the temperature is
in-creased This viscosity allows glasses to be formed by
processes that will not work for other ceramic
materi-als Glasses can be pressed into shallow shapes, drawn
or rolled into tubes and sheets, blown into hollow
shapes, or spun into fibers
Most glasses are naturally transparent to visible
light and are commonly used as windows, bottles,
lightbulbs, lenses, and optical fibers The basic
ingre-dient in most glasses is silica sand, but a wide range of
other materials can be added to produce glasses
pos-sessing a wide variety of tailored properties
Borosili-cate glasses are resistant to both chemicals and heat,
properties that make them useful both in the home
and in the laboratory Oxides of the transition metals
may be added to produce glass of almost any desired
color
The porcelain enamels are glassy coatings fused
onto metals to provide decoration and protection
from corrosion They are hard, rigid ceramics that
are electrical and thermal insulators as well as
wear-resistant and chemically inert Available in all colors,
they are found on household appliances, on
struc-tures used for food storage, in medical and hospital
equipment, and in vessels used in the production of
food and chemicals
Technical Ceramics
Research after World War II made possible a wide
vari-ety of nontraditional ceramic products based on
high-purity synthetic materials processed by special
tech-niques A few items will illustrate the scope of this
relatively new field
Ceramics have played an essential role in the
devel-opment of the computer industry The ceramic pro-cess is used in the fabrication of the complex inte-grated circuits that perform the basic operations of a computer on silicon semiconductor wafers These in-tegrated circuits are packaged on ceramic substrate materials
Oxides and carbides of uranium, plutonium, and thorium are ceramic materials that are used in the production of fuels for nuclear fission reactors High-strength concrete, often containing lead, is used in shielding structures around nuclear reactors “Hot cell” windows, made of leaded glass, maintain optical transparency when exposed to radiation Ceramic materials are also used in virtually all segments of the aerospace industry Refractory materials are used in building launching pads, rocket nozzles, and heat shields
Lasers, which came into prominence in the 1960’s, utilize the various quantum transitions that atoms and molecules undergo to produce intense beams of in-frared, visible, or ultraviolet light The original ruby laser used as its light-emitting medium a crystalline aluminum oxide ceramic that contained a small amount of chromium Another important ceramic la-ser is the yttrium aluminum garnet doped with neo-dymium to emit light in the infrared region of the spectrum As the need for more specialized materials grows, the field of ceramic science will continue to produce more and more exotic materials
Grace A Banks
Further Reading
Barsoum, M W Fundamentals of Ceramics Rev ed
Phil-adelphia: Institute of Physics, 2003
Bormans, P Ceramics Are More than Clay Alone: Raw Ma-terials, Products, Applications Cambridge, England:
Cambridge International Science, 2003
Carter, C Barry, and M Grant Norton Ceramic Mate-rials: Science and Engineering New York: Springer,
2007
Jones, J T., and M F Berard Ceramics Industrial Pro-cessing and Testing 2d ed Ames: Iowa State
Univer-sity Press, 1993
McColm, Ian J Dictionary of Ceramic Science and Engi-neering 2d ed New York: Plenum Press, 1994 Phillips, George C A Concise Introduction to Ceramics.
New York: Van Nostrand Reinhold, 1991
Sfmiya, Shigeyuki, et al., eds Handbook of Advanced
Ce-ramics 2 vols Boston: Elsevier/Academic Press,
2003