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Borax Category: Mineral and other nonliving resources Where Found Borax, the most widespread of the borate minerals, is found in the muds of alkaline lakes along with miner-als such as r

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the group There is only one naturally occurring

iso-tope, so the atomic weight of bismuth, 208.980, is

known very precisely The element is brittle and white

in appearance, with a pink tinge It occurs in a variety

of crystalline structures The metal has a high

resistiv-ity and melts at 271.4° Celsius with a boiling point of

1,564° Celsius Bismuth is unusual in that its volume

expands by about 3 percent when it solidifies from the

liquid The solid has a density of 9.9 grams per cubic

centimeter

Description, Distribution, and Forms

With a rarity akin to that of silver, bismuth is a

rela-tively minor component of the Earth’s crust It

pos-sesses some unique credentials: For example, all

ele-ments with an atomic number higher than bismuth

are radioactive It is one of three elements that is less

dense in the solid phase than in the liquid It is also

one of only a handful of metals that can be found in

nature in their elemental, or native, form Elemental

bismuth is not particularly toxic, an unusual property

in heavy metals However, inorganic bismuth

com-pounds are often extremely poisonous The relative

rarity of bismuth has minimized its environmental

im-pact

History

The earliest recorded use of bismuth was in the

mid-1400’s as an alloying material in casting type German

scientist Georgius Agricola stated that bismuth was a

metal in the same family of metals as tin and lead In

1753, French chemist Claude François Geoffroy

iden-tified bismuth as a chemical element, confirming

Agricola’s postulation

Obtaining Bismuth

In addition to the native state, bismuth occurs in ores

as an oxide, sulfide, and carbonate Because of the

scarcity of bismuth ores in the Earth’s crust, it is not

mined directly but is typically produced commercially

by extracting and refining it from the anode sludge

generated during the electrochemical production of

other metals Annual world production of bismuth is

on the order of 6,000 metric tons

Uses of Bismuth

Functioning as a metallurgical additive remains one

of the major uses of bismuth In particular, fusible

al-loys, which have low melting points and are

particu-larly useful in fire detection, often incorporate

bis-muth The other major use of bismuth is in the pharmaceutical industry, where it is used to treat indi-gestion and as an antisyphilitic agent

Craig B Lagrone

Web Sites Natural Resources Canada Canadian Minerals Yearbook, 2005: Bismuth http://www.nrcan-rncan.gc.ca/mms-smm/busi-indu/cmy-amc/content/2005/14.pdf U.S Geological Survey

Minerals Information: Bismuth Statistics and Information

http://minerals.usgs.gov/minerals/pubs/

commodity/bismuth/

See also: Alloys; Antimony; Belgium; Canada; China; Germany; Metals and metallurgy; Mexico; Native ele-ments

Borax

Category: Mineral and other nonliving resources

Where Found Borax, the most widespread of the borate minerals, is found in the muds of alkaline lakes along with miner-als such as rock salt, sulfates, carbonates, and other borates Large deposits are found in the western United States, South America, Turkey, and Tibet

Primary Uses Borax is essential to many industrial processes, nota-bly the manufacture of glass and enamel Other major users include the ceramics, agricultural, chemical, cleanser, and pharmaceutical industries

Technical Definition Borax (also known as sodium borate decahydrate, so-dium pyroborate, birax, soso-dium tetraborate decahy-drate, and sodium biborate) is an ore of boron with the chemical formula Na2(B4O5)(OH)4C8(H2O) Its average molecular weight is 381.4, composed of 12.06 percent sodium, 11.34 percent boron, 5.29 percent hydrogen, and 71.32 percent oxygen Borax may be colorless, white, yellowish, or gray Its hardness on the Mohs scale is 2 to 2.5 Borax occurs as prismatic

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tals or as a white powder Its specific gravity is 1.69 to

1.72 It is slightly soluble in cold water, very soluble in

hot water, and insoluble in acids It has a melting

point of 75° Celsius and a boiling point of 320°

Cel-sius When heated above 740° Celsius, it fuses to form

a “borax bead.”

Description, Distribution, and Forms

Borax is a member of a group of compounds known as

borates, minerals that contain the element boron

Bo-rax is an evaporite found in dried-up lakes and playas

(desert basins) A sedimentary deposit that forms in

arid regions, borax derives its name from b nraq, an

Arabic word meaning “white” that was used to refer to

the substance This widespread borate mineral is

found in association with other evaporites, including

rock salt, sulfates, carbonates, and other borates

Bo-rax occurs as a white powder on the soil surface or in

masses of short, prismatic crystals embedded in the

muds of alkaline lakes Borax is also present in many

mineral waters and salt lakes It commonly loses water

to form tincalconite (Na2B4O7C5H2O)

The most widespread of the borate minerals, borax

is notably found in arid regions near the sites of

Plio-cene lakes, where hot springs and volcanic activity are

believed to be the source of the boron-rich brines that

fed these lakes Upon evaporation (hence its

classifi-cation as an “evaporite”), deposits of borax and other

borates formed Buried accumulations of borax are

often found in the centers of dried-up alkaline lakes,

with outcrops of calcium and calcium-sodium boron minerals marking the periphery of the lake area

In the United States, there are large deposits of bo-rax in California, Nevada, and Oregon Almost half the world’s refined borates come from Southern Cali-fornia In California’s Mojave Desert, Searles Lake in San Bernardino County and Kramer in Kern County are two major borax deposits At Searles Lake, borax is the most abundant of the four borate-bearing miner-als found there Borax is miner-also the most abundant min-eral in the Kramer borate deposit, the largest known reserve of boron compounds in the world Other ma-jor deposits are located in Tibet, Argentina, and Tur-key In Argentina, for example, borax is mined at Salt Province (more than 4,000 meters above sea level) and at Tincalayu, Sijes, and the lakebeds at Salar Cauchari and Salar Diablillos

History Borax has been used commercially for thousands of years, with the earliest confirmed use in ceramic glazes traced to the tenth century c.e The early Chi-nese, Persians, Arabs, and Babylonians knew of the mineral and its properties It was introduced to Eu-rope by Marco Polo about 1275 c.e EuEu-rope’s earliest source for the mineral was Tibet, where tincal (crude borax) was used for making glazes and soldering gold

By the 1800’s, borax had gained widespread use in glassblowing and gold refining

Italy, Tibet, and Chile were the principal world

The mineral borax (USGS)

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pliers of borate minerals until extensive borate

depos-its were discovered in California and Nevada An 1864

report on borax crystals found in the muds of Borax

Lake in Lake County, California, was the first to

pub-lish the discovery of the mineral in the western United

States In the early 1880’s, borax was also found in

Death Valley The twenty-mule teams that hauled the

material mined from Death Valley across the

Califor-nia desert to the railroad junction at Mojave became a

widely recognized symbol for the borax industry in

the United States

Obtaining Borax

Borax may be obtained directly from dry lake beds

on which the evaporite has formed, from open-pit

borate mines, or from drilling for underground

mines At Searles Lake, borax is recovered by

frac-tional crystallization from lake brine Borax may also

be made from other borate ores, including as kernite

(Na2B4O7C4H2O), colemanite (Ca2B6O11C5H2O), and

ulexite (NaCaB5O9C8H2O), or by the reaction of boric

acid with soda Crystalline borax readily effloresces—

that is, it loses its water of crystallization to form a

white powder—particularly upon heating

Deposits of borate ores are found underground by

drilling and then blasting to remove the sandstone

that overlies the ore deposit (Eventually such sites

will turn into open-pit mining operations.) Huge

shovels remove the rubble to get at the ore, which is

then crushed and refined by mixing the crushed ore

with hot water Borates dissolve in the water, leaving

the unwanted debris in solid form; the debris-free

so-lution can then be pumped into tanks, which cool the

solution so that the borates can crystallize and then be

removed for drying, storage, and further processing

Uses of Borax

The uses of borax are based on its many functional

properties, which include metabolizing effects,

bleaching effects, buffering effects, dispersing

ef-fects, vitrifying efef-fects, inhibiting efef-fects,

flame-proof-ing effects, and neutron-absorbflame-proof-ing effects Borax has

been used for centuries in making glass and enamels,

and it has become an essential part of many other

in-dustrial processes It is used in the manufacture of

glass (notably heat-resistant and optical varieties),

porcelain enamels, ceramics, shellacs, and glazes It is

a component of agricultural chemicals such as

fertiliz-ers and herbicides It is used in the manufacture of

chemicals, soaps, starches, adhesives, cosmetics,

phar-maceuticals, insulation material, and fire retardants

In the textile industry, borax is used in fixing mor-dants on textiles, tanning leather, and spinning silk It

is effective as a mild antiseptic, a water softener, and a food preservative, although it is toxic if consumed in large doses It is added to antifreeze to inhibit corro-sion and used as a flux for soldering and welding Bo-rax is also a source of elemental boron, which is used

as a deoxidizer and alloy in nonferrous metals, a neu-tron absorber in shields for atomic reactors, and a component of motor fuel and rocket fuel

Borax also plays an important role in chemical analysis Borax fused by heating is used in the “bead test,” a form of chemical analysis used in the identifi-cation of certain metals Powdered borax is heated in

a platinum-wire loop over a flame until the mineral fuses to form a clear glassy bead The borax bead is then dipped into a small quantity of the metallic oxide

to be identified Upon reheating over the flame, the bead reacts chemically with the metallic oxide to form

a metal borate, which gives the bead a characteristic color that helps identify the metal For example, co-balt compounds yield a deep blue bead, and manga-nese compounds produce a violet one

Perhaps the most familiar use of borax is as a cleansing agent Borax combined with hot water will create hydrogen peroxide; it lowers the acidity of water, which facilitates the bleaching action of other cleansers Borax also acts as both a disinfectant and a pesticide by blocking the biochemistry of both macro-and microorganisms, such as bacteria, fungi, fleas, roaches, ants, and other pests These same properties, however, mean that people must avoid overexposure

to borax lest it prove toxic to the kidneys and other or-gans (a typical symptom is red and peeling skin) Finally, borates such as borax enhance the power of other cleansing chemicals by bonding with other compounds in such a way that it maintains the even dispersal of these cleansing agents in solution, thereby maximizing their surface area and hence their effectiveness

Karen N Kähler

Further Reading Chatterjee, Kaulir Kisor “Borax and Related

Min-erals.” In Uses of Industrial Minerals, Rocks, and Fresh-water New York: Nova Science, 2009.

Garrett, Donald E “Borax.” In Borates: Handbook of Deposits, Processing, Properties, and Use San Diego,

Calif.: Academic Press, 1998

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Grew, E S., and L M Anovitz, eds Boron: Mineralogy,

Petrology, and Geochemistry Washington, D.C.:

Min-eralogical Society of America, 1996

Spears, John Randolph Illustrated Sketches of Death

Val-ley and Other Borax Deserts of the Pacific Coast Edited

by Douglas Steeples Chicago: Rand McNally, 1892

Reprint Baltimore: Johns Hopkins University

Press, 2001

Travis, N J., and E J Cocks The Tincal Trail: A History

of Borax London: Harrap, 1984.

U.S Borax and Chemical Corporation The Story of

Bo-rax 2d ed Los Angeles: Author, 1979.

Web Sites

U.S Geological Survey

Boron: Statistics and Information

http://minerals.usgs.gov/minerals/pubs/

commodity/boron/index.html#myb

U.S Geological Survey

Death Valley Geology Field Trip: All About Death

Valley Borax

http://geomaps.wr.usgs.gov/parks/deva/

fthar4.html#basics

U.S Geological Survey

Death Valley Geology Field Trip: Harmony Borax

Works

http://geomaps.wr.usgs.gov/parks/deva/

fthar1.html

See also: Boron; Ceramics; Evaporites; Fertilizers;

Glass; Sedimentary processes, rocks, and mineral

de-posits

Boron

Category: Mineral and other nonliving resources

Where Found

Boron is not abundant There are about 9 parts per

million of boron in the Earth’s crust, which makes

bo-ron the thirty-eighth element in abundance

Com-mercially valuable deposits are rare, but the deposits

in California and Turkey are very large

Primary Uses

The main uses of boron are in heat-resistant glasses,

glass wool, fiberglass, and porcelain enamels It is also

used in detergents, soaps, cleaners and cosmetics, and synthetic herbicides and fertilizers

Technical Definition Boron (abbreviated B), atomic number 5, belongs to Group III of the periodic table of the elements and re-sembles silicon in many of its chemical properties It has two naturally occurring isotopes: boron 10 (19.8 percent) and boron 11 (80.2 percent) Boron exists in several allotropic forms The crystalline forms are a dark red color, and the powdered forms are black The most stable form has a melting point of 2,180° Celsius, a boiling point of 3,650° Celsius, and a density

of 2.35 grams per cubic centimeter

Description, Distribution, and Forms Boron is found primarily in dried lake beds in Califor-nia and Turkey Isolated deposits also occur in China and numerous South American countries The major deposits of borate minerals occur in areas of former volcanic activity and in association with the waters of former hot springs Searles Lake in southeastern Cali-fornia has layers that are 1.6 percent and 2.0 percent borax Boron is found naturally only as borate miner-als such as ulexite [B5O6(OH)6]C5H2O and borax

Na2[B4O5(OH)4]C8H2O or as borosilicates Boron is more concentrated in plants than in animal tissue The use of borax laundry detergents, the burning

of coal, and mining have filled the atmosphere and ir-rigation waters in some areas with boron compounds Although there have been some reports of damage to grazing animals, boron is not considered a danger un-less it is in the form of a pesticide, an herbicide, or fi-berglass, which is carcinogenic

Boron is an essential element only for higher plants The amount needed by those plants and the amount that is toxic are only a few parts per million apart, so toxicity effects can easily occur Boron is not known to be necessary to animal life, and it is quickly excreted in urine In high concentrations toxicity ef-fects can occur, especially in the brain, before all the boron is excreted

History Borax was used in ancient times to make glazes and hard glass and was traded by the Babylonians four thousand years ago However it was not isolated in pure enough form to be characterized as an element until 1808 The isolation was achieved by Joseph-Louis Gay-Lussac and Joseph-Louis-Jacques Thénard and

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dependently by Sir Humphry Davy.

Boron was isolated from boric acid

through a heated reaction with

po-tassium The first pure (95 to 98

per-cent) boron was isolated by Henri

Moissan in 1892

Obtaining Boron

The four main methods of isolating

boron are reduction by metals at high

temperature, electrolytic reduction

of fused borates or

tetrafluoro-borates, reduction by hydrogen of

volatile compounds, and thermal

de-composition of hydrides or halides

About 3.8 million metric tons are

produced annually Boron will form

compounds with almost every

ele-ment except the noble gases and a

few of the heavier metals It is said to

have the most diverse chemistry next

to carbon and is characterized as a

metalloid by some properties and as a

nonmetal by others This rich

chem-istry leads to a wide range of uses

Uses of Boron

One of the most common uses of

bo-ron is in the production of

borosili-cate glass (Pyrex glass) Borosiliborosili-cate glass does not

ex-pand or contract as much as regular glass, so it does

not break with temperature changes as easily as

regu-lar glass Pyrex cooking vessels and most laboratory

glassware are made of borosilicate glass Boron

im-proves the tempering of steel better than other

alloy-ing elements Boron carbide is one of the hardest

sub-stances known and is used in both abrasive and

abrasion-resistant applications as well as in nuclear

shielding Lighter elements are better shields for

neu-trons than are heavy elements such as lead Boron-10

neutron capture therapy is one of the few ways to treat

a nonoperable brain tumor The boron-10 isotope

collects in the tumor When a neutron hits the boron,

a reaction produces radiation to kill the cancer cells

Borate is used in the production of glass fiber

ther-mal insulation, the principal insulating material used

in construction Another glass application is as a thin,

glassy coating fused onto ceramics and metals

Exam-ples include wall and floor tiles, tableware, bone china,

porcelain, washing machines, pots, and architectural

paneling Boron is also used in algicides, fertilizers, herbicides, insecticides, and water treatments Sodium polyborate can be used to control fleas, and boric acid has been used in the control of cockroaches Fire re-tardants include zinc borate, ammonium pentaborate, and boric oxide These are used in chipboard, cellu-lose insulation, and cotton mattresses Boron com-pounds are also used in metallurgical processes such

as fluxes and shielding slags and in electroplating baths Borax is a water-softening agent, while boron

is used as a bleaching agent Perborates in water form hydrogen peroxide to act as a bleach Boron is also used in cosmetics, pharmaceutical and hygienic products, pH adjusters, emulsifiers, stabilizers, and buffers

C Alton Hassell

Further Reading

Adriano, Domy C “Boron.” In Trace Elements in Terres-trial Environments: Biogeochemistry, Bioavailability, and Risks of Metals 2d ed New York: Springer, 2001.

Glass 34%

Fire retardants 3% Soaps & detergents 3%

Textile-grade glass fibers 13%

Undistributed 34.5%

Other 12.5%

Source:

Historical Statistics for Mineral and Material Commodities in the United States

Note:

U.S Geological Survey, 2005, boron statistics, in T D Kelly and G R Matos, comps.,

, U.S Geological Survey Data Series 140 Available online at http://pubs.usgs.gov/ds/2005/140/.

“Undistributed” reflects trade, stocks changes, and data not reported by end use “Other” includes agriculture, enamels, frits, glazes, metallurgy, and nuclear applications.

U.S End Uses of Boron

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Greenwood, N N., and A Earnshaw “Boron.” In

Chemistry of the Elements 2d ed Boston:

Butter-worth-Heinemann, 1997

Grew, E S., and L M Anovitz, eds Boron: Mineralogy,

Petrology, and Geochemistry Washington, D.C.:

Min-eralogical Society of America, 1996

Housecroft, Catherine E Cluster Molecules of the P-Block

Elements New York: Oxford University Press, 1994.

Kogel, Jessica Elzea, et al., eds “Boron and Borates.”

In Industrial Minerals and Rocks: Commodities,

Mar-kets, and Uses 7th ed Littleton, Colo.: Society for

Mining, Metallurgy, and Exploration, 2006

Krebs, Robert E The History and Use of Our Earth’s

Chemical Elements: A Reference Guide Illustrations by

Rae Déjur 2d ed Westport, Conn.: Greenwood

Press, 2006

Massey, A G “Group 13: Boron, Aluminum, Gallium,

Indium, and Thallium.” In Main Group Chemistry.

2d ed New York: Wiley, 2000

Smallwood, C Boron Geneva, Switzerland: World

Health Organization, 1998

Weeks, Mary Elvira Discovery of the Elements: Collected

Reprints of a Series of Articles Published in the “Journal

of Chemical Education.” Kila, Mont.: Kessinger, 2003.

Web Site

U.S Geological Survey

Boron: Statistics and Information

http://minerals.usgs.gov/minerals/pubs/

commodity/boron/index.html#myb

See also: Borax; China; Fiberglass; Glass; Herbicides;

Pesticides and pest control; Turkey

Botany

Category: Scientific disciplines

Any topic dealing with plants, from the level of their

cellular biology to the level of their economic

produc-tion, is considered part of the field of botany.

Definition

Botany is an old branch of science that began with

early humankind’s interest in the plants around them

In modern society, plant science extends beyond that

interest to cutting-edge biotechnology

Overview The origins of botany, beginning around 5000 b.c.e., are rooted in human attempts to improve their lot by raising better food crops This practical effort devel-oped into intellectual curiosity about plants in gen-eral, and the science of botany was born Some of the earliest botanical records are included with the writ-ings of Greek philosophers, who were often physi-cians and who used plant materials as curative agents

In the second century b.c.e., Aristotle had a botanical garden and an associated library

As more details became known about plants and their function, particularly after the discovery of the microscope, the growing body of knowledge became too great for general understanding, so a number of subdisciplines arose Plant anatomy is concerned chiefly with the internal structure of plants Plant physiology delves into the living functions of plants Plant taxonomy has as its interest the discovery and systematic classification of plants Plant geography deals with the global distribution of plants Plant ecol-ogy studies the interactions between plants and their surroundings Plant morphology studies the form and structure of plants Plant genetics attempts to un-derstand and work with the way that plant traits are in-herited Plant cytology, often called cell biology, is the science of cell structure and function Economic any, which traces its interest back to the origins of bot-any, studies those plants that play important economic roles (these include major crops such as wheat, rice, corn, and cotton) Ethnobotany is a rapidly developing subarea in which scientists communicate with indige-nous peoples to explore the knowledge that exists as a part of their folk medicine Several new drugs and the promise of others have developed from this search

At the forefront of modern botany is the field of ge-netic engineering, including the cloning of organ-isms New or better crops have long been developed

by the technique of cross-breeding, but genetic engi-neering offers a much more direct course Using its techniques scientists can introduce a gene carrying a desirable trait directly from one organism to another

In this way scientists hope to protect crops from frost damage, to inhibit the growth of weeds, to provide in-sect repulsion as a part of the plant’s own system, and

to increase the yield of food and fiber crops

The role that plants play in the energy system of the Earth (and may someday play in space stations or other closed systems) is also a major area of study Plants, through photosynthesis, convert sunlight into

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other useful forms of energy upon which humans

have become dependent During the same process

carbon dioxide is removed from the air, and oxygen is

delivered Optimization of this process and

discover-ing new applications for it are goals for botanists

Kenneth H Brown

See also: Agricultural products; Agriculture

indus-try; Biotechnology; Farmland; Grasslands; Green

Rev-olution; Horticulture; Plant domestication and

breeding; Plants as a medical resource; Rain forests

Brass

Category: Products from resources

Brass, a metal alloy, has numerous practical

applica-tions because of its ease of fabrication, corrosion

resis-tance, and attractive appearance It is used in

hard-ware items, electrical fixtures, inexpensive jewelry, and

metal decorations.

Definition

Brass is a copper-based alloy consisting mainly of

cop-per and zinc It can also be mixed with lead, tin,

nickel, aluminum, iron, manganese, arsenic,

anti-mony, and phosphorus

Overview

The first brass was probably made accidentally by

melting copper ore that contained a small amount of

zinc The earliest known brass object was made by the

Romans about 20 b.c.e By the eleventh century, brass

was made on a large scale throughout Western

Eu-rope, and brass coins, kettles, and ornaments were

manufactured In the United States, the brass

indus-try developed mainly in Connecticut; at first it was

de-voted primarily to making buttons

The color and composition of brass vary with the

amount of copper, which ranges from 55 percent to

95 percent When the alloy contains about 70 percent

copper, it has a golden-yellow color (such brass is

called yellow brass or cartridge brass) When it

con-tains 80 percent or more copper, it has a reddish

cop-per color (red brass) When zinc is added, brass

be-comes stronger and tougher The ductility (ability to

be stretched) improves with increasing amounts of

zinc up to about 30 percent The best combination of

strength and ductility occurs in yellow brass

Lead is added to improve machinability (ease of cutting) Tin and nickel are often added to increase the alloy’s resistance to corrosion and wear Nickel may be added to obtain a silvery-white color that makes the alloy a more suitable base for silver plating Aluminum is useful in improving the corrosion resis-tance of brass in turbulent or fast-moving water The strength of brass is also improved with the addition of iron, manganese, nickel, and aluminum

The first step in making brass is to melt copper in

an electric furnace Solid pieces of zinc are then added to the melted copper, and the zinc melts rap-idly After the copper and zinc have been melted and thoroughly mixed, the brass is ready for pouring It is typically made into blocklike forms (ingots) or small bars (billets), making it easy to work with the brass or

to store it When it is time to make a particular piece, the bars are placed in a furnace, and after they have been reheated to the proper temperature for work-ing, the brass can be rolled and formed into the de-sired shape A milling machine removes surface im-perfections, and the brass is then cold rolled Brass is used in making automobile components, ship propellers, refrigeration and air-conditioning equipment (condenser tubes), decorative elements (architectural trim), plumbing hardware, camera parts, valves, screws, buttons, keys, watch and clock parts, and coins Some brasses, mainly containing tin and manganese, are called bronzes, which are used to make statues, bells, vases, cups, and a variety of orna-ments

Alvin K Benson

See also: Alloys; Bronze; Copper; Metals and metal-lurgy; Tin; Zinc

Brazil

Categories: Countries; government and resources

Brazil’s metallic mineral resources, especially iron and aluminum, underpin a strong industrial sector and are high-value exports Brazil is the second most impor-tant producer of iron ore in the world after China and

is a significant gold-producing nation It ranks tenth

as a diamond producer and has the second largest crude oil reserves in South America after Venezuela.

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Brazil’s forest industry contributes about 4 percent to

the nation’s gross domestic product (GDP) and

ac-counts for 7 percent of its exports, providing

employ-ment for two million people Brazil is in the top five

among world nations in relation to area of land used

for agriculture and ranks in the top three as an

ex-porter of agricultural produce.

The Country

Brazil is the fifth largest country in the world, with an

area of 8.5 million square kilometers It is the largest

and most geographically diverse country in South

America, occupying most of the northeast of the

con-tinent, and has a coastline of about 7,490 kilometers

along the Atlantic Ocean The country has a tropical

or semitropical climate, with diverse natural

vegeta-tion dominated by tropical rain forests, dry forests,

and savannas Brazil is generally low lying, with

eleva-tions between 200 and 800 meters Higher elevaeleva-tions,

of about 1,200 meters, are limited to the south Brazil

has a drainage system dominated by the Amazon

River, which originates in the Andes Mountains and

has created an extensive lowland floodplain area in

the northern part of the country

Brazil’s economy is growing rapidly It is the largest

in South America and the eighth largest in the world

Its resource base has not been fully ascertained, but

key resources so far exploited include iron ore, in the

states of Minas Gerais (in the south-central region)

and Pará (in the north); oil, mostly in offshore fields;

timber, from extensive natural forests and

planta-tions; and precious stones in various locations

Agri-culture is most important in the south, where most of

Brazil’s commercial crops are produced and where

most cattle ranches are located In the northeast

and in the Amazon basin, agriculture tends to be

subsistent and may involve shifting cultivation

Metals

Brazil’s iron ore accounts for about 5 percent of its

to-tal exports, with approximately half going to China,

Japan, and Germany Reserves of iron ore are

esti-mated at almost 20 billion metric tons, about 7

per-cent of the world total, ranking Brazil sixth in the

world However, in terms of iron content the reserves

are the best in the world Iron ore accounts for almost

58 percent of the value of Brazil’s mineral production

There are thirty-seven companies extracting iron and

fifty-nine mines, all of which are open cast The

Brazil-ian mining company Vale S.A (formerly Companhia

Vale do Rio Doce) produces more than 60 percent of the iron ore in Brazil and about 15 percent of world iron ore, making it the world’s largest producer of iron ore It is also the world’s second largest producer

of nickel and is involved in the mining of bauxite, manganese, copper, kaolin, and potash

Approximately 70 percent of Brazil’s iron reserves are in the state of Minas Gerais and 25 percent are in Pará The ores occur as hematite (ferric oxide), and,

in 2007, more than 300 million metric tons were pro-duced The Carajás Mine in Pará is the world’s largest iron-ore mine Owned by Vale S.A., it is an open-cast mine with reserves of 1.4 billion metric tons, plus de-posits of manganese, copper, tin, cobalt, and alumi-num In general, the Carajás District is exceptionally rich in minerals and has iron-ore reserves estimated at

16 billion metric tons Other base metals produced in substantial quantities include manganese and alumi-num, of which Brazil accounts for 25 percent and 12.4 percent, respectively, of world production

Gold, tantalum, and niobium are also produced in Brazil The late 1980’s were the period of peak gold production for Brazil Reserves comprise almost 2 percent of the world total and are found mainly in Minas Gerais and Pará In 2006, Brazil produced 40 metric tons; the chief mining company was Anglogold Ashanti Mineração Ltda., which contributed about 7.7 metric tons Most was used by the jewelry industry About 32 metric tons were exported; Japan was the major recipient

Tantalum and niobium are relatively rare metals, but Brazil is a major source of both Tantalum is extracted from tantalite and colombite mined from one site, Pitinga/Mineração Taboca, in the state of Amazonas It is used for the manufacture of electro-lytic capacitors Brazil provides roughly 20 percent of the world total, making it the second largest producer behind Australia This mine also produces tin, ura-nium, and niobium The latter is used in forensic sci-ence and to make alloys with iron to improve the strength of piping, among other uses It is found in four states, of which Minas Gerais contains 73 percent

of the reserves, and is extracted from pyrochlore (bium oxide) Brazil produces most of the world’s nio-bium, which amounted to about 57,000 metric tons in 2008

Fossil Fuels Brazil has substantial reserves of coal, oil, and natural gas Brazil’s energy production is as follows: 38

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138 • Brazil Global Resources

Brazil: Resources at a Glance

Official name: Federative Republic of Brazil Government: Federal republic

Capital city: Brasília Area: 3,287,851 mi2; 8,514,877 km2

Population (2009 est.): 198,739,269 Language: Portuguese

Monetary unit: real (BRL)

Economic summary:

GDP composition by sector (2008 est.): agriculture, 6.7%; industry, 28%; services, 65.3%

Natural resources: bauxite, gold, iron ore, manganese, nickel, niobium, phosphates, platinum, tin, tantalum,

uranium, petroleum, hydropower, timber, precious and semiprecious stones, graphite

Land use (2005): arable land, 6.93%; permanent crops, 0.89%; other, 92.18%

Industries: textiles, shoes, chemicals, cement, lumber, iron ore, tin, steel, aircraft, motor vehicles and parts, other

machinery and equipment

Agricultural products: coffee, soybeans, wheat, rice, corn, sugarcane, cocoa, citrus, beef

Exports (2008 est.): $197.9 billion

Commodities exported: transport equipment, iron ore, soybeans, footwear, coffee, automobiles

Imports (2008 est.): $173.1 billion

Commodities imported: machinery, electrical and transport equipment, chemical products, oil, automotive parts,

electronics

Labor force (2008 est.): 93.65 million

Labor force by occupation (2003 est.): agriculture, 20%; industry, 14%; services, 66%

Energy resources:

Electricity production (2007 est.): 437.3 billion kWh

Electricity consumption (2007 est.): 402.2 billion kWh

Electricity exports (2007 est.): 2.034 billion kWh

Electricity imports (2007 est.): 40.47 billion kWh (supplied by Paraguay)

Natural gas production (2007 est.): 9.8 billion m3

Natural gas consumption (2007 est.): 19.8 billion m3

Natural gas exports (2007 est.): 0 m3

Natural gas imports (2007 est.): 10 billion m3

Natural gas proved reserves ( Jan 2008 est.): 347.7 billion m3

Oil production (2007 est.): 2.277 million bbl/day Oil imports (2005): 648,800 bbl/day

Oil proved reserves ( Jan 2008 est.): 12.35 billion bbl Source: Data from The World Factbook 2009 Washington, D.C.: Central Intelligence Agency, 2009.

Notes: Data are the most recent tracked by the CIA Values are given in U.S dollars Abbreviations: bbl/day = barrels per day;

GDP = gross domestic product; km 2 = square kilometers; kWh = kilowatt-hours; m 3 = cubic meters; mi 2 = square miles.

Brasília

Brazil

Colombia

Argentina

Bolivia

Peru

Paraguay

Uruguay

Venezuela

A t l a n t i c

O c e a n

P a c i f i c

O c e a n

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cent from oil, 9.6 percent from natural gas, 6

per-cent from coal, and the remainder comprising

hydro-electric power, ethanol from sugarcane, and nuclear

power Globally, its coal reserves are not extensive (930

million metric tons compared to 271,000 million

met-ric tons produced by the United States) More than 50

percent of Brazil’s coal comes from the state of Rio

Grande do Sul, while 46 percent comes from Santa

Catarina and 1.3 percent comes from Paraná, Brazil’s

southernmost states This coal is used within Brazil

In relation to global oil reserves and production,

Brazil is ranked sixteenth and fourteenth,

respec-tively, and has about 1 percent of estimated global

re-serves In 2006, production was about 90 million

met-ric tons, an annual increase of more than 5 percent

that was mainly due to raised output from offshore

oil fields, notably the Campos and Santos basins

lo-cated off the southeast coast of the state of Rio de

Ja-neiro These fields contain the vast majority of Brazil’s

proven reserves Such increases have made Brazil

al-most self sufficient in oil, though light crude is still

im-ported because of refinery capacity The state-owned

company Petrobras controls about 95 percent of crude

oil production, which amounts to about 2.277 million

barrels per day Brazil ranks fortieth for natural gas

re-serves and thirty-third for production It produced

about 9.8 billion cubic meters in 2007, mostly from

offshore fields, all of which is consumed within Brazil

Other Energy Resources

Most of Brazil’s remaining energy needs are met by

hydroelectric power and ethanol, a biofuel made from

sugarcane Brazil is the third largest producer of

hydropower in the world Approximately 27 percent

of its potential could be exploited economically

Al-though just less than half has been realized, it

pro-vides about 84 percent of Brazil’s electricity Much of

this has been made possible by the vast Itaipu Dam

constructed in the late 1980’s, which Brazil shares

with neighboring Paraguay Other large-scale schemes

include the Tucurui Dam on the Tocantins River in

Pará and Boa Esperança on the Parnaíba River near

the city of Guadalupe Another dam, the Belo Monte,

is proposed on the Xingu River, also in the state of

Pará However, this project is controversial because of

the adverse environmental and social impacts

associ-ated with such large-scale projects Many small-scale

dams also contribute to Brazil’s hydropower capacity

Although Brazil is not the only nation to develop

biofuels, it is unique insofar as ethanol became

avail-able as a fuel in the 1920’s Ethanol rose to promi-nence in the mid-1970’s, when world oil crises prompted the Brazilian government to decree that all automobiles had to operate on a fuel that contained

at least 10 percent ethanol Brazil is a leading pro-ducer of ethanol and user of ethanol as a fuel; it has been described as having the world’s first sustainable biofuel economy In 2006, Brazil was responsible for

33 percent of the global production of ethanol and for 42 percent of the ethanol used as fuel Ethanol is produced by the fermentation of sugarcane, one of Brazil’s major crops, which was introduced by Europe-ans in the sixteenth century In 2007, Brazil produced

514 million metric tons of sugarcane from 6.7 million hectares, mostly in the central/southern region Be-tween 40 and 50 percent is used for ethanol fuel and the rest for sugar, which is a major export The sucrose content is the raw material for ethanol, which is pro-duced at more than 370 processing plants, mostly in Brazil’s southern and coastal states Brazil has auto-mobiles that can run on any combination of petro-leum/ethanol-based fuels, though environmental im-plications remain because sugarcane plantations rely

on irrigation, mechanization, and other techniques that affect the environment

Agricultural Resources Brazil is a world leader in the export of agricultural products, and the agricultural sector contributes more than 5 percent to the nation’s gross domestic product (GDP) Of Brazil’s total land area (almost 8.5 million square kilometers), about 2.6 million square kilome-ters are used for crop production Apart from sugar-cane, soybeans, maize, rice, coffee, wheat, and cotton are significant economic crops Beef production is also important in Brazil; the country has extensive cat-tle ranches in the hinterland of São Paulo According

to statistics compiled by the Food and Agriculture Or-ganization, soybeans and maize are grown on 20.6 and 13.8 million hectares, respectively, crops that pro-duce about 58 and 50 million metric tons, respec-tively Soybean cultivation has increased significantly but is no longer dominant in São Paulo’s hinterland, having expanded into central western and northeast-ern regions (where its and sugarcane’s spread occurs

at the expense of savanna and forest ecosystems) This expansion is partly associated with increased demand for biofuels Brazil is the world’s biggest exporter of soybeans, sending 25 million metric tons to markets

in Asia and Europe

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