Solution manual fundamentals of physics extended, 8th editionch18

Since a volume is the product of three lengths, the change in volume due to a temperature change ∆T is given by ∆V = 3αV ∆T, where V is the original volume and α is the coefficient of li

1 We take p3 to be 80 kPa for both thermometers According to Fig 18-6, the nitrogen thermometer gives 373.35 K for the boiling point of water Use Eq 18-5 to compute the pressure:

(a) The difference is pN−pH=0.056 kPa ≈0.06 kPa

(b) The pressure in the nitrogen thermometer is higher than the pressure in the hydrogen thermometer

2 From Eq 18-6, we see that the limiting value of the pressure ratio is the same as the absolute temperature ratio: (373.15 K)/(273.16 K) = 1.366

3 Let T L be the temperature and p L be the pressure in the left-hand thermometer

Similarly, let T R be the temperature and p R be the pressure in the right-hand thermometer According to the problem statement, the pressure is the same in the two thermometers

when they are both at the triple point of water We take this pressure to be p3 Writing Eq

18-5 for each thermometer,

First, we take T L = 373.125 K (the boiling point of water) and T R = 273.16 K (the triple

point of water) Then, p L – p R = 120 torr We solve

3

120 torr373.125 K 273.16 K (273.16 K)

p

for p3 The result is p3 = 328 torr Now, we let T L = 273.16 K (the triple point of water)

and T R be the unknown temperature The pressure difference is p L – p R = 90.0 torr Solving

90.0 torr273.16 K (273.16 K)

4 (a) Let the reading on the Celsius scale be x and the reading on the Fahrenheit scale be

5 (a) Let the reading on the Celsius scale be x and the reading on the Fahrenheit scale be

y Then 9

y= x + For x = –71°C, this gives y = –96°F

(b) The relationship between y and x may be inverted to yield 5

x= y− Thus, for y

= 134 we find x≈ 56.7 on the Celsius scale

6 We assume scales X and Y are linearly related in the sense that reading x is related to reading y by a linear relationship y = mx + b We determine the constants m and b by

solving the simultaneous equations:

which yield the solutions m = 40.00/500.0 = 8.000 × 10–2

and b = –60.00 With these values, we find x for y = 50.00:

7 We assume scale X is a linear scale in the sense that if its reading is x then it is related

to a reading y on the Kelvin scale by a linear relationship y = mx + b We determine the constants m and b by solving the simultaneous equations:

8 (a) The coefficient of linear expansion α for the alloy is

510.015cm 10.000 cm

9 The new diameter is

6

10 The change in length for the aluminum pole is

6

0αA1 T (33m)(23 10 / C )(15 C) = 0.011m.−

11 Since a volume is the product of three lengths, the change in volume due to a temperature change ∆T is given by ∆V = 3αV ∆T, where V is the original volume and α is

the coefficient of linear expansion See Eq 18-11 Since V = (4 π/3)R3

12 The volume at 30°C is given by

3

' (1 ) (1 3 ) (50.00 cm )[1 3(29.00 10 / C ) (30.00 C 60.00 C)]49.87 cm

=

where we have used β = 3α

13 The increase in the surface area of the brass cube (which has six faces), which had

side length is L at 20°, is

b 2

14 The change in length for the section of the steel ruler between its 20.05 cm mark and 20.11 cm mark is

23 10 / C

L T

15 If V c is the original volume of the cup, αa is the coefficient of linear expansion of aluminum, and ∆T is the temperature increase, then the change in the volume of the cup

is ∆V c = 3αa Vc ∆T See Eq 18-11 If β is the coefficient of volume expansion for glycerin then the change in the volume of glycerin is ∆Vg = βVc ∆T Note that the original

volume of glycerin is the same as the original volume of the cup The volume of glycerin that spills is

16 (a) We use ρ = m/V and

(b) Since α = ∆L/(L∆T ) = (0.23 × 10–2

) / (100°C – 0.0°C) = 23 × 10–6

/C°, the metal is aluminum (using Table 18-2)

17 After the change in temperature the diameter of the steel rod is D s = D s0 + αs D s0 ∆T and the diameter of the brass ring is D b = D b0 + αb D b0 ∆T, where D s0 and D b0 are the original diameters, αs and αb are the coefficients of linear expansion, and ∆T is the

change in temperature The rod just fits through the ring if D s = D b This means D s0 +

(c) The volume (a three-dimensional quantity) increases by 3(0.18%) = 0.54%

(d) The mass does not change

(e) The coefficient of linear expansion is

19 The initial volume V0 of the liquid is h0 A0 where A0 is the initial cross-section area

and h0 = 0.64 m Its final volume is V = hA where h – h0 is what we wish to compute

Now, the area expands according to how the glass expands, which we analyze as follows: Using A=πr2, we obtain

dA= πr dr= πr r dTα = α πr dT = αA dT.Therefore, the height is

βα

20 We divide Eq 18-9 by the time increment ∆t and equate it to the (constant) speed v =

∆

21 Consider half the bar Its original length is A0 =L0/ 2 and its length after the temperature increase is A= +A0 αA0∆T The old position of the half-bar, its new position,

and the distance x that one end is displaced form a right triangle, with a hypotenuse of

length A, one side of length A , and the other side of length x The Pythagorean theorem 0

yields x2 = − =A2 A20 A20(1+ ∆α T)2−A20 Since the change in length is small we may approximate (1 + α ∆T )2

by 1 + 2α ∆T, where the small term (α ∆T )2

was neglected Then,

22 The amount of water m which is frozen is

Therefore the amount of water which remains unfrozen is 260 g – 151 g = 109 g

23 (a) The specific heat is given by c = Q/m(T f – T i ), where Q is the heat added, m is the mass of the sample, T i is the initial temperature, and T f is the final temperature Thus, recalling that a change in Celsius degrees is equal to the corresponding change on the Kelvin scale,

30.0 10 kg

0.600 mol

50 10 kg/mol

m N M

24 We use Q = cm ∆T The textbook notes that a nutritionist's “Calorie” is equivalent to

1000 cal The mass m of the water that must be consumed is

25 The melting point of silver is 1235 K, so the temperature of the silver must first be raised from 15.0° C (= 288 K) to 1235 K This requires heat

26 The work the man has to do to climb to the top of Mt Everest is given by

W = mgy = (73.0 kg)(9.80 m/s2)(8840 m) = 6.32 × 106

J Thus, the amount of butter needed is

6 1.00cal 4.186J

27 The mass m = 0.100 kg of water, with specific heat c = 4190 J/kg·K, is raised from an initial temperature T i = 23°C to its boiling point T f = 100°C The heat input is given by Q

= cm(T f – T i ) This must be the power output of the heater P multiplied by the time t; Q =

t

28 (a) The water (of mass m) releases energy in two steps, first by lowering its

temperature from 20°C to 0°C, and then by freezing into ice Thus the total energy transferred from the water to the surroundings is

29 We note from Eq 18-12 that 1 Btu = 252 cal The heat relates to the power, and to the

temperature change, through Q = Pt = cm ∆T Therefore, the time t required is

5

(1000 cal / kg C )(40 gal)(1000 kg / 264 gal)(100 F 70 F)(5 C / 9 F)

(2.0 10 Btu / h)(252.0 cal / Btu)(1 h / 60 min)3.0 min

30 (a) Using Eq 18-17, the heat transferred to the water is

31 Let the mass of the steam be m s and that of the ice be m i Then

L F m c + c w m c (T f – 0.0°C) = L s m s + c w m s (100°C – T f),

where T f = 50°C is the final temperature We solve for m s:

( 0.0 C) (79.7 cal / g)(150 g) (1cal / g· C)(150g)(50 C 0.0°C)(100 C ) 539 cal / g (1cal / g C )(100 C 50 C)

32 While the sample is in its liquid phase, its temperature change (in absolute values) is

|∆T | = 30 °C Thus, with m = 0.40 kg, the absolute value of Eq 18-14 leads to

(b) During the final 20 minutes, the sample is solid and undergoes a temperature change (in absolute values) of |∆T | = 20 C° Now, the absolute value of Eq 18-14 leads to

J kg·C° ≈ 2.3 kJ

kg·C°

33 The power consumed by the system is

2.3 10 W

33m

700 W / m

34 We note that the heat capacity of sample B is given by the reciprocal of the slope of

the line in Figure 18-32(b) (compare with Eq 18-14) Since the reciprocal of that slope is 16/4 = 4 kJ/kg·C°, then c B = 4000 J/kg·C° = 4000 J/kg·K (since a change in Celsius is equivalent to a change in Kelvins) Now, following the same procedure as shown in Sample Problem 18-4, we find

c A m A (T f − T A ) + c B m B (T f − T B) = 0

cA (5.0 kg)(40°C – 100°C) + (4000 J/kg·C°)(1.5 kg)(40°C – 20°C) = 0

which leads to c A = 4.0×102 J/kg·K

35 To accomplish the phase change at 78°C, Q = L V m = (879) (0.510) = 448.29 kJ must

be removed To cool the liquid to –114°C, Q = cm| ∆T| = (2.43) (0.510) (192) = 237.95 kJ,

must be removed Finally, to accomplish the phase change at –114°C,

Q = L F m = (109) (0.510) = 55.59 kJ

must be removed The grand total of heat removed is therefore (448.29 + 237.95 + 55.59)

kJ = 742 kJ

36 (a) Eq 18-14 (in absolute value) gives |Q| = (4190)(0.530)(40°) = 88828 J Since d Q d t

is assumed constant (we will call it P) then we have

P = 88828 J

40 min =

88828 J

2400 s = 37 W (b) During that same time (used in part (a)) the ice warms by 20 C° Using Table 18-3 and Eq 18-14 again we have

mice = Q

cice ∆T =

88828 (2220)(20°) = 2.0 kg

(c) To find the ice produced (by freezing the water that has already reached 0°C – so we concerned with the 40 min < t< 60 min time span), we use Table 18-4 and Eq 18-16:

mwater becoming ice = Q L20 min = 33300044414 = 0.13 kg

37 We compute with Celsius temperature, which poses no difficulty for the J/kg·K values of specific heat capacity (see Table 18-3) since a change of Kelvin temperature is numerically equal to the corresponding change on the Celsius scale If the equilibrium

temperature is T f then the energy absorbed as heat by the ice is

Q I = L F m I + c w m I (T f – 0°C),

while the energy transferred as heat from the water is Q w = cwmw (T f – T i) The system is

insulated, so Q w + Q I = 0, and we solve for T f :

(b) Since no ice has remained at T f =5.3°C, we have m f =0

(c) If we were to use the formula above with T i = 70°C, we would get T f < 0, which is impossible In fact, not all the ice has melted in this case and the equilibrium temperature

L

×

Therefore, the amount of (solid) ice remaining is m f = mI – m'I = 500 g – 440 g = 60.0 g,

and (as mentioned) we have T f = 0°C (because the system is an ice-water mixture in thermal equilibrium)

38 The heat needed is found by integrating the heat capacity:

15.0 C

2 5.0 C

15.0

5.0

(2.09) (0.20 0.14 0.023 ) (2.0) (0.20 0.070 0.00767 ) (cal)

39 (a) We work in Celsius temperature, which poses no difficulty for the J/kg·K values

of specific heat capacity (see Table 18-3) since a change of Kelvin temperature is numerically equal to the corresponding change on the Celsius scale There are three possibilities:

• None of the ice melts and the water-ice system reaches thermal equilibrium at a temperature that is at or below the melting point of ice

• The system reaches thermal equilibrium at the melting point of ice, with some of the ice melted

• All of the ice melts and the system reaches thermal equilibrium at a temperature at or above the melting point of ice

First, suppose that no ice melts The temperature of the water decreases from T Wi = 25°C

to some final temperature T f and the temperature of the ice increases from T Ii = –15°C to

Tf If m W is the mass of the water and c W is its specific heat then the water rejects heat

ice reach thermal equilibrium at T f = 0°C, with mass m ( < m I) of the ice melted The magnitude of the heat rejected by the water is

|Q| = c m T W W Wi,and the heat absorbed by the ice is

Since the total mass of ice present initially was 100 g, there is enough ice to bring the

water temperature down to 0°C This is then the solution: the ice and water reach thermal equilibrium at a temperature of 0°C with 53 g of ice melted

(b) Now there is less than 53 g of ice present initially All the ice melts and the final temperature is above the melting point of ice The heat rejected by the water is

The first term is the energy required to raise the temperature of the ice to 0°C, the second

term is the energy required to raise the temperature of the melted ice from 0°C to T f, and the third term is the energy required to melt all the ice Since the two heats are equal,

40 We denote the ice with subscript I and the coffee with c, respectively Let the final temperature be T f The heat absorbed by the ice is Q I = λF m I + m I c w (T f – 0°C), and the

heat given away by the coffee is |Q c | = m wcw (T I – Tf ) Setting Q I = |Q c |, we solve for T f:

3(130 g) (4190 J/kg C ) (80.0 C) (333 10 J/g) (12.0 g)

Note that we work in Celsius temperature, which poses no difficulty for the J/kg·K values

of specific heat capacity (see Table 18-3) since a change of Kelvin temperature is numerically equal to the corresponding change on the Celsius scale Therefore, the temperature of the coffee will cool by |∆T | = 80.0°C – 66.5°C = 13.5C°

41 If the ring diameter at 0.000°C is D r0 then its diameter when the ring and sphere are in thermal equilibrium is

where T f is the final temperature and αc is the coefficient of linear expansion for copper

Similarly, if the sphere diameter at T i (= 100.0°C) is D s0 then its diameter at the final temperature is

The expansion coefficients are from Table 18-2 of the text Since the initial temperature

of the ring is 0°C, the heat it absorbs is Q =c m T c r f , where c c is the specific heat of

copper and m r is the mass of the ring The heat rejected up by the sphere is

c m T m

42 During process A → B, the system is expanding, doing work on its environment, so W

> 0, and since ∆Eint > 0 is given then Q = W + ∆Eint must also be positive

(a) Q > 0

(b) W > 0

During process B → C, the system is neither expanding nor contracting Thus,

(c) W = 0

(d) The sign of ∆Eint must be the same (by the first law of thermodynamics) as that of Q

which is given as positive Thus, ∆Eint > 0

During process C → A, the system is contracting The environment is doing work on the system, which implies W < 0 Also, ∆Eint < 0 because ¦ ∆Eint = 0 (for the whole cycle)

and the other values of ∆Eint (for the other processes) were positive Therefore, Q = W +

∆Eint must also be negative

(e) Q < 0

(f) W < 0

(g)∆Eint < 0

(h) The area of a triangle is 1

2 (base)(height) Applying this to the figure, we find

3 1

net 2

|W |= (2.0 m )(20 Pa)=20 J Since process C → A involves larger negative work (it occurs at higher average pressure) than the positive work done during process A → B, then the net work done during the cycle must be negative The answer is therefore Wnet

= –20 J

43 (a) One part of path A represents a constant pressure process The volume changes

from 1.0 m3 to 4.0 m3 while the pressure remains at 40 Pa The work done is

of the volume, so we may write p = a + bV, where a and b are constants In order for the

pressure to be 40 Pa when the volume is 1.0 m3 and 10 Pa when the volume is 4.00 m3

the values of the constants must be a = 50 Pa and b = –10 Pa/m3 Thus p =

(c) One part of path C represents a constant pressure process in which the volume

changes from 1.0 m3 to 4.0 m3 while p remains at 10 Pa The work done is

(10 Pa)(4.0 m 1.0 m ) 30 J

C

The other part of the process is at constant volume and no work is done The total work is

30 J We note that the work is different for different paths