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Enhanced Oil Recovery Polymer Flooding

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• SNF conceptual study about BoD, SoR for TLP and FSO, polymer properties, process, operation, logistics options, costs, ... • Lab studies of polymer AN125SH and FP5115 into field reservoir water, sea water and mix of both waters • SNF Answer: ‘The temperature being 86°C , the Flopaam 3630S (copolymer of acrylamide and acrylate) will not be stable . So we propose to use a polymer containing some sulfonated moieties , stable up to 100 °C , and also with less tendency to hydrolyzation . Flopaam AN125SH is a copolymer of acrylamide and ATBS (sulfonate monomer) , Flopaam 5115 is a terpolymer of acrylamide ATBSacrylate (the ATBS will pr event further hydrolysis or precipitation) . Both polymers should be tested on long term stability to select the best one in term of economic Technical ratio . AN125 will be the best in term of long term stability , but its cost is slightly higher.’

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Enhanced Oil Recovery

Polymer Flooding

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October 15 | Page 2

SNF Conceptual Study

logistics options, costs,

waters

SNF Answer: ‘The temperature being 86°C , the Flopaam 3630S (copolymer of acrylamide and acrylate) will not be stable So we propose to use a polymer

containing some sulfonated moieties , stable up to 100 °C , and also with less tendency to hydrolyzation

Flopaam AN125SH is a copolymer of acrylamide and ATBS (sulfonate monomer) , Flopaam 5115 is a terpolymer of acrylamide /ATBS/acrylate (the ATBS will pr event further hydrolysis or precipitation) Both polymers should be tested on long term stability to select the best one in term of economic/ Technical ratio AN125 will be the best in term of long term stability , but its cost is slightly higher.’

OCTL test SNF conceptual study

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October 15 | Page 3

SNF study - Polymer Injection Facilities

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Polymer Flooding simulation

0 10 20 30 40 50 60 70 80 90

Polymer Concentration (ppm)

Polymer Viscosity

Csalt 6000 ppm Csalt 20000 ppm Csalt 35000 ppm

EOR Mechanism: Polymer augmented increases

water viscosity, improve mobility ratio and

sweep efficiency.

PLYMAX, PLYROCK, WPOLYMER,

polymer solution viscosity

PLYVISC

polymer water viscosity

concentration multiplier

lb/stb [-]

Csalt 7.01 lb/stb (20000 ppm) from SALTNODE

0.0 1.0

0.1753 5.0

0.3505 10.0

0.7010 20.0 /

Polymer concentration of 1000 ppm as SNF suggestion

water cut about 40%)

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Chemical Injection simulation – 2D model

Polymer assumption:

Surfactant Flooding assumption:

0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

Fractional Flow

1 Base case 2 Polymer 500 ppm

3 Polymer 1000 ppm 4 Surfactant1

5 Surfactant2 6 ASP

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

Relative Permeability

Kro Krw fw

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Chemical Injection simulation – 2D model

Polymer Flooding

0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8

FOE

FOE PF000 FOE PF001 FOE SF000 FOE SP000

0

10

20

30

40

FOPR

FOPR PF000 FOPR PF001 FOPR SF000 FOPR SP000

Water Polymer

Surfactant Polymer +Surfactant

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Polymer Flooding simulation – 2D model

Profile of 2D model:

5

10

15

20

2D Polymer Flooding

FOPR PLYFLOOD005 FOPR PLYFLOOD003 FOPR PLYFLOOD004

1500 2500 3500 4500 5500

WBHP

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Polymer Flooding simulation – 2D model

0

10

20

30

40

2D Polymer Flooding

FOPR PF000 FOPR PF001 FOPR PF002

FOPR PF003 FOPR PF004 FOPR PF005

0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8

FOE

FOE PF000 FOE PF001 FOE PF002 FOE PF003 FOE PF004 FOE PF005

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Polymer Flooding simulation – Full Field model

Case name Case description

UR (mmstb)

% Variance RF %

Profile FFM:

Water Injectors (especially in the oil leg) => Need more injectors or increase injection pressure

20K

40K

60K

80K

100K

120K

0 50MM 100MM 150MM 200MM 250MM 300MM 350MM

Polymer Flooding

Ref case - Water Flooding

ASP Flooding from 2022

Polymer flooding

FOPR PH30_P136F4 FOPT PH30_P136F4 FOPR PH30_P136F10

FOPT PH30_P136F10 FOPR PH30_P136N FOPT PH30_P136N

Pv Injected

0 0.1 0.2 0.3 0.4

RF vs PV Injected

FOE PH30_P136N FOE PH30_P136F4 FOE PH30_P136F10

Start Polymer injection

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October 15 | Page 10

Way forward

• Cost and Economics evaluation

• Core experiment program for polymer flooding

• Pilot test

• Full field application

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