Minerals can be identified by their physical properties = atomic structure 5.. Identifying Minerals• Color: very variable, complex causes • Hardness: strength of atomic bonds • Density:
Trang 1Minerals
Trang 2Take-Away Points
1 Chemical elements form in stars
2 Atoms bond by sharing electrons
3 Minerals are classified by their chemistry
4 Minerals can be identified by their
physical properties = atomic structure
5 Silicates are the most important mineral
group
6 Crystals are determined by mathematical
rules called symmetry
Trang 3Composition of the Sun
1 Chemical elements form in stars
Trang 4Composition of the Sun
Iron, trailing off after
1 Chemical elements form in stars
Trang 5How Elements Form in Stars
• Sun: 4 H He
• He + particle Mass 5 – Unstable
• He + He Mass 8 – Unstable
• He + He + He C
• Add more He to make heavier elements
• End of the line is iron for energy production
• Atoms beyond Iron made in massive stars
1 Chemical elements form in stars
Trang 6What are Planets Made of?
• Same material as Sun
• Minus the elements that remain mostly in gases
• We find this pattern in a certain class of meteorites
1 Chemical elements form in stars
Trang 71 Chemical elements form in stars
Trang 8The Earth’s Crust looks Very
Different
1 Chemical elements form in stars
Trang 9Composition of the Crust
1 Chemical elements form in stars
Trang 10Minerals are the Chemicals that
make up the Earth
Trang 11Atomic Bonding
1 IONS
2 Atoms bond by sharing electrons
Trang 12Atomic Bonding
2 Electrical Neutrality
• (+) and (-) Cancel Out
3 Bonding (Satisfy 1 & 2)
• Ionic (NaCl)
• Covalent (O2)
• Metallic (Cu, Al, Fe)
• Hydrogen (in water)
2 Atoms bond by sharing electrons
Trang 13Ionic and Covalent Bonding
2 Atoms bond by sharing electrons
Trang 14Metallic Bonding
2 Atoms bond by sharing electrons
Trang 15Hydrogen Bonding
2 Atoms bond by sharing electrons
Trang 16• Metallic bonding holds civilization together
• Hydrogen bonding gives water its
heat-retaining and solvent properties
2 Atoms bond by sharing electrons
Trang 185 Complex Anions (Radicals)
• Many minerals contain groups of atoms that behave as single units
2 Atoms bond by sharing electrons
Trang 20Chemicals (and Minerals) Are
Classified by their Anions
3 Minerals are classified by their chemistry
Trang 21For Example: Iron Compounds
Have Little in Common
• Fe: Gray, Metallic
• FeCl2: Light Green, Water Soluble
• FeSO4: Light Green, Water Soluble
• FeCO3: Brown, Fizzes in Acid
• FeS2: Dense, Brittle, Metallic, Cubic Crystals
3 Minerals are classified by their chemistry
Trang 22On the Other Hand, Sulfides have Many Properties in
Trang 23Minerals
4 Minerals can be identified by their physical properties
Trang 24Identifying Minerals
• Color: very variable, complex causes
• Hardness: strength of atomic bonds
• Density: mass and spacing of atoms
• Luster: how electrons interact with light
• Cleavage: weak atomic planes
• Crystal Form: extremely useful but not for beginners
• Other properties distinctive at times
4 Minerals can be identified by their physical properties = atomic structure
Trang 26Hardness
• Resistance to Scratching
• Directly related to relative strength of
atomic bonds
• Scratch Test (Mohs)
• Indentation Test (Knoop)
Common Errors due to:
• Weathering, ‘Chalk' marks
• Breaking vs Scratching
4 Minerals can be identified by their physical properties = atomic structure
Trang 27Mohs vs Knoop Scales
1 Talc: very small
Trang 28Density
• Directly related to masses of component
atoms and their spacing
• Usually very consistent
4 Minerals can be identified by their physical properties = atomic structure
Trang 29Density - gm/cm3
(weight relative to water )
Wood - Balsa: 0.1, Pine: 0.5, Oak: 0.6-0.9
Gasoline: 0.7, Motor Oil: 0.9
Trang 30Iridium: 22.4 (densest material on Earth)
4 Minerals can be identified by their physical properties = atomic structure
Trang 31• Vitreous is often used for glassy luster
4 Minerals can be identified by their physical properties = atomic structure
Trang 32Cleavage
• Tendency to split along smooth planes of
weaknessbetween atoms in crystal
• Directly related to atomic structure
• Related to Crystal Form
• Every cleavage face is a possible crystal face
• Not every crystal face is a cleavage face
Quartz commonly forms crystals but lacks
cleavage
4 Minerals can be identified by their physical properties = atomic structure
Trang 33Other Properties
Crystal Form
• Takes Luck & Practice
• Well-formed crystals are uncommon
• Crystal Classification is somewhat subtle
Fracture
4 Minerals can be identified by their physical properties = atomic structure
Trang 34Identifying Minerals
Geologic Setting
• Some minerals occur in all geologic
settings: quartz, feldspar, pyrite
• Some minerals occur mostly in sedimentary settings: calcite, dolomite
• Some minerals occur mostly in igneous
settings: olivine
• Some minerals occur mostly in
metamorphic settings: garnet, kyanite
4 Minerals can be identified by their physical properties = atomic structure
Trang 35Identifying Minerals
Special Properties
• Taste, Magnetism, Etc
Experience and Reading
• “The best geologist is the one who’s seen the most rocks.”
Trang 364 Minerals can be identified by their physical properties = atomic structure
Trang 374 Minerals can be identified by their physical properties = atomic structure
Trang 38A Common Example
Trang 39Diffraction in Opal
4 Minerals can be identified by their physical properties = atomic structure
Trang 40MAJOR MINERAL SUITES
Elements
Metallic:Au, Ag, Cu
• Not Al, Pb, Zn, Fe, etc
Nonmetallic: C - Diamond, Graphite
• Sulfur
4 Minerals can be identified by their physical properties = atomic structure
Trang 41Copper Nugget
Trang 42MAJOR MINERAL SUITES
Sulfides: Dense, Usually Metallic
Many Major Ores
Trang 43MAJOR MINERAL SUITES
Halides: Usually Soft, Often Soluble
Trang 44MAJOR MINERAL SUITES
Oxides: Often Variable, Some Ores
• Hematite Fe2O3
• Bauxite Al(OH) 3 (a hydroxide)
• Corundum Al2O3 (Ruby, Sapphire)
Carbonates: Fizz in Acid, Give off CO2
• Calcite CaCO3
• Dolomite CaMg (CO3)2
4 Minerals can be identified by their physical properties = atomic structure
Trang 45MOST IMPORTANT MINERAL
Trang 47Sorosilicates - Paired Tetrahedra
Epidote is the most common example
5 Silicates are the most important mineral group
Trang 49Inosilicates - Chains
Single Chains (Pyroxenes)
5 Silicates are the most important mineral group
Trang 50Inosilicates - Chains
Double Chains (Amphiboles)
5 Silicates are the most important mineral group
Trang 51Phyllosilicates - Sheets
5 Silicates are the most important mineral group
Trang 52• Serpentine (asbestos) minerals
5 Silicates are the most important mineral group
Trang 53One Type of Asbestos
5 Silicates are the most important mineral group
Trang 54Tectosilicates - Dimensional Networks
Three-• Quartz Feldspars
5 Silicates are the most important mineral group
Trang 55Making Sense of Crystals
6 Crystals are determined by mathematical rules called symmetry
Trang 56Unit Cells
All repeating patterns can be described in
terms of repeating boxes
Trang 57The problem in Crystallography is to reason from the outward shape to the unit cell
6 Crystals are determined by mathematical rules called symmetry
Trang 58Which Shape Makes Each Stack?
Crystals are determined by mathematical rules called symmetry
Trang 59Stacking Cubes
6 Crystals are determined by mathematical rules called symmetry
Trang 63Some shapes that result from
stacking cubes
6 Crystals are determined by mathematical rules called symmetry
Trang 64Symmetry – the rules behind the shapes
6 Crystals are determined by mathematical rules called symmetry
Trang 65Symmetry – the rules behind the shapes
6 Crystals are determined by mathematical rules called symmetry
Trang 66The Crystal Classes
6 Crystals are determined by mathematical rules called symmetry
Trang 67Take-Away Points
1 Chemical elements form in stars
2 Atoms bond by sharing electrons
3 Minerals are classified by their chemistry
4 Minerals can be identified by their
physical properties = atomic structure
5 Silicates are the most important mineral
group
6 Crystals are determined by mathematical
rules called symmetry