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How to identify a mineral 3

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Minerals can be identified by their physical properties = atomic structure 5.. Identifying Minerals• Color: very variable, complex causes • Hardness: strength of atomic bonds • Density:

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Minerals

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Take-Away Points

1 Chemical elements form in stars

2 Atoms bond by sharing electrons

3 Minerals are classified by their chemistry

4 Minerals can be identified by their

physical properties = atomic structure

5 Silicates are the most important mineral

group

6 Crystals are determined by mathematical

rules called symmetry

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Composition of the Sun

1 Chemical elements form in stars

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Composition of the Sun

Iron, trailing off after

1 Chemical elements form in stars

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How Elements Form in Stars

• Sun: 4 H  He

• He + particle  Mass 5 – Unstable

• He + He  Mass 8 – Unstable

• He + He + He  C

• Add more He to make heavier elements

• End of the line is iron for energy production

• Atoms beyond Iron made in massive stars

1 Chemical elements form in stars

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What are Planets Made of?

• Same material as Sun

• Minus the elements that remain mostly in gases

• We find this pattern in a certain class of meteorites

1 Chemical elements form in stars

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1 Chemical elements form in stars

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The Earth’s Crust looks Very

Different

1 Chemical elements form in stars

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Composition of the Crust

1 Chemical elements form in stars

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Minerals are the Chemicals that

make up the Earth

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Atomic Bonding

1 IONS

2 Atoms bond by sharing electrons

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Atomic Bonding

2 Electrical Neutrality

• (+) and (-) Cancel Out

3 Bonding (Satisfy 1 & 2)

• Ionic (NaCl)

• Covalent (O2)

• Metallic (Cu, Al, Fe)

• Hydrogen (in water)

2 Atoms bond by sharing electrons

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Ionic and Covalent Bonding

2 Atoms bond by sharing electrons

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Metallic Bonding

2 Atoms bond by sharing electrons

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Hydrogen Bonding

2 Atoms bond by sharing electrons

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• Metallic bonding holds civilization together

• Hydrogen bonding gives water its

heat-retaining and solvent properties

2 Atoms bond by sharing electrons

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5 Complex Anions (Radicals)

• Many minerals contain groups of atoms that behave as single units

2 Atoms bond by sharing electrons

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Chemicals (and Minerals) Are

Classified by their Anions

3 Minerals are classified by their chemistry

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For Example: Iron Compounds

Have Little in Common

• Fe: Gray, Metallic

• FeCl2: Light Green, Water Soluble

• FeSO4: Light Green, Water Soluble

• FeCO3: Brown, Fizzes in Acid

• FeS2: Dense, Brittle, Metallic, Cubic Crystals

3 Minerals are classified by their chemistry

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On the Other Hand, Sulfides have Many Properties in

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Minerals

4 Minerals can be identified by their physical properties

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Identifying Minerals

• Color: very variable, complex causes

• Hardness: strength of atomic bonds

• Density: mass and spacing of atoms

• Luster: how electrons interact with light

• Cleavage: weak atomic planes

• Crystal Form: extremely useful but not for beginners

• Other properties distinctive at times

4 Minerals can be identified by their physical properties = atomic structure

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Hardness

• Resistance to Scratching

• Directly related to relative strength of

atomic bonds

• Scratch Test (Mohs)

• Indentation Test (Knoop)

Common Errors due to:

• Weathering, ‘Chalk' marks

• Breaking vs Scratching

4 Minerals can be identified by their physical properties = atomic structure

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Mohs vs Knoop Scales

1 Talc: very small

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Density

• Directly related to masses of component

atoms and their spacing

• Usually very consistent

4 Minerals can be identified by their physical properties = atomic structure

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Density - gm/cm3

(weight relative to water )

Wood - Balsa: 0.1, Pine: 0.5, Oak: 0.6-0.9

Gasoline: 0.7, Motor Oil: 0.9

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Iridium: 22.4 (densest material on Earth)

4 Minerals can be identified by their physical properties = atomic structure

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• Vitreous is often used for glassy luster

4 Minerals can be identified by their physical properties = atomic structure

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Cleavage

• Tendency to split along smooth planes of

weaknessbetween atoms in crystal

• Directly related to atomic structure

• Related to Crystal Form

• Every cleavage face is a possible crystal face

• Not every crystal face is a cleavage face

Quartz commonly forms crystals but lacks

cleavage

4 Minerals can be identified by their physical properties = atomic structure

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Other Properties

Crystal Form

• Takes Luck & Practice

• Well-formed crystals are uncommon

• Crystal Classification is somewhat subtle

Fracture

4 Minerals can be identified by their physical properties = atomic structure

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Identifying Minerals

Geologic Setting

• Some minerals occur in all geologic

settings: quartz, feldspar, pyrite

• Some minerals occur mostly in sedimentary settings: calcite, dolomite

• Some minerals occur mostly in igneous

settings: olivine

• Some minerals occur mostly in

metamorphic settings: garnet, kyanite

4 Minerals can be identified by their physical properties = atomic structure

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Identifying Minerals

Special Properties

• Taste, Magnetism, Etc

Experience and Reading

• “The best geologist is the one who’s seen the most rocks.”

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4 Minerals can be identified by their physical properties = atomic structure

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4 Minerals can be identified by their physical properties = atomic structure

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A Common Example

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Diffraction in Opal

4 Minerals can be identified by their physical properties = atomic structure

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MAJOR MINERAL SUITES

Elements

Metallic:Au, Ag, Cu

• Not Al, Pb, Zn, Fe, etc

Nonmetallic: C - Diamond, Graphite

• Sulfur

4 Minerals can be identified by their physical properties = atomic structure

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Copper Nugget

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MAJOR MINERAL SUITES

Sulfides: Dense, Usually Metallic

Many Major Ores

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MAJOR MINERAL SUITES

Halides: Usually Soft, Often Soluble

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MAJOR MINERAL SUITES

Oxides: Often Variable, Some Ores

• Hematite Fe2O3

• Bauxite Al(OH) 3 (a hydroxide)

• Corundum Al2O3 (Ruby, Sapphire)

Carbonates: Fizz in Acid, Give off CO2

• Calcite CaCO3

• Dolomite CaMg (CO3)2

4 Minerals can be identified by their physical properties = atomic structure

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MOST IMPORTANT MINERAL

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Sorosilicates - Paired Tetrahedra

Epidote is the most common example

5 Silicates are the most important mineral group

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Inosilicates - Chains

Single Chains (Pyroxenes)

5 Silicates are the most important mineral group

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Inosilicates - Chains

Double Chains (Amphiboles)

5 Silicates are the most important mineral group

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Phyllosilicates - Sheets

5 Silicates are the most important mineral group

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• Serpentine (asbestos) minerals

5 Silicates are the most important mineral group

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One Type of Asbestos

5 Silicates are the most important mineral group

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Tectosilicates - Dimensional Networks

Three-• Quartz Feldspars

5 Silicates are the most important mineral group

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Making Sense of Crystals

6 Crystals are determined by mathematical rules called symmetry

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Unit Cells

All repeating patterns can be described in

terms of repeating boxes

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The problem in Crystallography is to reason from the outward shape to the unit cell

6 Crystals are determined by mathematical rules called symmetry

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Which Shape Makes Each Stack?

Crystals are determined by mathematical rules called symmetry

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Stacking Cubes

6 Crystals are determined by mathematical rules called symmetry

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Some shapes that result from

stacking cubes

6 Crystals are determined by mathematical rules called symmetry

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Symmetry – the rules behind the shapes

6 Crystals are determined by mathematical rules called symmetry

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Symmetry – the rules behind the shapes

6 Crystals are determined by mathematical rules called symmetry

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The Crystal Classes

6 Crystals are determined by mathematical rules called symmetry

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Take-Away Points

1 Chemical elements form in stars

2 Atoms bond by sharing electrons

3 Minerals are classified by their chemistry

4 Minerals can be identified by their

physical properties = atomic structure

5 Silicates are the most important mineral

group

6 Crystals are determined by mathematical

rules called symmetry

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