Composites are produced by reinforcing a resin matrix thermoplastic/thermoset with fibres like glass fibre, aramid, carbon fibre and/or natural fibres... Reinforcement The reinforce
Trang 1BY ALANKAR G MHATRE FINAL YEAR B.TECH
Trang 3INTRODUCTION TO COMPOSITES
You might be know we all are surrounded by composites in day today life.
Everybody comes across composites in his daily life.You might be playing
tennis or badminton with a "graphite racket", You might have a "carbon bike" ,your bike breaks are made of composite, several parts of your car body are also made of composites.
Def :-A composite is a material made up of two or more different materials
that are combined in a way that allows the materials to stay distinct and
identifiable
The purpose of composites is to allow the new material to have strengths
from both materials.
• Composites can be easily found in nature Wood is an example of a
composite Another natural composite is rock and sand, materials used in concrete
Trang 4 Properties of composites like stiffness, thermal expansion etc can be
varied continuously over a broad range of values using appropriate fiber , resin and fabrication mechanism
The technical textile material in the composites is the fiber glass,
aramid and carbon fiber.
• Fibre glass dominates the composites industry as a preferred
reinforcement fibre, with a share of around 85%-90% Other
reinforcement fibers like carbon fibre and aramid fibre are sparingly used in India.
Trang 5WHAT ARE COMPOSITES?
Composites are created by combining two or more materials to
produce a new material that retains important properties from the original elements
Reinforcing fibers give composites the attributes of high strength
and stiffness.
In textile composites fibers are surrounded by a choice of polymers
that act as a support system.
Composites are produced by reinforcing a resin matrix
(thermoplastic/thermoset) with fibres like glass fibre, aramid, carbon fibre and/or natural fibres
Trang 6 A common example of a composite is concrete It
consists of a binder as a cement and a reinforcement as
a gravel
Trang 7COMPOSITION OF COMPOSITES
The individual materials that make up composites are called
constituents Most composites have two constituents, a matrix and reinforcement
Composite materials are usually classified by the type of
reinforcement they use This reinforcement is embedded into a matrix that hold it together
The reinforcement is used to strengthen the composite Composite
properties are best in the direction of the fibers Perpendicular, or
transverse, to the fibers, the matrix properties dominate because load
must be transferred by the matrix every fiber diameter
Trang 8Reinforcement
The reinforcement is usually much stronger and stiffer than the matrix, and
that gives the composite its good properties
The matrix hold the reinforcements in an orderly pattern, the matrix also
helps to transfer load among the reinforcements
Reinforcements basically come in three forms: particulate, discontinuous
fiber, and continuous fiber.
PARTICLE AS A REINFORCEMENT:-A particle has roughly
equal dimensions in all directions, though it doesn't have to be spherical Gravel, micro balloons, and resin powder are examples of particulate
reinforcements
become fibers when one dimension becomes long compared to others
DISCONTINUES FIBERS AS A REINFORCEMENT:
-:Discontinuous reinforcements (chopped fibers, milled fibers, or whiskers) vary in length from a few millimeters to a few centimeters Most fibers are only a few microns in diameter, so it doesn't take much length to make the transition from particle to fiber
Trang 9 Matrix materials are usually some type of plastic, and
these composites are often called reinforced plastics.
There are other types of matrices, such as metal or
ceramic, but plastics are the most
The two most common plastic matrices are epoxy
resins and polyester resins
Trang 10TYPES OF COMPOSITES
Metal matrix composites (MMC)
Ceramic matrix composites (CMC)
Polymer matrix composites (PMC)
Trang 11Metal matrix composites (MMC)
• Metal matrix composites (MMCs) are a subgroup of composite materials.
Composition:- MMC are made by dispersing a reinforcing material into a metal matrix The
reinforcement surface can be coated to prevent a chemical reaction with the matrix.
For example, carbon fibers are commonly used in aluminum matrix
to synthesize composites showing low density and high strength However, carbon reacts with aluminum to generate a brittle and water-soluble
compound Al4C3 on the surface of the fiber To prevent this reaction, the carbon fibers are coated with nickel or titanium boride.
Matrix:- In structural applications, the matrix is usually a lighter metal such as
aluminum, magnesium, or titanium, and provides a compliant support for the reinforcement
In high temperature applications, cobalt and cobalt-nickel alloy matrices are common
Trang 12Reinforcement to MMC
The reinforcement can be either continuous, or discontinuous
Discontinuous MMC can be isotropic, and can be worked with
standard metalworking techniques, such as extrusion, forging or
rolling
In addition, they may be machined using conventional techniques,
but commonly would need the use of polycrystalline diamond tooling (PCD).
Trang 13 Continuous reinforcement uses monofilament wires or
fibers such as carbon fiber or silicon carbide.
One of the first MMC used boron filament as
reinforcement Discontinuous reinforcement uses
"whiskers", short fibers, or particles
The most common reinforcing materials in this category
are alumina and silicon carbide
Trang 14Ceramic matrix composites
Ceramic matrix composites (CMCs) are a subgroup of composite
materials as well as a subgroup of technical ceramics.
They consist of ceramic fibers embedded in a ceramic matrix, thus forming a ceramic fiber reinforced ceramic (CFRC) material
The matrix and fibers can consist of any ceramic material, whereby
carbon and carbon fibers can also be considered a ceramic
material.
Generally, CMC names include a combination of type of fiber / type
of matrix For example, C/C stands for carbon-fiber-reinforced
carbon (carbon/carbon), or C/ SiC for carbon-fiber-reinforced
silicon carbide
Trang 15Ceramic composites
REINFORCEMENT- SiC (Silicon carbide)
MATRIX-Cu Metal
Trang 16Polymer Matrix composites
Polymer matrix composites are the imp and third subgroup of
composites.
It is also referred as fibre-reinforced plastics(FRP)
In these fibre-reinforced plastics, the plastic is reinforced with
fibers to make a light and strong material The material in
which the fibres are embedded, is called the matrix, while the
fibres are called the reinforcement.
The matrix can basically be any type of plastic: epoxy, polyester,
vinyl ester, polypropylene (PP).
Trang 17Matrix examples for PMC
• polyether sulphide (PES)
• polyphenylene sulphide (PPS)
• polyether imide (PEI)
• polyether ether ketone (PEEK)
Trang 18The fibres are typically glass, carbon (graphite) or aramid (trade name Kevlar) The fibre reinforcement can take any form: a mat
of short chopped fibres, a woven fabric, a unidirectional
arrangement of fibres, a braid, a knit.
Glass fabrics Plain weave glass
fabric
Trang 19Manufacturing and forming methods of
MMC
MMC manufacturing can be broken into three types: solid,
liquid, and vapor.
Solid state
methods:- 1)-Powder blending and consolidation (powder metallurgy):-
Powdered metal and discontinuous reinforcement are mixed and then bonded through a process of compaction, degassing, and thermo-mechanical treatment (possibly via hot isostatic pressing (HIP) or extrusion)
2)-Foil diffusion bonding:-Layers of metal foil are
sandwiched with long fibers, and then pressed through to form
a matrix
Trang 20Liquid state methods FOR MMC
1)-Electroplating / Electroforming:- A solution
containing metal ions loaded with reinforcing particles is co-deposited forming a composite material
2)-Stir casting:- Discontinuous reinforcement is stirred
into molten metal, which is allowed to solidify
3)-Squeeze casting:- Molten metal is injected into a
form with fibers preplaced inside it
4)-Spray deposition:- Molten metal is sprayed onto a
continuous fiber substrate
5)-Reactive processing:- A chemical reaction occurs,
with one of the reactants forming the matrix and the
other the reinforcement
Trang 21Vapor deposition
Physical vapor deposition: The fiber is
passed through a thick cloud of vaporized metal, coating it
Trang 22Manufacturing procedures for Ceramic
matrix composites
1)-Matrix deposition from a gas
phase:- Chemical vapor deposition (CVD) is well suited for this purpose
In the presence of a fiber perform, CVD takes place in between the fibers and their individual filaments and therefore is called chemical vapor
infiltration (CVI)
One example is the manufacture of C/C composites: a C-fiber perform is
exposed to a mixture of argon and a hydrocarbon gas (methane, propane, etc.) at a pressure of around or below 100 kPa and a temperature above
1000 °C
Trang 232)-Matrix forming via pyrolysis of C- and Si-containing
polymers- Hydrocarbon polymers shrink during paralysis, and upon out gassing form carbon with an amorphous, glass-like structure, which by additional heat treatment can be changed to a more graphite-like structure
Other special polymers, where some carbon atoms are replaced by
silicon atoms, the so-called polycarbosilanes, yield amorphous silicon
carbide of more or less stoichiometric composition
• Subsequent curing and pyrolysis yield a highly porous matrix, which is
undesirable for most applications Further cycles of polymer infiltration and pyrolysis are performed until the final and desired quality is achieved
Usually five to eight cycles are necessary
The process is called liquid polymer infiltration (LPI), or polymer
infiltration and pyrolysis (PIP) Here also a porosity of about 15% is
common due to the shrinking of the polymer The porosity is reduced after every cycle
Trang 24APPLICATION OF COMPOSITES
• Applications of Métal matrix composites (MMC)–
1 Carbide drills are often made from a tough cobalt matrix with hard tungsten
carbide particles inside
2 Some tank armors may be made from metal matrix composites, probably steel
reinforced with boron nitride Boron nitride is a good reinforcement for steel because it is very stiff and it does not dissolve in molten steel
3 Honda , Toyotas automobiles has used aluminum metal matrix composite
cylinder liners in some of their engines,
4 Specialized Bicycles has used aluminum MMC compounds for its top of the
range bicycle frames for several years Griffen Bicycles also makes boron
carbide-aluminum MMC bike frames, and Univega briefly did so as well
5 Some automotive disc brakes use MMC Modern high-performance sport
cars, such as those built by Porsche, use rotors made of carbon fiber within a silicon carbide matrix because of its high specific heat and
thermal conductivity
Trang 25A typical composites material construction
for helicopter blade
Trang 26Metal matrix composites
Trang 27Applications Of ceramic matrix composites
• Heat shield systems for space vehicles, which are needed during the re-entry
phase, where high temperatures, thermal shock conditions and heavy vibration loads take place
• Components for high-temperature gas turbines such as combustion chambers,
and turbine blades
• Components for burners, flame holders, and hot gas ducts, where the use of oxide
CMCs has found its way
• Disks breaks and brake system components, which experience extreme thermal
shock
Trang 28Applications of FRP or PMC
• Fibre-reinforced plastics are best suited for any design program that
demands weight savings, precision engineering, finite tolerances, and the simplification of parts in both production and operation A moulded polymer artefact is cheaper, faster, and easier to manufacture than cast aluminum or steel artefact, and maintains similar and sometimes better tolerances and material strengths
• Overall reduction in production and operational costs, economy of parts
results in lower production costs and the weight savings create fuel savings that lower the operational costs of flying the aero plane
Trang 29Design considerations
PMC IN AIRCRAFT PARTS
LIGHT WEIGHT
Trang 30APPLICATION PMC IN RAILWAYS
For passenger coach components.
Components of coaches are generally made of glass
fibre reinforced with polyesters/epoxies, phenolic
resins.
Trang 31Minardi Formula 1
All Formula One race cars have a carbon fibre monocoque structure that protects the driver for all crashes.
Trang 32BMC frame with carbon/epoxy pre-preg
One of the most well-known composite applications in
sports is the so-called "carbon bike" The frame consists
of carbon fibre-reinforced epoxy which makes the frame very stiff and lightweight.
Trang 33BMW M6 with carbon fibre roof
In automotive applications, composites are all around us Just as
in sports applications, weight reduction is pushing the designers to use more and more composites The examples are numerous.
Trang 34Composites Today's Material of
Choice
It gives lower manufacturing costs, composite material continues to
penetrate new markets and applications For industries that
traditionally use assemblies made from more traditional options such
as steel, wood or concrete, composites offer a dynamic alternative – especially for those products that are difficult to assemble or costly to manufacture as a result of increasing steel pieces Glass fibre as
reinforcement dominates the sector of composites material with a
share of 85-90%.
• Composites are created by combining two or more materials to produce a new material that retains important properties from the original elements
Reinforcing fibers give composites the attributes of high strength and
stiffness which in the industrial arena translates to high performance
These fibers are surrounded by a choice of polymers that act as a support system, transferring load between fibers and protecting the fibers from the
operating environment.The burgeoning infrastructure sectors project
involving highways, bridges, airports, buildings, and construction, power generation and transmission, telecommunications are expected
to provide an impetus to the composites industry in India.
Trang 35 Composites can also deliver reduced manufacturing/assembly
costs Since liquid resin can flow into any shape, products with complex shapes can be made at a lower cost when compared
to conventional methods using traditional materials
• Typically, complex shapes of metals or wood require labor intensive
assembly of multiple pieces to create the product Composites can
provide ultimately the lowest cost alternative
The lower cost of unitized composite parts is particularly
attractive for customers that purchase products assembled
from many metallic pieces or have difficult-to-form shapes.
Trang 36Properties of composite
products
Tensile strength of composites is four to six times greater than that of
conventional materials like steel, aluminium etc.
Improved torsion stiffness and impact properties
Higher fatigue endurance limit (up to 60% of the ultimate tensile strength)
30-45% lighter than aluminium structures designed for the same functional
requirements
Lower embedded energy
Composites are less noisy while in operation and provide lower vibration
transmission
Composites are more versatile and can be tailored to meet performance
needs and complex design requirements