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EMERGENCY PREPAREDNESS AND RESPONSE The importance of an effective workplace safety and health program cannot beoveremphasized.. • Emergency escape procedures and emergency escape route

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Chapter 6 SAFETY AND EMERGENCY PREPAREDNESS

INTRODUCTION

Chemicals can be described as the foundation of a modern, progressive society.They are an integral and ever-increasing part of our complex technological world,making it possible for us to enjoy a high standard of living Yet, as the 1984catastrophe in Bhopal, India dramatically and tragically demonstrated, those samechemicals are the source of danger to those in the workplace and surroundinglocales who are regularly exposed to them We have seen how their improper useand handling impact and exact unacceptable human and economic costs on families,industries, communities, and even nations As a result, we have learned thatcorrecting situations that could lead to disasters and catastrophes is moreresponsible and less expensive than hoping accidents will not occur and respondingonly when they inevitably do U.S Congress identified 14 different agenciesengaged in accident prevention-related activities and determined there was a need

to " improve the effectiveness of accident prevention programs and reduce theburden of duplicative requirements on regulated entities." (Senate Report 1989).Not surprisingly, the chemical industry, in hearings before Congress, agreed withthis finding The regulated industry voiced its support " for a coordinatedFederal approach to accident prevention and suggested that an agency like theBoard might most effectively carry out that responsibility" (Senate Report 1989).After looking into the problem and alternative solutions, Congress determinedthere, indeed, was the need to identify and address the causes of the tiiousands ofchemical accidents that occur annually, as well as the need to protect life, propertyand the environment from the costly consequences of those accidents

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As of February 1993, the U.S Environmental Protection Agency's ResourceConservation and Recovery Information System (RCRIS) reported the existence of278,755 facilities that generate, transport, treat, store and/or dispose of regulatedhazardous waste At these locations substances exist whose nature and quantitiespose significant risk to the workers, general public and environment As not alldangerous chemicals or wastes or facilities that handle chemicals are regulated, theactual number of locations may be much higher In addition, according to theNTSB, "about four billion tons of regulated hazardous materials are shipped eachyear with more than 250,000 shipments of hazardous materials entering into theU.S transportation system daily" (NTSB 1992).

The universe of chemical accidents within the United States cannot now beaccurately tallied No comprehensive, reliable historical records exist Further, theEPA acknowledges that many accidents occurring today at fixed facilities andduring transport are not reported to the federal government This underreporting

is documented by several studies (National Environmental Law Center et al 1994).What is known, however, is that in 1991 the National Response Center receivedover 16,300 calls reporting the release or potential release of a hazardous material(US EPA 1993) Also, NTSB's statistics indicate that, in 1992, chemicals wereinvolved in 3,500 fatal highway accidents and 6,500 railroad accidents (NTSB1992) One study analyzed information contained in the EPA's EmergencyResponse Notification System (ERNS) database ERNS (even with its significantlimitations) is acknowledged to be the largest and most comprehensive United Statesdatabase of chemical accident notifications, covering both transportation and fixedfacility accidents The study found that from 1988 through 1992 an average of 19accidents occurred each day 6,900 per year, with more than 34,500 accidentsinvolving toxic chemicals occurring over the five-year period The study's reportemphasized that the findings gravely understated the severity of the United States'chemical accident picture (National Environmental Law Center et al 1994).Although the absolute numbers vary depending on the source of statistics andperiod of time examined, there is no doubt about the effects of chemical accidents

on human life year after year, large numbers of people are killed and injured.Added to these imprecise numbers must be those long-term consequences ofexposure that are not immediately discernable and may not be reflected in studieddatabases low-level exposure to some chemicals may result in debilitatingdiseases that appear only years later During the years 1988 through 1992, sixpercent, or 2,070, of the 34,500 accidents that occurred resulted in immediatedeath, injury and/or evacuation; an average of two chemical-related injuriesoccurred every day during those five years (National Environmental Law Center

et al 1994) Between 1982 and 1986, the EPA's Acute Hazard Events (AHE)database, which contains information only for chemical accidents having acute

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hazard potential, recorded 11,048 events involving releases of extremely hazardoussubstances; these events resulted in 309 deaths, 11,341 injuries and, based onevacuation information for the one-half of the recorded events reporting whethersuch activity occurred, evacuation of 464,677 people from their homes and jobs(USEPA 1989) During the years 1987 through 1991, chemical accidents resulted

in 453 deaths and 1,576 injuries at fixed facilities, while transportation accidentsinvolving chemicals claimed 55 lives and injured 1,252 persons (US EPA 1993).Within a five-year period in the mid-1980s, the EPA's AHE database indicatesthere were 10,933 such accidents, of which 135 resulted in fatalities, 1,020 resulted

in injuries and 500 resulted in evacuations (US EPA 1993)

With this as an introduction, this chapter focuses on emergency preparedness,including proper planning and risk management issues Emphasis is given to thechemical industry, however, many of the concepts reviewed are general and can beapplied across different industry sectors

EMERGENCY PREPAREDNESS AND RESPONSE

The importance of an effective workplace safety and health program cannot beoveremphasized There are many benefits from such a program including increasedproductivity, improved employee morale, reduced absenteeism and illness, andreduced workers' compensation rates; however, incidents still occur in spite ofefforts to prevent them Therefore, proper planning for emergencies is necessary

to minimize employee injury and property damage Typical emergencies includeaccidental releases of toxic gases, chemical spills, fires, explosions, and bodilyharm and trauma caused by workplace violence

The effectiveness of response during emergencies depends on the amount ofplanning and training performed Senior level management must show its supportfor plant safety programs and the importance of emergency planning Ifmanagement is not interested in employee protection and in minimizing propertyloss, little can be done to promote a safe workplace It is therefore management'sresponsibility to see that a program is instituted and that it is frequently reviewedand updated The input and support of all employees must be obtained to ensure aneffective program The emergency response plan should be developed locally andshould be comprehensive enough to deal with all types of emergencies specific tothat site When emergency action plans are required by a particular OSHAstandard, the plan must be in writing; except for firms with 10 or fewer employees,the plan may be communicated orally to employees The plan must include, as aminimum, the following elements:

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• Emergency escape procedures and emergency escape route assignments,

• Procedures to be followed by employees who remain to perform (or shut

down) critical plant operations before the plant is evacuated,

• Procedures to account for all employees after emergency evacuation has

been completed,

• Rescue and medical duties for those employees who are to perform them,

• The preferred means for reporting fires and other emergencies, and

• Names or regular job titles of persons or departments to be contacted for

further information or explanation of duties under the plan

The emergency action plan should address all potential emergencies that can beexpected in the workplace Therefore, it will be necessary to perform a hazard audit

to determine toxic materials in the workplace, hazards, and potentially dangerousconditions For information on chemicals, the manufacturer or supplier can becontacted to obtain Material Safety Data Sheets (MSDS) These forms describe thehazards that a chemical may present, list precautions to take when handling,storing, or using the substance, and outline emergency and first-aid procedures.The employer must list in detail the procedures to be taken by those employees whomust remain behind to care for essential plant operations until their evacuationbecomes absolutely necessary This may include monitoring plant power supplies,water supplies, and other essential services that cannot be shut down for everyemergency alarm, and use of fire extinguishers

For emergency evacuation, the use of floor plans or workplace maps that clearlyshow the emergency escape routes and safe or refuge areas should be included inthe plan All employees must be told what actions they are to take in emergencysituations that may occur in the workplace, such as a designated meeting locationafter evacuation This plan must be reviewed with employees initially when the plan

is developed, whenever the employees' responsibilities under the plan change, andwhenever the plan is changed A copy should be kept where employees can refer

to it at convenient times In fact, to go a step further, the employer could providethe employees with a copy of the plan, particularly all new employees

A chain of command should be established to minimize confusion so that employeeswill have no doubt about who has authority for making decisions Responsibleindividuals should be selected to coordinate the work of the emergency responseteam In larger organizations, there may be a plant coordinator in charge of plant-wide operations, public relations, and ensuring that outside aid is called in Because

of the importance of these functions, adequate backup must be arranged so thattrained personnel are always available The duties of the Emergency ResponseTeam Coordinator should include the following:

• Assessing the situation and determining whether an emergency exists that

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requires activating the emergency procedures,

• Directing all efforts in the area including evacuating personnel,

• Ensuring that outside emergency services such as medical aid and local

fire departments are called in when necessary, and

• Directing the shutdown of plant operations when necessary

During a major emergency involving a fire or explosion it may be necessary toevacuate offices in addition to manufacturing areas Also, normal services, such aselectricity, water, and telephones, may be nonexistent Under these conditions, itmay be necessary to have an alternate area to which employees can report or thatcan act as a focal point for incoming and outgoing calls Since time is an essentialelement for adequate response, the person designated as being in charge shouldmake this the alternate headquarters so that he/she can be easily reached.Emergency communications equipment such as amateur radio systems, publicaddress systems, or portable radio units should be present for notifying employees

of the emergency and for contacting local authorities, such as law enforcementofficials, private sector charitable groups, and the fire department A method ofcommunication also is needed to alert employees to the evacuation or to take otheraction as required in the plan

Alarms must be audible or seen by all people in the plant and have an auxiliarypower supply in the event electricity is affected The alarm must be distinctive andrecognizable as a signal to evacuate the work area or perform actions designatedunder the emergency action plan

The employer must explain to each employee the means for reporting emergencies,such as manual pull box alarms, public address systems, or telephones Emergencyphone numbers should be posted on or near telephones, on employees' noticeboards, or in other conspicuous locations The warning plan should be in writingand management must be sure each employee knows what it means and what action

is to be taken It may be necessary to notify other key personnel such as the plantmanager or physician during off-duty hours An updated written list of keypersonnel should be kept listed in order of priority

Management will need to know when all personnel have been accounted for Thiscan be difficult during shift changes or if contractors are on site A responsibleperson in the control center must be appointed to account for personnel and toinform police or Emergency Response Team members of those persons believedmissing

Emergency Response Teams are the first line of defense in emergencies Beforeassigning personnel to these teams, the employer must assure that employees arephysically capable of performing the duties that may be assigned to them

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Depending on the size of the plant there may be one or several teams trained in thefollowing areas:

• Use of various types of fire extinguishers,

• First aid, including cardiopulmonary resuscitation (CPR),

• Shutdown procedures,

• Evacuation procedures,

• Chemical spill control procedures,

• Use of self-contained breathing apparatus (SCBA),

• Search and emergency rescue procedures,

• Incipient and advanced stage fire fighting, and

• Trauma counseling

The type and extent of the emergency will depend on the plant operations and theresponse will vary according to the type of process, the material handled, thenumber of employees, and the availability of outside resources OSHA's HazardCommunication Standard (29 CFR part 1910.1200) is designed to ensure that thehazards of all chemicals produced or imported are evaluated and that informationconcerning their hazards is transmitted to employers and employees This is done

by means of comprehensive hazard communication programs including containerlabeling and other forms of warnings, material safety data sheets, and employeetraining Emergency Response Teams should be trained in the types of possibleemergencies and the emergency actions to be performed They are to be informedabout special hazards such as storage and use of flammable materials, toxicchemicals, radioactive sources, and water-reactive substances to which they may

be exposed during fire and other emergencies It is important to determine when not

to intervene For example, team members must be able to determine if the fire istoo large for them to handle or whether search and emergency rescue proceduresshould be performed If there is the possibility of members of the EmergencyResponse Team receiving fatal or incapacitating injuries, they should wait forprofessional fire fighters or emergency response groups

Training is important to the effectiveness of an emergency plan Beforeimplementing an emergency action plan, a sufficient number of persons must betrained to assist in the safe and orderly evacuation of employees Training for eachtype of disaster response is necessary so that employees know what actions arerequired In addition to the specialized training for Emergency Response Teammembers, all employees should be trained in the following:

• Evacuation plans,

• Alarm systems,

• Reporting procedures for personnel,

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• Shutdown procedures, and

• Types of potential emergencies.

These training programs must be provided as follows:

• Initially when the plan is developed,

• For all new employees,

• When new equipment, materials, or processes are introduced,

• When procedures have been updated or revised,

• When exercises show that employee performance must be improved, and

• At least annually

The emergency control procedures should be written in concise terms and be madeavailable to all personnel A drill should be held for all personnel, at randomintervals at least annually, and an evaluation of performance made immediately bymanagement and employees When possible, drills should include groups supplyingoutside services such as fire and police departments In buildings with severalplaces of employment, the emergency plans should be coordinated with othercompanies and employees in the building Finally, the emergency plan should bereviewed periodically and updated to maintain adequate response personnel andprogram efficiency

Effective personal protection is essential for any person who may be exposed topotentially hazardous substances In emergency situations employees may beexposed to a wide variety of hazardous circumstances, including:

• Chemical splashes or contact with toxic materials,

• Falling objects and flying particles,

• Unknown atmospheres that may contain toxic gases, vapors or mists, or

inadequate oxygen to sustain life,

• Fires and electrical hazards, and

• Violence in the workplace

It is extremely important that employees be adequately protected in these situations.Some of the safety equipment that may be used includes:

• Safety glasses, goggles, or face shields for eye protection,

• Hard hats and safety shoes for head and foot protection,

• Proper respirators for breathing protection,

• Whole body coverings chemical suits, gloves, hoods, and boots for body

protection from chemicals, and

• Body protection for abnormal environmental conditions such as extreme

temperatures

The equipment selected must meet the criteria contained in the OSHA standards or

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described by a nationally recognized standards producing organization The choice

of proper equipment is not a simple matter and consultation should be made withhealth and safety professionals before making any purchases Manufacturers anddistributors of health and safety products may be able to answer questions if theyhave enough information about the potential hazards involved Professionalconsultation will most likely be needed in providing adequate respiratory protection.Respiratory protection is necessary for toxic atmospheres of dust, mists, gases, orvapors and for oxygen-deficient atmospheres There are four basic categories ofrespirators:

1 Air-purifying devices (filters, gas masks, and chemical cartridges), which

remove contaminants from the air but cannot be used in oxygen-deficientatmospheres

2 Air-supplied respirators (hose masks, air line respirators), which should

not be used in atmospheres that are immediately dangerous to life orhealth

3 Positive-pressure self-contained breathing apparatus (SCBA), which are

required for unknown atmospheres, oxygen-deficient atmospheres, oratmospheres immediately dangerous to life or health

4 Escape masks

Before assigning or using respiratory equipment the following conditions must bemet:

• A medical evaluation should be made to determine if the employees are

physically able to use the respirator

• Written procedures must be prepared covering safe use and proper care of

the equipment, and employees must be trained in these procedures and inthe use and maintenance of respirators

• A fit test must be made to determine a proper match between the facepiece

of the respirator and the face of the wearer This testing must be repeatedperiodically Training must provide the employee an opportunity to handlethe respirator, have it fitted properly, test its facepiece-to-face seal, wear

it in normal air for a familiarity period, and wear it in a test atmosphere

• A regular maintenance program must be instituted including cleaning,

inspecting, and testing of all respiratory equipment Respirators used foremergency response must be inspected after each use and at least monthly

to assure that they are in satisfactory working condition A written record

of inspection must be maintained

• Distribution areas for equipment used in emergencies must be readily

accessible to employees

• A positive-pressure self-contained breathing apparatus (SCBA) offers the

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best protection to employees involved in controlling emergency situations.

It must have a minimum service life rating of at least 30 minutes.Conditions that require a positive-pressure SCBA include the following:(1) Leaking cylinders or containers, smoke from chemical fires, orchemical spills that indicate high potential for exposure to toxicsubstances; (2) Atmospheres with unknown contaminants or unknowncontaminant concentrations, confined spaces that may contain toxicsubstances, or oxygen-deficient atmospheres

Emergency situations may involve entering confined spaces to rescue employeeswho are overcome by toxic compounds or who lack oxygen These permit-requiredconfined spaces include tanks, vaults, pits, sewers, pipelines, and vessels Entryinto permit-required confined spaces can expose the employee to a variety ofhazards, including toxic gases, explosive atmospheres, oxygen deficiency, electricalhazards, and hazards created by mixers and impellers that have not been deactivatedand locked out Personnel must never enter a permit-required confined space unlessthe atmosphere has been tested for adequate oxygen, combustibility, and toxicsubstances Conditions in a permit-required confined space must be consideredimmediately dangerous to life and health unless shown otherwise If a permit-required confined space must be entered in an emergency, the following precautionsmust be adhered to:

• All lines containing inert, toxic, flammable, or corrosive materials must

be disconnected or blocked off before entry

• All impellers, agitators, or other moving equipment inside the vessel must

be locked out

• Appropriate personal protective equipment must be worn by employees

before entering the vessel Mandatory use of harnesses must be stressed

• Rescue procedures must be specifically designed for each entry A trained

stand-by person must be present This person should be assigned a fullycharged, positive-pressure, self-contained breathing apparatus with a fullfacepiece The stand-by person must maintain unobstructed lifelines andcommunications to all workers within the permit-required confined spaceand be prepared to summon rescue personnel if necessary The stand-byperson should not enter the confined space until adequate assistance ispresent While awaiting rescue personnel, the stand-by person may make

a rescue attempt utilizing lifelines from outside the permit-requiredconfined space

A more complete description of procedures to follow while working in confinedspaces may be found in the OSHA standard for permit-required confined spaces,

29 CFR 1910.145 and the National Institute for Occupational Safety and Health

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(NIOSH) Publication Number 80-106, Criteria for a Recommended Standard Working in Confined Spaces.

In a major emergency, time is critical factor in minimizing injuries Most smallbusinesses do not have a formal medical program, but they are required to have thefollowing medical and first-aid services:

• In the absence of an infirmary, clinic, or hospital in close proximity to the

workplace that can be used for treatment of all injured employees, theemployer must ensure that a person or persons are adequately trained torender first aid The first aid is to begin within 3 to 4 minutes of theincident if the injury is of a serious nature

• Where the eyes or body of any employee may be exposed to injurious

corrosive materials, eye washes or suitable equipment for quick drenching

or flushing must be provided in the work area for immediate emergencyuse Employees must be trained to use the equipment

• The employer must ensure the ready availability of medical personnel for

advice and consultation on matters of employees' health This does notmean that health care must be provided, but rather that, if health problemsdevelop in the workplace, medical help will be available to resolve them

To fulfill the above requirements, the following actions should be considered:

• Survey the medical facilities near the place of business and make

arrangements to handle routine and emergency cases A written emergencymedical procedure should then be prepared for handling accidents withminimum confusion

• If the business is located far from medical facilities, at least one and

preferably more employees on each shift must be adequately trained torender first aid The American Red Cross, some insurance carriers, localsafety councils, fire departments, and others may be contacted for thistraining

• First-aid supplies should be provided for emergency use This equipment

should be ordered through consultation with a physician

• Emergency phone numbers should be posted in conspicuous places near

or on telephones

• Sufficient ambulance service should be available to handle any emergency

This requires advance contact with ambulance services to ensure theybecome familiar with plant location, access routes, and hospital locations.During an emergency, it is often necessary to secure the area to preventunauthorized access and to protect vital records and equipment An off-limits areamust be established by cordoning off the area with ropes and signs It may benecessary to notify local law enforcement personnel or to employ private security

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personnel to secure the area and prevent the entry of unauthorized personnel.Certain records also may need to be protected, such as essential accounting files,legal documents, and lists of employees' relatives to be notified in case ofemergency These records may be stored in duplicate outside the plant or inprotected secure locations within the plant.

The following is a list of some of the OSHA requirements pertaining to emergencyresponse These references refer to appropriate sections of the Occupational Safety

and Health Standards (Title 29, Code of Federal Regulations, Part 1910, which are

the OSHA General Industry Standards)

Subpart E - Means of Egress

910.37 Means of egress

1910.38 Employee emergency plans and fire prevention plans

Appendix to Subpart E: Means of egress

Subpart H - Hazardous Materials

1910.119 Process safety management of highly hazardous chemicals

1910.120 Hazardous waste operations and emergency response

Subpart I - Personal Protective Equipment

1910.132 General requirements for personnel protection

1910.133 Eye and face protection

1910.134 Respiratory protection

1910.135 Occupational head protection

1910.136 Occupational foot protection

1910.138 Hand protection

Subpart J - General Environmental Controls

1910.146 Permits for required confined spaces

1910.147 Control of hazardous energy sources

Subpart K - Medical and First Aid

1910.151 Medical services and first aid

Subpart L - Fire Protection

1910.155-156 Fire protection and fire brigades

1910.157- 163 Fire suppression equipment

1910.164 Fire detection systems

1910.165 Employee alarm systems

Appendix A-E of Subpart L

Subpart R - Special Industries, Electrical Power

Generation, Transmission, and Distribution

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Subpart Z - Toxic and Hazardous Substances

1910.1030 Bloodborne pathogens

1910.1200 Hazard communication

Much of the planning and program development for responding to occupationalemergencies will require professional assistance Many public and private agenciesprovide information and services free or at minimal cost (e.g., Federal, State, andlocal health and labor departments, insurance carriers, and local universities) Afterhaving exhausted these sources, consider using a private consultant selected bymatching his/her specialty with your specific needs If there is a carrier forworkers' compensation insurance, that company probably has safety and healthspecialists on staff who are familiar with minimum standards and technicalinformation currently available and may be quite helpful in advising about accidentand illness prevention and control Trade associations often have technicalmaterials, programs, and industry data available for specific needs The Department

of Labor through the Occupational Safety and Health Administration (OSHA)provides information in interpreting the law and on meeting the applicablestandards This information is available free of charge or obligation The OSHAArea Office or State Plan Office nearest to the plant may be contacted for thisinformation

The Department of Health and Human Services through the National Institute forOccupational Safety and Health (NIOSH) provides printed material relating toemployee safety and health in the workplace Staff from this agency will performindustrial hygiene surveys of plants upon request of employers or employees.Machine or product manufacturers can be helpful in providing additionalinformation on precautions to take in using their products Any special problemsshould be referred to them first Professional societies in the safety, industrialhygiene, and medical fields issue publications in the form of journals, pamphlets,and books that may be quite useful (e.g., American Society of Safety Engineers orthe Occupational Health Institute) They can also recommend individuals from theirsocieties to serve as consultants

Effective management of worker safety and health protection is a decisive factor inreducing the extent and severity of work-related injuries and their related costs Toassist employers and employees in developing effective safety and health programs,

OSHA published recommended Safety and Health Management Guidelines [Federal

Register 54(18): 3908-3916, January 26, 1988] These voluntary guidelines apply

to all places of employment covered by OSHA The guidelines identify four generalelements that are critical to the development of a successful safety and healthmanagement program:

• Management commitment and employee involvement;

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• Worksite analysis;

• Hazard prevention and control; and

• Safety and health training

The guidelines recommend specific actions, under each of these general elements,

to achieve an effective safety and health program A copy of the guidelines can beobtained from the OSHA Publications Office, U.S Department of Labor, 200Constitution Avenue, N.W., Room N3101, Washington DC 20210 The

Occupational Safety and Health Act of 1970, under Section 18(b), encourages States

to develop and operate their own State job safety and health plans under theapproval and monitoring of OSHA Twenty-five states and territories operate suchplans They are required to set standards that are at least as effective as the federal,conduct inspections to enforce those standards (including inspections in response

to workplace complaints), cover State and local government employees, and operateoccupational safety and health training and education programs In addition, allStates provide on-site consultation to help employers to identify and correctworkplace hazards Such consultation may be provided either under the plan orthrough a special agreement under section 7(c)(l) of the Act Federal OSHA doesnot conduct enforcement activities in the state plan States, except in very limitedcircumstances A listing of those States that operate approved State plans can beobtained from your local OSHA Area Office A comprehensive customer serviceposter listing OSHA services and how to contact agency Regional, Area, andDistrict offices is available from OSHA's Publications Office, 200 ConstitutionAvenue, N.W Washington D.C 20210, Rm N3101 Telephone (202) 219-4667.Free on-site safety and health consultation services are available to employers in allstates who want help in establishing and maintaining a safe and healthful workplace.This service is largely funded by OSHA Primarily developed for smalleremployers with more hazardous operations, the consultation service is delivered bystate governments employing professional safety consultants and health consultants.Comprehensive assistance includes an appraisal of all mechanical systems, physicalwork practices, and environmental hazards of the workplace and all aspects of theemployer's present job safety and health program This program is completelyseparate from OSHA's inspection efforts No penalties are proposed or citationsissued for any safety or health problems identified by the consultant The service

is confidential OSHA's area offices offer a variety of informational services, such

as publications, audiovisual aids, technical advice, and speakers for special events.OSHA's Training Institute in Des Plaines, IL, provides basic and advanced courses

in safety and health for federal and state compliance officers, state consultants,federal agency personnel, and private sector employers, employees, and theirrepresentatives OSHA also provides funds to nonprofit organizations, throughgrants, to conduct workplace training and education in subjects where OSHA

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believes there is a lack of workplace training Grants are awarded annually Grantrecipients are expected to contribute 20 percent of the total grant cost Thefollowing is a list of references where the reader can obtain detailed information:

AIHA Hygienic Guide Series American Industrial Hygiene Association, 2700

Prosperity Ave., Fairfax, VA 22031 Separate data sheets on specific substancesgiving hygienic standards, properties, industrial hygiene practices, specificprocedures, and references

ANSI Standards, Z37 Series, Acceptable Concentrations of Toxic Dusts and Gases.

American National Standards Institute, 11 West 42nd Street, New York, NY

10036 These guides represent a consensus of interested parties concerningminimum safety requirements for the storage, transportation, and handling of toxicsubstances; they are intended to aid manufacturers, consumers, and the public

ASTM Standards with Related Material American Society for Testing and

Materials, 1916 Race Street, Philadelphia, PA 19103

The following is a list of standards and specification groups where additionalinformation can be obtained:

American National Standards Institute, 11 West 42nd Street, New York, NY

10036, coordinates and administers the federated voluntary standardization system

in the United States

American Society for Testing and Materials, 1916 Race Street, Philadelphia, PA

10103 World's largest source of voluntary consensus standards for materials,products, systems, and services

The following is a list of fire protection organizations:

Factory Insurance Association, 85 Woodland Street, Hartford, CT 06105.Composed of capital stock insurance companies to provide engineering, inspections,and loss adjustment service to industry

Factory Mutual System, 1151 Boston-Providence Turnpike, Norwood, MA 02062

An industrial fire protection, engineering, and inspection bureau established andmaintained by mutual fire insurance companies

National Fire Protection Association, 470 Batterymarch Park, Quincy, MA 02269.The clearinghouse for information on fire protection and fire prevention also writesNFPA standards Nonprofit technical and educational organization

Underwriter Laboratories, Inc., 207 East Ohio Street, Chicago, IL 60611 profit organization whose laboratories publish annual lists of manufacturers whoseproducts proved acceptable under appropriate standards

Not-for-The following is a list of key references for more in-depth reading:

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Chemical Industries Association, Chemical Industry Safety and Health Council.

Recommended Procedures for Handling Major Emergencies Alembic House 93

Albert Embarkment London, SEIO 7TU, July 1976.

Krikorian, Michael "Advanced Planning is the Key to Controlling Emergencies

and Disasters in the Workplace." Prof Safety: 39-42, December 1977.

Lee, W.R Sources of Consultation and Reference Aids Section XI, in H.M Key,A.F Henschel, J.Butler, R.N Ligo, I.R Tabershaw, and L Ede (Eds):

Occupational Diseases: A Guide to Their Recognition NIOSH Publication No

77-181 Cincinnati, 1977 Pp 523-556 Also available as Lee, W.R Consultation and

Reference Sources for Occupational Health / Occu Med 17(7): 446-456, July

1975

National Safety Council Accident Prevention Manual for Industrial Operations

Administration and Programs 8th ed Chicago, 1981 Pp 439-471.

U.S Department of Labor Occupational Safety and Health Administration OSHA

Handbook for Small Businesses OSHA 2209 Washington, DC, 1996.

Occupational Safety and Health Administration Principal Emergency Response and

Preparedness Requirements in OSHA Standards and Guidance for Safety and Health Programs OSHA 3122 Washington, DC, 1990.

U.S Department of Health and Human Services National Institute for

Occupational Safety and Health, Safety and Health Alert: Request for Assistance In

Preventing Homicide In the Workplace U.S Department of Health and Human

Services, Cincinnati, Ohio, September 1993, Number 93-109

Public Health Service National Institute for Occupational Safety and Health A Guide to Industrial Respiratory Protection NIOSH Publication No 76-189.

Cincinnati, 1976

Criteria for a Recommended Standard Working in Confined Spaces NIOSH

Publication No.80-106 Cincinnati, 1980

Respiratory Protection An Employer's Manual NIOSH Publication No 78-198A.

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Site Security Issues

In the past, the major concern for site security evolved around issues whereby thepublic might be exposed directly to hazardous materials Facilities that handlechemicals are actively engaged in managing risks to ensure the safety of theirworkers and the community Most of their efforts focus on ensuring that the facility

is designed and operated safely on a daily basis, using well-designed equipment,preventive maintenance, up-to-date operating procedures, and well-trained staff.Because of today's increased concern about terrorism and sabotage, companies arealso paying increased attention to the physical security of facility sites, chemicalstorage areas, and chemical processes All companies, regardless of the size of theiroperations, have some measure of site security in place to minimize crime and toprotect company assets This is especially true for facilities that handle extremelyhazardous materials Under section 112(r) of the Clean Air Act (CAA), EPAdeveloped Risk Management Program (RMP) regulations that require facilities toexamine their chemical accident risk and develop a formalized plan to address it.The increased concern for the physical security of facilities that handle extremelyhazardous substances is also reflected in recent government actions Highlightingsite security, the Chemical Safety Information, Site Security and Fuels RegulatoryRelief Act contains a major provision that requires the Department of Justice toprepare reports to be submitted to Congress describing the effectiveness of RMPregulations in reducing the risk of criminally caused releases, the vulnerability offacilities to criminal and terrorist activity, and the security of transportation of listedtoxic and flammable substances Threats may come in different forms and fromdifferent sources Threats from outside the facility could affect people and thefacility itself, and may involve trespassing, unauthorized entry, theft, burglary,vandalism, bomb threats, or terrorism Threats from inside the facility may arisefrom inadequate designs, management systems, staffing or training, or otherinternal problems These may include theft, substance abuse, sabotage, disgruntledemployee or contractor actions, and workplace violence, among others Threats arenot restricted to people and property, but could also involve sensitive facilityinformation Both facility outsiders and employees or contractors could pose threats

to data storage and data transmission of, for example, confidential information,privacy data, and contract information They could also pose a threat to computer-controlled equipment These threats may include breaches in data access andstorage, uncontrolled dissemination of information, destruction of information orthreats to automated information systems Most security measures are intended toprevent intruders from gaining access to the site or to limit damage

Most facilities have some measures that are intended to prevent intruders from

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entering the grounds or buildings These measures may include fences, walls,locked doors, or alarm systems The location of the facilities and the types ofstructures will determine how much and what type of protection a facility needs Inaddition to basic measures, some facilities also provide physical protection of siteutilities at the fence perimeter Security lighting (good lighting around buildings,storage tanks, and storage areas) can also make it very difficult for someone toenter the facility undetected Some facilities find the need to augment thesemeasures with intrusion detection systems - video surveillance, security guards atfixed posts, rounds/mobile patrols, alarm stations, and detectors for explosives andmetal.

To protect against unauthorized people coming in through normal entrances,security clearances, badges, procedures for daily activities and abnormalconditions, as well as vehicular and pedestrian traffic control, can provide efficientaccess for employees while ensuring that any visitors are checked and clearedbefore entering Many facilities have procedures to recover keys from employeeswho leave and to immediately remove the employee's security codes from systems

At times it may be wise to consider additional measures, such as changing locks,when a disgruntled employee leaves

In addition to protecting a facility from intruders, it is important to limit the damagethat an intruder (whether physically at the site or "hacking" into the company'scomputers) or an employee could do Most of the steps to limit damage areprobably things you already do as part of good process safety management, becausethey also limit the loss of chemicals if management systems or equipment fails or

an operator makes a mistake These steps can be related to either the design of thefacility and its processes or to procedures implemented

A well-designed facility, by its layout, limits the possibility that equipment will bedamaged and, by its process design, limits the quantity of chemical that could bereleased Facility and process design (including chemicals used) determine the needfor safety equipment, site security, buffer zones, and mitigation planning.Eliminating or attenuating to the extent practicable any hazardous characteristicduring facility or process design is generally preferable to simply adding on safetyequipment or security measures The option of locating processes with hazardouschemicals in the center of a facility can thwart intruders and vandals who remainoutside the facility fenceline Transportation vehicles, which are usually placarded

to identify the contents, may be particularly vulnerable to attack if left near thefenceline or unprotected However, for some facilities and processes, the option oflocating the entire process at the center of the site may not be feasible Somefacilities may need to consider external versus internal threats, such as the threat

to workers if an accidental release occurs, or the access to the process in case of an

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emergency response Where feasible, providing layers of security will protectequipment from damage These layers could include, for example, blast resistantbuildings or structures Enclosing critical valves and pumps (behind fences or inbuildings) can make it less likely that an intruder will be able to reach them, avehicle will be able to collide with them, or that releases are compounded because

of damage to neighboring equipment Chlorine tanker valves are an example ofequipment design with several layers of security: (1) a heavy steel dome with lid;(2) a heavy cable sealing system that requires cable cutters to remove; (3) a heavyduty valve that can withstand abuse without leaking; and (4) a seal plug in eachvalve As many as three different tools would be needed to breach the container'sintegrity If equipment is located where cars, trucks, forklifts, or constructionequipment could collide with it or drop something on it, the equipment should beconstructed from materials that could stand some abuse In general, you should giveconsideration to collision protection to any equipment containing hazardouschemicals with, for example, collision barriers Layers of security may also beapplied to communications/computer security Some companies have developedalternate capabilities and systems to protect receipt and transmission of confidentialinformation Backup power systems and/or conditioning systems can be important,particularly if processes are computer controlled Access to computer systems used

to control processes may need to be controlled so that unauthorized users cannotbreak in; appropriate computer authentication and authorization mechanisms on allcomputer systems and remote access may prove useful; entrance into control roomsmay need to be monitored and limited to authorized personnel For emergencycommunications, some companies use radios and cell phones as a backup to theregular phone system Well-designed equipment will usually limit the loss ofmaterials if part of a process fails Excess flow check valves, for example, will stopflow from an opened valve if the design flow rate is exceeded These valves arecommonly installed on chlorine tankcars and some anhydrous ammonia trailers, aswell as on many chemical processes Like excess flow valves, fail-safe systems canensure that if a release occurs, the valves in the system will close, shutting off theflow Breakaway couplings, for example, shut off flow in transfer systems, such

as loading hoses, to limit the amount released to the quantity in the hose Ifhazardous liquids are staged or stored on-site, it's prudent to consider containmentsystems (e.g., buildings, dikes, and trenches) that can slow the rate at which thechemical evaporates and provide time to respond Double-walled vessels can alsoprotect against attempts to rupture a tank The installation of chemical monitors thatautomatically notify personnel of off-hour releases could be important if yourfacility is not staffed during certain periods (e.g., overnight) Such monitors,however, are not available for all chemicals The appropriateness of monitors, andany other equipment design solutions, will depend on site-specific conditions

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A company's policies and procedures can also limit the damage caused by a release.

As with design issues, the procedural steps you routinely take to operate safely alsohelp protect your facility from attacks Maintaining good labor relations mayprotect your facility from actions by either employees or contractors Opennegotiations, workplace policies emphasizing that violence and substance abuse arenot tolerated, and adequate training and resources to support these policies areimportant considerations The goal is to develop a workforce and managementcapacity to identify and solve problems by working together Following are severalexamples of specific areas where procedures and policies can prevent or limit thedamage of a release As a matter of good practice, as well as site security, you mayconsider disconnecting storage tanks and delivery vehicles from connecting piping,transfer hoses, or distribution systems when not in use Leaving the tanks linked

to the process or pipeline increases the chance of a release because the hoses orpipes are often more vulnerable than the tanks In addition to accurately monitoringyour inventory, another practice you may want to adopt is limiting the inventory ofhazardous materials to the minimum you need for your process This policy limitsthe quantity of a hazardous material that could be released You could also consideractions such as substituting less hazardous substances when possible to makeprocesses inherently safer Written procedures are also an important tool inprotecting your facility As part of your regular operating procedures, you probablyhave emergency shutdown procedures These procedures, and workers trained intheir use, can limit the quantity released The procedures are particularly important

if you have processes that operate under extreme conditions (high or low pressures,temperature) where rapid shutdown can create further hazards if done improperly

In reviewing a contingency plan, consider, if necessary, revisions to addressvandalism, bomb threats, burglary - including evaluating the desirability of yourfacility as a target - working with local law enforcement, and providing extrasecurity drills and audits Many companies find that working with local lawenforcement is an effective means of evaluating security risks As a matter of goodpractice, for both process and response equipment, it is important to have aprogram that ensures that all equipment is subject to inspection and to correctiveand preventive maintenance In this way, you can be sure that the safety systemsyou install will operate as designed

Steps taken to operate safely will often serve to address security concerns as well.Considering inherent safety in the design and operation of any facility will have thebenefit of helping to prevent and/or minimize the consequences of any release.Before taking steps to improve site security, evaluate the current system anddetermine whether it is adequate Factors to consider include: (1) The chemicalsstored at your site; some chemicals may be particularly attractive targets because

of the potential for greater consequences if released (2) The location of the site;

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sites in densely populated areas may need more security than those at a distancefrom populations (3) The accessibility of the site; are the existing security systems(e.g., fences, security lighting, security patrols) adequate to limit access to the site?(4) The age and type of buildings; older buildings may be more vulnerable becausethey have more windows; some newer building are designed for easy access (5)Hours of operation; a facility that operates 24-hours day may need less securitythan a facility that is unoccupied at night Decisions about improving site securityshould be made after evaluating how vulnerable your site is to threats and whatadditional measures, if any, are appropriate to reduce your vulnerability Eachfacility should make its own decision based on its circumstances.

If a facility produces, processes, handles, or stores extremely hazardous substances,under the Clean Air section 1 12(r)(l), it has a general duty "to identify hazardswhich may result from such releases, using appropriate hazard assessmenttechniques, to design and maintain a safe facility taking such steps as are necessary

to prevent releases, and to minimize the consequences of accidental releases which

do occur." Several organizations (e.g., ASTM, ANSI) have standards for sitesecurity or include site security issues in their codes The National Fire Protection

Association (NFPA) has a standard NFPA- 601, Standard for Site Security Services

for Fire Loss Prevention The American Petroleum Institute addresses security

issues in RP 554, Process Instrumentation and Control Likewise, the Chemical Manufacturers Association addresses this issue through the Responsible Care

Employee Health and Safety Code Site Security Management Practice Protocols

developed under the Responsible Distribution Process cover security concerns Youcan contact the following websites for additional security information:

www energysecuritvcouncil org The Energy Security Council is a national industryassociation to assist law enforcement agencies and energy companies in combatingall types of criminal activity

www.nfpa.org The National Fire Protection Association provides standards,research, training, and education to reduce the burden of fire and other hazards.www.nsc.org The National Safety Council provides general safety information onchemical and environmental issues

www asisonline.org and www.securitymanagement.com The American Society forIndustrial Security develops educational programs and materials that addresssecurity concerns Its Security Management Magazine site provides an onlineversion of its magazine

www siaonline org The Security Industry Association provides general securityinformation

www atsdr cdc gov The Agency for Toxic Substances and Disease Registry site

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provides a 10-step procedure to analyze, mitigate, and prevent public health hazardsresulting from terrorism involving industrial chemicals.

www aiche org/ccps The Center for Chemical Process Safety (CCPS) is anindustry-driven, nonprofit professional organization affiliated with the AmericanInstitute of Chemical Engineers (AIChE) It is committed to developing engineeringand management practices to prevent or mitigate the consequences of catastrophicevents involving the release of chemicals that could harm employees, neighbors andthe environment

www cdc gov/niosh The National Institute for Occupational Safety and Healthprovides multiple resources on workplace violence prevention

The Complete Manual of Corporate and Industrial Security, by Russell L Bintliff

(Prentice Hall, 1992) provides detailed discussions of the advantages anddisadvantages

EPA's Risk Management Programs for Chemical Accident Release Prevention (40

CFR 68) requires regulated facilities to develop and implement appropriate riskmanagement programs to minimize the frequency and severity of chemical plantaccidents In keeping with recent regulatory trends, EPA is requiring aperformance-based approach towards compliance with the risk managementprogram rule In recent developments, the amendments to the RMP rule, proposed

on April 17, 1998 were signed by Administrator Browner on December 29th andpublished in the Federal Register on January 6, 1998 The RMP that is required to

be developed by facilities must include a description of the hazard assessment,prevention program, and the emergency response program Facilities are required

to submit the RMP to governmental agencies, the state emergency responsecommission, the local emergency planning committees, and as needed the RMPwould be communicated to the public The final rule defines the worst-case release

as the release of the largest quantity of a regulated substance from a vessel orprocess line failure, including administrative controls and passive mitigation thatlimit the total quantity involved or release rate For gases, the worst-case releasescenario assumes the quantity is released in 10 minutes For liquids, the scenarioassumes an instantaneous spill and that the release rate to the air is the volatilizationrate from a pool 1 cm deep unless passive mitigation systems contain the substance

in a smaller area For flammables, the scenario assumes an instantaneous releaseand a vapor cloud explosion using a 10 percent yield factor For alternative

scenarios (note: EPA is using the term alternative scenario as compared to the term

more-likely scenario used earlier in the proposed rule), facilities may take credit for

both passive and active mitigation systems Appendix A of the final rule listsendpoints for toxic substances to be used in worst-case and alternative scenarioassessment The toxic endpoints are based on ERPG-2 or level of concern data

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compiled by EPA The flammable endpoints represent vapor cloud explosiondistances based on overpressure of 1 psi or radiant heat distances based on exposure

to 5 kW/m2 for 40 seconds The promulgation of the final rule follows some recentactions by EPA to amend the final list rule promulgated earlier by EPA on January

31, 1994 These recent actions include the following proposed amendments to thelist rule: (1) Exemption of crude oil prior to initial processing and gasoline; (2) Therisk management program rule does not apply to sources in the outer continentalshelf, Entire weight of the mixture containing a flammable substance shall betreated as a regulated substance unless experimental measurements can demonstratethat the mixture does not meet NFPA 4 criteria, and Exemption of explosives (asdefined under DOT Class 1, Division 1 1 - 4 9 CFR 172.101) from coverage bythe rule

The EPA has proposed a stay of effectiveness of the risk management program rulerequirements for those facilities impacted by the proposed amendments to the listrule

ACCIDENT INVESTIGATION PRINCIPLES

An accident is any unplanned event that results in personal injury or in propertydamage When the personal injury requires little or no treatment, it is minor If itresults in a fatality or in a permanent total, permanent partial, or temporary total(lost-time) disability, it is serious Similarly, property damage may be minor orserious Investigate all accidents regardless of the extent of injury or damage.Thousands of industrial accidents occur every day

The failure of people, equipment, supplies, or surroundings to behave or react asexpected causes most of the accidents Accident investigations determine how andwhy these failures occur By using the information gained through an investigation,

a similar or perhaps more disastrous accident may be prevented Conduct accidentinvestigations with accident prevention in mind The objectives of investigations arenot to place blame

Accidents are part of a broad group of events that adversely affect the completion

of a task These events are incidents For simplicity, the procedures discussedbelow refer only to accidents They are, however, also applicable to incidents.Accidents are usually complex An accident may have 10 or more events that can

be causes

A detailed analysis of an accident will normally reveal three cause levels: basic,indirect, and direct (refer to Figure 1)

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BASIC CAUSES

INDIRECT CAUSES (SYMPTOMS)

DIRECT CAUSES

Management Safety Policy & Decisions

Personal Factors Environmental Factors

Unplanned Release of Energy

and/or Hazardous Material

ACCIDENT

Personal Injury Property Damage

Figure 1 The three cause levels of any accident.

At the lowest level, an accident results only when a person or object receives anamount of energy or hazardous material that cannot be absorbed safely This energy

or hazardous material is the direct cause of the accident The direct cause is usuallythe result of one or more unsafe acts or unsafe conditions, or both

Unsafe acts and conditions are the indirect causes or symptoms In turn, indirectcauses are usually traceable to poor management policies and decisions, or topersonal or environmental factors These are the basic causes In spite of theircomplexity, most accidents are preventable by eliminating one or more causes.Accident investigations determine not only what happened, but also how and why.The information gained from these investigations can prevent recurrence of similar

or perhaps more disastrous accidents Accident investigators are interested in eachevent as well as in the sequence of events that led to an accident The accident type

is also important to the investigator

The recurrence of accidents of a particular type or those with common causesshows areas needing special accident prevention emphasis

The actual procedures used in a particular investigation depend on the nature andresults of the accident The agency having jurisdiction over the location determines

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the administrative procedures In general, responsible officials will appoint anindividual to be in charge of the investigation The investigator uses most of thefollowing steps:

1 Define the scope of the investigation

2 Select the investigators Assign specific tasks to each (preferably in writing)

3 Present a preliminary briefing to the investigating team, including:

a Description of the accident, with damage estimates,

b Normal operating procedures,

c Maps (local and general)

d Location of the accident site,

e List of witnesses,

f Events that preceded the accident

4 Visit the accident site to get updated information

5 Inspect the accident site

a Secure the area Do not disturb the scene unless a hazard exists,

b Prepare the necessary sketches and photographs Label each carefully andkeep accurate records

6 Interview each victim and witness Also interview those who were presentbefore the accident and those who arrived at the site shortly after the accident.Keep accurate records of each interview Use a tape recorder if desired and

10 Check each sequence against the data from step 7

11 Determine the most likely sequence of events and the most probable causes

12 Conduct a post-investigation briefing

13 Prepare a summary report, including the recommended actions to prevent arecurrence Distribute the report according to applicable instructions

An investigation is not complete until all data are analyzed and a final report iscompleted In practice, the investigative work, data analysis, and report preparationproceed simultaneously over much of the time spent on the investigation

Gather evidence from many sources during an investigation Get information fromwitnesses and reports as well as by observation Interview witnesses as soon aspossible after an accident Inspect the accident site before any changes occur Take

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photographs and make sketches of the accident scene Record all pertinent data onmaps Get copies of all reports Documents containing normal operatingprocedures, flow diagrams, maintenance charts, or reports of difficulties orabnormalities are particularly useful Keep complete and accurate notes in a boundnotebook Record pre-accident conditions, the accident sequence, and post-accidentconditions In addition, document the location of victims, witnesses, machinery,energy sources, and hazardous materials.

In some investigations, a particular physical or chemical law, principle, or propertymay explain a sequence of events Include laws in the notes taken during theinvestigation or in the later analysis of data In addition, gather data during theinvestigation that may lend itself to analysis by these laws, principles, or properties

An appendix in the final report can include an extended discussion

In general, experienced personnel should conduct interviews If possible, the teamassigned to this task should include an individual with a legal background Inconducting interviews, the team should:

1 Appoint a speaker for the group

2 Get preliminary statements as soon as possible from all witnesses

3 Locate the position of each witness on a master chart (including the direction

of view)

4 Arrange for a convenient time and place to talk to each witness

5 Explain the purpose of the investigation (accident prevention) and put each

witness at ease

6 Listen, let each witness speak freely, and be courteous and considerate

7 Take notes without distracting the witness Use a tape recorder only withconsent of the witness

8 Use sketches and diagrams to help the witness

9 Emphasize areas of direct observation Label hearsay accordingly

10 Be sincere and do not argue with the witness

11 Record the exact words used by the witness to describe each observation Donot "put words into a witness' mouth."

12 Word each question carefully and be sure the witness understands

13 Identify the qualifications of each witness (name, address, occupation, years

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should assemble the available testimony into a logical order Analyze thisinformation along with data from the accident site Not all people react in the samemanner to a particular stimulus For example, a witness within close proximity tothe accident may have an entirely different story from one who saw it at a distance.Some witnesses may also change their stories after they have discussed it withothers The reason for the change may be additional clues A witness who has had

a traumatic experience may not be able to recall the details of the accident Awitness who has a vested interest in the results of the investigation may offer biasedtestimony Finally, eyesight, hearing, reaction time, and the general condition ofeach witness may affect his or her powers of observation A witness may omitentire sequences because of a failure to observe them or because their importancewas not realized

Accidents represent problems that must be solved through investigations Severalformal procedures solve problems of any degree of complexity This sectiondiscusses two of the most common procedures: Change Analysis and Job SafetyAnalysis

Change Analysis: As its name implies, this technique emphasizes change To solve

a problem, an investigator must look for deviations from the norm Consider allproblems to result from some unanticipated change Make an analysis of the change

to determine its causes Use the following steps in this method:

1 Define the problem (What happened?)

2 Establish the norm (What should have happened?)

3 Identify, locate, and describe the change (What, where, when, to whatextent)

4 Specify what was and what was not affected

5 Identify the distinctive features of the change

6 List the possible causes

7 Select the most likely causes

Job Safety Analysis: Job safety analysis (JSA) is part of many existing accident

prevention programs In general, JSA breaks a job into basic steps, and identifiesthe hazards associated with each step The JSA also prescribes controls for eachhazard A JSA is a chart listing these steps, hazards, and controls Review the JSAduring the investigation if a JSA has been conducted for the job involved in anaccident Perform a JSA if one is not available Perform a JSA as a part of theinvestigation to determine the events and conditions that led to the accident Asnoted above, an accident investigation is not complete until a report is prepared andsubmitted to proper authorities

Special report forms are available in many cases Other instances may require a

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