phân tích eclectron trong hóa phân tích phần 10 pdf

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10 4

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[] Included p o i n t "

CX I = 0 7 4

M

w

- P = 1.48 M P a , H2/CO = 1.0

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I! ' [] Included point I

• E x c l u d e d p o i n t I

10"

10 "~

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T = 235 °C

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F i g u r e 3 3 A n , l ~ r ~ n - $ e h t , l z - R o r y p l o t f o r r , n P ^ - 0 3 - 1 3 0 8 - 4 t o t a l p r o d u c t s r x c l , d i , g u n r e ¢ o v e r r d ~ ' a x

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P = 1,48 M P a |

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Carbon number

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l " i g u r e 3 4 A n d e r s o n - S d m l T , - F l o r y p l o t I ' o r r I , ' A - t } ~ - I , l O S - x , t c ; t n l p r o d ¢ t ~ e x c l m l i n g u n r e ¢ o v e r e ( ! w n x ,

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• FA-15-1698 (100 Fell.0 Cu/0.2 K)

• FA-15-1768

235 °C 1.48 MPa 2.0 NI/g-cst.h (H2/CO) = 0.67

O O

Time on stream (h)

200

Pig,r, 3~ SL,iI)ility ploi (II~-I-CO) conversion vers,IA time on stfesm, for r,ns F ^ - I 5-1098 and l.'A-15- 1768

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FB-99-1588 (Ruhrohemle LP 33/81)

250 °C ,

1.48 MPa

2,0 NI/g-cat.h

• _ , 0 _ , _1 , , _ , , I , j • I , ! , , , I , • • , I , , , ,

Time on stream (h)

700

PigLzre 30 SL~l)ility plof (llz4-CO) ronversion vers,s tiz,e on streams For r.n Fn-90-1588

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71 167 263 36O 42"7 528 623

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Tin~ on S ~ (h)

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Figure 37 Effec~ of time on stream cn Ruhrchem]e LP 33/81 selectivity for rm~ FB 99-15S8:250

=C, 1.48 MPa, 2 ]v'l/g-cat.h, (H2/CO) = 0.67 (71-427 h) amd 1.0 (528, 623 h)

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Fig, u~e 38 Comparison offixecl bed a~cl slur~' reactor select3v]ty wi¢]~ tL~hrchemie I.P 33/81 cata]ys~

(FB = TB-99-1588, SA = 5A-99-0888): 250 °C, 1.48 M P a , 2.0 ~'l/g-cat-h, (H2/CO) = 0.67 (FB-2 amd SA-3) and 1.0 (PB-6 a~d SA-12)

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