l o o
10 "1
0"
_e
O
10 -~
10"'
• N
T = 250 °C
P = !.48 MPa
SV - 2.0 N i / g - c a t , h
0
c x I = 0.74
C~I] = 0.90 /~ = 0.84
[] Included point
• E x c l u d e d p o i n t
C a r b o n n u m b e r
54
Figure 2 hnderson-S¢l,ulz-lrlory plot for rnn ]~A-25-,'1077-2, I.ot.l products exrluding re:recovered wnx
Trang 2- , , j
I
10 "1
c-
,P
:~ 10"
10"'
10"'
U
O( I - - 0 6 4
C(II = 0 9 2
/3 - 0.82
H 2 / C O = 0.98
, I , , , , , I , , , I , , , , , I , , , , , I , , , , , I I I
C a r b o n n u m b e r
54
FiK,rr 3 ^mlerson-Sch,ls-Plory plot for r,n F!1-00-1348-3 (¢nlcinrd It, hrchemie t,P 33/01), toLal plod,eLm exrl,d-
in8 nrerc~vere(I wnx;
Trang 3O
I I N
O
L
N k "
tD
/
O
10 0
10 -1
10 -~
10 -~
10"'
10 5
0
, , I n c l u d e d p o i n t
• E x c l u d e d p o i n t
cx I = 0 6 3
~I= = 0.92
= 0.80
T = 2 5 0 °C
P = 1.48 M P a
H 2 / C O = 0 9 8
- S V = 2.0 N I / g - c a t , h
@
O
C a r b o n n u m b e r
I
Figule 4 Anderson-Schul~-Flory plot for rlin PD-00-1348-4 (Rtihrchemle LP 33/81), l~olal produHs exel,ding lwn-
54
Trang 4e0
70
r-
O
"~ e0
I , , ,
q~
>
¢::
O
(3 60
O
O
+
"1"
~ , 40
30
20
.<
O FA-03-0410 (100 Fel5 Gu14.2 KlO 810 2 ) I"1 F A - 0 0 - 0 5 4 0 (100 FeI§ Cu14.2 KI25 810 )
F A - 0 0 - 0 0 0 8 (100 Fel6 Cul4.2 KI100 sl 2)
-t- FB-90-1340 (Ruhrohomle LP 33181
100 Fe/§ Cu/4.2 KI24 810 :)
F A - 7 3 - 0 8 2 8 (100 Fel6 CUl4.2 K18 A I 2 0 3 ) 2
F A - 7 8 - 0 9 8 8 (100 Fe/5 Cu/4.2 K/g0 A ] 2 0 3 )
O FA-81-1118 (100 Fe/6 Cu/4.2 K)
Space Velocity (NI/g-Fe.h)
I &
- I
11.0
Ylg.f~" 5 (:ompnri.qo nf (!!1-1-('0) ronvrr~l.,s for the hinder/s, ppoH catalysts nnd R,hrchemlr |,P 33/A1:
251) °C, 1.48 ALP,, (II=/CO) - 1.0
Trang 5In
E
O
42
13
"I"
3D~
~X).0
ID0
0.(]
SiO.~ A1203
Parts Support/IO0 Parts Fe
0~4
ff2-C4
C5-~1
Figure 6 Wei~t percent ]~y~rocazbon ~ r i b u t i o n ofbtnder]~pport cat~dysts mid ~ c h e n ~ e LP
33/81.- 235 °C, 1.48 M.Pa, 2 ~'//9-cat-h, (H_~/CO) = 1.0
6o
Trang 6700
0
IJ
to
.r
00
LP 33~1 D 8 25 100 8 2O
5iO2 " AI203 Parts Suppon/lO0 Parts Fe
C2q34
ff~-~1
CI~
Figure T Weight percent hy&ocarbon dist~butJon ofb~ader/support cazalysts and Ruhrchemie LP
3 3 / 8 1 : 2 5 0 °C, 1.48 M P a 2 J~'I/g-cat.h, (H=/CO) -" 1.0
61
Trang 7u1
e
0
1 - -
' m
k
0
0
cf)
rY
J - -
Temperoture (°C)
Figure 8 T P R profile in H2 at 20 °C/rain for calcined (16 hrs in air at 300 °C) samp]e of commercial
]~thrchemie catalyst
62
Trang 8C
0
I
.,Q
L -
~0
V
t -
O
Q
n ~
! -
Cc)
{b)
{a)
Temperature (°C)
Figure 9 TPP profiles in H2 at 20 °C/rain for calciuecl (16 Jars in air at 300 °C) samples of: (a) 100
Fe/5 Cu/4.2 E l 8 Si02; (b) 100 Fe/5 Cu/4.2 K/25 SiO~; (¢) 100 Fe/5 C'u/4.2 KI100 SiO.~
63
Trang 9t _
a m
L
V
0
0
w'
C.)
I -
Time (rain)
F i ~ e 10 Isothermal reduction profile in H2 for e.alcined (16 ]n-s in air at 300 °C) sample of com-
mexdal ~.uh.rchemie c.a.'~yst
Trang 10C J
L
.,4,,.e
u~ml,
L ,
c-
O
b
• ~ ! , , ~ I , • I • , I , , I • •
360
F i ~ e 11 Iso~ermal reducticm profile i~ CO for calcined (16 hr~ i~ air at 300 ©C) sample of ¢c~-
inertial ~ - c b e ~ e ~ y s t
65