Project Gutenberg Etext of AnIntroduction to Chemical Science by R.P.Williams Copyright laws are changing all over theworld, be sure to check the laws for yourcountry before redistributi
Trang 2Project Gutenberg Etext of An
Introduction to Chemical Science by R.P.Williams
Copyright laws are changing all over theworld, be sure to check the laws for yourcountry before redistributing these files!!!
Please take a look at the important
information in this header We encourageyou to keep this file on your own disk,keeping an electronic path open for thenext readers
Please do not remove this
This should be the first thing seen whenanyone opens the book Do not change oredit it without written permission The
Trang 3words are carefully chosen to provideusers with the information they need aboutwhat they can legally do with the texts.
**Welcome To The World of Free PlainVanilla Electronic Texts**
**Etexts Readable By Both Humans and
By Computers, Since 1971**
*****These Etexts Are Prepared By
Thousands of Volunteers!*****
Information on contacting Project
Gutenberg to get Etexts, and further
information is included below, includingfor donations
The Project Gutenberg Literary Archive
Trang 4Foundation is a 501(c)(3) organizationwith EIN [Employee IdentificationNumber] 64-6221541
Title: An Introduction to ChemicalScience
Trang 5Language: English
Project Gutenberg Etext of An
Introduction to Chemical Science
*****This file should be named aitcs10.txt
This etext was produced by John Mamoun
<mamounjo@umdnj.edu> with the OnlineDistributed Proofreading Team of CharlesFranks
Project Gutenberg Etexts are usually
created from multiple editions, all of
Trang 6which are in the Public Domain in theUnited States, unless a copyright notice isincluded Therefore, we usually do NOTkeep any of these books in compliancewith any particular paper edition.
We are now trying to release all our
books one year in advance of the officialrelease dates, leaving time for betterediting Please be encouraged to send userror messages even years after the
official publication date
Please note neither this listing nor itscontents are final til midnight of the lastday of the month of any such
announcement The official release date ofall Project Gutenberg Etexts is at
Midnight, Central Time, of the last day of
Trang 7the stated month A preliminary versionmay often be posted for suggestion,
comment and editing by those who wish to
indexes our cataloguers produce
obviously take a while after an
announcement goes out in the ProjectGutenberg Newsletter
Trang 8Just search by the first five letters of the
filename you want, as it appears in our
Newsletters
Information about Project Gutenberg (one
page)
We produce about two million dollars for
each hour we work The time it takes us, a
rather conservative estimate, is fifty hours
to get any etext selected, entered,
proofread, edited, copyright searched and
Trang 9analyzed, the copyright letters written, etc.This projected audience is one hundredmillion readers If our value per text isnominally estimated at one dollar then weproduce $2 million dollars per hour thisyear as we release fifty new Etext filesper month, or 500 more Etexts in 2000 for
a total of 3000+ If they reach just 1-2% ofthe world's population then the total
should reach over 300 billion Etexts givenaway by year's end
The Goal of Project Gutenberg is to GiveAway One Trillion Etext Files by
December 31, 2001 [10,000 x
100,000,000 = 1 Trillion] This is tenthousand titles each to one hundred
million readers, which is only about 4%
of the present number of computer users
Trang 10At our revised rates of production, wewill reach only one-third of that goal bythe end of 2001, or about 4,000 Etextsunless we manage to get some real
funding
The Project Gutenberg Literary ArchiveFoundation has been created to secure afuture for Project Gutenberg into the nextmillennium
We need your donations more than ever!
As of July 12, 2001 contributions are onlybeing solicited from people in:
Arkansas, Colorado, Connecticut,
Delaware, Florida, Georgia, Hawaii,Idaho,
Illinois, Indiana, Iowa, Kansas, Louisiana,
Trang 11Maine, Massachusetts, Minnesota,
Missouri, Montana, Nebraska, New
Mexico, Nevada, New Jersey, New York,North
Carolina, Ohio, Oklahoma, Oregon,
Rhode Island, South Carolina, South
Dakota,
Tennessee, Texas, Utah, Vermont,
Virginia, Washington, West Virginia,Wisconsin, and Wyoming
We have filed in about 45 states now, butthese are the only ones that have
responded
As the requirements for other states aremet, additions to this list will be made andfund raising will begin in the additionalstates Please feel free to ask to check the
Trang 12status of your state.
In answer to various questions we havereceived on this:
We are constantly working on finishing thepaperwork to legally request donations inall 50 states If your state is not listed andyou would like to know if we have added
it since the list you have, just ask
While we cannot solicit donations frompeople in states where we are not yetregistered, we know of no prohibitionagainst accepting donations from donors
in these states who approach us with anoffer to donate
International donations are accepted, but
Trang 13we don't know ANYTHING about how tomake them tax-deductible, or even if theyCAN be made deductible, and don't havethe staff to handle it even if there areways.
All donations should be made to:
Project Gutenberg Literary Archive
Number] 64-6221541, and has been
Trang 14approved as a 501(c)(3) organization bythe US Internal Revenue Service (IRS).Donations are tax-deductible to the
maximum extent permitted by law As therequirements for other states are met,additions to this list will be made andfund raising will begin in the additionalstates
We need your donations more than ever!
You can get up to date donation
Trang 15can always email directly to:
Michael S Hart <hart@pobox.com>
hart@pobox.com forwards to
hart@prairienet.org and archive.org ifyour mail bounces from archive.org, I willstill see it, if it bounces from
prairienet.org, better resend later on
Prof Hart will answer or forward yourmessage
We would prefer to send you information
by email
***
Trang 16Example command-line FTP session:
ftp ftp.ibiblio.org login: anonymous
password: your@login cd
pub/docs/books/gutenberg cd etext90through etext99 or etext00 through etext02,etc dir [to see files] get or mget [to getfiles .set bin for zip files] GET
GUTINDEX.?? [to get a year's listing ofbooks, e.g., GUTINDEX.99] GET
GUTINDEX.ALL [to get a listing of ALLbooks]
**The Legal Small Print**
(Three Pages)
***START**THE SMALL
Trang 17PRINT!**FOR PUBLIC DOMAIN
ETEXTS**START*** Why is this "SmallPrint!" statement here? You know:
lawyers They tell us you might sue us ifthere is something wrong with your copy
of this etext, even if you got it for freefrom someone other than us, and even ifwhat's wrong is not our fault So, amongother things, this "Small Print!" statementdisclaims most of our liability to you Italso tells you how you may distributecopies of this etext if you want to
*BEFORE!* YOU USE OR READ THISETEXT By using or reading any part ofthis PROJECT GUTENBERG-tm etext,you indicate that you understand, agree toand accept this "Small Print!" statement Ifyou do not, you can receive a refund of the
Trang 18money (if any) you paid for this etext bysending a request within 30 days of
receiving it to the person you got it from
If you received this etext on a physicalmedium (such as a disk), you must return itwith your request
ABOUT PROJECT GUTENBERG-TMETEXTS This PROJECT GUTENBERG-
tm etext, like most PROJECT
GUTENBERG-tm etexts, is a "publicdomain" work distributed by ProfessorMichael S Hart through the Project
Gutenberg Association (the "Project").Among other things, this means that no oneowns a United States copyright on or forthis work, so the Project (and you!) cancopy and distribute it in the United Stateswithout permission and without paying
Trang 19copyright royalties Special rules, set forthbelow, apply if you wish to copy anddistribute this etext under the "PROJECTGUTENBERG" trademark.
Please do not use the "PROJECT
GUTENBERG" trademark to market anycommercial products without permission
To create these etexts, the Project expendsconsiderable efforts to identify, transcribeand proofread public domain works
Despite these efforts, the Project's etextsand any medium they may be on may
contain "Defects" Among other things,Defects may take the form of incomplete,inaccurate or corrupt data, transcriptionerrors, a copyright or other intellectualproperty infringement, a defective or
Trang 20damaged disk or other etext medium, acomputer virus, or computer codes thatdamage or cannot be read by your
equipment
LIMITED WARRANTY; DISCLAIMER
OF DAMAGES But for the "Right ofReplacement or Refund" described below,[1] Michael Hart and the Foundation (andany other party you may receive this etextfrom as a PROJECT GUTENBERG-tmetext) disclaims all liability to you fordamages, costs and expenses, includinglegal fees, and [2] YOU HAVE NO
REMEDIES FOR NEGLIGENCE ORUNDER STRICT LIABILITY, OR FORBREACH OF WARRANTY OR
CONTRACT, INCLUDING BUT NOTLIMITED TO INDIRECT,
Trang 21CONSEQUENTIAL, PUNITIVE ORINCIDENTAL DAMAGES, EVEN IFYOU GIVE NOTICE OF THE
POSSIBILITY OF SUCH DAMAGES
If you discover a Defect in this etext
within 90 days of receiving it, you canreceive a refund of the money (if any) youpaid for it by sending an explanatory notewithin that time to the person you received
it from If you received it on a physicalmedium, you must return it with your note,and such person may choose to
alternatively give you a replacement copy
If you received it electronically, suchperson may choose to alternatively giveyou a second opportunity to receive itelectronically
Trang 22THIS ETEXT IS OTHERWISE PROVIDED
TO YOU "AS-IS" NO OTHER WARRANTIES
OF ANY KIND, EXPRESS OR IMPLIED, ARE MADE TO YOU AS TO THE ETEXT OR ANY MEDIUM IT MAY BE ON, INCLUDING BUT NOT LIMITED TO WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE.
Some states do not allow disclaimers ofimplied warranties or the exclusion orlimitation of consequential damages, sothe above disclaimers and exclusions maynot apply to you, and you may have otherlegal rights
INDEMNITY You will indemnify andhold Michael Hart, the Foundation, and itstrustees and agents, and any volunteersassociated with the production and
Trang 23distribution of Project Gutenberg-tm textsharmless, from all liability, cost andexpense, including legal fees, that arisedirectly or indirectly from any of thefollowing that you do or cause: [1]
distribution of this etext, [2] alteration,modification, or addition to the etext, or[3] any Defect
DISTRIBUTION UNDER "PROJECTGUTENBERG-tm" You may distributecopies of this etext electronically, or bydisk, book or any other medium if youeither delete this "Small Print!" and allother references to Project Gutenberg, or:
[1] Only give exact copies of it Amongother things, this requires that you do notremove, alter or modify the etext or this
Trang 24"small print!" statement You may
however, if you wish, distribute this etext
in machine readable binary, compressed,mark-up, or proprietary form, includingany form resulting from conversion byword processing or hypertext software,but only so long as *EITHER*:
[*] The etext, when displayed, is
clearly readable, and does *not*
contain characters other than thoseintended by the author of the work,although tilde (~), asterisk (*) andunderline (_) characters may be used
to convey punctuation intended by theauthor, and additional characters may
be used to indicate hypertext links;OR
Trang 25[*] The etext may be readily
converted by the reader at no
expense into plain ASCII, EBCDIC
or equivalent form by the programthat displays the etext (as is the case,for instance, with most word
processors); OR
[*] You provide, or agree to alsoprovide on request at no additionalcost, fee or expense, a copy of theetext in its original plain ASCII form(or in EBCDIC or other equivalentproprietary form)
[2] Honor the etext refund and
replacement provisions of this "SmallPrint!" statement
Trang 26[3] Pay a trademark license fee to theFoundation of 20% of the gross profitsyou derive calculated using the methodyou already use to calculate your
applicable taxes If you don't derive
profits, no royalty is due Royalties arepayable to "Project Gutenberg LiteraryArchive Foundation" the 60 days
following each date you prepare (or werelegally required to prepare) your annual(or equivalent periodic) tax return Pleasecontact us beforehand to let us know yourplans and to work out the details
WHAT IF YOU *WANT* TO SENDMONEY EVEN IF YOU DON'T HAVETO? Project Gutenberg is dedicated toincreasing the number of public domainand licensed works that can be freely
Trang 27distributed in machine readable form.
The Project gratefully accepts
contributions of money, time,
public domain materials, or royalty freecopyright licenses
Money should be paid to the:
"Project Gutenberg Literary ArchiveFoundation."
If you are interested in contributing
scanning equipment or software or otheritems, please contact Michael Hart at:hart@pobox.com
[Portions of this header are copyright (C)
2001 by Michael S Hart and may bereprinted only when these Etexts are free
of all fees.] [Project Gutenberg is a
Trang 28TradeMark and may not be used in anysales of Project Gutenberg Etexts or othermaterials be they hardware or software orany other related product without expresspermission.]
*END THE SMALL PRINT! FOR
PUBLIC DOMAIN
ETEXTS*Ver.07/27/01*END*
This etext was produced by John Mamoun
<mamounjo@umdnj.edu> with the OnlineDistributed Proofreading Team of CharlesFranks
Trang 29An Introduction to Chemical Science
by R.P Williams, A.M.,
Trang 30ORIGINAL EDITION INFO
Trang 31ABOUT THIS E-TEXT
Trang 32For the accomplishment of this purposethe author has endeavored to omit
superfluous matter, and give only the mostuseful and interesting experiments, factsand theories
In calling attention, by questions, andotherwise, to the more important
phenomena to be observed and facts to belearned, the best features of the inductivesystem have been utilized Especially isthe writing of equations, which constitutethe multum in parvo of chemical
knowledge, insisted upon As soon as thepupil has become imbued with the spiritand meaning of chemical equations, heneed have little fear of failing to
understand the rest To this end ChaptersIX., XI., and XVI should be studied with
Trang 33great care.
In the early stages of the work the
equations may with advantage be
memorized, but this can soon be
discontinued Whenever symbols areemployed, pupils should be required togive the corresponding chemical names,
or, better, both names and symbols
The classification of chemical substancesinto acids, bases and salts, and the
distinctions and analogies between each
of these classes, have been brought intoespecial prominence The general
relationship between the three classes,and the general principles prevailing inthe preparation of each, must be fullyunderstood before aught but the merest
Trang 34smattering of chemical science can beknown.
Chapters XV.-XXI should be mastered as
a key to the subsequent parts of the book
The mathematical and theoretical parts ofChemistry it has been thought best tointersperse throughout the book, placingeach where it seemed to be especiallyneeded; in this way, it is hoped that thetedium which pupils find in studyingconsecutively many chapters of theorieswill be avoided, and that the arrangementwill give an occasional change from thediscussion of facts and experiments to that
of principles In these chapters additionalquestions should be given, and the pupilshould be particularly encouraged to make
Trang 35new problems of his own, and to solvetheta.
It is needless to say that this treatise isprimarily designed to be used in
connection with a laboratory Like allother text- books on the subject, it can bestudied without such an accessory; but theauthor attaches very little value to thestudy of Chemistry without experimentalwork The required apparatus and
chemicals involve but little expense, andthe directions for experimentation are theresult of several years' experience withclasses as large as are to be found in thelaboratory of any school or college in thecountry
During the present year the author
Trang 36personally supervises the work of morethan 180 different pupils in chemistry.This enables him not only to assure
himself that the experiments of the bookare practical, but that the directions forperforming them are ample It is foundadvisable to perform most of the
experiments, with full explanation, inpresence of the class, before requiring thepupils either to do the work or to recitethe lesson In the laboratory each pupil has
a locker under his table, furnished withapparatus, as specified in the Appendix.Each has also the author's "LaboratoryManual," which contains on every left-hand page full directions for an
experiment, with observations to be made,etc The right-hand page is blank, and onthat the pupil makes a record of his work
Trang 37These notes are examined at the time, orsubsequently, by the teacher, and the pupil
is not allowed to take the book from thelaboratory; nor can he use any other book
on Chemistry while experimenting By thismeans he learns to make his own
observations and inferences
For the benefit of the science and the
added interest in the study, it is earnestlyrecommended that teachers encouragepupils to fit up laboratories of their own athome This need not at first entail a largeoutlay A small attic room with runningwater, a very few chemicals, and a littleapparatus, are enough to begin with; thesecan be added to from time to time, as newmaterial is wanted In this way the studentwill find his love for science growing
Trang 38While endeavoring, by securing an ablecorps of critics, and in all other wayspossible, to reduce errors to a minimum,the author disclaims any pretensions to awork entirely free from mistakes, holdinghimself alone responsible for any
shortcomings, and trusting to the leniency
of teachers and critics
The manuscript has been read by Prof.Henry Carmichael, Ph.D., of Boston, and
to his broad and accurate scholarship, aswell as to his deep personal interest in thework, the author is indebted for muchvaluable and original matter The
following persons have generously readthe proof, as a whole or in part, and made
Trang 39suggestions regarding it, and to them theauthor would return his thanks, as well asacknowledge his obligation: Prof E J.Bartlett, Dartmouth College, N.H.; Prof F.
C Robinson, Bowdoin College, Me.;Prof H S Carhart, Michigan University;Prof B D Halsted, Iowa AgriculturalCollege; Prof W T Sedgwick, Institute
of Technology, Boston; Pres M E
Wadsworth, Michigan Mining School;Prof George Huntington, Carleton
College, Minn.; Prof Joseph Torrey, IowaCollege; Mr C J Lincoln, East BostonHigh.School; Mr W H Sylvester,
English High School, Boston; Mr F W.Gilley, Chelsea, Mass., High School; thelate D S Lewis, Chemist of the BostonGas Works, and others