GavashelidzePetre Melikishvili Institute of Physical and Organic Chemistry of Ivane, Javakhishvili Tbilisi, State University, I.. GurgenishviliPetre Melikishvili Institute of Physical an
SYNTHESIS AND APPLICATION
H Durgaryan, N Durgaryan, R H Arakelyan,
Yerevan State University, Alek Manoogian 1, Yerevan, 375025, Republic of Armenia , E-mail: durnar63@yahoo.com
Yerevan State University, Alek Manoogian 1, Yerevan, 375025, Republic of Armenia
V I Vernadsky Institute of General and Inorganic Chemistry NASU, Kyiv, Ukraine
Taras Shevchenko National University, Faculty of Chemistry, 60 Volodymyrska Str., Kyiv 0160, Ukraine
Polymer Technology Department, Chemical Faculty, Gdansk University of Technology, Gabriela Narutowicza Street 11/12, 80-233 Gdansk, Poland
Ilia Vekua Sukhumi Institute of Physics and Technology, Laboratory of Cryogenic Technique and Technologies, Mindeli str, 7, 0186 Tbilisi, Georgia
Ivane Javakhishvili Tbilisi State University, Rafiel Agladze Institute of Inorganic Chemistry and Electrochemistry Mindeli str, 11, 0186, Tbilisi, Georgia
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane, Javakhishvili Tbilisi , State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane Javakhishvili Tbilisi , State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia
Energy Recovery Agency of Oslo County, PO-BOX 54 Mortensrud, NO-1215, Oslo, Norway, E-mail: Espen.Govasmark@ege.oslo.kommune.no
The Scientific Technological Centre of Organic and Pharmaceutical Chemistry NAS RA, Institute of Organic Chemistry, 26, Azatutyan STR, 0014, Yerevan, Armenia
The Scientific Technological Centre of Organic and Pharmaceutical Chemistry NAS RA, Institute of Organic Chemistry 26, Azatutyan STR, 0014, Yerevan, Armenia
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane, Javakhishvili Tbilisi , State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia, E-mail: marina.gurgenishvili@yahoo.com
Department of Resin and Additives, Institute for Color Science and Technology, Tehran, Iran, E-mail: zeinab.hesari@yahoo.com
Polymer Technology Department, Chemical Faculty, Gdansk University of Technology, Gabriela Narutowicza Street 11/12, 80-233 Gdansk, Poland, E-mail: jozef.haponiuk@pg.gda.pl
Taras Shevchenko National University, Faculty of Chemistry, 60 Volodymyrska Str., Kyiv 0160, Ukraine
Yerevan State University, A Manookyan St 1, 0025, Armenia , E-mail: Scirec@mail.ru
Yerevan State University, A Manookyan St 1, 0025, Armenia, E-mail: Scirec@mail.ru
Polymer Technology Department, Chemical Faculty, Gdansk University of Technology, Gabriela Narutowicza Street 11/12, 80-233 Gdansk, Poland
Department of Chemistry, Faculty of Science, Science and Research of Tehran Branch Islamic Azad University, Tehran, Iran, E-mail: zeinab.hesari@yahoo.com
The Scientific Technological Centre of Organic and Pharmaceutical Chemistry NAS RA, Institute of Organic Chemistry 26, Azatutyan STR, 0014, Yerevan, Armenia, E-mail: hovarnos@gmail.com
Moldova State University, 60 A Mateevici str., MD-2009, Chisinau, Moldova
JSC, “Institue of Chemical Sciences after A.B Bekturov”, Sh Valikhanov st 106, Almaty, Republic of Kazakhstan, E-mail: jumadilov@mail.ru
Peoples’ Friendship University of Russia, Scientific-Educational Centre of Nanotechnology, Miklukho- Maklaya 10/2, 117198, Moscow, Russia
Kyiv Taras Shevchenko National University, Volodymyrska Str 60, 01033, Kyiv, Ukraine
Department of Macromolecular Chemistry, Taras Shevchenko National University of Kyiv, 60 Volodymyrska Street, 01033, Kyiv, Ukraine
Al-Farabi Kazakh National University, Faculty of Chemistry and Chemical Technology, Al-Farabi ave
Kyiv Taras Shevchenko National University, Volodymyrska Str 60, 01033, Kyiv, Ukraine
Center of Physical and Chemical Methods of Research and Analysis, Tole bi Str 96a, 050012, Almaty, Kazakhstan
Taras Shevchenko National University, Faculty of Chemistry, 60 Volodymyrska Str., Kyiv 0160, Ukraine
Taras Shevchenko National University, Faculty of Chemistry, 60 Volodymyrska Str., Kyiv 0160, Ukraine, Email: kutsevol@ukr.net
Department of Sciences, Ivan Franko Zhytomyr State University, 40 Velyka Berdychivska Str., 10008 Zhytomyr, Ukraine
Chuiko Institute of Surface Chemistry, National Academy of Science of Ukraine, General Naumov Str
17, 03164 Kyiv, Ukraine, E-mail: okslinnik@yahoo.co.uk
Iv Javakhishvili Tbilisi State University, Department of Chemistry, I Chavchavadze Ave, 1, 0179 Tbilisi, Georgia
Nagiyev Institute of Catalysis & Inorganic Chemistry, Azerbaijan National Academy of Sciences,
H Javid Ave., 113, AZ1143 Baku, Azerbaijan
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane, Javakhishvili Tbilisi , State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia
Ivane Javakhishvili Tbilisi State University Chavchavadze Avenue 1, Tbilisi 0128, Georgia
Ivane Javakhishvili Tbilisi State University Chavchavadze Avenue 1, Tbilisi, 0128, Georgia
Ivane Javakhishvili Tbilisi State University, E Andronikashvili Institute of Physics, Tamarashvili str, 6,
Problem Research Laboratory, National University of Food Technology, 68, Volodymyrska Street
Ivane Javakhishvili Tbilisi State University, Rafiel Agladze Institute of Inorganic Chemistry and Electrochemistry Mindeli str, 11, 0186, Tbilisi, Georgia, E-mail: tamazmarsagishvili@gmail.com
Chemistry Faculty, Kyiv National Taras Shevchenko University, 12 L Tolstogo Str., 01033 Kyiv, Ukraine
Ivane Javakhishvili Tbilisi State University, Rafiel Agladze Institute of Inorganic Chemistry and Electrochemistry Mindeli str., 11, 0186, Tbilisi, Georgia
Ilia Vekua Sukhumi Institute of Physics and Technology, Laboratory of Cryogenic Technique and Technologies, Mindeli Str 7, 0186 Tbilisi, Georgia
Georgian Technical University, Department of Engineering Physics, Kostava Str 77, 0175 Tbilisi, Georgia
Yerevan State University, Alek Manoogian 1, Yerevan, 375025, Republic of Armenia
Georgian Technical University, V Chavchanidze Institute of Cybernetics, 5 S Euli , St, 0186 Tbilisi, Georgia
Taras Shevchenko National University of Kyiv, Department of Chemistry, Volodymyrska Str., 60,
Faculty of Physics and Engineering, Moldova State University, 60 A Mateevici str., MD 2009, Chisinau, Moldova
Chemistry Faculty, Kyiv National Taras Shevchenko University, 12 L Tolstogo Str., 01033 Kyiv, Ukraine
G.A Krestov Institute of Solution Chemistry, Russian Academy of Sciences, Akademicheskaya Str., 1, Ivanovo, 153045, Russia
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane, Javakhishvili Tbilisi , State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane Javakhishvili Tbilisi , State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane, Javakhishvili Tbilisi , State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia
Georgian Technical University, V Chavchanidze Institute of Cybernetics, 5 S Euli , St, 0186 Tbilisi, Georgia
Georgian Technical University, 68 Merab Kostava Street, Tbilisi, Georgia Tbilisi, 0175, Georgia
Yerevan State University, A Manookyan St 1, 0025, Armenia , E-mail: Scirec@mail.ru Ł Piszczyk
Polymer Technology Department, Chemical Faculty, Gdansk University of Technology, Gabriela Narutowicza Street 11/12, 80-233 Gdansk, Poland
Tbilisi State University, 1 Ilia Chavchavadze Ave, Tbilisi 0179, Georgia
Faculty of Physics and Engineering, Moldova State University, 60 A Mateevici str., MD 2009, Chisinau, Moldova
Moldova State University, 60 A Mateevici str, MD-2009, Chisinau, Moldova, E-mail: s.v.robu@mail.ru
Norwegian University of Life Sciences (NMBU), Department of Env Sci., PO-Box 5003, No 1432, Ås, Norway , E-mail: Brit.Salbu@nmbu.no
Kyiv National Taras Shevchenko University, Department of Chemistry, Kyiv, Ukraine , E-mail: iras@univ.kiev.ua
Georgian Technical University, V Chavchanidze Institute of Cybernetics, 5 S Euli St, 0186 Tbilisi, Georgia
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane, Javakhishvili Tbilisi , State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia
Center of Physical and Chemical Methods of Research and Analysis, Tole bi Str 96a, 050012, Almaty, Kazakhstan
Chuiko Institute of Surface Chemistry, National Academy of Science of Ukraine, General Naumov str,
Kyiv Taras Shevchenko National University, Volodymyrska Str., 60, 01033, Kyiv, Ukraine, E-mail: vitaliismokal@gmail.com
Maria Curie-Skłodowska University, pl Maria Curie-Skłodowskiej 3, 20-031 Lublin, Poland
Ivane Javakhishvili Tbilisi State University Chavchavadze Avenue 1, Tbilisi, 0128, Georgia
Department of Macromolecular Chemistry, Taras Shevchenko National University of Kyiv, 60 Volodymyrska Street, 01033, Kyiv, Ukraine , E-mail: svg@univ.kiev.ua
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane Javakhishvili Tbilisi, State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia
Ivane Javakhishvili Tbilisi State University, Rafiel Agladze Institute of Inorganic Chemistry and Electrochemistry Mindeli str, 11, 0186, Tbilisi, Georgia
Institute of Molecular Biology and Genetics of Natl Acad of Sci of Ukraine, 150 Zabolotnogo str.150, Kyiv 03680, Ukraine, E-mail: gtelegeev@ukr.net
Taras Shevchenko National University, Faculty of Chemistry, 60 Volodymyrska Str., Kyiv 0160, Ukraine
Polymer Technology Department, Chemical Faculty, Gdansk University of Technology, Gabriela Narutowicza Street 11/12, 80–233 Gdansk, Poland
Alvarenga, L Hayrapetyan, S Hayrapetyan, G Pirumyan, Govasmark, and B Salbu 4 Aromatic Azides and Pentazenes in Multistep Radical
NIBIO, Norwegian Institute of Bioeconomy Research, Pb 115, N-1431, Ås, Norway, E-mail: Emilio.Alvarenga@nibio.no
Ivane Javakhishvili Tbilisi State University, Rafiel Agladze Institute of Inorganic Chemistry and Electrochemistry Mindeli str., 11, 0186, Tbilisi, Georgia
Moldova State University, 60 A Mateevici str., MD-2009, Chisinau, Moldova
Yerevan State University, Alek Manoogian 1, Yerevan, 375025, Republic of Armenia
Center of Physical and Chemical Methods of Research and Analysis, Tole bi Str 96a, 050012, Almaty, Kazakhstan
G A Krestov Institute of Solution Chemistry, Russian Academy of Sciences, Akademicheskaya str., 1, Ivanovo, 153045, Russia
Ilia Vekua Sukhumi Institute of Physics and Technology, Laboratory of Cryogenic Technique and Technologies, Mindeli Str 7, 0186 Tbilisi, Georgia
V I Vernadsky Institute of General and Inorganic Chemistry NASU, Kyiv, Ukraine
Moldova State University, 60 A Mateevici str., MD-2009, Chisinau, Moldova
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane Javakhishvili Tbilisi , State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia
Chuiko Institute of Surface Chemistry, National Academy of Science of Ukraine, General Naumov str,
Tbilisi State University, 1 Ilia Chavchavadze Ave, Tbilisi 0179, Georgia, E-mail: chubinidzeketino@yahoo.com
Problem Research Laboratory, National University of Food Technology, 68, Volodymyrska Street
Moldova State University, 60 A Mateevici str., MD-2009, Chisinau, Moldova
Faculty of Physics and Engineering, Moldova State University, 60 A Mateevici str., MD 2009, Chisinau, Moldova
Polymer Technology Department, Chemical Faculty, Gdansk University of Technology, Gabriela Narutowicza Street 11/12, 80-233 Gdansk, Poland
Armenian National Polytechnic University 105, Teryana Str., 105 375009 Yerevan, Armenia
Ilia Vekua Sukhumi Institute of Physics and Technology, Laboratory of Cryogenic Technique and Technologies, Mindeli Str 7, 0186 Tbilisi, Georgia
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane Javakhishvili Tbilisi , State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia
Georgian Technical University, Kostava Str., 77, 0175, Tbilisi, Georgia
Faculty of Chemistry and Chemical Technology
Yerevan State University, Alek Manoogian 1, Yerevan, 375025, Republic of Armenia , E-mail: durnar63@yahoo.com
Yerevan State University, Alek Manoogian 1, Yerevan, 375025, Republic of Armenia
V I Vernadsky Institute of General and Inorganic Chemistry NASU, Kyiv, Ukraine
Taras Shevchenko National University, Faculty of Chemistry, 60 Volodymyrska Str., Kyiv 0160, Ukraine
Polymer Technology Department, Chemical Faculty, Gdansk University of Technology, Gabriela Narutowicza Street 11/12, 80-233 Gdansk, Poland
Ilia Vekua Sukhumi Institute of Physics and Technology, Laboratory of Cryogenic Technique and Technologies, Mindeli str, 7, 0186 Tbilisi, Georgia
Ivane Javakhishvili Tbilisi State University, Rafiel Agladze Institute of Inorganic Chemistry and Electrochemistry Mindeli str, 11, 0186, Tbilisi, Georgia
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane, Javakhishvili Tbilisi , State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane Javakhishvili Tbilisi , State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia
Energy Recovery Agency of Oslo County, PO-BOX 54 Mortensrud, NO-1215, Oslo, Norway, E-mail: Espen.Govasmark@ege.oslo.kommune.no
The Scientific Technological Centre of Organic and Pharmaceutical Chemistry NAS RA, Institute of Organic Chemistry, 26, Azatutyan STR, 0014, Yerevan, Armenia
The Scientific Technological Centre of Organic and Pharmaceutical Chemistry NAS RA, Institute of Organic Chemistry 26, Azatutyan STR, 0014, Yerevan, Armenia
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane, Javakhishvili Tbilisi , State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia, E-mail: marina.gurgenishvili@yahoo.com
Department of Resin and Additives, Institute for Color Science and Technology, Tehran, Iran, E-mail: zeinab.hesari@yahoo.com
Polymer Technology Department, Chemical Faculty, Gdansk University of Technology, Gabriela Narutowicza Street 11/12, 80-233 Gdansk, Poland, E-mail: jozef.haponiuk@pg.gda.pl
Taras Shevchenko National University, Faculty of Chemistry, 60 Volodymyrska Str., Kyiv 0160, Ukraine
Yerevan State University, A Manookyan St 1, 0025, Armenia , E-mail: Scirec@mail.ru
Yerevan State University, A Manookyan St 1, 0025, Armenia, E-mail: Scirec@mail.ru
Polymer Technology Department, Chemical Faculty, Gdansk University of Technology, Gabriela Narutowicza Street 11/12, 80-233 Gdansk, Poland
Department of Chemistry, Faculty of Science, Science and Research of Tehran Branch Islamic Azad University, Tehran, Iran, E-mail: zeinab.hesari@yahoo.com
The Scientific Technological Centre of Organic and Pharmaceutical Chemistry NAS RA, Institute of Organic Chemistry 26, Azatutyan STR, 0014, Yerevan, Armenia, E-mail: hovarnos@gmail.com
Moldova State University, 60 A Mateevici str., MD-2009, Chisinau, Moldova
JSC, “Institue of Chemical Sciences after A.B Bekturov”, Sh Valikhanov st 106, Almaty, Republic of Kazakhstan, E-mail: jumadilov@mail.ru
Peoples’ Friendship University of Russia, Scientific-Educational Centre of Nanotechnology, Miklukho- Maklaya 10/2, 117198, Moscow, Russia
Kyiv Taras Shevchenko National University, Volodymyrska Str 60, 01033, Kyiv, Ukraine
Department of Macromolecular Chemistry, Taras Shevchenko National University of Kyiv, 60 Volodymyrska Street, 01033, Kyiv, Ukraine
Al-Farabi Kazakh National University, Faculty of Chemistry and Chemical Technology, Al-Farabi ave
Kyiv Taras Shevchenko National University, Volodymyrska Str 60, 01033, Kyiv, Ukraine
Center of Physical and Chemical Methods of Research and Analysis, Tole bi Str 96a, 050012, Almaty, Kazakhstan
Taras Shevchenko National University, Faculty of Chemistry, 60 Volodymyrska Str., Kyiv 0160, Ukraine
Taras Shevchenko National University, Faculty of Chemistry, 60 Volodymyrska Str., Kyiv 0160, Ukraine, Email: kutsevol@ukr.net
Department of Sciences, Ivan Franko Zhytomyr State University, 40 Velyka Berdychivska Str., 10008 Zhytomyr, Ukraine
Chuiko Institute of Surface Chemistry, National Academy of Science of Ukraine, General Naumov Str
17, 03164 Kyiv, Ukraine, E-mail: okslinnik@yahoo.co.uk
Iv Javakhishvili Tbilisi State University, Department of Chemistry, I Chavchavadze Ave, 1, 0179 Tbilisi, Georgia
Nagiyev Institute of Catalysis & Inorganic Chemistry, Azerbaijan National Academy of Sciences,
H Javid Ave., 113, AZ1143 Baku, Azerbaijan
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane, Javakhishvili Tbilisi , State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia
Ivane Javakhishvili Tbilisi State University Chavchavadze Avenue 1, Tbilisi 0128, Georgia
Ivane Javakhishvili Tbilisi State University Chavchavadze Avenue 1, Tbilisi, 0128, Georgia
Ivane Javakhishvili Tbilisi State University, E Andronikashvili Institute of Physics, Tamarashvili str, 6,
Problem Research Laboratory, National University of Food Technology, 68, Volodymyrska Street
Ivane Javakhishvili Tbilisi State University, Rafiel Agladze Institute of Inorganic Chemistry and Electrochemistry Mindeli str, 11, 0186, Tbilisi, Georgia, E-mail: tamazmarsagishvili@gmail.com
Chemistry Faculty, Kyiv National Taras Shevchenko University, 12 L Tolstogo Str., 01033 Kyiv, Ukraine
Ivane Javakhishvili Tbilisi State University, Rafiel Agladze Institute of Inorganic Chemistry and Electrochemistry Mindeli str., 11, 0186, Tbilisi, Georgia
Ilia Vekua Sukhumi Institute of Physics and Technology, Laboratory of Cryogenic Technique and Technologies, Mindeli Str 7, 0186 Tbilisi, Georgia
Georgian Technical University, Department of Engineering Physics, Kostava Str 77, 0175 Tbilisi, Georgia
Yerevan State University, Alek Manoogian 1, Yerevan, 375025, Republic of Armenia
Georgian Technical University, V Chavchanidze Institute of Cybernetics, 5 S Euli , St, 0186 Tbilisi, Georgia
Taras Shevchenko National University of Kyiv, Department of Chemistry, Volodymyrska Str., 60,
Faculty of Physics and Engineering, Moldova State University, 60 A Mateevici str., MD 2009, Chisinau, Moldova
Chemistry Faculty, Kyiv National Taras Shevchenko University, 12 L Tolstogo Str., 01033 Kyiv, Ukraine
G.A Krestov Institute of Solution Chemistry, Russian Academy of Sciences, Akademicheskaya Str., 1, Ivanovo, 153045, Russia
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane, Javakhishvili Tbilisi , State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane Javakhishvili Tbilisi , State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane, Javakhishvili Tbilisi , State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia
Georgian Technical University, V Chavchanidze Institute of Cybernetics, 5 S Euli , St, 0186 Tbilisi, Georgia
Georgian Technical University, 68 Merab Kostava Street, Tbilisi, Georgia Tbilisi, 0175, Georgia
Yerevan State University, A Manookyan St 1, 0025, Armenia , E-mail: Scirec@mail.ru Ł Piszczyk
Polymer Technology Department, Chemical Faculty, Gdansk University of Technology, Gabriela Narutowicza Street 11/12, 80-233 Gdansk, Poland
Tbilisi State University, 1 Ilia Chavchavadze Ave, Tbilisi 0179, Georgia
Faculty of Physics and Engineering, Moldova State University, 60 A Mateevici str., MD 2009, Chisinau, Moldova
Moldova State University, 60 A Mateevici str, MD-2009, Chisinau, Moldova, E-mail: s.v.robu@mail.ru
Norwegian University of Life Sciences (NMBU), Department of Env Sci., PO-Box 5003, No 1432, Ås, Norway , E-mail: Brit.Salbu@nmbu.no
Kyiv National Taras Shevchenko University, Department of Chemistry, Kyiv, Ukraine , E-mail: iras@univ.kiev.ua
Georgian Technical University, V Chavchanidze Institute of Cybernetics, 5 S Euli St, 0186 Tbilisi, Georgia
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane, Javakhishvili Tbilisi , State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia
Center of Physical and Chemical Methods of Research and Analysis, Tole bi Str 96a, 050012, Almaty, Kazakhstan
Chuiko Institute of Surface Chemistry, National Academy of Science of Ukraine, General Naumov str,
Kyiv Taras Shevchenko National University, Volodymyrska Str., 60, 01033, Kyiv, Ukraine, E-mail: vitaliismokal@gmail.com
Maria Curie-Skłodowska University, pl Maria Curie-Skłodowskiej 3, 20-031 Lublin, Poland
Ivane Javakhishvili Tbilisi State University Chavchavadze Avenue 1, Tbilisi, 0128, Georgia
Department of Macromolecular Chemistry, Taras Shevchenko National University of Kyiv, 60 Volodymyrska Street, 01033, Kyiv, Ukraine , E-mail: svg@univ.kiev.ua
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane Javakhishvili Tbilisi, State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia
Ivane Javakhishvili Tbilisi State University, Rafiel Agladze Institute of Inorganic Chemistry and Electrochemistry Mindeli str, 11, 0186, Tbilisi, Georgia
Institute of Molecular Biology and Genetics of Natl Acad of Sci of Ukraine, 150 Zabolotnogo str.150, Kyiv 03680, Ukraine, E-mail: gtelegeev@ukr.net
Taras Shevchenko National University, Faculty of Chemistry, 60 Volodymyrska Str., Kyiv 0160, Ukraine
Polymer Technology Department, Chemical Faculty, Gdansk University of Technology, Gabriela Narutowicza Street 11/12, 80–233 Gdansk, Poland
Armenian National Polytechnic University, 105 Teryana Str., 375009 Yerevan, Armenia , E-mail: atonoyan@mail.ru
Georgian Technical University, V Chavchanidze Institute of Cybernetics, 5 S Euli , St, 0186 Tbilisi, Georgia
Chemistry Faculty, Kyiv National Taras Shevchenko University, 12 L Tolstogo Str., 01033 Kyiv, Ukraine , E-mail: lvretik@gmail.com
Department of Macromolecular Chemistry, Taras Shevchenko National University of Kyiv, 60 Volodymyrska Street, 01033, Kyiv, Ukraine
Papava, N Maisuradze, E Gavashelidze, Sh Papava, M Gurgenishvili, I Chitrekashvili, and V Sherozia
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane, Javakhishvili Tbilisi , State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane Javakhishvili Tbilisi , State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane, Javakhishvili Tbilisi , State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia
Georgian Technical University, V Chavchanidze Institute of Cybernetics, 5 S Euli , St, 0186 Tbilisi, Georgia
Georgian Technical University, 68 Merab Kostava Street, Tbilisi, Georgia Tbilisi, 0175, Georgia
Yerevan State University, A Manookyan St 1, 0025, Armenia , E-mail: Scirec@mail.ru Ł Piszczyk
Polymer Technology Department, Chemical Faculty, Gdansk University of Technology, Gabriela Narutowicza Street 11/12, 80-233 Gdansk, Poland
Tbilisi State University, 1 Ilia Chavchavadze Ave, Tbilisi 0179, Georgia
Faculty of Physics and Engineering, Moldova State University, 60 A Mateevici str., MD 2009, Chisinau, Moldova
Moldova State University, 60 A Mateevici str, MD-2009, Chisinau, Moldova, E-mail: s.v.robu@mail.ru
Norwegian University of Life Sciences (NMBU), Department of Env Sci., PO-Box 5003, No 1432, Ås, Norway , E-mail: Brit.Salbu@nmbu.no
Kyiv National Taras Shevchenko University, Department of Chemistry, Kyiv, Ukraine , E-mail: iras@univ.kiev.ua
Georgian Technical University, V Chavchanidze Institute of Cybernetics, 5 S Euli St, 0186 Tbilisi, Georgia
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane, Javakhishvili Tbilisi , State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia
Center of Physical and Chemical Methods of Research and Analysis, Tole bi Str 96a, 050012, Almaty, Kazakhstan
Chuiko Institute of Surface Chemistry, National Academy of Science of Ukraine, General Naumov str,
Kyiv Taras Shevchenko National University, Volodymyrska Str., 60, 01033, Kyiv, Ukraine, E-mail: vitaliismokal@gmail.com
Maria Curie-Skłodowska University, pl Maria Curie-Skłodowskiej 3, 20-031 Lublin, Poland
Ivane Javakhishvili Tbilisi State University Chavchavadze Avenue 1, Tbilisi, 0128, Georgia
Department of Macromolecular Chemistry, Taras Shevchenko National University of Kyiv, 60 Volodymyrska Street, 01033, Kyiv, Ukraine , E-mail: svg@univ.kiev.ua
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane Javakhishvili Tbilisi, State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia
Ivane Javakhishvili Tbilisi State University, Rafiel Agladze Institute of Inorganic Chemistry and Electrochemistry Mindeli str, 11, 0186, Tbilisi, Georgia
Institute of Molecular Biology and Genetics of Natl Acad of Sci of Ukraine, 150 Zabolotnogo str.150, Kyiv 03680, Ukraine, E-mail: gtelegeev@ukr.net
Taras Shevchenko National University, Faculty of Chemistry, 60 Volodymyrska Str., Kyiv 0160, Ukraine
Polymer Technology Department, Chemical Faculty, Gdansk University of Technology, Gabriela Narutowicza Street 11/12, 80–233 Gdansk, Poland
Armenian National Polytechnic University, 105 Teryana Str., 375009 Yerevan, Armenia , E-mail: atonoyan@mail.ru
Georgian Technical University, V Chavchanidze Institute of Cybernetics, 5 S Euli , St, 0186 Tbilisi, Georgia
Chemistry Faculty, Kyiv National Taras Shevchenko University, 12 L Tolstogo Str., 01033 Kyiv, Ukraine , E-mail: lvretik@gmail.com
Department of Macromolecular Chemistry, Taras Shevchenko National University of Kyiv, 60 Volodymyrska Street, 01033, Kyiv, Ukraine
Chemistry Faculty, Kyiv National Taras Shevchenko University, 12 L Tolstogo Str., 01033 Kyiv, Ukraine
Nagiyev Institute of Catalysis & Inorganic Chemistry, Azerbaijan National Academy of Sciences, H Javid Ave., 113, AZ1143 Baku, Azerbaijan, E-mail: zeynalov 2000@yahoo.com
Peoples’ Friendship University of Russia, Scientific-Educational Centre of Nanotechnology, Miklukho-Maklaya 10/2, 117198, Moscow, Russia
BHT 3,5-di-tert-butyl-4-hydroxyphenyl BPO benzoyl peroxide
DCPC dicyclohexylperoxide carbonate DLS dynamic light scattering
DSA differential scanning analyzer DSC differential scanning calorimetry DSC dye-sensitised solar cells
DTA differential thermal analysis EAS electronic absorption spectra EOS epoxidized soybean oil
FAME fatty acids methyl esters
GZSD graded zone stretching device HAuCl 4 thetrachloroauric acid
HOMO highest occupied molecular orbital
LCHP liquid cyclo hexanone peroxide
LUMO lowest unoccupied molecular orbital
MEKP methy ethyl kentone peroxide
MRO maintenace, repairing and overhall
OLEDs organic light emitting diodes
QELS quasy elastic light scattering
SAPF solid amorphous polymer fraction
TBO-Pc-Zn tetrabenzoxyphthalocyanine zinc
Full Professor, Iv Javakhishvili Tbilisi State University,
Faculty of Exact and Natural Sciences, Department of Chemistry;
Chair of Macromolecular Chemistry; Director, Institute of
Macromolecular Chemistry and Polymeric Materials, Tbilisi, Georgia
Omari Vasilii Mukbaniani, DSc, is Professor and Head of the Macromolecular Chemistry Department of Iv Javakhishvili Tbilisi State University, Tbilisi, Georgia He is also the Director of the Institute of Macromolecular Chemistry and Polymeric Materials He is a member of the Academy of Natural Sciences of the Georgian Republic For several years he was a member of the advisory board of the Journal Proceedings of Iv Javakhishvili Tbilisi State University (Chemical Series) and contributing editor of the journals Polymer News and the Polymers Research Journal He is member of editorial board of the Journal of Chemistry and Chemical Technology His research interests include polymer chemistry, polymeric materials, and chemistry of organo- silicon compounds He is an author more than 420 publication, 13 books, four monographs, and 10 inventions He created in 2007 the “International Caucasian Symposium on Polymers and Advanced Materials,” ICSP, which takes place every other two years in Georgia The last symposium, ICSP 5, was held in July 2017 in Tbilisi, Georgia.
Emeritus Professor, Institute Charles Gerhardt of Montpelier—Aggregates, Interfaces & Materials for Energy (ICGM-AIME, UMR CNRS 5253), University Montpelier, France
Professor Marc J M Abadie is Emeritus Professor at the University Montpellier, Institute Charles Gerhardt of Montpelier, Aggregates, Interfaces and Materials Energy (ICGM-AIME, UMR CNRS 5253), France He was head of the Laboratory of Polymer Science and Advanced Organic Materials
– LEMP/MAO He is currently “Michael Fam” Visiting Professor at the School of Materials Sciences and Engineering, Nanyang Technological University NTU, Singapore His present activity concerns high performance polymers for PEMFCs, composites and nanocomposites, UV/EB coatings, and biomaterials He has published 11 books and 11 patents He has advised nearly 95 MS and 52 PhD students with whom he has published over 402 papers He has more than 40 years of experience in polymer science with 10 years in the industry (IBM, USA – MOD, UK & SNPA/Total, France) He created in the 1980s the “International Symposium on Polyimides and High Temperature Polymers,” a.k.a STEPI, which takes place every other three years in Montpellier, France A recent symposium, STEPI 10, look place in June 5–8, 2016.
Senior Specialist, Unite of Academic Process Management
(Faculty of Exact and Natural Sciences), Ivane Javakhishvili Tbilisi State University; Senior Researcher, Institute of Macromolecular Chemistry and Polymeric Materials, Georgia
Tamara Tatrishvili, PhD, is Senior Specialist at the Unite of Academic Process Management (Faculty of Exact and Natural Sciences) at Ivane Javakhishvili Tbilisi State University as well as Senior Researcher of the Institute of Macromolecular Chemistry and Polymeric Materials in Tbilisi, Georgia.
Increasing interest in lightweight and high performance materials is leading to significant research activity in the area of polymers and composites One recent focus is to develop multifunctional materials that have more than one property tailored as per the design requirements in addition to achieving low density.
The possibility of simultaneously tailoring several desired properties is attractive but very challenging, and it requires significant advancements in the science and technology of high performance functional polymers and composites.
The structures and functions of these advanced polymer and composite systems are evaluated with respect to improved or novel performance, and the potential implications of those developments for the future of polymer- based composites and multifunctional materials are discussed
The ensemble selected papers presented at the 4th International Caucasian Symposium on Polymers and Advanced Materials are collected, as original unpublished research, in this book ICSP1AM-4 took place in Batumi Black sea beach, Georgia July 1–4, 2015 This book focuses exclusively on the latest research related to polymer and composite materials, especially new trends in frontal polymerization and copolymerization synthesis, function- alization of polymers, physical properties and hybrid systems A large part is devoted to composites and nanocomposites; their mechanical impact on their properties are evaluated and discussed Applications in medicine as drug-release for cancer treatment or as development of green materials and as renewable resources with a particular emphasis on the research of the authors’ group(s) are presented Coating and curing processes are also cov- ered in this book in order to have a better control and understanding of the crosslinking reactions
The progress captured in the current set of articles shows promise for developing materials that seem capable of moving this field from laboratory- scale prototypes to actual industrial applications.
This book serves as a valuable and informative reference for scientists, engineers, medical technologists and practioners engaged in the teaching, research, development and use of functional polymers and composites.
Professor, Dr of Science, Omari Mukbaniani
Iv Javakhishvili Tbilisi State University, Faculty of Exact and Natural Sciences, Department of Chemistry, Chair of Macromolecular Chemistry,
Director of the Institute of Macromolecular Chemistry and Polymeric Materials
Professor Emeritus, Doctor Honoris Causa Institut Charles Gerhardt de Montpellier – Agrégats, Interfaces et Matériaux pour l’Energie (IGCM AIME UMR CNRS 5253) STEPI General Chairman, Expert près la Cour d’Appel
“Michael Fam” Visiting Professor @ NTU/MSE, Singapore
Ivane Javakhishvili Tbilisi State University, Senior Specialist of the Unite of Academic Process Management
(Faculty of Exact and Natural Sciences), Senior Researcher of the Institute of Macromolecular Chemistry and
A H DURGARYAN, N A DURGARYAN, R H ARAKELYAN, and N A MIRAQYAN
Yerevan State University, Alek Manoogian 1, Yerevan, 375025,
Republic of Armenia, E-mail: durnar63@yahoo.com
Abstract 3 1.1 Introduction 4 1.2 Experimental Part 5 1.3 Results and Discussion 8 Acknowledgments 12 Keywords 12 References 12
The oxidative copolymerization of aniline with p-phenylenediamine in an acetic acid medium has been investigated for the first time It has been deter- mined that as a result of copolymerization; a polymer having a structure analogous to the polyaniline called emeraldine is formed The obtained copo- lymer doped with 3N hydrochloric acid has an electrical conductivity five times higher than that of polyaniline prepared by the usual method Aniline polymerization proceeds more slowly at 273K under the same copolymer- ization conditions and the obtained polymer has low conductivity However, in a mixture of acetic acid-methanol, the reaction proceeds faster and the obtained polymer has conductivity almost equal to that of emeraldine It has been observed that the conductivity of polymers doped with formic acid is lower than that of polymers obtained by doping with hydrochloric acid by 2 orders of magnitude.
Among the electro active polymers, the emeraldine form of polyaniline (PANI) attracts intense interest [1, 2] PANI occupies a particular place among the electro active conjugated polymers owing to its environmental stability, easy and cheap method of preparation and its unique properties
It is extensively used in various fields of technology [3–14] To improve the properties of PANI, studies of aniline copolymerization with different monomers have been conducted [12–19]; however, the conductivity of the obtained copolymers is inferior to that of PANI in spite of high solubility. According to the literature data, copolymer Ι[20] is formed during the copolymerization of p-phenylenediamine (PPDA) with aniline.
In the formation of copolymer Ι, for 1 mole each of aniline and PPDA,
3 moles of peroxydisulfate (PDS) are required [20] because when using 1 mole of PDS for 1 mole of aniline, the calculated yield for aniline cannot be higher than 33%, while a yield of 62% to 75% was actually obtained [20] It may be concluded from these data that the reaction does not proceed accord- ing to Figure 4 given in the Ref [20].
According to other literature data, in the case of a molar ratio of aniline/ PPDA of 50:1, the presence of PPDA greatly increases the rate of polymer- ization and does not affect the structure and crystalline of PANI [21].
These data strengthen our opinion that the reaction mechanism differs from that described in the literature [20], and considering the scheme for the oxidative polymerization of PPDA [22]; we have proposed that it proceeds with a mechanism similar to that depicted in Scheme 1[23].
If the reaction occurs according to Scheme 1, the maximum yield calcu- lated for aniline will be 67%, while in the case of a ratio of PPDA-aniline in the copolymer of more than 1; the yield will be above 67%.
The purpose of the present work is to verify the possibility that the reac- tion proceeds according to Scheme 1.
The inherent viscosity of DMSO solution was determined at 25°C, using Ubbelohde viscometer.
COMPOSITES AND NANOPARTICLES
Alekseeva, N Bagrovskaya, and A Noskov 9 Composites on the Basis of Sawdust with Some Organic
G.A Krestov Institute of Solution Chemistry, Russian Academy of Sciences, Akademicheskaya str., 1, Ivanovo, 153045, Russia, E-mail: avn@isc-ras.ru
NIBIO, Norwegian Institute of Bioeconomy Research, Pb 115, N-1431, Ås, Norway, E-mail: Emilio.Alvarenga@nibio.no
Ivane Javakhishvili Tbilisi State University, Rafiel Agladze Institute of Inorganic Chemistry and Electrochemistry Mindeli str., 11, 0186, Tbilisi, Georgia
Moldova State University, 60 A Mateevici str., MD-2009, Chisinau, Moldova
Yerevan State University, Alek Manoogian 1, Yerevan, 375025, Republic of Armenia
Center of Physical and Chemical Methods of Research and Analysis, Tole bi Str 96a, 050012, Almaty, Kazakhstan
G A Krestov Institute of Solution Chemistry, Russian Academy of Sciences, Akademicheskaya str., 1, Ivanovo, 153045, Russia
Ilia Vekua Sukhumi Institute of Physics and Technology, Laboratory of Cryogenic Technique and Technologies, Mindeli Str 7, 0186 Tbilisi, Georgia
V I Vernadsky Institute of General and Inorganic Chemistry NASU, Kyiv, Ukraine
Moldova State University, 60 A Mateevici str., MD-2009, Chisinau, Moldova
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane Javakhishvili Tbilisi , State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia
Chuiko Institute of Surface Chemistry, National Academy of Science of Ukraine, General Naumov str,
Tbilisi State University, 1 Ilia Chavchavadze Ave, Tbilisi 0179, Georgia, E-mail: chubinidzeketino@yahoo.com
Problem Research Laboratory, National University of Food Technology, 68, Volodymyrska Street
Moldova State University, 60 A Mateevici str., MD-2009, Chisinau, Moldova
Faculty of Physics and Engineering, Moldova State University, 60 A Mateevici str., MD 2009, Chisinau, Moldova
Polymer Technology Department, Chemical Faculty, Gdansk University of Technology, Gabriela Narutowicza Street 11/12, 80-233 Gdansk, Poland
Armenian National Polytechnic University 105, Teryana Str., 105 375009 Yerevan, Armenia
Ilia Vekua Sukhumi Institute of Physics and Technology, Laboratory of Cryogenic Technique and Technologies, Mindeli Str 7, 0186 Tbilisi, Georgia
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane Javakhishvili Tbilisi , State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia
Georgian Technical University, Kostava Str., 77, 0175, Tbilisi, Georgia
Faculty of Chemistry and Chemical Technology
Yerevan State University, Alek Manoogian 1, Yerevan, 375025, Republic of Armenia , E-mail: durnar63@yahoo.com
Yerevan State University, Alek Manoogian 1, Yerevan, 375025, Republic of Armenia
V I Vernadsky Institute of General and Inorganic Chemistry NASU, Kyiv, Ukraine
Taras Shevchenko National University, Faculty of Chemistry, 60 Volodymyrska Str., Kyiv 0160, Ukraine
Polymer Technology Department, Chemical Faculty, Gdansk University of Technology, Gabriela Narutowicza Street 11/12, 80-233 Gdansk, Poland
Ilia Vekua Sukhumi Institute of Physics and Technology, Laboratory of Cryogenic Technique and Technologies, Mindeli str, 7, 0186 Tbilisi, Georgia
Ivane Javakhishvili Tbilisi State University, Rafiel Agladze Institute of Inorganic Chemistry and Electrochemistry Mindeli str, 11, 0186, Tbilisi, Georgia
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane, Javakhishvili Tbilisi , State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane Javakhishvili Tbilisi , State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia
Energy Recovery Agency of Oslo County, PO-BOX 54 Mortensrud, NO-1215, Oslo, Norway, E-mail: Espen.Govasmark@ege.oslo.kommune.no
The Scientific Technological Centre of Organic and Pharmaceutical Chemistry NAS RA, Institute of Organic Chemistry, 26, Azatutyan STR, 0014, Yerevan, Armenia
The Scientific Technological Centre of Organic and Pharmaceutical Chemistry NAS RA, Institute of Organic Chemistry 26, Azatutyan STR, 0014, Yerevan, Armenia
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane, Javakhishvili Tbilisi , State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia, E-mail: marina.gurgenishvili@yahoo.com
Department of Resin and Additives, Institute for Color Science and Technology, Tehran, Iran, E-mail: zeinab.hesari@yahoo.com
Polymer Technology Department, Chemical Faculty, Gdansk University of Technology, Gabriela Narutowicza Street 11/12, 80-233 Gdansk, Poland, E-mail: jozef.haponiuk@pg.gda.pl
Taras Shevchenko National University, Faculty of Chemistry, 60 Volodymyrska Str., Kyiv 0160, Ukraine
Yerevan State University, A Manookyan St 1, 0025, Armenia , E-mail: Scirec@mail.ru
Yerevan State University, A Manookyan St 1, 0025, Armenia, E-mail: Scirec@mail.ru
Polymer Technology Department, Chemical Faculty, Gdansk University of Technology, Gabriela Narutowicza Street 11/12, 80-233 Gdansk, Poland
Department of Chemistry, Faculty of Science, Science and Research of Tehran Branch Islamic Azad University, Tehran, Iran, E-mail: zeinab.hesari@yahoo.com
The Scientific Technological Centre of Organic and Pharmaceutical Chemistry NAS RA, Institute of Organic Chemistry 26, Azatutyan STR, 0014, Yerevan, Armenia, E-mail: hovarnos@gmail.com
Moldova State University, 60 A Mateevici str., MD-2009, Chisinau, Moldova
JSC, “Institue of Chemical Sciences after A.B Bekturov”, Sh Valikhanov st 106, Almaty, Republic of Kazakhstan, E-mail: jumadilov@mail.ru
Peoples’ Friendship University of Russia, Scientific-Educational Centre of Nanotechnology, Miklukho- Maklaya 10/2, 117198, Moscow, Russia
Kyiv Taras Shevchenko National University, Volodymyrska Str 60, 01033, Kyiv, Ukraine
Department of Macromolecular Chemistry, Taras Shevchenko National University of Kyiv, 60 Volodymyrska Street, 01033, Kyiv, Ukraine
Al-Farabi Kazakh National University, Faculty of Chemistry and Chemical Technology, Al-Farabi ave
Kyiv Taras Shevchenko National University, Volodymyrska Str 60, 01033, Kyiv, Ukraine
Center of Physical and Chemical Methods of Research and Analysis, Tole bi Str 96a, 050012, Almaty, Kazakhstan
Taras Shevchenko National University, Faculty of Chemistry, 60 Volodymyrska Str., Kyiv 0160, Ukraine
Taras Shevchenko National University, Faculty of Chemistry, 60 Volodymyrska Str., Kyiv 0160, Ukraine, Email: kutsevol@ukr.net
Department of Sciences, Ivan Franko Zhytomyr State University, 40 Velyka Berdychivska Str., 10008 Zhytomyr, Ukraine
Chuiko Institute of Surface Chemistry, National Academy of Science of Ukraine, General Naumov Str
17, 03164 Kyiv, Ukraine, E-mail: okslinnik@yahoo.co.uk
Iv Javakhishvili Tbilisi State University, Department of Chemistry, I Chavchavadze Ave, 1, 0179 Tbilisi, Georgia
Nagiyev Institute of Catalysis & Inorganic Chemistry, Azerbaijan National Academy of Sciences,
H Javid Ave., 113, AZ1143 Baku, Azerbaijan
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane, Javakhishvili Tbilisi , State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia
Ivane Javakhishvili Tbilisi State University Chavchavadze Avenue 1, Tbilisi 0128, Georgia
Ivane Javakhishvili Tbilisi State University Chavchavadze Avenue 1, Tbilisi, 0128, Georgia
Ivane Javakhishvili Tbilisi State University, E Andronikashvili Institute of Physics, Tamarashvili str, 6,
Problem Research Laboratory, National University of Food Technology, 68, Volodymyrska Street
Ivane Javakhishvili Tbilisi State University, Rafiel Agladze Institute of Inorganic Chemistry and Electrochemistry Mindeli str, 11, 0186, Tbilisi, Georgia, E-mail: tamazmarsagishvili@gmail.com
Chemistry Faculty, Kyiv National Taras Shevchenko University, 12 L Tolstogo Str., 01033 Kyiv, Ukraine
Ivane Javakhishvili Tbilisi State University, Rafiel Agladze Institute of Inorganic Chemistry and Electrochemistry Mindeli str., 11, 0186, Tbilisi, Georgia
Ilia Vekua Sukhumi Institute of Physics and Technology, Laboratory of Cryogenic Technique and Technologies, Mindeli Str 7, 0186 Tbilisi, Georgia
Georgian Technical University, Department of Engineering Physics, Kostava Str 77, 0175 Tbilisi, Georgia
Yerevan State University, Alek Manoogian 1, Yerevan, 375025, Republic of Armenia
Georgian Technical University, V Chavchanidze Institute of Cybernetics, 5 S Euli , St, 0186 Tbilisi, Georgia
Taras Shevchenko National University of Kyiv, Department of Chemistry, Volodymyrska Str., 60,
Faculty of Physics and Engineering, Moldova State University, 60 A Mateevici str., MD 2009, Chisinau, Moldova
Chemistry Faculty, Kyiv National Taras Shevchenko University, 12 L Tolstogo Str., 01033 Kyiv, Ukraine
G.A Krestov Institute of Solution Chemistry, Russian Academy of Sciences, Akademicheskaya Str., 1, Ivanovo, 153045, Russia
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane, Javakhishvili Tbilisi , State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane Javakhishvili Tbilisi , State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane, Javakhishvili Tbilisi , State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia
Georgian Technical University, V Chavchanidze Institute of Cybernetics, 5 S Euli , St, 0186 Tbilisi, Georgia
Georgian Technical University, 68 Merab Kostava Street, Tbilisi, Georgia Tbilisi, 0175, Georgia
Yerevan State University, A Manookyan St 1, 0025, Armenia , E-mail: Scirec@mail.ru Ł Piszczyk
Polymer Technology Department, Chemical Faculty, Gdansk University of Technology, Gabriela Narutowicza Street 11/12, 80-233 Gdansk, Poland
Tbilisi State University, 1 Ilia Chavchavadze Ave, Tbilisi 0179, Georgia
Faculty of Physics and Engineering, Moldova State University, 60 A Mateevici str., MD 2009, Chisinau, Moldova
Moldova State University, 60 A Mateevici str, MD-2009, Chisinau, Moldova, E-mail: s.v.robu@mail.ru
Norwegian University of Life Sciences (NMBU), Department of Env Sci., PO-Box 5003, No 1432, Ås, Norway , E-mail: Brit.Salbu@nmbu.no
Kyiv National Taras Shevchenko University, Department of Chemistry, Kyiv, Ukraine , E-mail: iras@univ.kiev.ua
Georgian Technical University, V Chavchanidze Institute of Cybernetics, 5 S Euli St, 0186 Tbilisi, Georgia
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane, Javakhishvili Tbilisi , State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia
Center of Physical and Chemical Methods of Research and Analysis, Tole bi Str 96a, 050012, Almaty, Kazakhstan
Chuiko Institute of Surface Chemistry, National Academy of Science of Ukraine, General Naumov str,
Kyiv Taras Shevchenko National University, Volodymyrska Str., 60, 01033, Kyiv, Ukraine, E-mail: vitaliismokal@gmail.com
Maria Curie-Skłodowska University, pl Maria Curie-Skłodowskiej 3, 20-031 Lublin, Poland
Ivane Javakhishvili Tbilisi State University Chavchavadze Avenue 1, Tbilisi, 0128, Georgia
Department of Macromolecular Chemistry, Taras Shevchenko National University of Kyiv, 60 Volodymyrska Street, 01033, Kyiv, Ukraine , E-mail: svg@univ.kiev.ua
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane Javakhishvili Tbilisi, State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia
Ivane Javakhishvili Tbilisi State University, Rafiel Agladze Institute of Inorganic Chemistry and Electrochemistry Mindeli str, 11, 0186, Tbilisi, Georgia
Institute of Molecular Biology and Genetics of Natl Acad of Sci of Ukraine, 150 Zabolotnogo str.150, Kyiv 03680, Ukraine, E-mail: gtelegeev@ukr.net
Taras Shevchenko National University, Faculty of Chemistry, 60 Volodymyrska Str., Kyiv 0160, Ukraine
Polymer Technology Department, Chemical Faculty, Gdansk University of Technology, Gabriela Narutowicza Street 11/12, 80–233 Gdansk, Poland
Armenian National Polytechnic University, 105 Teryana Str., 375009 Yerevan, Armenia , E-mail: atonoyan@mail.ru
Georgian Technical University, V Chavchanidze Institute of Cybernetics, 5 S Euli , St, 0186 Tbilisi, Georgia
Chemistry Faculty, Kyiv National Taras Shevchenko University, 12 L Tolstogo Str., 01033 Kyiv, Ukraine , E-mail: lvretik@gmail.com
Department of Macromolecular Chemistry, Taras Shevchenko National University of Kyiv, 60 Volodymyrska Street, 01033, Kyiv, Ukraine
Chemistry Faculty, Kyiv National Taras Shevchenko University, 12 L Tolstogo Str., 01033 Kyiv, Ukraine
Nagiyev Institute of Catalysis & Inorganic Chemistry, Azerbaijan National Academy of Sciences, H Javid Ave., 113, AZ1143 Baku, Azerbaijan, E-mail: zeynalov 2000@yahoo.com
Peoples’ Friendship University of Russia, Scientific-Educational Centre of Nanotechnology, Miklukho-Maklaya 10/2, 117198, Moscow, Russia
BHT 3,5-di-tert-butyl-4-hydroxyphenyl BPO benzoyl peroxide
DCPC dicyclohexylperoxide carbonate DLS dynamic light scattering
DSA differential scanning analyzer DSC differential scanning calorimetry DSC dye-sensitised solar cells
DTA differential thermal analysis EAS electronic absorption spectra EOS epoxidized soybean oil
FAME fatty acids methyl esters
GZSD graded zone stretching device HAuCl 4 thetrachloroauric acid
HOMO highest occupied molecular orbital
LCHP liquid cyclo hexanone peroxide
LUMO lowest unoccupied molecular orbital
MEKP methy ethyl kentone peroxide
MRO maintenace, repairing and overhall
OLEDs organic light emitting diodes
QELS quasy elastic light scattering
SAPF solid amorphous polymer fraction
TBO-Pc-Zn tetrabenzoxyphthalocyanine zinc
Full Professor, Iv Javakhishvili Tbilisi State University,
Faculty of Exact and Natural Sciences, Department of Chemistry;
Chair of Macromolecular Chemistry; Director, Institute of
Macromolecular Chemistry and Polymeric Materials, Tbilisi, Georgia
Omari Vasilii Mukbaniani, DSc, is Professor and Head of the Macromolecular Chemistry Department of Iv Javakhishvili Tbilisi State University, Tbilisi, Georgia He is also the Director of the Institute of Macromolecular Chemistry and Polymeric Materials He is a member of the Academy of Natural Sciences of the Georgian Republic For several years he was a member of the advisory board of the Journal Proceedings of Iv Javakhishvili Tbilisi State University (Chemical Series) and contributing editor of the journals Polymer News and the Polymers Research Journal He is member of editorial board of the Journal of Chemistry and Chemical Technology His research interests include polymer chemistry, polymeric materials, and chemistry of organo- silicon compounds He is an author more than 420 publication, 13 books, four monographs, and 10 inventions He created in 2007 the “International Caucasian Symposium on Polymers and Advanced Materials,” ICSP, which takes place every other two years in Georgia The last symposium, ICSP 5, was held in July 2017 in Tbilisi, Georgia.
Emeritus Professor, Institute Charles Gerhardt of Montpelier—Aggregates, Interfaces & Materials for Energy (ICGM-AIME, UMR CNRS 5253), University Montpelier, France
Professor Marc J M Abadie is Emeritus Professor at the University Montpellier, Institute Charles Gerhardt of Montpelier, Aggregates, Interfaces and Materials Energy (ICGM-AIME, UMR CNRS 5253), France He was head of the Laboratory of Polymer Science and Advanced Organic Materials
– LEMP/MAO He is currently “Michael Fam” Visiting Professor at the School of Materials Sciences and Engineering, Nanyang Technological University NTU, Singapore His present activity concerns high performance polymers for PEMFCs, composites and nanocomposites, UV/EB coatings, and biomaterials He has published 11 books and 11 patents He has advised nearly 95 MS and 52 PhD students with whom he has published over 402 papers He has more than 40 years of experience in polymer science with 10 years in the industry (IBM, USA – MOD, UK & SNPA/Total, France) He created in the 1980s the “International Symposium on Polyimides and High Temperature Polymers,” a.k.a STEPI, which takes place every other three years in Montpellier, France A recent symposium, STEPI 10, look place in June 5–8, 2016.
Senior Specialist, Unite of Academic Process Management
(Faculty of Exact and Natural Sciences), Ivane Javakhishvili Tbilisi State University; Senior Researcher, Institute of Macromolecular Chemistry and Polymeric Materials, Georgia
Tamara Tatrishvili, PhD, is Senior Specialist at the Unite of Academic Process Management (Faculty of Exact and Natural Sciences) at Ivane Javakhishvili Tbilisi State University as well as Senior Researcher of the Institute of Macromolecular Chemistry and Polymeric Materials in Tbilisi, Georgia.
Increasing interest in lightweight and high performance materials is leading to significant research activity in the area of polymers and composites One recent focus is to develop multifunctional materials that have more than one property tailored as per the design requirements in addition to achieving low density.
The possibility of simultaneously tailoring several desired properties is attractive but very challenging, and it requires significant advancements in the science and technology of high performance functional polymers and composites.
The structures and functions of these advanced polymer and composite systems are evaluated with respect to improved or novel performance, and the potential implications of those developments for the future of polymer- based composites and multifunctional materials are discussed
The ensemble selected papers presented at the 4th International Caucasian Symposium on Polymers and Advanced Materials are collected, as original unpublished research, in this book ICSP1AM-4 took place in Batumi Black sea beach, Georgia July 1–4, 2015 This book focuses exclusively on the latest research related to polymer and composite materials, especially new trends in frontal polymerization and copolymerization synthesis, function- alization of polymers, physical properties and hybrid systems A large part is devoted to composites and nanocomposites; their mechanical impact on their properties are evaluated and discussed Applications in medicine as drug-release for cancer treatment or as development of green materials and as renewable resources with a particular emphasis on the research of the authors’ group(s) are presented Coating and curing processes are also cov- ered in this book in order to have a better control and understanding of the crosslinking reactions
The progress captured in the current set of articles shows promise for developing materials that seem capable of moving this field from laboratory- scale prototypes to actual industrial applications.
This book serves as a valuable and informative reference for scientists, engineers, medical technologists and practioners engaged in the teaching, research, development and use of functional polymers and composites.
Professor, Dr of Science, Omari Mukbaniani
Iv Javakhishvili Tbilisi State University, Faculty of Exact and Natural Sciences, Department of Chemistry, Chair of Macromolecular Chemistry,
Director of the Institute of Macromolecular Chemistry and Polymeric Materials
Professor Emeritus, Doctor Honoris Causa Institut Charles Gerhardt de Montpellier – Agrégats, Interfaces et Matériaux pour l’Energie (IGCM AIME UMR CNRS 5253) STEPI General Chairman, Expert près la Cour d’Appel
“Michael Fam” Visiting Professor @ NTU/MSE, Singapore
Ivane Javakhishvili Tbilisi State University, Senior Specialist of the Unite of Academic Process Management
(Faculty of Exact and Natural Sciences), Senior Researcher of the Institute of Macromolecular Chemistry and
A H DURGARYAN, N A DURGARYAN, R H ARAKELYAN, and N A MIRAQYAN
Yerevan State University, Alek Manoogian 1, Yerevan, 375025,
Republic of Armenia, E-mail: durnar63@yahoo.com
Abstract 3 1.1 Introduction 4 1.2 Experimental Part 5 1.3 Results and Discussion 8 Acknowledgments 12 Keywords 12 References 12
The oxidative copolymerization of aniline with p-phenylenediamine in an acetic acid medium has been investigated for the first time It has been deter- mined that as a result of copolymerization; a polymer having a structure analogous to the polyaniline called emeraldine is formed The obtained copo- lymer doped with 3N hydrochloric acid has an electrical conductivity five times higher than that of polyaniline prepared by the usual method Aniline polymerization proceeds more slowly at 273K under the same copolymer- ization conditions and the obtained polymer has low conductivity However, in a mixture of acetic acid-methanol, the reaction proceeds faster and the obtained polymer has conductivity almost equal to that of emeraldine It has been observed that the conductivity of polymers doped with formic acid is lower than that of polymers obtained by doping with hydrochloric acid by 2 orders of magnitude.
Among the electro active polymers, the emeraldine form of polyaniline (PANI) attracts intense interest [1, 2] PANI occupies a particular place among the electro active conjugated polymers owing to its environmental stability, easy and cheap method of preparation and its unique properties
It is extensively used in various fields of technology [3–14] To improve the properties of PANI, studies of aniline copolymerization with different monomers have been conducted [12–19]; however, the conductivity of the obtained copolymers is inferior to that of PANI in spite of high solubility. According to the literature data, copolymer Ι[20] is formed during the copolymerization of p-phenylenediamine (PPDA) with aniline.
In the formation of copolymer Ι, for 1 mole each of aniline and PPDA,
3 moles of peroxydisulfate (PDS) are required [20] because when using 1 mole of PDS for 1 mole of aniline, the calculated yield for aniline cannot be higher than 33%, while a yield of 62% to 75% was actually obtained [20] It may be concluded from these data that the reaction does not proceed accord- ing to Figure 4 given in the Ref [20].
According to other literature data, in the case of a molar ratio of aniline/ PPDA of 50:1, the presence of PPDA greatly increases the rate of polymer- ization and does not affect the structure and crystalline of PANI [21].
These data strengthen our opinion that the reaction mechanism differs from that described in the literature [20], and considering the scheme for the oxidative polymerization of PPDA [22]; we have proposed that it proceeds with a mechanism similar to that depicted in Scheme 1[23].
If the reaction occurs according to Scheme 1, the maximum yield calcu- lated for aniline will be 67%, while in the case of a ratio of PPDA-aniline in the copolymer of more than 1; the yield will be above 67%.
The purpose of the present work is to verify the possibility that the reac- tion proceeds according to Scheme 1.
The inherent viscosity of DMSO solution was determined at 25°C, using Ubbelohde viscometer.
S Askarova, K A Ablayeva, A P Kurbatov, and Ye S Sivokhina 15 Dextran-Polyacrylamide as Nanocarrier for Targeted Delivery
Center of Physical and Chemical Methods of Research and Analysis, Tole bi Str 96a, 050012, Almaty, Kazakhstan
G A Krestov Institute of Solution Chemistry, Russian Academy of Sciences, Akademicheskaya str., 1, Ivanovo, 153045, Russia
Ilia Vekua Sukhumi Institute of Physics and Technology, Laboratory of Cryogenic Technique and Technologies, Mindeli Str 7, 0186 Tbilisi, Georgia
V I Vernadsky Institute of General and Inorganic Chemistry NASU, Kyiv, Ukraine
Moldova State University, 60 A Mateevici str., MD-2009, Chisinau, Moldova
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane Javakhishvili Tbilisi , State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia
Chuiko Institute of Surface Chemistry, National Academy of Science of Ukraine, General Naumov str,
Tbilisi State University, 1 Ilia Chavchavadze Ave, Tbilisi 0179, Georgia, E-mail: chubinidzeketino@yahoo.com
Problem Research Laboratory, National University of Food Technology, 68, Volodymyrska Street
Moldova State University, 60 A Mateevici str., MD-2009, Chisinau, Moldova
Faculty of Physics and Engineering, Moldova State University, 60 A Mateevici str., MD 2009, Chisinau, Moldova
Polymer Technology Department, Chemical Faculty, Gdansk University of Technology, Gabriela Narutowicza Street 11/12, 80-233 Gdansk, Poland
Armenian National Polytechnic University 105, Teryana Str., 105 375009 Yerevan, Armenia
Ilia Vekua Sukhumi Institute of Physics and Technology, Laboratory of Cryogenic Technique and Technologies, Mindeli Str 7, 0186 Tbilisi, Georgia
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane Javakhishvili Tbilisi , State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia
Georgian Technical University, Kostava Str., 77, 0175, Tbilisi, Georgia
Faculty of Chemistry and Chemical Technology
Yerevan State University, Alek Manoogian 1, Yerevan, 375025, Republic of Armenia , E-mail: durnar63@yahoo.com
Yerevan State University, Alek Manoogian 1, Yerevan, 375025, Republic of Armenia
V I Vernadsky Institute of General and Inorganic Chemistry NASU, Kyiv, Ukraine
Taras Shevchenko National University, Faculty of Chemistry, 60 Volodymyrska Str., Kyiv 0160, Ukraine
Polymer Technology Department, Chemical Faculty, Gdansk University of Technology, Gabriela Narutowicza Street 11/12, 80-233 Gdansk, Poland
Ilia Vekua Sukhumi Institute of Physics and Technology, Laboratory of Cryogenic Technique and Technologies, Mindeli str, 7, 0186 Tbilisi, Georgia
Ivane Javakhishvili Tbilisi State University, Rafiel Agladze Institute of Inorganic Chemistry and Electrochemistry Mindeli str, 11, 0186, Tbilisi, Georgia
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane, Javakhishvili Tbilisi , State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane Javakhishvili Tbilisi , State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia
Energy Recovery Agency of Oslo County, PO-BOX 54 Mortensrud, NO-1215, Oslo, Norway, E-mail: Espen.Govasmark@ege.oslo.kommune.no
The Scientific Technological Centre of Organic and Pharmaceutical Chemistry NAS RA, Institute of Organic Chemistry, 26, Azatutyan STR, 0014, Yerevan, Armenia
The Scientific Technological Centre of Organic and Pharmaceutical Chemistry NAS RA, Institute of Organic Chemistry 26, Azatutyan STR, 0014, Yerevan, Armenia
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane, Javakhishvili Tbilisi , State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia, E-mail: marina.gurgenishvili@yahoo.com
Department of Resin and Additives, Institute for Color Science and Technology, Tehran, Iran, E-mail: zeinab.hesari@yahoo.com
Polymer Technology Department, Chemical Faculty, Gdansk University of Technology, Gabriela Narutowicza Street 11/12, 80-233 Gdansk, Poland, E-mail: jozef.haponiuk@pg.gda.pl
Taras Shevchenko National University, Faculty of Chemistry, 60 Volodymyrska Str., Kyiv 0160, Ukraine
Yerevan State University, A Manookyan St 1, 0025, Armenia , E-mail: Scirec@mail.ru
Yerevan State University, A Manookyan St 1, 0025, Armenia, E-mail: Scirec@mail.ru
Polymer Technology Department, Chemical Faculty, Gdansk University of Technology, Gabriela Narutowicza Street 11/12, 80-233 Gdansk, Poland
Department of Chemistry, Faculty of Science, Science and Research of Tehran Branch Islamic Azad University, Tehran, Iran, E-mail: zeinab.hesari@yahoo.com
The Scientific Technological Centre of Organic and Pharmaceutical Chemistry NAS RA, Institute of Organic Chemistry 26, Azatutyan STR, 0014, Yerevan, Armenia, E-mail: hovarnos@gmail.com
Moldova State University, 60 A Mateevici str., MD-2009, Chisinau, Moldova
JSC, “Institue of Chemical Sciences after A.B Bekturov”, Sh Valikhanov st 106, Almaty, Republic of Kazakhstan, E-mail: jumadilov@mail.ru
Peoples’ Friendship University of Russia, Scientific-Educational Centre of Nanotechnology, Miklukho- Maklaya 10/2, 117198, Moscow, Russia
Kyiv Taras Shevchenko National University, Volodymyrska Str 60, 01033, Kyiv, Ukraine
Department of Macromolecular Chemistry, Taras Shevchenko National University of Kyiv, 60 Volodymyrska Street, 01033, Kyiv, Ukraine
Al-Farabi Kazakh National University, Faculty of Chemistry and Chemical Technology, Al-Farabi ave
Kyiv Taras Shevchenko National University, Volodymyrska Str 60, 01033, Kyiv, Ukraine
Center of Physical and Chemical Methods of Research and Analysis, Tole bi Str 96a, 050012, Almaty, Kazakhstan
Taras Shevchenko National University, Faculty of Chemistry, 60 Volodymyrska Str., Kyiv 0160, Ukraine
Taras Shevchenko National University, Faculty of Chemistry, 60 Volodymyrska Str., Kyiv 0160, Ukraine, Email: kutsevol@ukr.net
Department of Sciences, Ivan Franko Zhytomyr State University, 40 Velyka Berdychivska Str., 10008 Zhytomyr, Ukraine
Chuiko Institute of Surface Chemistry, National Academy of Science of Ukraine, General Naumov Str
17, 03164 Kyiv, Ukraine, E-mail: okslinnik@yahoo.co.uk
Iv Javakhishvili Tbilisi State University, Department of Chemistry, I Chavchavadze Ave, 1, 0179 Tbilisi, Georgia
Nagiyev Institute of Catalysis & Inorganic Chemistry, Azerbaijan National Academy of Sciences,
H Javid Ave., 113, AZ1143 Baku, Azerbaijan
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane, Javakhishvili Tbilisi , State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia
Ivane Javakhishvili Tbilisi State University Chavchavadze Avenue 1, Tbilisi 0128, Georgia
Ivane Javakhishvili Tbilisi State University Chavchavadze Avenue 1, Tbilisi, 0128, Georgia
Ivane Javakhishvili Tbilisi State University, E Andronikashvili Institute of Physics, Tamarashvili str, 6,
Problem Research Laboratory, National University of Food Technology, 68, Volodymyrska Street
Ivane Javakhishvili Tbilisi State University, Rafiel Agladze Institute of Inorganic Chemistry and Electrochemistry Mindeli str, 11, 0186, Tbilisi, Georgia, E-mail: tamazmarsagishvili@gmail.com
Chemistry Faculty, Kyiv National Taras Shevchenko University, 12 L Tolstogo Str., 01033 Kyiv, Ukraine
Ivane Javakhishvili Tbilisi State University, Rafiel Agladze Institute of Inorganic Chemistry and Electrochemistry Mindeli str., 11, 0186, Tbilisi, Georgia
Ilia Vekua Sukhumi Institute of Physics and Technology, Laboratory of Cryogenic Technique and Technologies, Mindeli Str 7, 0186 Tbilisi, Georgia
Georgian Technical University, Department of Engineering Physics, Kostava Str 77, 0175 Tbilisi, Georgia
Yerevan State University, Alek Manoogian 1, Yerevan, 375025, Republic of Armenia
Georgian Technical University, V Chavchanidze Institute of Cybernetics, 5 S Euli , St, 0186 Tbilisi, Georgia
Taras Shevchenko National University of Kyiv, Department of Chemistry, Volodymyrska Str., 60,
Faculty of Physics and Engineering, Moldova State University, 60 A Mateevici str., MD 2009, Chisinau, Moldova
Chemistry Faculty, Kyiv National Taras Shevchenko University, 12 L Tolstogo Str., 01033 Kyiv, Ukraine
G.A Krestov Institute of Solution Chemistry, Russian Academy of Sciences, Akademicheskaya Str., 1, Ivanovo, 153045, Russia
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane, Javakhishvili Tbilisi , State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane Javakhishvili Tbilisi , State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane, Javakhishvili Tbilisi , State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia
Georgian Technical University, V Chavchanidze Institute of Cybernetics, 5 S Euli , St, 0186 Tbilisi, Georgia
Georgian Technical University, 68 Merab Kostava Street, Tbilisi, Georgia Tbilisi, 0175, Georgia
Yerevan State University, A Manookyan St 1, 0025, Armenia , E-mail: Scirec@mail.ru Ł Piszczyk
Polymer Technology Department, Chemical Faculty, Gdansk University of Technology, Gabriela Narutowicza Street 11/12, 80-233 Gdansk, Poland
Tbilisi State University, 1 Ilia Chavchavadze Ave, Tbilisi 0179, Georgia
Faculty of Physics and Engineering, Moldova State University, 60 A Mateevici str., MD 2009, Chisinau, Moldova
Moldova State University, 60 A Mateevici str, MD-2009, Chisinau, Moldova, E-mail: s.v.robu@mail.ru
Norwegian University of Life Sciences (NMBU), Department of Env Sci., PO-Box 5003, No 1432, Ås, Norway , E-mail: Brit.Salbu@nmbu.no
Kyiv National Taras Shevchenko University, Department of Chemistry, Kyiv, Ukraine , E-mail: iras@univ.kiev.ua
Georgian Technical University, V Chavchanidze Institute of Cybernetics, 5 S Euli St, 0186 Tbilisi, Georgia
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane, Javakhishvili Tbilisi , State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia
Center of Physical and Chemical Methods of Research and Analysis, Tole bi Str 96a, 050012, Almaty, Kazakhstan
Chuiko Institute of Surface Chemistry, National Academy of Science of Ukraine, General Naumov str,
Kyiv Taras Shevchenko National University, Volodymyrska Str., 60, 01033, Kyiv, Ukraine, E-mail: vitaliismokal@gmail.com
Maria Curie-Skłodowska University, pl Maria Curie-Skłodowskiej 3, 20-031 Lublin, Poland
Ivane Javakhishvili Tbilisi State University Chavchavadze Avenue 1, Tbilisi, 0128, Georgia
Department of Macromolecular Chemistry, Taras Shevchenko National University of Kyiv, 60 Volodymyrska Street, 01033, Kyiv, Ukraine , E-mail: svg@univ.kiev.ua
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane Javakhishvili Tbilisi, State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia
Ivane Javakhishvili Tbilisi State University, Rafiel Agladze Institute of Inorganic Chemistry and Electrochemistry Mindeli str, 11, 0186, Tbilisi, Georgia
Institute of Molecular Biology and Genetics of Natl Acad of Sci of Ukraine, 150 Zabolotnogo str.150, Kyiv 03680, Ukraine, E-mail: gtelegeev@ukr.net
Telegeeva, N Kutsevol, S Filipchenko, and G Telegeev 16 Investigation Photothermal and Photooptical Energy Conversions
Taras Shevchenko National University, Faculty of Chemistry, 60 Volodymyrska Str., Kyiv 0160, Ukraine
Polymer Technology Department, Chemical Faculty, Gdansk University of Technology, Gabriela Narutowicza Street 11/12, 80–233 Gdansk, Poland
Armenian National Polytechnic University, 105 Teryana Str., 375009 Yerevan, Armenia , E-mail: atonoyan@mail.ru
Georgian Technical University, V Chavchanidze Institute of Cybernetics, 5 S Euli , St, 0186 Tbilisi, Georgia
Chemistry Faculty, Kyiv National Taras Shevchenko University, 12 L Tolstogo Str., 01033 Kyiv, Ukraine , E-mail: lvretik@gmail.com
Department of Macromolecular Chemistry, Taras Shevchenko National University of Kyiv, 60 Volodymyrska Street, 01033, Kyiv, Ukraine
Chemistry Faculty, Kyiv National Taras Shevchenko University, 12 L Tolstogo Str., 01033 Kyiv, Ukraine
Nagiyev Institute of Catalysis & Inorganic Chemistry, Azerbaijan National Academy of Sciences, H Javid Ave., 113, AZ1143 Baku, Azerbaijan, E-mail: zeynalov 2000@yahoo.com
Peoples’ Friendship University of Russia, Scientific-Educational Centre of Nanotechnology, Miklukho-Maklaya 10/2, 117198, Moscow, Russia
BHT 3,5-di-tert-butyl-4-hydroxyphenyl BPO benzoyl peroxide
DCPC dicyclohexylperoxide carbonate DLS dynamic light scattering
DSA differential scanning analyzer DSC differential scanning calorimetry DSC dye-sensitised solar cells
DTA differential thermal analysis EAS electronic absorption spectra EOS epoxidized soybean oil
FAME fatty acids methyl esters
GZSD graded zone stretching device HAuCl 4 thetrachloroauric acid
HOMO highest occupied molecular orbital
LCHP liquid cyclo hexanone peroxide
LUMO lowest unoccupied molecular orbital
MEKP methy ethyl kentone peroxide
MRO maintenace, repairing and overhall
OLEDs organic light emitting diodes
QELS quasy elastic light scattering
SAPF solid amorphous polymer fraction
TBO-Pc-Zn tetrabenzoxyphthalocyanine zinc
Full Professor, Iv Javakhishvili Tbilisi State University,
Faculty of Exact and Natural Sciences, Department of Chemistry;
Chair of Macromolecular Chemistry; Director, Institute of
Macromolecular Chemistry and Polymeric Materials, Tbilisi, Georgia
Omari Vasilii Mukbaniani, DSc, is Professor and Head of the Macromolecular Chemistry Department of Iv Javakhishvili Tbilisi State University, Tbilisi, Georgia He is also the Director of the Institute of Macromolecular Chemistry and Polymeric Materials He is a member of the Academy of Natural Sciences of the Georgian Republic For several years he was a member of the advisory board of the Journal Proceedings of Iv Javakhishvili Tbilisi State University (Chemical Series) and contributing editor of the journals Polymer News and the Polymers Research Journal He is member of editorial board of the Journal of Chemistry and Chemical Technology His research interests include polymer chemistry, polymeric materials, and chemistry of organo- silicon compounds He is an author more than 420 publication, 13 books, four monographs, and 10 inventions He created in 2007 the “International Caucasian Symposium on Polymers and Advanced Materials,” ICSP, which takes place every other two years in Georgia The last symposium, ICSP 5, was held in July 2017 in Tbilisi, Georgia.
Emeritus Professor, Institute Charles Gerhardt of Montpelier—Aggregates, Interfaces & Materials for Energy (ICGM-AIME, UMR CNRS 5253), University Montpelier, France
Professor Marc J M Abadie is Emeritus Professor at the University Montpellier, Institute Charles Gerhardt of Montpelier, Aggregates, Interfaces and Materials Energy (ICGM-AIME, UMR CNRS 5253), France He was head of the Laboratory of Polymer Science and Advanced Organic Materials
– LEMP/MAO He is currently “Michael Fam” Visiting Professor at the School of Materials Sciences and Engineering, Nanyang Technological University NTU, Singapore His present activity concerns high performance polymers for PEMFCs, composites and nanocomposites, UV/EB coatings, and biomaterials He has published 11 books and 11 patents He has advised nearly 95 MS and 52 PhD students with whom he has published over 402 papers He has more than 40 years of experience in polymer science with 10 years in the industry (IBM, USA – MOD, UK & SNPA/Total, France) He created in the 1980s the “International Symposium on Polyimides and High Temperature Polymers,” a.k.a STEPI, which takes place every other three years in Montpellier, France A recent symposium, STEPI 10, look place in June 5–8, 2016.
Senior Specialist, Unite of Academic Process Management
(Faculty of Exact and Natural Sciences), Ivane Javakhishvili Tbilisi State University; Senior Researcher, Institute of Macromolecular Chemistry and Polymeric Materials, Georgia
Tamara Tatrishvili, PhD, is Senior Specialist at the Unite of Academic Process Management (Faculty of Exact and Natural Sciences) at Ivane Javakhishvili Tbilisi State University as well as Senior Researcher of the Institute of Macromolecular Chemistry and Polymeric Materials in Tbilisi, Georgia.
Increasing interest in lightweight and high performance materials is leading to significant research activity in the area of polymers and composites One recent focus is to develop multifunctional materials that have more than one property tailored as per the design requirements in addition to achieving low density.
The possibility of simultaneously tailoring several desired properties is attractive but very challenging, and it requires significant advancements in the science and technology of high performance functional polymers and composites.
The structures and functions of these advanced polymer and composite systems are evaluated with respect to improved or novel performance, and the potential implications of those developments for the future of polymer- based composites and multifunctional materials are discussed
The ensemble selected papers presented at the 4th International Caucasian Symposium on Polymers and Advanced Materials are collected, as original unpublished research, in this book ICSP1AM-4 took place in Batumi Black sea beach, Georgia July 1–4, 2015 This book focuses exclusively on the latest research related to polymer and composite materials, especially new trends in frontal polymerization and copolymerization synthesis, function- alization of polymers, physical properties and hybrid systems A large part is devoted to composites and nanocomposites; their mechanical impact on their properties are evaluated and discussed Applications in medicine as drug-release for cancer treatment or as development of green materials and as renewable resources with a particular emphasis on the research of the authors’ group(s) are presented Coating and curing processes are also cov- ered in this book in order to have a better control and understanding of the crosslinking reactions
The progress captured in the current set of articles shows promise for developing materials that seem capable of moving this field from laboratory- scale prototypes to actual industrial applications.
This book serves as a valuable and informative reference for scientists, engineers, medical technologists and practioners engaged in the teaching, research, development and use of functional polymers and composites.
Professor, Dr of Science, Omari Mukbaniani
Iv Javakhishvili Tbilisi State University, Faculty of Exact and Natural Sciences, Department of Chemistry, Chair of Macromolecular Chemistry,
Director of the Institute of Macromolecular Chemistry and Polymeric Materials
Professor Emeritus, Doctor Honoris Causa Institut Charles Gerhardt de Montpellier – Agrégats, Interfaces et Matériaux pour l’Energie (IGCM AIME UMR CNRS 5253) STEPI General Chairman, Expert près la Cour d’Appel
“Michael Fam” Visiting Professor @ NTU/MSE, Singapore
Ivane Javakhishvili Tbilisi State University, Senior Specialist of the Unite of Academic Process Management
(Faculty of Exact and Natural Sciences), Senior Researcher of the Institute of Macromolecular Chemistry and
A H DURGARYAN, N A DURGARYAN, R H ARAKELYAN, and N A MIRAQYAN
Yerevan State University, Alek Manoogian 1, Yerevan, 375025,
Republic of Armenia, E-mail: durnar63@yahoo.com
Abstract 3 1.1 Introduction 4 1.2 Experimental Part 5 1.3 Results and Discussion 8 Acknowledgments 12 Keywords 12 References 12
The oxidative copolymerization of aniline with p-phenylenediamine in an acetic acid medium has been investigated for the first time It has been deter- mined that as a result of copolymerization; a polymer having a structure analogous to the polyaniline called emeraldine is formed The obtained copo- lymer doped with 3N hydrochloric acid has an electrical conductivity five times higher than that of polyaniline prepared by the usual method Aniline polymerization proceeds more slowly at 273K under the same copolymer- ization conditions and the obtained polymer has low conductivity However, in a mixture of acetic acid-methanol, the reaction proceeds faster and the obtained polymer has conductivity almost equal to that of emeraldine It has been observed that the conductivity of polymers doped with formic acid is lower than that of polymers obtained by doping with hydrochloric acid by 2 orders of magnitude.
Among the electro active polymers, the emeraldine form of polyaniline (PANI) attracts intense interest [1, 2] PANI occupies a particular place among the electro active conjugated polymers owing to its environmental stability, easy and cheap method of preparation and its unique properties
It is extensively used in various fields of technology [3–14] To improve the properties of PANI, studies of aniline copolymerization with different monomers have been conducted [12–19]; however, the conductivity of the obtained copolymers is inferior to that of PANI in spite of high solubility. According to the literature data, copolymer Ι[20] is formed during the copolymerization of p-phenylenediamine (PPDA) with aniline.
In the formation of copolymer Ι, for 1 mole each of aniline and PPDA,
3 moles of peroxydisulfate (PDS) are required [20] because when using 1 mole of PDS for 1 mole of aniline, the calculated yield for aniline cannot be higher than 33%, while a yield of 62% to 75% was actually obtained [20] It may be concluded from these data that the reaction does not proceed accord- ing to Figure 4 given in the Ref [20].
According to other literature data, in the case of a molar ratio of aniline/ PPDA of 50:1, the presence of PPDA greatly increases the rate of polymer- ization and does not affect the structure and crystalline of PANI [21].
These data strengthen our opinion that the reaction mechanism differs from that described in the literature [20], and considering the scheme for the oxidative polymerization of PPDA [22]; we have proposed that it proceeds with a mechanism similar to that depicted in Scheme 1[23].
If the reaction occurs according to Scheme 1, the maximum yield calcu- lated for aniline will be 67%, while in the case of a ratio of PPDA-aniline in the copolymer of more than 1; the yield will be above 67%.
The purpose of the present work is to verify the possibility that the reac- tion proceeds according to Scheme 1.
The inherent viscosity of DMSO solution was determined at 25°C, using Ubbelohde viscometer.
MATERIALS AND PROPERTIES
K Jumadilov, Zh A Abilov, and R G Kondaurov 21 Investigation of a Complex Formation Process of Copper
JSC, “Institue of Chemical Sciences after A.B Bekturov”, Sh Valikhanov st 106, Almaty, Republic of Kazakhstan, E-mail: jumadilov@mail.ru
Peoples’ Friendship University of Russia, Scientific-Educational Centre of Nanotechnology, Miklukho- Maklaya 10/2, 117198, Moscow, Russia
Kyiv Taras Shevchenko National University, Volodymyrska Str 60, 01033, Kyiv, Ukraine
Department of Macromolecular Chemistry, Taras Shevchenko National University of Kyiv, 60 Volodymyrska Street, 01033, Kyiv, Ukraine
Al-Farabi Kazakh National University, Faculty of Chemistry and Chemical Technology, Al-Farabi ave
Kyiv Taras Shevchenko National University, Volodymyrska Str 60, 01033, Kyiv, Ukraine
Center of Physical and Chemical Methods of Research and Analysis, Tole bi Str 96a, 050012, Almaty, Kazakhstan
Taras Shevchenko National University, Faculty of Chemistry, 60 Volodymyrska Str., Kyiv 0160, Ukraine
Taras Shevchenko National University, Faculty of Chemistry, 60 Volodymyrska Str., Kyiv 0160, Ukraine, Email: kutsevol@ukr.net
Department of Sciences, Ivan Franko Zhytomyr State University, 40 Velyka Berdychivska Str., 10008 Zhytomyr, Ukraine
Chuiko Institute of Surface Chemistry, National Academy of Science of Ukraine, General Naumov Str
17, 03164 Kyiv, Ukraine, E-mail: okslinnik@yahoo.co.uk
Iv Javakhishvili Tbilisi State University, Department of Chemistry, I Chavchavadze Ave, 1, 0179 Tbilisi, Georgia
Nagiyev Institute of Catalysis & Inorganic Chemistry, Azerbaijan National Academy of Sciences,
H Javid Ave., 113, AZ1143 Baku, Azerbaijan
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane, Javakhishvili Tbilisi , State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia
Ivane Javakhishvili Tbilisi State University Chavchavadze Avenue 1, Tbilisi 0128, Georgia
Lobzhanidze, I Metskhvarishvili, G Dgebuadze, B Bendeliani, M Metskhvarishvili, and V Gabunia 23 Study of Temperature Dependence of Specific Resistance of Nickel-
Iv Javakhishvili Tbilisi State University, Department of Chemistry, I Chavchavadze Ave, 1, 0179 Tbilisi, Georgia
Nagiyev Institute of Catalysis & Inorganic Chemistry, Azerbaijan National Academy of Sciences,
H Javid Ave., 113, AZ1143 Baku, Azerbaijan
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane, Javakhishvili Tbilisi , State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia
Ivane Javakhishvili Tbilisi State University Chavchavadze Avenue 1, Tbilisi 0128, Georgia
Ivane Javakhishvili Tbilisi State University Chavchavadze Avenue 1, Tbilisi, 0128, Georgia
Ivane Javakhishvili Tbilisi State University, E Andronikashvili Institute of Physics, Tamarashvili str, 6,
Problem Research Laboratory, National University of Food Technology, 68, Volodymyrska Street
Hovhannisyan, M Khaddazh, N G Grigoryan, G K Grigoryan,
Ivane Javakhishvili Tbilisi State University Chavchavadze Avenue 1, Tbilisi, 0128, Georgia
Ivane Javakhishvili Tbilisi State University, E Andronikashvili Institute of Physics, Tamarashvili str, 6,
Problem Research Laboratory, National University of Food Technology, 68, Volodymyrska Street
Ivane Javakhishvili Tbilisi State University, Rafiel Agladze Institute of Inorganic Chemistry and Electrochemistry Mindeli str, 11, 0186, Tbilisi, Georgia, E-mail: tamazmarsagishvili@gmail.com
Chemistry Faculty, Kyiv National Taras Shevchenko University, 12 L Tolstogo Str., 01033 Kyiv, Ukraine
Ivane Javakhishvili Tbilisi State University, Rafiel Agladze Institute of Inorganic Chemistry and Electrochemistry Mindeli str., 11, 0186, Tbilisi, Georgia
Ilia Vekua Sukhumi Institute of Physics and Technology, Laboratory of Cryogenic Technique and Technologies, Mindeli Str 7, 0186 Tbilisi, Georgia
Georgian Technical University, Department of Engineering Physics, Kostava Str 77, 0175 Tbilisi, Georgia
Yerevan State University, Alek Manoogian 1, Yerevan, 375025, Republic of Armenia
Georgian Technical University, V Chavchanidze Institute of Cybernetics, 5 S Euli , St, 0186 Tbilisi, Georgia
Taras Shevchenko National University of Kyiv, Department of Chemistry, Volodymyrska Str., 60,
Faculty of Physics and Engineering, Moldova State University, 60 A Mateevici str., MD 2009, Chisinau, Moldova
Chemistry Faculty, Kyiv National Taras Shevchenko University, 12 L Tolstogo Str., 01033 Kyiv, Ukraine
G.A Krestov Institute of Solution Chemistry, Russian Academy of Sciences, Akademicheskaya Str., 1, Ivanovo, 153045, Russia
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane, Javakhishvili Tbilisi , State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane Javakhishvili Tbilisi , State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane, Javakhishvili Tbilisi , State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia
Georgian Technical University, V Chavchanidze Institute of Cybernetics, 5 S Euli , St, 0186 Tbilisi, Georgia
Georgian Technical University, 68 Merab Kostava Street, Tbilisi, Georgia Tbilisi, 0175, Georgia
Yerevan State University, A Manookyan St 1, 0025, Armenia , E-mail: Scirec@mail.ru Ł Piszczyk
Polymer Technology Department, Chemical Faculty, Gdansk University of Technology, Gabriela Narutowicza Street 11/12, 80-233 Gdansk, Poland
Tbilisi State University, 1 Ilia Chavchavadze Ave, Tbilisi 0179, Georgia
Faculty of Physics and Engineering, Moldova State University, 60 A Mateevici str., MD 2009, Chisinau, Moldova
Linnik, Nadtoka, N Chorna, N Smirnova,
Chuiko Institute of Surface Chemistry, National Academy of Science of Ukraine, General Naumov Str
17, 03164 Kyiv, Ukraine, E-mail: okslinnik@yahoo.co.uk
Iv Javakhishvili Tbilisi State University, Department of Chemistry, I Chavchavadze Ave, 1, 0179 Tbilisi, Georgia
Nagiyev Institute of Catalysis & Inorganic Chemistry, Azerbaijan National Academy of Sciences,
H Javid Ave., 113, AZ1143 Baku, Azerbaijan
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane, Javakhishvili Tbilisi , State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia
Ivane Javakhishvili Tbilisi State University Chavchavadze Avenue 1, Tbilisi 0128, Georgia
Syromyatnikov 29 Graded Zone Stretching of the Linear Polymers
P Davtyan and A O Tonoyan
Armenian National Polytechnic University 105, Teryana Str., 105 375009 Yerevan, Armenia
Ilia Vekua Sukhumi Institute of Physics and Technology, Laboratory of Cryogenic Technique and Technologies, Mindeli Str 7, 0186 Tbilisi, Georgia
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane Javakhishvili Tbilisi , State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia
Georgian Technical University, Kostava Str., 77, 0175, Tbilisi, Georgia
Faculty of Chemistry and Chemical Technology
Yerevan State University, Alek Manoogian 1, Yerevan, 375025, Republic of Armenia , E-mail: durnar63@yahoo.com
Yerevan State University, Alek Manoogian 1, Yerevan, 375025, Republic of Armenia
V I Vernadsky Institute of General and Inorganic Chemistry NASU, Kyiv, Ukraine
Taras Shevchenko National University, Faculty of Chemistry, 60 Volodymyrska Str., Kyiv 0160, Ukraine
Polymer Technology Department, Chemical Faculty, Gdansk University of Technology, Gabriela Narutowicza Street 11/12, 80-233 Gdansk, Poland
Ilia Vekua Sukhumi Institute of Physics and Technology, Laboratory of Cryogenic Technique and Technologies, Mindeli str, 7, 0186 Tbilisi, Georgia
Ivane Javakhishvili Tbilisi State University, Rafiel Agladze Institute of Inorganic Chemistry and Electrochemistry Mindeli str, 11, 0186, Tbilisi, Georgia
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane, Javakhishvili Tbilisi , State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane Javakhishvili Tbilisi , State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia
Energy Recovery Agency of Oslo County, PO-BOX 54 Mortensrud, NO-1215, Oslo, Norway, E-mail: Espen.Govasmark@ege.oslo.kommune.no
The Scientific Technological Centre of Organic and Pharmaceutical Chemistry NAS RA, Institute of Organic Chemistry, 26, Azatutyan STR, 0014, Yerevan, Armenia
The Scientific Technological Centre of Organic and Pharmaceutical Chemistry NAS RA, Institute of Organic Chemistry 26, Azatutyan STR, 0014, Yerevan, Armenia
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane, Javakhishvili Tbilisi , State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia, E-mail: marina.gurgenishvili@yahoo.com
Department of Resin and Additives, Institute for Color Science and Technology, Tehran, Iran, E-mail: zeinab.hesari@yahoo.com
Polymer Technology Department, Chemical Faculty, Gdansk University of Technology, Gabriela Narutowicza Street 11/12, 80-233 Gdansk, Poland, E-mail: jozef.haponiuk@pg.gda.pl
Taras Shevchenko National University, Faculty of Chemistry, 60 Volodymyrska Str., Kyiv 0160, Ukraine
Yerevan State University, A Manookyan St 1, 0025, Armenia , E-mail: Scirec@mail.ru
Yerevan State University, A Manookyan St 1, 0025, Armenia, E-mail: Scirec@mail.ru
Polymer Technology Department, Chemical Faculty, Gdansk University of Technology, Gabriela Narutowicza Street 11/12, 80-233 Gdansk, Poland
Department of Chemistry, Faculty of Science, Science and Research of Tehran Branch Islamic Azad University, Tehran, Iran, E-mail: zeinab.hesari@yahoo.com
The Scientific Technological Centre of Organic and Pharmaceutical Chemistry NAS RA, Institute of Organic Chemistry 26, Azatutyan STR, 0014, Yerevan, Armenia, E-mail: hovarnos@gmail.com
Moldova State University, 60 A Mateevici str., MD-2009, Chisinau, Moldova
JSC, “Institue of Chemical Sciences after A.B Bekturov”, Sh Valikhanov st 106, Almaty, Republic of Kazakhstan, E-mail: jumadilov@mail.ru
Peoples’ Friendship University of Russia, Scientific-Educational Centre of Nanotechnology, Miklukho- Maklaya 10/2, 117198, Moscow, Russia
Kyiv Taras Shevchenko National University, Volodymyrska Str 60, 01033, Kyiv, Ukraine
Department of Macromolecular Chemistry, Taras Shevchenko National University of Kyiv, 60 Volodymyrska Street, 01033, Kyiv, Ukraine
Al-Farabi Kazakh National University, Faculty of Chemistry and Chemical Technology, Al-Farabi ave
Kyiv Taras Shevchenko National University, Volodymyrska Str 60, 01033, Kyiv, Ukraine
Center of Physical and Chemical Methods of Research and Analysis, Tole bi Str 96a, 050012, Almaty, Kazakhstan
Taras Shevchenko National University, Faculty of Chemistry, 60 Volodymyrska Str., Kyiv 0160, Ukraine
Taras Shevchenko National University, Faculty of Chemistry, 60 Volodymyrska Str., Kyiv 0160, Ukraine, Email: kutsevol@ukr.net
Department of Sciences, Ivan Franko Zhytomyr State University, 40 Velyka Berdychivska Str., 10008 Zhytomyr, Ukraine
Chuiko Institute of Surface Chemistry, National Academy of Science of Ukraine, General Naumov Str
17, 03164 Kyiv, Ukraine, E-mail: okslinnik@yahoo.co.uk
Iv Javakhishvili Tbilisi State University, Department of Chemistry, I Chavchavadze Ave, 1, 0179 Tbilisi, Georgia
Nagiyev Institute of Catalysis & Inorganic Chemistry, Azerbaijan National Academy of Sciences,
H Javid Ave., 113, AZ1143 Baku, Azerbaijan
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane, Javakhishvili Tbilisi , State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia
Ivane Javakhishvili Tbilisi State University Chavchavadze Avenue 1, Tbilisi 0128, Georgia
Ivane Javakhishvili Tbilisi State University Chavchavadze Avenue 1, Tbilisi, 0128, Georgia
Ivane Javakhishvili Tbilisi State University, E Andronikashvili Institute of Physics, Tamarashvili str, 6,
Problem Research Laboratory, National University of Food Technology, 68, Volodymyrska Street
Ivane Javakhishvili Tbilisi State University, Rafiel Agladze Institute of Inorganic Chemistry and Electrochemistry Mindeli str, 11, 0186, Tbilisi, Georgia, E-mail: tamazmarsagishvili@gmail.com
Chemistry Faculty, Kyiv National Taras Shevchenko University, 12 L Tolstogo Str., 01033 Kyiv, Ukraine
Ivane Javakhishvili Tbilisi State University, Rafiel Agladze Institute of Inorganic Chemistry and Electrochemistry Mindeli str., 11, 0186, Tbilisi, Georgia
Ilia Vekua Sukhumi Institute of Physics and Technology, Laboratory of Cryogenic Technique and Technologies, Mindeli Str 7, 0186 Tbilisi, Georgia
Georgian Technical University, Department of Engineering Physics, Kostava Str 77, 0175 Tbilisi, Georgia
Yerevan State University, Alek Manoogian 1, Yerevan, 375025, Republic of Armenia
Georgian Technical University, V Chavchanidze Institute of Cybernetics, 5 S Euli , St, 0186 Tbilisi, Georgia
Taras Shevchenko National University of Kyiv, Department of Chemistry, Volodymyrska Str., 60,
Faculty of Physics and Engineering, Moldova State University, 60 A Mateevici str., MD 2009, Chisinau, Moldova
Chemistry Faculty, Kyiv National Taras Shevchenko University, 12 L Tolstogo Str., 01033 Kyiv, Ukraine
G.A Krestov Institute of Solution Chemistry, Russian Academy of Sciences, Akademicheskaya Str., 1, Ivanovo, 153045, Russia
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane, Javakhishvili Tbilisi , State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane Javakhishvili Tbilisi , State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane, Javakhishvili Tbilisi , State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia
Georgian Technical University, V Chavchanidze Institute of Cybernetics, 5 S Euli , St, 0186 Tbilisi, Georgia
Georgian Technical University, 68 Merab Kostava Street, Tbilisi, Georgia Tbilisi, 0175, Georgia
Yerevan State University, A Manookyan St 1, 0025, Armenia , E-mail: Scirec@mail.ru Ł Piszczyk
Polymer Technology Department, Chemical Faculty, Gdansk University of Technology, Gabriela Narutowicza Street 11/12, 80-233 Gdansk, Poland
Tbilisi State University, 1 Ilia Chavchavadze Ave, Tbilisi 0179, Georgia
Faculty of Physics and Engineering, Moldova State University, 60 A Mateevici str., MD 2009, Chisinau, Moldova
Moldova State University, 60 A Mateevici str, MD-2009, Chisinau, Moldova, E-mail: s.v.robu@mail.ru
Norwegian University of Life Sciences (NMBU), Department of Env Sci., PO-Box 5003, No 1432, Ås, Norway , E-mail: Brit.Salbu@nmbu.no
Kyiv National Taras Shevchenko University, Department of Chemistry, Kyiv, Ukraine , E-mail: iras@univ.kiev.ua
Georgian Technical University, V Chavchanidze Institute of Cybernetics, 5 S Euli St, 0186 Tbilisi, Georgia
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane, Javakhishvili Tbilisi , State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia
Center of Physical and Chemical Methods of Research and Analysis, Tole bi Str 96a, 050012, Almaty, Kazakhstan
Chuiko Institute of Surface Chemistry, National Academy of Science of Ukraine, General Naumov str,
Kyiv Taras Shevchenko National University, Volodymyrska Str., 60, 01033, Kyiv, Ukraine, E-mail: vitaliismokal@gmail.com
Maria Curie-Skłodowska University, pl Maria Curie-Skłodowskiej 3, 20-031 Lublin, Poland
Ivane Javakhishvili Tbilisi State University Chavchavadze Avenue 1, Tbilisi, 0128, Georgia
Department of Macromolecular Chemistry, Taras Shevchenko National University of Kyiv, 60 Volodymyrska Street, 01033, Kyiv, Ukraine , E-mail: svg@univ.kiev.ua
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane Javakhishvili Tbilisi, State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia
Ivane Javakhishvili Tbilisi State University, Rafiel Agladze Institute of Inorganic Chemistry and Electrochemistry Mindeli str, 11, 0186, Tbilisi, Georgia
Institute of Molecular Biology and Genetics of Natl Acad of Sci of Ukraine, 150 Zabolotnogo str.150, Kyiv 03680, Ukraine, E-mail: gtelegeev@ukr.net
Taras Shevchenko National University, Faculty of Chemistry, 60 Volodymyrska Str., Kyiv 0160, Ukraine
Polymer Technology Department, Chemical Faculty, Gdansk University of Technology, Gabriela Narutowicza Street 11/12, 80–233 Gdansk, Poland
Armenian National Polytechnic University, 105 Teryana Str., 375009 Yerevan, Armenia , E-mail: atonoyan@mail.ru
Georgian Technical University, V Chavchanidze Institute of Cybernetics, 5 S Euli , St, 0186 Tbilisi, Georgia
Chemistry Faculty, Kyiv National Taras Shevchenko University, 12 L Tolstogo Str., 01033 Kyiv, Ukraine , E-mail: lvretik@gmail.com
Department of Macromolecular Chemistry, Taras Shevchenko National University of Kyiv, 60 Volodymyrska Street, 01033, Kyiv, Ukraine
Chemistry Faculty, Kyiv National Taras Shevchenko University, 12 L Tolstogo Str., 01033 Kyiv, Ukraine
Nagiyev Institute of Catalysis & Inorganic Chemistry, Azerbaijan National Academy of Sciences, H Javid Ave., 113, AZ1143 Baku, Azerbaijan, E-mail: zeynalov 2000@yahoo.com
Peoples’ Friendship University of Russia, Scientific-Educational Centre of Nanotechnology, Miklukho-Maklaya 10/2, 117198, Moscow, Russia
BHT 3,5-di-tert-butyl-4-hydroxyphenyl BPO benzoyl peroxide
DCPC dicyclohexylperoxide carbonate DLS dynamic light scattering
DSA differential scanning analyzer DSC differential scanning calorimetry DSC dye-sensitised solar cells
DTA differential thermal analysis EAS electronic absorption spectra EOS epoxidized soybean oil
FAME fatty acids methyl esters
GZSD graded zone stretching device HAuCl 4 thetrachloroauric acid
HOMO highest occupied molecular orbital
LCHP liquid cyclo hexanone peroxide
LUMO lowest unoccupied molecular orbital
MEKP methy ethyl kentone peroxide
MRO maintenace, repairing and overhall
OLEDs organic light emitting diodes
QELS quasy elastic light scattering
SAPF solid amorphous polymer fraction
TBO-Pc-Zn tetrabenzoxyphthalocyanine zinc
Full Professor, Iv Javakhishvili Tbilisi State University,
Faculty of Exact and Natural Sciences, Department of Chemistry;
Chair of Macromolecular Chemistry; Director, Institute of
Macromolecular Chemistry and Polymeric Materials, Tbilisi, Georgia
Omari Vasilii Mukbaniani, DSc, is Professor and Head of the Macromolecular Chemistry Department of Iv Javakhishvili Tbilisi State University, Tbilisi, Georgia He is also the Director of the Institute of Macromolecular Chemistry and Polymeric Materials He is a member of the Academy of Natural Sciences of the Georgian Republic For several years he was a member of the advisory board of the Journal Proceedings of Iv Javakhishvili Tbilisi State University (Chemical Series) and contributing editor of the journals Polymer News and the Polymers Research Journal He is member of editorial board of the Journal of Chemistry and Chemical Technology His research interests include polymer chemistry, polymeric materials, and chemistry of organo- silicon compounds He is an author more than 420 publication, 13 books, four monographs, and 10 inventions He created in 2007 the “International Caucasian Symposium on Polymers and Advanced Materials,” ICSP, which takes place every other two years in Georgia The last symposium, ICSP 5, was held in July 2017 in Tbilisi, Georgia.
Emeritus Professor, Institute Charles Gerhardt of Montpelier—Aggregates, Interfaces & Materials for Energy (ICGM-AIME, UMR CNRS 5253), University Montpelier, France
Professor Marc J M Abadie is Emeritus Professor at the University Montpellier, Institute Charles Gerhardt of Montpelier, Aggregates, Interfaces and Materials Energy (ICGM-AIME, UMR CNRS 5253), France He was head of the Laboratory of Polymer Science and Advanced Organic Materials
– LEMP/MAO He is currently “Michael Fam” Visiting Professor at the School of Materials Sciences and Engineering, Nanyang Technological University NTU, Singapore His present activity concerns high performance polymers for PEMFCs, composites and nanocomposites, UV/EB coatings, and biomaterials He has published 11 books and 11 patents He has advised nearly 95 MS and 52 PhD students with whom he has published over 402 papers He has more than 40 years of experience in polymer science with 10 years in the industry (IBM, USA – MOD, UK & SNPA/Total, France) He created in the 1980s the “International Symposium on Polyimides and High Temperature Polymers,” a.k.a STEPI, which takes place every other three years in Montpellier, France A recent symposium, STEPI 10, look place in June 5–8, 2016.
Senior Specialist, Unite of Academic Process Management
(Faculty of Exact and Natural Sciences), Ivane Javakhishvili Tbilisi State University; Senior Researcher, Institute of Macromolecular Chemistry and Polymeric Materials, Georgia
Tamara Tatrishvili, PhD, is Senior Specialist at the Unite of Academic Process Management (Faculty of Exact and Natural Sciences) at Ivane Javakhishvili Tbilisi State University as well as Senior Researcher of the Institute of Macromolecular Chemistry and Polymeric Materials in Tbilisi, Georgia.
Increasing interest in lightweight and high performance materials is leading to significant research activity in the area of polymers and composites One recent focus is to develop multifunctional materials that have more than one property tailored as per the design requirements in addition to achieving low density.
The possibility of simultaneously tailoring several desired properties is attractive but very challenging, and it requires significant advancements in the science and technology of high performance functional polymers and composites.
The structures and functions of these advanced polymer and composite systems are evaluated with respect to improved or novel performance, and the potential implications of those developments for the future of polymer- based composites and multifunctional materials are discussed
The ensemble selected papers presented at the 4th International Caucasian Symposium on Polymers and Advanced Materials are collected, as original unpublished research, in this book ICSP1AM-4 took place in Batumi Black sea beach, Georgia July 1–4, 2015 This book focuses exclusively on the latest research related to polymer and composite materials, especially new trends in frontal polymerization and copolymerization synthesis, function- alization of polymers, physical properties and hybrid systems A large part is devoted to composites and nanocomposites; their mechanical impact on their properties are evaluated and discussed Applications in medicine as drug-release for cancer treatment or as development of green materials and as renewable resources with a particular emphasis on the research of the authors’ group(s) are presented Coating and curing processes are also cov- ered in this book in order to have a better control and understanding of the crosslinking reactions
The progress captured in the current set of articles shows promise for developing materials that seem capable of moving this field from laboratory- scale prototypes to actual industrial applications.
This book serves as a valuable and informative reference for scientists, engineers, medical technologists and practioners engaged in the teaching, research, development and use of functional polymers and composites.
Professor, Dr of Science, Omari Mukbaniani
Iv Javakhishvili Tbilisi State University, Faculty of Exact and Natural Sciences, Department of Chemistry, Chair of Macromolecular Chemistry,
Director of the Institute of Macromolecular Chemistry and Polymeric Materials
Professor Emeritus, Doctor Honoris Causa Institut Charles Gerhardt de Montpellier – Agrégats, Interfaces et Matériaux pour l’Energie (IGCM AIME UMR CNRS 5253) STEPI General Chairman, Expert près la Cour d’Appel
“Michael Fam” Visiting Professor @ NTU/MSE, Singapore
Ivane Javakhishvili Tbilisi State University, Senior Specialist of the Unite of Academic Process Management
(Faculty of Exact and Natural Sciences), Senior Researcher of the Institute of Macromolecular Chemistry and
A H DURGARYAN, N A DURGARYAN, R H ARAKELYAN, and N A MIRAQYAN
Yerevan State University, Alek Manoogian 1, Yerevan, 375025,
Republic of Armenia, E-mail: durnar63@yahoo.com
Abstract 3 1.1 Introduction 4 1.2 Experimental Part 5 1.3 Results and Discussion 8 Acknowledgments 12 Keywords 12 References 12
The oxidative copolymerization of aniline with p-phenylenediamine in an acetic acid medium has been investigated for the first time It has been deter- mined that as a result of copolymerization; a polymer having a structure analogous to the polyaniline called emeraldine is formed The obtained copo- lymer doped with 3N hydrochloric acid has an electrical conductivity five times higher than that of polyaniline prepared by the usual method Aniline polymerization proceeds more slowly at 273K under the same copolymer- ization conditions and the obtained polymer has low conductivity However, in a mixture of acetic acid-methanol, the reaction proceeds faster and the obtained polymer has conductivity almost equal to that of emeraldine It has been observed that the conductivity of polymers doped with formic acid is lower than that of polymers obtained by doping with hydrochloric acid by 2 orders of magnitude.
Among the electro active polymers, the emeraldine form of polyaniline (PANI) attracts intense interest [1, 2] PANI occupies a particular place among the electro active conjugated polymers owing to its environmental stability, easy and cheap method of preparation and its unique properties
It is extensively used in various fields of technology [3–14] To improve the properties of PANI, studies of aniline copolymerization with different monomers have been conducted [12–19]; however, the conductivity of the obtained copolymers is inferior to that of PANI in spite of high solubility. According to the literature data, copolymer Ι[20] is formed during the copolymerization of p-phenylenediamine (PPDA) with aniline.
In the formation of copolymer Ι, for 1 mole each of aniline and PPDA,
3 moles of peroxydisulfate (PDS) are required [20] because when using 1 mole of PDS for 1 mole of aniline, the calculated yield for aniline cannot be higher than 33%, while a yield of 62% to 75% was actually obtained [20] It may be concluded from these data that the reaction does not proceed accord- ing to Figure 4 given in the Ref [20].
According to other literature data, in the case of a molar ratio of aniline/ PPDA of 50:1, the presence of PPDA greatly increases the rate of polymer- ization and does not affect the structure and crystalline of PANI [21].
These data strengthen our opinion that the reaction mechanism differs from that described in the literature [20], and considering the scheme for the oxidative polymerization of PPDA [22]; we have proposed that it proceeds with a mechanism similar to that depicted in Scheme 1[23].
If the reaction occurs according to Scheme 1, the maximum yield calcu- lated for aniline will be 67%, while in the case of a ratio of PPDA-aniline in the copolymer of more than 1; the yield will be above 67%.
The purpose of the present work is to verify the possibility that the reac- tion proceeds according to Scheme 1.
The inherent viscosity of DMSO solution was determined at 25°C, using Ubbelohde viscometer.
GREEN CHEMISTRY AND RECYCLING
T Haponiuk, A Hejna, Ł Piszczyk, Datta, and K Formela 34 Modification of Polyethylene Films via Photochemical Reaction
Polymer Technology Department, Chemical Faculty, Gdansk University of Technology, Gabriela Narutowicza Street 11/12, 80-233 Gdansk, Poland, E-mail: jozef.haponiuk@pg.gda.pl
Taras Shevchenko National University, Faculty of Chemistry, 60 Volodymyrska Str., Kyiv 0160, Ukraine
Yerevan State University, A Manookyan St 1, 0025, Armenia , E-mail: Scirec@mail.ru
Yerevan State University, A Manookyan St 1, 0025, Armenia, E-mail: Scirec@mail.ru
Polymer Technology Department, Chemical Faculty, Gdansk University of Technology, Gabriela Narutowicza Street 11/12, 80-233 Gdansk, Poland
Department of Chemistry, Faculty of Science, Science and Research of Tehran Branch Islamic Azad University, Tehran, Iran, E-mail: zeinab.hesari@yahoo.com
The Scientific Technological Centre of Organic and Pharmaceutical Chemistry NAS RA, Institute of Organic Chemistry 26, Azatutyan STR, 0014, Yerevan, Armenia, E-mail: hovarnos@gmail.com
Moldova State University, 60 A Mateevici str., MD-2009, Chisinau, Moldova
JSC, “Institue of Chemical Sciences after A.B Bekturov”, Sh Valikhanov st 106, Almaty, Republic of Kazakhstan, E-mail: jumadilov@mail.ru
Peoples’ Friendship University of Russia, Scientific-Educational Centre of Nanotechnology, Miklukho- Maklaya 10/2, 117198, Moscow, Russia
Kyiv Taras Shevchenko National University, Volodymyrska Str 60, 01033, Kyiv, Ukraine
Department of Macromolecular Chemistry, Taras Shevchenko National University of Kyiv, 60 Volodymyrska Street, 01033, Kyiv, Ukraine
Al-Farabi Kazakh National University, Faculty of Chemistry and Chemical Technology, Al-Farabi ave
Kyiv Taras Shevchenko National University, Volodymyrska Str 60, 01033, Kyiv, Ukraine
Center of Physical and Chemical Methods of Research and Analysis, Tole bi Str 96a, 050012, Almaty, Kazakhstan
Taras Shevchenko National University, Faculty of Chemistry, 60 Volodymyrska Str., Kyiv 0160, Ukraine
Taras Shevchenko National University, Faculty of Chemistry, 60 Volodymyrska Str., Kyiv 0160, Ukraine, Email: kutsevol@ukr.net
Department of Sciences, Ivan Franko Zhytomyr State University, 40 Velyka Berdychivska Str., 10008 Zhytomyr, Ukraine
Chuiko Institute of Surface Chemistry, National Academy of Science of Ukraine, General Naumov Str
17, 03164 Kyiv, Ukraine, E-mail: okslinnik@yahoo.co.uk
Iv Javakhishvili Tbilisi State University, Department of Chemistry, I Chavchavadze Ave, 1, 0179 Tbilisi, Georgia
Nagiyev Institute of Catalysis & Inorganic Chemistry, Azerbaijan National Academy of Sciences,
H Javid Ave., 113, AZ1143 Baku, Azerbaijan
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane, Javakhishvili Tbilisi , State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia
Ivane Javakhishvili Tbilisi State University Chavchavadze Avenue 1, Tbilisi 0128, Georgia
Ivane Javakhishvili Tbilisi State University Chavchavadze Avenue 1, Tbilisi, 0128, Georgia
Ivane Javakhishvili Tbilisi State University, E Andronikashvili Institute of Physics, Tamarashvili str, 6,
Problem Research Laboratory, National University of Food Technology, 68, Volodymyrska Street
Ivane Javakhishvili Tbilisi State University, Rafiel Agladze Institute of Inorganic Chemistry and Electrochemistry Mindeli str, 11, 0186, Tbilisi, Georgia, E-mail: tamazmarsagishvili@gmail.com
Chemistry Faculty, Kyiv National Taras Shevchenko University, 12 L Tolstogo Str., 01033 Kyiv, Ukraine
Ivane Javakhishvili Tbilisi State University, Rafiel Agladze Institute of Inorganic Chemistry and Electrochemistry Mindeli str., 11, 0186, Tbilisi, Georgia
Ilia Vekua Sukhumi Institute of Physics and Technology, Laboratory of Cryogenic Technique and Technologies, Mindeli Str 7, 0186 Tbilisi, Georgia
Georgian Technical University, Department of Engineering Physics, Kostava Str 77, 0175 Tbilisi, Georgia
Yerevan State University, Alek Manoogian 1, Yerevan, 375025, Republic of Armenia
Georgian Technical University, V Chavchanidze Institute of Cybernetics, 5 S Euli , St, 0186 Tbilisi, Georgia
Taras Shevchenko National University of Kyiv, Department of Chemistry, Volodymyrska Str., 60,
Faculty of Physics and Engineering, Moldova State University, 60 A Mateevici str., MD 2009, Chisinau, Moldova
Chemistry Faculty, Kyiv National Taras Shevchenko University, 12 L Tolstogo Str., 01033 Kyiv, Ukraine
G.A Krestov Institute of Solution Chemistry, Russian Academy of Sciences, Akademicheskaya Str., 1, Ivanovo, 153045, Russia
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane, Javakhishvili Tbilisi , State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane Javakhishvili Tbilisi , State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane, Javakhishvili Tbilisi , State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia
Georgian Technical University, V Chavchanidze Institute of Cybernetics, 5 S Euli , St, 0186 Tbilisi, Georgia
Georgian Technical University, 68 Merab Kostava Street, Tbilisi, Georgia Tbilisi, 0175, Georgia
Yerevan State University, A Manookyan St 1, 0025, Armenia , E-mail: Scirec@mail.ru Ł Piszczyk
Polymer Technology Department, Chemical Faculty, Gdansk University of Technology, Gabriela Narutowicza Street 11/12, 80-233 Gdansk, Poland
Tbilisi State University, 1 Ilia Chavchavadze Ave, Tbilisi 0179, Georgia
Faculty of Physics and Engineering, Moldova State University, 60 A Mateevici str., MD 2009, Chisinau, Moldova
Moldova State University, 60 A Mateevici str, MD-2009, Chisinau, Moldova, E-mail: s.v.robu@mail.ru
Norwegian University of Life Sciences (NMBU), Department of Env Sci., PO-Box 5003, No 1432, Ås, Norway , E-mail: Brit.Salbu@nmbu.no
Kyiv National Taras Shevchenko University, Department of Chemistry, Kyiv, Ukraine , E-mail: iras@univ.kiev.ua
Georgian Technical University, V Chavchanidze Institute of Cybernetics, 5 S Euli St, 0186 Tbilisi, Georgia
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane, Javakhishvili Tbilisi , State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia
Center of Physical and Chemical Methods of Research and Analysis, Tole bi Str 96a, 050012, Almaty, Kazakhstan
Chuiko Institute of Surface Chemistry, National Academy of Science of Ukraine, General Naumov str,
Kyiv Taras Shevchenko National University, Volodymyrska Str., 60, 01033, Kyiv, Ukraine, E-mail: vitaliismokal@gmail.com
Maria Curie-Skłodowska University, pl Maria Curie-Skłodowskiej 3, 20-031 Lublin, Poland
Ivane Javakhishvili Tbilisi State University Chavchavadze Avenue 1, Tbilisi, 0128, Georgia
Department of Macromolecular Chemistry, Taras Shevchenko National University of Kyiv, 60 Volodymyrska Street, 01033, Kyiv, Ukraine , E-mail: svg@univ.kiev.ua
Petre Melikishvili Institute of Physical and Organic Chemistry of Ivane Javakhishvili Tbilisi, State University, I Chavchavadze Ave 1, 0179 Tbilisi, Georgia
Ivane Javakhishvili Tbilisi State University, Rafiel Agladze Institute of Inorganic Chemistry and Electrochemistry Mindeli str, 11, 0186, Tbilisi, Georgia
Institute of Molecular Biology and Genetics of Natl Acad of Sci of Ukraine, 150 Zabolotnogo str.150, Kyiv 03680, Ukraine, E-mail: gtelegeev@ukr.net
Taras Shevchenko National University, Faculty of Chemistry, 60 Volodymyrska Str., Kyiv 0160, Ukraine
Polymer Technology Department, Chemical Faculty, Gdansk University of Technology, Gabriela Narutowicza Street 11/12, 80–233 Gdansk, Poland
Armenian National Polytechnic University, 105 Teryana Str., 375009 Yerevan, Armenia , E-mail: atonoyan@mail.ru
Georgian Technical University, V Chavchanidze Institute of Cybernetics, 5 S Euli , St, 0186 Tbilisi, Georgia
Chemistry Faculty, Kyiv National Taras Shevchenko University, 12 L Tolstogo Str., 01033 Kyiv, Ukraine , E-mail: lvretik@gmail.com
Department of Macromolecular Chemistry, Taras Shevchenko National University of Kyiv, 60 Volodymyrska Street, 01033, Kyiv, Ukraine
Chemistry Faculty, Kyiv National Taras Shevchenko University, 12 L Tolstogo Str., 01033 Kyiv, Ukraine
Nagiyev Institute of Catalysis & Inorganic Chemistry, Azerbaijan National Academy of Sciences, H Javid Ave., 113, AZ1143 Baku, Azerbaijan, E-mail: zeynalov 2000@yahoo.com
Peoples’ Friendship University of Russia, Scientific-Educational Centre of Nanotechnology, Miklukho-Maklaya 10/2, 117198, Moscow, Russia
BHT 3,5-di-tert-butyl-4-hydroxyphenyl BPO benzoyl peroxide
DCPC dicyclohexylperoxide carbonate DLS dynamic light scattering
DSA differential scanning analyzer DSC differential scanning calorimetry DSC dye-sensitised solar cells
DTA differential thermal analysis EAS electronic absorption spectra EOS epoxidized soybean oil
FAME fatty acids methyl esters
GZSD graded zone stretching device HAuCl 4 thetrachloroauric acid
HOMO highest occupied molecular orbital
LCHP liquid cyclo hexanone peroxide
LUMO lowest unoccupied molecular orbital
MEKP methy ethyl kentone peroxide
MRO maintenace, repairing and overhall
OLEDs organic light emitting diodes
QELS quasy elastic light scattering
SAPF solid amorphous polymer fraction
TBO-Pc-Zn tetrabenzoxyphthalocyanine zinc
Full Professor, Iv Javakhishvili Tbilisi State University,
Faculty of Exact and Natural Sciences, Department of Chemistry;
Chair of Macromolecular Chemistry; Director, Institute of
Macromolecular Chemistry and Polymeric Materials, Tbilisi, Georgia
Omari Vasilii Mukbaniani, DSc, is Professor and Head of the Macromolecular Chemistry Department of Iv Javakhishvili Tbilisi State University, Tbilisi, Georgia He is also the Director of the Institute of Macromolecular Chemistry and Polymeric Materials He is a member of the Academy of Natural Sciences of the Georgian Republic For several years he was a member of the advisory board of the Journal Proceedings of Iv Javakhishvili Tbilisi State University (Chemical Series) and contributing editor of the journals Polymer News and the Polymers Research Journal He is member of editorial board of the Journal of Chemistry and Chemical Technology His research interests include polymer chemistry, polymeric materials, and chemistry of organo- silicon compounds He is an author more than 420 publication, 13 books, four monographs, and 10 inventions He created in 2007 the “International Caucasian Symposium on Polymers and Advanced Materials,” ICSP, which takes place every other two years in Georgia The last symposium, ICSP 5, was held in July 2017 in Tbilisi, Georgia.
Emeritus Professor, Institute Charles Gerhardt of Montpelier—Aggregates, Interfaces & Materials for Energy (ICGM-AIME, UMR CNRS 5253), University Montpelier, France
Professor Marc J M Abadie is Emeritus Professor at the University Montpellier, Institute Charles Gerhardt of Montpelier, Aggregates, Interfaces and Materials Energy (ICGM-AIME, UMR CNRS 5253), France He was head of the Laboratory of Polymer Science and Advanced Organic Materials
– LEMP/MAO He is currently “Michael Fam” Visiting Professor at the School of Materials Sciences and Engineering, Nanyang Technological University NTU, Singapore His present activity concerns high performance polymers for PEMFCs, composites and nanocomposites, UV/EB coatings, and biomaterials He has published 11 books and 11 patents He has advised nearly 95 MS and 52 PhD students with whom he has published over 402 papers He has more than 40 years of experience in polymer science with 10 years in the industry (IBM, USA – MOD, UK & SNPA/Total, France) He created in the 1980s the “International Symposium on Polyimides and High Temperature Polymers,” a.k.a STEPI, which takes place every other three years in Montpellier, France A recent symposium, STEPI 10, look place in June 5–8, 2016.
Senior Specialist, Unite of Academic Process Management
(Faculty of Exact and Natural Sciences), Ivane Javakhishvili Tbilisi State University; Senior Researcher, Institute of Macromolecular Chemistry and Polymeric Materials, Georgia
Tamara Tatrishvili, PhD, is Senior Specialist at the Unite of Academic Process Management (Faculty of Exact and Natural Sciences) at Ivane Javakhishvili Tbilisi State University as well as Senior Researcher of the Institute of Macromolecular Chemistry and Polymeric Materials in Tbilisi, Georgia.
Increasing interest in lightweight and high performance materials is leading to significant research activity in the area of polymers and composites One recent focus is to develop multifunctional materials that have more than one property tailored as per the design requirements in addition to achieving low density.
The possibility of simultaneously tailoring several desired properties is attractive but very challenging, and it requires significant advancements in the science and technology of high performance functional polymers and composites.
The structures and functions of these advanced polymer and composite systems are evaluated with respect to improved or novel performance, and the potential implications of those developments for the future of polymer- based composites and multifunctional materials are discussed
The ensemble selected papers presented at the 4th International Caucasian Symposium on Polymers and Advanced Materials are collected, as original unpublished research, in this book ICSP1AM-4 took place in Batumi Black sea beach, Georgia July 1–4, 2015 This book focuses exclusively on the latest research related to polymer and composite materials, especially new trends in frontal polymerization and copolymerization synthesis, function- alization of polymers, physical properties and hybrid systems A large part is devoted to composites and nanocomposites; their mechanical impact on their properties are evaluated and discussed Applications in medicine as drug-release for cancer treatment or as development of green materials and as renewable resources with a particular emphasis on the research of the authors’ group(s) are presented Coating and curing processes are also cov- ered in this book in order to have a better control and understanding of the crosslinking reactions
The progress captured in the current set of articles shows promise for developing materials that seem capable of moving this field from laboratory- scale prototypes to actual industrial applications.
This book serves as a valuable and informative reference for scientists, engineers, medical technologists and practioners engaged in the teaching, research, development and use of functional polymers and composites.
Professor, Dr of Science, Omari Mukbaniani
Iv Javakhishvili Tbilisi State University, Faculty of Exact and Natural Sciences, Department of Chemistry, Chair of Macromolecular Chemistry,
Director of the Institute of Macromolecular Chemistry and Polymeric Materials
Professor Emeritus, Doctor Honoris Causa Institut Charles Gerhardt de Montpellier – Agrégats, Interfaces et Matériaux pour l’Energie (IGCM AIME UMR CNRS 5253) STEPI General Chairman, Expert près la Cour d’Appel
“Michael Fam” Visiting Professor @ NTU/MSE, Singapore
Ivane Javakhishvili Tbilisi State University, Senior Specialist of the Unite of Academic Process Management
(Faculty of Exact and Natural Sciences), Senior Researcher of the Institute of Macromolecular Chemistry and
A H DURGARYAN, N A DURGARYAN, R H ARAKELYAN, and N A MIRAQYAN
Yerevan State University, Alek Manoogian 1, Yerevan, 375025,
Republic of Armenia, E-mail: durnar63@yahoo.com
Abstract 3 1.1 Introduction 4 1.2 Experimental Part 5 1.3 Results and Discussion 8 Acknowledgments 12 Keywords 12 References 12
The oxidative copolymerization of aniline with p-phenylenediamine in an acetic acid medium has been investigated for the first time It has been deter- mined that as a result of copolymerization; a polymer having a structure analogous to the polyaniline called emeraldine is formed The obtained copo- lymer doped with 3N hydrochloric acid has an electrical conductivity five times higher than that of polyaniline prepared by the usual method Aniline polymerization proceeds more slowly at 273K under the same copolymer- ization conditions and the obtained polymer has low conductivity However, in a mixture of acetic acid-methanol, the reaction proceeds faster and the obtained polymer has conductivity almost equal to that of emeraldine It has been observed that the conductivity of polymers doped with formic acid is lower than that of polymers obtained by doping with hydrochloric acid by 2 orders of magnitude.
Among the electro active polymers, the emeraldine form of polyaniline (PANI) attracts intense interest [1, 2] PANI occupies a particular place among the electro active conjugated polymers owing to its environmental stability, easy and cheap method of preparation and its unique properties
It is extensively used in various fields of technology [3–14] To improve the properties of PANI, studies of aniline copolymerization with different monomers have been conducted [12–19]; however, the conductivity of the obtained copolymers is inferior to that of PANI in spite of high solubility. According to the literature data, copolymer Ι[20] is formed during the copolymerization of p-phenylenediamine (PPDA) with aniline.
In the formation of copolymer Ι, for 1 mole each of aniline and PPDA,
3 moles of peroxydisulfate (PDS) are required [20] because when using 1 mole of PDS for 1 mole of aniline, the calculated yield for aniline cannot be higher than 33%, while a yield of 62% to 75% was actually obtained [20] It may be concluded from these data that the reaction does not proceed accord- ing to Figure 4 given in the Ref [20].
According to other literature data, in the case of a molar ratio of aniline/ PPDA of 50:1, the presence of PPDA greatly increases the rate of polymer- ization and does not affect the structure and crystalline of PANI [21].
These data strengthen our opinion that the reaction mechanism differs from that described in the literature [20], and considering the scheme for the oxidative polymerization of PPDA [22]; we have proposed that it proceeds with a mechanism similar to that depicted in Scheme 1[23].
If the reaction occurs according to Scheme 1, the maximum yield calcu- lated for aniline will be 67%, while in the case of a ratio of PPDA-aniline in the copolymer of more than 1; the yield will be above 67%.
The purpose of the present work is to verify the possibility that the reac- tion proceeds according to Scheme 1.
The inherent viscosity of DMSO solution was determined at 25°C, using Ubbelohde viscometer.