Flowing fluids undergo boiling or condensation in many of the cases inwhich we transfer heat to fluids moving through tubes.. 498 Heat transfer in boiling and other phase-change configurati
Trang 1496 Heat transfer in boiling and other phase-change configurations §9.7
range of the data
The influence of fluid flow on film boiling Bromley et al [9.40] showedthat the film boiling heat flux during forced flow normal to a cylindershould take the form
q = constant
k
g ρ g h fg ∆T u ∞ D
1/2
(9.42)
for u2∞ /(gD) ≥ 4 with h fg from eqn (9.29) Their data fixed the constant
at 2.70 Witte [9.41] obtained the same relationship for flow over a sphereand recommended a value of 2.98 for the constant
Additional work in the literature deals with forced film boiling onplane surfaces and combined forced and subcooled film boiling in a vari-ety of geometries [9.42] Although these studies are beyond our presentscope, it is worth noting that one may attain very high cooling rates usingfilm boiling with both forced convection and subcooling
Flowing fluids undergo boiling or condensation in many of the cases inwhich we transfer heat to fluids moving through tubes For example,such phase change occurs in all vapor-compression power cycles and
refrigerators When we use the terms boiler, condenser, steam generator,
or evaporator we usually refer to equipment that involves heat transfer
within tubes The prediction of heat transfer coefficients in these systems
is often essential to determining U and sizing the equipment So let us
consider the problem of predicting boiling heat transfer to liquids flowingthrough tubes
Trang 2Figure 9.18 The development of a two-phase flow in a vertical
tube with a uniform wall heat flux (not to scale)
497
Trang 3498 Heat transfer in boiling and other phase-change configurations §9.7
Relationship between heat transfer and temperature difference
Forced convection boiling in a tube or duct is a process that becomes veryhard to delineate because it takes so many forms In addition to the usualsystem variables that must be considered in pool boiling, the formation
of many regimes of boiling requires that we understand several boilingmechanisms and the transitions between them, as well
Collier and Thome’s excellent book, Convective Boiling and
Condensa-tion [9.43], provides a comprehensive discussion of the issues involved
in forced convection boiling Figure9.18 is their representation of the
fairly simple case of flow of liquid in a uniform wall heat flux tube in
which body forces can be neglected This situation is representative of a
fairly low heat flux at the wall The vapor fraction, or quality, of the flow
increases steadily until the wall “dries out.” Then the wall temperaturerises rapidly With a very high wall heat flux, the pipe could burn outbefore dryout occurs
Figure9.19, also provided by Collier, shows how the regimes shown inFig.9.18are distributed in heat flux and in position along the tube Noticethat, at high enough heat fluxes, burnout can be made to occur at any sta-
tion in the pipe In the subcooled nucleate boiling regime (B in Fig.9.18)
and the low quality saturated regime (C), the heat transfer can be
pre-dicted using eqn (9.37) in Section 9.6 But in the subsequent regimes
of slug flow and annular flow (D, E, and F ) the heat transfer mechanism
changes substantially Nucleation is increasingly suppressed, and ization takes place mainly at the free surface of the liquid film on thetube wall
vapor-Most efforts to model flow boiling differentiate between
nucleate-boiling-controlled heat transfer and convective boiling heat transfer In
those regimes where fully developed nucleate boiling occurs (the later
parts of C), the heat transfer coefficient is essentially unaffected by the
mass flow rate and the flow quality Locally, conditions are similar to poolboiling In convective boiling, on the other hand, vaporization occursaway from the wall, with a liquid-phase convection process dominating
at the wall For example, in the annular regions E and F , heat is convected
from the wall by the liquid film, and vaporization occurs at the interface
of the film with the vapor in the core of the tube Convective boilingcan also dominate at low heat fluxes or high mass flow rates, where wallnucleate is again suppressed Vaporization then occurs mainly on en-trained bubbles in the core of the tube In convective boiling, the heattransfer coefficient is essentially independent of the heat flux, but it is
Trang 4§9.7 Forced convection boiling in tubes 499
Figure 9.19 The influence of heat flux on two-phase flow behavior.
strongly affected by the mass flow rate and quality
Building a model to capture these complicated and competing trends
has presented a challenge to researchers for several decades One early
effort by Chen [9.44] used a weighted sum of a nucleate boiling heat
trans-fer coefficient and a convective boiling coefficient, where the weighting
depended on local flow conditions This model represents water data to
an accuracy of about ±30% [9.45], but it does not work well with most
other fluids Chen’s mechanistic approach was substantially improved
in a more complex version due to Steiner and Taborek [9.46] Many other
investigators have instead pursued correlations built from dimensional
analysis and physical reasoning
To proceed with a dimensional analysis, we first note that the liquid
and vapor phases may have different velocities Thus, we avoid
Trang 5intro-500 Heat transfer in boiling and other phase-change configurations §9.7
ducing a flow speed and instead rely on the the superficial mass flux, G,
through the pipe:
tion for the flow boiling heat transfer coefficient, hfb, should take the
following form for saturated flow in vertical tubes:
hfb= fnhlo, G, x, h fg , q w , ρ f , ρ g , D
(9.45)
It should be noted that other liquid properties, such as viscosity and
con-ductivity, are represented indirectly through hlo This functional
equa-tion has eight dimensional variables (and one dimensionless variable, x)
in five dimensions (m, kg, s, J, K) We thus obtain three more
dimension-less groups to go with x, specifically
Bo≡ qw
Trang 6§9.7 Forced convection boiling in tubes 501
Table 9.4 Fluid-dependent parameter F in the Kandlikar
cor-relation for copper tubing Additional values are given in [9.47]
When the convection number is large (Co 1), as for low quality,
nucleate boiling dominates In this range, hfb/hlorises with increasing Bo
and is approximately independent of Co When the convection number
is smaller, as at higher quality, the effect of the boiling number declines
and hfb/hloincreases with decreasing Co
Correlations having the general form of eqn (9.49) were developed
by Schrock and Grossman [9.48], Shah [9.49], and Gungor and
Winter-ton [9.50] Kandlikar [9.45, 9.47, 9.51] refined this approach further,
obtaining good accuracy and better capturing the parametric trends His
method is to calculate hfb/hlofrom each of the following two correlations
and to choose the larger value:
where “nbd” means “nucleate boiling dominant” and “cbd” means
“con-vective boiling dominant”
In these equations, the orientation factor, f o, is set to unity for
ver-tical tubes4 and F is a fluid-dependent parameter whose value is given
4 The value for horizontal tubes is given in eqn ( 9.52 ).
Trang 7502 Heat transfer in boiling and other phase-change configurations §9.7
in Table9.4 The parameter F arises here for the same reason that
fluid-dependent parameters appear in nucleate boiling correlations: surfacetension, contact angles, and other fluid-dependent variables influencenucleation and bubble growth The values in Table9.4are for commer-cial grades of copper tubing For stainless steel tubing, Kandlikar recom-
mends F = 1 for all fluids Equations (9.50) are applicable for the
satu-rated boiling regimes (C through F ) with quality in the range 0 < x ≤ 0.8.
For subcooled conditions, see Problem9.21
Example 9.9
0.6 kg/s of saturated H2O at T b = 207 ◦C flows in a 5 cm diameter
ver-tical tube heated at a rate of 184,000 W/m2 Find the wall temperature
at a point where the quality x is 20%.
Solution. Data for water are taken from Tables A.3–A.5 We first
compute hlo
G = A m˙
pipe = 0.001964 0.6 = 305.6 kg/m2sand
Relo= GD
µ f = (305.6)(0.05)
1.297 × 10 −4 = 1.178 × 105From eqns (7.42) and (7.43):
for water, and for a vertical tube, f o = 1 Also,
Trang 8§9.7 Forced convection boiling in tubes 503
Substituting into eqns (9.50):
hfb
nbd= (3, 115)(1 − 0.2) 0.8
0.6683 (0.3110) −0.2 (1) + 1058 (3.147 × 10 −4 ) 0.7 (1)
= 11, 950 W/m2K
hfb
cbd= (3, 115)(1 − 0.2) 0.8
1.136 (0.3110) −0.9 (1) + 667.2 (3.147 × 10 −4 ) 0.7 (1)
The Kandlikar correlation leads to mean deviations of 16% for water
and 19% for the various refrigerants The Gungor and Winterton
corre-lation [9.50], which is popular for its simplicity, does not contain
fluid-specific coefficients, but it is somewhat less accurate than either the
Kan-dlikar equations or the more complex Steiner and Taborek method [9.45,
9.46] These three approaches, however, are among the best available
Two-phase flow and heat transfer in horizontal tubes
The preceding discussion of flow boiling in tubes is largely restricted to
vertical tubes Several of the flow regimes in Fig 9.18 will be altered
as shown in Fig 9.20if the tube is oriented horizontally The reason is
that, especially at low quality, liquid will tend to flow along the bottom of
the pipe and vapor along the top The patterns shown in Fig.9.20, by the
way, will also be observed during the reverse process—condensation—or
during adiabatic two-phase flow
Which flow pattern actually occurs depends on several parameters
in a fairly complex way While many methods have been suggested to
predict what flow pattern will result for a given set of conditions in the
pipe, one of the best is that developed by Dukler, Taitel, and their
co-workers Their two-phase flow-regime maps are summarized in [9.52]
and [9.53]
For the prediction of heat transfer, the most important additional
parameter is the Froude number, Frlo, which characterizes the strength
of the flow’s inertia (or momentum) relative to the gravitational forces
Trang 9504 Heat transfer in boiling and other phase-change configurations §9.7
Figure 9.20 The discernible flow
regimes during boiling, condensation, or
adiabatic flow from left to right in
horizontal tubes
that drive the separation of the liquid and vapor phases:
Frlo≡ G2
When Frlo< 0.04, the top of the tube becomes relatively dry and hfb/hlo
begins to decline as the Froude number decreases further
Kandlikar found that he could modify his correlation to account for
gravitational effects in horizontal tubes by changing the value of f o ineqns (9.50):
Peak heat flux
We have seen that there are two limiting heat fluxes in flow boiling in atube: dryout and burnout The latter is the more dangerous of the twosince it occurs at higher heat fluxes and gives rise to more catastrophictemperature rises Collier and Thome provide an extensive discussion ofthe subject [9.43], as does Hewitt [9.54]
Trang 10§9.8 Forced convective condensation heat transfer 505
One effective set of empirical formulas was developed by Katto [9.55]
He used dimensional analysis to show that
where L is the length of the tube and D its diameter Since G2L σ ρ f
is a Weber number, we can see that this equation is of the same form
as eqn (9.39) Katto identifies several regimes of flow boiling with both
saturated and subcooled liquid entering the pipe For each of these
re-gions, he and Ohne [9.56] later fit a successful correlation of this form to
existing data
Pressure gradients in flow boiling
Pressure gradients in flow boiling interact with the flow pattern and the
void fraction, and they can change the local saturation temperature of the
fluid Gravity, flow acceleration, and friction all contribute to pressure
change, and friction can be particularly hard to predict In particular, the
frictional pressure gradient can increase greatly as the flow quality rises
from the pure liquid state to the pure vapor state; the change can amount
to more than two orders of magnitude at low pressures Data correlations
are usually used to estimate the frictional pressure loss, but they are,
at best, accurate to within about ±30% Whalley [9.57] provides a nice
introduction such methods Certain complex models, designed for use
in computer codes, can be used to make more accurate predictions [9.58]
When vapor is blown or forced past a cool wall, it exerts a shear stress
on the condensate film If the direction of forced flow is downward, it
will drag the condensate film along, thinning it out and enhancing heat
transfer It is not hard to show (see Problem9.22) that
(9.53)
where τ δis the shear stress exerted by the vapor flow on the condensate
film
Equation (9.53) is the starting point for any analysis of forced
convec-tion condensaconvec-tion on an external surface Notice that if τ δis negative—if
Trang 11506 Heat transfer in boiling and other phase-change configurations §9.9
the shear opposes the direction of gravity—then it will have the effect of
thickening δ and reducing heat transfer Indeed, if for any value of δ,
τ δ = − 3g(ρ f − ρg)
the shear stress will have the effect of halting the flow of condensate
completely for a moment until δ grows to a larger value.
Heat transfer solutions based on eqn (9.53) are complex because theyrequire that one solve the boundary layer problem in the vapor in order
to evaluate τ δ; and this solution must be matched with the velocity atthe outside surface of the condensate film Collier and Thome [9.43,
§10.5] discuss such solutions in some detail One explicit result has beenobtained in this way for condensation on the outside of a horizontalcylinder by Shekriladze and Gomelauri [9.59]:
An automobile windshield normally is covered with droplets during alight rainfall They are hard to see through, and one must keep the wind-shield wiper moving constantly to achieve any kind of visibility A glasswindshield is normally quite clean and is free of any natural oxides, sothe water forms a contact angle on it and any film will be unstable Thewater tends to pull into droplets, which intersect the surface at the con-tact angle Visibility can be improved by mixing a surfactant chemicalinto the window-washing water to reduce surface tension It can also be
Trang 12§9.9 Dropwise condensation 507
improved by preparing the surface with a “wetting agent” to reduce the
contact angle.5
Such behavior can also occur on a metallic condensing surface, but
there is an important difference: Such surfaces are generally wetting
Wetting can be temporarily suppressed, and dropwise condensation can
be encouraged, by treating an otherwise clean surface (or the vapor) with
oil, kerosene, or a fatty acid But these contaminants wash away fairly
quickly More permanent solutions have proven very elusive, with the
result the liquid condensed in heat exchangers almost always forms a
film
It is regrettable that this is the case, because what is called
drop-wise condensation is an extremely effective heat removal mechanism.
Figure 9.21 shows how it works Droplets grow from active nucleation
sites on the surface, and in this sense there is a great similarity between
nucleate boiling and dropwise condensation The similarity persists as
the droplets grow, touch, and merge with one another until one is large
enough to be pulled away from its position by gravity It then slides off,
wiping away the smaller droplets in its path and leaving a dry swathe in
its wake New droplets immediately begin to grow at the nucleation sites
in the path
The repeated re-creation of the early droplet growth cycle creates a
very efficient heat removal mechanism It is typically ten times more
effective than film condensation under the same temperature difference
Indeed, condensing heat transfer coefficients as high as 200,000 W/m2K
can be obtained with water at 1 atm Were it possible to sustain dropwise
condensation, we would certainly design equipment in such a way as to
make use of it
Unfortunately, laboratory experiments on dropwise condensation are
almost always done on surfaces that have been prepared with oleic, stearic,
or other fatty acids, or, more recently, with dioctadecyl disulphide These
nonwetting agents, or promoters as they are called, are discussed in
[9.60,9.61] While promoters are normally impractical for industrial use,
since they either wash away or oxidize, experienced plant engineers have
sometimes added rancid butter through the cup valves of commercial
condensers to get at least temporary dropwise condensation
Finally, we note that the obvious tactic of coating the surface with a
5 A way in which one can accomplish these ends is by wiping the wet window with
a cigarette It is hard to tell which of the two effects the many nasty chemicals in the
cigarette achieve.
Trang 13a The process of liquid removal during dropwise
con-densation
b Typical photograph of dropwise condensation
pro-vided by Professor Borivoje B Miki´c Notice the dry paths
on the left and in the wake of the middle droplet
Figure 9.21 Dropwise condensation.
508
Trang 14§9.10 The heat pipe 509
thin, nonwetting, polymer film (such as PTFE, or Teflon) adds just enough
conduction resistance to reduce the overall heat transfer coefficient to a
value similar to film condensation, fully defeating its purpose!
(Suffi-ciently thin polymer layers have not been found to be durable.) Noble
metals, such as gold, platinum, and palladium, can also be used as
non-wetting coating, and they have sufficiently high thermal conductivity to
avoid the problem encountered with polymeric coatings For gold,
how-ever, the minimum effective coating thickness is about 0.2 µm, or about
1/8 Troy ounce per square meter [9.62] Such coatings are far too
expen-sive for the vast majority of technical applications
A heat pipe is a device that combines the high efficiencies of boiling and
condensation It is aptly named because it literally pipes heat from a hot
region to a cold one
The operation of a heat pipe is shown in Fig.9.22 The pipe is a tube
that can be bent or turned in any way that is convenient The inside of
the tube is lined with a layer of wicking material The wick is wetted with
an appropriate liquid One end of the tube is exposed to a heat source
that evaporates the liquid from the wick The vapor then flows from the
hot end of the tube to the cold end, where it is condensed Capillary
action moves the condensed liquid axially along the wick, back to the
evaporator where it is again vaporized
Placing a heat pipe between a hot region and a cold one is thus
sim-ilar to connecting the regions with a material of extremely high thermal
conductivity—potentially orders of magnitude higher than any solid
ma-terial Such devices are used not only for achieving high heat transfer
rates between a source and a sink but for a variety of less obvious
pur-poses They are used, for example, to level out temperatures in systems,
since they function almost isothermally and offer very little thermal
re-sistance
Design considerations in matching a heat pipe to a given application
center on the following issues
• Selection of the right liquid The intended operating temperature of
the heat pipe can be met only with a fluid whose saturation
tem-peratures cover the design temperature range Depending on the
temperature range needed, the liquid can be a cryogen, an organic
Trang 15510 Heat transfer in boiling and other phase-change configurations §9.10
Figure 9.22 A typical heat pipe configuration.
liquid, water, a liquid metal, or, in principle, almost any fluid ever, the following characteristics will serve to limit the vapor massflow per watt, provide good capillary action in the wick, and controlthe temperature rise between the wall and the wick:
How-i) High latent heatii) High surface tensioniii) Low liquid viscositiesiv) High thermal conductivityTwo liquids that meet these four criteria admirably are water andmercury, although toxicity and wetting problems discourage theuse of the latter Ammonia is useful at temperatures that are abit too low for water At high temperatures, sodium and lithiumhave good characteristics, while nitrogen is good for cryogenic tem-
peratures Fluids can be compared using the merit number, M =
h fg σ /ν f (see Problem9.36)
• Selection of the tube material The tube material must be compatible
with the working fluid Gas generation and corrosion are particularconsiderations Copper tubes are widely used with water, methanol,and acetone, but they cannot be used with ammonia Stainless steel
Trang 16§9.10 The heat pipe 511
tubes can be used with ammonia and many liquid metals, but are
not suitable for long term service with water In some aerospace
applications, aluminum is used for its low weight; however, it is
compatible with working fluids other than ammonia
• Selection and installation of the wick Like the tube material, the
wick material must be compatible with the working fluid In
ad-dition, the working fluid must be able to wet the wick Wicks can
be fabricated from a metallic mesh, from a layer of sintered beads,
or simply by scoring grooves along the inside surface of the tube
Many ingenious schemes have been created for bonding the wick to
the inside of the pipe and keeping it at optimum porosity
• Operating limits of the heat pipe The heat transfer through a heat
pipe is restricted by
i) Viscous drag in the wick at low temperature
ii) The sonic, or choking, speed of the vapor
iii) Drag of the vapor on the counterflowing liquid in the wick
iv) Ability of capillary forces in the wick to pump the liquid through
the pressure rise between evaporator and condenser
v) The boiling burnout heat flux in the evaporator section
These items much each be dealt with in detail during the design of
a new heat pipe [9.63]
• Control of the pipe performance Often a given heat pipe will be
called upon to function over a range of conditions—under varying
evaporator heat loads, for example One way to vary its
perfor-mance is through the introduction of a non-condensible gas in the
pipe This gas will collect at the condenser, limiting the area of
the condenser that vapor can reach By varying the amount of gas,
the thermal resistance of the heat pipe can be controlled In the
absence of active control of the gas, an increase in the heat load
at the evaporator will raise the pressure in the pipe, compressing
the noncondensible gas and lowering the thermal resistance of the
pipe The result is that the temperature at the evaporator remains
essentially constant even as the heat load rises as falls
Heat pipes have proven useful in cooling high power-density
elec-tronic devices The evaporator is located on a small elecelec-tronic component
Trang 17512 Chapter 9: Heat transfer in boiling and other phase-change configurations
Figure 9.23 A heat sink for cooling a microprocessor tesy of Dr A B Patel, Aavid Thermalloy LLC
Cour-to be cooled, perhaps a microprocessor, and the condenser is finned andcooled by a forced air flow (in a desktop or mainframe computer) or isunfinned and cooled by conduction into the exterior casing or structuralframe (in a laptop computer) These applications rely on having a heatpipe with much larger condenser area than evaporator area Thus, theheat fluxes on the condenser are kept relatively low This facilitates suchuncomplicated means for the ultimate heat disposal as using a small fan
to blow air over the condenser
One heat-pipe-based electronics heat sink is shown in Fig.9.23 Thecopper block at center is attached to a microprocessor, and the evapora-tor sections of two heat pipes are embedded in the block The condensersections of the pipes have copper fins pressed along their length A pair
of spring clips holds the unit in place These particular heat pipes havecopper tubes with water as the working fluid
The reader interested in designing or selecting a heat pipe will find abroad discussion of such devices in the book by Dunn and Reay [9.63]
Trang 18Problems 513
Problems
9.1 A large square tank with insulated sides has a copper base
1.27 cm thick The base is heated to 650◦C and saturated water
is suddenly poured in the tank Plot the temperature of the
base as a function of time on the basis of Fig.9.2if the bottom
of the base is insulated In your graph, indicate the regimes
of boiling and note the temperature at which cooling is most
rapid
9.2 Predict qmaxfor the two heaters in Fig.9.3b At what
percent-age of qmax is each one operating?
9.3 A very clean glass container of water at 70◦C is depressurized
until it is subcooled 30◦C Then it suddenly and explosively
“flashes” (or boils) What is the pressure at which this
hap-pens? Approximately what diameter of gas bubble, or other
disturbance in the liquid, caused it to flash?
9.4 Plot the unstable bubble radius as a function of liquid
super-heat for water at 1 atm Comment on the significance of your
curve
9.5 In chemistry class you have probably witnessed the phenomenon
of “bumping” in a test tube (the explosive boiling that blows
the contents of the tube all over the ceiling) Yet you have
never seen this happen in a kitchen pot Explain why not
9.6 Use van der Waal’s equation of state to approximate the
high-est reduced temperature to which water can be superheated at
low pressure How many degrees of superheat does this
sug-gest that water can sustain at the low pressure of 1 atm? (It
turns out that this calculation is accurate within about 10%.)
What would R bbe at this superheat?
9.7 Use Yamagata’s equation, (9.3), to determine how nucleation
site density increases with∆T for Berenson’s curves in Fig.9.14
(That is, find c in the relation n = constant ∆T c.)
9.8 Suppose that Csffor a given surface is high by 50% What will
be the percentage error in q calculated for a given value of ∆T ?
[Low by 70%.]
Trang 19514 Chapter 9: Heat transfer in boiling and other phase-change configurations
9.9 Water at 100 atm boils on a nickel heater whose temperature
is 6◦ C above Tsat Find h and q.
9.10 Water boils on a large flat plate at 1 atm Calculate qmaxif the
plate is operated on the surface of the moon (at16of gearth−normal).
What would qmax be in a space vehicle experiencing 10−4 of
gearth−normal?
9.11 Water boils on a 0.002 m diameter horizontal copper wire Plot,
to scale, as much of the boiling curve on log q vs log ∆T
coor-dinates as you can The system is at 1 atm
9.12 Redo Problem 9.11 for a 0.03 m diameter sphere in water at
10 atm
9.13 Verify eqn (9.17)
9.14 Make a sketch of the q vs (T w −Tsat) relation for a pool boiling
process, and invent a graphical method for locating the points
where h is maximum and minimum.
9.15 A 2 mm diameter jet of methanol is directed normal to the
center of a 1.5 cm diameter disk heater at 1 m/s How many
watts can safely be supplied by the heater?
9.16 Saturated water at 1 atm boils on a ½ cm diameter platinum
rod Estimate the temperature of the rod at burnout
9.17 Plot (T w − Tsat) and the quality x as a function of position x
for the conditions in Example9.9 Set x = 0 where x = 0 and
end the plot where the quality reaches 80%
9.18 Plot (T w − Tsat) and the quality x as a function of position in
an 8 cm I.D pipe if 0.3 kg/s of water at 100 ◦C passes through
it and q w = 200, 000 W/m2
9.19 Use dimensional analysis to verify the form of eqn (9.8)
9.20 Compare the peak heat flux calculated from the data given in
Problem 5.6with the appropriate prediction [The prediction
is within 11%.]
...by Schrock and Grossman [9.48], Shah [9.49], and Gungor and
Winter-ton [9.50] Kandlikar [9.45, 9.47, 9.51] refined this approach further,
obtaining good accuracy and better capturing... the wick to
the inside of the pipe and keeping it at optimum porosity
• Operating limits of the heat pipe The heat transfer through a heat< /i>
pipe is restricted by
i)... developed by Dukler, Taitel, and their
co-workers Their two-phase flow-regime maps are summarized in [9.52]
and [9.53]
For the prediction of heat transfer, the most important