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Oligozinc Enzymes J Am Chem Soc., 118 , 9288-9294 Ruggiero, C.E., Carrier, S.M., Antholine, W.E., Whittaker, J.W., Cramer, C.J & Tolman, W.B (1993) Synthesis and structural and spectroscopic characterization of mononuclear copper nitrosyl complexes: models for nitric oxide adducts of copper proteins and copper-exchanged zeolites J Am Chem Soc., 115 , 112 85 -112 98 424 Biomimetic Based Applications Santini, C.,... 3, 117 1 -118 4 422 Biomimetic Based Applications Pate, J.E., Thamann, T.J & Solomon, E.I (1986) Resonance raman studies of the coupled binuclear copper active site in met azide hemocyanin Spectroc Acta Pt A-Molec Biomolec Spectr., 42A, 313-318 Pellei, M., Gioia Lobbia, G., Papini, G & Santini, C (2010) Synthesis and Properties of Poly(pyrazolyl)borate and Related Boron-Centered Scorpionate Ligands Part. .. (M = Mo, W) Inorg Chem., 36, 356-361 416 Biomimetic Based Applications Hulse, C.L., Tiedje, J.M & Averill, B.A (1989) Evidence for a copper-nitrosyl intermediate in denitrification by the copper-containing nitrite reductase of Achromobacter cycloclastes J Am Chem Soc., 111 , 2322-2323 Ibrahim, M.M., He, G., Seebacher, J., Benkmil, B & Vahrenkamp, H (2005) Biomimetic thiolate alkylation with zinc pyrazolylbis(thioimidazolyl)borate... Creation of type-1 and type-2 copper sites by addition of exogenous ligands to the Pseudomonas aeruginosa azurin His117Gly mutant J Am Chem Soc., 115 , 112 1 -112 9 Den Blaauwen, T., Hoitink, C.W., Canters, G.W., Han, J., Loehr, T.M & Sanders-Loehr, J (1993) Resonance Raman spectroscopy of the azurin His117Gly mutant Interconversion of type 1 and type 2 copper sites through exogenous ligands Biochemistry, 32,... Hedman, B., Hodgson, K.O., Fujisawa, K & Solomon, E.I (2000) Spectroscopic and electronic structural studies of blue copper model Biomimetic Applications of Metal Systems Supported by Scorpionates 423 complexes Part 1 Perturbation of the thiolate-Cu bond J Am Chem Soc., 122, 116 20 -116 31 Randall, D.W., DeBeer George, S., Holland, P.L., Hedman, B., Hodgson, K.O., Tolman, W.B & Solomon, E.I (2000) Spectroscopic... Proteins J Am Chem Soc., 119 , 4182-4196 Lee, S.C & Holm, R.H (2003) Speculative synthetic chemistry and the nitrogenase problem Proc Natl Acad Sci U S A., 100, 3595-3600 Biomimetic Applications of Metal Systems Supported by Scorpionates 419 Lee, S.C & Holm, R.H (2004) The Clusters of Nitrogenase: Synthetic Methodology in the Construction of Weak-Field Clusters Chem Rev., 104, 113 5 -115 7 Lehnert, N., Cornelissen,... molecular topological analogues of the PN cluster of nitrogenase 406 Biomimetic Based Applications High-nuclearity metal-sulfur clusters may function as precursors to other clusters related in structure to the P-cluster (Fe8S9) and FeMo-cofactor cluster (MoFe7S9) of nitrogenase (Zhou et al., 2002; Berlinguette et al., 2006) In particular, the double cubane [HB(pz)3]2Mo2Fe6S8(PEt3)4 system has been... complexes as manganese superoxide dismutase mimics Inorg Chem., 32, 1879-1880 418 Biomimetic Based Applications Kitajima, N., Osawa, M., Tanaka, M & Morooka, Y (1991) A novel dioxygenase type oxygen insertion Carbon-hydrogen bond oxidation of isopropyl groups in a dimanganese complex with molecular oxygen J Am Chem Soc., 113 , 8952-8953 Kitajima, N & Tolman, W.B (1995) Coordination chemistry with sterically... enzymes have become excellent targets within biomimetic chemistry Modelling of hydrogenase enzymes requires the efficient synthesis of half-sandwich complexes of the form [HB(timR)3]NiX or [H2B(timR)2]NiX The chemistry of nikel is driven by the formation of bis-ligand complexes such as [HB(timR)3]2Ni (Garner et al., 2003; Senda et al., 2006) and 408 Biomimetic Based Applications [H2B(timR)2]2Ni (Alvarez et... Chem Commun., 4, 126-129 Biomimetic Applications of Metal Systems Supported by Scorpionates 411 Brombacher, H & Vahrenkamp, H (2004) Pyrazolylborate-Zinc Alkoxide Complexes 3 Acid-Base Reactions Inorg Chem., 43, 6054-6060 Brondino, C.D., Romao, M.J., Moura, I & Moura, J.J.G (2006) Molybdenum and tungsten enzymes: the xanthine oxidase family Curr Opin Chem Biol., 10, 109 -114 Bruce, M.I & Ostazewski, . $+)*"/)-*C%S4)1%6('O)3)()/J%)1%/4-#I4/%/-%3'%&apos ;11& apos;*/)"(%6-$%/4'%4J+$-(J/)H%"H/):)/J%-6% 5"*J%-6%/4'%K)*H%'*KJ5'1C% Biomimetic Based Applications 396 B)-)*-$I"*)H%. 7'CIC=% /B#% I$-#NE=% 3#/% "(1-% /4'% '('H/$-*% 2)/4+$"2)*I% Biomimetic Based Applications 394 H4"$"H/'$% 7'CIC,%,8 f %I$-#NE%-6%/4'%XaB7NK j=jU E f _M1#31/)/#'*/1%. 3''*b% @E% -3/")*% ,#700EM/4)-("/'% 1N'H)'1=% 2)/4-#/% /4'% Biomimetic Based Applications 392 H-*H-5)/"*/% 6-$5"/)-*% -6% +)1#(6)+'1% "*+% ,#70E%