Iec 60086 3 2016

This edition in lu es the fol owin sig ificant tec nical c an es with resp ct to the previou edition: a A harmonization of the cel sizes an service output tests with IEC 6 0 6-2; b Clari

Primary bat eries –

Part 3: W atch bat eries

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Primary bat eries –

Part 3: Watch bat eries

CONTENTS

FOREWORD 4

INTRODUCTION 6

1 Sco e 7

2 Normative referen es 7

3 Terms an definition 7

4 Ph sical req irements 8

4.1 Bat ery dimen ion , s mb ls an size codes 8

4.2 Terminals 10 4.3 Projection of the negative terminal (h 5 ) 10 4.4 Sha e of negative terminal 10 4.5 Mec anical resistan e to pres ure 1

4.6 Deformation 1

4.7 L a age 1

4.8 Markin 12 4.8.1 General 1

2 4.8.2 Disp sal 12 5 Electrical req irements 12 5.1 Electroc emical s stem, nominal voltage, en -p int voltage an o en-circ it voltage 12 5.2 Closed circ it voltage U c (CCV), internal resistan e an imp dan e 13 5.3 Ca acity 13 5.4 Ca acity retention 13 6 Sampl n an q al ty as uran e 13 7 Test method 13 7.1 Sha e an dimen ion 13 7.1.1 Sha e req irement 13 7.2 Electrical c aracteristic 14 7.2.1 En ironmental con ition 14 7.2 2 Eq ivalent circ it – ef ective internal resistan e – DC method 1

4 7.2.3 Eq ipment 15 7.2.4 Me s rement of o en-circ it voltage U oc (OCV) an closed circ it voltage U c (CCV) 15 7.2.5 Calc lation of the internal resistan e R i 16 7.2.6 Me s rement of the ca acity 16 7.2.7 Calc lation of the internal resistan e R i d rin dis harge in case of method A (o tional) 18 7.3 Test method for determinin the resistan e to le k ge 20 7.3.1 Precon itionin an initial vis al examination 20 7.3.2 Hig temp rature an h midity test 2

7.3.3 Test by temp rature c cles 2

8 Vis al examination an ac e tan e con ition 21

8.1 Precon itionin 21

8.2 Mag ification 21

8.3 Lig tin 21

8.4 L a age levels an clas ification 21

An ex A (normative) Desig ation 2

Bibl ogra h 2

Fig re 1 – Dimen ional drawin 8

Fig re 2 – Sha e of negative terminal 1

Fig re 3 – Sha e req irement 14 Fig re 4 – Sc ematic voltage tran ient 14 Fig re 5 – Curve: U = f(t) 15 Fig re 6 – Circ itry prin iple 16 Fig re 7 – Circ itry prin iple for method A 17 Fig re 8 – Circ itry prin iple for method B 18 Fig re 9 – Test by temp rature c cles 2

Ta le 1 – Dimen ion an size codes 9

Ta le 2 – Dimen ion an size codes 10 Ta le 3 – Minimum values of l 1

Ta le 4 – Ap l ed force F by b t ery dimen ion 1

Ta le 5 – Stan ardised electroc emical s stems 12 Ta le 6 – Test method for U c (CCV) me s rement 16 Ta le 7 – Test method A for U c (CCV) me s rement 17 Ta le 8 – Dis harge resistan e (values) 19 Ta le 9 – Storage con ition for the recommen ed test 2

Ta le 10 – Storage con ition for o tional test 2

Ta le 1 – L a age levels an clas ification ( of 2) 2

INTERNATIONAL ELECTROTECHNICAL COMMISSION

Part 3: Watch bat eries

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p te t rig ts IEC sh l n t b h ld resp nsible for id ntifyin a y or al su h p te t rig ts

International Stan ard IEC 6 0 6-3 has b en pre ared by IEC tec nical commite 3 :

Primary cel s an b t eries, an ISO tec nical commit e 1 4: Horolog

This fourth edition can els an re laces the third edition publ s ed in 2 1 This edition

con titutes a tec nical revision

This edition in lu es the fol owin sig ificant tec nical c an es with resp ct to the previou

edition:

a) A harmonization of the cel sizes an service output tests with IEC 6 0 6-2;

b) Clarification of Clau es 6: Sampln an Qual ty As uran e, 7: Test method , an 8:

Vis al examination an ac e tan e con ition;

This publcation is publ s ed as a double logo stan ard.

The text of this stan ard is b sed on the fol owin doc ments:

Ful information on the votin for the a proval of this stan ard can b fou d in the re ort on

votin in icated in the a ove ta le

This publcation has b en drafed in ac ordan e with the ISO/IEC Directives, Part 2

A l st of al p rts in the IEC 6 0 6 series, publ s ed u der the general title Primary b ateries,

can b fou d on the IEC we site

The commit e has decided that the contents of this publcation wi remain u c an ed u ti

the sta i ty date in icated on the IEC we site un er "htp:/we store.iec.c " in the data

related to the sp cific publ cation At this date, the publ cation wi b

• reconfirmed,

• with rawn,

• re laced by a revised edition, or

• amen ed

This p rt of IEC 6 0 6 provides sp cific req irements an information for primary watc

b t eries This p rt of IEC 6 0 6 was pre ared throu h joint work b twe n the IEC an ISO to

b nefit primary b t ery u ers, watc desig ers an b t ery man facturers by en urin the

b st comp tibi ty b twe n b t eries an watc es

This p rt of IEC 6 0 6 wi remain u der contin al s rutin to en ure that the publ cation is

k pt up to date with the ad an es in b th b t ery an watc tec nologies

NOT Safety informatio is a aia le in IEC 6 0 6-4 a d IEC 6 0 6-5

PRIMARY BATTERIES –

Part 3: Watch bat eries

This p rt of IEC 6 0 6 sp cifies dimen ion , desig ation, method of tests an req irements

for primary b teries for watc es In several cases, a men of test method is given When

presentin b tery electrical c aracteristic an /or p rforman e data, the man facturer

sp cifies whic test method was u ed

The folowin doc ments, in whole or in p rt, are normatively referen ed in this doc ment an

are in isp n a le for its a pl cation For dated referen es, only the edition cited a pl es For

u dated referen es, the latest edition of the referen ed doc ment (in lu in an

amen ments) a pl es

IEC 6 0 6-1:2 15, Primary b aterie s – Part 1: G en ral

IEC 6 0 6-2:2 15, Prim ary b ateries – Part 2: Ph sical a d electricalsp e cificato s

IEC 6 0 6-4:2 14, Prim ary b ateries – Part 4: Safety of l hium b ateries

IEC 6 0 6-5:- , Primary b aterie s – Part 5: Safety of b ate ries wih a ueous electrolyte

3 Terms and definitions

For the purp ses of this doc ment, the terms an definition given in IEC 6 0 6-1 as wel as

the fol owin terms an definition a ply

electric c arge (q antity of electricity) whic a cel or b t ery can delver u der sp cified

dis harge con ition

Note 1 to e try: Th SI u it for ele tric c arg is th c ulomb (1 C = 1 As) b t, in pra tic , c p city is usu ly

e pres e inamp re h urs (Ah)

3.3

fre h bat ery

u dis harged b t ery 6 day maximum afer date of man facture

3.4

ohmic drop

p rt of the internal resistan e that le d to a voltage dro immediately af er switc in the lo d

on

4 Physical requirements

4.1 Bat ery dime sions, s mbols a d size code

Dimen ion an toleran es of b teries for watc es s al b in ac ordan e with Fig re 1,

Ta le 1 an Ta le 2 The dimen ion of the b teries s al b tested in ac ordan e with 7.1

The s mb ls u ed to denote the variou dimen ion in Fig re 1 are in ac ordan e with

minimum diameter of th flat n g tiv c nta t

NOT This n mb rin folows th h rmo izatio in th IEC 6 0 6 series

NOT Op n b x s in th a o e matrix are n t n c s ariy a aia le for sta d rdisatio d e to th c n e t of

o erla pin tolera c s

Ta les 1 an 2 This is not a pl ed to those b t eries with a two-ste

negative contact

Positive contact (+): the c l n rical s rface is con ected to the p sitive terminal Positive

contact s ould b made to the side of the b t ery but may b made to

the b se

4.3 Proje tion of the n gativ termin l (h

5)

2

≥ 2,5

The negative contact s ould b the hig est p int of the b t ery

4.4 Shape of ne ativ terminal

The sp ce req irements s al b contained within an an le of 4 ° (see Fig re 2)

The minimum values of l

1, for dif erent heig ts of h

1h

2, are given in Ta le 3

Figure 2 – Shape of ne ativ terminal

Table 3 – Minimum v lue of l

D ime sio s in mi imetres

h

1h

2

3,6 ≤ h

1h

2

5,4 ≤ h

1h

2

0,9

A force F (N), as sp cified in Ta le 4, a pl ed for 10 s throu h a ste l b l of 1 mm diameter,

at the centre of e c contact are , s al not cau e an deformation preju icial to the pro er

fu ctionin of the b t ery, i.e afer this test, the b tery s al p s the tests sp cified in

Clau e 7

Table 4 – Appl e forc F by bat ery dime sion

d

1

h

1h

The dimen ion of b teries s al conform with the relevant sp cified dimen ion at al times

in lu in dis harge to the defined en -p int voltage

NOT 1 A b tery h ig t in re se u to 0,2 mm c no c r, if disc arg d b low this v lta e

NOT 2 A b tery h ig t d cre se c n o c r in Ba d Csystemsas disc arg c ntin es

Un is harged b t eries an , if req ired, b t eries tested ac ordin to 7.2.6 s al b examined

as stated in 7.3 The ac e ta le n mb r of defects s al b agre d b twe n the man facturer

4.8 Marking

The desig ation an the p larity s al b mark d on the b t ery Batery markin s ould not

imp de electrical contact Al other markin s may b given on the p ckin in te d of on the

b t ery:

a) desig ation ac ordin to normative An ex A, or common;

b) expiration of a recommen ed u age p riod or ye r an month or we k of man facture;

The ye r an month or we k of man facture may b in code The code is comp sed by

the last digit of the ye r an by a n mb r in icatin the month Octo er, Novemb r an

Decemb r s ould b re resented by the let ers O, Y an Z resp ctively

e) name or trade mark of the s p l er;

f cautionary ad ice;

g) caution for in estion of b t eries s al b given Refer to IEC 6 0 6-4:2 14 (7.2 a) an 9.2)

The req irements con ernin the electroc emical s stem, the nominal voltage, the en -p int

voltage an the o en-circ it voltage are given in Ta le 5

Table 5 – Sta dardis d ele troc emic l s stems

5.2 Clos d circ it volta e U

c(CCV), internal re ista c a d impe a c

Closed circ it voltage an internal resistan e s al b me s red ac ordin to 7.2

AC imp dan e s ould b me s red with an LCR meter

Limit values s al b agre d b twe n the man facturer an the purc aser

5.3 Capa ity

The ca acity s al b agre d b twe n the man facturer an the purc aser on the b sis of a

contin ou dis harge test lastin a proximately 3 day , ac ordin to 7.2.6

5.4 Capa ity rete tion

The ca acity retention is the ratio b twe n the ca acities u der the given dis harge

con ition me s red on fres b teries an a sample of the same lot stored d rin 3 5 day

at (2 ± 2) °C an a relative h midity b twe n 5 ± 2 %

The ratio of ca acity retention s al b agre d b twe n the man facturer an the purc aser

The minimum value s ould b at le st 9 % for a p riod of 12 month The ca acity

me s rement is car ied out ac ordin to 7.2.6

For the purp se of verifyin compl an e with this stan ard, con itional ac e tan e may b

given afer completion of the initial ca acity tests

Figure 3 – Shape re uireme t

7.2 Ele tric l c ara teristic

7.2.1 En ironme tal conditions

Unles otherwise sp cified, the sample b t eries s al b tested at a temp rature of

(2 ± 2) °C an a relative h midity b twe n 5 + 2 / – 4 %

Durin u e, b t eries may b exp sed to low temp ratures; it is therefore recommen ed to

car y out complementary tests at (0 ± 2) °C an at (–10 ± 2) °C

7.2.2 Eq iv le t circ it – ef e tiv internal re ista c – DC method

Resistan e of an electrical comp nent determined by calc latin the ratio b twe n the

voltage dro ∆U acros this comp nent an the ran e of c r ent ∆i p s in throu h this

comp nent an cau in the voltage dro R = ∆U / ∆i

NOT As a a alo y, th intern l d.c resista c R

i

of a y ele tro h mic l c l is d fin d b th folowin relatio :

)(

)(

)(

AV

i

iU

R

∆

∆

=Ω

2t

1

U

2 (

2)

U

2

= ƒ(

2, t)

As can b se n from the diagram in Fig re 4, the voltage dro ∆U of the two comp nents

dif ers in nature, as s own in the fol owin relation:

1) is in e en ent of time (ohmic dro ), an res lts from the

in re se in c r ent ∆i ac ordin to the relation:

is a pure ohmic resistan e The secon comp nent ∆U (t) is time

de en ent an is of electroc emical origin (ca acitive re ctan e)

7.2.3 Equipme t

The eq ipment u ed for the voltage me s rements s al have the fol owin sp cification :

– precision: ≤ 0 % of last digit;

– internal resistan e: ≥1 MΩ;

– me s rement time: in the tests pro osed in the fol owin s bclau es, it is imp rtant to

ma e s re that the me s rement is ta en d rin the flat p riod of

the voltage tran ient (se Fig re 5) Otherwise, a me s rement er or

d e to the ca acitive re ctan e may oc ur (lower internal resistan e)

The time ∆t ' neces ary for the me s rement s al b brief in comp rison to ∆t , an the

me s rement eq ipment comp tible with these criteria

Ke

1 o e -circ it v lta e U

oc(OC )

2 efe t of c p citiv re cta c

3 close circ it v lta e U

c(C V)

4 ∆t' me sureme t U

c)

Figure 5 – Curv : U = f(t)

7.2.4 Me s reme t of ope -circ it volta e U

oc(OCV) a d clos d circ it volta e

out

c: The b t ery b in tested s al b con ected to the lo d R

m The

Te t metho Bat ery with K H ele t olyte

R sh uld ta e into c nsid ratio th resista c of th c n e tio ln s of th b tery b in teste a d th

c nta t resista c of th switc

co

i

/RU

UU

7.2.6 Me s reme t of the c pa ity

There are two method for me s rin ca acity:

– the recommen ed method is method A, whic is more in icative of watc req irements;

– method B is a more general method an is alre d sp cified in IEC 6 0 6-1 an

resista c of c ntin o s disc arg

Fig re 7 – Circ itry principle for method A

s al in lu e al p rts of the external circ it an s al b ac urate to within ± ,5 %

c) Determination of the ca acity

The me s rements of the o en-circ it voltage U'

The switc is lef o en whie the me s rement is bein car ied out

2) Next me s rement U

c: the b tery b in tested is con ected to R

m The switc is lef

closed d rin the d ration ∆t ac ordin to Ta le 7

Table 7 – Te t method A for U

c(CCV) me s reme t

formula:

d

io

p

R

tU

resista c of c ntin o s disc arg

Fig re 8 – Circ itry principle for method B

b) Se proced re in 7.2.6.2 b)

c) Determination of the ca acity: when the on-lo d voltage of the b t ery u der test dro s for

the first time b low the sp cified en p int as sp cified in Ta le 5, the time t is calc lated

an defined as service l fe

The ca acity is calc lated by the fol owin formula:

t

RU

C

dc

)aver age(

7.2.7 Calc lation of the internal re ista c R

is car ied out ac ordin to the proced re des rib d

in 7.2.6, it is p s ible to calc late the internal resistan e R

i

of the b tery u in the folowin

formula:

mc

co

i

/'

RU

UU

Table 8 – Dis harge re ista c (v lue )

7.3 Te t methods for determining the re ista c to le k ge

7.3.1 Pre on itionin a d initial vis al e amin tion

Before car yin out the tests sp cified in 7.3.2 an 7.3.3, the b t eries s al b s bmit ed to a

vis al examination ac ordin to the req irements stated in Clau e 8

For tests in 7.3.2.1 an 7.3.2.2, b teries s al b pre-stored at the sp cified temp rature

(4 °C an 4 °C resp ctively) for 2 h Bat eries s al b moved from the precon itionin

(alternative pre-stored) c amb r (or oven) into the hig temp rature an h midity test

c amb r within min tes in order to avoid co l n of the b tery an the risk of con en ation at

elevated h midity

7.3.2 High temperature a d humidity te t

The b tery s al b stored u der the con ition sp cified in Ta le 9

Table 9 – Stora e conditions for the re omme de te t

4 ± 2

Th test time of 3 d ys ma b use for a a c lerate ro tin q alty c ntrol test, wh re s th test time of

9 d ys a ples to q alfic tio testin of n w b teries

7.3.2.2 Optional te t

Afer agre ment b twe n the man facturer an purc aser, the fol owin testin con ition

may b c osen (se Ta le 10)

Table 10 – Stora e condition for o tional te t

4 ± 2

Th test time of 2 d ys ma b use for a a c lerate ro tin q alty c ntrol test, wh re s th test time of

6 d ys a ples to q alfic tio testin of n w b teries

8 Visual examination and ac epta ce conditions

8.1 Pre on itionin

Before car yin out the initial vis al examination or af er the tests sp cified in Clau e 7, the

b t eries s al b stored for at le st 2 h at ro m temp rature an at a relative h midity

The le k ge s ould b o served af er cry tal sation of the electrolyte The time of the

storage of 2 h can b prolon ed if neces ary This examination may b a pl ed to new or

u ed b teries, or to b t eries whic have b en s bmit ed to diferent tests

8.2 Ma nific tion

The vis al examination s al b car ied out at a mag ification of x15

8.3 Lig ting

The vis al examination s al b car ied out u der a difu e white l g t of 9 0 lx to 1 10 lx at

the s rface of the b tery to b in p cted

8.4 Le k g le els a d cla sific tion

The vis al examination s al b car ied out u der a difu e white l g t of 9 0 lx to 1 10 lx at

the s rface of the b tery to b in p cted (Se Ta le 1 )

Th a c mulatio of crystal se lq id

c min from th ele trolyte swels u

o p rt of th clo d spre d, whic

c v rs th e tire surfa e of th flat

n g tiv c nta t

L

Th a c mulatio of crystal se lq id

c min from th ele trolyte swels u

o th e tire clo d spre d, whic

c v rs th e tire surfa e of th flat

n g tiv c nta t

The ac e ta le level, as wel as the pro ortion of defective pieces, s al b agre d b twe n

the man facturer an the purc aser

Fres b teries, with a level of le k ge ex e din S1, s al not b s bmit ed for q al fication

The ac e tan e criteria may b les restrictive for b teries whic have b en tested ac ordin

to 7.3.2 If neces ary, photogra hic referen es may b esta ls ed

IEC IEC

Annex A

(normative)

Designation

Watc b teries man factured with the expres purp se of complyin with this stan ard

s ould b desig ated by a s stem of coded leters an n mb rs as s own b low However,

– P: Potas ium h dro id KOH (o tio al)

L ter P ma b lef o t in th c se of ele tro h mic l system leter S

– Org nic ele trolyte: n l

L ter W: c mpla c with IEC 6 0 6-3

Bibl ography

IEC 6 0 8-2-7 :2 01, En iro me ntal testn – Part 2-78: Tests – Test Cab : Damp h at,

ste dy state

ISO 8 01:2 0 , Data eleme nts a d inte rch nge formats – Informato interch n e –

Rep rese ntato of date s a d tmes

ISO 2 5 , Sampln p rocedure s for insp e cto b y atrib u tes p ack ge

ISO 217 7, Statstcal meth ds – Proce ss p erforma ce a d cap ab il y statstc forme sured

qual y ch racteristc