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724 improvement after combination therapy J Am Acad Dermatol 2006;54(5) 914–6 102 Jan F, Segal JM, Dyer J, LeBoit P, Siegfried E, Frieden IJ Nephrogenic fibrosing dermopathy two pediatric cases J Pedi[.]

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© Springer Nature Switzerland AG 2021

B A Warady et al (eds.), Pediatric Dialysis, https://doi.org/10.1007/978-3-030-66861-7_38

Extracorporeal Therapy for Drug Overdose and Poisoning

Vimal Chadha

Introduction

Poisoning continues to be a significant cause of

morbidity and mortality The 2018 Annual Report

of the American Association of Poison Control

Centers National Poison Data System (NPDS):

36th Annual Report published information on

2,099,751 human exposure cases of poisoning of

which more than half (59%) were children and

adolescents <20 years old, with majority (75%)

occurring in children ≤5 years [1] A male

pre-dominance was found among cases involving

children ≤12 years, but this gender distribution

was reversed in teenagers and adults, with

females comprising the majority of reported

exposures [1] Prescription drugs, over-the-

counter medications, illicit drugs, and common

household substances can all be responsible for

poisoning The top five most frequently involved

substances in all human exposures were

analge-sics (10.9%), household cleaning substances

(7.3%), cosmetics/personal care products (6.5%),

sedatives/hypnotics/antipsychotics (5.5%), and

antidepressants (5.2%) In children ≤5  years, analgesics (9%) were surpassed by cosmetics/ personal care products (12.1%) and household cleaning substances (10.7%) [1]

Of note, there has been a steady decline (15.7% since 2008) in the number of poisoning cases, but this has been accompanied by an increase (4.45% per year since 2000) in the num-ber of cases with serious outcomes The most rapidly increasing substance categories resulting

in more serious outcomes for the past 10  years have been antidepressants, stimulants/street drugs, antihistamines, and anticonvulsants [1] While most (76.7%) poison exposures are still unintentional, suicide attempts by adolescents are becoming an important emerging trend; sui-cidal intent was suspected in 19.1% (almost dou-ble since 2008) of cases It is noteworthy that in 13% of exposures (273,581 cases), poisoning resulted due to therapeutic errors such as inadver-tent double dosing, incorrect dosing, wrong med-ication taken or given, and inadvertent exposure

to someone else’s medication

The management of poisoning continues to be

a significant burden on the healthcare system In

2018, approximately one-third (31%) of all cases received treatment in a healthcare facility While half of them were treated and released without hospital admission, 97,963 (15%) had to be admitted for critical care management, and 78,401 (12%) were admitted to a non-critical

V Chadha (*)

Department of Pediatrics, University of

Missouri-Kansas City School of Medicine, Acute Kidney

Injury Program, Children’s Mercy Kansas City,

Kansas City, MO, USA

e-mail: vchadha@cmh.edu

38

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care unit Despite being the most common age

group with poisonings, only 12.5% of children

≤5 years and 18.4% of children between 6 and

12  years were managed in a healthcare facility

compared to 66% of teenagers (13–19 years) and

50% of adults Similarly, children younger than

6 years also experienced the least (<2%) of the

exposure-related fatalities [1]

Poison Characteristics

In the discipline of clinic toxicology, poison

gen-erally refers to any agent (drug or toxin) that can

kill, injure, or impair normal physiologic

func-tion A poison is often referred to as a xenobiotic,

a chemical substance found within an organism

that is not naturally produced or expected to be

present within the organism The term also

includes any naturally existing substances in an

organism that are present in abnormally higher

concentrations

For practical purposes, the poisons can be

divided into two broad categories: those that

cause tissue damage and those that do not

Tissue damage is defined as irreversible or

slowly reversible structural or functional

changes in one or more organ systems that occur

as a direct result of the poison (or its toxic

metabolite) in the body Poisons such as

salicy-lates, acetaminophen, and methanol fall in this

category, and they can cause direct tissue

dam-age despite provision of intensive supportive

care [2 5] Thus, in patients poisoned with this

group of chemicals, use of a specific antidote (if

available) and/or active removal of the poison

by extracorporeal therapies (ECTs) is necessary

to prevent irreversible tissue damage The

sec-ond group of poisons such as barbiturates and

other common sedative/hypnotic drugs does not

have any direct tissue-damaging effect but

causes indirect harm due to respiratory

compro-mise or hypotension These patients can be

treated with specific antidotes (if available) and

supportive care, provided they will metabolize

and/or excrete the poison in a reasonable time

Management of the Poisoned Patient

The general approach to the management of an acute poisoning includes:

1 Patient stabilization (maintenance of the air-way, ventilation, and hemodynamic status)

2 Establishing accurate diagnosis by clinical evaluation which in many cases is aided by identification and determination of blood con-centration of the toxic substance Recognition

of toxidromes (constellation of symptoms and signs associated with certain class of poisons) can be valuable in expediting diagnosis

3 Decontamination (removal of poison from site

of absorption such as GI tract or skin)

4 Administration of antidotes, if available

5 Supportive care (treatment of hypotension, arrhythmias, respiratory failure, electrolyte imbalance, and seizures)

6 Enhancing elimination of poison by manipu-lation of urinary pH

7 Removal of poison by ECTs

Fortunately, the vast majority of patients with poisoning recover with appropriate supportive care and/or timely usage of specific antidote ther-apy As a result, a very limited number of patients require ECTs, but they are also the most critically sick patients where a judicious usage of ECT can determine their outcome According to the NPDS 36th Annual Report, ECTs were utilized in 2817 (2.9%) of 97,963 patients admitted for critical care management [1]

Since poisons achieve their toxic effects on target organs via the bloodstream, it seems logi-cal that their elimination from the blood should result in amelioration of the patient’s condition Accordingly, changes in the serum poison levels are the most frequently used parameters of response to extracorporeal therapy in intoxica-tion; however, this pretext can be misleading and provides false assurance of dialysis efficacy (vide infra) To better understand these perplexi-ties, the nephrologist ought to be well versed

V Chadha

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with the basic concepts of pharmacokinetics and

principles of detoxification when dealing with

the management of an acutely poisoned patient

These concepts also help in determining the

usefulness of extracorporeal therapy as well as

selection of the optimum modality for drug

removal

Extracorporeal therapies are typically reserved

for a small subset of patients that can be divided

into the following five subgroups:

(a) Patients intoxicated with poisons that cause

direct tissue damage and are life-threatening

(e.g., salicylate overdose)

(b) Patients intoxicated with poisons that can

cause permanent disability (e.g., blindness

with methanol overdose)

(c) Patients intoxicated with poisons that do not

cause direct tissue damage, but the patient’s

ability to metabolize or excrete the toxic

sub-stance is compromised (e.g., metformin

overdose with renal impairment)

(d) Patients intoxicated with poisons in which

active poison removal is considered to

avoid prolonged supportive care and its

associated complications (e.g., barbiturate

overdose with coma requiring mechanical

ventilation)

(e) Patients intoxicated with poisons who

develop signs of toxicity despite provision of

standard supportive measures

Pharmacokinetic Concepts

The extracorporeal removal (dialyzability) of a

substance is determined by various

physico-chemical and pharmacokinetic properties

These properties predict the extent to which

ECT enhances the total body clearance, thereby

lowering the total body poison load faster than

without treatment By far, the primary

determi-nants of poison removal by ECT are the

molec-ular weight (MW), volume of distribution (Vd),

and protein binding; additional factors such as

hydro- and lipophilicity, ionization, and rate of

intercompartmental transfer also play a

signifi-cant role

Molecular Weight

The lower the MW, the more likely that a poison

is dialyzable While older cuprophane dialyzers were able to clear substances with MW up to

500 Da, contemporary high-efficiency high-flux dialyzers with diffusive modalities are capable of clearing poisons in the middle MW range (≤15,000 Da) In contrast, convective modalities such as hemofiltration and hemodiafiltration can permit clearance of solutes approaching 25,000 Da

Volume of Distribution

Volume of distribution (Vd) is an imaginary space that represents the volume of fluid in which a known amount of drug would have to be diluted

to yield the measured serum concentration Theoretically, if the body is presumed to be a single compartment and a substance is homoge-nously distributed in body water without binding

to protein or accumulating in tissues, it would have an apparent Vd equal to the total body water

V Litersd 0 6 L kg body weight kg/    (38.1)

For some substances such as methanol that dis-tribute in body water without significant binding

to tissue or plasma protein and without signifi-cant accumulation in adipose tissue, the apparent

Vd corresponds to a physiologic space: in this case equivalent to total body water However, most substances are not homogeneously distrib-uted but rather vary in their concentration throughout the body as a result of lipid solubility, protein binding, active cellular transport, and pH gradients, and as a result Vd can vary over a wide range of values (0.2  L/kg for valproic acid to

20 L/kg for imipramine) A Vd significantly larger than actual body water reflects a high degree of tissue concentration, while a small Vd suggests concentration within the intravascular space Volume of distribution is clinically important in two ways First, knowing the Vd and plasma con-centration of a particular drug allows calculation

of the total amount of the drug in the body, as:

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X mg V Ld C mg Lp /  (38.2)

where X is the total amount of the drug in

milli-grams (mg) and Cp is the plasma concentration in

mg/L. Second, Vd is one of the factors that

deter-mine accessibility of a drug to removal by

extracorporeal therapy A large Vd implies that

the amount of drug present in blood represents

only a small fraction of the total body load;

there-fore, as the Vd increases, the usefulness of any

ECT decreases substantially Thus, even if a

hemodialysis session extracts most of the drug

present in blood passing through the circuit, the

amount of drug removed represents a small

per-centage of the total body drug burden Although

there is no precise cut-off, a Vd > 1–2 L/kg

usu-ally limits usefulness of ECT [6] On the

con-trary, poisons with a smaller Vd (< 1  L/kg) are

more amenable to removal by ECT.  Volume of

distribution of some of the common substances

involved in poisoning is listed in Table 38.1 It is

important to note that these values for Vd are

derived from the general population under

nor-mal dosing conditions and may not apply in the situation of a substantial drug overdose In addi-tion, the presence of renal and/or hepatic dys-function in a poisoned patient can further alter the value of Vd (see section on toxicokinetics, vide infra)

Protein Binding

Many substances bind with varying affinity to plasma proteins, such as albumin, or to intracel-lular proteins in the tissues Thus, in addition to dissolving in fat, substances can accumulate in tissues according to their degree of protein bind-ing A poison-protein complex may exceed 65,000 Da and is too large to be filtered Highly protein-bound (>80%) substances are therefore not amenable to therapy with extracorporeal modalities However, at toxic levels the protein binding sites are usually saturated, thus increas-ing the proportion of free fraction which poten-tially increases poisoning severity because the

Table 38.1 Pharmacokinetic properties of some of the drugs frequently involved in poisoning

Drug

Molecular weight (Da)

Volume of distribution (L/kg)

Protein binding (%)

Preferred extracorporeal modality

Tricyclic

antidepressant

IHD intermittent hemodialysis

a Relatively limited effect, used in select patients with severe toxicity

b Protein binding decreases to 30% with toxic levels

c Protein binding decreases to 15% with toxic levels

d Use high-efficiency high-flux dialyzer

V Chadha

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free fraction exerts toxicity, but this also

facili-tates removal by the ECT. This explains the high

removal rate of protein-bound drugs such as

val-proate and salicylates, both of which exhibit

satu-rable binding at toxic levels [7 8] Of note, when

the protein binding is <80%, there is little

differ-ence between the removal of a substance that is,

for example, 20% protein-bound and one that is

70% protein-bound because of the logarithmic

nature of extracorporeal solute removal

(Fig. 38.1) [9] It is also important to note that

most drug-protein bonds are weak and easily

reversible, and protein binding can be altered by

a number of variables such as pH and drug

com-petition for the binding sites

Hydro- and Lipophilicity

Hydrophilic poisons distribute primarily in total

body water, have a smaller Vd, and are more

readily removed by ECT. Lipid solubility affects

the accumulation of drug in lipid-rich tissues

such as adipose tissue and the brain The degree

of lipid solubility of a substance is expressed by

its partition coefficient, which is an in  vitro measurement of the ratio of lipid (non-polar) phase to aqueous (polar) phase concentration of its non-ionized form Lipid-soluble drugs can accumulate extensively in the adipose tissue and act as a reservoir with poor accessibility due to decreased vascular perfusion

Ionization

Non-ionized substances are more lipid soluble and, therefore, more easily transported across cellular membranes in the body than their ionized form The pK of the substance is the pH at which it is half ionized and half non-ionized An acid is increas-ingly ionized as the pH rises above its pK, and a base is increasingly ionized as pH falls below its

pK. Therefore, pH gradients across the cell mem-branes can affect the extent of diffusion by trapping the ionized form on one side In the stomach and kidney, where large pH gradients exist (or can be induced) with respect to plasma, this phenomenon can have therapeutic implications to prevent absorption and enhance clearance

100%

80%

60%

40%

20%

0%

13% protein bound

73% protein bound

95% protein bound

Time (minutes)

Fig 38.1 Removal of toxins via HD decreases with

greater degrees of protein binding Comparison of removal

of three uremic toxins (p-cresyl glucuronide, 13% protein

bound; indole-3-acetic acid, 73% protein bound; and

p-cre-syl sulfate, 95% protein bound) during a single HD session averaged over 10 patients Blood flow rates were 300 mL/ min, dialysate flow rates were 700 mL/min, and dialyzer urea clearances varied (Modified from King et al [ 9 ])

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