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The protein binds in a sequence specific manner to the CaMV 35S promoter which is down regulated when ABZ1 is coexpressed.. In the present work, a small basic leucine zipper bZIP transcri

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Functional dissection of a small anaerobically induced bZIP

transcription factor from tomato

Simone Sell and Reinhard Hehl

Institut fu¨r Genetik, Technische Universita¨t Braunschweig, Germany

A small anaerobically induced tomato transcription factor

was isolated from a subtractive library This factor,

desig-nated ABZ1 (anaerobic basic leucine zipper), is

anaerobi-cally induced in fruits, leaves and roots and encodes a

nuclear localized protein ABZ1 shares close structural and

sequence homology with the S-family of small basic leucine

zipper (bZIP) transcription factors that are implicated in

stress response Nuclear localization of ABZ1 is mediated by

the basic region and occurs under normoxic conditions

ABZ1 binds to G-box-like target sites as a dimer Binding

can be abolished by heterodimerization with a truncated

protein retaining the leucine zipper but lacking the DNA binding domain The protein binds in a sequence specific manner to the CaMV 35S promoter which is down regulated when ABZ1 is coexpressed This correlates with the anaer-obic down regulation of the 35S promoter in tomato and tobacco These results may suggest that small bZIP proteins are involved in the negative regulation of gene expression under anaerobic conditions

Keywords: anaerobiosis; bZIP; DNA binding; Lycopersicon esculentum; transcription factor

Plant survival under adverse environmental situations is

largely dependent on their adaptation strategies

Anaero-biosis or low oxygen conditions occur when plants are

subjected to flooding or to waterlogging of the soil Under

these conditions oxygen is rapidly consumed by

micro-organisms and plant roots [1] Plants react to these

conditions with a variety of responses To compensate the

decrease in energy production and the lack of NADH

regeneration, the rate of glycolysis is increased and

fermen-tative pathways are induced [1] Furthermore, plants can

respond to flooding with the induction of aerenchyma in the

root cortex and hyponastic growth to push their vital organs

above water level [2,3]

The reactions of plants towards a low oxygen

environ-ment entail a significant reprogramming of gene expression

which comprises transcriptional induction and selective

translation of mRNAs for anaerobic proteins [4] Plants

probably sense the lack of oxygen as an electron acceptor in

the mitochondria Mitochondria are implicated in an early

response because they release calcium to the cytosol in

response to anaerobiosis [5] The complete signal

transduc-tion pathway has yet to be elucidated Recent data suggest that O2deprivation stimulates a G-protein signal transduc-tion pathway that results in the inductransduc-tion of alcohol dehydrogenase (ADH) expression [6] Other components of the signal transduction pathway may comprise 14-3-3 proteins, calcium dependent kinases and several transcrip-tion factors [7–9] ADH, one of the most extensively studied genes that is induced during oxygen deprivation, is probably induced by the transcription factor AtMYB2 in Arabidopsis thaliana[10]

A comprehensive analysis of low oxygen regulated gene expression was recently reported for A thaliana [11] In a microarray containing 3500 cDNA clones, 210 differentially expressed genes were identified Among these were 21 nonredundant down regulated genes In contrast to tran-scriptional induction and post-trantran-scriptional regulation, little is known about low oxygen mediated down regulation

of gene expression

In the present work, a small basic leucine zipper (bZIP) transcription factor (TF) designated ABZ1, was isolated from a tomato cDNA library enriched for anaerobically induced genes This TF was studied in detail In addition to binding site specificity, nuclear localization, identification of DNA– and protein–protein binding domains it is shown that efficient DNA binding of a heterodimer requires two DNA binding domains in the interacting proteins The putative role of ABZ1 in the anaerobic response pathway is discussed

Materials and methods Tomato cDNA library construction and screening

A cDNA library from tomato, Lycopersicon esculentum cv Micro-Tom [12], was generated in plasmid pSport1 using the Invitrogen (Karlsruhe, Germany) SuperScriptTM Plas-mid System with Gateway Technology for cDNA

Correspondence to R Hehl, Institut fu¨r Genetik Technische

Universita¨t Braunschweig Spielmannstr 7, D-38106 Braunschweig,

Germany Fax: +49 531 391 5765, Tel.: +49 531 391 5772,

E-mail: R.Hehl@tu-braunschweig.de

Abbreviations: ADH, alcohol dehydrogenase; as-1, activation

sequence-1; bZIP, basic leucine zipper; DAPI,

4¢-6-diamidino-2-phenylindole; EMSA, electrophoretic mobility shift assay; GUS,

b-glucuronidase; LUC, luciferase; NLS, nuclear localization signal;

RBSS, random binding site selection.

Note: A website is available at http://www.tu-braunschweig.de/ifg/ag/

hehl

Note: The EMBL/GenBank accession number of ABZ1 is AJ715788.

(Received 9 July 2004, revised 30 September 2004,

accepted 4 October 2004)

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Synthesis and Cloning according to the protocol of the

supplier Poly(A)+ RNA (5 lg) isolated from fruits, roots,

leaves, and stems of anaerobically induced tomato plants

was employed for cDNA synthesis The plants were grown

in a greenhouse and were  3 months old Anaerobic

incubations were carried out in an airtight glass container

(Merck, Darmstadt, Germany) together with Anaerocult A

(Merck) for 20 h in a light chamber (12 : 12 h light/

darkness) Screening of the library and all other

recombin-ant DNA work was done according to standard protocols

[13] Sequence analysis of cDNA clones and other in vitro

constructs used in this work was performed by Seqlab

Company, Go¨ttingen, Germany The sequences were

ana-lysed for subcellular localization signals using PSORT at

http://psort.nibb.ac.jp/form.html Sequence comparisons

and alignments were performed at http://www.ncbi.nlm

nih.gov/BLAST and http://www.ch.embnet.org/software/

ClustalW.html The phylogenetic tree was generated using

CLUSTALX1.81 [14]

RNA isolation and Northern blot hybridizations

Total RNA was isolated according to a previously

published procedure [15] To isolate poly(A)+ RNA,

1 mg total RNA was used with the OligotexTM mRNA

Midi Kit (Qiagen, Hilden, Germany) according to the

manufacturer’s protocol Northern blots were performed

according to standard protocols [13] Total RNA (10 lg)

was used for RNA gel electrophoresis and radioactive

probes were generated using the HexaLabelTM DNA

Labeling Kit from MBI Fermentas (St Leon-Rot,

Germany)

Recombinant protein production and purification

For the expression in and purification of recombinant

proteins from Escherichia coli the QIAexpressionistTM

system from Qiagen was used The ABZ1 coding region

and two truncated derivatives from ABZ1 were PCR

amplified from a full size cDNA clone using the following

primer pairs Full size, ABZ1(1–138): 5¢-TATAGGA

TCCATGTCACCTTTAAGGCAGAG-3¢ and 5¢-ATAT

N-ter-minal deletion, ABZ1(47–138): 5¢-TATGGATCCATGC

TTCTGCAAGATTTGACAGG-3¢ and 5¢-ATATCCC

deletion, ABZ1(1–100): 5¢-TATAGGATCCATGTCACC

TTTAAGGCAGAG-3¢ and 5¢-ATACCCGGGTTATAA

ATACCTGAGCCTATCAGTC-3¢

The BamHI and SmaI sites within the primers

(under-lined) were used to directionally clone the amplified DNA

fragments into plasmid pQE-30 Prior to this, the amplified

DNA fragments were cloned into pCR2.1 (Invitrogen)

and sequenced Recombinant pQE-30 plasmids were

transformed together with the repressor plasmid pREP4

(Qiagen) in BL21-CodonPlus(DE3)-RIL E coli cells

(Stratagene, Amsterdam, the Netherlands) Induction of

protein expression and purification over Ni-nitrilotriacetic

acid columns were performed according to The

QIAex-pressionistTM manual Because the recombinant proteins

were mainly localized in the insoluble fraction, a previously

reported method that includes steps for de- and re-naturing

of the protein was employed [16] Protein concentrations were determined according to Bradford [17]

Electrophoretic mobility shift assays and random binding site selection

Electrophoretic mobility shift assays (EMSA) were carried out according to Ausubel et al [18] The four probes used for EMSA, RBSS1, 1.1, 5 and 6.1 are shown in Table 1 These probes were used because they represent different classes of binding sites RBSS1-Mu, containing a mutation

in the ACGT core sequence (GGTTGATTAGGGAA), was used as a nonspecific competitor All fragments are bordered by primer binding sites 5¢-CAGGTCAGT TCAGCGGATCCTGTCG-3¢ and 5¢-GCTGCAGTTG CACTGAATTCGCCTC-3¢ that were also used for PCR amplifications during the random binding site selection (RBSS) assay Random binding site selection was per-formed according to Ausubel et al [18] Oligonucleotides consisted of five random nucleotides 5¢ and 3¢ of the ACGT core sequence bordered by the above mentioned primer binding sites Oligonucleotides were amplified in the pres-ence of [32P]dCTP[aP] and incubated with recombinant ABZ1 After electrophoretic separation the bound oligo-nucleotides were eluted from the gel and subjected to another round of PCR amplification, ABZ1 binding, and EMSA Following five rounds of selection the amplified fragments were cloned into pCR2.1 and sequenced Another fragment used for EMSA was a 100 bp fragment from the CaMV 35S promoter that was amplified

by PCR using the primers 5¢-TATGTCGACCGAG GAACATAGTGGAAAAAG-3¢ and 5¢-ATAGTCGACT GGGATTGTGCGTCATCCCTT-3¢

Fragments for EMSA were amplified by PCR from recombinant pCR2.1 (RBSS1, 1.1, 5 6.1, and RBSS1-Mu) and pRT103-GUS (b-glucuronidase) [19] in the presence of [32P]dCTP[aP] Binding reactions were carried out in 15 lL

10 mMTris/HCl pH 7.5; 40 mMNaCl; 1 mMEDTA; 4% (v/v) glycerol; 10 mM 2-mercaptoethanol; 10 mM dithio-threitol; 5 mMphenylmethanesulfonyl fluoride; 2 lg/15 lL poly(dI-dC) [20] for 30 min at room temperature The amounts of recombinant protein, radioactively labelled

Table 1 Sequences obtained from a random binding site selection (RBSS) assay with ABZ1 RBSS1, 1.1, 5 and 6.1 are among the 17 selected binding sites Nucleotide frequency at each position is shown relative to the center of the palindromic core K ¼ G/T, N ¼ A/C/G/

T Below the sequences the frequency of the nucleotides A, C, G and T

at each position of the 17 selected binding sites is shown A consensus sequence was derived from these frequencies.

–5 )4 )3 )2 )1 Core +1 +2 +3 +4 +5

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fragment and competitor DNA is given in the relevant

figure legends After addition of 3 lL nondenaturing 5·

loading dye [50 mM EDTA pH 8.0; 50 mM Tris/HCl

pH 8.0; 50% (v/v) glycerol; 12.5 mg/10 mL

bromphenol-blue; 12.5 mg/10 mL xylencyanol] the binding assay was

loaded on a native polyacrylamide gel (5–9%) After

electrophoresis in 1· Tris/glycine the gel was dried under

vacuum and exposed to X-ray films

Nuclear localization assays

Plasmid constructs for the analysis of nuclear localization

were generated by fusing full size ABZ1 and truncated

derivatives of ABZ1 in-frame upstream to the amino

terminal end of the uidA gene in pRT103-GUS [19] The

ABZ1 coding region and three truncated derivatives from

ABZ1 were PCR amplified from a full size cDNA clone

using the following primer pairs Abz1(1–138): 5¢-TA

5¢-ATATCCATGGAAAATTTAAACAATCCTGATG-3¢

GCAGAG-3¢ and 5¢-ATATCCATGGGCTTCTTCATC

CTCGATCGC-3¢ Abz1(1–24): 5¢-TATACTCGAGAT

GTCACCTTTAAGGCAGAG-3¢ and 5¢-ATATCCATG

GTCTCATCCATTCCTGCATAC-3¢ Abz1(45–138):

5¢-TATACTCGAGATGCAGAAGCTTCTGCAAGATTT

GAC-3¢ and 5¢-ATATCCATGGAAAATTTAAACAA

TCCTGATG-3¢

The XhoI and NcoI sites within the primers (underlined)

were used to directionally clone the amplified DNA

fragments into plasmid pRT103-GUS The resulting clones

were subsequently sequenced

Layers of onion epidermal cells were placed on

Mur-ashige–Skoog media containing 3% (w/v) sucrose and

transformed by particle bombardment with recombinant

ABZ1-GUS constructs Loading of the gold particles was

performed according to the CaCl2/spermidin protocol [21]

Particle bombardment of epidermal cell layers was

per-formed with 600–700 p.s.i using the Du Pont PDS-1000

particle delivery system [22] After bombardment the tissue

was incubated at 24C for 24 h in a light chamber

(12 : 12 h light/darkness) The histochemical GUS assay

was performed by incubating the tissue in 1 lgÆmL)1

5-bromo-4-chloro-3-indolyl-b-glucuronic acid (X-Gluc) in

50 mM NaPO4 pH 7.0; 1 mM EDTA; 0.1% (v/v) Triton

X-100; 1 mMK-ferrocyanid; 1 mMK-ferricyanid for 4 h at

37C [23] For microscopy, tissues were transferred into

50 mM NaPO4 pH 7.0 For staining of the nuclei, tissues

were treated by adding 1 lgÆmL)1

4¢-6-diamidino-2-phen-ylindole (DAPI) and incubated for 15 min at room

temperature Light microscopy was carried out with a

fluorescent microscope (Axioplan 2, Zeiss, Jena, Germany)

using a 360–370 nm filter for DAPI stained tissue

Transient gene expression analysis in tobacco and

tomato leaves

For transient gene expression analysis four different effector

plasmids were constructed

All constructs are based on plasmid pVKH-35S-pA1

(kindly provided by D Großkopf,

Max-Delbru¨ck-Laboratorium, Ko¨ln, Germany) pVKH-35S-pA1 harbours

a CaMV 35S promoter and a poly(A)+ signal separated by

a cloning linker The coding region of ABZ1 was released with BamHI and SmaI from a recombinant pCR2.1 plasmid that harboured the complete ABZ1 coding region (see above) This fragment was subcloned into pVKH-35S-pA1 which was digested with BamHI and HindIII in which the HindIII site has been filled in This resulted in effector construct designated pVKH-35S-ABZ1-pA1

To generate pVKH-35S-AD-ABZ1-pA1 the activation domain of GAL4 was amplified from pGADT7-Rec (Clon-tech, Heidelberg, Germany) The following primers were used to amplify the activation domain: 5¢-TATAGGATCC ATGGCCAATTTTAATCAAAGTGGGA-3¢ and 5¢-AT ATGGATCCCTCTTTTTTTGGGTTTGGTGGGGT-3¢ The amplified fragment was cut with BamHI (restriction site is underlined in the primers) and cloned into BamHI digested pVKH-35S-ABZ1-pA1 The orientation of the insert and the integrity of the construct was analysed by restriction digest and sequencing

The two effector plasmids pVKH-C1-ABZ1-pA1 and pVKH-C1-AD-ABZ1-pA1 were generated by replacing the 35S promoter with the C1 promoter from the sugar beet cab11gene The 1097 bp long C1 promoter was released with HindIII and BamHI from plasmid pC1L-1097 (kindly provided by D Stahl, Planta GmbH, Einbeck, Germany) After HindIII digestion, the ends were filled in so that the released fragment harbours one blunt and one BamHI end This allowed the directional cloning of the C1 promoter into pVKH-35S-ABZ1-pA1 and pVKH-35S-AD-ABZ1-pA1 from which the 35S promoter was released with SacI and BamHI and in which the SacI site was filled in to generate a blunt end

As a reporter, a 35S-uidA construct was generated by removing the TATA box from plasmid pBT10-TATA-GUS [24] with NcoI and PstI and replacing it with a 500 bp NcoI/PstI CaMV 35S promoter fragment The resulting plasmid is designated pBT10-35S-GUS

For transformation controls, a luciferase gene was used that was either expressed from the 35S promoter in pRT101-LUC [19] or from the C1 promoter in pC1L-1097 For transformation, leaf discs with a diameter of 4 cm were cut from tobacco leaves and placed on wet 3MM Whatman paper Equimolar amounts of effector, reporter and control plasmids were loaded onto gold particles according to standard protocols [21] Particle bombardment was performed with 1100 p.s.i using the Du Pont PDS-1000 particle delivery system [22] After bombardment the tissue was incubated at 24C for 24 h in a light chamber (12 : 12 h light/darkness)

For protein extraction 0.3 g of tissue was homogenized with liquid nitrogen and by adding of 100 lL extraction buffer (0.1MNaH2PO4pH 7.8; 1 mMdithiothreitol) After centrifugation for 10 min with 25 500 g at 4C the supernatant was used for quantitative GUS and luciferase assays Protein concentrations were determined according

to Bradford [17] The determination of GUS activity was performed according to Jefferson & Jefferson et al [25,26] Four hundred and fifty microliters of GUS-reaction buffer [1 mM 4-methyl-umbelliferyl-b-D-glucuronide;

50 mM NaPO4 pH 7.0; 10 mMEDTA; 0.1% (v/v) Triton X-100; 0.1% (v/v) N-laurylsarcosine; 10 m

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2-mercapto-ethanol] were prewarmed to 37C and 50 lL protein

extract was added to start the reaction A blank value was

determined by transferring 50 lL of the reaction after 1 min

into 950 lL stop-buffer (0.2M Na2CO3) Additional

ali-quots were transferred into stop-buffer after 20, 40 and

60 min, respectively The extinction generated by the

reaction product 4-MU was measured in a spectral

photometer (Kontron Instruments, Eching, Germany,

SFM 25; excitation 365 nm; emission 455 nm) to determine

the relative fluorescence units of the generated 4-MU per

min and lg protein These values were corrected with the

values obtained for the transformation control plasmid

expressing the luciferase gene [27] For luciferase assays,

50 lL protein extract was transferred to 350 lL luciferase

buffer (25 mM glycylglycine; 15 mM MgSO4; 1 mM ATP

pH 7.8) After injecting 150 lL substrate solution (0.2 mM

luciferin in 25 mMgycylglycine pH 7.8) the emitted photons

were measured in a luminometer in a time interval of 10 s

(Berthold Lumat 9501; Bad Wildbad, Germany)

The determination of the relative GUS activity using the

luciferase values were performed as described previously

[24,28] The resulting values were used to display the GUS

activity of the different transformations relative to the GUS

activity obtained without effector plasmids which was set to

100% (see below)

For the determination of the relative expression strength

of the CaMV 35S promoter under aerobic and anaerobic

conditions in tobacco and tomato, a previously reported

approach was employed [29] As a reporter a 35S-uidA

construct was generated by removing the TATA box from

plasmid pBT10-TATA-GUS [24] with NcoI and PstI and

replacing it with a 500 bp NcoI/PstI CaMV 35S promoter

fragment The resulting plasmid is designated

pBT10-35S-GUS After bombardment of leaf discs with equimolar

amounts of pBT10-35S-GUS and pRT101-LUC [19], two

of the leaf discs from the same bombardment were incubated aerobically and the other two were incubated anaerobically in an airtight glass container (Merck) together with Anaerocult A (Merck) Incubation was carried out for

24 h in a light chamber (12 : 12 h light/darkness) Luci-ferase activity, b-glucuronidase activity, and the determin-ation of the relative b-glucuronidase activity were performed as described [29]

Results ABZ1 belongs to a family of small bZIP transcription factors and is anaerobically induced in fruits, roots, and leaves

Suppression subtractive hybridization was employed for the isolation of cDNA fragments for anaerobically induced genes from tomato cv Micro-Tom (S Sell & R Hehl, unpublished observations) A full size clone was isolated for

a cDNA fragment that is homologous to bZIP transcription factors The cDNA is 1216 base pairs long, which includes a poly(A) tail of 20 base pairs Figure 1 shows the cDNA that contains a 596 bp leader encoding a short 30 amino acid long peptide reminiscent of upstream open reading frames found in other TFs [30,31] The 596 bp leader is followed by

414 bp coding region and 186 bp 3¢ untranslated sequence The 414 bp coding region translates into a 138 amino acids long protein with a proposed molecular mass of 15.4 kDa Figure 1 shows that the protein harbours a basic region followed by a leucin zipper consisting of five leucines and one isoleucine that are spaced exactly by six amino acids The basic region also harbours a putative nuclear localiza-tion signal (see below) The gene for the small bZIP protein from tomato was designated ABZ1 for anaerobic basic leucine bZIP

Fig 1 cDNA sequence and deduced amino

acid sequence of the ABZ1 gene The138 amino

acid long sequence of ABZ1 (nucleotide

posi-tions 597–1010) harbours a basic leucine

zip-per domain (bold) that contains a putative

bipartite nuclear localization signal (double

underlined) The single amino acids that are

part of the leucine zipper are underlined The

30 amino acid long sequence encoded by the

upstream open reading frame (nucleotide

positions 358–447) harbours several amino

acids (bold) that are conserved in other

up-stream open reading frames.

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To investigate the spatial expression of ABZ1, RNA blot

hybridizations were carried out Total RNA from

aerobi-cally and anaerobiaerobi-cally treated organs from tomato was

hybridized with the ABZ1 cDNA fragment isolated in the

differential screen for anaerobically induced genes Figure 2

shows that the gene is anaerobically induced in fruits, leaves,

and roots of tomato The ubiquitous nature of the anaerobic

induction of ABZ1 may suggest a more general role in

regulating anaerobic gene expression

Phylogenetic analysis using the basic and leucine zipper

domains of 16 bZIP transcription factors shown in Fig 3

indicates that ABZ1 is most closely related to BZI-4 from

tobacco [32], and belongs to a family of small bZIP proteins

that are often induced upon environmental stress [31] For

example, maize LIP15 and rice LIP19 are low temperature

induced bZIP transcription factors that share 68.9%

sequence identity at the amino acid level [33,34] BZI-4

from tobacco is transcribed specifically in the stamen, the

petals and the pistils of the tobacco flower [32]

The basic domain confers nuclear localization of ABZ1

For gene expression regulation ABZ1 needs to be imported

into the nucleus Using bioinformatic tools it was found that

ABZ1 harbours a putative bipartite nuclear localization

signal (NLS) in its basic region between amino acids 25 and

44 (Fig 1) To determine whether this region harbours a

functional NLS, nuclear localization was investigated with

fusion proteins using the b-glucuronidase (uidA) reporter

gene Fusion constructs were made with the whole 138

amino acid long protein, with the 24 and 44 amino terminal

and 94 carboxy terminal amino acids, respectively These

fusion constructs were transformed by particle

bombard-ment into onion epidermal cells Figure 4 shows that the

majority of the GUS protein that is fused with the complete

138 or the amino terminal 44 amino acids of ABZ1 localizes

to the nucleus while the GUS protein alone or fused either

with the 24 amino terminal or with the 94 carboxy terminal

amino acids of ABZ1 does not localize to the nucleus This

indicates that ABZ1 harbours the signal for nuclear

localization and that a functional NLS is localized within

the basic region between amino acids 25 and 44 Further-more, nuclear localization was achieved under aerobic conditions

ABZ1 binding specificity and dimer formation Transcription factors of the bZIP family are known to bind

to G-box like sequences [35] To investigate the binding specificity of ABZ1, the protein was expressed in E coli as a His-tag fusion protein The purified protein was employed

in a binding site selection experiment in which 17 putative binding sites were identified Table 1 shows the sequence of four binding sites and the frequency of the nucleotides at each position of the 17 selected binding sites Figure 5A shows EMSA for the four individual binding sites RBSS1, 1.1, 5 and 6.1 (Table 1) These four sites are efficiently and specifically bound by ABZ1 while the sequence GGTTGATTAGGGAA that harbours a mutation in the

Fig 2 Anaerobiosis specific expression of ABZ1, in tomato Total

RNA from fruits (lanes 1 and 2), leaves (lanes 3 and 4), and roots (lanes

5 and 6) that were either prepared from aerobic organs (lanes 1, 3, and

5) or anaerobically incubated organs (lanes 2, 4, and 6), were

hybrid-ized with a cDNA fragment from the ABZ1 gene A single 1.2 kb

transcript hybridizes with the probe Staining of the gels prior to

blotting indicates equal loading of the RNA.

Fig 3 Phylogenetic relationship of ABZ1 with other bZIP proteins A phylogenetic tree was constructed by the neighbor joining method with the basic leucine zipper region of 16 different bZIP proteins Zm, Zea mays; Os, Oryza sativa; Nt, Nicotiana tabacum; Le, Lycopersicon esculentum; Am, Antirrhinum majus; Pc, Petroselinum crispus; At, Arabidopsis thaliana The bZIP proteins compared are BZI-4, BZI-3, and BZI-2 [32], tbz17 [53], bZIP911 and bZIP910 [30], CPRF6 [54], mLIP15 [33], LIP19 [34], BZI-1 [55] The five most similar Arabidopsis proteins were also included and the Arabidopsis genome identification number provided At3g62420 corresponds to AtbZIP53, At1g75390 to AtbZIP44, At2g18160 to AtbZIP02, and At4g34590 to AtbZIP11 [31] ABZ1 is underlined The scale represents the frequency of amino acid changes Bootstrap values are indicated.

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G-box core sequence (RBSS1-Mu) and was used as an

unspecific competitor in EMSAs is not bound by ABZ1

(Fig 5A; u Cmp) EMSAs with RBSS1 were subsequently

used to analyse specific binding conditions

To confirm that the DNA binding domain resides in the

basic region, an N-terminally deleted protein was expressed

in E coli The deleted protein comprises amino acids 47–

138 Figure 5B shows that the wild type ABZ1 binds

efficiently to the RBSS1 sequence while the amino

termin-ally deleted protein does not bind This shows that the

binding domain of ABZ1 resides in the amino terminal 46

amino acids

Because both proteins harbour the leucine zipper domain,

it was analysed if they interact with each other If interaction

of the full size and the amino terminally deleted protein leads

to a heterodimer that binds DNA, a faster migrating

complex would be expected Surprisingly, addition of the

truncated ABZ1 protein abolishs binding of full size ABZ1 in

a concentration dependent manner (Fig 5B) This indicates

that in vitro binding of a dimer requires the presence of a

DNA binding domain in each interacting protein

This was further investigated using a carboxy terminal

deletion of ABZ1 This protein harbours the first 100 amino

acids including basic and leucine zipper domains Figure 5C

shows that binding of this protein yields a faster migrating

complex (C2) compared to the full size ABZ1 (C1) When

both proteins are added in equimolar concentrations a third

complex is observed that shows an intermediate migrating

behaviour (Fig 5C; C1+2) This complex is interpreted to

be caused by heterodimer formation between full size ABZ1

and the carboxy terminally deleted ABZ1

To summarize, ABZ1 binds to RBSS1 as a dimer and

efficient DNA binding requires a DNA binding domain in

both interacting proteins This result may have important

implications for the regulatory properties of small bZIP

transcription factors

ABZ1 binds to the CaMV 35S promoter which is

anaerobically down regulated in tobacco and tomato

One well known target of bZIP transcription factors is the

CaMV 35S promoter [36] Figure 6A,B shows that

recom-binant ABZ1 binds to a 100 bp fragment from the CaMV

35S promoter which harbours three potential binding sites

for ABZ1 One of the three putative binding sites within this fragment is the activation sequence-1 (as-1) between positions )65 and )85 that consists of two imperfect palindromes, with the palindromic centers spaced by 12 bp and which is known to be bound by different tobacco bZIP TFs [37] The random binding site selection experiment indicates a high similarity between RBSS6.1 and the second imperfect palindrome of as-1

EMSA analysis with recombinant ABZ1 revealed three shifted complexes of which two complexes can be com-pletely competed with RBSS1 (Fig 6A) The three shifted complexes observed may be due to differential occupation

of ABZ1 binding sites and may represent different numbers

of ABZ1 proteins bound to the promoter fragment These results show that ABZ1 can also bind to the CaMV 35S promoter

The binding of the anaerobically induced ABZ1 tran-scription factor to the CaMV 35S promoter indicates that the 35S promoter may be regulated under anaerobic conditions To investigate this proposal, transient gene expression analyses were performed by transforming a CaMV 35S promoter uidA reporter gene construct into tobacco and tomato leaves Subsequent to particle bom-bardment, leaves were incubated under aerobic and anaer-obic conditions followed by a quantitative GUS assay As shown in Fig 6C, in both host tissues, expression of the 35S promoter is significantly lower under anaerobiosis when compared with expression under aerobic conditions In tobacco, anaerobic expression is only 14% relative to aerobic expression while in tomato the difference between anaerobic and aerobic expression is less stringent (52%, Fig 6C)

ABZ1 down regulates the CaMV 35S promoter

in a transient gene expression assay The effect of ABZ1 on gene expression of the CaMV 35S promoter was analysed with transient expression assays conducted by coexpressing the ABZ1 protein together with the CaMV 35S driven uidA (GUS) gene in tobacco leaves

As a transformation standard, a luciferase gene under the control of the sugar beet cab11 promoter was employed This promoter does not harbour G-box binding sites and confers reporter gene expression in tobacco leaves (D Stahl,

Fig 4 The basic region of ABZ1 is required for nuclear localization Fusion gene constructs expressing parts of or the whole ABZ1 protein fused to the b-glucuronidase (uidA) reporter gene were transformed by particle bombardment into onion epidermal cells As indicated, the constructs express amino acids 1–24, 1–44, 1–138, and 45–138 from the ABZ1 protein fused in-frame with the uidA gene Transformed cells were subjected to histochemical GUS staining and to a DAPI staining of the nucleus.

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personal communication) Figure 7 shows that the

coex-pression of ABZ1 with the 35S-uidA construct leads to

down regulation of GUS expression compared to the

35S-uidA construct alone (compare 35S-35S-uidA with 35S-ABZ1/

35S-uidA, Fig 7A) Expression of the 35S promoter is

about 40% reduced in the presence of ABZ1 than without

When a fusion construct between ABZ1 and the activation

domain of GAL4 is coexpressed with the 35S-uidA

construct, expression is higher than observed with ABZ1

(compare 35S-ABZ1/35S-uidA with

35S-AD-ABZ1/35S-uidA, Fig 7A)

To minimize possible autoregulatory effects of ABZ1 on its own expression this experiment was repeated by expres-sing ABZ1 with the sugar beet cab11 promoter which is void

of putative ABZ1 binding sites Figure 7B shows that similar results were obtained compared to ABZ1 expression with the 35S promoter Coexpression of ABZ1 with the 35S-uidA construct leads to down regulation of GUS expression compared to the uidA construct alone (compare 35S-uidA with C1-ABZ1/35S-35S-uidA, Fig 7B) Expression of the 35S promoter is again about 40% reduced in the presence of ABZ1 than without When a fusion construct between

A

Fig 5 ABZ1 binding specificity and dimer formation Electrophoretic mobility shift assays with recombinant full size ABZ1(1–138) and two truncated derivatives harbouring amino acids 47–138 and 1–100, respectively Shifted complexes (C) and free probe (P) are indicated (A) Four sequences (probes) derived from a random binding site selection assay (Table 1) were radioactively labelled, and 0.1 ng (4 · 10 3 c.p.m.) were either incubated with (+) or without (–) ABZ1 As indicated (+/–) specific (RBSS1) or unspecific (u Cmp) competitor was added in a 1 · 10 5 molar excess and separated on a nondenaturing polyacrylamide gel (10%) (B) Increasing amounts of truncated derivative of ABZ1 harbouring amino acids 47–138 interferes with DNA binding of full size ABZ1 One microgram of protein (+) and increasing amounts of truncated ABZ1 (1.5 lg, 2.1 lg, and 2.5 lg, designated by the elongated triangle) was incubated with 0.05 ng (2 · 10 3 c.p.m.) radioactively labeled RBSS1 fragment (P) and separated on a nondenaturing polyacrylamide gel (9%) The complex C1 decreases when truncated ABZ1 lacking the first 46 amino acids is incubated in increasing concentrations together with full size ABZ1 (C) Dimer formation between full size ABZ1 and a truncated derivative of ABZ1 harbouring amino acids 1–100 One microgram of ABZ1 (+) and 770 ng truncated ABZ1 (+) was incubated with 0.1 ng (4 · 10 3 c.p.m.) radioactively labeled RBSS1 fragment and separated on a nondenaturing polyacrylamide gel (9%) A novel complex (C1+2) is observed when truncated and full size ABZ1 are incubated simultaneously with the radioactive probe.

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ABZ1 and the activation domain of GAL4 is coexpressed

with the 35S-uidA construct, expression is higher than

observed with ABZ1 (compare 35S-ABZ1/35S-uidA with

C1-AD-ABZ1/35S-uidA, Fig 7B)

In summary, these two independent sets of experiments

support the notion that the anaerobically induced ABZ1

transcription factor contributes to the anaerobic down

regulation of the 35S CaMV promoter

Discussion

Anaerobic gene expression regulation

The primary plant stress in flooded or compressed soils is

conferred by oxygen limitation that is most apparent in

below ground tissue Plants respond to oxygen limitation

with a significant reprogramming of gene expression These

responses usually permit a prolonged survival under these

adverse conditions Gene expression regulation involves

various mechanisms Many genes are induced by

transcription factors In Arabidopsis thaliana for example, this is achieved by the low oxygen induction of the AtMYB2 transcription factor which leads to the enhanced expression

of the ADH1 gene [10] The extent of post-transcriptional regulation is best illustrated when the limited number of anaerobic proteins detected is compared to the large number

of genes that are still transcribed under low oxygen conditions [4,11,38,39] It has long been observed that low oxygen conditions suppress the translation of the majority

of mRNAs and increase translation of a particular subset corresponding to anaerobic proteins This may be related to impaired ribosomal RNA transcription and ribosomal protein synthesis under oxygen deprivation [40–42] The analysis of ribosome loading patterns indicated that trans-lational control of anaerobic genes occurs at the initiation and postinitiation phases in a message-specific manner [43] Another post-transcriptional mechanism of low oxygen regulated gene expression is the increased splicing efficiency

of specific introns [44,45]

In the present study a small anaerobically induced bZIP transcription factor designated ABZ1 was identified from tomato ABZ1 binds to the CaMV 35S promoter (Fig 6A)

C

Fig 6 Binding of ABZ1 to the CaMV 35S promoter and down

regu-lation under anaerobic conditions (A) An electrophoretic mobility shift

assay with a radioactively labeled 100 bp fragment from the CaMV

35S promoter is shown Lanes 1–4 harbour the radioactive probe (P)

while in lanes 2–4, 500 ng recombinant ABZ1 was added to the probe

(0.3 ng, 2 · 10 3 c.p.m.) resulting in three shifted complexes (C1, C2,

and C3) Specific competition was achieved with a 4 · 10 3 molar excess

of fragment RBSS1 (lane 3) The unspecific competitor in which the

ACGT core sequence of fragment RBSS1 was altered to ATTA did

not compete for binding when added in a 4 · 10 3 molar excess (lane 4).

(B) The sequence of the 100 bp fragment from the 35S promoter used

for EMSA is shown Putative ABZ1 binding sites are underlined The

as-1 element between positions )65 and )85 is indicated (C)

Expres-sion of a 35S-uidA promoter reporter gene construct after transient

bombardment of tobacco and tomato leaves under aerobic and

anaerobic conditions The expression strength under anaerobic

con-ditions is displayed relative to the expression under aerobic concon-ditions

(100%) The mean values were derived from seven (tobacco) and six

(tomato) measurements.

Fig 7 Transient gene expression analysis using reporter and effector gene constructs in particle bombardments on tobacco leaves Reporter construct 35S-uidA harbours the b-glucuronidase gene under the control of the CaMV 35S promoter (A) Relative expression strength

of the 35S promoter in the presence and absence of effector constructs under the control of the 35S promoter Expression strength is shown relative to the 35S-uidA expression (100%) The mean value was derived from 10 uidA), 10 uidA + 35S-ABZ1), and 12 (35S-uidA + 35S-AD-ABZ1) measurements, respectively (B) Relative expression strength of the 35S promoter in the presence and absence of effector constructs under the control of the C1 promoter Expression strength is shown relative to the 35S-uidA expression (100%) The mean value was derived from eight (35S-uidA), seven (35S-uidA + C1-ABZ1), and eight (35S-uidA + C1-AD-ABZ1) measurements, respectively.

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The promoter activity is reduced under anaerobiosis in

tobacco and tomato (Fig 6C) Although many bZIP

transcription factors have been isolated from plants, their

role in gene expression regulation under low oxygen

conditions has not been analysed extensively Previously,

de Vetten & Ferl isolated a G-box binding protein from

maize, GBF1, which is anaerobically induced [46] The main

structural differences between GBF1 and ABZ1 are the size

(377 amino acids for GBF1 vs 138 for ABZ1) and a proline

rich region at the N terminus of GBF1 The proline rich

region of GBF1 may indicate that this protein is a

transcriptional activator [47] A second anaerobically

induced G-box binding factor from maize, mLIP15, is

structurally more similar to ABZ1 because it is 135 amino

acids long and also lacks a proline rich region at its N

terminus [33] Both maize G-box binding factors were

shown to interact with the maize ADH1 promoter, which is

anaerobically induced [33,46] It may be conceivable that in

maize GBF1 acts as a transcriptional activator while

expression of mLIP15 may modulate or repress anaerobic

expression by competing or interacting with GBF1 Small

bZIP proteins may be one of the components of the cellular

machinery that contribute to the low oxygen mediated

down regulation of gene expression

Functional dissection of ABZ1

The ABZ1 transcription factor isolated in this study was

extensively analysed using biochemical approaches

Although the basic and leucine zipper domain are often

assumed to be the DNA binding and dimerization domains,

the present study confirms this experimentally (Fig 5) The

nuclear localization signal resides within the basic domain

required for DNA binding Some bZIP factors are regulated

by a subcellular localization mechanism in response to

environmental cues For example nuclear import of the

parsley bZIP factor CPRF2 is light mediated [48]

Cyto-plasmatic retention of the bZIP factor RSG is mediated by a

14-3-3 protein which has been suggested to modulate the

endogenous amounts of gibberellins through the control of

a gibberellic acid biosynthetic enzyme [49] In the study

presented here no evidence for cytoplasmatic retention of

ABZ1 was found for the full size ABZ1 and the protein is

readily detected in the nucleus under aerobic conditions

(Fig 4)

Interestingly, the binding of ABZ1 to its target sequence

can be abolished with increasing amounts of a truncated

ABZ1 that lacks the DNA binding domain (Fig 5B)

Therefore, efficient DNA binding requires that the

dimeri-zation occurs with another bZIP factor harbouring a basic

DNA binding domain Whether heterodimerization of

ABZ1 to other bZIP factors occurs, has not been analysed

directly However, because its closest relative BZI-4

hetero-dimerizes with BZI-1 [32] it may be conceivable that ABZ1

can also form heterodimers Remarkably, no other bZIP

transcription factor was isolated in a yeast two hybrid screen

(S Sell & R Hehl, unpublished observations) This may

either relate to an insufficient number of primary clones or to

the fact that the mRNA used for constructing the prey library

was isolated from anaerobic tissue and may not contain

transcripts for other bZIP factors because their expression

may be down regulated under anaerobic conditions

Because ABZ1 is able to bind to the 35S promoter which

is down regulated under anaerobic conditions and in the presence of ABZ1 in cobombardment analyses, this may suggest that ABZ1 either competes with other bZIP factors for the same binding sites or that heterodimerization also down regulates target gene expression In mammalian systems heterodimer formation of a bZIP factor with another leucine zipper containing transcription factor results in down regulation of target gene expression [50]

To date several attempts to generate transgenic tomato or tobacco plants that overexpress ABZ1 have failed Reverse genetic approaches to analyse the role of small bZIP proteins in anaerobic gene expression may be more readily carried out in A thaliana

Therefore, a screen for A thaliana homologs was performed usingTAIR BLAST [51] ABZ1 is closely related

to the four bZIP transcription factors AtbZIP53 (At3g62420; 53% identity), AtbZIP44 (At1g75390; 42% identity), AtbZIP02 (At2g18160; 50% identity), and Atb-ZIP11 (At4g34590; 58% identity) Recently, data on AtbZIP02 and AtbZIP11 suggested that these small bZIP factors bind to the sequence ACTCAT and may act as transcriptional activators under hypoosmotic conditions [52] It may be very interesting to learn how small bZIP proteins are involved in transcriptional activation This may relate to the position of the cis-regulatory element in the promoter or to the presence of interacting proteins that contribute a transcription activation domain

Acknowledgements

This work was supported by a grant through the Forschungsschwer-punkt Agrarbiotechnologie des Landes Niedersachsen (VW-Vorab).

We are grateful to Ralf R Mendel for critical reading of the manuscript and to Robert Ha¨nsch for advice using the particle delivery system We would like to thank Jo¨rn Petersen for help with the phylogenetic analysis.

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