Giáo trình chất diện hoạt bề mặt và ứng dụng trong công nghiệp Surfactants for industrial applications

Alkyl polyethyleneglycol ether 13 phosphoric acid estersAlkyl phosphonic acids 13 Alkyl polyethylene glycol 13 ether carboxylic acidFatty acid condensates 13 fatty acid isethionates, met

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Nonionic and Anionic Emulsifiers, Copolymerizable Surfactants, Dispersing Agents and Defoamers

Division Functional Chemicals Exactly your chemistry.

Surfactants

Division Functional Chemicals

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Contents

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Alkyl polyethyleneglycol ether 13

phosphoric acid estersAlkyl phosphonic acids 13

Alkyl polyethylene glycol 13

ether carboxylic acidFatty acid condensates 13

(fatty acid isethionates, methyl taurides,sarkosin and sarkoside)

Alkyl benzene sulphonates, Ca-salts 13

Fluorine containing defoamers 16

Silicone containing defoamers 16

Silicone and fluorine-free defoamers 16

Surfactants from Clariant

Emulsifiers for emulsion 17

polymerization

®

What we offer for industrial customers 4

oxide block polymers

Fatty acid polyethyleneglycol esters 11

Fatty acid polyglycerol esters 11

Fatty acid polyglycerol 11

ester ethoxylates

Castor oil ethoxylates 11

Sorbitan ester ethoxylates 11

Alkyl ether sulphates 12

Alkyl aryl ether sulphates 12

Polyglycol ether sulphates 12

Sulphosuccinic acid esters 12

Fatty alkyl amine sulphosuccinamates 12

Alkyl phosphoric acid esters 12

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What we offer for industrial customers

Research and development

In addition to the product range we offerour customers comprehensive adviceand technical service Our applicationlaboratories assist you in developingmodern system solutions and help you toselect the products that are suitable for your applications

Our product range is constantly beingexpanded by intensive research and development work and is thus geared tothe requirements of our customers aswell as to optimization of the productionmethods

Quality and environment

Clariant’s Functional Chemicals Division

in Germany has established a quality management system in accordance with ISO 9001 in the production, rese-arch & development and marketing sectors All products are subject to strict quality control in our analytical department to ensure our high qualitystandard

To safeguard environmentally friendlyoperations the environment manage-ment system in accordance with the ecoaudit regulations (EEC 1836/93) was introduced at Gendorf/Burgkirchen (Germany), our largest production site

Clariant’s Division Functional

Chemi-cals is one of the world's leading

manufacturers of surfactants and

po-lyglycols The product range

encom-passes anionic, nonionic, cationic and

amphoteric surfactants These include

raw materials for detergents and

cleaners, cosmetics and special

pro-ducts for chemical and industrial

applications

This brochure presents a selection

of our products for chemical and

Production and sales

Our surfactants are manufactured at ourproduction sites in Gendorf/Burgkirchenand Wiesbaden (Germany), Tarragona(Spain), Charlotte (USA), Clear Lake(USA), Mexico City (Mexico), Coatza-coalcos (Mexico), Maracay (Venezuela),Sao Paulo (Brazil), Zarate (Argentina)and elsewhere, and are available world-wide through our sales organization

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Division Functional Chemicals in Tarragona (Spain).

Industrial Applications of Surfactants

Surfactants are used as wetting agents,

emulsifiers and dispersing agents

for different chemical and industrial

applications Clariant offers products for

the following fields:

■ Emulsifiers for emulsion polymerization

■ Dispersing agents for pigment

pre-parations, coatings, inks and paints

■ Wetting agents for hard surfaces,

ceramics, wood, plastics and metals

■ Emulsifiers for micro- and macro

emulsions of fats, hydrocarbons and

■ Surfactants for the building industry

■ Emulsifiers for bitumen emulsions

■ Auxiliaries for the sugar industry

We will gladly supply product samplesfrom our commercial range for thesepreliminary trials

Besides the existing range Clariantoffers smaller sample amounts ofnon-commercial products for labora-tory investigations These include nonionic emulsifiers based on alcoholethoxylates, which are synthesized inour development laboratory If requi-red, almost any alcohol can be reac-ted with the desired amount of ethyleneoxide and a sample provided

Our production know-how permits rapid scale-up of new products fromthe laboratory to the production stage.Development products are thus rapidly available commercially Wewill gladly advise you of what we can do for you

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The following product range provides

a selection of our products and containsnonionic and anionic surfactants used

as emulsifiers and wetting agents, and further more dispersing agents anddefoamers

New development products, which will extend our product range, are notyet included in this list

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Trade name Chemical name Active content Appearance (20°C) Cloud point (°C) HLB value

Alkyl ethoxylates

Genapol O 020 Oleyl alcohol ethoxylate with 2 EO ca 100 % liquid 35 – 38(2) ca 5

Genapol O 050 Oleyl alcohol ethoxylate with 5 EO ca 100 % liquid 67 – 69(2) ca 9

Genapol O 080 Oleyl alcohol ethoxylate with 8 EO ca 100 % liquid paste > 40(1) ca 11

79 – 81(2)

Genapol O 100 Oleyl alcohol ethoxylate with 10 EO ca 100 % paste > 75(1) ca 12

49 – 51(3)

Genapol O 150 Oleyl alcohol ethoxylate with 15 EO ca 100 % waxy 71 – 73(3) ca 13

Genapol O 200 Oleyl alcohol ethoxylate with 20 EO ca 100 % waxy 74 – 76(3) ca 15

Genapol O 300 Oleyl alcohol ethoxylate with 30 EO ca 100 % waxy – ca 17

Genapol OA 040 C14/ C15oxo alcohol ethoxylate with 4 EO ca 100 % liquid 51 +/- 1,5(2) ca 9

Genapol OA 070 C14/ C15oxo alcohol ethoxylate with 7 EO ca 100 % paste 72 – 74(2) ca 12

Genapol OA 080 C14/ C15oxo alcohol ethoxylate with 8 EO ca 100 % paste 76 – 80(2) ca 12

Genapol OA 089 C14/ C15oxo alcohol ethoxylate with 8 EO ca 90 % liquid 76 – 80(2)* ca 12

Genapol OX 050 C12/ C15oxo alcohol ethoxylate with 5 EO ca 100 % liquid 63 – 64,5(2) ca 10

Genapol OX 060 C12/ C15oxo alcohol ethoxylate with 6 EO ca 100 % liquid paste 64 – 67(2) ca 11

Genapol OX 070 C12/ C15oxo alcohol ethoxylate with 7 EO ca 100 % liquid paste ca 73(2) ca 12

Genapol OX 080 C12/ C15oxo alcohol ethoxylate with 8 EO ca 100 % paste 75 – 78(2) ca 13

Genapol OX 100 C12/ C15oxo alcohol ethoxylate with 10 EO ca 100 % paste 62 – 65(1) ca 14

Genapol OX 109 C12/ C15oxo alcohol ethoxylate with 10 EO ca 90 % liquid 62 – 65(1)* ca 14

„Alkyl ethoxylates“ to be continued on page 8

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Nonionic Surfactants

Product range

Alkyl ethoxylates continued from page 7

Genapol T 080 Tallow fatty alcohol ethoxylate with 8 EO ca 100 % waxy 83 – 85(2) ca 11Genapol T 110 Tallow fatty alcohol ethoxylate with 11 EO ca 100 % waxy 84 – 90(1) ca 13

60 – 63(3)

Genapol T 150 Tallow fatty alcohol ethoxylate with 15 EO ca 100 % waxy 71 – 73(3) ca 14Genapol T 200 Tallow fatty alcohol ethoxylate with 20 EO ca 100 % waxy 75 – 77(3) ca 15Genapol T 250 Tallow fatty alcohol ethoxylate with 25 EO ca 100 % waxy 77 – 79(3) ca 16Genapol T 250 p Tallow fatty alcohol ethoxylate with 25 EO ca 100 % powder 77 – 79(3) ca 16Genapol T 500 Tallow fatty alcohol ethoxylate with 50 EO ca 100 % waxy – ca 18Genapol T 500 p Tallow fatty alcohol ethoxylate with 50 EO ca 100 % powder – ca 18Genapol T 800 Tallow fatty alcohol ethoxylate with 80 EO ca 100 % waxy – ca 19Genapol T 800 p Tallow fatty alcohol ethoxylate with 80 EO ca 100 % powder – ca 19Genapol UD 030 C11oxo alcohol ethoxylate with 3 EO ca 100 % liquid 37 – 41(2) ca 9Genapol UD 050 C11oxo alcohol ethoxylate with 5 EO ca 100 % liquid 66 – 69(2) ca 11Genapol UD 079 C11oxo alcohol ethoxylate with 7 EO ca 90 % liquid 52 – 55(1)* ca 13Genapol UD 080 C11oxo alcohol ethoxylate with 8 EO ca 100 % liquid 62 – 65(1) ca 13Genapol UD 088 C11oxo alcohol ethoxylate with 8 EO ca 80 % liquid 62 – 65(1)* ca 13Genapol UD 110 C11oxo alcohol ethoxylate with 11 EO ca 100 % liquid paste 62 – 65(3) ca 15Genapol X 020 C13oxo alcohol ethoxylate with 2 EO ca 100 % liquid 25 – 30(2) ca 6Genapol X 050 C13oxo alcohol ethoxylate with 5 EO ca 100 % liquid 59 – 62(2) ca 10Genapol X 060 C13oxo alcohol ethoxylate with 6 EO ca 100 % liquid 64 – 66(2) ca 11Genapol X 080 C13oxo alcohol ethoxylate with 8 EO ca 100 % liquid > 45(1) ca 13

74 – 76(2)

Genapol X 089 C13oxo alcohol ethoxylate with 8 EO ca 90 % liquid > 45(1)* ca 13

74 – 76(2)*Genapol X 090 C13oxo alcohol ethoxylate with 9 EO ca 100 % liquid 62 – 65(1) ca 13Genapol X 158 C13oxo alcohol ethoxylate with 15 EO ca 80 % liquid – ca 15Genapol X 250 C13oxo alcohol ethoxylate with 25 EO ca 100 % waxy – ca 18Genapol X 307 C13oxo alcohol ethoxylate with 30 EO ca 70 % liquid – ca 17Genapol X 407 C13oxo alcohol ethoxylate with 40 EO ca 70 % liquid – ca 18Genapol X 1000 C13oxo alcohol ethoxylate with 100 EO ca 100 % solid – ca 19Genapol X 1003 C13oxo alcohol ethoxylate with 100 EO ca 35 % liquid – ca 19Genapol X 1005 C13oxo alcohol ethoxylate with 100 EO ca 50 % liquid – ca 19Genapol 1879 C13oxo alcohol ethoxylate ca 40 % liquid – ca 15Genapol 3214 C13oxo alcohol ethoxylate ca 25 % liquid – ca 18

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Nonylphenol ethoxylates

®Arkopal N 040 Nonylphenol ethoxylate with 4 EO ca 100 % liquid 36 – 38(2) ca 9

Arkopal N 060 Nonylphenol ethoxylate with 6 EO ca 100 % liquid 61 – 63(2) ca 11

76 – 78(2)

Arkopal N 130 Nonylphenol ethoxylate with 13 EO ca 100 % liquid paste 83 – 86(1) ca 14

Arkopal N 150 Nonylphenol ethoxylate with 15 EO ca 100 % paste 92 – 95(1) ca 15

61 – 63(3)

Arkopal N 200 Nonylphenol ethoxylate with 20 EO ca 100 % paste 70 – 73(3) ca 16

Arkopal N 208 Nonylphenol ethoxylate with 20 EO ca 80 % liquid 70 – 73(3)* ca 16

Arkopal N 230 Nonylphenol ethoxylate with 23 EO ca 100 % waxy 73 – 75(3) ca 16

Arkopal N 300 Nonylphenol ethoxylate with 30 EO ca 100 % waxy 76 – 78(3) ca 17

Arkopal N 1000 Nonylphenol ethoxylate with 100 EO ca 100 % waxy – ca 19

Tributylphenol ethoxylates

®Sapogenat T 060 Tributylphenol ethoxylate with 6 EO ca 100 % liquid 53 – 56(2) ca 10

Sapogenat T 080 Tributylphenol ethoxylate with 8 EO ca 100 % liquid 60 – 68(2) ca 11

Sapogenat T 139 Tributylphenol ethoxylate with 13 EO ca 90 % liquid 62 – 64(1)* ca 14

Sapogenat T 180 Tributylphenol ethoxylate with 18 EO ca 100 % waxy 61 – 64(3) ca 15

Sapogenat T 300 Tributylphenol ethoxylate with 30 EO ca 100 % waxy – ca 17

Sapogenat T 500 Tributylphenol ethoxylate with 50 EO ca 100 % waxy – ca 18

Tristyrylphenol ethoxylates

®Emulsogen TS 050 Tristyrylphenol ethoxylate with 5 EO ca 100 % liquid 23 – 27(2) ca 7

Emulsogen TS 100 Tristyrylphenol ethoxylate with 10 EO ca 100 % liquid 65 – 69(2) ca 10

Emulsogen TS 160 Tristyrylphenol ethoxylate with 16 EO ca 100 % liquid 58 – 62(1) ca 13

Emulsogen TS 200 Tristyrylphenol ethoxylate with 20 EO ca 100 % waxy 55 – 60(3) ca 14

Emulsogen TS 600 Tristyrylphenol ethoxylate with 60 EO ca 100 % waxy – ca 17

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Genapol EP 0244 Alcohol EO-PO adduct ca 100 % liquid ca 20(1)

Genapol EP 2424 Alcohol EO-PO adduct ca 100 % liquid 25 – 27(2)

(former name Genapol 3970)

Genapol EP 2464 Alcohol EO-PO adduct ca 100 % liquid 42 – 44(2)

Genapol EP 2544 Oxoalcohol EO-PO adduct ca 100 % liquid 31 – 33(2)

Genapol EP 2564 Oxoalcohol EO-PO adduct ca 100 % liquid 27,5 – 31(1)

Genapol PL 120 Alcohol EO-PO adduct ca 100 % liquid > 25(1)

31 – 34(2)

Ethylene oxide-propylene oxide block polymers

Emulsogen 4084 EO-PO block polymer with 60 % EO ca 100 % waxy 68 – 70(3) ca 12Genapol PF 10 EO-PO block polymer with 10 % EO ca 100 % liquid 34 – 37(2) ca 2Genapol PF 20 EO-PO block polymer with 20 % EO ca 100 % liquid 55 – 58(2) ca 4Genapol PF 40 EO-PO block polymer with 40 % EO ca 100 % liquid 66 – 69(2) ca 8Genapol PF 80 p EO-PO block polymer with 80 % EO ca 100 % powder 69 – 72(3) ca 16Genapol ED 3030 Ethylenediamine EO-PO block polymer ca 100 % liquid 52 – 55(2) ca 9

(former name Genapol B)

Genapol ED 3060 Ethylenediamine EO-PO block polymer ca 100 % liquid 27 – 30(2) ca 6

(former name Genapol PN 30)

End capped Alkylethoxylates

Genapol BE 2410 Lauryl ethoxylate with 10 EO,

butyl-end capped ca 100 % liquid 36 – 39(2)

Genapol BE 2805 Coconut fatty alkyl ethoxylate

with 5 EO, butyl-end capped ca 100 % liquid – Genapol BE 2810 Coconut fatty alkyl ethoxylate

with 10 EO, butyl-end capped ca 100 % liquid 39 – 42(2)

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Trade name Chemical name Active content Appearance (20°C)

Fatty acid polyethyleneglycol esters

®Genagen C 100 C12/ C14fatty acid polyglycol ester with 10 EO ca 100 % liquid

Genagen O 060 C16/ C18fatty acid polyglycol ester with 6 EO ca 100 % liquid

Genagen S 250 Stearic acid polyglycol ester with 25 EO ca 100 % waxy

Fatty acid polyglycerol esters

Emulsogen OG Diglycerol oleate ca 100 % liquid

Hostacerin DGI Diglycerol diisostearate ca 100 % liquid

Hostacerin DGMS Diglycerol monostearate ca 100 % pellets

Hostacerin TGI Polyglycerol diisostearate ca 100 % liquid

Fatty acid polyglycerol ester ethoxylates

Hostacerin DGSB Diglycerol distearate ethoxylated with 4 EO ca 100 % waxy

Hostacerin DGL Diglycerol laurate ethoxylated with 10 EO ca 100 % liquid

Castor oil ethoxylates

Emulsogen EL 200 Castor oil ethoxylate with 20 EO ca 100 % liquid

Emulsogen HCO 040 Hydrogenated castor oil ethoxylate with 40 EO ca 100 % paste

Emulsogen HCO 060 Hydrogenated castor oil ethoxylate with 60 EO ca 100 % paste

Emulsogen HCP 049 Hydrogenated castor oil ethoxylate with 40 EO ca 090 % liquid

Sorbitane ester ethoxylate

Emulsogen 4156 Lauroyl sorbitane ethoxylate with 20 EO ca 100 % liquid

Wax emulsifiers

Emulsogen P Alkylethoxylate ca 100 % paste

Emulsogen PN extra Mixture of different alkyl ethoxylates ca 100 % paste

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Anionic Surfactants

Product range

Trade name Chemical name Active content Appearance (20°C)

Secondary alkyl sulphonates (Secondary alkane sulphonates)

®Hostapur SAS 30 Secondary alkyl sulphonate, Na salt ca 30 % liquid

Hostapur SAS 60 Secondary alkyl sulphonate, Na salt ca 60 % paste

Hostapur SAS 93 Secondary alkyl sulphonate, Na salt ca 93 % waxy pellets

Olefin sulphonates

Hostapur OS liquid C14/ C16alpha-olefin sulphonate, Na salt ca 42 % liquid

Hostapur OSB C14/ C16alpha-olefin sulphonate, Na salt ca 90 % powder

Alkyl sulphates

Emulsogen EPA 1954 C12/ C14alkyl sulphate, Na salt ca 30 % liquid

Emulsogen LS C12alkyl sulphate, Na salt ca 15 % liquid

Alkyl ether sulphates

Emulsogen EPA 073 Alkyl ether sulphate with 7 EO, Na salt ca 28 % liquid

Emulsogen LCA 073 Alkyl ether sulphate with 7 EO, Na salt ca 28 % liquid

Emulsogen LA 083 Alkyl ether sulphate with 8 EO, Ammonium salt ca 30 % liquid

®Genapol LRO liquid C12/ C14alkyl ether sulphate with 2 EO, Na salt ca 27 % liquid

Genapol LRO paste C12/ C14alkyl ether sulphate with 2 EO, Na salt ca 68 % paste

Emulsogen ZRO liquid C12/ C14alkyl ether sulphate with 3 EO, Na salt ca 27 % liquid

Zeliquid LP 2 Lauryl ether sulphate with 3 EO, ammonium salt + organ solvent ca 50 % liquid

Alkyl aryl ether sulphates

®Hostapal BV conc Tributyl phenol ether sulphate with 7 EO, Na salt ca 50 % paste

Hostapal BV liquid Tributyl phenol ether sulphate with 7 EO, Na salt ca 17 % liquid

Polyglycol ether sulphates

Emulsogen PF 20 S Polyalkylene glycol ether sulphate, ammonium salt ca 50 % liquid

Sulphosuccinic acid esters

Emulsogen SB 10 Diisodecyl sulphosuccinate, Na salt +IPA ca 65 % liquid

Emulsogen SF 8 Diisooctyl sulphosuccinate, Na salt ca 50 % liquid

Fatty alkyl amine sulphosuccinamates

Emulsogen OLS Octyl amine sulphosuccinamate, Na salt ca 36 % liquid

Emulsogen TAS Tallow alkyl amine sulphosuccinamate, Na salt ca 36 % liquid

Phosphoric acid mono esters

Hostaphat CC 100 Cetyl phosphoric acid ester, acid form ca 100 % powder

Phosphoric acid di esters

Hostaphat L 327 Phosphoric acid ester of lauryl ethoxylate (2 EO) ca 95 % liquid

and polyethylene glycol

Phosphoric acid mono/di esters

Hostaphat MDAH Mono-/di-2-ethylhexyl phosphoric acid ester, acid form ca 98 % liquid

Hostaphat CG 120 Mono-/diisostearyl phosphoric acid ester, acid form ca 90 % liquid

Hostaphat CS 120 Mono-/distearyl phosphoric acid ester, acid form ca 92 % wax

Hostaphat 1306 Isotridecyl polyoxethyl (6 EO) phosphoric acid mono/diester, ca 96 % liquid

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