Lời giải và đề thi đại học môn Hóa khối A, A1 2013 mã đề 463

Lời giải và đề thi đại học môn Hóa khối A, A1 2013 mã đề 463

DE CHIN1I TIHJC

(D€ thi c6 6 trang)

DE TI-n: 'I'UYEN SINH DJ.~I IIQC r~~t\.lVi 2013

Irion: IIOA IIQC; Khfii A

Thcii gian lam bed: 90 phut, khong kJ thai gian phat a€

I Ma ct~ thi 463

HQ, ten thi sinh:

sa bao <lanh:

Cho bi~t nguyen tv kh6i cua cac nguye t6:

H = 1; C = 12~ N = 14; 0 = 16; Na = 23 Mg = 24; AI= 27; P = 31; S = 32; Cl = 35,5; Ca = 40; Cr =52; Fe= 56; Cu = 64; Zn = 65; Br = 80; A = 108~ Ba = 137

I PHAN CfiUNG-CHO TAT cA T i SINH ( 40 cau, til cau 1 d~n cau 40)

Cau 1: Cho h6n hqp X g6m 0)01 mo Alva a mol Fe vao dung dich AgN03 d~n khi phan (rng hoan toan, thu duqc 1n gam ch~t r~n Y va tmg dich Z chua 3 cation kim loe:ti Cho Z phim (mg v6i dung dich NaOH ,du tr~ng diSu ki~n kh?n c6 khong khi, thu 9u~c 1,97 gam k~t tu~ T Nun~ T trong khong khi den khoi hrc;mg khong doi: thu duqc 1 ,6 gam chat ran chi chua n1<)t chat duy nhat Gia tri etta m la

Cau 2: Cho 0,1 rnol tristearin ((C17H 5C00)3C3H5) tac d\1ng hoan toan v6i dung dich NaOH du, dun nong, thu dm:;rc rn gan1 glixerol <.1ia t cua m la

Cau 3: 0 tr~ng thai co ban, c§u hinh lectron cua ngp yen ru Na (Z = 11) la

A ls22s22p53s2• B ls22s22 63s2

• 'C hs22s~p63s1• D ls22s22p43s1• Cau 4: Len n1en m gam glucoza d~ t~o thanh aJl~o · i' etylic (hi~u su~t phan (mg bfulg 90%) Hftp thv hoim toan luqng khi C02 sinh ra vao ung dich Ca(OH)2 dtr, thu duqc 15 g'lm ket rua Gia tri cua m 18

Cau 5: Cho 111 gam Fe vao b1nh chua dung dich gbxn H2S04 va HN03'; thu duqc dung djch X va 1,12 lit khi NO Thern ti€p dung dich H2S 4 du vao binh thu duqc 0,448 lit khi NO va dung dich Y BiSt trong ea ~ai tru6ng h<;YP NO la san h~m khi'r duy rlhftt, do a di~u ki~n tieu chuAn Du!lg dich Y hoa tan vira het 2,08 gam Cu (kh6ng t~lO hfmh san ph&tn khu Ctla N+5) Biet cac phan (mg deu xay ra ho~;,.l

Cau 6: Chdt nao sau day khong t~o @t tua khi cho vao dung dich AgN03?

Can 7: Trong di~u ki~n thich hqp, , ay ra cac phan ung sau:

(a) 2H2S04 + C ~ 2802 + C 2 + 2H20

(c) 4H2S04 + 2Fe0 > Fe2(S 4)3 + S02 + 4I-h0

(d) 6H2S04 + 2Fe -1- Fe2(S )3 + 3S02 + 6I-h0

, .- l - ' · h' , l i: 'l LJ c:: , -) lo-;:-u"g la-·

1 rong cac p11ar1 unc trcn D ,an g xa·l ra vu; (J.ung G)C 1 .1T2uu4 1 • 1

Cau 8: Phenol phan ling duqc v6i ung dich nao sau day?

Cau ~~: U ng v&i cong thuc phan tU C4H100 co hao nhieu ancolla d6ng phan cfru t?o cua nhau?

_t~ •• ) •

A_tlUu.;s ,_ ,, _ _ , ~t~ ' 0 ll1Ql !lct1 Kt.l 0! \ '- -.-) :- c l.s 1 - _;,«u.t .t • "'\ } f 'h a b"· , h;_ chay thn duac 25,56 gam ht~n hap ll1 U r i Dot c.ht.~; hoan :oan lU gam X, 1ap ~ \1 ~0;-~ .• Q san ~ a~ ~

~· · , , , T ' " ' -¥ ::~ - ~~ · ·end008 ua·mT6ng~a:oi1Ucmg l , uanw axn

bang ciung o.1cn 1~au11 <1U) Knoi 1 1 Q!l.g aung _-qdl 1an g fn 1 • , o · · · • ·· · - ¥

ca cbo :~ · ;;·lie kbf')ng no trong In garr X la

6 111 15 - C, 1 ,06 g_am D 18,96 gan1

A ';\ 9) rr.:-un _ }}., ~ · o :~mn ~

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Cau 11: Cho cac can b~ng h6a hQc sa :

(a) H2 (k) + h (k) < ) 2HI (k) (b) 2N02 (k) < > N204 (k)

(c) 3H2 (k) + N2 (k) < > 2NH3 (k_ (d) 2S02 (k) + Oz (k) < ) 2S03 (k)

(j nhi~t de) khong dfli, khi thay d~ 1 ap sudt chung CUa m3i he can b~ng can bfutg h6a hQC nao a

Cau 12: Cho SCY do cac phan trng:

Trong sa d6 tren, X va Z l~n luqt '

A HCOOCH=CH2 va HCHO B CH3COOCH=CH2 va HCHO

Cau 13: Khi dugc ~hiSu ,sang, hidro ac~on nEw sau day tham gia phan ung th~ v6i clo theo ti 1~ mol

1 : l, thu duqc ba dan xuat monocle a dong phan cAu t?o cua nhau?

A butan .B neope tan C pentan D isopentan

C~u 14,: Hoa tan hoan toan m gam b~g dung dich HN03 loang, thu duqc 5,376 lit (dktc) han hgp

(a) Cho dung dich HCl vao d ng dich Fe(N03)2

(b) Cho FeS vao dung dich Cl

(e) Cho Si vao binh chua kh F2

(f) S\lc khi S02 vao dung di h H2S

Trang cac thi nghi~m tren, sb thi nghi~m c6 xay ra phan (rng la

cau 16: a di~u ki~n t~ich hqp xay a cac phan wg"sau:

D 3

n~uyen tl:r cacbo,n D5t chay hoan oan 0,4 mol h8n hqp g5m X va Y (trong d6 sA mol cua ~ 1~ han

so mol cua Y) can vira du 30,24li' khi 02, thu dugc 26,88 lit khi C02 va 19,8 gam H20 Biet the tich

cac khi do a diSu ki~n tieu chuAn 6i luQ'llg cua Y trong 0,4 mol hfin hgp tren Ia

Cau 18: Dung dich axit axetk ph ·n irng duqc v6i cit.ca cac chAt trong day nao sau day?

A NaOH, Cu, NaCi B 1'-ia, aCl, CuO C Na, CuO, HCl D 1~aOH, Na, CaC03 Cau 19: HOP ch~t X c6 thanh ph~ g6m C, H, 0, chua vong be:nzen Cho 6,9 gam X vao 360 ml dung

dich NaOH O,SM (du 20% so v6i ue,mg cfut phan Un.g) den phan 6ng hoan toan, thu d;rgc dung dich Y

0

2 (dktc), thu duqc 15,4 ga.111 C 2 Bi€t X c6 cong thuc phan tu trung v&i cong thuc dan gian nhat

Gia ( tri cua m la

ci~ 20: H6n hqp X gbm 3,92 g _Fe, 16 gam Fe203 va m gam Al Nu n g X~ nhi~t d9 cao tro~g diau

kien khong co 1r~1ong krd~ thu ch c h5n hgp chAt :r~n Y Chia Y th r.Lh pai pi1a n hang nhau Phan n:<>t

ta~ dung v&i dung dich I-bS04 i ang (du), thu ctuqc 4a .- L ol k~~i H2 Phan hai phim tmg v6i dung dtch

NaOfi du, thn duqc a mol khi H Bi€t cac phan (rng d~u xay ra hoan toan Gi<l tri cua rn la

frang 2/6 - !vHt { ~~ ;hi 463

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Cau 21: Chftt nao sau day khi dun n6ng

A CHJ·-COO C-1 12·-CH=:CH-

C CH2=CH COO CI-h-Cl-b

Cau 22: Oxi h6a hoan toan 3,1 gam p

dung dich l'~aOH 1M d~n khi phan 1m

&i dung dich NaOH thu duqc san ph~m c6 anc.1ehit?

B CH3-COO-C1-I=CH-CH3

D CI-l)-COO-C(CH3)=CH2

otpho trong khf oxi du Cho toan bQ san phAm vao 200 ml

xay ra hoan toan, L~u uqc dung !Ch X K _ol lugng muo1 trong X Ht

A 11,1 gan1 B 12,0 gam C 14,2 gam ~ D 16,4 gam

Cau 23: Day cac ch~t d~u tac d\mg duq v6i dung dich Ba(HC03)2 la:

.A HN03l Ca(OH)

2 va Ki'I03 B HN03, NaC1 va Na2S04

C NaCl, Na2S0

4 vit Ca(OH)2 D HN03, Ca(OH)2 va NazS04

Cllu 24: Trong mQt binh kin chUa 0,35 ol C2H2; 0,65 mol H2 vit mQt it bQt Ni Nung n6ng binh mQt thai gian, thu duqc hi'\n hgp khi X c6 ti 6i so v6i H2 b~ng 8 S1,1c X vito luqng du dung djch AgN03 trong NH3 d~n phim lmg hoim toim, th duqc hi'\n hgp khi Y va 24 gam k~t tim H6n hgp khi Y phan tmg vua du vai bao nhieu mol Br2 tron dung dich?

A 0,20 mol B 0, l 0 mol C 0,15 mol D 0,25 mol

Cilu 25: Hi'\n hgp X gbm Na, Ba, Na2 vit BaO HOa tan ho<l.n toim 21,9 gam X vao nmJc, thu duqc 1,12 lit khi H2 (dktc) va dung dich Y, tong d6 c6 20,52 gam Ba(OH)2 H!§.p th1,1 hoim toim 6,72 lit khl C02 ( dktc) vao Y, thu duqc m gam k~t · a Gia tri q)a m la

: D 23,64

Cilu 26: Cho 100 ml dung dich am in axit X nbng dQ 0,4M tac dlJng vira dU v&i 80 ml dung dich NaOH O,SM, thu Gu9c dung dich chUa 5 gam mu6i COng thUc cUa X 18

Cilu 27: Ti~n hlinh di~n phiin dung di h chUa m gam hi'\n hqp CuS04 va NaCl (hi~u su~t 100%, di~n

C\IC trcr, mitng ngiin xf>p), d~n khi nu' C b~t d~U bi di~n phan i:J cit hai di~n Cl;IC thi ng\mg di~n philn, thu duqc dung dich X va 6,72 lit kh (dktc) a anot Dung dich X hOa tan t6i da 20,4 gam Al203 Gia tri cua m la

Cau 28: Ti~n h2mh cac thi nghi~rn sat:

(a) S\lC khi etilen vao dung di ~Mn04 loang

(b) Cho hoi ancol etylic di qu bQt CuO nung n6ng

(c) Svc khi etilen vao dung di h Br2 trong CCl4 :

(d) Cho dung d\ch glucoza va dung djch AgNOJ trong NHJ du, dun n6ng

(e) Cho Fe20:> vao dung dich l2S04 d~c, n6ng

Trong c:l.c thi nghi~m tren, s6 thi 1 ghi~m c6 x:l.y ra philn lrng oxi h6a-kl/-ir lB

cau 29: Kim lo;ti s~t t:l.c dl,lllg v&i d ng dich nao Sau diiy t;to ra mu6i s~t(II)?

A MgS0

C H

2S04 d~, n6ng, du D HNO, dl).c, n6ng\ du ,

Cllu 30: Lien ket h6a hQc giiia c8.c uyen tlr trong philn tir HCl thuQc iol;\i lien k6t

A cQng h6a tri Jrll6ng c1,rc B ion

C cQng h6a tri c6 eve D hidro

cau 31: Dung dich · · nilo sau B , dil.y lEt 1 · phenolphtalein dbi milu? C axit axetlc · D metylam1n

A glpnn , a ant · ; , C • (NO ) s u kh~ cac pharl · U'ng xay ra hoan , , toan~

cau 32: Cl-.0 bOt fe vilo dung d!Ch om AgJ;l03, va u 3 ~- _a • <· T X , hai kim

thu duqc k"lg ·d: :h X g6m hai m 5i va chilt ran Y g5m hru ktm lo:;n Ha1 mum tronb va

lo~i trong Y 1~n \iJQ't He

A CuC·:/)~~:l; Fe(N03)2 ·vzt i\g; ).1

C Fe(.f'·-h ~ }~~ Fe(NCh)3 v(,~ Cu; / g

cau 33: -TCI nilon-6,6 iil - s an phfun rUng ngung cUa s ptv en l o • l' co va ex l ·_ am"'tylend"l' "" 0(.d ffil·n -·

A ax1t achp1c va etylen ghcol , · y • • ':' ~ ~ , , , - ' " "

1

· · · - t 1 ·1· • • ' '), av·lt ~-\fl!D1t, ,, a :!.· · ~ero"'

r· -:.s~; ·~· ri· n· ·1 -: hf • X;;l.JriP -v1em< am1n L •• •• .(>_ • · 1 ~ - ·

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Cau 34: Hoa tan hoan toan 1,805 g h6n hqp gbm Fe va kim lo~i X b~ng dung dich HCI, thu du<;t:

1 ,064 lit khi H2 M~t khac, hoa tan ho to an 1 ,805 gam h6n hgp tren bfulg dung dich HN03 loang ( du),

thu dugc 0,896 lit khi NO (san ph! khu duy nh~t) Biet dac the tich khi de~ do 6 di8u ki~n tieu

chuan K.im lo~i X la

Cau 35: K.h6i lugng Ag thu duQ'c i cho 0,1 mol CH3CHO phan Un.g hoan toan v6i luQllg du dung dich AgN03 trong NH3, dun n6ng la

A 43,2 gam B 21 ,6 g m C 16,2 gam D 10,8 gam

Cau 36: H6n hgp X gflm Ba va AI Cho m gam X vao nu6c du, sau khi cac {>han tffig xay ra hoan toan, thu duQ'c 8,96 lit khi H2 (dktc M~t khac, hoa tan hoan toan m gam X bang dung dich NaOH, thu_qgqc 15,68 lit khi H2 (dktc) Gia tri cua m la

Ca~u 37: Cho, 1,37 gam Ba vao 1 lit ung dich CuS04 O,OIM Sau khi cac phan i:rng xay ra hoan toan, khoi lu<;mg ket rua thu duqc la

Cau 38: Cac chAt trong day nao sa day d~u t~o k~ftua khi cho tac d\Ulg v6i dung dich AgN03 trong

A vinylaxetilen, glucoza, andeh't axetic rB~ vinylaxetilen, glucozo, axit propionic

C vinylaxetilen, glucoza, dimet laxetilen ~ glucozcr, dimetylaxetilen, andehit axetic

Cau 39: Cho X la hexapeptit Al -Gly-Ala-Val-Gly-Val va Y la tetrapeptit Gly-Ala-Gly-Glu Thuy phan hoan toan m gam h6n h gam X va Y thu duqc 4 amino axit, trong d6 c6 30 gam glyxin

va 28,48 gam alanin Gia tri cua m a

cua (CH3)3C-CI:-h-CH(CH3)2 la

\ B 2,4,4-trimetylpentan

Cau 40: Ten thay th~ (thea- IUP AC

A~ 2,2,4-trimetylpentan

Thi sinh chi dtrqc lam mqt trong ha phAn (PhAn A ho~c Phin B)

A Theo chll01lg trlnh Chuin (1 diu, tit cau 41 d~n diu 50)

Cau 41: Cho cac cttp oxi h6a - ir duqc s~p-xep theo thu t\1 tang ddtll tinh oxi h6a cua cac ion kim

(a) Cho sat vao dung dich dong II) sunfat

(b) Cho d6ng vao dung dich nh m sunfat

(c) Cho thi~c vao dung dich db g(II) sunfat

(d) Cho thiSc vao dung dich s~ (II) sunfat

A (a) va (c) B (a) a (b) (C (b) va (d) D (b) va (c)

Cau 42: Cho 25,5 gam h6n hqp g6~ Cup va AhO~ tan hoan toan trong dung d}ch H2S04 loang, thu dugc dung dich chua 57,9 g· muoi Phan tram khoi luqng cua Ah03 trong X la

c · ii\143: £>fit chay hoan toan h61 hqp X g6m 0,07 mol m(lt ancol da chuc va 0,03 mo.l ~Qt an,col khong no, c6 m9t lien k~t doi, m ch hcr, thu duqc 0,23 mol khi C02 va m gam H20 Gta tq cua m la

-(a) Trong bang tu§.n hoan cac guyen tfi h6a h<;>c, ·crom thu9c chu ki 4, nh6m VIB

(b) Cac ox it cua crom ci~u la ~ xit baza

(c) Trong cac hgp ch~t, s6 o:~·~- h6a cao ~At cua cron1l~ +? , : ,

(d) Trortg cac phan [rng h6a h c, hgp chat crom(Ill) ~hi dong vm tro chat ox1 hoa

(e) Khi phan t!ng v6i khi (::i2 iu~ crom t~o rE t hqp chat crom(III)

' ' • X " -h ~ h 1 b•; d ', 1' •

Trong cac phat bteu tren, rL 1.11 ~g p at teu ltng a

A (a) (b) va (e) B, (t l (d.) vt (e) C (b), (c) va (e)

(

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Cau 45; Trong ~:.:ac dung dich: C 3-CH2-NH2 , H2i T-CH2-COOH,

(c) bong c6 t&m nu6c voi (d) bong c6 tfun gifun an

Trong 4 bi~n phap tren~ bi~n phap 6 hi~u qua nhftt la

Cau 47: Cho X va Y la hai axit cac xylic m~ch ho, c6 cimg s6 nguyen tir cacbon, trong d6 X don

chuc, Y hai chuc Chia h6n hgp g~m va Y thimh hai phAn b~g nhau PhAn mo<)t tac d\IDg-h€t v6i ~a,

thu duq? 4,48 lit khi H2 (dktc) Dot c uiy hoan toan phan hai, thu duqc 13,44lit khi C02 (dktc) Phan

Cau 48: Cho phuang trinh phan (rng AJ +_bHN03 ~ cAl(N03) 3 + dNO + eH20

Cau 49: Day cac chAt deu c6 kha no ng tham gia phan tmg thuy phan trong dung djch H2S04 dun

A saccaroza, tinh b9t va xenluloz-0 • -OB':o glucoza, saccarozo va ftuctoza

C fructozo, saccarozo va tinh b<)t D glucoza, tinh b<)t va xenluloza

Cau 50: H6n hgp X gbm H2, C2I-4 v' C3H6 c6 ti khbi so v6i H2la 9,25 Cho 22,4 lit X (dktc) vao binh

kin c6 s~ m9t it b9t Ni Dun n6ng b m<)t thai gian, thu dugc h6n hqp khi Y c6 ti khAi so v6i H2

B Theo chtrong trinh Nang cao (1 0 c au, tiT cau 51 din cau 60)

Cau 51: Cho 13,6 gam ~<)t ch~t hfru a X (c6 thanh phfln nguyen t6 C, H, 0) tac dl)11g vira du v6i dl.lllg

d!ch chua 0,6 mol AgN03 trong NH3, un n6ng, thu duqc 43,2 gam Ag Cong thuc cdu ~o ciia X Ia

A Na[Cr(OH)4 ] B Cr(OH C Na2Cr207 D Cr(OH)2

Cau 53: H6n hqp X gbm ancol me lie, ancol etylic va glixerol £>6t chay hoan toan, m gam X, thu I

Cau 54: Cho cac phat bi~u sau:

(a) Db xu li thuy ngan roi vai, ngu ita c6 th6 dung b9t hru huynh

(b) Khi thoat vao khi quy~n, freon pha huy tAng ozon

(c) Trong khi quy~n, n6ng d9 C02 vuqt qua tieu chuftn cho phep gay ra hi~u ung nha kfnh

Trong cac phat bi€u tren, s6 phat

Cau 55: Tmbng hgp nao sau day kh )ng xay ra phEm U:n.g':>

' r , - ~-, t0

(b) Cl-h Cfh-CHr-Cl + H20 ?

Trang 5/o-!via de tb1 4o

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; (v6i C6Hs-la gBc phenyl)

to

A.2: 3

-Tra._ng 6/6 ~ J \/ la d~ thi 463

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