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Ohanin a novel protein from king cobra (ophiophagus hannah) venom 2

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a The expression vector contains the lac promoter which drives the expression of lacZ gene encoding for β-galactosidase.. Lactose or its analog IPTG will stimulate the expression of β-g

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APPENDICES

Figure A.1 Map of pGEM®-T Easy Vector

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Figure A.2 Production of recombinant proteins (a) The expression vector contains the

lac promoter which drives the expression of lacZ gene encoding for

β-galactosidase Lactose or its analog IPTG will stimulate the expression of

β-galactosidase (b) If lacZ is replaced by the gene encoding the protein of interest, lactose

or IPTG will stimulate the expression of desired proteins

Many proteins of interest are expressed in low concentration in endogenous system Through recombinant DNA technology as above, large quantities of recombinant proteins

can be produced using an in vitro expression system

(Modified from http://www.web-books.com/MoBio/Free/Ch9H.htm)

Note

Blue white selection: Many vectors (such as pUC series) carry coding information for

the first 146 amino acids of the β-galactosidase gene Embedded in this coding region is the multiple cloning site (does not disrupt the reading frame of the gene) into which the insert DNA is cloned After IPTG induction, this 146 amino acid fragment of β-galactosidase protein is expressed but incapable of acting on the chromogenic substrate (X-gal) It is only when transformed in an appropriate host cells which expressed the other half of the carboxyl terminal fragment of the β-galactosidase protein, these two protein fragments can then associate to form an enzymatically active protein to cleave the chromogenic substrates This process is called as α-complementation Properly expressed β-galactosidase protein (after α-complementation) will turn cells into blue colonies when

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Table A.1 Reagents and chemicals used for molecular biology experiments

Name Components Amount in 1 l Note

TAE buffer (10X) Tris-base

EDTA

0.40 M 0.01 M

Æ Prepare from the stock solution of the chemicals, adjust

to pH 7.8 using glacial acetic acid and autoclave

Æ Dilute to 1X before use

SOB medium

(for preparation of

competent cells)

Tryptone Yeast extract NaCl

KCl MgCl2.6H2O MgSO4.7H2O

20.00 g 5.00 g 0.58 g 0.19 g 2.03 g 2.46 g

Æ Prepare without Mg2+

, adjust

to pH 7.0 and autoclave

Æ A 2 M stock of Mg2+

(1 M MgCl2 and MgSO4, filter stelize) is used to make the medium 20 mM in Mg2+

TB buffer

(for preparation of

competent cells)

Pipes MnCl2 CaCl2

KCl

10 mM

55 mM

15 mM

25 mM

Æ Prepare from the stock solution of the chemicals, adjust

to pH 6.7 and filter sterilize

IPTG stock

(20 mg/ml)

IPTG 2.00 g

Æ Dissolve in dH2O, filter sterilize and store at -20 oC

Æ IPTG induces synthesis of a β-galactosidase It is used to

detect lacZ gene expression in

cloning experiment

Æ Use for blue-white colonies selection

X-gal stock

(50 mg/ml)

X-gal 5.00 g Æ Dissolve in dimethyl

formamide, filter sterilize, wrap containers with aluminium foil and store at -20 oC

Æ Use as chromogenic substrates in blue-white colonies selection

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Table A.2 Antibiotics, reagents and chemicals used for growing bacterial culture and

for recombinant protein expression

Name Components Amount in 1 l Note

Yeast extract NaCl

10.00 g 5.00 g 10.00 g

Æ Adjust to pH 7.5, sterilize by autoclaving

Æ To make the agar medium, add

15 g agar to 1 l liquid medium before autoclaving

Ampicillin (Amp)

(100 mg/ml)

Ampicillin 100.00 g Æ Dissolve in dH2O, filter

sterilize and store at -20 oC

Æ Use for inhibition of cell-wall synthesis by interfering with peptidoglycan cross-linking

IPTG stock

(1 M)

IPTG 238.30 g Æ Dissolve in dH2O, filter

sterilize and store at -20 oC

Æ Use to induce expression of plasmid-based genes for the production of recombinant

proteins under control of the lac

promoter Lysozyme

(100 mg/ml)

Lysozyme 100.00 g Æ Dissolve in dH2O, filter

sterilize and store at -20 oC

Æ Use for hydrolyzing peptidoglycan Osmotic lysis will occur as a result of destruction of the bacterial cell wall

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Table A.3 Solutions for preparing 15 % resolving and 4 % stacking gels for SDS-

glycine Polyacrylamide Gel Electrophoresis (SDS-PAGE)

Solutions components Component volumes/

4 gels (0.75 mm thickness)

Note

Resolving

H2O

30 % Acrylamide mix (37.5:1)

1.5 M Tris-base (pH 8.8)

10 % SDS

10 % Ammonium persulfate

TEMED

4.70 ml 10.00 ml 5.00 ml 200.00 µl 100.00 µl 10.00 µl

Æ Mix the components in the order shown, swirl the mixture rapidly and pour the resolving mixture into the gap between glass plate

Stacking

H2O

30 % Acrylamide mix (37.5:1)

0.5 M Tris-base (pH 6.8)

10 % SDS

10 % Ammonium persulfate

TEMED

6.00 ml 1.32 ml 2.52 ml 100.00 µl 50.00 µl 10.00 µl

Æ Mix the components in the order shown, swirl the mixture rapidly and pour the stacking mixture onto the surface of the polymerized resolving gel

Æ Insert a clean Teflon comb into the stacking solution

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Table A.4 Reagents and chemicals used for SDS-PAGE

SDS-glycine

buffer (5X)

Tris-base Glycine SDS

15.10 g 72.00 g 5.00 g

Æ Dissolve Tris and Glycine, adjust pH to 8.3

Æ Add SDS and adjust the volume to 1000 ml

Æ Dilute to 1X before use

Staining solution Coomassie

Brilliant Blue R-250

Ethanol Acetic acid

1.00 g

300.00 ml 100.00 ml

Æ Dissolve Coomassie Brilliant Blue R-250 in 600 ml dH2O, ethanol and acetic acid

Destaining

solution

Methanol Acetic acid

400.00 ml 100.00 ml

Æ Mix 500 ml dH2O with methanol and acetic acid Gel drying solution

Methanol Acetic acid Glycerol

400.00 ml 100.00 ml 100.00 ml

Æ Mix 400 ml dH2O with methanol, acetic acid and glycerol

Table A.5 Preparation of SDS gel-loading buffer

SDS

gel-loading

buffer (4X)

Bromophenol blue Glycerol

Upper Tris (pH 6.8)

20 % SDS

0.0185 g

8 ml

10 ml

4 ml

Æ 4X SDS gel-loading buffer without the β-mercaptoethanol can

be store at room temperature

Æ Add 28 µl of β-mercaptoethanol

to 190 µl of loading buffer before

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Table A.6 Preparation of DNA ladders for molecular biology experiments

Components Note

DNA ladders stock

(1 kb plus, 100 bp, 50 bp)

(Working stock: 1 µg/ µl)

Æ Mix 10 µl of stock DNA ladders with 90 µl

dH2O and 20 µl loading dye, store at -20 o

C

Æ Load 6 µl each time

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