1. Trang chủ
  2. » Giáo Dục - Đào Tạo

Synthetic studies of azido inositols and inositol based glycans 3

13 272 0
Tài liệu được quét OCR, nội dung có thể không chính xác

Đang tải... (xem toàn văn)

Tài liệu hạn chế xem trước, để xem đầy đủ mời bạn chọn Tải xuống

THÔNG TIN TÀI LIỆU

Thông tin cơ bản

Định dạng
Số trang 13
Dung lượng 2,99 MB

Các công cụ chuyển đổi và chỉnh sửa cho tài liệu này

Nội dung

Trang 1

=1 NUS Appendix 2: NMR Spectra of the selected Compounds in Chapter 3 | 2012 National University

of Singapore

sp030111/5 38% SIRs mĩ h=ĩh<=hh h6 BRR

+ 1.40E+09 + 1.30E+09 + 1.20E+09 + 1.10E+09 + 1.00E+09 + 9.00E+08 + 8.00E+08

+ 5.00E+08 + 4.00E+08 + 3.00E+08 + 2.00E+08 + 1.00E+08

0.00E+00

_

6.5 6.0 5.5 4.0 3.5 3.0 2.5 2.0 1.5 1.0

ose-| 0.985 0.98-T

~ b |

8.5 8.0 7.5 5.0 4.5

fl (ppm)

sp030111/6

13C AMXSQ9 MLSP-315 Ƒ 1.70E+09

F 1.50E+09 1.40E+o9 + 1,30E+09

F 1.20E+09 1.10E+os F1.00E+09

F6.00E+08 + 5.00E+08 + 4.00E+08 + 3,00E+08 F2.00E+08

í ` ph w “ “ 4 “ T 0.00E+00

[ -1.00E+0£

- -2,00E+08

150 145 140 135 130 125 120 115 110 105 100 95 90 85

f1 (ppm)

Trang 2

23 NUS National University

of Singapore

AM

[ 9.0E+08

| 8.0E+08

| 7.0E+08

| 6.0E+08

[ 5.0E+08

| 4.0E+08

[ 3.0E+08

| 2.0E+08

[ 1.0E+08

| 0.0E+00

6.0 3.5

sp030111/8

13C AMX500 MLSP-316 ý cổ 2 geese

131 131

—92.12 —-

KÀ N

3.0 2.5 2.0 1.5

1.0

| 1.50E+09 1.40E+09

F 1.30E+09

Ƒ 1.20E+09

Ƒ 1.10E+09

Ƒ 1.00E+09 9.00E+08

| 8.00E+08 7.00E+08 6.00E+08

| 5.00E+08 4.00E+08

| 3.00E+08

| 2.00E+08

Ƒ 1.00E+08

| 0.00E+00 [ -1.00E+0£

155 150 145 140 135 130 125 120 115 110 105 100 95

f1 (ppm)

Trang 3

23 NUS National University

of Singapore

sp070111/1 335 3

1H AMX500 MP1 >> NE?

rs Pil Lr

1.88 2,91

4.92 4.91

TT"

sp070111/2

12C AMX50QMLSP:348

132 131 129 128 128 127

6.5

5.5

5.0 4.5 f1 (ppm)

L NX

4.0

1.0 0.5

Xương

(50 145 140 135 130 125 120 115 110 105 100 95 90 85 80 7

f1 (ppm) 5 70 65 60 55 50 45

[ 1.80E+08

| 1.70E+08

Ƒ 1.60E+08

Ƒ 1.50E+08

Ƒ 1.40E+08 [ 1.30E+08

T 1.20E+08

Ƒ 1.10E+08

Ƒ 1.00E+08 [ 9.00E+07

| 8.00E+07 [ 7.00E+07 [ 6.00E+07 [ 5.00E+07

| 4.00E+07 3.00E+07

| 2.00E+07 1.00E+07

| 0.00E+00

| -1.00E+07 [ 7.0E+08 [ 6.5E+08

[ 6.0E+08

[ 5.5E+08

[ 5.0E+08

[ 4.5E+08

| 4.0E+08

[ 3.5E+08

| 3.0E+08

[ 2.5E+08 [ 2.0E+08 [ 1.5E+08

Ƒ 1.0E+08

[ 5.0E+07

[ 0.0E+00 [ -5.0E+07

Trang 4

NUS National University

of Singapore

T

3.5 3.0 2.5 2.0

4.0

f1 (ppm)

sp120111/2

13C AMX500 M B.321.,

5

LSI tổ

`

OH

NHBoc

3-12

1.0 0.5

| 6.0E+08

[ 5.5E+08

| 5.0E+08

[ 4.5E+08

F 4.0E+08

[ 3.5E+08

| 3.0E+08

[ 2.5E+08

| 2.0E+08

[ 1.5E+08

F 1.0E+08

[ 5.0E+07

| 0.0E+00

5,0E+07

| 4.0E+08

F 3.5E+08

| 3.0E+08

[ 2.5E+08

| 2.0E+08

[ 1.5E+08

[ 1.0E+08

[ 5.0E+07

| 0.0E+00

145 140 135 130 125 120 115 110 105 100 95 90 85 80 75 70 65 60 55 50 45

f1 (ppm)

Trang 5

=1 NUS Appendix 2: NMR Spectra of the selected Compounds in Chapter 3 | 2012 National University

of Singapore

1H AMXSOG-MLSP-322 TS ii 30 28 26 19 18 16 09 08 00 98 89 88 87 78 78 76 51 + F2.00E+08

- 1.90E+08

- 1.70E+08

- 1.60E+08

_ 1.30E+08

L 1.20E+08

- 1.10E+08

- 1.00E+08

- 9.00E+07

[ 8.00E+07

[ 7.00E+07

| 6.00E+07

- 5.00E+07 4.00E+07

| 3.00E+07

| 2,00E+07 1.00E+07

ˆ wl Le | 0.00E+00

k r -1.00E+0?

fl (ppm)

13C AMX500 MLSP-322

| 5.0E+08

[ 4.5E+08

| 4.0E+08

[ 3.5E+08

| 3.0E+08

[ 2.5E+08

| 2.0E+08

[ 1.5E+08

[ 5.0E+07

wate i | 0.0E+00 5.0E+07

f1 (ppm)

Trang 6

SANUS Appendix 2: NMR Spectra of the selected Compounds in Chapter 3 | 2012 National University

of Singapore

spPINSAANNASS SRB SSRaRess - Rà 0Ð (DO tÕ (Ð (O (Ð tD (D O (O 8 t+

Co Nee

+ 1.00E+09 + 9.00E+08

+ 7.00E+08

3-14

+ 4.00E+08 + 3.00E+08 + 2.00E+08 + 1.00E+08

T T T T T T T T T T T r T T T T T T T T T T T T T T T T T

fl (ppm)

sp170311/2 5 3 8

+ 6.5E+08 + 6,0E-+08 + 5.5E+08 + 5.0E+08

N + 4.0E+08

+ 3.0E+08 + 2.5E+08 + 2.0E+08 + 1.5E+08 + 1.0E+08 + 5,0E+07 + 0.0E+00

- -5.0E+07

60 155 150 145 140 135 130 125 120 115 110 105 100 95 H a ) 8 80 75 70 6 60 55 50 45 40 35 30 25

ppm

Trang 7

TANI LS Appendix 2: NMR Spectra of the selected Compounds in Chapter 3

National University

of Singapore

2012

Sf

LS”

1.60E+09

Ƒ 1.50E+09

| 1.40E+09

Ƒ 1.30E+09

Ƒ 1.20E+09

Ƒ 1.10E+09

Ƒ 1.00E+09

| 9.00E+08

| 8.00E+08

- 7.00E+08 6.00E+08

Ƒ 5.00E+08

| 4.00E+08

| 3.00E+08

| 2.00E+08

Ƒ 1.00E+08

| 0.00E+00

—— FT+T FTTIE—T—"

}.5 8.0 7.5 7.0 6.5 5.0

sp090711/1 RR AAAANR RRA A AREER TAS SS ese saagws NNN NO OOOO OD

St

7

St SIT

| -1.00E+08

| 2.8E+09

| 2.6E+09

[ 2.4E+09 2.2E+09 [ 2.0E+09 [ 1.8E+09

F 1.6E+09

F 1.4E+09 [ 1.2E+09

Ƒ 1.0E+09

[ 8.0E+08 [ 6.0E+08 [ 4.0E+08 [ 2.0E+08 [ 0.0E+00

F -2.0E+08

84 82 80 78 76 74 72 70 68 6.6 64 62 6.0 5.8 5.6 At mộ 5.0 48 46 44 4.2 40 3.8 3.6 3.4 3.2

Trang 8

National University

of Singapore

23 NUS

eS _—

MJ

4

8.0 7.8 7.6 74 7.2 70 68 66 64 62 60 5.8 5.6

1 (ppm

sp100711/2

_-147.5Ÿn ™

67.81 67.35 67.23

155 155.1 152.248

⁄ `

5.4 5.2 70 46 44 42 40 38 3.6 3.4 3.2 3.0 2.8 2.6 24 2.2 2.0

T T T r T r T r T r T T T r T r T r T r T T T r T r T r T r T T T r T r T r T r T

60 155 150 145 140 135 130 125 120 115 110 105 100 95

f1 (ppm)

[ 5.5E+08

[ 5.0E+08

[ 4.5E+08

| 4.0E+08

[ 3.5E+08

| 3.0E+08

[ 2.5E+08

[ 2.0E+08

[ 1.5E+08

| 1.0E+08

[ 5.0E+07

| 0.0E+00

5.0E+07 [ 1.90E+08

[ 1.80E+08

F 1.70E+08

- 1.60E+08

- 1.50E+08

[ 1.40E+08

Ƒ 1.30E+08

- 1.20E+08

- 1.10E+08

F 1.00E+08

Ƒ 9.00E+07

[ 8.00E+07 [ 7.00E+07 [ 6.00E+07

| 5.00E+07

- 4.00E+07

- 3.00E+07

F 2.00E+07 [ 1.00E+07

- 0.00E+00

[ -1.00E+07

Trang 9

=1 NUS Appendix 2: NMR Spectra of the selected Compounds in Chapter 3 | 2012 National University

of Singapore

sp130711@

1H AMXSO8 MLSP-404 5.21 5.20 5.19 3.36 3.34 2.53 2.52 2.51 h | 1.60E+08

1.50E+08

Ƒ 1.40E+08

T 1.30E+08

F 1.20E+08

—- NHBoc SJ Ss [+ 1.10E+08

F 1.00E+08 3-19

[ 9.00E+07 [ 8.00E+07

F 7.00E+07 [ 6.00E+07

| 5.00E+07

F 4.00E+07

| 3.00E+07

2.00E+07

| 1.00E+07

5 I 1 1 I

°

Ƒ 0.00E+00

$

A

45 110 105 100 95 90 85 80 75 70 65 50 45 40 35 3.0 nN un

2.05]

6.0 5.5

f1 (ppm)

sp130711/4

15C AMX500.MLSP-404 | 3.2E+08

F 2.8E+08

F 2.6E+08

F 2.4E+08

[ 2.2E+08

F 1.6E+08

F 1.4E+08

F 1.2E+08

[ 1.0E+08

[ 8.0E+07

F 6.0E+07 F4.0E+07

Ị Ị [ 2.0E+07 | 0.0E+00

[ -2.0E+07

f1 (ppm)

Trang 10

SINUS National University

of Singapore

N

O

BocHN 3-20

|

fl (ppm)

sp130711/2 9 8 8

N

O

BocHN 3-20

|

f1 (ppm)

[ 2.20E+08

[ 2.10E+08 [ 2.00E+08

F 1.90E+08

- 1.80E+08

[ 1.70E+08

- 1.60E+08

- 1.50E+08

F 1.40E+08

- 1.30E+08

[ 1.20E+08

- 1.10E+08

- 1.00E+08

- 9.00E+07 [ 8.00E+07 [ 7.00E+07 [ 6.00E+07

| 5.00E+07

- 4.00E+07

- 3.00E+07

| 2.00E+07

- 1.00E+07

F 0.00E+00

Ƒ -1.00E+07

—-2.00E+0?

[ 6.0E+08 [ 5.5E+08

| 5.0E+08

[ 4.5E+08

| 4.0E+08 [ 3.5E+08

| 3.0E+08

[ 2.5E+08

| 2.0E+08

[ 1.5E+08

F 1.0E+08 [ 5.0E+07

| 0.0E+00

| -5.0E+07

10

Trang 11

2012

NMR Spectra of the selected Compounds in Chapter 3

Appendix 2 National University

of Singapore

ae

3

[ 1.5E+08

[ 1.0E+08

F 5.0E+07

| 0.0E+00

- -5.0E+07

11

10

20

30

40

50

60

70

f1 (ppm)

110

120

a a

160 150 140 130

170

Trang 12

=1 NUS Appendix 2: NMR Spectra of the selected Compounds in Chapter 3 | 2012 National University

of Singapore

NR

| 3.6E+08

[ 3.4E+08 [ 3.2E+08

r 3.0E+08 [ 2.BE+08

[ 2.6E+08

F 2.4E+08

[ 2.2E+08

[ 2.0E+08 [ 1.BE+08

F 1.6E+08

Ƒ 1.4E+08 [ 1.2E+08

Ƒ 1.0E+08

| 6.0E+07

| 4.0E+07

[ 2.0E+07

[ 0.0E+00 | -2.0E+07

sp140711/4

13C AMX500 MLSP-412

78.86 77.25

‹ | 4.0E+08

[ 3.5E+08

T 3.0E+08

[ 2.5E+08

| 2.0E+08

[ 1.5E+08

Ƒ 1.0E+08

Ị [ 5.0E+07

r 0.0E+00

f1 (ppm)

12

Trang 13

2012

NMR Spectra of the selected Compounds in Chapter 3 Appendix 2

of Singapore

[ 4.5E+08

[ 4.0E+08

[ 3.5E+08

| 3.0E+08

[ 2.5E+08

| 2.0E+08

[ 1.5E+08

| 1.0E+08

[ 5.0E+07

| 0.0E+00

—-5.0E+07

nwo Màn

TT

=

78 76 74 7.22 70 68 66 64 62 60 58 56 54 52 50 48 46 44 4.2 40 38 36 34 32 30 28 26 24 2.2 2.0 18

fl (ppm)

13

Ngày đăng: 09/09/2015, 17:56

🧩 Sản phẩm bạn có thể quan tâm