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In conclusion, liposomal bupivacaine is effective for treating postoperative pain when used via local infiltration when compared to placebo with a prolonged duration of action, predictab

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Liposomal bupivacaine: a review of a new

bupivacaine formulation

Praveen Chahar

Kenneth C Cummings III

Anesthesiology Institute, Cleveland

Clinic Foundation, Cleveland,

Ohio, USA

Correspondence: Kenneth Cummings III

Cleveland Clinic Foundation, 9500 Euclid

Avenue, Mail code G30, Cleveland,

OH 44195, USA

Tel +1 216 444 1016

Fax +1 216 444 4383

Email cummink2@ccf.org

Abstract: Many attempts have been made to increase the duration of local anesthetic action One

avenue of investigation has focused on encapsulating local anesthetics within carrier molecules

to increase their residence time at the site of action This article aims to review the literature surrounding the recently approved formulation of bupivacaine, which consists of bupivacaine loaded in multivesicular liposomes This preparation increases the duration of local anesthetic action by slow release from the liposome and delays the peak plasma concentration when compared to plain bupivacaine administration Liposomal bupivacaine has been approved by the US Food and Drug Administration for local infiltration for pain relief after bunionectomy and hemorrhoidectomy Studies have shown it to be an effective tool for postoperative pain relief with opioid sparing effects and it has also been found to have an acceptable adverse effect profile Its kinetics are favorable even in patients with moderate hepatic impairment, and it has been found not to delay wound healing after orthopedic surgery More studies are needed to establish its safety and efficacy for use via intrathecal, epidural, or perineural routes

In conclusion, liposomal bupivacaine is effective for treating postoperative pain when used via local infiltration when compared to placebo with a prolonged duration of action, predictable kinetics, and an acceptable side effect profile However, more adequately powered trials are needed to establish its superiority over plain bupivacaine.

Keywords: liposomal bupivacaine, postoperative pain, pharmacokinetics, pharmacodynamics,

efficacy, safety

Introduction

Pain is a protective mechanism which has adaptive value, and the inability to experi-ence pain has been linked to early mortality from accidental injuries or damage to joints.1,2 However, pain in the postoperative setting is an unwanted side effect of surgery directed to improve morbidity or mortality The potential benefits of optimal postoperative pain control include: improved cardiac, respiratory, and gastrointestinal functions; fewer thromboembolic complications; improved arterial graft survival; fewer septic complications; reduced chronic post surgical pain; reduced mortality in

of relief for perioperative pain; however, opioids have numerous side effects includ-ing nausea, vomitinclud-ing, respiratory depression, prolonged ileus, itchinclud-ing, tolerance, and

Increasingly, multimodal analgesia is used to reduce perioperative opiate require-ments, thus potentially reducing opioid side effects and improving the quality of analgesia.6,7 Local anesthetics are increasingly used perioperatively via different routes

R E v I E w

open access to scientific and medical research Open Access Full Text Article

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This article was published in the following Dove Press journal:

Journal of Pain Research

13 August 2012

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as part of a multimodal regimen.8 The use of bolus injection

of local anesthetics is limited by duration of post operative

pain relief with the average duration of block via interscalene

injection being 8 to 12 hours with either bupivacaine 0.5% or

catheters are used to increase the duration of postoperative

perineu-ral catheters involves additional training11 in addition to the

Complications due to perineural catheters are infrequent

but can be life threatening, and these complications can

include infection, septicemia, intravascular placement, or

long acting local anesthetics, like liposomal bupivacaine is

potentially important in the management of perioperative pain

This article will review liposomal bupivacaine as a potential

addition to the clinician’s analgesic armamentarium

Liposomal bupivacaine

Liposomes are microscopic structures consisting of a

phospho-lipid bilayer encapsulating an aqueous core They may be

unila-mellar, multilaunila-mellar, or multivesicular Unilamellar liposomes

Figure 1 Scanning electron microscope image of DepoFoam® containing bupivacaine.

Image supplied courtesy of Pacira Pharmaceuticals, Inc, 5 Sylvan way, Parsippany, NJ 07054.

consist of a single lipid bilayer surrounding the aqueous core, whereas multilamellar liposomes consist of concentric lipid layers Multivesicular liposomes (MVL), however, consist of nonconcentric lipid bilayers The nonconcentric nature of MVL confers characteristic drug release patterns from the aqueous core that are different from the unilamellar and multilamellar liposomes, leading to increased stability and longer duration of drug release The release of drug from the MVL requires only a breach in the external layer, and release of a drug from internal vesicles leads to redistribution of the drug within the particle without release The multivesicular structure also ensures that the vesicles rearrange themselves without release of drug by internal fusion and division.14,15 These vesicles can encapsu-late water soluble drugs in their core, and lipid soluble drugs within the membrane They are used in the systemic delivery of antifungals, antineoplastics, and antibiotics.16,17 Currently avail-able liposomal bupivacaine consists of vesicles of bupivacaine

(Pacira Pharmaceuticals Inc, San Diego, CA) Each particle is composed of a honeycomb like structure of numerous internal aqueous chambers containing encapsulated bupivacaine18,19 (Figures 1 and 2)

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Bupivacaine is an amide local anesthetic, which acts by

inac-tivating voltage-dependent sodium channels It has a pKa of

8.1 so only 15% is present in uncharged form at tissue pH

The uncharged fraction of bupivacaine travels across the cell

membrane of the nerve, and once charged binds to the inner

side of sodium channels, inactivating them.20 The release of

bupivacaine from its binding site is slow, which leads to a

longer duration of action than lidocaine.21

Pharmacokinetics

The pharmacokinetics of MVL bupivacaine have been

compared MVL bupivacaine in doses of 9, 18, and 30 mg/kg

with 9 mg/kg of plain bupivacaine injected by wound

for the three doses of MVL bupivacaine, respectively

concentra-tion in the group receiving plain bupivacaine peaked

for the three doses of MVL bupivacaine, respectively Plasma bupivacaine concentrations were detectable in most animals (dogs) who received MVL bupivacaine 9 mg/kg over a 96-hour study period

In the pharmacokinetic study of human volunteers,

of 2% liposomal bupivacaine versus 20 mL of 0.5% plain

liposomal groups, respectively) despite a 4-fold increase

in bupivacaine dose and a 9.8-fold increase in the terminal half-life displayed by the liposomal bupivacaine group

the liposomal bupivacaine group compared to the group administered plain bupivacaine, which was attributable to the slow release of liposomal bupivacaine The attributes of slow release leading to prolonged Tmax and long T ½ leading

to prolonged detectable plasma concentration of liposomal bupivacaine have been confirmed in a subsequent Phase II, multicenter clinical trial conducted by Langford et al.23 Bupivacaine is metabolized mainly in the liver by glucuronide conjugation and hepatic N-dealkylation into pipecolylxylidine Pipecolylxylidine is then hydroxylated and forms glucuronide conjugates A small amount of bupivacaine is excreted unchanged in urine.24 In a phar-macokinetic study of liposomal bupivacaine in patients

although bupivacaine and pipecolylxylidine concentrations were higher in patients with moderate hepatic impairment than in patients with normal hepatic function, the concentra-tion time plots were similar in both groups, and the differ-ences were small enough not to warrant dose adjustments

as per Food and Drug Administration (FDA) guidelines

Efficacy in postoperative pain

Liposomal bupivacaine has been FDA approved for single dose wound infiltration in postoperative pain relief among patients undergoing hemorrhoidectomy and bunionectomy.26 Gorfine et al27 conducted a multicenter, randomized, double blind, placebo-controlled trial in patients undergoing hemorrhoidectomy At the end of surgery, patients were randomized to receive either 300 mg (30 mL) extended release MVL bupivacaine or placebo (30 mL

of 0.9% sodium chloride) in 5 mL increments via wound infiltration Intraoperative use of all analgesics or local anesthetics, except fentanyl, was prohibited unless needed for the treatment of adverse effects Patients remained at the

DepoFoam (non-concentric)

®

10–30 μm

Figure 2 Cross-sectional diagram of DepoFoam containing bupivacaine.

Image supplied courtesy of Pacira Pharmaceuticals, Inc, 5 Sylvan way, Parsippany,

NJ 07054.

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study center for 72 hours, and were administered postsurgical

analgesia in response to breakthrough pain consisting of

morphine sulfate as needed

The primary outcome measure consisted of a cumulative

pain score in the first 72 hours as reflected in the AUC0–72 (area

under the curve) numerical rating score (NRS) of pain

inten-sity Secondary efficacy measures consisted of assessing the

proportion of patients who received no opioid rescue

medica-tions, total amount of opioid rescue medications consumed,

time to first postsurgical use of rescue medications, and the

patient’s rating of satisfaction with postsurgical analgesia

The researchers found the pain scores to be markedly lower

in the bupivacaine extended release group compared to

those receiving the placebo with a least mean square (SE)

AUC ranging from 0 to 72 hours of 141.8 (10.7) in the MVL

bupivacaine group versus 202.5 (10.7) in the placebo group

(P , 0.0001) In the bupivacaine extended release group,

59% of patients were opioid free at 12 hours, and 28% were

opioid free at 72 hours when compared to 14% and 10% in the

placebo group, respectively (P , 0.0008 through 72 hours)

In addition, the mean total amount of opioid consumed was

lower in the MVL bupivacaine group (22.3 mg vs 29.1 mg,

P # 0.0006), and the median time to first opioid use was

longer (14.3 hours vs 1.2 hours with P , 0.0001) and was

associated with greater patient satisfaction with

to placebo

Golf et al28 conducted a multicenter, parallel group,

pla-cebo controlled, randomized, double blind study in which they

compared extended release MVL bupivacaine to placebo in

patients undergoing bunionectomy The patients underwent

primary first metatarsal bunionectomy under midazolam and/

or propofol sedation with Mayo block with up to 25 mL of

2% lidocaine with epinephrine Within 30 minutes after

injec-tion of lidocaine, the patients received either a single dose

of 120 mg (8 mL) extended release bupivacaine or placebo

(8 mL 0.9% sodium chloride) by local infiltration Patients

were observed for 24 hours at the study center Rescue

anal-gesia consisted of 5 mg oxycodone/325 mg acetaminophen

tablets up to a maximum of 12 tablets per day with a single

dose of intravenous ketorolac 15–30 mg as a second rescue

The primary outcome measure was the AUC of NRS pain

scores through 24 hours Secondary outcome measures

consisted of: the proportion of patients who received no

rescue pain medications; AUC of NRS pain scores through

36, 48, 60, and 72 hours; the proportion of patients who

were pain free during the observation period; the time to first

rescue medication use; and total oxycodone/acetaminophen

consumption through 24, 36, 48, 60, and 72 hours The researchers found markedly reduced pain intensity scores at

24 and 36 hours post injection in the MVL bupivacaine group

percentage of patients who were pain free showed a statisti-cally significant difference at 2, 4, 8, and 48 hours only in

the MVL bupivacaine group (P , 0.05), with more patients

in the MVL bupivacaine group not receiving any rescue

pain medication through 24 hours only (P , 0.05) The

time to first opioid use was longer (7.2 hours vs 4.3 hours,

P , 0.0001), and fewer mean total number of oxycodone/

acetaminophen tablets were used through 24 hours (3.8 vs 4.7

to the placebo group

Smoot et al29 conducted a randomized, multicenter, double blind, parallel group, active control study comparing MVL bupivacaine 300 mg to bupivacaine HCl 100 mg (bupi-vacaine 0.5% with epinephrine 1:200,000) in patients under-going bilateral cosmetic submuscular breast augmentation

At the end of the surgical procedure, the patients received either 300 mg of MVL bupivacaine or 100 mg of bupivacaine HCl (with epinephrine) on each side, injected locally at the breast implant pockets at the end of surgery Postoperatively, the patients received 1000 mg of acetaminophen three times daily with rescue analgesia (oxycodone) for breakthrough pain through 96 hours The primary outcome measure was the AUC of NRS pain scores through 72 hours Secondary outcomes consisted of cumulative pain scores at time points other than 72 hours, proportion of patients not requiring rescue analgesia, total amount of rescue opioid medication consumed, and integrated rank assessment through multiple time points

The mean cumulative pain score (numeric rating score with activity through 72 hours) was not significantly dif-ferent in the two groups (441.5 in the MVL bupivacaine

The lack of a difference was attributed to a lack of statisti-cal power The NRS pain score with activity mean (SE) was markedly lower in the MVL bupivacaine group at 8 and 12 hours [4.9 (0.41) and 5.6 (0.40)] compared with the

and 0.0143, respectively] The difference in mean (SE) pain scores at rest was also lower in the MVL bupivacaine group

at 8 hours only compared to the bupivacaine HCl group

[3.5 (0.35) vs 5.0 (0.34) respectively (P = 0.027)] The total amount of postsurgical rescue opioid medication used at

24 and 48 hours was also lower in the MVL bupivacaine

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group compared to the bupivacaine HCl group (P = 0.0211

and 0.0459, respectively)

study comparing wound infiltration of MVL bupivacaine

to bupivacaine HCl for postsurgical analgesia in total

knee arthroplasty They compared 150 mg of bupivacaine

HCl (with 1:200,000 epinephrine) to MVL bupivacaine

in doses of 133 mg, 266 mg, 399 mg, and 532 mg The

patients were between 18–75 years old and were

classi-fied as American Society of Anesthesiologists physical

status 1–3 patients undergoing unilateral knee replacement

under general anesthesia For 24 hours prior to surgery, all

patients received 1000 mg of acetaminophen three times

daily Intraoperatively, only intravenous fentanyl use was

permitted The study medications were diluted in 60 mL of

0.9% saline and were injected via local infiltration in the

deep tissues, the capsulotomy incision, and the subcutaneous

tissues intraoperatively Postoperatively, patients received a

single dose of a nonsteroidal anti-inflammatory drug

paren-tally with oral acetaminophen For rescue analgesia,

patient-controlled intravenous morphine was used until patients could

be switched to oral oxycodone 5–10 mg every 4–6 hours once

oral intake was established The primary outcome measure

was AUC of NRS pain scores with activity (NRS-A) through

day 4 Secondary outcome measures consisted of: AUC of NRS-A through time points other than day 4; AUC of NRS pain scores at rest (NRS-R); NRS-R and NRS-A scores at each assessed time point; total consumption of opioid rescue medications; total consumption of opioid medications; time

to resumption of daily activities; and provider’s satisfaction with postoperative analgesia on day 8

There was no difference between the groups for the primary outcome measure of the mean AUC of NRS pain scores with activity The mean (SD) scores were 20.4 (3.9)

in the bupivacaine HCl group versus 19.1 (4.4), 18.8 (5.3), 19.5 (5.3), and 20.7 (5.4), in the MVL bupivacaine 532 mg,

399 mg, 266 mg, and 133 mg groups, respectively There was no detectable difference in the groups with regard to mean numeric rating scale pain scores, total consumption of rescue opioids, or the time to resumption of work or normal daily activities (Table 1)

1:200,000 epinephrine) with 0.5% liposomal bupivacaine (a multilamellar formulation different from the clinically available multivesicular DepoFoam) administered epidur-ally for the management of postsurgical pain The patients were classified as American Society of Anesthesiologists physical status 2 and 3 undergoing major abdominal surgery

Table 1 Studies comparing the efficacy of MVL bupivacaine versus placebo or bupivacaine HCl

Author Type

of study

Comparison Surgery Primary outcome Results

Gorfine

et al 27

RCT 300 mg DepoFoam

bupivacaine compared with placebo

Hemorrhoidectomy AUC0–72 of NRS

pain intensity scores

Least square mean (SE) AUC0–72 141.8 (10.7)

in the DepoFoam bupivacaine (n = 94) group compared to 202.5 (10.7) in placebo (n = 93) P , 0.0001.

Golf

et al 28

RCT 120 mg DepoFoam

bupivacaine compared with placebo

Bunionectomy AUC0–24 of NRS

pain intensity scores

Least square mean (SE) AUC0–24 123.936 (4.4854) in DepoFoam bupivacaine group (n = 93) compared to 146.233 (4.5869) in placebo (n = 92) P , 0.0005 95% CI

of difference between DepoFoam bupivacaine vs placebo -34.799 to -9.794 Smoot

et al 29

RCT 600 mg DepoFoam

bupivacaine compared with 200 mg bupivacaine HCl with epinephrine 1:200,000

Submuscular augmentation mammoplasty

AUC0–72 of NRS-A pain intensity scores

Mean (SE) AUC0–72 441.5 (23.6) in DepoFoam bupivacaine group (n = 66) and 468.2 (23.0) in bupivacaine HCl group (n = 70) P = 0.3999.

Bramlett

et al 30

RCT Bupivacaine HCl 150 mg

(0.5%) with epinephrine 1:200,000 compared with four doses of DepoFoam bupivacaine (133, 266,

399, and 532 mg)

Total knee arthroplasty

AUC0–96 of NRS-A pain intensity scores

Mean (SD) 20.7 (5.4), 19.5 (5.3), 18.8 (5.3), and 19.1 (4.4) in DepoFoam bupivacaine

133 mg, 266 mg, 399 mg, and 532 mg groups (n = 25, 24, 26, and 21, respectively) and 20.4 (3.9) in the bupivacaine HCl group (n = 30) P value 0.05 in each DepoFoam bupivacaine group compared to bupivacaine HCl group.

Abbreviations: AUC, area under the curve; MVL, multivesicular liposomes; NRS, numerical rating score; NOS, not otherwise specified; NRS-A, numerical rating score with

activity; RCT, randomized clinical trial; SD, standard deviation; SE, standared error.

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The epidural catheter was inserted with a test dose of

bupiva-caine (0.5% 3 mL) with epinephrine 1:200,000 given at the

time of insertion Postoperatively, when patients experienced

pain after complete recovery of motor function, they received

a 10 mL bolus of either liposomal bupivacaine 0.5% or 10 mL

of plain bupivacaine 0.5% (with 1:200,000 epinephrine) The

researchers found no detectable difference in the time of onset

of analgesia (13.75 ±1.25 min in the plain bupivacaine group

versus 13.92 ± 1.58 min in the liposomal bupivacaine group),

though the duration of analgesia increased significantly in

plain bupivacaine group, P , 0.05) In a subset of patients

who underwent abdominal aortic surgery, the duration of

group versus 2.42 ± 0.35 hours in the plain bupivacaine group

(P , 0.001) There was no motor block in the liposomal

bupivacaine group though intraoperative surgical anesthesia

was not observed with the liposomal bupivacaine group The

lack of surgical block was thought to be due to alterations in

the pharmacodynamics of the drug preventing the necessary

amount of free bupivacaine available at the site of action,

thus producing only postsurgical analgesia There are no

studies evaluating the epidural use of DepoFoam bupivacaine

to assess whether the lack of surgical analgesia is seen with

the DepoFoam formulation as well

Safety

Bupivacaine may produce many adverse effects The most

common life threatening side effects involve the

cardiovas-cular and central nervous systems.32,33 Bupivacaine is more

cardiotoxic than lidocaine, and it produces its toxicity by

shown that bupivacaine uncouples oxidative

phosphoryla-tion, may induce apoptosis in muscle cells, and may cause

Schwann cell damage The damage to Schwann cells

hap-pens in both a time as well as a concentration dependent

and may be related to Ca2+-induced apoptosis of muscle cells

The myotoxicity of bupivacaine is most pronounced after

retrobulbar and peribulbar blocks with an overall incidence

of anesthesia-related diplopia reported to be 0.25%.36,37

Although the diplopia may resolve spontaneously, it may

require surgical correction.38

The most common side effects of MVL bupivacaine

in clinical trials included nausea, vomiting,

constipa-tion, pyrexia, dizziness, and headache.28,30 Bergese et al39

compared the cardiac safety of MVL bupivacaine in four

doses (150, 300, 450, or 600 mg) to bupivacaine HCl with epinephrine injected via wound infiltration intraoperatively

in patients undergoing total knee arthroplasty They found

no significant differences in change from baseline in QRS

or QTc duration in the two groups, nor did the two groups differ in mean change from baseline heart rate and PR

of MVL bupivacaine (300, 450, 600, and 750 mg) injected subcutaneously on the QTc interval in healthy volunteers None of the participants receiving MVL bupivacaine had a maximum QTc interval greater than 500 ms, and there were

no changes in QTc of greater than 60 ms at any measured time point

In a 2-year follow up study assessing the effect of MVL bupivacaine on the integrity of breast implants after

impact of intraoperative use of MVL bupivacaine on the integrity of breast implants Local anesthetics have inhibi-tory effects on platelet aggregation in response to different agonists Pinto et al42 studied the effect of multilamellar liposomal local anesthetics on the inhibition of platelet aggre-gation in response to adenosine diphosphate They found that encapsulation of local anesthetics into liposomes increased the inhibitory effect of local anesthetics; however, the clinical impact (if any) of this finding remains to be seen in larger trials In an animal studies by Richard et al18,19 evaluating the safety and efficacy of MVL bupivacaine compared to plain bupivacaine and saline, the authors did find granulomatous inflammation in the MVL bupivacaine group, which was considered to be a normal reaction to liposomes; however, there was no effect on wound healing MVL bupivacaine did not alter wound healing or wound scarring when used for postsurgical analgesia after total knee arthroplasty in humans.30

local anesthetic as it may increase the release of bupivacaine from the liposomes It should not be allowed to come in contact with antiseptics like chlorhexidine or povidine iodine

as they may disrupt the lipid layers leading to uncontrolled release of bupivacaine.43

Discussion

DepoFoam-encapsulated bupivacaine is a new formula-tion of bupivacaine that provides slow sustained release of bupivacaine from multivesicular liposomes Compared to placebo, it has been shown to produce prolonged analgesia with an opioid sparing effect, although more adequately powered trials are needed to assess its efficacy and duration of

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analgesia compared to standard local anesthetic solutions At

present, it is approved by the FDA for use via local infiltration

after bunionectomy and hemorrhoidectomy It has not been

shown to be more toxic compared to plain bupivacaine, and

it does not have markedly different cardiac effects than plain

bupivacaine It appears safe for use in patients with moderate

hepatic impairment and does not warrant dose adjustment in

that group.25 It has not been evaluated for use via

intrathe-cal, epidural, or perineural administration or in pediatric

to evaluate its efficacy and safety in these populations If its

safety and efficacy are established for epidural, intrathecal,

and perineural use, it holds a potentially valuable place in

the analgesic arsenal for use against postoperative pain and

may substantially reduce the cost and complications

associ-ated with catheter and local anesthetic infusion pumps In

addition, the opioid sparing effects of MVL bupivacaine are

valuable in potentially reducing opioid-related side effects

This in turn may reduce unwanted hospital admissions related

to postoperative pain or opioid side effects

In summary, the current literature studying MVL

bupiva-caine has, in general, demonstrated prolonged analgesia and

reduced opioid side effects compared to placebo However, its

increased analgesic efficacy (and cost effectiveness) compared

to plain bupivacaine in various clinical settings needs to be

evaluated in adequately powered clinical trials At present, the

literature supports only a limited role for MVL bupivacaine

This may change as larger studies are conducted

Acknowledgements

Figure 1 and a copy of References 23, 25, 39, and 40 were

provided by Pacira Pharmaceuticals, Inc, 5 Sylvan Way,

Parsippany, NJ 07054 The company had no input in the

preparation or editing of this manuscript

Disclosure

The authors report no conflicts of interest in this work

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