PART TWORESPONSE RESOURCES© 1998 by CRC Press LLC.PART TWO PESTICIDE AND CHEMICAL TABLES AND potx

Pesticides Listed Alphabetically by Trade NameNumber a Manufacturer Category Formulations b CAS Number c Protectant WP, 5-EC 83-4E American Cyanamid Company Gib-berellins Regu-lator Com

PART TWO

RESPONSE RESOURCES

TABLES AND GUIDES

Part Two will provide the information required to apply, store, and pose of specific pesticides and other hazardous chemicals properly This in-formation can be obtained from the following three tables and the pesticideand chemical guides Emergency response guidelines can be found in theguides These guidelines will enable the reader to handle emergency incidentsthat require a quick, accurate, and safe response

dis-I TABLES USAGE

There are three important tables in Part Two The first of these is Table

1 This table lists the trade names or brands of pesticides of current tance alphabetically

impor-The user of a specific product would look up the product’s trade or brandname in Table 1 For example, specific information is needed on the productAAtrex From this table you would learn that the common name of the activeingredient in the product is atrazine Important information on its health haz-ards, recommended handling and storage precautions, PPE and emergencyguidelines could be found by referring to Pesticide Guide 61 The manufac-turer’s name is Ciba-Geigy, the type of pest contol product, e.g., herbicide,and the other formulations available containing this active ingredient Furtherinformation could be obtained by using the CAS Number (i.e., the ChemicalAbstract Service Number) in selected references These references includeSax’s “Dangerous Properties of Industrial Materials,” the “Chris” Manual andRTECs, etc

Table 2 provides the reader with other important information Using thecommon name you can identify the family or group of chemicals that yourchemical of concern belongs to or is derived from If your product is notlisted in this table, using the chemical or common name you can find otherproducts with the same active ingredient and use their guide number

Table 3 lists alphabetically the chemicals that are important to users ofpes ticides These chemicals may b e hazardous in th emselv es and , when u s e d with pesticides as adjuvants, carriers, diluents, anti-caking agents, fertilizers,baits, emulsifiers, or detergents, their activity can be potentiated For exam-

ple, the product you are using requires petroleum oil or xylene as a carrier.The pesticide by itself may be relatively nontoxic, but the addition of xylene

to the product could elevate the product to a Toxicity Category I or II, ing the use of specific PPE, and may also require specific handling and dis-posal procedures

requir-II PESTICIDE AND CHEMICAL GUIDES’ USAGE

The pesticides listed under trade name in Tables 1 and 2 have each beenassigned to a specific pesticide guide These guides have been developed toassist the user in handling various tasks from mixing and applying pesticides

to cleaning up spilled pesticide and disposing of the waste properly Theseguides also provide information on how to handle emergencies involving thelisted pesticides

Over 500 formulated pesticides are listed in the Tables 1 and 2 In order toprovide usable information, these pesticides are organized into groups of p es -ticid es with similar attr ib utes an d h azar ds , and a gu id e w as develo p ed to p ro vid epertinent information for each group As a result there are 61 unique pesticideguides

The hazardous chemicals were treated in a similar fashion and 18 uniquechemical guides were developed to provide similar information

First aid information can be found in Chapter 7, Section E

and information on the handling, storage, clean up, and disposal of mable and nonflammable pesticides and chemicals can be found in Chapter 6,Section V

flam-III HOW TO USE THE PESTICIDE AND CHEMICAL

TABLES AND GUIDES

Each of the pesticides listed in Table 1 is referenced to a specific cide guide number In the event of an incident involving a pesticide, the userwould use Table 1 to determine which pesticide guide to follow in responding

pesti-to that specific incident If the pesticide is suspended in, emulsified with, ordissolved in a chemical that poses a hazard, the user should read the labelcarefully to identify the carrier, emulsifying agent, or other material(s) andthen consult the proper Chemical Guide for that chemical

in water or nonaqueous carriers, EPA toxicity category, handling and storageprecautions.

Protective clothing recommendations, which suggests the PPE that

should be used when mixing, applying, rinsing, or disposing of the pesticide

or chemical

Emergency guidelines, which include fire and explosive hazards, spills

response and remediation, and first aid

The following example will demonstrate the use of the guides

With the advice of the Cooperative Extension Service, you have decided

to apply Asana™XL as a treatment for the cutworms on your field corn fore opening the container, read the label From the label information youdetermine that this product is a restricted use pesticide, meaning that you have

Be-to be a certified applicaBe-tor or work under direct supervision of a certified plicator to apply this product The label also tells what the formulation is.This product is an emulsifiable concentrate that contains 0.66 lbs of activeingredient per gallon The chemical name of the active ingredient is alsogiven as (S)-cyano(3-phenoxyphenyl)methyl-(S)-4-chloro-alpha-(1-methylethyl) benzeneacetate Its percentage of the product is 8.4% The inert ornonactive ingredients are not listed but their percentage of the product is listed

ap-as 91.6% The label also states that the product contains a xylene range matic solvent, EPA registration number 352-515, the signal word WARNING,first aid instructions, environmental hazards, storage and disposal recommen-dations, and directions for use

aro-To access additional information contained in the Pesticide Guides, youwould look up the trade name in Table 1 From this table you learn thatAsana is an insecticide, which is manufactured by the Du Pont AgriculturalProducts and whose common name is Esfenvalerate The information alsoincludes the fact that the active ingredient is only available as an emulsifiableconcentrate The table also tells you to consult Pesticide Guide 53 for moreinformation

From Pesticide Guide 53 you find the following facts:

1) Imminent health hazards and environmental concerns

2) Toxicity of the product

3) Handling and storage precautions

4) Protective equipment to use when mixing and applying the product5) Fire and explosive hazards are present when using this product6) Spill cleanup procedures

7) Suggested first aid treatments

In addition to the above information you should also consult the cal Guides for the chemical xylene, which is the carrier fluid mentioned on thelabel To access the proper guide, first look up xylene in Table 3 From thistable you find that Chemical Guide 10 should be consulted

Chemi-The following information is given in Guide 10:

1) Imminent health hazards and environmental concerns

2) The NFPA-Hazard Rating

3) Handling and storage precautions

4) Recommendations for protective equipment when using this cal

chemi-5) Fire and explosive hazards when using this product

6) Spill cleanup procedures

7) Suggested first aid treatments

Read the label very carefully Most labels contain most of the tion needed to use the product safely However, if the label is vague, missing,

informa-or illegible informa-or if an emergency occurs, you will need to consult these tablesand guides

It is not unusual for a pesticide user, even a trained and certified one, tograb a container of pesticide without reading the label At one time or an-other, virtually every pesticide user has identified a product by the color orgeneral configuration of the label It's a relatively common occurrence, butcertainly not a safe business practice Labels of the same color and generalmakeup may contain very different ingredients How would you know if thepesticide is too toxic or hazardous to be used safely under your intended con-ditions? How do you know the formulation is right for your intended use?How do you know what precautions should be taken when mixing the pesti-cide? How do you know what protective equipment to wear when applying

the material? YOU DON'T - unless you read the label and, when necessary,

consult the following tables and guides

TABLES

ERRATA Agrochemical and Pesticide Safety Handbook

Michael WaxmanPlease note that this listing contains revised Guide Numbers that supercede those in Table 1

39-200,61-75W

Table 1 Pesticides Listed Alphabetically by Trade Name

Number a

Manufacturer Category Formulations b

CAS Number c

Protectant

WP, 5-EC

83-4E

American Cyanamid Company

Gib-berellins

Regu-lator

Company

© 1998 by CRC Press LLC

Table 1 Pesticides Listed Alphabetically by Trade Name

Number a

Manufacturer Category Formulations b

CAS Number c

Company

(NAAm and NAD)

Regu-lator

ascari-cide

Insecti-cide

Company

© 1998 by CRC Press LLC

Michael F Waxman

Table 1 Pesticides Listed Alphabetically by Trade Name

Company

Company

FWP

3337-71-1

WP

1912-24-9

17-PC

Regu-lator

water-oil emulsion, WP

55219-65-3

© 1998 by CRC Press LLC

Table 1 Pesticides Listed Alphabetically by Trade Name

Phen-medipham

kurstaki

benthio-carb

Protectant

WP,

1897-45-6

© 1998 by CRC Press LLC

Michael F Waxman

Table 1 Pesticides Listed Alphabetically by Trade Name

Number a

Manufacturer Category Formulations b

CAS Number c

liquid

NA

salt

Metribuzin

Protectant

Hydrochlo-ride

Regu-lator

Company

© 1998 by CRC Press LLC

Table 1 Pesticides Listed Alphabetically by Trade Name

Number a

Manufacturer Category Formulations b

CAS Number c

thifensulfuron-methyl

Company

Insecticide, cide

Microencapsu-lated

15972-60-8

Company

Plant Growth lator

© 1998 by CRC Press LLC

Michael F Waxman

Table 1 Pesticides Listed Alphabetically by Trade Name

American Cyanamid Company

nemati-cide

D, EC, G, ULV,WP, Microencapsulated

333-41-5

100-G, DF, WP

regu-lator

kurstaki

© 1998 by CRC Press LLC

Table 1 Pesticides Listed Alphabetically by Trade Name

91-G

Regu-lator

gran-ule), L

NA

© 1998 by CRC Press LLC

Michael F Waxman

Table 1 Pesticides Listed Alphabetically by Trade Name

Number a

Manufacturer Category Formulations b

CAS Number c

Me-tasulfuron methyl

penetrant

Lindane

Fungi-cide

israelensis

© 1998 by CRC Press LLC

Table 1 Pesticides Listed Alphabetically by Trade Name

Number a

Manufacturer Category Formulations b

CAS Number c

higher fatty acids

Company

kurstaki

microencap-sulated

333-41-5

© 1998 by CRC Press LLC

Michael F Waxman

Table 1 Pesticides Listed Alphabetically by Trade Name

Number a

Manufacturer Category Formulations b

CAS Number c

and Glyphosate

Microencapsu-lated

15972-60-8

Ascricide

Nemati-cide

(Oxythio-quinox)

© 1998 by CRC Press LLC

Table 1 Pesticides Listed Alphabetically by Trade Name

100-G

Company

sus-pension

NA

Regu-lator

© 1998 by CRC Press LLC

Michael F Waxman

Table 1 Pesticides Listed Alphabetically by Trade Name

Number a

Manufacturer Category Formulations b

CAS Number c

Company

Pendi-methalin

Company

© 1998 by CRC Press LLC

Table 1 Pesticides Listed Alphabetically by Trade Name

Number a

Manufacturer Category Formulations b

CAS Number c

Regu-lator

Metalaxyl

(Quintozene)

92-D-Pak

Company

© 1998 by CRC Press LLC

Michael F Waxman

Table 1 Pesticides Listed Alphabetically by Trade Name

Number a

Manufacturer Category Formulations b

CAS Number c

lator

Pro-tectant

Regula-tor

Pendi-methalin

Company

dichlo-ride

© 1998 by CRC Press LLC

Table 1 Pesticides Listed Alphabetically by Trade Name

Number a

Manufacturer Category Formulations b

CAS Number c

Company

Company

© 1998 by CRC Press LLC

Michael F Waxman

Table 1 Pesticides Listed Alphabetically by Trade Name

Number a

Manufacturer Category Formulations b

CAS Number c

and MCPA

acid)

Regu-lator

bacteria

Protectant

Metribuzin

© 1998 by CRC Press LLC

Table 1 Pesticides Listed Alphabetically by Trade Name

Number a

Manufacturer Category Formulations b

CAS Number c

91-75W

Protectant

Methylisothiocyanate

Nematicide

(2,4-DP)

65-WP

a The Pesticide Guide Number is assigned to a particular group of pesticides with a specific set of properties This guide contains all the information required to dle those pesticides properly and safely (see Errata for correct guide number).

han-b The formulations commercially available for this brand See Chapter 4 for the meaning of the abbreviation used for the formulations.

c A unique numbering system established by the Chemical Abstract Service Each chemical formulation is given a specific number Therefore, different formulations

of the same chemical will have different CAS numbers.

© 1998 by CRC Press LLC

NA used to designate that the CAS number is not abailable.

d

Table 2 Pesticides Listed Alphabetically by Common Name

Spray

dipropyl-p-toluidine Alachor and Trifluralin Freedom Acetanilide and dinitroaniline 2-chloro-2',6'-diethyl-N-(methoxy-methyl)acetanilide and a,a,a trifluoro-2,6-dinitro-N,N-

dipropyl-p-toluidine

© 1998 by CRC Press LLC

Table 2 Pesticides Listed Alphabetically by Common Name

Ammonium soaps of higher fatty acids

Bacillus thuringiensis, var israelensis

Bacillus thuringiensis, var kurstaki

Bacillus thuringiensis, var kurstaki

© 1998 by CRC Press LLC

Michael F Waxman

Table 2 Pesticides Listed Alphabetically by Common Name

Bacillus thuringiensis, var kurstaki

Copo-phos

© 1998 by CRC Press LLC

Table 2 Pesticides Listed Alphabetically by Common Name

aromatic

5,6-dihydro-2-methyl-N-phenyl-1,4-oxathiin-3-carboxamide and pentachloronitrobenzene Carboxin and Thiram RTU-Vitavax-Thiram Oxathiin and thiocarbamate 5,6-dihydro-2-methyl-N-phenyl-1,4-oxathiin-3-carboxamide and bis(dimethylthiocarbamoyl)

disulfide or tetramethylthiuram disulfide

disulfide Carboxin, Diazinon, and

O-[6-methyl-Chinomethionat (Oxythioquinox)

Chlorimuron ethyl and Linuron

urea

Ethyl 2-[[[[(4-chloro-6-methoxy-2-pyrimidindinyl)amino]carbonyl]-amino]sulfonyl]benzoate and 3-(3,4-dichlorophenyl)-1-methoxy-1-methylurea

Chlorimuron ethyl and Metribuzin

and 4-amino-6-(1,1-dimethylethyl)-3-(methylthio)-1,2,4-triazin-5(4H)-one

© 1998 by CRC Press LLC

Michael F Waxman

Table 2 Pesticides Listed Alphabetically by Common Name

Chlorimuron ethyl and Metribuzin

2-[[[[(4-chloro-6-methoxy-2-pyrimidindinyl)amino]carbonyl]-amino]sulfonyl]benzoate and triazin-5(4H)-one

4-amino-6-(1,1-dimethylethyl)-3-(methylthio)-1,2,4-Chlorimuron-ethyl and thifensulfuron-methyl

2-[[[[(4-chloro-6-methoxy-2-pyrimidindinyl)amino]carbonyl]-amino]sulfonyl]benzoate and Methyl yl)amino]carbonyl]amino]sulfonyl]-2-thiophencarboxylate

Chlorothalonil and Metalaxyl

phenylamide

Tetrachloroisophthalonitrile and alanine methyl ester

benzenesulfona-mide

benzenesulfona-mide Chlorsulfuron and Me-

tasulfuron methyl

benzenesulfona-mide and methyl 2-[[[[(4-methoxy-6-methyl-1,3,5-triazin-2 yl)-amino]carbonyl] amino]sulfonyl] benzoate

heptane

Clomazone and ralin

dini-troaniline

2-[(2-chlorophenyl)methyl]-4,4-dimethyl-3-isoxazolidinone and a,a,a dinitro-N,N-dipropyl-p-toluidine

© 1998 by CRC Press LLC

Table 2 Pesticides Listed Alphabetically by Common Name

chlorin-ated phenoxy

3,6-dichloropicolinic acid and 2,4-dichlorophenoxyacetic acid

distill)

Picolinic acid and ated phenoxy

chlorin-3,6-dichloropicolinic acid and (4-chloro-2-methyl)phenoxyacetic acid

Cyanazine and chlor

2-chloro-N-(2-ethyl-6-methylphenyl)-N-(2-methoxy-1-methylethyl) Acetamide

ben-zoic acid

2,4-dichlorophenoxyacetic acid and 3,6-dichloro-2-methoxybenzoic acid

Chlorophe-noxy acids

2,4-dichlorophenoxyacetic acid and 4-amino-3,5,6-trichloropicolinic acid

chloro-pyridinyl

2,4-dichlorophenoxyacetic acid and (3,5,6-trichloro-2-pyridinyloxy) acetic acid

© 1998 by CRC Press LLC

Michael F Waxman

Table 2 Pesticides Listed Alphabetically by Common Name

2,4-D, and prop(2,4-DP)

2,4-D, and prop(2,4-DP)

2,4-D, dimethyl-amine salt

2,4-D, dimethyl-amine salt

2,4-D, isopropylamine salt and Glyphosate

phosphonate

2,4-dichlorophenoxyacetic acid and isopropyl-amine salt of glycine

N-(phosphonomethyl)-2,4-DB (dimethyl-amine salt)

Desmedipham and Phenmedipham

m-methylcarbanilate ester

phospho-nate

3,6-dichloro-2-methoxybenzoic acid and isopropylamine salt of glycine

fumigant

1,3-dichloropropene Dichloropropene and

Table 2 Pesticides Listed Alphabetically by Common Name

Dichloropropene and Methylisothiocyanate

and isothiocyanate

1,3-dichloropropene, methylisothio cyanate and other chlorinated C3 hydrocarbons

Difenzoquat Methyl Sulfate

H/A

Disodium sonate

phos-phorodithioate

3-oxide

3-oxide

© 1998 by CRC Press LLC

Michael F Waxman

Table 2 Pesticides Listed Alphabetically by Common Name

salts

salts

Her-bicidet

Regu-lator

Ethoxylated fatty amines

Ornamental

© 1998 by CRC Press LLC

Table 2 Pesticides Listed Alphabetically by Common Name

Fenoxaprop-ethyl,

2,4-D, and MCPA

2,4-dichlorophenoxyacetic acid and (4-chloro-2-methyl)phenoxyacetic acid

N-[[[4-[[[[(4-chlorophenyl)cyclopropyl-methylene]amino]oxy]methyl]phenyl]carbonyl]-2,6-difluorobenzamide

2-chloro-N-[2,6-dinitro-4-(trifluoromethyl)phenyl]-N-ethyl-6-fluoro-benzenemethanamine

Formetanate ride

monohy-drochloride

acid 1,4a-lactone

© 1998 by CRC Press LLC

Michael F Waxman

Table 2 Pesticides Listed Alphabetically by Common Name

acid 1,4a-lactone

acid 1,4a-lactone

Gibberellins and ladenine

[3-[4-(trifluoromethyl)phenyl]-1-[2-[4-(trifluoro-methyl)phenyl]rthenyl]-2-propenylidene] hydrazone

(±)-2-(4-isopropyl-4-methyl-5-oxo-2-imidazolin-2-yl) methyl ester

Granule

2-[4,5-dihydro-4-methyl-(1-methylethyl)-5-oxo-1H-imidazol-2-yl]-3-quinolinecarboxylic acid

-3-quinolinecarboxylic acid Imazaquin and pendi-

methalin

dinitro-analine

(±)2-[4,5-dihydro-4-methyl-4-(1-methylethyl)-5-oxo-1H-imidazol-2-yl] quinolinecarboxylic acid and N-(1-ethylpropyl)-3,4-dimethyl-2,6-dinitrobenzenamine

dinitroani-line

quinolinecarboxylic acid and a,a,a trifluoro-2,6-dinitro-N,N-dipropyl-p-toluidine

(±)-2-[4,5-dihydro-4-methyl-4-(1-methylethyl)-5-oxo-1H-imidazol2-yl]-5-ethyl-3-© 1998 by CRC Press LLC

Table 2 Pesticides Listed Alphabetically by Common Name

pyridine carboxylic acid

(±)-2-[4,5-dihydro-4-methyl-4-(1-methylethyl)-5-oxo-1H-imidazol2-yl]-5-ethyl-3-pyridine carboxylic acid Imazethapyr and pendi-

methalin

dinitroani-line

pyridine carboxylic acid and N-(1-ethylpropyl)-3,4-dimethyl-2,6-dinitrobenzenamine

3-(2-chloro-3,3,3-trifluoroprop-1-enyl)-2,2-dimethylcyclopropanecarboxylate

2,3,5,6-tetrafluoro-4-methylphenyl)-methyl-1a,3a,)-(Z)-(±)-3-(2-chloro-3,3,3-trifluoro-1-propenyl)-2,2-dimethylcyclopropanecarboxylate

phen-ylamide

Zn ion and manganese ethylene bisdithiocarbamate and (methoxyacetyl(-DL-alanine methyl ester

sodium

MCPA, dimethylamine salt

© 1998 by CRC Press LLC