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Since the phase transformations can be activated un-der very different conditions to obtain different effects, to have a picture of SMMs behavior, it is necessary to see how stress and t

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SHAPE MEMORY ALLOYS, TYPES AND FUNCTIONALITIES 961

important conclusion is that for most practical

constrain-ing conditions, only a small fraction of martensite is

ac-tually transforming during the constrained heating and

cooling Therefore, the observed hysteresis is much smaller

than the overall hysteresis, typically below 10 K for Ni–Ti,

below 5K for Ni–Ti–Cu, and below 2K for the R-phase

transformation (99,114)

As stated before, it is often assumed that stress changes

linearly as temperature changes Moreover, the stress rate

dσr/dT is often considered a material constant directly

de-rived from a Clausius–Clapeyron equation Such

descrip-tions should be considered very elementary simplificadescrip-tions

The results in Fig 5 show clearly that the stress rate

de-creases during constrained heating It has been also found

that the stress is affected by many other parameters,

in-cluding the thermomechanical history and the prestrain

(69,86)

Depending on the magnitude of the prestrain, either

a plastic upper limit or an elastic upper limit to σr

ex-ists At lower prestrains, the stress increases during

heat-ing until the reverse transformation is completed The

upper stress limit in this case is given by the strain

di-vided by Young’s modulus When the prestrain is

suffi-ciently high, the stress increases during heating until

plas-tic yield occurs at a temperature Md So, the upper stress

limit in this case is the plastic yield stressσy Evidently, in

cyclic actuation, the maximum temperature should be kept

below Md

In all cases discussed, a constraint prevents the SMA

el-ement from returning to the hot shape when heated Thus,

a more specific name would be “hot shape” recovery stress

It has been found in trained Cu-based SMA-elements that

stresses can also be generated when the TWME is

im-peded during cooling (69,83) Because the constraint in

this case prevents the sample from returning to the cold

shape when cooled, the generated stress was called “cold

shape” recovery stress to contrast with “hot shape”

recov-ery stress Practical applications have not been reported so

far

Quantitative comprehension of recovery stress

genera-tion presented in the literature is far below the

comprehen-sion of the other functional properties of shape-memory

al-loys Therefore, recovery stress generation was discussed

a bit more extensively than other functional properties

Considering the substantial research efforts in developing

hybrid composites that have embedded shape-memory

ele-ments, substantial progress in quantitatively

understand-ing recovery stress generation can be expected in the near

future

Work Output

One- and two-way memory effects can be used for free

re-covery applications in which the single function of the SMA

element is to cause motions without any biasing stress

Under constant strains, shape-memory elements can

generate substantial recovery stresses Between these two

extremes of free recovery and completely constrained

re-covery, shape-memory components can yield a wide

var-iety of combinations of strains and stresses As shown in

F T

Figure 6 The work output The sample is deformed at a

tem-perature at a below Mf(A →B), followed by unloading (B→C) and

loading again using a bias weight W (C→D) Shape recovery

oc-curs under an opposing force W during heating to a temperature

above Af (D →E) So work is done [from (69)].

Fig 6, a shape-memory element can be deformed by lowforce in the martensitic condition or during the forwardtransformation and can exert a substantially higher force

as it reverts to the hot shape when heated So, work up

to 5 J/g is done during heating This concept can be used

in thermal actuators in which the SMA element is vated by an increase in the environmental temperature,

acti-or in electrical actuatacti-ors in which the SMA element is ingeneral activated by direct Joule heating The work needed

to deform the SMA element is much lower than the workthat can be obtained during heating This has been the ba-sis of many prototypes of heat engines that convert heatinto useful work [see (117)]

SMA actuators offer distinct advantages comparedother types of actuators (118) The main advantage is that

by far SMA actuators offer the highest work and to-weight ratios of all available actuating technologies atlow levels of weight (119) These high-work and high-powerdensities enable a whole class of applications (e.g., in thefield of micro actuation) that are impossible to realize byusing other actuating technologies (120–123) SMA actua-tors can be reduced mostly to a single SMA element withoutauxiliary parts, resulting in simple compact and reliabledevices

power-Several important drawbacks that limit the use of SMAactuators to specific niches should also be considered Theconversion of heat into mechanical energy via SMA actua-tors was studied extensively 15 to 25 years ago Simplethermodynamic calculations showed that the maximumtheoretical efficiency of an SMA actuator is less than 10%(124) In practice, the conversion of heat into mechanicalwork is less efficient, and the result is that real efficiency iseven one order of magnitude smaller than the theoreticalvalue Another drawback is that the SMA actuator has to

be heated and cooled The low cooling rate, especially limitsthe use of SMA actuators to relatively low-frequency ap-plications It was discussed before that stresses in trainedCu-based SMA elements can also be generated when the

Trang 3

TWME is impeded during cooling Similarly, it has been

shown that these trained SMA elements can do a small

amount of work during cooling (82,83)

High Damping Capacity

SMA elements have high damping capacity in the

austenitic and martensitic conditions Shape-memory

al-loys show strong amplitude-dependent internal friction in

the martensitic condition For impact loads, the specific

damping capacity can be as high as 90% Starting from

the austenitic condition, energy is dissipated during

su-perelastic cycling as a result of stress hysteresis between

superelastic loading and unloading, as explained before A

detailed analysis can be found in (125,126)

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SHAPE-MEMORY MATERIALS, MODELING

DAVIDEBERNARDINI Universit `a di Roma “La Sapienza”

Rome, Italy

THOMASJ PENCE Michigan State University East Lansing, MI

INTRODUCTION

An understanding of shape-memory behavior requiresknowledge of various physical processes that operate ondifferent length scales The crystallographic shifts thatare responsible for shape-memory behavior take place inunit cells of atomic dimension Here, however, these mi-croscopic length scales are not the focus, rather, this arti-cle considers the macroscopic scale modeling that allowsfor the engineering assessment of thermomechanical re-sponse (stress–strain–temperature) and energy balances(including damping) for devices such as connectors, actua-tors, vibration absorbers, and biomedical stents The macroscale is useful for primary design evaluation such as pre-dicting triggering forces and determining range of motion.Since the shape-memory material is typically incorporatedinto a larger engineered device or structure, there is also aneed for detailed computational simulation of the system

as a whole

BASIC MATERIAL BEHAVIOR AND MODELING ISSUES

The term shape-memory material (SMM) is meant to

en-compass a wide class of metallic alloys with the commonfeature that they exhibit, at the macroscopic scale, somepeculiar and useful functional properties such as pseu-doelasticity and shape memory Nickel-titanium (NiTi) isperhaps the best known and most widely used such ma-terial SMM functional properties derive from transforma-

tions between two different solid phases: austenite (A) and martensite (M) Aspects of the A↔ M phase transforma-

tion are essential for model development and tation In addition, certain intermediate phases may alsooccur, but these are neglected here because their effect onthe macroscopic response is small in comparison

implemen-The A↔ M transformation can be induced by a

vari-ety of energy inputs (mechanical, thermal, magnetic, trasonic, etc.), and it is influenced by grain boundaries,dislocations, inclusions, and other material defects Thisarticle considers the standard thermomechanical setting,

ul-namely the A↔ M transformation that is induced by

tem-perature T and stress σ In general, austenite is favored at

high temperatures and low stress, whereas martensite isfavored at low temperatures and high stress We will use a

boldface σ (and ε) to denote a general stress and strain

ten-sors with componentsσ i j(andε i j) Models involving only

a single stress componentσ will be developed more than

those involving the tensor σ.

Austenite is of higher crystallographic symmetry and socan transform into one or more martensite variants thatdiffer mainly by their orientation relation to the austenite

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SHAPE-MEMORY MATERIALS, MODELING 965

Figure 1 A phase diagram defines the zones of the (σ, T )-plane

where the various phase transformations can occur Each curve

represents the (σ, T )-points at which a transformation can either

be activated or else completed Hence there are two curves (start

and finish) for each transformation The figure shows a sketch of

a phase diagram that can arise when the SMM is modeled as a

mixture of austenite A and two martensite variants M+, M− Such

a diagram can be viewed as an unfolding of a conventional phase

diagram triple point so as to include the effects of phase mixing

and transformational hysteresis.

parent By contrast, all martensite variants tend to

trans-form into a single common austenite crystal structure

The transformation from the A structure to that of a

par-ticular M variant is characterized by a crystallographic

transformation strain Typically, an A material region

transforms into a martensitic microstructure with several

variants that combine in complicated twin arrangements

and plate morphologies These microstructures provide a

local transformation strain γ This in turn gives a

macro-scopic transformation strain ε∗ at the engineering scale

This ε∗gives a potentially large strain in stress-induced

A→ M transformations It is negligible in cooling-induced

A→ M transformations because the resulting

microstruc-tures involve so-called self-accommodated martensite with

local strains γ∗that cancel each other

Since the phase transformations can be activated

un-der very different conditions to obtain different effects, to

have a picture of SMMs behavior, it is necessary to see

how stress and temperature differ with respect to A↔ M

transformation Figure 1 shows a stress and temperature

phase diagram of a single austenite phase A and two

fam-ilies of martensite variants M+ and M− The curves in

this diagram show the relation between stress and

tem-perature levels at which various phase transformations

begin and end This partitions the (σ, T )-plane into three

single phase regions, three double phase regions, and a

triple phase region

Purely Thermal Transformation

In the absence of stress, austenite is stable at high

tem-peratures, and martensite is stable at low temperatures

Stress-free cooling of austenite gives A → M conversion

beginning and concluding at temperatures M s and M f,

re-spectively (M f < M s) The resulting microstructure is an

unbiased martensite with a fine-scale arrangement of

vari-ant twins with opposing local transformation strainsγ

This produces a negligible engineering scale tion strainε∗= 0 Similarly, a temperature increase causes

transforma-M → A conversion, the start and finish temperatures

being A s and A f , with A f > A s The transformation

tem-peratures M f , M s , A s , and A fare the basic material eters for purely thermal transformations They are highlysensitive to the alloy concentrations and to the granularand defect structure as determined by heat treatment andcold work Once the material is ready for service, thesetemperatures are easily determined by various means in-cluding resistivity and calorimetry testing

param-Low-Temperature Martensite Reorientation

Austenite is not present at temperatures below M f.Nonzero stress at these low temperatures causes certainmartensite variants to be relatively more favored Thisfavoritism correlates with the value of the transforma-

tion work σ · γ= σ i j γ

i j In the important special case ofuniaxial tension/compression, the variants favored in ten-sion are those for whichγ∗projects onto the tensile axis as

a positive quantity It is convenient to group all of the

vari-ants favored in tension into an M+ variant family, and all variants favored in compression into an M− variant fam- ily Unbiassed martensite involves a mixture of both M+

and M− Sufficiently high tensile loading at temperatures

below M f causes movement of the internal boundariesseparating the martensite plates, which can be viewed

as a conversion from the M− family into the M+ family This M− → M+ transformation yields biased martensite,

namelyε∗= 0 Unloading does not cause the reverse

trans-formation (M+ → M−) so long as the load does not

be-come compressive Hence the transformation strain ε∗ islike a conventional plastic strain upon unloading (Fig 2)

The M− ↔ M+ transformation is referred to as

reorien-tation As a result, a plasticlike reorientation plateau is

observed on the isothermal stress–strain curve, with thetensile reorientation beginning and concluding at stresses

σ+

s andσ+

f (σ+

f > σ+

s > 0) These reorientation stresses are

relatively insensitive to temperature changes (there may

Low temperature reorientation

Figure 2 Sketch of the macroscopic effects of the various phase

transformations in the stress–strain–temperature (σ -ε-T) space

(left) Effect of the loading rate on the pseudoelastic behavior:

faster loads give rise to greater hardening and temperature

vari-ations (right, where t denotes time).

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decrease) Similar reorientation processes occur in

com-pressive loading due to the M+ → M− transformation,

with the start and finish of the reorientation plateau

Austenite can be present at temperatures above M f Such

austenite is converted to biased martensite upon

applica-tion of sufficiently high stress, either tensile (activating

A → M+) or compressive (activating A → M−).

Consider the tensile case A stress increase gives the

A→ M+ transformation, which again generates a plateau

on the stress–strain diagram This is referred to as a

pseu-doelastic plateau so as to distinguish it from the

reorien-tation plateau observed at the lower temperatures For

T > A f, the start and finish stresses for pseudoelasticity

are greater than the M− → M+ reorientation stresses

σ+

s andσ+

f They are also highly temperature sensitive, creasing with temperature at an approximately constant

in-rate However, if the temperature is close to Mf, then

little distinction can be made between pseudoelasticity and

reorientation because the loading plateau stresses match

the reorientation valuesσ+

s andσ+

f Unloading activates

the M+ → A transformation if T > As, resulting in an

un-loading plateau below the A→ M+ loading plateau The

unloading plateau rejoins the loading curve if M+ → A

goes to completion (T > A f), and so defines a hysteresis

loop (Fig 2) At temperatures A s < T < A f, the M+ → A

unloading conversion does not go to completion and the

un-loading plateau intersects the strain axis before reaching

the origin of the stress-strain diagram If T < A s, then the

M+ → A transformation is not even activated upon

unload-ing Thus, in all cases where T < A f, there is some residual

strain due to the presence of M+ martensite when

unload-ing is complete

Shape-Memory Effect

At all temperatures, where T < A f, after sufficiently high

load causing either A → M+ or M− → M+ transformation,

residual strain is present after unloading due to the

pres-ence of biased martensite Unlike conventional plastic flow

in metals (generated by dislocations) the SMM plasticlike

residual strain is recovered by heating above A f, because

this converts martensite to austenite Since this

austen-ite converts to unbiased martensausten-ite upon any later

stress-free cooling, the residual plastic strain does not return

(unless there is further loading/unloading) This

heat-ing/cooling elimination of an apparently “plastic” strain

due to previous loading/unloading is the shape-memory

effect.

While the preceding discussion has covered the basic

aspects of the material behavior that macroscopic models

should reproduce, SMM is often employed in situations

in-volving further effects that are important objectives for

useful modeling The most important of these are briefly

described next

Response to Complex Loading Paths

At constant temperature, loading reversals that interrupt

A → M and M → A before completion lead to internal

subloops within the major stress–strain hysteresis loopassociated with complete transformation Load paths in-

volving simulataneous change in T and σ generally

aug-ment or diminish transformation that would occur undereither T orσ alone This is critical for modeling the rate

effect that is described next

Rate Dependency due to Transformational Heating

If mechanical loads producing phase transformation arenot applied in a quasi-static way, then temperature varia-tion occurs in the sample and a rate-dependent response isobserved This is due to the exothermic and endothermic

nature of the A → M and M → A transformations,

re-spectively During A→ M the material self-heats and the

temperature rise works against the transformation

(con-versely during M→ A the sample self-cools) This might

involve a number of consequences: different onset stressesfor transformation plateaus, plateau steepening, and vari-ation in the shape of internal loops (Fig 2) The extent

of this effect is governed by the heat exchange with theenvironment: high rates of loading can cause significantdeparture from isothermal behavior High rates of loadingcan occur in both actuator and damping shape-memory de-vices

Tension/Compression Asymmetries

In uniaxial loading, significant differences in the stress–strain behavior have been observed between tension andcompression This is due to the different microstructures

that the formed In particular, the behavior of the M+

vari-ant family in tension is not the symmetric image of the

behavior of the M− variant family in compression Such

a phenomenon is modeled by a phase diagram that is symmetric with respects toσ

un-Three-Dimensional States

In the three-dimensional case involving tensor σ rather

than scalarσ, the experimental behavior is less well

un-derstood, and complex multivariant structures are to beexpected in most cases A key issue in three-dimensionalmodeling is the proper constitutive description of an appro-priate local transformation strain that transcends the lack

of information about the actual multivariant ture In view of the correlation of variant favoritism with

microstruc-the transformation work σ · γ= σ i j γ

i j, some sort of iality relations between stress and transformation strainare conjectured at modeling scales appropriate to a multi-variant microstructure These difficulties are compoundedunder nonproportional loading, since the transformationstrain then evolves as a consequence of both pseudoelastic

coax-A ↔ M processes and M ↔ M reorientation of existing

variants

STATE OF THE ART AND HISTORICAL DEVELOPMENTS

Modeling of the macroscopic behavior of SMM has beenthe subject of much activity since the beginning of the1980s, attracting the interest of engineers, applied mathe-maticians, and materials scientists This section surveysthe state of the art on the basis of the huge literature

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SHAPE-MEMORY MATERIALS, MODELING 967

available on the subject The survey is restricted to models

that directly relate to macroscopic modeling and does not

delve into the voluminous literature on metal physics and

purely microstructural development, even though much of

this literature provides enormous insight While an effort

has been made to be rather comprehensive, the survey is

still far from complete We have attempted to give

care-ful bibliographic references by selecting one

representa-tive paper for each approach Each of these models then

typically gives rise to refinements, generalizations,

verifi-cation studies, and implementation strategies For the sake

of conciseness, complete bibliographic references cannot be

given for all of these modeling extensions

The discussion of the previous section makes clear that

the behavior of SMM observable at the macroscopic scale

is the effect of several complex microstructural

pheno-mena This section is organized, as in the list below, with

respect to contributions that include an explicit model

for such microstructural phenomena and others that do

not Although certain models that will be discussed can

be viewed as spanning more than one such approach, the

classification given below aids in organizing the numerous

modeling approaches that have been proposed

Approaches modeling one or

more microstructural

phenomena

Lattice cell mechanics Interface nucleation and propagation

Approaches Modeling One or More

Microstructural Phenomena

Models included in this group are grounded in theories that

analyze the material at a scale in which the multiphase

na-ture of the material is rendered explicit and one or more

effects of phase transformations can be described by some

direct microstructural model Macroscopic behavior is then

recovered by some kind of averaging procedure In a

con-tinuum setting, this implies that each point belongs to one

phase and the first spatial derivatives of the displacement

and temperature fields can be discontinuous

Lattice Cell Mechanics In this approach, the

macro-scopic response of the material is determined by

study-ing the behavior of a collection of lattice cells that can

be in a particular phase or phase variant In response to

loads and temperature changes at the system boundary,

cell transitions between different phases can take place

Two approaches for the transition kinetics can be broadly

identified: statistical mechanics and strain energy

minimi-zation.

The statistical mechanics approach has roots in Muller

and Wilmanski (1) and has been further developed by

Achenbach (2) The cellular array is grouped as a stack of

layered aggregates of cells that can be found in one of the

Figure 3 The three-well energy function of the

Muller-Achenbach model without (left) or with (right) mechanical load.

Each minimum corresponds to a phase with different structure

(austenite A and two martensite variants M+, M− ) The ences among the ordinates of the various minima represent the en- ergy barriers that cells have to overcome to undergo phase trans- formations The right graph shows the effect of a mechanical load

differ-P that lowers the right minumum and causes the M+ phase to be the energetical favorite.

three phases: austenite A and two martensite variants

M+, M−; each characterized by a different cell length Cellsare in random thermal motion, and thermal fluctuationspermit them to transform from one phase to another Suchtransitions lead to variations in the stack compositionthat are monitored by the phase fractions ξA , ξ+, and ξ− A three-well potential energy φ whose minima are

each associated with one phase is the basic tive ingredient from which all material parameters arederived by statistical arguments (Fig 3) Macroscopicstrain and temperature are obtained respectively fromthe normalized length of the whole layer aggregate andfrom a measure of the thermal fluctuation The phasefraction evolution is governed by a system of ordinarydifferential equations expressing the transition ratebalance between layers on the basis of the probability ofovercoming the energy barriers that separate the minima

constitu-of φ This finally provides a complete model for uniaxial

stress pseudoelasticity and reorientation

A second approach for the description of the transitionsbetween lattice cells is based on strain energy minimiza-tion A model developed by Morris and his collaborators(3) involves a multidimensional lattice of cells with cor-responding multidimensional transformation strains foreach cell The total free energy is the sum of a temperature-dependent chemical free energy and a strain-dependentelastic strain energy The strain energy contribution ishighly dependent on cell location and choice of transforma-tion variant, due to the constraint of surrounding cells Thecomputation is based on isotropic elasticity, and the under-lying mathematical technique developed by Khachaturyanrequires equality of elastic constants in all phases For agiven change in temperature, the overall transformationprocess is simulated by a stepwise energy minimization

At each step, the particular cell that transforms is selected

as the one that most lowers the energy, and such mations continue so long as the overall energy is lowered.Complex microstructures and internal stress states occur.These complex states are the main focus of such modeling,

transfor-as opposed to providing a macroscopic model for overallstress–strain–temperature behavior

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Interface Nucleation and Propagation Large

deforma-tion theories of continuum mechanics have also been used

to treat martensitic phase transformation These

treat-ments stem from analysis by Ericksen of a uniaxial

con-tinuum with a nonconvex elastic strain energy density

(4) These energies give rise to nonmonotone stress–strain

curves Fundamental thermodynamic arguments harking

back to Gibbs and Maxwell indicate that strains on the

de-scending branches of these stress–strain curves are

unsta-ble in that they cannot be part of a deformation field that

minimizes energy Energy minimization naturally gives

rise to distinct material regions, each involving

continu-ous strain, that are separated from each other by

inter-faces across which the strain is discontinuous so as to

avoid unstable branches The connection to stress-induced

phase transformation follows by placing the distinct stable

branches of the stress–strain curve into correspondence

with distinct material phases Avoidance of the unstable

branches is then formally similar to spinodal

decomposi-tion One outgrowth of this work has focused on putting the

crystallographic theory of martensite on a rigorous

mathe-matical foundation so as to predict microstructure without

invoking the approximations inherent in the linear theory

of elasticity (5–7)

The fundamental nature of much of the work cited

im-mediately above renders it outside the scope of this

model-ing survey However, under suitable interpretation, certain

treatments of this type do provide a macroscopic model for

the thermomechanical behavior of shape-memory

materi-als In particular, SMM uniaxial response follows from a

thermoelastic free-energy density with either two or three

minima that each define a distinct phase Boundary value

problems give solutions in which the continuum is

subdi-vided via phase boundary interfaces into different phase

regions Phase transformation proceeds from the

nucle-ation of new interfaces or from the propagnucle-ation of the

ex-isting ones (8) The jump in the Gibbs free energy across

the interface follows from the Eshelby energy-momentum

tensor in the form of a generally nonzero driving traction

Phase boundary movement gives either energy dissipation

or energy accumulation as determined by the direction of

interface motion Standard boundary value problems do

not have a unique solution when phase boundaries are

present unless the constitutive theory is augmented with

both interface nucleation criteria and interface kinetic

mo-tion criteria These typically depend on the driving

trac-tion, and they can be formulated so that the overall load–

displacement–temperature relation reproduces

pseudoe-lastic and reorientation behavior Kinetic criteria can be

derived, for example, similarly to that of Achenbach and

Muller, so as to involve a probability of overcoming the

en-ergy barriers between phases on the basis of thermal

fluc-tuation Quasi-static and fully dynamic treatments follow

for isothermal, adiabatic, and heat conducting cases The

kinetic motion criteria can be extracted from more refined

theories in which the phase boundaries are regarded as

transition zones exhibiting additional physical effects (9)

Micromechanics In the models of this group each

mac-roscopic point is put in correspondence with a

represen-tative volume element (RVE) of a multiphase material in

P

RVE ΩMacroscopic scale

Microscopic scale

A

M

Figure 4 Macroscopic versus microscopic scale modeling Each

macroscopic point P corresponds to a microscopic region

the multiphase nature of the alloy (A, M) can be appreciated

ex-plicitly At the macroscopic scale the features of described by the internal variablesα.

which some regions are subjected to local transformationstrains due to the different crystal structure of the phases(Fig 4)

Under proper boundary conditions, a boundary valueproblem on the RVE that models the effects of the phasetransformations is obtained Local quantities are volumeaveraged over the RVE, giving macroscopic quantities thatgenerally retain a dependence on the microstructural fea-tures through some overall descriptorα (usually the phase

fractionsξ) The resulting equations for the macroscopic

behavior fit into the framework of internal variable els, as described later in this section Constitutive ingre-dients are a macroscopic free-energy function and a set

mod-of kinetic rate equations for the microstructural tors α The free energy provides, via partial differentia-

descrip-tion with respect to stress (or strain), equadescrip-tions for strain(or stress) while derivatives with respect to α give gen-

eralized forces that drive the phase transformations Thefree-energy functions are structured as the sum of an elas-tic strain energy and a chemical a free energy While thechemical contribution is specified mainly by standard ther-modynamic expressions, the elastic term varies consider-ably among such models as it follows from different mi-cromechanic assumptions on the accommodation processdue to phase interaction (10) Kinetic equations are de-rived from phase transformation criteria stating that thetransformations occur when the generalized driving forcesmeet experimentally determined threshold values.Patoor, Eberhardt, and Berveiller initiated such anapproach in 1987 by combining ideas from transforma-tion plasticity, continuum micromechanics, and crystallo-graphic theories of martensitic transformation (11) In itsrecent formulation, their model considers, at the single-crystal level, a linear elastic RVE consisting of an austen-ite matrix with inclusions of 24 martensite variants, eachexhibiting a local transformation strain computable fromthe lattice parameters Each variant is assumed to grow,mixed with austenite, in a well-defined cluster The inter-action energy describing the accommodation between pairs

of variants is then computed using the interfacial tor method of Hill The minimization of this interactionenergy determines the cluster orientation and the over-all free energy finally depends only on the variant frac-tions At the polycrystalline level, a second RVE consisting

opera-of nontextured assemblies opera-of spherical grains is ered and a self-consistent approach is used to derive the

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consid-SHAPE-MEMORY MATERIALS, MODELING 969

final macroscopic constitutive equations Large numerical

simulations involving the representation of each grain are

required Comparisons with experimental data are given,

mainly for uniaxial stress, and show good agreement even

in the prediction of tension–compression asymmetry

Re-cent developments also include the consideration of

non-isothermal behavior Promising applications of this model

have been proposed by Gall and Sehitoglu (1999) who used

experimentally determined grain orientation distribution

functions to simulate the effect of texture

In 1993, Sun and Hwang proposed to treat the

prob-lem focusing directly on the polycrystals with an RVE

con-sisting of grains that are each wholly in the austenite or

martensite phase The phase interaction energy is

com-puted using Mori-Tanaka theory by considering martensite

grains as randomly dispersed spherical inclusions within

the matrix of austenite grains While martensite is

con-sidered as a single phase without explicitly accounting

for the different variant orientations, neglect of the

mul-tivariant structure is overcome by proposing a direct

re-lation between the local transformation strain and the

average stress in the matrix so as to simulate the

bias-ing effect of stress in the variant selection process The

local transformation strain is therefore not strictly

crys-tallographic, and the resulting description is in terms of

an equivalent transformation strain Reorientation effects

are taken into account by introducing a second martensite

fraction Issues related to nonproportional loading are also

discussed (12)

Starting in the early 1990s, Levitas developed

mod-els from a somewhat different viewpoint (13) The SMM

is modeled as a dissipative material already at the

mi-croscale where, due to the phase transformations, relevant

field quantities vary between two values reflecting an

un-derlying two-phase model for the microstructure A

first-averaging procedure is performed over an internal time

scale representative of the transformation duration in

or-der to obtain an average dissipation rate and driving force

Different energetic transformation criteria are given: an

overall nucleation criterion results after integration over

the RVE while a criterion for interface propagation is given

after integration over the propagating interface An

ex-tremum principle with respect to the variation of the RVE

boundary conditions is invoked to determine the evolution

of the microstructural parameters

Goo and Lexcellent (14) proposed a model for single

crystals based on a free-energy function and a

dissipa-tion rate funcdissipa-tion The free-energy funcdissipa-tion is derived by

a self-consistent evaluation of internal stresses among the

phases The model allows for nonisothermal behavior,

re-orientation, and two-way shape-memory effect The

influ-ence of the interaction energy on the macroscopic modeling

is examined, and the comparisons with experimental data

under uniaxial stress show good agreement with the

mod-eling prediction

The analysis of Lu and Weng (15) treats each grain as

a mixture of austenite and a single martensite variant

whose local transformation strain is computed from lattice

parameters The particular variant is selected in analogy

with the Patel-Cohen criterion on maximum

transforma-tion work Polycrystals are then modeled by an assembly of

nontextured spherical grains, and a self-consistent method

is used to compute the macroscopic response As with thePatoor-Eberhardt-Berveiller model, this requires large nu-merical simulations involving the representation of eachgrain

Huang and Brinson (16) propose a different tural model at the single-crystal level An austenitematrix with martensite inclusions made of groups of self-accomodating variants, each exhibiting the local crystal-lographic transformation strain, is arranged in a wayreminiscent of the experimentally observed wedgelike mi-crostructure Free energy is then computed by assuming

microstruc-a rmicrostruc-andom distribution of such inclusions thmicrostruc-at microstruc-are tmicrostruc-aken to

be of spherical shape This idealization is shown to be ful in modeling thermally activated transformations andlow-temperature reorientation The model captures alsothe tension/compression asymmetry and the different re-sponse observed experimentally when the loading direc-tion varies with respect to crystal axes The model hasbeen extended to cover penny-shaped inclusions and poly-crystalline behavior by studying an assembly of nontex-tured spherical grains homogenized by a self-consistentmethod

use-Summarizing, micromechanic approaches incorporateseveral features into the modeling, including the effect

of a multiple-variant microstructure and the effect of itspolycrystalline texture This permits explanations for mostmacroscopically observed behaviors, though certain de-tailed issues remain under discussion Such issues includethe determination of the number of variants and the mod-eling of their arrangement (17), as well as the modeling ofnonproportional multi-axial loading; for recent experimen-tal studies, see (18,19)

Approaches Modeling Directly the Macroscopic Behavior

Direct modeling will be understood as including theorieswhere each point of the material, instead of being in anidentifiably distinct phase, is representative of a phasemixture whose microstructural features are described byone or more descriptive variables In a continuum setting,the associated strain and temperature gradient fields arecontinuous

Models without Internal Variables In such models the

material behavior is described by strain, stress, ature, and entropy without the introduction of quantitiesrepresenting the phase mixture Constitutive information

temper-is provided by a free-energy function whose partial tives provide constitutive equations for strain (or stress)and entropy

deriva-In 1980, Falk proposed a Landau-Devonshire type

of free-energy function based on the analogy betweenSMM uniaxial stress–strain curves and the electric field–magnetization curves of ferromagnetic materials (20).Nonmonotone stress–strain curves are obtained, and theunstable negative slope part is interpreted as the occur-rence of the phase transition The actual pattern followedduring transformation is assumed to proceed at constantstress The particular form of the Landau-Devonshire free-energy accounts for the temperature dependence of the

Trang 11

ε

Figure 5 Nonmonotone stress–strain curves The negative slope

part is unstable and the dashed lines represent an assumed

trans-formation path.

isothermal stress–strain behavior Hysteresis arises as

consequence of the different stress levels of the extremal

points of the unstable region, as indicated in Fig 5

Under suitable interpretation, many aspects of this

model correspond to aspects of Ericksen’s treatment and

its subsequent extensions In particular, although the time

evolution of a phase transformation is not treated directly,

such information can be inferred by associating the extent

of the transformation with the strain distance on the

con-stant stress transitions

Hysteresis Models Hysteresis models seek to reproduce

experimentally observed curves that involve high

nonlin-earity and complex looping They have been widely used in

several fields, with that of magnetic materials being most

developed In this approach, constitutive equations are

pro-posed directly on the basis of their mathematical

proper-ties, often without explicit focus on their link with the

phys-ical phenomena of interest Reliability and the robustness

of the model are favorably matched to experiments, and the

resulting algorithm allows for the treatment of arbitrarily

complex driving input

Two main algorithm classes have received special

atten-tion in the context of SMM phase transformaatten-tion The first

one is based on tracking subdomain conversion/reversion

and lead to integral based algorithms The most common of

these is known as the Preisach algorithm and it has been

used to describe uniaxial isothermal pseudoelastic stress–

strain SMM response (21,22)

The second algorithm class involves differential

equa-tions with separate forms for driving input increase and

driving input decrease Differential equations of

Duhem-Madelung form have been used to model SMM phase

frac-tion evolufrac-tion during thermally induced transformafrac-tion

(23,24) This gives phase fraction subloops for temperature

histories obeying M f < T (t) < A f Under sustained

ther-mal cycling, these subloops collapse onto a final limiting

subloop, with the resulting shakedown behavior

register-ing the fadregister-ing influence of the initial phase-fraction state

By being formulated so as to link the internal variable of

phase fraction to the driving force variable of temperature,

such algorithms lend themselves to a wider internal

vari-able framework as is described next

Models with Internal Variables The key feature of this

approach is to introduce one or more internal variables

(order parameters) α describing the internal structure of

the material (see again Fig 4) A general thermodynamicaltreatment then proceeds by providing equations for theevolution of these internal variables (23,26) The first ap-plication of such an approach to SMM seems to be due

to Tanaka and Nagaki (27) where internal variables areemployed to describe the development of the underlying

phase mixture The internal variables α, along with a

set of mechanical and thermal control variables, then

de-fine a collection of state variables s Typical mechanical control variables are either strain ε or stress σ Typical

thermal control variables are either temperature T or

en-tropyη The internal variables α typically include one or more phase fractions ξ and/or macroscopic transformation

strains For example,

The temperature gradient∇T must also be incorporated

into s if heat conduction is considered The theory is

com-posed of the physical laws, the constitutive equations that characterize the features typical of each material, and ma- terial behavior requirements that ensure thermodynamical

process restrictions

Constitutive information is specified by two kinds of lations:

re-1 State equations for the entities that are conjugate

to the control variables These can be formulateddirectly or else obtained as partial derivatives of

a suitable free energy function after enforcing theClausius-Duhem inequality for every process The

Gibbs free-energy G is appropriate for Eq (1) and

constitu-heat flux q (usually the Fourier equation) is also

re-quired The relation between microscale phenomenaand the structure of the macroscale free-energy func-tions is discussed in (10)

2 A set of kinetic equations for the internal variables

α In view of phase transformation hysteresis, theseequations generally depend on the past history of thematerial Standard practice in most internal variablemodels is to specify this dependence through equa-tions relating the rates of the internal variables to thestate and its time derivatives The internal state thenfollows from the solution of differential equations intime:



F (s, ˙s) = 0 typically giving ˙α = f (s, ˙σ, ˙T ),

(3)and often linear in ˙σand ˙T as well The superposed

dot in Eq (3) denotes time differentiation

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SHAPE-MEMORY MATERIALS, MODELING 971

The full thermomechanical behavior of a system

involv-ing SMM is then described by a complete “initial value

problem”: given an initial state, an initial time, and an

arbitrary loading history, predict the state reached by the

system at subsequent times This initial value problem is

governed by the preceding constitutive equations together

with appropriate initial and boundary conditions and with

the physical laws of:

Energy conservation (first law of thermodynamics)

˙e = σ · ˙ε + ˙Q, (4)

Conservation of linear momentum (equation of motion)

Entropy balance and Clausius-Duhem inequality

(sec-ond law of thermodynamics)

 = ˙η − Q˙

where e is the internal energy, ρ the mass density, ˙ Q the

rate of heat exchange with the environment (positive if

ab-sorbed by the SMM), u the displacement, b the body force

density, and the internal entropy density production rate.

The Gibbs free energy is G = e − Tη − σ · ε.

Although sometimes employing formalisms that are

quite different, several models fitting into this basic

frame-work have been proposed to describe SMM behavior

Irrespective of their derivation, they involve a

constitu-tive description prescribed via state equations and kinetic

equations Differences involve the choice and

interpreta-tion of the internal variables α and the form of the kinetic

equations The following survey proceeds in chronological

order, using a common notation that may depart from that

of the original work

One of the first explicit macroscopic models for SMM

has been given by Tanaka and his coworkers for

uniax-ial isothermal pseudoelasticity (28) This model for A↔ M

transformation employs one scalar internal variable, the

martensite fractionξ M, together with strain and

temper-ature as control variables so that α = {ξ M} and s=

{ε, T, ξ M} The constitutive equation for stress is given

asσ = L(ε − ε∗), where the overall transformation strain

is ε= γξ M Here L is the elastic modulus and γ∗ the

local transformation strain, both of which are regarded

as material parameters The kinetic equation for the

martensite fraction ξ M is derived from a dissipation

po-tential resulting in a form analogous to the exponential

Koistinen-Marburger relation used in metallurgy The

ki-netic equation is especially simple and so enables closed

form integration to give

β F = a M (M s − T) + b M σ,

β R = a A ( A s − T) + b A σ, where a M , b M , a A and b Aare material constants

In 1987 Fr´emond proposed a three-dimensional modelbased on the following state description:

s= {ε, T, ξ A , ξ+, ξ, ∇ξ A , ∇ξ+, ∇ξ},

where ξ A , ξ+, ξ− are the fractions of austenite and twomartensite variants and∇ denotes gradient (29) The freeenergy is the sum of the pure phase energies weighted bythe respective fractions plus a term aimed to enforce theconstraintξ A + ξ++ ξ .= 1 The evolution equations arederived from a dissipation potential The balance equa-tions governing the model are derived on the basis of theprinciple of virtual power taking into account explicitlythe contribution of the internal variables The model per-formances are discussed within simplified constitutive as-sumptions, and show the ability of the model to capture themain qualitative features of pseudoelasticy and low tem-perature reorientation

In 1988 Bondaryev and Wayman developed a surface plasticity theory for SMM to account for three-dimensional isothermal pseudoelasticity and reorienta-tion (30) This yields a three-dimensional framework thatwould allow for the generalization of many of the uniaxialstress models that are the major focus of this article The

multi-macroscopic transformation strain tensor ε∗is treated as

an internal variable on its own so that s= {σ, T, ε∗} Freeenergies are given for the austenite phase and for a gen-eral martensite phase in which the transformation strain is

of arbitrary orientation The free-energy difference amongthe phases initiates the transformation activity when re-sistive the thresholds are met This defines temperature-dependent threshold surfaces in stress space, which areanalogous to traditional yield surfaces These surfaces,

govern transformation strain accumulation (A→ M),

re-duction (M→ A), and reorientation (M → M) The change

in transformation strain proceeds according to a ity condition with respect to these threshold surfaces and

normal-so determines the orientation of a transformation strainincrement This gives:

A→ M: Transformation strain increment dε∗coaxialwith the stress deviator

M→ A: Transformation strain annihilated without

regard to stress orientation

M→ M: dε∗ oriented according to the difference tween the current stress deviator orientation and thecurrentε∗orientation

be-The magnitude of the transformation strain incrementfollows by analogy to traditional yield surface plasticity.Under hardening, continued plastic straining requires asustained increase in stress A consistency condition for re-maining on the evolving yield surface then determines themagnitude of the plastic strain increment In the absence

of hardening, the yield surface is fixed so that continuedplastic straining can be sustained under constant stress.The magnitude of the plastic strain increment is then de-termined from boundary conditions Bondaryev-Wayman

initially present A→ M and M → A thresholds that do not

harden (corresponding to M s = M ffor A→ M and A s = A f

Trang 13

for M→ A) In contrast, the M → M reorientation

thresh-old is naturally dependent on the currentε∗and so exhibits

a changing form analogous to hardening At any instant

of time there may be (1) no transformation, (2) a single

transformation from among A→ M, M → A, M → M, or

(3) a multiple transformation consisting of M→ M in

con-cert with one of M→ A, A → M Case 3 requires the

de-termination of a transformation strain incremental

mul-tiplier for each simultaneous process Modifications are

then presented for A→ M and M → A threshold

harden-ing (M s > M f and A s < A f) The few model predictions that

are presented confirm the correct qualitative features of

this approach, but a detailed discussion of the full range of

model predictions is not given

Muller and his coworkers (31) proposed one of the first

models for stress–strain curve sublooping when phase

transformations do not go to completion The main

con-stitutive ingredient of the theory is an overall Helmholtz

free energy of the form

(ε A , ε M , T, ξ M)= (1 − ξ M)φ A(ε A , T ) + ξ M φ M(ε M , T )

M(1− ξ M),

whereφA, φM, εA, εM are the free energies and strains of

the pure phases andξ M is the martensite fraction

inter-nal variable The last term is a phase interaction energy,

with

ε = (1 − ξ M)ε A + ξ M ε M Values ofξ M , ε A, andε M are

deter-mined by minimizing under strain constraint As in the

models of Ericksen (4) and Falk (20), the resulting uniaxial

stress–strain response is nonmonotone with the negative

slope part being unstable Constant stress lines from the

maxima and minima define a stress–strain outer envelope

loop associated with complete transformations The

unsta-ble negative slope portion of the stress–strain response

then provides a triggering threshold for phase

transfor-mations within the interior of the stress-strain envelope

(Fig 6) The associated model for internal sublooping

deter-mines the evolution ofξ Mand so, roughly speaking, plays

a similar role to the kinetic evolution equations in other

internal variable models

Ortin and planes have developed a detailed

thermody-namic framework for SMM materials (32) that provides a

basis for thermomechanical modeling and the

experimen-tal determination of material characterization parameters

They develop a model uniaxial stress, describing the state

as s= {σ, T, ξ M} Energy balance during phase

transforma-tion generates a transformatransforma-tion kinetic in which the

free-energy differential during transformation is balanced by

the sum of an elastic energy storage rate differential and an

energy dissipation rate differential The evolution ofσ and

T then determines the evolution of ξ Monce the dissipation

rate is given a constitutive prescription Dissipation

func-tions can be constructed so as to ensure known qualitative

aspects of phase transformation hysteresis, including fine

sublooping features Experimental data fitting with

refer-ence to purely thermal transformation allows for explicit

functional forms Full stress–strain–temperature

depen-dence for uniaxial A↔ M transformation then follows.

In 1990, Liang and Rogers proposed a modification of

the Tanaka A↔ M transformation model so as to account

for the effect of phase fraction values at the beginning ofthe transformation in the event of an initial phase mixture(33) This allows for the treatment of internal subloops.They also replaced the exponential Koistinen-Marburgerkinetic equation with a trigonometric expression, giving

whereξ0is the value ofξ Mwhen the transformation process

is first activated andβ F , β Rare as given previously

In 1992, Raniecki, Tanaka, and Lexcellent proposed

a model for three-dimensional pseudoelasticity based on

the martensite fraction as internal variable so that s=

{ε, T, ξ M} (34) They proposed a Helmholtz free-energyfunction in the form

given as ε= γξ M The local transformation strain tensor

γ∗is assumed to be traceless and coaxial with the straindeviator In this context the phase equilibrium corresponds

to the vanishing of the quantity = ∂ /∂ξ M, which is

iden-tified as the driving force for A↔ M phase transformation.

The condition = 0 gives rise to a stress–strain curve with

a descending branch which, as in Muller’s model, triggersthe activation of certain transformations (Fig 6) Here,however, the transformation evolution is described by akinetic equation forξM A generalized expression for such

a kinetic equation is proposed and includes the exponentialform of Tanaka as a special case Subsequent development

of the model includes the incorporation of micromechanicalconsiderations into the derivation of the free energy and

the proposal of a modified relation between γ∗and the state

σ

ε

Figure 6 Modeling of subloops in a model of Muller (31) The

up-per and lower constant stress lines arise as in Fig 5 and bound an internal region in stress–strain space where subloops can occur.

If a transformation associated with these bounding lines is terrupted before completion due to load reversal, then the stress– strain path enters the internal region The reverse transformation

in-is only activated if the internal path encounters the negatively sloped line associated with unstable stress–strain response.

Trang 14

SHAPE-MEMORY MATERIALS, MODELING 973

variables so as to capture an optimal variant arrangement

on the assumption that the actual value of γ∗minimizes

the free energy

In 1993, Brinson proposed a further extension of the

Tanaka-Liang-Rogers model in order to distinguish

be-tween stress-induced (oriented) martensite and thermally

induced (unbiased) martensite (35) Accordingly, ξ M=

ξ s + ξ Twhereξ sis the fraction of stress-induced martensite

resulting in a local transformation strainγ∗andξ Tis the

fraction of thermally induced self-accommodated

marten-site resulting in a zero transformation strain Hence α=

{ξ s , ξ T}, and the resulting model gives a true shape-memory

capability, formally absent in the earlier

Tanaka-Liang-Rogers model, in that transformation strain at zero stress

is annihilated on heating without reappearing on cooling

Kinetic equations for ξ s and ξ T then model both A↔ M

pseudoelasticity and low-temperature conversion of

ther-mally induced martensite to oriented martensite under

isothermal uniaxial stress Subsequent development

ex-plicitly correlates the kinetic equations to the (σ, T )-phase

diagram, with the resulting model permiting both

analyt-ical and numeranalyt-ical treatment of initial value problems for

uniaxial response (36)

In 1994, Ivshin and Pence proposed a model for uniaxial

pseudoelasticity based on s= {σ, T, ξ A }, where ξ A = 1 − ξ M

is the austenite phase fraction (24,37) State equations are

given for strain and entropy by assuming that the pure

phases are subject to a common overall stress Kinetic

equations are given in terms of the Duhem-Madelung

hys-teresis algorithm Both stress and temperature-induced

A↔ M transformation are treated in a unifying

thermody-namic framework by the identification of the proper driving

input via the Clausius-Clapeyron equation This allows

for a straightforward treatment of arbitrary

thermomecha-nical loading paths in (σ T )-space under uniaxial tension.

Load-cycling behavior and the resulting shakedown

re-sponse are then easily determined Unlike earlier

treat-ments, rate effects due to heating and cooling intrinsic

in the A↔ M transformation are systematically

investi-gated To treat uniaxial compression in the same

frame-work, Wu and Pence (38) decompose the martensite phase

into two martensite variant families M+ and M− each

characterized by its own transformation strain and,

respec-tively, favored under tension (M+) or compression (M−)

Accordingly, ξ M = ξ++ ξ, leading to s= {σ, T, ξ+, ξ−} In

this setting, unbiased (thermally induced) martensite is

the specific mixture of the two variant families giving zero

overall transformation strain While maintaining all of the

features of the Ivshin-Pence formulation, the Wu-Pence

model provides a complete uniaxial description for SMM

not only at temperatures near A fbut also at temperatures

well below M f where reorientation applies

In Lubliner and Auricchio (39), a three-dimensional

model for isothermal pseudoelasticity is proposed on the

basis of s= {σ, T, ξ M , v}, where v defines the

orienta-tion of εvia ε= γv and γ∗ is a material parameter

Kinetic equations for v andξ Mare given by normality

con-ditions to proper loading functions specified for each type

of transformation A Drucker-Prager form is taken for v

so as to treat the dependence of phase transformation on

hydrostatic stress Pseudoelasticity and high-temperature

reorientation as induced by nonproportional loads are sidered In the uniaxial setting, the Brinson decomposition

con-ξ M = ξ s + ξ Tis introduced to account for low-temperaturereorientation The extension to finite kinematics is develo-ped Numerical implementation is given in the context offinite elements

Boyd and Lagoudas (40) present a three-dimensional

model for SMM behavior based on s= {σ, T, ξ M , ε∗} Afree energy with a structure similar to that of Muller isgeneralized so that the phase interaction term is speci-fied by a series expansion whose coefficients are left to ex-perimental identification The macroscopic transformationstrain rate is decomposed into the sum of a pseudoelastic

and a reorientation contribution, ˙ε= ˙ε pe + ˙ε re Similar toTanaka et al (28), dissipation potentials are used to de-rive kinetic equations for ˙ξ M , ˙ε re , while ˙ε pe is related to

the martensite fraction rate via ˙ε pe = Λ˙ξ M The

orienta-tion tensor Λ is assumed as coaxial with a modified stress deviator for A→ M transformation, whereas it is aligned with the εdeviator for M→ A transformation Various

aspects of the model, such as sublooping, connection withmicromechanics, and numeral implementation, have beendeveloped in subsequent papers

Rajagopal and Srinivasa (41) apply the concept of rials with multiple natural configurations to uniaxial pseu-doelasticity with the martensite fractionξM acting as aninternal variable The Green-Naghdi approach to balanceand constitutive equations is used together with a principle

mate-of maximum dissipation This elegant treatment accountsfor nonisothermal behavior and finite deformations within

a rigorous and innovative framework of continuum momechanics

ther-Sittner, Stalmans, and Tokuda (18) have developed

a hysteretic model for uniaxial pseudoelasticity based

on a martensite fraction that is governed by an tion equation with a driving force that involves the con-cept of an effective equilibrium temperature This effec-tive equilibrium temperature, which generally differs fromthe actual material temperature, is formally dependent

evolu-on the martensite volume fractievolu-on Unlike other models,the macroscopic transformation strain is assumed in thefrom ε= χγξ M, where χ = χ(σ ) is a nonlinear stress-

dependent function The model is able to capture a widevariety of sublooping behavior including a notion of returnpoint memory

Within the setting of finite kinematics Govindjee andHall (42) present a model based on two martensite vari-ants M+ and M− A phase diagram approach is used,and the transformation kinetics are derived by argumentsreminiscent to those of Muller-Achenbach and Abeyaratne-Knowles The resulting model allows for both pseudoelas-ticity and reorientation Algorithmic issues specific to finiteelement implementation are carefully considered, and civilengineering scale applications are presented

A COMPREHENSIVE MODEL FOR UNIAXIAL STRESS

As seen from the previous section, SMM uniaxial behavior

is well understood This covers a wide range of applicationsincluding several kinds of actuators, vibration absorbers,

Trang 15

and applications exploiting the material in the form of

wires Models available for this setting treat

reorienta-tion, shape memory, and pseudoelasticity under arbitrary

temperature-stress paths so as to reproduce

nonisother-mal behavior, transformational heating/cooling, and

inter-nal subloops Accordingly, this section summarizes a

prac-tical and complete one stress-component material model

It synthesizes aspects of the previous section’s discussion

with a focus on the complementary roles of state equations

and kinetic equations in generating a well-posed and

com-plete model The development is framed in the context of

tensile and compressive loading, although it also applies

to other choices of stress component, such as a

particu-lar shear stress component The equations that are

pre-sented in the final implementation follow those of Ivshin

and Pence (24,37) and Wu and Pence (38), although the

discussion is framed so as to permit alternative

implemen-tations

The SMM is treated as subject to mechanical loads

specified by histories of prescribed stressσ(t) or strain ε(t)

or a combination of both (e.g., representing bias springs in

actuators among elastic restraints) and thermal loads

spec-ified by histories of prescribed temperature or heat rate

Al-ternatively, under mechanical loads, the temperature can

be determined as a consequence of the heat exchange with

a known environmental temperature T E

The state in Eq (1) is given by s= {σ, T, α} with α =

+> 0, representing the maximum positive

macro-scopic transformation strain when an M+ microstructure

is maximally oriented with the tensile stress Similarly, the

M−family has an associated scalar transformation strain

State Equations for Strain and Entropy

The first group of constitutive equations are obtained from

a Gibbs free energy that is taken as

G(s) = ξ A g A(σ A , T) + ξ+g+(σ+, T) + ξg−(σ, T), (8)

where g A , g+, g− andσ A , σ+, σ− are the free energies and

the stresses relative to the pure phase The phase stresses

depend on the microstructural phase arrangement This

arrangement is henceforth regarded as giving

In conditions different from Eq (9), an additional term

ex-pressing the interaction energy between the phases would

otherwise arise (10) In the present model, hysteresis

prop-erties that would be influenced by such an interaction

en-ergy are instead modeled with the aid of envelope functions

introduced below This permits easy specification of desired

thermal hysteresis properties

Standard forms for the pure phase free energies are

g A= −12

σ2

E+− γ∗ +σ − m+σ(T − T∗)+ C+

Here E A , E+, E− are the elastic moduli; m A , m+, m − are

the coefficients of thermal expansion, and C A , C+, C

are the specific heats at constant stress of the ous phases The expressions (10) make use of a stress-temperature reference state (σ, T) = (O, T∗), which is re-garded as at the center of the multiphase region of Fig 1

vari-by taking T∗as the average of the four transformation peratures The constantsη A0, η+0, η−0 and g A0 , g+0, g−0arethe single-phase entropies and single-phase free energies

tem-at this reference sttem-ate Additional simplifictem-ation follows byassuming the following:

rA common specific heat C in martensite and austenite.

rA common reference state entropyη Moin all site variants

marten-rNegligible thermal expansion.

rNegligible slip plasticity.

None of these simplifications is essential, and the ciated generalizations are easily made According to thegeneral formulation, the macroscopic strain and entropyfollow from Eq (2) as

asso-ε = − ∂G ∂σ = Dσ + ε, η = − ∂G ∂T = CIn T

T+ η0, (11)where

the Reuss estimate of the effective compliance Introduce

η 0 = η A0 − η M0, whereuponη 0(ξ) = η M0 + ξ A η 0 Otherthan the baseline value ofη in Eq (11), the model depen-

dence onη M0andη A0is only via the basic material eterη 0 > 0 It is given by η 0 = H/T∗whereH is the

param-latent heat of the M→ A transformation as measured from

, C These eleven parameters are

suffi-cient for modeling the basic SMM behavior with the

ex-ception of M− ↔ M+reorientation As will be explained inwhat follows, reorientation is modeled by including four

Trang 16

SHAPE-MEMORY MATERIALS, MODELING 975

additional material parametersσ+

s , σ+

f , σ

s , σ

f All 15 terial parameters are taken to be positive by definition

ma-Phase Transformation Kinetics

The second group of constitutive equations give the phase

transformation kinetics The model derives such equations

from two constitutive ingredients that are, in principle,

both experimentally measurable:

rThe phase diagram that defines the loci of the points

in the stress-temperature plane in which the variousphase transformations can be activated (an example

of which is reported in Fig 1)

rThe envelope functions ζ M →A (T) and ζ A →M (T) that, as

explained below, determine the equations for the ternal variables thus describing how the phase trans-formations evolve once activated

in-Here, ζ A →M (T ) is the value of ξ A associated with σ = 0

and T decreasing from above A f to below M f Similarly,

ζ M →A (T ) is the value of ξ Aassociated withσ = 0 and T

in-creasing from below M f to above A f Each function has

a graph that monotonically increases from zero to one

as T increases over an appropriate interval: M f < T < M s

for ζ A →M (T ); A s < T < A f for ζ M →A (T ) In the absence of

detailed experimental data, these functions can be

proximated on their transition interval The simplest

ap-proximation is a linear function of T, but this gives a

slope change at the associated start and finish

tempera-tures Such slope changes give rise to sharp corners on the

model stress-strain curves at the beginning and end of the

transformation plateaus Smoother forms, which eliminate

such corners, involve hyperbolic or trigonometric functions

A simple and useful representation is the Liang-Rogers

For the sake of clarity of exposition, it is useful to discuss

the features of the phase transformation kinetics with

ref-erence first to purely thermal transformation and then to

combined stress and thermally induced transformation

Purely Thermal Transformation In this case the driving

input is the temperature history T(t) Times t of

temper-ature reversal are switching instants The martensite is

then unbiased in that it involves M+and M−in the ratio

, λ−= γ+∗

γ∗ ++ γ

and ξ M = ξ++ ξ= 1 − ξ A is the overall martensite tion The transformation kinetic reduces to the determina-tion ofξ A as T changes The graph of ξ A versus T will gener-

frac-ally involve complicated sublooping if there are numerous

switching instants obeying M f < T < A f that prevent the

M→ A and A → M transformations from going to

comple-tion However, no matter how complicated, this graph will

be contained between the two envelope functions so that

con-such as d ξ M /dT = H A →M(ξ A , T ) for A → M The

center-pieces of Eq (15) are the governing functions H M →A and

H A →M, which must be formulated so that the phase fractionobeys the envelope containment conditionζ M →A (T ) ≤ ξ A

ζ A →M (T ) Envelope coincidence must occur for

transforma-tions that begin from a pure M or a pure A state so long

as temperature reversal is avoided The following generalform for the governing functions ensures these properties:

flat-that enhanced experimental correlation is obtained for n near n = 3 Further refinements and modifications can be

invoked, and certain sublooping situations that are cult to describe with a D-M equation have been noted (44)

diffi-Some examples of (T , ξ A)-trajectories within the boundingenvelope functions are shown in Fig 7

The purely thermal process involves simultaneous

A→ M+and A→ M−transformation for temperature

de-crease, and simultaneous M+→ A and M→ A

transfor-mation for temperature increase, always with ξ+= λ+ξ M

and ξ− = λ−ξM It follows thatξ M can be eliminated from

Eq (15) by rewriting them as

Trang 17

Figure 7 Magnetic susceptibility versus T under purely

ther-mal loading for a NiTi thin film as determined by measurement

(above) Magnetic susceptibility correlates directly with austenite

phase fraction Both the outer hysteresis loops for cooling (upper

envelope) and heating (lower envelope) are shown The internal

curves leave the upper envelope if T is increased before A → M

transformation is complete This behavior is modeled (below) on

the basis of Eq (15), with a hyperbolic tangent envelope form and

H M →A governing function with n= 3.

These equations, in conjunction with Eq (7), determine

the evolution of the phase fraction variablesξ A , ξ+, ξ−for

purely thermal transformation Although unwieldy

com-pared to Eq (15), the alternative formulations (17) and

(18) recast the phase transformation kinetic in terms of

the internal variables α = {ξ A , ξ+, ξ−}

Pseudoelasticity While temperature is the driving input

in the purely thermal case, under simultaneous change in

temperature and stress, the functions

−12

1

1

E− − 1

E A



are the more generalized driving forces for the

respec-tive transformations M+↔ A, M↔ M+, and M↔ A.

Changes in (σ, T) that cause +A, −+, and−Ato increase

favor M+→ A, M→ M+, and M→ A, respectively.

Conversely, the decrease favors transformation in theopposite direction The associated transformation is acti-vated only if the current value of (σ, T) is also within the

corresponding transformation zone of the (σ, T)-phase

dia-gram (e.g., see Fig 1)

The M↔ M+transformation zone does not extend into

T ≥ A f, in which case only transformations M+↔ A and

M↔ A can occur Accordingly, for T ≥ A f attention is cused on+Aand−Awhich are renormalized as follows:

2 = (E A − E−)/(2E A E−ηo)≥ 0 Theinequalities follow from η o > 0, γ

+> 0, γ

> 0, E A ≥ E+,

and E A ≥ E− Under this renormalizationβ+(0, T) = T For

σ = 0, the function β+(σ, T) behaves like a “stress-adjusted

temperature” that governs the M+↔ A transformation

for general changes in (σ, T) The function β−(σ, T)

plays a corresponding role with respect to M↔ A

transformation

Extending the purely thermal algorithm with driving

input T(t) to the case where the driving input is given by

σ (t) in conjunction with T(t) ≥ A f amounts to replacing

T(t) in Eq (17) with β+(σ(t), T(t)) and to replacing T(t) in

Eq (18) withβ−(σ(t), T(t)) This gives

H A →M, H M →Aandζ A →M, ζ M →A, it follows that the A→ M+

and M+→ A transformations are activated and completed

for those values of (σ, T) such that β+= M s , β+= M f , β+=

A s , β+= A f, respectively Along with Eq (20), they definethe boundaries of the relevant zones of the (σ, T) phase

diagram A similar remark applies to the

transforma-tions A→ Mand M→ A vis-`a-vis the function β−(σ, T).

The strain and entropy follow from Eqs (11) and (12)

The resulting model for T ≥ A faithfully predicts general

Trang 18

SHAPE-MEMORY MATERIALS, MODELING 977

tension/compression asymmetry, pseudoelastic

transfor-mation, and pseudoelastic sublooping

Low-Temperature Reorientation If the temperature is

below A f, then two additional phenomena have to be taken

into account: The M↔ M+reorientation transformation

and the possibility of multiple transformations An

exam-ple of the latter is provided in the purely thermal case

when A↔ Mand A↔ M+take place simultaneously The

model can be extended to cover such situations provided a

phase diagram is available that describes the activation

and the completion of all possible transformations

Equa-tions (21), (22) can then model the additional

transforma-tion possibilities provided that the functransforma-tionsβ+(σ, T) and

β−(σ, T) are modified from the specification (20) so as to

ac-count for the change in zonal geometry of the (σ, T )-phase

diagram when T < A f A modification that accomplishes

this purpose and so establishes such a phase diagram is

Contours of constantβ+and constantβ−give

continu-ous curves on the phase diagram, although each such curve

will have up to two sharp corners by virtue of the abrupt

formula changes in Eqs (23) and (24) Smooth contoursmore resembling those in Fig 1 can be obtained by a morecomplicated redefinition ofβ+, β

Note that the phase diagram of Fig 1 is defined by sixcontinuous curves The present treatment provides simi-

lar such curves The four curves that continue into T < M f

as approximately constant stress curves parallel to the

T-axis are defined by β+= A s , β+= A f , β= A s , and β−=

A f The zone A s < β+< A fbounded by two of these curves,

β+= A s andβ+= A f, is associated with transformations

that deplete M+ This depletion gives M+ → A for σ > 0.

For σ < 0, this depletion gives M+→ M− reorientation

provided that T is sufficiently low The low-temperature threshold for such pure reorientation is given by T=

M f − k

1σ + k

2σ2as specified in Eq (23) In particular, this

M+→ M− reorientation is activated in compression, ginning at σ = −σ

2σ2 Here M+transforms into a mixture

of A and M− Similar comments hold with respect to the

zone A s < β< A f provided that the roles of M+and M

are interchanged Note that neither zone is specifically

as-sociated with depletion of A The zone of A depletion is

bounded by the remaining two curves on the phase

dia-gram These two curves pass through T = M s and T = M f

on the T-axis and are given by β+= M sand β+= M f on

σ > 0 and by β= M sandβ= M f onσ < 0 The

auste-nite depletion is via A→ M+ifσ is sufficiently tensile, and

is via A→ M−ifσ is sufficiently compressive For σ near

zero, the depletion of A is into a mixture of M+and M−, as

in the case of thermally induced martensite

In summary, Eqs (7), (21), and (22) with (23) and (24)

now describe general A↔ M+, A ↔ M−, M−↔ M+formation throughout the full extent of the (σ, T )-phase di-

trans-agram A more detailed discussion is given in Wu and Pence(38) for the special case of symmetric tension/compressionbehavior Equations (23), (24) also give the proper ten-sion/compression asymmetry if any of the equalitiesγ

dis-an unexpressed unstable austenite intermediary (45) gorithm (15) is recovered under purely thermal trans-

Al-formation At temperatures T < A f, isothermal tensionfollowed by compression generates open stress–straincurves that are sometimes referred to as ferroelasticresponse

Operative Equations for Various Driving Conditions

The set of equations required for the actual computation

of SMM response are summarized in the following Thisset may be different depending on the conditions in whichthe material is used and the way that the loading inputspecified

If T and σ in the material are prescribed, then the

de-termination ofξ A , ξ+, ξ−proceeds directly on the basis ofEqs (7), (21), and (22) In this case the strainε as provided

by Eq (11) decouples from the kinetics

Trang 19

If T in the material is prescribed, but σ in the

mate-rial is not, then the first of Eqs (11) must be solved in

conjunction with Eqs (7), (21), (22) This includes cases

whereε is prescribed (various hard constraint situations)

or whenσ is related to ε by external constraint (e.g., a bias

spring)

If T in the material is not prescribed directly, then the

complete thermomechanical behavior requires

considera-tion of the material thermal balance and heat exchange

with the environment The heating rate ˙Q can be written

˙

Q= ˙Qrev+ ˙Qirrev (26)where, in view of Eq (6), the reversible contribution is

˙

The irreversible contribution ˙Qirrev = −T  includes

dissi-pative effects that are intrinsic with the phase

transfor-mation, and by Eqs (2), (4), (8), (26), and (27), it can be

According to Ortin and Planes (46), ˙Qirrevcan be neglected

in a first approximation More generally,

Here ˙Q provides the heat exchange with the environment

and requires additional description to this effect

Impor-tant situations in which T is not prescribed include

adia-batic conditions and conditions of convective heat transfer

to an ambient temperature T E The adiabatic case is ˙Q= 0,

and involves no heat exchange with the environment It is

an appropriate model under sustained and rapid

mechani-cal loading The case of convective heat transfer may often

be described by

˙

whereκ > 0 is a known parameter Here κ → 0 gives the

adiabatic limit, whileκ → ∞ enforces T(t) = T E (t) If T is

in fact prescribed, then Eqs (29) and (30) determine

ei-ther the heat exchange ˙Q or the fluid/atmospheric media

temperature T Ethat is necessary to sustain the

prescrip-tion Table 1 summarizes the equations one uses for the

determination ofξ A , ξ+, ξ−

Table 1 Modeling Equation Summary

Prescribed Quantities Equations Stressσ Temperature T (7), (21), (22)

Strainε Temperature T (7), (11)1, (21), (22)

Stressσ Heat rate ˙Q (7), (21), (22), (29)

Strainε Heat rate ˙Q (7), (11)1, (21), (22), (29)

Stressσ Media temperature T E (7), (21), (22), (29), (30)

Strainε Media temperature T E (7), (11)1, (21), (22), (29), (30)

Table 2 Representative Values for Material Constants

erning functions (16), with n= 1 and tension/compressionsymmetry, which implies thatγ

circum-Subloops The subloop model provides internal stress–

strain subloops within the fuller stress–strain curve that

is associated with complete transformation Repeated cling between either fixed stresses or fixed strains causesthe subloops to converge onto a final limiting response Thisallows for the prediction of shakedown behavior associatedwith either repeated stress cycling or repeated strain cy-cling (Fig 8)

cy-Pseudoelasticity and Reorientation For T > A f, bined tension/compression loading gives transforma-

com-tion behavior that alternates: A→ M+→ A → M→ A →

M+→ · · · As the temperature is lowered, the model gives

isothermal stress–strain behavior with plateau stressesthat decrease with temperature in the correct way Once

the temperature is lowered below A f, the isothermalstress–strain behavior under tension/compression begins

to involve A↔ M transformation in conjunction with

di-rect M↔ M+reorientation The model Eqs (7), (21), (22)track this multiple transformation activity The model also

retrieves pure M↔ M+reorientation with

temperature-independent plateau stresses when T < M f For T <

A f, isothermal tension/compression loading excursions

200 400

Strain

Figure 8 Stress cycling between 150 MPa and 400 MPa is

mod-eled at T = 315 K > A fusing the trigonometric envelope functions

(13) and D-M governing functions (16) with n= 1 Each new loop

is richer in M+and leaner in A than the previous loop After about

five transient loops, the response has converged to a repeating loop

that stabilizes the cycling between A and M+.

Trang 20

SHAPE-MEMORY MATERIALS, MODELING 979

Figure 9 Stress cycling between−150 MPa and 150 MPa is

mod-eled at T = 235 K > M f using the same envelope and

govern-ing functions as in Fig 8 Hereσ+

s = −σ

s = 120 MPa and σ+

f =

−σ

f = 210 MPa Since 120 < 150 < 210 MPa, the cycling

gener-ates a sequence of transformations: M→M+→M→M+→ ,

all of which are incomplete The convergent stable loop is

symmet-ric, because the particular material parameter choice represents

a tension/compression symmetric material.

generate open stress–strain curves (ferroelasticity) As is

the case for high-temperature behavior, loop convergence

takes place under repeated cycling The convergence is

im-mediate after the first cycle if the stress or strain

magni-tude is sufficient to complete all of the transformations

If, however, the cycling magnitudes do not cause complete

transformation, then the curves again shake down to their

limiting response (Fig 9)

Nonisothermal Pseudoelasticity Rate dependency

fol-lows from this model under the common condition of

con-vective heat transfer as described by Eqs (29), (30) For

fixed κ, faster loading gives less phase transformation

because convection inefficiency gives heat retention that

works against the A↔ M transformation The adiabatic

limit is approached under very rapid loading The opposite

limit of isothermal transformation occurs under very slow

loading Figure 10 shows the connection among

isother-mal, convective, and adiabatic loading as predicted by this

modeling

Experimental Validation As an example of validation of

the model, we report a comparison of the model

predic-tions with experimental data Figure 11 shows the results

of mechanical loading tests with temperature

measure-ments performed on 1 mm near equiatomic commercial

grade NiTi wires (47) and the corresponding prediction of

the model after straightforward material parameter

iden-tification The comparison gives excellent agreement in

predicting sublooping behavior and temperature change

under the combined conditions of cyclic loading,

transfor-mational heating/cooling, and convective heat transfer

Further features of the model that also follow but are

not obvious from the previous figures include

temperature-dependent stress–strain curves due to the change in

pseu-doelastic yield stress with temperature, stress–free strain

upon unloading due to the presence of stress-induced

martensite, and the shape-memory effect

Figure 10 Three stress–strain simulations beginning at T=

323 K> A f (above) This simulation uses a hyperbolic tangent

envelope function and slightly changed material parameters

sug-gestive of a different NiTi material microstructure (e.g., A f =

315 K, E M= 20000 MPa) The extended stress–strain curve is the isothermal response The curve on the far left is the adiabatic res-

ponse, and the middle curve models heat transfer to T E= 323 K over 20 s loading and unloading intervals Nonisothermal loading

gives heating since A→ M+ is exothermic Nonisothermal

unload-ing gives coolunload-ing since M+→A is endothermic Under adiabatic

conditions, the cooling returns the material temperature back to

T= 323 K at the conclusion of unloading Under convective

con-ditions, there is temperature undershoot on unloading (below)

be-cause of net heat transfer to the generally cooler ambient.

SUMMARY AND CONCLUSIONS

The thermomechanical stress–strain–temperature ior of SMM can be modeled so as to predict shape memory,pseudoelasticity, and martensite reorientation In order toachieve broad engineering utility, it is also necessary topredict sublooping, shakedown, and nonisothermal behav-ior Current models can reliably capture these effects under

behav-350 700

294 303

Figure 11 Comparison of this modeling (red) to measured

res-ponse (black) in a NiTi wire at a loading rate for which convection

is important.

Trang 21

simple states of stress such as uniaxial tension or simple

shear These settings cover a rather wide range of

appli-cations such as actuators, vibrations absorbers and other

devices Models for multi-axial loads are not yet as

thoro-ughly validated with experiment, especially with regard

to reorientation under nonproportional loading As was

indicated by the literature surveyed above, these models

differ principally in how refined a description of the

mi-crostructure is implicit in their framework Some models

explicitly treat interactions between microstructural

enti-ties, whereas others treat the effect of microstructural

evo-lution in a thermodynamic framework with consolidated

internal variables

A brief description of a generally useful internal

vari-able model for uniaxial stress and a variety of heating

ef-fects was also presented The internal variables describe

the microstructure in terms of local phase fractions for

austenite A and two variants of martensite M+ and M

with transformation strains of opposite orientation The

internal variables evolve with temperature and stress

ac-cording to kinetic equations (7), (21), (22) Strain and

en-tropy follow from Eqs (11) in a way that is consistent with

their status as thermodynamic conjugates to stress and

temperature Equations (29), (30) treat the effect of

trans-formational heating/cooling and heat transfer, which

nat-urally provides a rate effect to the stress–strain behavior

The examples presented here have not addressed the effect

of inhomogeneous deformation or nonuniform temperature

within the SMM material These issues can be treated for

this and similar models with appropriate field equations,

such as Eqs (4) to (6), and Fourier’s law This approach in

turn allows for computational simulation of SMM

compo-nents within larger systems

BIBLIOGRAPHY

1 I Muller and K Wilmanski, Il Nuovo Cimento B57: 283–318

(1980).

2 M Achenbach, Int J Plast 5: 371–398 (1989).

3 P Xu and J.W Morris, Metall Trans A24: 1281–1294 (1993).

9 L Truskinovsky In P.M Duxbury and T.J Pence, eds.,

Dynamics of Crystal Surfaces and Interfaces, Plenum, New

York, 1997, pp 185–197.

10 D Bernardini, J Mech Phys Sol 49: 813–837 (2001).

11 E Patoor, A Eberhardt, and M Berveiller, Arch Mech 40:

755–794 (1988).

12 Q.P Sun and K.C Hwang (1994) In J Hutchinson and T.W.

Wu, eds., Advances in Applied Mechanics, Vol 31, Academic

Press, San Diego, CA, 1994, pp 249–298.

13 V.I Levitas, Int J Sol Struct 35: 889–940 (1998).

14 B.C Goo and C Lexcellent, Acta Mater 45: 727–737 (1997).

15 Z.K Lu and G.J Weng, Acta Mater 46: 5423–5433 (1998).

16 M Huang and L.C Brinson, J Mech Phys Sol 46: 1379–1409

20 F Falk, Acta Metall 28: 1773–1780 (1980).

21 Y Huo, Continuum Mech Thermodyn 1: 283–303 (1989).

22 J Ortin, J Appl Phys 71: 1454–1461 (1992).

23 A.A Likhacev and Y.N Koval Scripta Metall Mater 27: 223–

26 J.R Rice, J Mech Phys Sol 19: 433–455 (1971).

27 K Tanaka and S Nagaki, Ingenieur Archiv 51: 287–299

31 I Muller, Continuum Mech Thermodyn 1: 125–142 (1989).

32 J Ortin and A Planes, Acta Metall Mater 37: 1433–1441

35 L.C Brinson, J Intell Mater Syst Struct 4: 229–242 (1993).

36 A Bekker and L.C Brinson, J Mech Phys Sol 45: 949–988

45 R Wasilewski, Metall Trans 2: 2973–2981 (1971).

46 J Ortin and A Planes, J Physique IV, C4: C4–C13 (1991).

47 D Bernardini and F Brancaleoni, In Proc Manside Workshop,

January 28–29 1999, Rome, Italy, part II, pp 73–84.

48 K Gall and H Sehitoglu, Int J Plast 15: 69–92 (1999).

49 P Sittner, M Takakura, and M Tokuda, Mater Sci Eng A,

234–236:216–219 (1997).

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SHIP HEALTH MONITORING 981

SHIP HEALTH MONITORING

Although ships have been sailing for hundreds of years,

the field of ship health monitoring is relatively near Two

main forces have spurred the rise in the popularity and

importance of ship health monitoring systems First,

re-duced budgets and rere-duced manpower have resulted in

smaller crew sizes and less routine maintenance This

re-duced maintenance has brought into question the health

of many ships, their components, and the ability to detect

a problem quickly Clearly, a failure aboard any vessel will

bring a loss of revenue and productivity, if not worse The

second driver behind the growth of ship health

monitor-ing systems is the decrease in the expense of computers

and sensors coupled with an increase in their capabilities

and the associated data processing algorithms Until

re-cently, an automated health monitoring system was either

impossible to achieve or prohibitively expensive to install

and maintain Today, ship health monitoring systems are

becoming increasingly more common as their capabilities

are further demonstrated and understood by the maritime

community Nevertheless, many issues remain to be settled

as technology improves, resulting in continuously

expand-ing requrements

OVERVIEW OF SHIP HEALTH MONITORING

Modern ships, both commercial and military, are extremely

complicated machines, so that the aspects of the ship to

which a ship health monitoring system can be applied

are numerous To date, efforts have focused primarily on

the global hull response and diagnostic monitoring of the

propulsion system Although these two applications have

the greatest potential for financial and safety

improve-ments, other areas, such as local hull stresses and cargo

tanks, can benefit from monitoring (1) In military

appli-cations, many specialized monitoring applications can be

envisioned, such as weapon systems or ordinance

monitor-ing and battle damage estimates (2)

Potential Benefits

Ship health monitoring systems can be employed for many

reasons In almost all cases (except research vessels), the

primary reason is to reduce the overall cost of ship

op-erations In isolated cases, other reasons have dictated

the use and development of monitoring systems Another

readily apparent benefit of an installed system is failure

prevention Although this is rarely the primary factor for

ship monitoring, the safety benefit gained from avoiding a

catastrophic failure is a strong motivator for using a

sys-tem Finally, because of the advanced technology and

re-cent emergence of ship health monitoring systems, many

systems have been installed for research The research hasfocused on the capabilities, benefits, and logistics of long-term ship health monitoring system use

Financial Ultimately, for the field of ship health

mon-itoring to be viable, installed systems must decrease theoverall costs of operating a ship and/or provide a substan-tial performance benefit In both cases, a financial impetuswill exist for installating and using a ship monitoring sys-tem In general, cost savings will come from three sources:

a reduction in maintenance labor-hours, reduced ment costs, and increased readiness and uptime Unfortu-nately, of these three, only the cost savings from the reduc-tion in maintenance labor-hours can be easily calculated

equip-If a ship health monitoring system is operating properly,many equipment failures are likely to be detected earlierbefore they become disastrous Early detection will in turnhelp prevent one failure from affecting other componentsand lower the costs to fix a failure, resulting in a reduction

in equipment costs that is hard to quantify Furthermore,unscheduled maintenance will be reduced, resulting in anincrease in ship availability The increased availability willthen create higher revenues for the entire system

Safety An additional benefit of ship health monitoring is

the inherent safety provided by such a system If the cal health of critical areas is constantly monitored, catas-trophic failures are less likely to occur Most critical regions

physi-of the ship can be monitored for stress overloads Should

a stress overload occur, the monitoring system quickly forms the bridge and provides pertinent information to thecrew to lessen the amount of damage caused by the over-load If a failure has occurred, this information will also

in-be passed to the bridge In this case, although the systemwas unable to prevent a major failure, it will give the crewadditional time and information to deal with the problem.For military vessels, the safety of the crew can be protected

by the provision of real-time, accurate battle damage mates Again, this information will allow for a rapid dam-age assessment that could easily save lives onboard a crip-pled vessel

esti-Potential Dangers to Ships

Ocean and seagoing ships are subject to many tial hazards The following sections describe some of theoperational hazards in detail In general, these hazards arecaused by wind and waves, ice, and material (cargo) han-dling/storage In addition to the hazards faced by commer-cial vessels, military vessels face the obvious threats fromenemy actions However, this section discusses only haz-ards that are encountered during typical ship operations

poten-Wind and Waves Waves, both large and small, are

an ever-present hazard to shipping Waves stress a shipthrough several different phenomena that are adaptedfrom (3) and described here

Quasi-Static Hull Girder Stress (Global Stress). Hullgirder shears and moments are caused by the cyclic buoy-ancy of a wave that is superimposed on the ship’s geometry

in a quasi-static balance with the ship accelerations The

Trang 23

moment values depend more on the projected wave length

superimposed on the hull (wave length/cosine of the

head-ing angle) than on the encounter frequency However, the

pitch and heave resonance (a function of the encounter

fre-quency versus the motion natural frefre-quency) can increase

the hull girder moments

Hull Girder Whipping (Global Stress) When a structure

is impacted, much of the impact energy is absorbed by the

structure as vibrational energy This vibration generally

forms as motion of the structure at its first natural

fre-quency When a ship is impacted, such as during a slam,

the ship hull vibrates in its fundamental bending modes

(vertical and lateral) This is termed hull girder whipping

Slams can occur on the bottom and on the flare of the ship’s

bow Bottom slams occur when the forefoot of the ship is

lifted clear of the sea by severe ship and wave motions

during rough seas A slam occurs as the ship reenters the

sea and the bow impacts the water Flare slamming may

occur as the result of relative motion between the vessel

and the sea, even without bow emergence, but can also

occur when there is little motion between the vessel and

the sea, if the wave is steep enough Bottom slams tend to

have shorter lengths and higher loading frequencies than

flare slams The dominant slam type depends on the ship

type High-speed containerships that have finer forward

lines and a flaring bow experience greater stresses from

a flare slam, but the opposite is true for full-form tankers

that have little flare Measurements on an aircraft carrier

have shown that the whipping moments are of the same

magnitude as the quasi-static moments during flare slam

(1) Although the whipping vibrations and energy

dissipa-tion mechanisms are not well understood for large complex

vessels, they are generally less severe in flexible (i.e., high

L/D ratio) ships (4) The whipping moment components are

usually small compared to the quasi-static moment, but the

whipping moments occur at higher frequencies Recent

in-vestigations suggest that whipping may increase fatigue

damage by 20% to 30% (5)

Springing (Global Stress) When a ship impacts waves

at a frequency that is at or close to the primary hull

res-onant frequency (the two-noded, vertical bending mode),

springing may occur Springing is steady-state resonance

of the ship at its natural frequency Although this is also a

low-frequency event, springing frequencies are of an order

of magnitude higher than quasi-static hull girder stresses

The resulting moment, especially when superimposed on

the quasi-static stresses, may be significant in long-term

fatigue damage Ships can experience springing in small

and moderate seas, as long as the encounter frequency

ap-proaches the ship’s natural frequency

Wave Refraction (Local Stress) Hull girder stresses are

generally caused by larger waves of the order of the ship’s

length But the lower stresses created by smaller waves

impacting on the sides of the ship can cause localized

long-term fatigue damage and may lead to cracks and crack

propagation This effect is intensified by wave reflection in

beam seas Localized fatigue cracking has been a problem

on some Trans Alaska Pipeline System (TAPS) trade

tankers where the local waves generally strike the

star-board side during the southern voyages and the port side

on the northerly routes

Slamming (Local Stress). The damage from forefootslamming has been mentioned previously as a cause ofwhipping In addition, the locally high stresses can causedamage to the bow structure Bottom slamming in shipsoften results in dishing of the bottom shell plate, and flareslamming results in dishing of the side shell and possiblythe loss of the flare strake

Ice In addition to the stresses caused by sea loading,

ice represents a significant danger to shipping The dangerfrom ice comes primarily from localized impact loading onthe hull However, global stresses can also become a factordue to hull girder whipping

Ice Transit (Local Stress) Because ship speed, heading,

and ice conditions can vary greatly, local ice loads on theship’s structure are complex The danger from ice dependsmore on local stresses than on the global hull forces Ship-board measurements have shown that typical hull girderstresses induced by ice transit are less than those induced

by opwater waves (3) The pressures and forces countered during ship–ice impacts are random and followlog-normal type probability distributions (6) Ice loads arenonuniform, and high loads are applied to small areas ofthe hull (e.g., 0.5 m2) In addition, these loads occur at manylocations along the hull, predominately on the bow The in-stantaneous area of the hull that is most highly loaded de-pends on the type of operation (ramming, turning, etc.) andthe geometry and strength of the hull structure Ice loadsare more difficult to measure than slamming loads because

en-of their high frequencies and random distributions ies indicate that strain rates for ice loading in the localstructure are similar to those for the global response andthat neither of these is significantly different from thoseexperienced from sea loading (3)

Stud-Hull Girder Whipping (Global Stress) Stud-Hull girder

whip-ping caused by slamming is described in the previoussection Because whipping is the vibration of the ship’sprimary bending modes due to impulsive loading, ice ram-ming can also induce hull girder whipping This effect isusually felt during initial ice impact and less during steadyice transit

Cargo As for ice, cargo and material handling can also

add additional stresses to a ship’s hull Cargo loads can becategorized into two forms

Static Hull Girder Stress (Global Stress)

Quasi-static hull girder stress was mentioned previously whencaused by long length waves superimposed on the geom-etry of the ship, causing high moment and stress val-ues For cargo, quasi-static girder stresses are caused

by differences in the loading distribution curve and theship’s buoyancy curve along the length of the ship.Care must be taken during cargo loading and unload-ing so that the maximum allowable stress values are notexceeded

Cargo Loads (Local Stress) Cargo loading anomalies can

often result in localized regions of high stress Two ples of loading anomalies are uneven loading in bulk ships(this, it has been hypothesized, is the cause for a number ofbulk ship failures) and unequal hydrostatic pressure heads

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exam-SHIP HEALTH MONITORING 983

across tank boundaries The American Bureau of Shipping

(ABS) SafeHull code specifically considers a checkerboard

loading pattern in cargo and ballast tanks as a worst case

scenario Hence, the loading sequence can result in

exces-sively high global and local stresses

Different Ship Types and Requirements

Ship Types Specific ship designs are susceptible to

var-ious hull responses Table 1, taken from (3), shows the

typical monitoring requirements for several common ship

types

Operating Environment Ships are designed for many

functions and operate in a wide variety of conditions The

size, type, and operating environment of a ship greatly

in-fluence the requirements placed on a health monitoring

system For example, because container ships that

oper-ate in calm, smooth woper-aters in the tropical zones are rarely

subjected to icy conditions or severe storms, whipping and

other wave/ice-induced fatigue stresses are not critical

fac-tors Therefore, a proper health monitoring system should

concentrate on cargo-induced loads and maximizing

oper-ational efficiency

On the other hand, TAPS trade tankers are constantly

subjected to severe storms, high waves, and very

direc-tional sea states (7) As cargo runs are made to the south,

waves primarily strike the starboard side of the ship On

the return trip to the north, waves strike the port side

pri-marily This pattern has resulted in localized fatigue

prob-lems and requires a high density of local stress sensors to

detect the onset of cracking In the North Sea, hull girder

bending, slamming, and green water are present because of

Table 1 Monitoring Requirements by Ship Type

Passenger ship Ship motion (roll)

Bow flare slam Tanker/products carrier Midship hull girder stress

Bow/amidships shell stiffeners Forefoot slam

Explosive environment Bulk ships Cargo loading hull girder stresses

Cargo hold frame stresses Stress concentrations at hatch corners Forefoot slam

Container ships Stress concentrations at hatch corners

Hull girder torsion Bow flare slam Green water Whipping/cargo accelerations LNG/internal tank Forefoot slam

Temperature/explosive environment Sloshing

Barges/platforms Towline/mooring tension

Motions and inertial forces Lateral motion

Naval combatant Bow flare slam

Fire control plane deflections

the very steep waves and require sensors similar to thosefor the TAPS trade tankers to detect any potential prob-lems Bulk ships operating on the Great Lakes are sus-ceptible to springing because of their high L/D ratios andrequire global hull bending sensors Ice breakers are sub-ject to high localized stresses, especially around the bow,but the global bending stresses are typically lower thanthose experienced by other oceangoing vessels

These basic generalizations apply only to small groups

of ships that continuously operate in a given environment.Many ships are not easy to classify; their health monitoringconsiderations must include all of the potential operatingconditions for a specific vessel Most military vessels areprime examples of ships that are commonly operated with

no fixed route and that experience many types of sea statesthroughout a voyage

Additional Capabilities

Industry has realized that ship operators expect a shiphealth monitoring system to do more than simply mea-sure the state of stress throughout the ship and monitormachinery health As mentioned previously, ship healthmonitoring systems must be financially attractive to becommercially acceptable It is clear that preventing the loss

of a ship or increasing the useful life of a ship by structuralmonitoring are financial benefits However, additional ben-efits can be gained by incorporating external (non-ship-based) sensor readings into a comprehensive monitoringsystem These external readings are currently composed oftwo primary types: weather avoidance/planning and routemonitoring

Weather Reports Current weather reports are available

to ships from a variety of environmental sensor platforms,including fixed land sensors, ocean buoys, other ships, air-craft, and satellites Collectively, these platforms can pro-vide the necessary information to a ship to help prepare

an optimal route to increase the efficiency of the route and

to lessen any damage that may be caused by ice or poorweather

Fixed Land Sensors Fixed land sensors are primarily

used to measure basic meteorological conditions such aswind speed and direction, temperature, and precipitation

Ocean Buoys The National Data Buoy Center (NDBC)

operates the Ocean Data Acquisition System (ODAS),which is a network of more than 60 buoys that are anchored

in deep ocean areas off of North America These buoys sendsatellite transmissions to the National Weather Service(NWS) that provide weather and oceanographic data fromtheir stations in the Atlantic, Pacific, Gulf of Mexico, andthe Great Lakes The wind speed and direction data, onceprocessed by NDBC, is reportedly accurate to within± 10◦and± 1 m/s

Ships NWS receives weather reports every 3 hours

from ships that participate in the U.S and World orological Organization (WMO) Voluntary Observing ShipProgram (VOS) These reports include basic meteorologi-cal conditions and best estimates of the current sea state,ice, and visibility These programs include 49 participatingcountries and approximately 7000 ships that provide about

Trang 25

Mete-1000 reports a day The U.S program has existed as a

des-cendant of the U.S Coast Guard Ocean Weather Station

ships for several decades The data provided by the VOS is

commonly used for weather forecasting and is distributed

by the National Ocean Weather Service through the Global

Telecommunications System

Aircraft Aircraft are most commonly used to track

hur-ricanes in the Atlantic Ocean But they have also been

ex-perimentally used to track ice conditions in the polar

re-gions (8) and have been used to provide Synthetic Aperture

Radar (SAR) readings to estimate local sea states

Satellites In general, satellites provide a great deal of

information to weather forecasters Due to the advent of

modern satellite imaging technology, forecasters can

accu-rately predict the weather many days in advance In

ad-dition to the basic weather forecasting functions, several

satellite instruments have been used to aid in ship

naviga-tion

Advanced High-Resolution Radiation (AVHRR) sensors

are used to sense ocean temperatures and map sea

cur-rents Flown by NOAA since 1978, AVHRR sensors detect

infrared radiation to measure the sea surface temperature

This data is critical to helping oceanographers track ocean

currents Generally, two AVHRR satellites are in polar

or-bit on 24-hour cycles phased 12 hours apart to give both

day and night readings Although clouds interfere with

AVHRR readings, this interference has not significantly

affected their usefulness

Radar altimetry has been used to measure the distance

between a satellite and the ocean waves to estimate the sea

state Although the technology was first demonstrated

on-board the GEOS-3 in the 1970s, suitable accuracy was not

obtained until the recent launch of the TOPEX/Poseidon

in 1992 However, until additional satellites become

oper-ational, this technology will be used primarily for research

A final sensor technology is scatterometry

Scatterom-etry measures the scatter within a return pulse from a

radar altimeter to determine the roughness of the seas

Calm seas give a clear, concise radar reflection, whereas

rough seas tend to distort the return The sea state is then

related to the local wind speed through an empirical

cor-relation Again, scatterometry is a new technology that is

currently in the development stages and that will hopefully

be available to health monitoring systems in the future

Route Monitoring/Planning Adding the capability of

monitoring weather conditions to a ship health monitoring

system can improve the crew’s ability to plan an optimal

course through the weather Ideally, though, the

moni-tored weather conditions would be integrated with a route

planning system to provide an optimal route to the crew

automatically By integrating the local health monitoring

system with a real-time routing system, the ship’s

han-dling can also be adjusted to minimize danger to the ship

Using this type of system, it is possible to plan the best

route to reach a given destination while reducing time and

fuel consumption from unwanted ship responses Several

technologies needed for such a system are already in

ex-istence, including weather forecasting, the predicted ship

responses, and the local sensors to determine the actual

ship response However, an intelligent software product for

performing the optimization at real-time speeds has notbeen fully realized

The benefits of route planning were demonstrated in

1993 by ARCO Marine (9) Two sister TAPS trade tankerstraveled from San Francisco, California to Valdez, Alaskawith the same ballast condition One ship contained a voy-age planning system based on the predicted wave heightsand directions; the other did not The ships remainedwithin a narrow corridor and varied only the timing andspeed The ship that used route planning arrived approxi-mately 18 hours earlier than the sister ship, and the sistership suffered $400,000 in wave-induced damage

ENVIRONMENTAL ISSUES

For a ship health monitoring unit to be acceptable, it shouldnot adversely affect the operation of the ship or its crew.Furthermore, the system must be reliable and require verylow maintenance A primary driving benefit of a ship healthmonitoring system is a reduction in crew workload If thesystem is constantly in need of repairs, this benefit doesnot materialize Unfortunately, the maritime environment

is very harsh and unforgiving Every component of a healthmonitoring system must be considered for reliability andmaintenance The primary factor that reduces the life ofship components is the highly corrosive marine environ-ment Many other sensor location-specific factors may alsocontribute to component failures These include explosiveenvironments, inadvertent physical damage by the crew,and operational overloads

Corrosive Marine Environment

The marine environment is tremendously harsh and sive This environment quickly affects most exposed metalsand many other materials Therefore, a ship’s health mon-itoring system components must either be protected fromthis environment or constructed of materials that are notsubject to marine corrosion Although any material willeventually corrode, corrosion in the marine environment

corro-is more severe for several reasons First, most metals rode slowly at ambient temperatures and low humidity.Increasing the humidity provides water, which is neces-sary as an electrolyte for charge transfer In addition to theever-present water, the saline environment of ocean waterfurther increases corrosion by speeding up the localizedbreakdown of oxide films The chloride also increases theconductivity of seawater compared to freshwater, again in-creasing the corrosion of many metals A final contributor

cor-to corrosion is the low acidity of seawater The pH of water is usually 8.1 to 8.3

sea-Other

In addition to the highly corrosive marine environment,ship health monitoring sensors are placed in other types ofextreme environments Many modern ships are designedfor and dedicated to transporting large quantities of oil

or natural gas For these ships, it is desirable to sure the health of the fuel storage tanks This environ-ment places additional safety requirements on the sensor

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mea-SHIP HEALTH MONITORING 985

and any associated electronics due to the explosive nature

of the cargo A few sensors are intrinsically safe in an

explosive environment, but most sensors must be

encap-sulated or encased in an explosion-proof container, which

can substantially increase the cost and complexity of the

sensor

Another concern is to protect the health monitoring

sys-tem’s components from physical harm It is often necessary

to place sensors or wiring in locations that are susceptible

to physical damage Examples include deck-mounted

com-ponents that can be damaged by the crew’s activities or

forefoot-mounted pressure sensors that must be designed

to handle the high forces experienced during slams or

ice-breaking duties In some early systems, pressure sensors

failed most frequently of all equipment (3) Without the

proper protection, these sensors fail quickly

SENSOR TECHNOLOGY

The sensor network is crucial to providing real-time,

accu-rate information from the ship health monitoring unit to

the ship’s crew It is the distributed sensors that directly

measure the motions and health of the ship To provide a

detailed picture of the entire ship, these sensors must

com-prise many different types and must be placed throughout

the vessel Therefore, current and future health monitoring

systems will incorporate a wide variety of sensor types that

measure a diverse number of physical parameters Figure 1

illustrates a possible ship health monitoring sensor

ar-rangement In addition to choosing the physical

param-eters that must be measured, where they are to be

mea-sured, and the type of sensor to be used, one must make

decisions concerning the cost, reliability, and safety of the

specific sensor Current state-of-the art sensors can meet

these objectives, but novel sensor designs are continuously

being developed and must be considered as possible

im-provements over existing designs

Vertical acceleration

Long-base strain gauges

Data acquisition display and recorder

Trust power shaft speed Ship motions

roll and pitch vertical acceleration In-tank local

strain gauges

Measurands and Potential Sensors

As mentioned, a wide variety of parameters must be sured to obtain an adequate picture of a ship’s motionsand health The following sections describe many of thesemeasurands and the potential sensors that are currentlyavailable for the measurement

mea-Pressure Pressure gauges are most often used in a ship

health monitoring system to measure slamming pressures,forefoot emergence, and in-tank hydrostatic pressures.Multiple pressure gauges are often located longitudinallyalong the forefoot to detect the extent of emergence and

to determine the magnitude and extent of bottom impactpressures (10) To facilitate maintenance, it is important toensure that any sensors, especially forefoot pressure sen-sors, can be replaced or repaired without entering dry-dock.There are two primary types of pressure transducers:diaphragm and piezoelectric types Both types are com-monly available commercially at about the same cost, buteach has certain advantages and disadvantages

Diaphragm-Type Pressure Transducers There are two

types of diaphragm style pressure transducers: one has

a clamped circular plate, and the other employs a hollowcylinder However, the clamped plate design is more suitedfor the pressure ranges of ship health monitoring, and onlythey are discussed in this section The strain distribution

on a clamped circular plate of constant thickness has beensolved analytically and has been experimentally validated.Based on these results, a special purpose diaphragm straingauge has been designed to take advantage of this straindistribution Using this type of strain gauge arrangement,one finds that the pressure is proportional to the measuredstrain Typical strain gauge instrumentation can be used

to sample the data

Piezoelectric-Type Pressure Transducer. This type ofpressure transducer uses a piezoelectric crystal as both thediaphragm and sensor In general, the piezoelectric crystal

Trang 27

Figure 2 Long-base strain

gauge.

(most commonly quartz) is placed inside a hollow

cylin-der Because of the piezoelectric effect, an applied

pres-sure generates an electrostatic charge that is proportional

to the pressure The piezoelectric crystal has a high output

impedance Therefore, a charge amplifier is commonly

em-ployed to convert the charge into an amplified voltage that

is read by a standard voltage recorder The low-frequency

response of the transducer depends on the time constant of

the amplifying circuit but can be designed to use

frequen-cies that are low enough for ship health monitoring The

primary disadvantage of this type of transducer is that the

charge amplifier electronics make the system less

intrinsi-cally safe than diaphragm-type pressure transducers

Global Strain Global strain is most commonly measured

using long-baseline strain gauges Long-baseline strain

gauges normally consist of a long rod (approximately 2

me-ters long) rigidly attached at one end to the hull The

sec-ond end is allowed to move freely through a set of guides

that ensure only axial movement The extent of movement

of the free end, as measured from a set “zero” strain

loca-tions, divided by the length of the rod gives the average

strain in the deck across a region of the hull that is the

length of the rod Figure 2 is an illustrative example of a

long-base strain gauge

Although the basic mechanism is simple and robust,

these devices are commonly placed on the deck of a ship

and must be appropriately protected from both physical

damage and the environment Three common techniques

are currently available for measuring the displacement of

the free end

Linear Potentiometer Linear potentiometers are

sim-ple resistors that have a varying resistance that is

pro-portional to the displacement The displacement is

mea-sured by sending a low voltage and current through the

po-tentiometer and measuring the resistance This method is

very inexpensive, and recent advances have made precision

linear potentiometers as accurate and repeatable as other

technologies One disadvantage is that the resistor’s life is

limited and it must be protected from the environment

Linear Variable Differential Transformers (LVDT) LVDTs

are the most popular variable-inductance sensor used for

displacement measurements In an LVDT, a magnetic core

moves through an insulated bobbin without physical tact Three symmetrically spaced coils are wound aroundthe bobbin The position of the magnetic core controls themutual inductance between the center primary coil andthe two outer secondary coils When a voltage is applied tothe primary coil, a voltage is set up in the two secondarycoils The secondary coils are wired 180◦out of phase witheach other Therefore, when the core is centered within thebobbin, the secondary voltages are of equal magnitude andcancel out However, a small movement of the core results

con-in a larger voltage con-in one of the secondary coils and hence

a sensor reading Because there is no contact between faces, LVDTs are free from friction and have very long lives.The response is also free from hysteresis The resolution of

sur-an LVDT is partially determined by the voltage recorder,which give LVDTs superb resolution and accuracy The twoprimary disadvantages of LVDTs are their higher cost com-pared to linear potentiometers and the relatively high volt-age (5 to 15 volts) that must be supplied to the primary coil

Linear Displacement Transducer A linear displacement

transducer is a magnetostrictive sensor that measures thetime between an interrogating magnetic pulse and a returnpulse that is generated by a magnet connected to the freeend of the rod As for an LVDT, this type of device has

no contacts and a long service life It is also intrinsicallysafe for hazardous environments but is much higher in costthan either of the other two options

Local Strain Local strain measurements are often used

in ship health monitoring systems They are applicable todetecting a wide variety of potential hazards They aremost commonly used along the bow, in cargo and ballasttanks, and along any other critical internal structures.Local strain gauges are also ideal for detecting crackingaround certain areas such as hatch corners and highlystressed welds In general, the number of local straingauges is limited by the cost of installation and data ac-quisition as opposed to the cost of the gauges or the desire

to measure more parameters Ideally, almost any failurecan be detected by a local strain gauge if it is installed inthe right location

By far the most common method of measuring localstrains is to use a resistance foil strain gauge Details of

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SHIP HEALTH MONITORING 987

the performance and use of resistance strain gauges can be

found in many texts The strain gauge operates by

detect-ing a change in resistance of metal wire as it is stretched

The change in resistance is caused by a decrease in the

con-ductive cross-sectional area due to Poisson’s ratio To

am-plify the change in resistance, one employs thin metal-foil

grids to maximize the amount of conductor within a given

region Because the change in resistance is very slight, a

Wheatstone bridge is usually used to convert the changing

resistance to a variable voltage Resistance strain gauges

can be purchased in a wide variety of sizes, sensitivities,

and geometries It is also possible to purchase strain gauge

rosettes that permit measuring all three surface stress

components simultaneously Because strain gauge

read-ings depend on measuring a changing resistance, they can

be made safe by using very low voltages

An important consideration is the temperature

sensi-tivity of strain gages As a material is heated or cooled, the

material expands or contracts, depending on the material’s

coefficient of thermal expansion If the strain gauge does

not similarly expand or contract, an apparent strain will be

seen by the strain gauge Two methods exist for

eliminat-ing this apparent strain The first method is ensureliminat-ing that

the coefficient of expansion is identical for both the

struc-ture and gauge Therefore, both expand at the same rate,

and no apparent strain is seen For this reason, commercial

vendors sell strain gauges made from a wide variety of

ma-terials The second approach is not as attractive for

practi-cal applications In this approach, a second gauge/material

combination is bonded together but is placed in a region

that is completely free of stress Through this technique,

the amount of apparent temperature-induced strain can

be calculated from the second gauge and can be subtracted

from the active gauge to provide the final mechanical

strain reading However, finding a suitable location for the

dummy gauge is not generally possible

The installation of strain gauges is also a

well-documented field that has a myriad of options The most

common techniques include adhesive bonding and welding,

but other methods are also available for packaged sensors

Generally, it is preferable to protect the strain gauge

af-ter installation Again, this is done by using a variety of

protective coatings and encapsulation techniques Many

strain gauges sold have the gage itself prepackaged into

an encapsulated enclosure for protection

Motion Ships’ motions are possible in all six degrees of

freedom The three translational degrees of freedom are

surge (longitudinal), sway (lateral), and heave (vertical)

Roll, pitch, and yaw are the three rotational degrees of

freedom Roll, pitch, and heave are generally considered

the three most important degrees of freedom for the

fol-lowing reasons:

Roll Roll generally affects the crew and cargo loads.

In addition to crew and passenger discomfort, rolling

cre-ates lateral cargo loads that must be resisted by horizontal

restraints In fluid tanks, rolling may increase the

hydro-static pressure head or induce sloshing A ship’s master

usually turns the ship into waves to reduce rolling, but

this increases hull girder stresses

Pitch Pitching has the same effect on fluid-filled cargo

tanks as rolling and results in an increased hydrostaticpressure head and sloshing In addition, the length of theship increases the distance between the ends of the shipsand the pitch axis, resulting in high pitch accelerationsthat may in turn result in slamming

Heave Heave is more pronounced than surge or sway

because of wave motions and the coupling with pitch tions Heave causes effects similar to roll and pitch in fluid-filled tanks In addition, the vertical accelerations requirevertical cargo restraints

mo-Ship motions are commonly measured by a variety ofsensor types The most common devices are accelerome-ters and gyros, although there are many variations of both.Table 2 lists the current state of the art in ship motionsensors (11)

Shaft Speed, Power, and Thrust The ship’s performance

parameters (shaft speed, power, and thrust) can providemeasurements of the propulsive efficiency relative to thecurrent environmental conditions These measurementscan also provide an indication of the health of the propul-sion equipment Most ships are currently configured withequipment to measure these parameters directly from thepropeller shaft In general, this information is alreadypassed into the engine control room and can be furtherrouted to the ship health monitoring system

Global Positioning Similar to the propulsion system

measurements, ships usually already have an installedGlobal Positioning Systems (GPS) As a rule, GPS unitsoutput a serial signal dictating the ship’s position (lati-tude and longitude), heading, and speed on a regular ba-sis Therefore, the ship health monitoring unit only needs

to read this information from the preexisting unit

Advanced Sensors Fiber-Optic Strain Gauges One promising new technol-

ogy is fiber optic strain gauges There are two primarytypes of fiber-optic strain gauges, Fabry–Perot and fiberBragg grating sensors (12) Both types offer a number ofadvantages over traditional resistance strain gauges Be-cause fiber-optic strain gauges use light as the sensing andtransmitting element, they are intrinsically safe and pose

no fire or explosive hazards Furthermore, fiber optics arevery resistant to corrosive elements because they have nometallic components and are covered by protective hermet-ically sealed coatings A final common advantage is thatfiber optics are immune to electromagnetic interference.Therefore, they can be placed in regions of high electric ormagnetic fields without any degradation of performance.Both types of fiber-optic strain gauges are also capable ofstrain resolutions equal to or greater than that of resis-tance strain gauges

Fabry–Perot Fiber-Optic Strain Gauges. Fabry–Perotstrain gauges are manufactured by placing a small air gap(or an internal mirror) within a fiber, followed by a reflec-tive surface, which can be either a micromirror or moreoptic fiber A broadband light wave is transmitted downthe length of the fiber At the first junction between the

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Table 2 Ship Motion Sensor Technology

Roll and pitch Vertical gyro Reliable, may be able to Drift, cost, power

use existing ship unit Magnetometer Moderate cost Calibration on steel ships Solid-state gyro Low cost and power, units Sensitive to external vibrations

packaged with integral rates and displacements

“Watson meter” Reliable, accurate for Moderate cost

pendulum-based design

Yaw (heading) Gyrocompass Current state of the art Expensive, frequently needs service

Solid-state Low-cost combination of rate Unproven, unknown life and reliability gyro (KVH) gyro and flux gate compass

Solid-state gyro New laser ring technology, Expensive, not yet commercialized (fiber optic) no moving parts for ship use

Flux gate Good for small ships once Difficult to use effectively unless compass compensated for, low cost able to swing the ship for compensation Magnetometer Moderate cost Calibration on steel ships

Piezoelectric Good for machinery Unsuitable for ship response accelerometer vibrational measurements frequencies

Surge Sway Heave Piezoresistive Low cost, good for short- Subject to temperature

accelerometer term ship motions cross-axis errors Servo-accelerometer Excellent stability, Expensive

accuracy, and reliability Capacitative Moderate cost, performance Cross-axis sensitivity higher accelerometer nearing that of a servo- than that of servoaccelerometers

accelerometer

fiber and the air gap (or mirror), some of the light is

re-flected back to the source, and some of the light is

trans-mitted into the gap At the mirror or second air/fiber

in-terface, light is again reflected and transmitted Now, two

separate light sources are reflecting light back along the

length of the fiber The length of the air gap dictates the

phase difference between the two waves Allowing this air

gap to expand or contract, based on the local strain, creates

a strain sensor Hence, a measurement of the phase offset

can be correlated to a strain measurement There are

ex-trinsic Fabry–Perot sensors, inex-trinsic Fabry–Perot sensors,

and in-line fiber etalon (ILFE) sensors All three are based

on the same principle, the differences lie in the choice of the

reflective medium Although intrinsic Fabry–Perot sensors

are sensitive to strain and temperature, extrinsic Fabry–

Perot sensors and ILFEs have very low thermal

sensitiv-ity One disadvantage of Fabry–Perot sensors, compared to

fiber Bragg grating sensors, is the difficulty in multiplexing

many sensors along a single fiber

Fiber Bragg Grating Strain Gauges Fiber Bragg gratings

are based on the photorefractive effect Bare fiber is

ex-posed to a hydrogen environment and then imprinted

us-ing an ultraviolet laser The imprintus-ing is done by one of

several methods, and it leaves a series of equally spaced

lines along a region of the fiber This series of lines is

called a Bragg grating; the lines are actually very small

regions that have a slightly different index of refraction

Bragg gratings can be fabricated through an

interferomet-ric (holographic) method or by using phase masks In a fiber

that has a Bragg grating, transmitted broadband light is

reflected back toward the source at a specific frequency thatcorresponds to the grating wavelength All other frequen-cies of light pass unaffected through the Bragg grating.Because the frequency of the reflected light is propor-tional to the spacing of the Bragg grating, a change in thespacing will result in a change in the reflected wavelength.Hence, a strain gauge can be made by bonding a Bragggrating of a specific wavelength to a structure As the struc-ture is strained, the Bragg grating will expand or contract,thereby changing the wavelength of the reflected light Bymeasuring the wavelength of the reflected light, one candeduce the strain at the location of the grating (13).One major advantage of using fiber Bragg gratings as lo-cal strain sensors is the capability of using wavelength and/

or time division multiplexing to place many Bragg gratings(strain sensors) along a single optical fiber (14) When abroadband light source is used with a Bragg grating, everywavelength, except the wavelength corresponding to thegrating, is transmitted through the grating Therefore, asecond Bragg grating, at a different wavelength, may beplaced further along the fiber This second Bragg gratingwill reflect a different wavelength back to the source Now,two separate strain readings can be taken by monitoringthe two reflected wavelengths This process can be repeatedmany times along the length of the fiber, which allows mak-ing many distributed local strain readings within a singlefiber-optic cable that also transmits all of the data back

to the control computer Similarly, time division ing can be achieved by monitoring the time of return ofthe Bragg grating wavelengths, enabling interrogation of

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multiplex-SHIP HEALTH MONITORING 989

multiple sensors along a fiber One disadvantage of Bragg

grating strain sensors is its strong thermal sensitivity

Nu-merous methods have been proposed to compensate for this

thermal sensitivity, but none have yet been commercially

successful

Other Fiber-Optic Gauges In addition to fiber-optic

strain gauges, Fabry–Perot and Bragg grating strain

sen-sors have been incorporated into other designs to enable

de-tecting pressure, temperature, or even chemical content In

general, these sensors have many of the same advantages

due to the nature of fiber optics as opposed to electrical

components But again, very few of these hybrid sensors

are currently available commercially These sensors will

probably become more available and less expensive as the

technology matures Using Bragg grating-type sensors, it

will also be possible to construct a series of varying sensors

that are connected to the same fiber-optic transmission

ca-ble For example, the fiber-optic cable from several forefoot

pressure sensors could be run up to the cargo tanks where

several Bragg grating strain sensors were located Each of

these sensors could be multiplexed together so that all of

them are interrogated by a single fiber-optic cable running

back to the control computer

Sensor Power

Another consideration for ship health monitoring sensor

systems is the source of the required power Most

com-mon sensors, including strain gages and accelerometers,

require a constant electrical input to operate This power

is usually provided by the control computer and is sent

through installed wiring to the individual sensors The

dis-advantage is that this approach often leads to additional

bulky cabling An alternative is to use the ship’s existing

power distribution network This approach is, however,

complicated because the existing power, especially near

the bow, is limited and of poor quality, and high voltage

spikes are common The control computer and critical

sen-sors must also be connected to an uninterruptable power

supply (UPS) to maintain operation in the event of a power

failure

DATA

The wealth of information obtained from the remote and

on-board sensors of a health monitoring system must be

transmitted and processed into a form that is both useful

and concise It is widely accepted that a useful health

mon-itoring system must have a bridge terminal to display all of

the pertinent information to the ship’s crew This first step

is to transmit the data to a central location, either on the

bridge or nearby After the data has been transmitted to

a central location, it is input into a computer system that

analyzes and formats it into easy-to-read displays In

ad-dition to displaying the real-time data to the crew during

the voyage, it is often desirable to store this data for future

analysis Each step in this process is an involved function,

and each is described in the following sections

fac-Hard Wiring fac-Hard wiring is the most common form of

data transmission in currently installed health monitoringsystems In ships that have protected longitudinal passage-ways, shielded and grounded cables offer the route thathas the lowest installation expense However, many ships,including tankers and product carriers, do not have thesepassageways and require more extensive cable routing andcost The use of armored cable is also recommended forany external cable routing to protect it from physical dam-age In explosive environments, it is extremely important

to ground all cables to reduce the risk of sparking; in factthis procedure is generally preferred in all applications toreduce noise

Radio Links Radio links between sensors and the

con-trol computer offer the advantage of simplicity of lation because no cables need to be run through the ship’shull Nevertheless radio links have increased costs because

instal-of the transmitter and antenna An additional advantagefor explosive environments is that radio links eliminatethe spark hazard found in hard wiring This type of signaltransmission becomes less attractive for large numbers oflocalized sensors When wiring, one can lay a multitude ofsensor cables at one time For radio transmission, multipletransmitters are required for additional sensors Althoughradio transmission does not degrade over the length of theship, signal interference is possible and can corrupt thedata with spurious signals

Fiber-Optic Network Fiber-optic networks represent a

good alternative to hard wiring and many advantages buthigher cost As proved by the telecommunications industry,fiber optics can easily transmit many signals hundreds offeet without any signal degradation Fiber optics are alsoinherently safe for explosive environments and do not suf-fer from electromagnetic interference For many of thesereasons, current naval vessels are being outfitted withwide area distributed fiber-optic networks (15) Similar tohard wiring, fiber-optic networks suffer the disadvantage

of needing a fiber-optic cable from the sensors to the trol computer In addition, most standard analog electricalsensors require expensive signal converters and decoders

con-to convert the data incon-to a corresponding light signal andback to electrical signals at the control computer However,for a ship that has a preexisting fiber optic network, thisform of transmission is extremely attractive and will beattractive for other systems as the cost of fiber-optic com-ponents continues to drop

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The analysis and display of the sensor data are the primary

objectives of the standard ship health monitoring unit It is

the responsibility of the control computer to perform data

acquisition from the individual sensors and to process this

data to determine whether the ship has been damaged or

faces any immediate danger The most common method

of analyzing the information is to monitor each sensor in

terms of the absolute magnitude of the sensor reading

Al-though the algorithm is relatively simple, the crew should

determine whether the ship has experienced a reading that

approaches or exceeds the maximum allowable level If an

overload has occurred, the crew must know immediately,

so that appropriate action may be taken This may dictate

a change in the ship’s heading, an adjusted cargo

load-ing pattern, or possibly a visual inspection of the sensor

location

More complicated analyses are also performed to

de-termine the overall fatigue experienced by the ship and

to locate any general trends in the data that might

indi-cate a potential failure These analyses include average

sensor levels, standard deviations, and peak values More

complicated signal processing techniques have been

devel-oped for machinery health monitoring, but such techniques

have not yet been used for ship health monitoring systems

Limited attempts have been made at this point to use ship

health monitoring information to predict the remaining

fa-tigue life of ship components

Display

A key component of the ship health monitoring system is

the bridge display The information displayed on at the

bridge is the primary interface between the monitoring

system and the ship’s crew To be easily used by the crew,

the information must meet many different requirements

Information The information given by the display is the

most important function of the entire system The crew

re-quires simple displays that can quickly inform them of any

potential dangers and the effect of various maneuvers on

the state of the ship Complicating the information

dis-play is the crew members’ needs for different types and

amounts of data The information that is required during

cargo loading is very different from the information needed

when traveling through rough seas Support personnel are

interested in different types of information as they

post-process the data To meet these many demands

simultane-ously, it is common practice for the bridge display to consist

of numerous (more than five) different screens

Experience has also shown which data formats and

types of information are the most helpful to bridge

person-nel For example, the ABS requires displaying hull girder

stresses over a relatively short period of time so that the

effect of speed or heading changes on the measured stress

levels can be evaluated Experience has also shown that

bridge crews want the stress information to be displayed as

a percentage of the maximum allowable stress as opposed

to actual stress or strain readings The actual values are

important and are generally saved for later use, but theimmediate needs do not require this information

Alarms Both audible and visual alarms are standard in

all ship health monitoring systems The alarms are needed

to inform the crew quickly of any potential dangers ever, it is very important to set the alarm sensitivity levelshigh enough so that the crew does not become frustrated

How-by the alarm system Excessively sensitive alarms have sulted in disconnection of the alarm system in previous ap-plications, especially because of ice-induced local stresses(3)

re-Color/Lighting The graphical display of the ship health

monitoring system must be capable of operating in twomodes During the daytime, it is desirable to have a brightscreen with obvious color clues to inform the crew quickly

of the ship’s status Standard danger colors such as redand yellow should be used to highlight high sensor levels

or overloads Similarly, cool colors should be used to cate that the ship is operating normally However, the dis-play must not interfere with the crew’s night vision duringevening hours Hence, the display must be able to switch to

indi-a second mode where lower intensity schemes cindi-an be used

to maintain night vision Intensity variations can then beused to signify danger as opposed to a color change

Storage

After the information has been displayed to the crew, thesensor information must be stored for later retrieval andanalysis Using modern storage media, it is not difficult

to store vast amounts of data in relatively little space.Nonetheless, a continuously operating ship health moni-toring system can generate huge amounts of data Severaloptions exist for storing data, including magnetic disks andtapes and optical disks The primary considerations for thestorage medium are the cost and capacity of the deviceversus the frequency with which the medium needs to bechanged by the ship’s crew during a voyage

COMMERCIAL SYSTEMS

To date, there are a few commercially available hensive ship health monitoring systems In addition, sev-eral manufacturers commercially produce Hull ResponseMonitoring Systems (HRMS) Although these systems arenot comprehensive health monitoring systems that en-compass the entire vessel, they provide detailed and ad-equate monitoring of the vessel’s hull structure and in-clude many other associated monitoring functions Thesesystems will surely form the basis for a comprehensive shiphealth monitoring system To regulate commercial HRMS,the ABS published, in 1995, classifications for Hull Con-dition Monitoring Systems Although these guidelines aregeneral, they do provide a minimum compliance level forall HRMS These requirements are listed in Table 3

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compre-SHIP HEALTH MONITORING 991

Table 3 ABS HRMS Requirements

Measurement Device Parameter Sensitivity

Accuracy ±0.01 g’s Frequency 3 × required response

Accuracy ± 5 µε

Frequency 5 Hz

Current Systems

Currently, there are approximately 10 commercial

manu-facturers of HRM systems Although many of the systems

focus on recording the same physical parameters, no two

systems are identical and almost every manufacturer will

specially design a system to the end user’s needs

Nonethe-less, it is helpful to give approximate capabilities of these

individual systems The values in Table 4 are given only as

a reference; individual or all values may be higher or lower

for any given manufacturer and system

Future Enhancements

The future of HRMS and comprehensive ship health

moni-toring systems is both exciting and dynamic As the cost

of new vessels continues to rise, there is an increasing

demand to maintain and extend the operational life of

new and existing vessels A ship health monitoring unit

is uniquely capable of extending the life of a vessel by

pro-viding the optimal course to the crew to avoid severe storms

and to limit the damage incurred by the ship The health

monitoring system may also allow aging ships to be kept in

service for longer periods of time by accurately identifying

any failures before they become catastrophic

Almost every aspect of future systems is likely to be

enhanced over the current state of the art within the next

decade These advancements include the following:

1 Improved Sensors Almost every type of sensor will

have more capabilities, reduced cost, and improvedsafety and reliability

2 Increased Sensor Density As the cost of individual

sensors and data acquisition hardware decreases, thenumber of sensors installed in a typical system willincrease This will bring a greater density of sensors

to a given region and will allow for more detailedmeasurements of local stresses

Table 4 Typical HRMS Features

Data storage capacity 1 GB

Average display length 5 min

No of display screens 5–10

3 Additional Monitoring Functions: In addition to

im-proving the ability to detect and locate any tial damage to the ship’s hull, advancements will al-low monitoring the health of additional regions of theship or ship components For example, researchers inrelated fields have demonstrated the capability of ac-curately detecting transmission faults before they be-come catastrophic Faults such as cracked or brokengear teeth, damaged bearing raceways, or misalignedshafts have all been successfully detected before fail-ure These systems generally use accelerometers tomeasure the vibrations close to the gears, bearings,and shafts in many transmission systems The mea-sured vibrational signals can be analyzed by a widevariety of methods of varying complexity and comput-ing power Although the global parameters of power,speed, and torque are measured in current systems,they can only inform the crew of a transmission faultafter it has occurred and has begun to affect the ship’soperation Therefore, this type of transmission healthmonitoring system is a logical addition to currentship health monitoring systems

poten-4 Increased Computing Power: The continued push for

faster computers will enable health monitoring tems to perform more detailed analysis in real time.Such advances will lead to more sophisticated andsensitive algorithms that can inform the crew of apotential problem before it occurs This is especiallyhelpful in machinery diagnostics

sys-5 Condition-Based Maintenance: Currently, ship

com-ponents are repaired or replaced based on one of twofactors Either the part is replaced on a time-dictatedschedule, to prevent the part statistically from everfailing, or it is repaired/replaced after failing Nei-ther of the current methods is optimal In the firstcase, healthy components are discarded only becausethey have been used for a set amount of time In thelatter case, the ship is potentially unavailable for ser-vice because of the required repairs An alternativeapproach, which may be provided by an advancedship health monitoring system, is condition-basedmaintenance (16–18) By monitoring the health of astructure, one can also monitor the remaining life

of that component For example, a crack may be tected, but the monitoring system may show that thepart has an additional 6 months of life before failure.This monitoring capability will ensure that the ship’savailability is not lost because of repairs or waitingfor a component to become available, and healthyparts will not be inadvertently wasted

de-6 Increased Data Storage: It is well known that the

cost of data storage is continuously dropping Thistrend will be very beneficial to ship health monitoringsystems as increased amounts of raw data will bestored for possible retrieval and postprocessing

7 Improved Weather Forecasting and Route Planning:

Although weather forecasting is not a direct part of aship health monitoring unit, the advances in weatherforecasting will give the system greater confidence in

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the predicted weather and will improve the ness of route planning activities This will be cou-pled to improved route planning algorithms that will

effective-be developed, as the relationships effective-between the ship’sresponse and weather conditions are more fully un-derstood

BIBLIOGRAPHY

1 J.A Kuny, R.R Lewis, and M.D Dianora, Am Soc Nav Eng.,

Int Ship Symp II Philadelphia, Nov 1996.

2 S Phoa, Am Soc Nav Eng., Int Ship Symp II, Philadelphia,

Nov 1996.

3 S.B Slaughter, M.C Cheung, D Sucharski, and B Cowper,

Ship Structure Committee, NTIS #PB98-100431, 1997.

4 E.V Lewis, Structural Dynamics of Ships Royal Institute of

Architects, 1974.

5 P.B Lacey and H Chen, SNAME Los Angeles Metropolitan

Sect Paper, 1993.

6 J.W St John et al., SNAME Icetech ’94, Mar 1994.

7 D.J Witmer and J.W Lewis, SNAME Trans 102: 501–533

(1994).

8 E.D Leavitt and G McAvoy, MTS J 21: 29–36 (1987).

9 R Lovdahl, P Lacey, and H Chen, SNAME 1995 Calif Joint

Sect Meet., Apr 2, 1995.

10 D.J Witmer and J.W Lewis, SNAME 1994 Los Angeles

Metropolitan Sect Meet., Jan 13, 1994.

11 F.H Ashcroft, R.D Goebel, and W.F Hennessy, SNAME 1995

Joint Calif Sect Meet., Apr 22, 1995.

12 G.A Johnson, S.T Vohra, and S Mastro, Am Soc of Nav Eng.,

Int Ship Symp III, Philadelphia, June 1999.

13 P Ross, P Chen, R Wagreich, S Chen, J Sirkis, J Kuny, and R.

Lewis, Am Soc Nav Eng., Int Ship Symp III, Philadelphia,

June 1999.

14 K Pran, G Johnson, A.E Jensen, K.A Hegstad, G Sagvolden,

Y Farsund, C.C Change, L Malsawma, and G.W Wang,

Proc SPIE 7th Int Symp Smart Struct Mater., March

2000.

15 D.J Coyle and R.J Patterson, Am Soc Nav Eng., Int Ship

Symp II, Philadelphia, Nov 1996.

16 D.K Hoth, Am Soc Nav Eng., Int Ship Symp II,

Philadelphia, Nov 1996.

17 E Rerisi and J Hutter, Am Soc Nav Eng., Int Ship Symp.

III, Philadelphia, June 1999.

18 J.D Keenan and W.H Sims, Am Soc Nav Eng., Int Ship

Symp III, Philadelphia, June 1999.

SMART PEROVSKITES

ZHONGL WANG

Georgia Institute of Technology

Atlanta, GA

Perovskite and perovskite-related structures are a class of

smart materials (1) Perovskite-structured materials have

important applications in ferroelectricity, piezoelectricity,

ferromagnetism, magnetoresistance, superconductivity,

ionic conductivity, and dielectricity Typical perovskite

materials of technological importance are piezoelectricPb(Zr,Ti)O3, electrostrictive Pb(Mg,Nb)O3, magnetoresis-tant (La,Ca)MnO3, and superconductive YBa2Cu3O7.Perovskite-related materials are versatile matrices forgenerating transition- and rare-earth metal oxides that ex-hibit a broad spectrum of properties and functions (2) thatare related to the following characteristics: (1) Nearly in-numerable combinations of metal cations can be accommo-dated within perovskite-related structural systems (2) Byreduction / reoxidation processes, nonstoichiometry (i.e.,controlled amounts of ordered oxygen vacancies) can beintroduced into the structure In turn, high oxygen ion mo-bility or modified electronic and magnetic features can beimplemented, and (3) the design of composite structuralsystems containing perovskite building units (perovskiteslabs of different thicknesses) allows fine-tuning electronicand magnetic properties

From the viewpoint of crystal structure, the ABO3typestructure, in which the cation A usually has valence 2+ andthe cation B has valence 4+, is the fundamental perovskite.The perovskite family is created by doping other types ofcations into the stoichiometry and /or introducing anion de-ficiency Understanding the structures and the relation-ships among the abundant structures in the perovskitesmay lead to some insights into the intrinsic connection be-tween structure and properties This article focuses on thestructure and structural evolution of perovskites and ex-plores the intrinsic linkages among the members of theperovskite family First, we introduce the “smart” proper-ties of perovskites Then, the intrinsic connection amongthe perovskites is explored Finally, the analysis of mixedvalences and oxygen deficiency is addressed

THE FAMILY OF PEROVSKITE–STRUCTURED MATERIALS Examples of Perovskite Structures

The most typical perovskite structure is BaTiO3(Fig 1a).The Ba atoms appear at the corners of the unit cell andoxygen atoms at the face centers Both the Ba and O make

up a face-centered lattice structure The octahedrally dinated titanium ion is located at the center of the unit cell.This structure can be generically written as ABO3, which

coor-is the fundamental structural configuration of perovskites.Materials that have perovskite-like structures are nu-merous The most typical are ceramic high-temperaturesuperconductors such as YBa2Cu3O7(Fig 1b) The unit cellcan be considered a stack of three perovskite units alongthe c-axis direction, where the cation lattice preserves that

of the perovskite, and oxygen vacancies are introduced Thedistortion in the oxygen lattice sites is due mainly to thevacancies The long periodicity of the c axis (e.g., super-structure) is the result of alternate distribution of the

Y and Ba cations and the ordered structure of oxygenvacancies

A comparison of BaTiO3 with YBa2Cu3O7 indicatesthe following In BaTiO3, the cations are screened by an-ions so that two cations are not directly face-to-face InYBa2Cu3O7, although the cation distribution is the same

as that in BaTiO , the Cu ions at the top layer of the

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SMART PEROVSKITES 993

(a)

Ba

TiO

Figure 1 Atomic structural models of (a) BaTiO3 and

(b) YBa2Cu3O7.

unit cell are face-to-face without the screening of anions,

whereas the Cu cations next to Y are well coordinated This

structural configuration is possible only if Cu ions have

different valence states at the two types of lattice sites

Therefore, perovskites have three major structural

char-acteristics: cation substitution, ordered oxygen vacancies,

and mixed valences of cations

Perovskite-Like Structures

In the ABO3 structure, the valences of the A

(12-coordi-nated) and B (6-coordi(12-coordi-nated) cations are usually 2+ and

4+, respectively The valence variation at the A cation

po-sition can cause distortion or displacement of the oxygen

anion array, possibly resulting in distortion in the

B-cation-centered octahedron The B cation must have the flexibility

to tolerate this effect, and the transition-metal elements

are candidates for filling the B-cation position because of

their multivalences and their special 3d and 4d electronic

configurations This is the reason that transition-metal

oxides have perovskite-type structures (3) Perovskite-like

structures can be sorted by the valence combination of the

A and B cations as follows (4):

1 A1 +B5 +O3 type, such as KNbO3, NaNbO3, LiNbO3

and KTaO3

2 A2 +B4 +O3type, in which the A2 +cations are

alkaline-earth ions such as cadmium or lead, and the B4 +ionscan be Ce, Fe, Pr, Pu, Sn, Th, Hf, Ti, Zr, Mo, and

U BaTiO3and PbTiO3are typical examples Thesetwo compounds are well known for their remarkableferroelectic properties (see later section)

3 A3 +B3 +O3 type, such as GdFeO3, YAlO3, PrVO3,

PrCrO3, NdGaO3and YScO3

4 A2 +(B3+0.67 B6+0.33)O3 type, such as Ba(Sc0.67 W0.33)O3

and Sr( Cr0.67Re0.33)O3

5 A2 +(B2+0.33B5+0.67)O3type, for example Ba(Sr0.33Ta0.67)

O , and Pb(Mg.33Nb .67)O

6 A2 +(B3+0.5 B5+0.5)O3, A2 +(B2+0.5 B6+0.5)O3, A2 +(B1+0.5 B7+0.5)

O3, and A3 +(B2+0.5B4+0.5)O3types, such as Ba(Sr0.5W0.5)

O3, Pb(Sc0.5Ta0.5)O3and Pb(Sc0.5Nb0.5)O3 The ounds, Pb(Mg0.33 Nb0.67)O3,Pb(Sc0.5 Ta0.5)O3 and Pb(Sc0.5Nb0.5)O3, are very important ferroelectric ma-terials, and they are usaully called “relaxors.”

comp-7 A2 +(B1+0.25 B5+0.75)O3type, such as Ba(Na0.25Ta0.75)O3and Sr(Na0.25Ta0.75)O3

8 A2 +(B2+0.5 B5+0.5)O2.75 and A2 +(B3+0.5 B4+0.5)O2.75 thatare anion deficient, such as Sr(Sr0.5 Ta0.5)O2.75 andBa(Fe0.5Mo0.5)O2.75

9 A2 +(B3+0.5B2+0.5)O2.25

It is apparent that the perovskite structures cover alarge group of materials Three questions are particularlyinteresting: What are the special properties of perovskites

as far as smart materials are concerned? What is the tionship between these structures, for example, the struc-tural evolution in perovskite, and what is the relationshipbetween the cation valence and its coordination? The fol-lowing analysis explores the answers to these questions

rela-STRUCTURES AND PROPERTIES Ferroelectricity

Ferroelectric materials are candidates for robust volatile memories (5) Figure 2 gives a high-resolutiontransmission electron microscopy (TEM) image of BaTiO3oriented along [100] (or [001]), where the cations are indark contrast and the contrast is directly related to the

non-Figure 2 High-resolution transmission electron microscopy

im-age of BaTiO3oriented along [100], showing the cation (in dark contrast) distribution in the crystal The atom types can be clearly identified At the top of the film, surface steps of one unit cell height are seen, and the termination layer is Ba–O.

Trang 35

cc

atomic number The oxygen anions are not clearly resolved

in the image because of its weak scattering power At the

top of the film, the last ending layer is the Ba–O layer,

clearly indicating that the Ti atom strongly demands a

complete octahedral coordination even at the boundary of

the crystal The octahedral coordination of Ti is at the root

of ferroelectricity

The Ti ion is surrounded by six oxygen ions in an

octahe-dral configuration (Fig 1a) BaTiO3has a cubic structure

at T > 120◦C For 5 < T < 120◦C, it is tetragonal In the

low-temperature range of− 90 < T < 5◦C, it has an orthorhombic

structure, and for T <−90◦C, it is rhombohedral

There-fore, the structural transformation from centrosymmetric

to noncentrosymmetric occurs at 120◦C, and

ferroelectric-ity occurs at T < 120◦C Below the 120◦C transition

tem-perature, the oxygen and titanium ions are displaced to

new positions (Fig 3a,b), forming a tetragonal structure

where c/a = 1.01 (3) A unilateral displacement of the Ti4 +

ion against O2 − results in a dipole moment When all of

the dipoles of different domains point in the same

direc-tion, the material is ferroelectric If the dipoles have equal

strength but are aligned in an antiparallel configuration

so that they cancel each other and the material does not

exhibit a macroscopic dipole, it is antiferroelectric If these

dipoles cannot completely cancel each other, the residual

dipoles add up, forming a macroscopic dipole, which is

ferroelectricity.

The spontaneous alignment of dipoles that occurs at

the onset of ferroelectricity is often associated with a

crystallographic phase change from a centrosymmetric,nonpolar lattice to a noncentrosymmetric polar lattice If

an external electric field is applied to the crystal, the ulation of the domains whose polarizations are parallel tothe field increases, and those whose polarizations are an-tiparallel and not parallel to the field decrease If the ex-ternal electric field is removed, the domains cannot spon-taneously compensate for each other again, and a rema-

pop-nent polarization Prremains To remove the remanent larization, an oppositely oriented electric field whose field

po-strength is E c , called the coercive field, has to be applied to

the crystal The polarization hysteretic loop (Fig 3c) is thebasis of electric data storage using ferroelectric materials

An increasing number of materials have been foundthat demonstrate spontaneous polarization Lead titanate(PbTiO3), which has the same perovskite structure asBaTiO3, is ferroelectric Other examples includes Rochellesalt (potassium sodium tartrate tetrahydrate), KH2PO4,

KH2AsO4; perovskites NaCbO3, KCbO3, NaTaO3, andKTaO3; ilmenite structures, LiTaO3 and LiCbO3; andtungsten oxide, WO3

Domains and domain boundaries can be formed in

fer-roelectric materials The spontaneous polarization of the

Ti and oxygen ions creates an electrostatic polarization P

along the c axis This anisotropic structural configurationcan form 90 and 180◦domain boundaries defined with ref-

erence to the orientations of the c axes or the P vectors

that belong to the two crystal domains (Fig 3d,e) The 90◦domain boundary is just a (101) [or (011)] twin boundary of

... 28: 17 73? ?17 80 (19 80).

21 Y Huo, Continuum Mech Thermodyn 1: 283–303 (19 89).

22 J Ortin, J Appl Phys 71: 14 54? ?14 61 (19 92). ... determination of the number of variants and the mod-eling of their arrangement (17 ), as well as the modeling ofnonproportional multi-axial loading; for recent experimen-tal studies, see (18 ,19 )

Approaches...

Perovskite-Like Structures

In the ABO3 structure, the valences of the A

(12 -coordi-nated) and B (6-coordi (12 -coordi-nated) cations are usually 2+ and

4+,

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