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This research presents an attempt to assess the energy recovery potential from the Municipal Solid Waste MSW landfill, targeting at gas recovery and gas utilization, in mitigating metha

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J Sci Dev 2009, 7 (Eng.Iss.1): 70 - 78 HA NOI UNIVERSITY OF AGRICULTURE

70

Energy recovery potential from landfill and

environmental evaluation of landfill gas power

generation system

at nam son landfill, Vietnam

Tiềm năng thu hồi năng lượng từ bãi rác và đánh giá lợi ích môi trường

của hệ thống phát điện sử dụng khí từ bãi rác tại bãi rác Nam Sơn, Việt Nam

Pham Chau Thuy 1 , Sohei Shimada 2

1

Department of Environmental Technology, Faculty of Natural Resource and Environment,

Hanoi Agricultural University, Trau Quy, Gia Lam, Hanoi 2

Graduate School of Frontier Sciences, Institute of Environmental Studies, The University of

Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, JAPAN

TÓM TẮT Khí từ bãi rác là nguồn năng lượng xanh, sạch, có thể tái tạo được và có thể sử dụng để tạo ra điện, hay sử dụng trong công nghiệp năng lượng Bài báo này đánh giá tiềm năng thu hồi năng lượng

từ khí bãi chôn lấp chất thải rắn đô thị, mục đích làm giảm lượng phát thải methan nói riêng và giảm phát thải khí nhà kính nói chung Ngoài ra, bài báo cung cấp cách sử dụng mô hình đánh giá lượng khí methan tạo ra từ bãi chôn lấp chất thải rắn đô thị và tiềm năng tạo ra năng lượng từ khí đã thu hồi Đặc biệt, bài báo sử dụng phương pháp đánh giá vòng đời để đánh giá việc giảm phát thải khí nhà kính của hệ thống phát điện sử dụng khí từ bãi rác Kết quả nghiên cứu chỉ ra rằng, bãi rác Nam Sơn

là một bãi rác có tiềm năng lương lượng lớn cần thu hồi và sử dụng, góp phần đáng kể vào việc làm giảm phát thải khí nhà kính, hướng tới sự phát triển bền vững Bài báo cung cấp một cách nhìn mới

về công nghệ năng lượng sử dụng khí từ bãi rác cho Viêt Nam: hệ thống phát điên sử dụng động cơ khí và tuabin khí Kết quả còn chỉ ra rằng, hệ thống phát điện bằng động cơ khí tỏ ra hiệu quả hơn về lợi ích về môi trường so với hệ thống phát điện bằng tuabin khí Hệ thống này có thể ứng dụng cho bãi rác Nam Sơn và ứng dụng cho các bãi rác khác của Việt Nam trong tương lai

Từ khóa: Đánh giá vòng đời, giảm phát thải khí nhà kính, khí từ bãi rác, mô hình phát thải khí

bãi rác

SUMMARY Landfill gas (LFG), a green, clean, and renewable energy source can be used for electricity generation or fuel industries This research presents an attempt to assess the energy recovery potential from the Municipal Solid Waste (MSW) landfill, targeting at gas recovery and gas utilization,

in mitigating methane emission in particular and green house gas (GHG) emission in general Our research provides the using of landfill gas emission model (LFGEM) to quantify the methane generation volume for MSW landfill We then evaluate of energy generation potential from recovered gas Especially, this research conducted the Life Cycle Inventory to evaluate GHG emission mitigation

of power generation system using LFG The results show that the methane gas flow at Nam Son landfill can provide a considerable energy potential LFG recovery and utilization could contribute remarkable to GHG emission mitigation, toward to sustainability The research supplies a new vision

of energy technology from LFG for Viet Nam: Gas Engine and Gas Turbine The research found that Gas Engine is more attractive in term of environmental benefit, which can be applied primarily for Nam Son landfill and continue applied for other landfill in Vietnam for the future

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71

Key words: Green House Gas emission mitigation, landfill gas, landfill gas emission model, life cycle Inventory

1 INTRODUCTION

Climbing LFG is considered as the largest

anthropogenic emission source in the developed

countries and also as a considerable emission

source in developing countries up to now Landfill

gas (LFG) is produced from anaerobic

biodegradable decomposition of organic content

of landfilled waste Release of LFG is one of the

dangerous contaminations due to high methane

content contributing to GHG emission and global

warming Hence, collecting LFG and using it not

only to avoid the pollution and explosion, but also

can get attractive benefits The main mechanism

for reducing future methane emission from landfill

sites is the use of engineered sites and the

collection and utilization of LFG

There are several ways to utilize LFG The

most prevalent use is converting LFG to electricity

for utilization Power generation is advantageous

because it produces a valuable end product -

electricity – from waste LFG recovery and

converting to electricity is optimum solution for

environmental burdens decrease by CH4 emission

mitigation from landfills, a large emission source

from human’s activities Hence, the purpose of this

study is to make an attempt to assess the energy

recovery potential from LFG and utilize it, targeting

at gas recovery and gas utilization, in mitigating

methane emission in particular and GHG emission in

general

For initial assessment, an estimate of landfill

gas quantity is all needed to estimate power

potential, which is necessary for LFG power

generation design This research presents the method

with the combination of using theoretical model and

experimental research to estimate LFG quantity in

more accurate Then energy recovery potential from

LFG continuing is estimated

Several good conversion technologies exist for

generating power from LFG – Internal combustion

engine (Gas Engine), combustion Turbine (Gas

Turbine) and steam turbine Steam turbine is

applicable in very large landfill Other technology is

fuel cell However, this application is too expensive

This research considers on Gas Engine (GE) and Gas

Turbine (GT) in converting LFG to electricity Use

of Life Cycle Inventory will analyzed attractive in

term of environmental advantages obtained from power generation plant

Viet Nam has carried out a number of studies and project relevant landfill gas recovery and power generation, for example: project of Landfill gas capture and power generation in Dong Thanh and in

Go Cat landfill Landfilling is the common way for Municipal Solid Waste treatment in Viet Nam There are a lot of landfills in Vietnam with high capacity which are not considered in landfill gas capture and power generation The research approaches a new vision of LFG technology, which is necessary in environmental protection and sustainability development for Viet Nam in particular and for the world in general

2 MATERIALS AND METHODS

2.1 Case study- Nam Son landfill

Nam Son (NS) landfill is the biggest landfill in Hanoi city, with the largest area (83.5 ha) compared

to other landfills opened in Hanoi It is the important site, which is active now and prospect of use is in a long time (it will be closed in 2020) With a large area and high capacity, NS landfill receives 1850 tons of solid waste per day today and more in the future The waste volume is expected to be 12 million tons when landfill close Gas migration in

NS landfill has made serious consideration to the government The question to them is how to collect landfill gas and how to use it with the aim of getting advantages including environmental pollution reduction and economic yield

2.2 Materials and methods

The first method used in this study is investigation at field and gas measurement The data obtained from this method includes: characteristic and structure of the landfill, quantity and composition of waste disposed at NS landfill daily, local weather condition and other relevant characteristics around the landfill Gas measurement includes sampling landfill gas and analyzing the samples, which focused on methane and carbon dioxide concentration determination Using vacuum pump and Tedlar bag carried out

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Pham Chau Thu, Sohei Shimada

72

LFG sampling GC-FID and GC-TCD machine

analyze gas samples

The continuing method in this study is using

landfill gas emission model (LFGEM) to estimate

landfill gas emission and energy recovery potential

at NS landfill There are several ways used to

evaluate the theoretical production of methane from

MSW landfill This study uses the theoretical

model for evaluating of LFG emission The model

is based on the first order decay equation, which

can be run by site-specific data for parameters need

to estimate emission If the data is not available, the

method will use default value sets included in

landfill Site-specific data in this study is

determined by on-site testing and through IPCC

guideline

For the sites with known (or estimated)

year-to-year solid waste acceptance rates, the model

estimate LFG generation rate for given year using

the following equation:

n

kt

i 1

Where:

M

Q = Maximum expected generation flow

rate of methane for Mi tons of solid waste

(m3/year)

n

i 1

= Sum from opening year + 1 (i=1)

through year of projection (n)

k = methane generation rate constant (1/year)

Lo = methane generation potential (m3/t)

Mi = mass of solid waste disposed in the ith

year (ton)

ti = age of the waste disposed in the ith year

(years)

The life cycle inventory of power plant was

considered in four lifecycle phases, namely,

upstream LFG, construction, operation, and

decommissioning Upstream landfill gas includes

waste collection, transportation and operation of

landfill The construction phase considered both of

LFG collection system and power plant construction

In the decommissioning phase, demolition of power

plant, material recycling and material reusing was included within the system boundary LFG recovery and utilization of it is optimum solution for environmental burdensdecrease by CO2 and CH4 emission mitigation from landfills, a large emission source from human’s activities The aim of this method is to evaluate environmental impacts associate to the whole life cycle of LFG energy conversion systems This method is important in accounting of GHG emission mitigation from utilization of recovered LFG

3 RESULTS AND DISCUSSION

3.1 Determining site-specific input of NS landfill

3.1.1 Determining the concentration of LFG in Nam Son landfill

To define the concentration of landfill gas, total 9 samples were taken in the different cells and locations and analyzed on GC machine Using of vacuum pump and Tedlar bag carried out LFG sampling Microclimate factors including temperature, moisture, and wind velocity were measured also The samples were analyzed on GC-FID or GC-TCD in laboratory LFG analyzing focuses on the measurement of methane and carbon dioxide concentration

By volume, LFG typically contains 45% - 65% methane and 40-60% carbon dioxide The rate and volume of LFG produced at a specific site depends

on characteristic of waste (waste composition and age of refuse) and a number of environmental factors (present of oxygen in the landfill, moisture content and temperature) Typically, the more organic waste present in the landfill, the more landfill gas produces Waste component in NS landfill was described in Fig 1 The results of sample analysis are shown in Table 1 These results are not so different due to a stable component of waste and the time of refuse of each cell The result of analyzing samples is around 50% of CH4 in LFG (53% CH4 concentration in average level)

51.9

0.5 6.1 0.9

papers plastic leather, rubber, wo od textile

glass stone, clay,percelain metal

fine fraction

31.9

51.9

0.6.

1 0.5

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73

Figure 1 Composition of Municipal Solid Waste Table 1 Results of LFG sample analysis at NS landfill

Microclimate

Location of

(0C)

Moisture

(%)

Wind velocity

(m/s)

CH 4

(%)

CO 2

(%)

Cell 1

Cell 3

Cell 4B

Table 2 Input parameters used in calculation of Lo

Input parameters Category

3.1.2 Determining methane generation potential of

waste disposed at NS landfill (Lo)

This data was defined through IPCC guidelines

IPCC guidelines presented that Lo correspond

to MCF x DOC x DOCd x 16/12 x F

Where:

MCF = methane correction factor (= 1 with

well managed landfill, supposing that

MCF of NS landfill is 1)

DOC = fraction of degradable organic carbon

DOCd = fraction DOC dissimilate

F = fraction of CH4 in landfill gas

Defining of DOC and DOCd was carried out

depending on waste component, calculated by

IPCC guideline also DOC = 0.4 (A) + 0.17(B) +

0.15 (C) + 0.3 (D), where A: percentage of paper

and textile; B: percentage of garden waste, park

waste and other non-food organic putrescible

waste; C: percentage of food waste; D: percentage

of wood or straw Apply datum from analyzed

sample of waste in Nam Son landfill, the

percentage of DOC is 26.6%

DOCd is calculated based on the theoretical

model that the variation depends on the temperature

of anaerobic zones of the landfill

DOCd= 0.014 x T + 0.28 Where: T is temperature

This factor may vary from 0.42 for 100C to 0.98 for 500C In fact, in many deep landfills (>20m), temperatures of more than 500C have been registered in gas streams from highly productive gas wells (thus clearly anaerobic) In the Nam Son landfill, the height of site now is 18 m Expected height in the future is 30m In this case, assumption

of average temperature of anaerobic zone is 400C, therefore DOCd = 0.84 Taking account the value

of methane concentration in landfill gas F, fraction

of degradable organic content DOC and dissimilate fraction of degradable organic content DOCd, Lo is calculated in the Table 2

Lo calculated in NS landfill is suitable with range of Lo in IPCC guidelines and also suitable with two set of default value used in US-EPA standards

3.1.3 Methane generation rate constant k

As mentioned above, k is a parameter to reflect the LFG emission rate The k relates to waste component, landfill condition and local weather Commonly, if easy-digest organic waste has a higher proportion, landfill is under the

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Pham Chau Thu, Sohei Shimada

74

warmer climate condition, and waste has a

reasonable press by compactor, the k will be larger,

waste easy to digest; the time of digestion will be

shorter In converse, if the waste has a lower

proportion of easy-digest organic waste, landfill is

under the colder climate condition, waste has an

un-well press, k will be smaller, waste difficult to

digest, and time of digestion will be longer For a

landfill, the k can be obtained via site test for

accurate calculation In this study, a k value was

suggested depending on the consideration to the

climate condition at Nam Son landfill, landfill

design, landfill condition, and reference of other

default k values K = 0.04 is assumed for using in

estimation of landfill gas in Nam Son landfill

3.2 Estimation of methane emission at NS landfill

This study used Landfill gas emission model

(LFGEM) to evaluate methane emission from

landfill This model was be run by site - specific

data supplied by above calculation With the

methane concentration of 53% in LFG, methane

generation potential Lo of 158 m3 CH4 per ton of

waste, and the methane generation rate constant

k of 0.04, landfill gas emission model calculates

the methane emission for NS landfill and

presents the development of methane emission

with the time

Figure 2 shows the change of methane

emission at NS landfill with time Methane

emission from landfill decreases according to the

exponential curve after reaching peak gas

production The results show Nam Son landfill has

been exposed with an abundant volume of

methane Maximum of methane emission occurs

at the time of closed landfill operation It takes

account for 60 million m3 at 2020 approximately

Minimum of emission is 2.3 millions m3 of

methane at the second year of landfill operation

(2000) Suppose that gas collection efficiency of recovery system is 70%, maximum of methane collected will be 42 millions m3 These results will

be used to estimate energy recovery potential of

NS landfill, which can be useful for good design

of power generation plant in energy recovery orientation

3.3 Energy recovery potential of NS landfill

Methane has a high calorific potential considered as ideal energy source (39700 MJ/m3) Estimation of energy recovery potential from LFG

is useful for good designing power capacity of plant Figure 3 shows the possible ways for using recovered gas and energy generation potential attaining from recovered gas

Energy generation potential in Nam Son landfill can be started to exploit in 2006 for power generation At this time, methane flow can support enough for power generation with a minimum capacity of 6MW The lifetime of power plant is projected for 20 year In the case of LFG flow excess the design capacity of generator, the gas redundancy should be treated and sale for nearby site Other incentive is burning excess gas in purpose of environmental pollution mitigation only The designed capacity for LFG power generation system at Nam Son landfill further depends on the energy consumption requirement in Nam Son commune The electricity capacity of 6MW could provide enough for the resident’s consumption need located nearby Nam Son area In the Nam Son landfill, there will have compost processing plant, incineration plant and plant for industrial waste treatment in the future Therefore, recovered gas can be also supplied for waste treatment units located on site as a replacement of energy power or supplementary fuel

0

10

20

30

40

50

60

70

Tim e (ye ar)

Lo=158,k=0.04

LFG emission curve by the waste filled in a year (for Mi tons of waste)

Total methane emission volume in a year

(for 

n

i

Mi

1

tons of

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75

0 2 4 6 8 10 12 14 16

1 3 5 7 9 11 13 15 17 19 21 23 25 27 29

Time(year)

Sale medium Btu LFG

Power generation

Sale medium Btu LFG or LFG burning

Figure 3 Energy recovery potential from LFG at Nam Son landfill

3.4 Life Cycle Inventory of LFG power

generation system

28%

Landfill gas

Gas Engine Gas Turbine

Annual electricity generation:42,048 MW 37.7%

20 years

Total life cycle electricity outputs: 840,960 MW

Steam Turbine

Applicable in very large landfill

Figure 4 Outline of Nam Son Landfill gas power generation system

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Pham Chau Thu, Sohei Shimada

76

3.4.1 Options to be compared for LFG conversion

systems

Due to high landfill gas generation potential of

Nam Son landfill, the most appropriate use for

landfill gas is as a fuel for power generation

Several good conversion technologies exist for

generating power: Internal Combustion Engines,

Combustion Turbine, and Boiler/Steam Turbine

Among them, both Gas Turbine and Gas Engine are

capable used in the Nam Son landfill, where landfill gas volumes are sufficient to generate a minimum of 3 to 4 MW The comparison should be done between 3 units of GE with a 2MW capacity

of each and 1 unit of GT with a 6MW capacity The next section will analyze and compare energy consumption and emission each system The electricity can be used on-site to displace purchased electricity or be sold to a nearby electricity user

Table 3 Summary of energy consumption and CO2 emission in whole lifecycle of GE power plant

(kcal/kWh)

CO 2 emission (kg/kWh)

E.C (%)

CO 2 emission (%)

Table 4 Summary of energy consumption and CO 2 emission in lifecycle of G.T power plant

(kcal/kWh)

CO 2 emission (kg/kWh)

E.C (%)

CO 2 emission (%)

3.4.2 Life cycle energy use and CO 2 emission of Gas

Engine power generation system

The results were attained from analytical

accounting of the matter and energy flux, which

can enter or go out of system The energy per

functional unit (kcal/kWh) was calculated from the

life cycle energy use and total electricity generation

during the entire lifetime of power plant

The results in Table 3 show that the

energy-intensive phase is operational phase Operational

phase consumed 2307.7 kcal/kWh while total

thermal energy consumption for lifecycle of system

is 2385.8 kcal/kWh (accounting for 96.7% of total

energy consumption (EC) of system) The negative

value in decommissioning phase shows that energy

can be saved from reusing of materials The primary source of used energy was traced back to estimate the CO2 emission then GHG emission evaluation The result presents the emission in operational phase contributed 95.3% of total emission from whole life cycle of system It can be recorded that most of EC and emission occurs on the operational phase of GE power generation system using LFG

3.4.3 Life cycle energy use and CO 2 emission of Gas Turbine power generation system

Calculating of LCI energy used and GHG emission of G.T system was carried out similar to GE system The results once more demonstrates that energy consumption and GHG emission of LFG power generation system concentrated mainly on operational

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77

phase Gas Turbine has a high compression

requirement, but lower lubricating oil consumption than

Gas Engine The results in Table 4 shows that energy

consumption is accounted for 97.67% and CO2

emission is 96.69% in operational phase of GT system,

slightly higher than that of GE system

3.4.4 Comparison of energy consumption and GHG

emission between G.E and G.T power

generation system

G.T power generation system using LFG consumed energy and emitted CO2 much more than that of GE system The different of them shows in Table 5 Although the difference of each phase, Gas Turbine power plant presents energy consumption and also CO2 emission is higher than that of Gas Engine power plant The reason for this mainly is efficiency of G.T (27%) is lower than that of G.E (37.7%) This estimation is important in comparison of GHG emission mitigation obtained from each of LFG power generation alternative

Table 5 Comparison between Gas Engine power plant and Gas Turbine power plant

Thermal energy consumption

(%)

CO 2 emission (%) Phase

(kg/kWh)

3337.2 (kg/kWh)

0.538 (kcal/kWh)

0.759 (kg/kWh)

3.4.5 Green House Gas (GHG) emission mitigation

attained from LFG power generation system

GHG emission mitigation obtained from

installation of LFG power generation system is

evaluated from total emission reduction by methane

combustion, CO2 emission from whole life cycle of

electricity production (as calculated in previous

section), and CO2 emission offset for electricity

production Because methane emission is a global

climate change agent with 23 times the negative

impact of CO2

Hence:

GHG emission mitigation from whole life

cycle of Gas Engine power plant is:

-[(1*22-5695*0.538/1000)+5695*0.5/1000]*28.88*365*20

= - 4.6 million tons (CO2 equivalent)

= - 2.35 billion m3 (CO2 equivalent)

Where:

1*22 is CO2 mitigation from 1 ton CH4

combustion

5696*0.538/1000 is CO2 emission from whole

life cycle of LFG power generation system by

combustion of 1ton methane

5695*0.5/1000 is CO2 emission offset for

electricity production

GHG emission mitigation from whole life cycle of Gas Turbine power plant is:

-[(1*22-4283*0.759/1000)+4283*0.5/1000]*28.88*365*20

= - 4.4 million tons (CO2 equivalent) = - 2.24 billion m3 (CO2 equivalent) Negative sign indicates the net positive reduction of CO2 emissionusing power generation system

Both Gas Engine and Gas Turbine contribute remarkable to GHG emission mitigation The results indicate that Gas Engine power generation plant was considered more friendly environmental than Gas Turbine system In the consideration of environmental benefits, Gas Engine system appears more attractively than Gas Turbine Gas Engine power generation system could be an ideal style insuring sustainable development for converting LFG to electricity for Nam Son landfill

4 CONCLUSION

By using of LFGEM, the study found the methane gas flow at Nam Son landfill could provide a considerable potential that has many options to be used as a source of energy, where

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Pham Chau Thu, Sohei Shimada

78

LFG electricity generation option is most

preferable Both of GE and GT contribute

remarkable to GHG emission mitigation

Comparison between two LFG power generation

systems with the same capacity, the analysis shows

that the Gas Turbine power generation system

presents a higher thermal energy consumption and

also higher GHG emission However, considering

in whole life cycle, G.E contributes to GHG

emission mitigation more remarkably than that of

G.T system Gas Engine system should be used for

converting LFG to electricity in the consideration

both of environment protection and economic

interest Gas Engine power generation system could

be an ideal style in LFG management orientating to

sustainable development of society

Acknowledgments

The authors wish to acknowledge the help

provided by Ha Noi Urban Environment

Company (URENCO) and Ha Noi Department of

Science, Technology and Environment in

fieldwork testing

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