A P I PUBL*4bL3 94 0732290 0533383 7 5 4 Emissions from Equipment Leaks Volume 111: Appendices Prepared for: American Petroleum Institute Health and Environmental Sciences Department
Trang 2A P I PUBL*4bL3 94 0732290 0533383 7 5 4
Emissions from Equipment Leaks Volume 111: Appendices
Prepared for:
American Petroleum Institute Health and Environmental Sciences Department and
Western States Petroleum Association
API PUBLICATION NUMBER 461 3
PREPARED UNDER CONTRACT BY:
RADIAN CORPORATION SACRAMENTO, CALIFORNIA APRIL 1994
American Petroleum Institute
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API IS NOT UNDERTAKING TO MEET THE DUTIES OF EMPLOYERS, MANUFAC- TURERS, OR SUPPLIERS TO WARN AND PROPERLY TRAIN AND EQUIP THEIR EMPLOYEES, AND OTHERS EXPOSED, CONCERNING HEALTH AND SAFETY RISKS AND PRECAUTIONS, NOR UNDERTAKING THEIR OBLIGATIONS UNDER
NOTHING CONTAINED IN ANY API PUBLICATION IS TO BE CONSTRUED AS GRANTING ANY RIGHT, BY IMPLICATION OR OTHERWISE, FOR THE MANU- FACTURE, SALE, OR USE OF ANY METHOD, APPARATUS, OR PRODUCT COV- ERED BY LETTERS PATENT NEITHER SHOULD ANYTHING CONTAINED IN
ITY FOR INFRINGEMENT OF LETTERS PATENT
THE PUBLICATION BE CONSTRUED AS INSURING ANYONE AGAINST LIABIL-
NOTE: This is to advise the reader that these studies are now under
review by the U.S Environmental Protection Agency The Agency's review may be complete by summer 1994
Copyright 8 1994 Amencan Pctroleum Insuiurc
II
Trang 4API STAFF CONTACTS:
Karin Ritter, Health and Environmental Affairs Department
Paul Wakim, Statistics Department MEMBERS OF THE AIR TOXICS MULTIYEAR STUDY WORKGROUP :
Julian Blomlcy, UNOCAL Miriam Lev-On, ARCO Products Company Richard Russell, API Consultant Hal Taback, M I Consultant Daniel VanDcrZandcn, Chevron Research and Technology Company
This study was Co-funded by the Wcstem States Petroleum Association (WSPA) The following membcrs of the WSPA Fugitivc Emissions Project Steering Committee are recognized for their contributions of timc and expertise:
Frank Giles, Ultramar Mau Marusich, Tosco Refining Company Julian Blomley, UNOCAL
Miriam Lev-On, ARCO Products Company Daniel Van Dcr Zanden, Chevron Research and Technology Company
In addition thc U.S EPA Officc of Air Quality Planning and Standards, Emission Inventory Branch, Research Triangle Park, North Carolina; South Coast Air Quality Management District; Bay Arca Air Quality Management District; and, California Air
Resources Board are gntcfully recognized for providing oversight, additional review of draft reports and concurrcnt QA/QC of final measurements during this study
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Trang 5Data and Calculations B-1 Statistical Evaluations and Correlation Details C-1 Development of Emission Correlation Equations Using the Measurement
Error Method (MEM) Statistical Analysis Method D-1
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INTRODUCTION
This volume, Volume III of the 1993 Study of Refinery Fugitive Em'ssionsffom Equipment Leaks, contains the appendices related to the data calculations and independent audit results Specifically:
e
Appendix A contains raw data from field and emissions calculations;
Appendix B documents the comparison of vapor leak composition to liquid stream composition data and calculations;
Appendix C contains statistical evaluations and correlation details;
Appendix D discusses the development of emission correlation equations using the Measurement Error Method (MEM) statistical analysis method;
Appendix E contains independent audit results; and
Appendix F reprints the Response to Regulatory Agency Comments on the Final Draft of the 1993 Refinery Study
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:ODES:
ACCY AUDTC AUDTD
A U D l l
BL DINV DUP
C
OEL
PRV
Accuracy check Audit gas directly to canister Audit duplicate
Audit gas through tent Blank sampie
Determined to be invalid after review Sample duplicate
Default zero Invalid Liquid sample Nitrogen flow test Pegged source Final screening value pegged but not initial Initial screening value pegged but not final Pure gas accuracy check
Screening values invalid (¡e, initial and final screening values varied by more than a factor of 2)
Component dripping; liquids collected and liquid concentration added to emission rates
Control Manual
Heavy liquid tight liquid
Sulfur recovery unit Vapor recovery unit
Connector Open-ended line Pressure relief valve
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FL
HC
MC NEDL
LCO LPG LVGO OVHG gas
Pa B
R Diesel Reg UL
LABORATORY DATA
NA
Butterfly valve Connector Centrifugal Coupler Diaphrarn valve mange
Horizontal centrifugal
Needle Open-ended line Pressure relief valve Threaded connector Union connector Vertical centrifugal Vertical
Debutinized bottoms Heavy cycle oil
Hydrotreated gas oil Light cycle oil
Uquified petroleum gas Light vacuum gas oil Overhead gas
Pa bottoms Recycled diesel Regular unleaded gasoline
Not analvzed
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