Tiêu chuẩn iso tr 16218 2013

ISO TR 16218 2013(E) Character PDF document pdf © ISO 2013 Packaging and the environment — Processes for chemical recovery Emballage et environnement — Processus de valorisation chimique TECHNICAL REP[.]

Packaging and the environment — Processes for chemical recovery

Emballage et environnement — Processus de valorisation chimique

TECHNICAL REPORT

ISO/TR 16218

First edition 2013-03-15

Reference number

``,`,,,,,,`,,,`,``,,`,,```,`,`-`-`,,`,,`,`,,` -ISO/TR 16218:2013(E)

COPYRIGHT PROTECTED DOCUMENT

© ISO 2013

ŽŽ”‹‰Š–•”‡•‡”˜‡†ǤŽ‡••‘–Š‡”™‹•‡•’‡…‹ϐ‹‡†ǡ‘’ƒ”–‘ˆ–Š‹•’—„Ž‹…ƒ–‹‘ƒ›„‡”‡’”‘†—…‡†‘”—–‹Ž‹œ‡†‘–Š‡”™‹•‡‹ƒ›ˆ‘”

‘” „› ƒ› ‡ƒ•ǡ ‡Ž‡…–”‘‹… ‘” ‡…Šƒ‹…ƒŽǡ ‹…Ž—†‹‰ ’Š‘–‘…‘’›‹‰ǡ ‘” ’‘•–‹‰ ‘ –Š‡ ‹–‡”‡– ‘” ƒ ‹–”ƒ‡–ǡ ™‹–Š‘—– ’”‹‘”

™”‹––‡’‡”‹••‹‘Ǥ‡”‹••‹‘…ƒ„‡”‡“—‡•–‡†ˆ”‘‡‹–Š‡”ƒ––Š‡ƒ††”‡••„‡Ž‘™‘”ǯ•‡„‡”„‘†›‹–Š‡…‘—–”›‘ˆ

–Š‡”‡“—‡•–‡”Ǥ

…‘’›”‹‰Š–‘ˆϐ‹…‡

Tel + 41 22 749 01 11

ƒšΪͶͳʹʹ͹ͶͻͲͻͶ͹

Ǧƒ‹Ž…‘’›”‹‰Š–̷‹•‘Ǥ‘”‰

Web www.iso.org

—„Ž‹•Š‡†‹™‹–œ‡”Žƒ†

Copyright International Organization for Standardization

``,`,,,,,,`,,,`,``,,`,,```,`,`-`-`,,`,,`,`,,` -ISO/TR 16218:2013(E)

Foreword iv

Introduction v

1 Scope 1

2 Normative references 1

͵ ‡”•ƒ††‡ϐ‹‹–‹‘• 1

4 Inventory of relevant existing documents 2

ͷ †‡–‹ϐ‹…ƒ–‹‘‘ˆˆ—”–Š‡”’ƒ…ƒ‰‹‰Ǧ•’‡…‹ϐ‹…‡‡†•”‡Žƒ–‡†–‘…Š‡‹…ƒŽ”‡…‘˜‡”› 2

6 Suitability for chemical recovery process 2

Annex A ȋ‹ˆ‘”ƒ–‹˜‡Ȍ Examples of monomer recovery of PET 4

Annex B ȋ‹ˆ‘”ƒ–‹˜‡Ȍ An example of oil recovery 6

Annex C ȋ‹ˆ‘”ƒ–‹˜‡Ȍ An example of gas recovery 7

Annex D ȋ‹ˆ‘”ƒ–‹˜‡Ȍ An example of reduction agent in blast furnaces 8

Annex E ȋ‹ˆ‘”ƒ–‹˜‡Ȍ An example of raw material for coke manufacturing 9

Annex F ȋ‹ˆ‘”ƒ–‹˜‡Ȍ Assessment checklist — suitability for chemical recovery process 10

Bibliography 11

``,`,,,,,,`,,,`,``,,`,,```,`,`-`-`,,`,,`,`,,` -ISO/TR 16218:2013(E)

Foreword

ȋ–Š‡–‡”ƒ–‹‘ƒŽ”‰ƒ‹œƒ–‹‘ˆ‘”–ƒ†ƒ”†‹œƒ–‹‘Ȍ‹•ƒ™‘”Ž†™‹†‡ˆ‡†‡”ƒ–‹‘‘ˆƒ–‹‘ƒŽ•–ƒ†ƒ”†•

„‘†‹‡• ȋ ‡„‡” „‘†‹‡•ȌǤ Š‡ ™‘” ‘ˆ ’”‡’ƒ”‹‰ –‡”ƒ–‹‘ƒŽ –ƒ†ƒ”†• ‹• ‘”ƒŽŽ› …ƒ””‹‡† ‘—–

–Š”‘—‰Š  –‡…Š‹…ƒŽ …‘‹––‡‡•Ǥ ƒ…Š ‡„‡” „‘†› ‹–‡”‡•–‡† ‹ ƒ •—„Œ‡…– ˆ‘” ™Š‹…Š ƒ –‡…Š‹…ƒŽ …‘‹––‡‡ Šƒ• „‡‡ ‡•–ƒ„Ž‹•Š‡† Šƒ• –Š‡ ”‹‰Š– –‘ „‡ ”‡’”‡•‡–‡† ‘ –Šƒ– …‘‹––‡‡Ǥ –‡”ƒ–‹‘ƒŽ

‘”‰ƒ‹œƒ–‹‘•ǡ ‰‘˜‡”‡–ƒŽ ƒ† ‘Ǧ‰‘˜‡”‡–ƒŽǡ ‹ Ž‹ƒ‹•‘ ™‹–Š ǡ ƒŽ•‘ –ƒ‡ ’ƒ”– ‹ –Š‡ ™‘”Ǥ  …‘ŽŽƒ„‘”ƒ–‡• …Ž‘•‡Ž› ™‹–Š –Š‡ –‡”ƒ–‹‘ƒŽ Ž‡…–”‘–‡…Š‹…ƒŽ ‘‹••‹‘ ȋȌ ‘ ƒŽŽ ƒ––‡”• ‘ˆ

‡Ž‡…–”‘–‡…Š‹…ƒŽ•–ƒ†ƒ”†‹œƒ–‹‘Ǥ

–‡”ƒ–‹‘ƒŽ–ƒ†ƒ”†•ƒ”‡†”ƒˆ–‡†‹ƒ……‘”†ƒ…‡™‹–Š–Š‡”—Ž‡•‰‹˜‡‹–Š‡Ȁ‹”‡…–‹˜‡•ǡƒ”–ʹǤ

Š‡ ƒ‹ –ƒ• ‘ˆ –‡…Š‹…ƒŽ …‘‹––‡‡• ‹• –‘ ’”‡’ƒ”‡ –‡”ƒ–‹‘ƒŽ –ƒ†ƒ”†•Ǥ ”ƒˆ– –‡”ƒ–‹‘ƒŽ

–ƒ†ƒ”†• ƒ†‘’–‡† „› –Š‡ –‡…Š‹…ƒŽ …‘‹––‡‡• ƒ”‡ …‹”…—Žƒ–‡† –‘ –Š‡ ‡„‡” „‘†‹‡• ˆ‘” ˜‘–‹‰Ǥ

—„Ž‹…ƒ–‹‘ ƒ• ƒ –‡”ƒ–‹‘ƒŽ –ƒ†ƒ”† ”‡“—‹”‡• ƒ’’”‘˜ƒŽ „› ƒ– Ž‡ƒ•– ͹ͷ Ψ ‘ˆ –Š‡ ‡„‡” „‘†‹‡• …ƒ•–‹‰ƒ˜‘–‡Ǥ

‡š…‡’–‹‘ƒŽ…‹”…—•–ƒ…‡•ǡ™Š‡ƒ–‡…Š‹…ƒŽ…‘‹––‡‡Šƒ•…‘ŽŽ‡…–‡††ƒ–ƒ‘ˆƒ†‹ˆˆ‡”‡–‹†ˆ”‘

–Šƒ–™Š‹…Š‹•‘”ƒŽŽ›’—„Ž‹•Š‡†ƒ•ƒ–‡”ƒ–‹‘ƒŽ–ƒ†ƒ”†ȋDz•–ƒ–‡‘ˆ–Š‡ƒ”–dzǡˆ‘”‡šƒ’Ž‡Ȍǡ‹–ƒ›

†‡…‹†‡„›ƒ•‹’Ž‡ƒŒ‘”‹–›˜‘–‡‘ˆ‹–•’ƒ”–‹…‹’ƒ–‹‰‡„‡”•–‘’—„Ž‹•Šƒ‡…Š‹…ƒŽ‡’‘”–Ǥ‡…Š‹…ƒŽ

‡’‘”–‹•‡–‹”‡Ž›‹ˆ‘”ƒ–‹˜‡‹ƒ–—”‡ƒ††‘‡•‘–Šƒ˜‡–‘„‡”‡˜‹‡™‡†—–‹Ž–Š‡†ƒ–ƒ‹–’”‘˜‹†‡•ƒ”‡ …‘•‹†‡”‡†–‘„‡‘Ž‘‰‡”˜ƒŽ‹†‘”—•‡ˆ—ŽǤ

––‡–‹‘‹•†”ƒ™–‘–Š‡’‘••‹„‹Ž‹–›–Šƒ–•‘‡‘ˆ–Š‡‡Ž‡‡–•‘ˆ–Š‹•†‘…—‡–ƒ›„‡–Š‡•—„Œ‡…–‘ˆ

’ƒ–‡–”‹‰Š–•Ǥ•ŠƒŽŽ‘–„‡Š‡Ž†”‡•’‘•‹„Ž‡ˆ‘”‹†‡–‹ˆ›‹‰ƒ›‘”ƒŽŽ•—…Š’ƒ–‡–”‹‰Š–•Ǥ

Ȁ ͳ͸ʹͳͺ ™ƒ• ’”‡’ƒ”‡† „› ‡…Š‹…ƒŽ ‘‹––‡‡ Ȁ ͳʹʹǡ Packagingǡ —„…‘‹––‡‡  Ͷǡ Packaging and Environment.

Copyright International Organization for Standardization

``,`,,,,,,`,,,`,``,,`,,```,`,`-`-`,,`,,`,`,,` -ISO/TR 16218:2013(E)

Introduction

‡•‘—”…‡—•‡‘’–‹‹œƒ–‹‘ǡ”‡•‘—”…‡•ƒ˜‹‰•ǡ‡˜‹”‘‡–ƒŽ‹’ƒ…–•ǯ‹‹‹œƒ–‹‘ƒ”‡ƒ‘‰’”‹‘”‹–‹‡•

‹ƒ’‡”•’‡…–‹˜‡‘ˆ•—•–ƒ‹ƒ„Ž‡†‡˜‡Ž‘’‡–ǤŠ‡•‡’”‹‘”‹–‹‡•ƒ’’Ž›ƒŽ•‘–‘–Š‡’ƒ…ƒ‰‹‰•‡…–‘”Ǥ‹…‡

ƒ››‡ƒ”•ǡ–Š‹•Žƒ––‡”Šƒ•†‡˜‡Ž‘’‡†‹‹–‹ƒ–‹˜‡•‹–Š‡•‡†‹”‡…–‹‘•ǡ™‘”‹‰‘–Š‡’ƒ…ƒ‰‹‰†‡•‹‰

ƒ•’‡…–•ƒ•™‡ŽŽƒ•‘–Š‡‘”‰ƒ‹œƒ–‹‘‘ˆ–Š‡Ž‘‰‹•–‹……Šƒ‹ǡ‘•‡––‹‰—’”‡…‘˜‡”›ƒ†”‡…›…Ž‹‰•…Š‡‡•

‘”‘–Š‡†‡˜‡Ž‘’‡–‘ˆ—•‡†’ƒ…ƒ‰‹‰”‡…‘˜‡”›‘””‡…›…Ž‹‰–‡…Š‘Ž‘‰‹‡•Ǥ ‘”˜ƒ”‹‘—•”‡ƒ•‘•ǡ‹…Ž—†‹‰–Š‡†‹˜‡”•‹–›‘ˆƒ–‹‘ƒŽ‘””‡‰‹‘ƒŽ…‘–‡š–•ǡ•‘‡…‘ˆ—•‹‘ƒ”‘•‡ˆ”‘

–Š‡ˆƒ…––Šƒ–‡‹–Š‡”Ž‡‰‹•Žƒ–‹‘•‘”…‘—‹…ƒ–‹‘‡••ƒ‰‡•ˆ”‘–Š‡…‘…‡”‡†•–ƒ‡Š‘Ž†‡”•…‘—Ž†

”‡Ž›‘…Ž‡ƒ”ƒ†—ƒ‹‘—•Ž›ƒ‰”‡‡†—’‘†‡ϐ‹‹–‹‘•‘ˆ–Š‡–‡”•—•‡†ƒ†‘ˆ–Š‡”‡•’‡…–‹˜‡„‡‡ϐ‹–•

‘ˆ–Š‡˜ƒ”‹‘—•”‡…‘˜‡”›Ȁ”‡…›…Ž‹‰‘’–‹‘•Ǥ ȀͳʹʹȀͶ‹•†‡˜‡Ž‘’‹‰•–ƒ†ƒ”†•‘–Š‡‘’–‹‹œƒ–‹‘‘ˆ–Š‡’ƒ…ƒ‰‹‰•›•–‡ȋͳͺ͸ͲʹȌǡ‘

”‡—•‡ȋͳͺ͸Ͳ͵Ȍǡ‘ƒ–‡”‹ƒŽ”‡…›…Ž‹‰ȋͳͺ͸ͲͶȌǡ‘‡‡”‰›”‡…‘˜‡”›ȋͳͺ͸ͲͷȌƒ†‘‘”‰ƒ‹…

”‡…›…Ž‹‰ȋͳͺ͸Ͳ͸ȌǤͳͺ͸Ͳͳ™‹ŽŽ†‡ϐ‹‡–Š‡‰‡‡”ƒŽ”‡“—‹”‡‡–•ˆ‘”–Š‡—•‡‘ˆ–Š‡•‡•–ƒ†ƒ”†•

‹–Š‡ϐ‹‡Ž†‘ˆ’ƒ…ƒ‰‹‰ƒ†–Š‡‡˜‹”‘‡–Ǥ

Š‹•‡…Š‹…ƒŽ‡’‘”–‹•ƒƒ––‡’––‘…Žƒ”‹ˆ›•‘‡‹†‡ƒ•”‡Žƒ–‹‰–‘–Š‡…‘…‡’–‘ˆDzŠ‡‹…ƒŽ‡…‘˜‡”›dzǡ

–‘’—–‹–‹–Š‡’‡”•’‡…–‹˜‡‘ˆ–Š‡‘–Š‡””‡…‘˜‡”›‘’–‹‘•ƒ†–‘Š‡Ž’Ž‘…ƒŽ•–ƒ‡Š‘Ž†‡”•–‘‹†‡–‹ˆ›–Š‡

Ž‘…ƒŽŽ›‘•–ƒ’’”‘’”‹ƒ–‡–”‡ƒ–‡–‘’–‹‘ǡ‘–Š‡„ƒ•‹•‘ˆƒ…‘‘—†‡”•–ƒ†‹‰‘ˆ–Š‡–‡”•ƒ†‘ˆ

–Š‡„ƒ•‹…”‡“—‹”‡‡–••’‡…‹ϐ‹…–‘‡ƒ…Š”‡…‘˜‡”›–‡…Š‘Ž‘‰›Ǥ–Š‹•‡…Š‹…ƒŽ‡’‘”–ǡ–Š‡‡–Š‘†‘Ž‘‰‹‡•

‘ˆ…Š‡‹…ƒŽ”‡…‘˜‡”›‘ˆ—•‡†’ƒ…ƒ‰‹‰ƒ”‡†‡•…”‹„‡†Ǥ

``,`,,,,,,`,,,`,``,,`,,```,`,`-`-`,,`,,`,`,,` -Copyright International Organization for Standardization

Packaging and the environment — Processes for chemical recovery

1 Scope

‡˜‡”ƒŽ’”‘…‡••‡•ˆ‘”…Š‡‹…ƒŽ”‡…‘˜‡”›‘ˆ—•‡†’ƒ…ƒ‰‹‰ƒ”‡…‘•‹†‡”‡†–‘„‡ƒ–‡”‹ƒŽ”‡…›…Ž‹‰ǤŠ‡

ˆ‘…—•‘ˆ–Š‹•‡…Š‹…ƒŽ‡’‘”–‹•ˆ‘”—•‡†’ƒ…ƒ‰‹‰ǡƒŽ–Š‘—‰Š–Š‡’”‘…‡••‡•†‡•…”‹„‡†ƒ”‡‘–•’‡…‹ϐ‹…

ˆ‘”—•‡†’ƒ…ƒ‰‹‰ƒ†…ƒ„‡—•‡†ˆ‘””‡…‘˜‡”›‘ˆ‘–Š‡”ƒ–‡”‹ƒŽ•‘ˆ•ƒ‡–›’‡Ǥ”‘…‡••‡•ˆ‘”…Š‡‹…ƒŽ

”‡…‘˜‡”› ‘ˆ —•‡† ’ƒ…ƒ‰‹‰ ƒ”‡ ƒ’’Ž‹…ƒ„Ž‡ ˆ‘” ’Žƒ•–‹… ’ƒ…ƒ‰‹‰ ‘” „‹‘ƒ••Ǧ„ƒ•‡† ’ƒ…ƒ‰‹‰ǡ ™Š‹…Š

‹‰Š–„‡‹–‡”’”‡–‡†‹–™‘†‹ˆˆ‡”‡–™ƒ›•ǣ Ȅ ’”‘…‡••‡•–‘”‡…‘˜‡”˜ƒŽ—ƒ„Ž‡…Š‡‹…ƒŽ•—„•–ƒ…‡•„›…Š‡‹…ƒŽ–”‡ƒ–‡–‘ˆ—•‡†’ƒ…ƒ‰‹‰ǡˆ‘”

‡šƒ’Ž‡ǡ –‘ ”‡…‘˜‡” ‘‘‡”• ‘ˆ ’‘Ž›‡–Š›Ž‡‡ –‡”‡’Š–ŠƒŽƒ–‡ ȋȌ „› Š›†”‘Ž›•‹•ǡ ‰Ž›…‘Ž›•‹• ‘”

‡–Šƒ‘Ž›•‹•ǡ –‘ ”‡…‘˜‡” ‘‹Ž „› …ƒ–ƒŽ›–‹… ”‡ƒ…–‹‘ ‘” ’›”‘Ž›•‹•ǡ –‘ ”‡…‘˜‡” ˜ƒŽ—ƒ„Ž‡ ‰ƒ•‡• •—…Š ƒ•

Š›†”‘‰‡„›‰ƒ•‹ϐ‹…ƒ–‹‘ǡ–‘”‡…‘˜‡”…‘‡ǡ‘‹Žƒ†‰ƒ••‡•„›…‘‡ˆƒ…–‹‘Ǣ Ȅ ’”‘…‡••‡•–‘†‹”‡…–Ž›•—„•–‹–—–‡—•‡†’ƒ…ƒ‰‹‰ˆ‘”ƒ–—”ƒŽ”‡•‘—”…‡•™‹–Š‘—–…Š‡‹…ƒŽ’”‡–”‡ƒ–‡–ǡ

ˆ‘” ‡šƒ’Ž‡ǡ ϐŽƒ‡• ‘ˆ —•‡† ’Žƒ•–‹… ’ƒ…ƒ‰‹‰ ƒ› —•‡ ‹ „Žƒ•– ˆ—”ƒ…‡ ‹ –Š‡ ’Žƒ…‡ ‘ˆ …‘‡ ƒ• ƒ

”‡†—…‹‰ƒ‰‡–Ǥ

šƒ’Ž‡•ƒ†‡›…Šƒ”ƒ…–‡”‹•–‹…•‘ˆ…Š‡‹…ƒŽ”‡…‘˜‡”›’”‘…‡••‡•ƒ”‡‰‹˜‡‹‡š‡• to E

‹†‡–‹…ƒŽ –‘ ‘” †‹ˆˆ‡”‹‰ ˆ”‘ǡ –Š‡ •–ƒ”–‹‰ ”ƒ™ ƒ–‡”‹ƒŽ• –Šƒ– ™‡”‡ —•‡† ˆ‘” –Š‡ ’”‘†—…–‹‘ ‘ˆ –Š‡ ’ƒ…ƒ‰‹‰

ƒ–‡”‹ƒŽ•ǡ‘”–Š‡†‹”‡…–•—„•–‹–—–‹‘‘ˆƒ–—”ƒŽ”‡•‘—”…‡•„›—•‹‰—•‡†’ƒ…ƒ‰‹‰ǤŠ‡•‡”‡…‘˜‡”‡†…Š‡‹…ƒŽ•…ƒ

„‡—•‡†ƒ••—…Šǡ‘”ƒ•”‡ƒ…–ƒ–•‹ˆ—”–Š‡”…Š‡‹…ƒŽ•›–Š‡•‡•Ǣ†‹”‡…–Ž›Ǯin situǯ‘”‹ƒ‘–Š‡”’”‘†—…–‹‘’”‘…‡••Ǥ

2 Normative references

Š‡ ˆ‘ŽŽ‘™‹‰ †‘…—‡–•ǡ ‹ ™Š‘Ž‡ ‘” ‹ ’ƒ”–ǡ ƒ”‡ ‘”ƒ–‹˜‡Ž› ”‡ˆ‡”‡…‡† ‹ –Š‹• †‘…—‡– ƒ† ƒ”‡

‹†‹•’‡•ƒ„Ž‡ ˆ‘” ‹–• ƒ’’Ž‹…ƒ–‹‘Ǥ ‘” †ƒ–‡† ”‡ˆ‡”‡…‡•ǡ ‘Ž› –Š‡ ‡†‹–‹‘ …‹–‡† ƒ’’Ž‹‡•Ǥ ‘” —†ƒ–‡†

”‡ˆ‡”‡…‡•ǡ–Š‡Žƒ–‡•–‡†‹–‹‘‘ˆ–Š‡”‡ˆ‡”‡…‡††‘…—‡–ȋ‹…Ž—†‹‰ƒ›ƒ‡†‡–•Ȍƒ’’Ž‹‡•Ǥ

ʹͳͲ͸͹ǡPackaging — Vocabulary

of packaging and the environment

͵ ‡”•ƒ††‡ϐ‹‹–‹‘•

‘”–Š‡’—”’‘•‡•‘ˆ–Š‹•†‘…—‡–ǡ–Š‡–‡”•ƒ††‡ϐ‹‹–‹‘•‰‹˜‡‹ʹͳͲ͸͹ǡͳͺ͸Ͳͳǡƒ†–Š‡

ˆ‘ŽŽ‘™‹‰ƒ’’Ž›Ǥ

3.1 monomer recovery

’”‘…‡••‡•–‘”‡…‘˜‡”‘‘‡”••—…Šƒ•„›†‡…‘’‘•‹–‹‘‘ˆ—•‡†’ƒ…ƒ‰‹‰

‘–‡ ͳ –‘ ‡–”›ǣ Š‡ ‹†—•–”‹ƒŽ ’”‘…‡••‡• ƒ”‡ ‡•–ƒ„Ž‹•Š‡† –‘ ”‡…‘˜‡” ‘‘‡”• –‘ ’”‘†—…‡ ’‘Ž›‡–Š›Ž‡‡

–‡”‡’Š–ŠƒŽƒ–‡ȋȌ•—…Šƒ•†‹‡–Š›ŽǦ–‡”‡’Š–ŠƒŽƒ–‡ȋȌǡ„‹•ǦŠ›†”‘š›‡–Š›ŽǦ–‡”‡’Š–ŠƒŽƒ–‡ȋȌƒ†‡–Š›Ž‡‡

ƒ”‡ƒ––Š‡†‡˜‡Ž‘’‡–•–ƒ‰‡ˆ‘”’‘Ž›‡”••—…Šƒ•Ǣ’‘Ž›…ƒ”„‘ƒ–‡ȋȌǡ’‘Ž›ƒ‹†‡ȋȌǡ’‘Ž›•–›”‡‡ȋȌƒ†’‘Ž›

Žƒ…–‹…ƒ…‹†ȋȌ’‘Ž›‡”Ǥ

``,`,,,,,,`,,,`,``,,`,,```,`,`-`-`,,`,,`,`,,` -ISO/TR 16218:2013(E)

3.2

oil recovery

’”‘…‡••‡•–‘”‡…‘˜‡”‘‹Žˆ”‘—•‡†’ƒ…ƒ‰‹‰•—…Šƒ•„›†‡…‘’‘•‹–‹‘™‹–Š‘”™‹–Š‘—–…ƒ–ƒŽ›•–

3.3

gas recovery

’”‘…‡••‡•–‘”‡…‘˜‡”‰ƒ•‡•—•‡ˆ—Žˆ‘”…Š‡‹…ƒŽ‹†—•–”‹‡•ƒ•–Š‡‹””ƒ™ƒ–‡”‹ƒŽ•ȋŠ›†”‘‰‡ƒ†…ƒ”„‘

‘‘Ǧ‘š‹†‡Ȍ•—…Šƒ•„›…ƒ”„‘‹œƒ–‹‘ƒ†’ƒ”–‹ƒŽ„—”‹‰‘ˆ—•‡†’ƒ…ƒ‰‹‰

3.4

reduction agent in blast furnaces

’”‘†—…– ’”‘˜‹†‹‰ …ƒ”„‘ ƒ† Š›†”‘‰‡ –‘ ”‡’Žƒ…‡ …‘‡ ™‹–Š —•‡† ’ƒ…ƒ‰‹‰ ‹ „Žƒ•– ˆ—”ƒ…‡• ˆ‘” steel production

‘–‡ͳ–‘‡–”›ǣ–Š‡…‘˜‡–‹‘ƒŽ•–‡‡Ž’”‘†—…–‹‘’”‘…‡••‡•ǡ…‘‡‹•—•‡†ƒ•ƒ”‡†—…–‹‘ƒ‰‡–Ǥ

3.5

raw material for coke manufacturing

’”‘†—…––‘’ƒ”–‹ƒŽŽ›”‡’Žƒ…‡…‘ƒŽ™‹–Š—•‡†’ƒ…ƒ‰‹‰ˆ‘””ƒ™ƒ–‡”‹ƒŽ‘ˆ…‘‡ˆ—”ƒ…‡•–‘’”‘†—…‡…‘‡

4 Inventory of relevant existing documents

ƒ”‹‘—•‘’–‹‘•‘ˆ…Š‡‹…ƒŽ”‡…‘˜‡”›ƒ”‡ƒŽ•‘ƒ††”‡••‡†‹•‘‡•–ƒ†ƒ”†‹œƒ–‹‘†‘…—‡–•ǡˆ‘”‡šƒ’Ž‡

–Š‡ϐ‹‡Ž†‘ˆ’ƒ…ƒ‰‹‰ƒ†–Š‡‡˜‹”‘‡–

Ȅ ͳͺ͸ͲͶǡƒ…ƒ‰‹‰ƒ†–Š‡‡˜‹”‘‡–Ȅƒ–‡”‹ƒŽ”‡…›…Ž‹‰

Ȅ ʹͳͲ͸͹ǡƒ…ƒ‰‹‰Ȅ‘…ƒ„—Žƒ”›

ͷ †‡–‹ϐ‹…ƒ–‹‘‘ˆˆ—”–Š‡”’ƒ…ƒ‰‹‰Ǧ•’‡…‹ϐ‹…‡‡†•”‡Žƒ–‡†–‘…Š‡‹…ƒŽ”‡…‘˜‡”›

Š‡’”‹‡‘„Œ‡…–‹˜‡‘ˆ–Š‹•‡…Š‹…ƒŽ‡’‘”–‹••’‡…‹ϐ‹…ˆ‘”—•‡†’ƒ…ƒ‰‹‰Ǥ‘”†‡”–‘‡‡––Š‡‡‡†•‘ˆ

–Š‡ƒ”‡–ǡ–Š‡—•‡†’ƒ…ƒ‰‹‰ˆ”ƒ…–‹‘‡†‹‰—’‹ƒ…Š‡‹…ƒŽ”‡…‘˜‡”›’”‘…‡••‹•‹ƒ›…ƒ•‡•—•‡†

‹…‘„‹ƒ–‹‘™‹–Š‘–Š‡”ƒ–‡”‹ƒŽˆ”ƒ…–‹‘•‘ˆ–Š‡•ƒ‡–›’‡ǤŠ‡”‡ˆ‘”‡–Š‡’”‘…‡••‡•†‡•…”‹„‡†‹–Š‹•

‡…Š‹…ƒŽ‡’‘”–ƒ”‡‹’”ƒ…–‹•‡‘–”‡•–”‹…–‡†–‘—•‡†’ƒ…ƒ‰‹‰Ǥ

ƒ…Š ”‡…‘˜‡”› ‘’–‹‘ Šƒ• ‹–• ‘™ •’‡…‹ϐ‹…ƒ–‹‘•ǡ ‡Ǥ‰Ǥ —„‡” ‘ˆ ƒ–‡”‹ƒŽ•ǡ ƒš‹— Ž‡˜‡Ž• ‘ˆ …‘–ƒ‹ƒ–‹‘ǡ‡–…Ǥ‡”–ƒ‹ƒ–‡”‹ƒŽ•ƒ›„‡‹…‘’ƒ–‹„Ž‡™‹–Š•‘‡…Š‡‹…ƒŽ”‡…‘˜‡”›’”‘…‡••‡•Ǥ …ƒ•‡•‘ˆ•‹‰‹ϐ‹…ƒ–ƒ‘—–‘ˆ•—…Šƒ–‡”‹ƒŽ•„‡‹‰‹…Ž—†‡†ǡ’”‡Ǧ–”‡ƒ–‡––‘”‡‘˜‡–Š‡•‡•Š‘—Ž†„‡

‹–”‘†—…‡†–‘ƒ˜‘‹†–Š‘•‡’”‘„Ž‡•Ǥ

6 Suitability for chemical recovery process

Š‡‹…ƒŽ”‡…‘˜‡”›‹•‹…Ž—†‡†ƒ•ƒ–‡”‹ƒŽ”‡…›…Ž‹‰ƒ•ƒ‘’–‹‘Ǥˆ—•‡†’ƒ…ƒ‰‹‰ǡ‹Ǥ‡Ǥ•‘—”…‡ƒ–‡”‹ƒŽǡ

‹•…‘ŽŽ‡…–‡†‹‘‘Ǧƒ–‡”‹ƒŽ”‘—–‡ǡ–Š‡—•‡†’ƒ…ƒ‰‹‰‹•ˆ‡ƒ•‹„Ž‡ˆ‘”‡…Šƒ‹…ƒŽ”‡…›…Ž‹‰Ǥ–Š‡…ƒ•‡

‘ˆ„‘––Ž‡•ǡŠ‘™‡˜‡”ǡ…Š‡‹…ƒŽ”‡…‘˜‡”›„›‘‘‡””‡…‘˜‡”›‹•ƒŽ•‘ˆ‡ƒ•‹„Ž‡–‘‘„–ƒ‹Š‹‰Š‰”ƒ†‡

”‡•‹Ǥ–Š‡…ƒ•‡‘ˆ‡š’ƒ†‡†’‘Ž›•–›”‡‡ȋȌǡ•‘‡’ƒ”–•‘ˆ•‘—”…‡ƒ–‡”‹ƒŽ…ƒ„‡”‡…›…Ž‡†„›

‡…Šƒ‹…ƒŽ”‡…›…Ž‹‰ǡƒ†–Š‡‘–Š‡”’ƒ”–•ǡ‹Ǥ‡Ǥ…‘–ƒ‹ƒ–‡†ƒ–‡”‹ƒŽǡƒ”‡‰‡‡”ƒŽŽ›—•‡†ƒ••‘—”…‡‘ˆ …Š‡‹…ƒŽ”‡…‘˜‡”›Ǥˆ—•‡†’ƒ…ƒ‰‹‰ǡ‹Ǥ‡Ǥ•‘—”…‡ƒ–‡”‹ƒŽǡ‹•…‘ŽŽ‡…–‡†‹…‘‹‰Ž‡†ƒ–‡”‹ƒŽ”‘—–‡ǡ

•—…Šƒ–‡”‹ƒŽ…ƒ„‡—•‡†ƒ••‘—”…‡•‘ˆ…Š‡‹…ƒŽ”‡…‘˜‡”›‘–Š‡”–Šƒ‘‘‡””‡…‘˜‡”›ǤŠ‡•‡”‡…‘˜‡”›

‘’–‹‘•’‘••‡••™‹†‡ƒ……‡’–ƒ„‹Ž‹–›‘ˆ•‘—”…‡ƒ–‡”‹ƒŽǡ…‘‹‰Ž‡†‘”…‘–ƒ‹ƒ–‡†ǡ‹ˆ‘Ž›‹–†‘‡•‘–

‹’‡†‡–Š‡‘’‡”ƒ–‹‘‘ˆˆƒ…‹Ž‹–‹‡•Ǥ

Copyright International Organization for Standardization

``,`,,,,,,`,,,`,``,,`,,```,`,`-`-`,,`,,`,`,,` -ISO/TR 16218:2013(E)

‡šƒ’Ž‡‘ˆƒ••‡••‡–…Š‡…Ž‹•–‹•‰‹˜‡‹‡š

‘ˆˆƒ…‹Ž‹–‹‡•ǡ„‹‘ƒ••Ǧ„ƒ•‡†ƒ–‡”‹ƒŽ••—…Šƒ•™‘‘†ǡ’ƒ’‡”ƒ†ϐ‹„”‡…ƒ„‡‹…‘”’‘”ƒ–‡†‹–‘–Š‡’”‘…‡••Ǥ

``,`,,,,,,`,,,`,``,,`,,```,`,`-`-`,,`,,`,`,,` -ISO/TR 16218:2013(E)

Annex A

ȋ‹ˆ‘”ƒ–‹˜‡Ȍ

Examples of monomer recovery of PET

A.1 Material

›’”‘†—…–ǡ‹…Ž—†‹‰„‘––Ž‡•ǡϐ‹Žǡϐ‹„”‡ƒ†ˆƒ„”‹…•ǡ…ƒ„‡—•‡†ˆ‘”–Š‡‘‘‡””‡…‘˜‡”›‘ˆ

Ǥ•‡†„‘––Ž‡•ƒ”‡ƒ…ƒ†‹†ƒ–‡‘ˆ•–ƒ”–‹‰ƒ–‡”‹ƒŽˆ‘”–Š‡’”‘…‡••Ǥ•‡†„‘––Ž‡•ƒ”‡•‘”–‡† before processing

A.2 Decomposition processes

‹†—•–”‹ƒŽ’”‘…‡••‡•ǡ„‘––Ž‡•ƒ”‡•Š”‡††‡†ǡ™ƒ•Š‡†ǡƒ††”‹‡†–‘’”‘†—…‡ϐŽƒ‡•ƒ••Š‘™‹

–Š‡ϐŽƒ‹‰‘’‡”ƒ–‹‘Ǥ

PET bottle

shredding washing drying

PET lakes chemical

decomposition

‹‰—”‡ǤͳȄ”‡Ǧ–”‡ƒ–‡–ȋϐŽƒ‡’”‘†—…–‹‘Ȍ

™‘†‡…‘’‘•‹–‹‘’”‘…‡••‡•Šƒ˜‡„‡‡‡•–ƒ„Ž‹•Š‡†ǡƒ‡Ž›‰Ž›…‘Ž›•‹•ƒ†‡–Šƒ‘Ž›•‹•ǡƒ••Š‘™‹

Figure A.2ƒ†Figure A.3ǡ”‡•’‡…–‹˜‡Ž›Ǥ

PET

lakes

Ethylene glycol

Depolymerization BHET Puriied

BHEAT

Ethylene glycol

Decolouration Crystallization Filtration Molecular distillation

Polymerization

PET resin

Figure A.2 — Glycolysis process

 ‰Ž›…‘Ž›•‹•ǡ –Š‡ ‹š–—”‡ ‘ˆ  ϐŽƒ‡• ƒ† ‡–Š›Ž‡‡ ‰Ž›…‘Ž ‹• Š‡ƒ–‡† —’ –‘ †‡…‘’‘•‡ Ǥ ‹•Ǧ

Š›†”‘š›‡–Š›ŽǦ–‡”‡’Š–ŠƒŽƒ–‡ȋȌ‹•”‡…‘˜‡”‡†„›–Š‹•’”‘…‡••ǤŠ‡”‡…‘˜‡”‡†‹•†‡Ǧ…‘Ž‘—”‡†ǡ …”›•–ƒŽŽ‹œ‡†ǡ ϐ‹Ž–‡”‡†ǡ ƒ† –Š‡ ‘Ž‡…—Žƒ” †‹•–‹ŽŽ‡† –‘ ‘„–ƒ‹ ’—”‡ Ǥ Š‡ ’—”‡  ‹• †‹”‡…–Ž›

‡’Ž‘›‡†–‘’‘Ž›‡”‹œ‡”‡•‹Ǥ–Š›Ž‡‡‰Ž›…‘Ž‹•”‡…‘˜‡”‡†ˆ”‘–Š‡’‘Ž›‡”‹œƒ–‹‘’”‘…‡••Ǥ

Copyright International Organization for Standardization

``,`,,,,,,`,,,`,``,,`,,```,`,`-`-`,,`,,`,`,,` -ISO/TR 16218:2013(E)

BHET

Puriied DMT PET lakes

Methanol

Depolymerization

DMT

Ethylene glycol

TPA Methanol

Polymerization PET resin

Ethylene Glycol

Decolouration Crystallization Filtration

Figure A.3 — Methanolysis process

‡–Šƒ‘Ž›•‹•ǡ–Š‡‹š–—”‡‘ˆϐŽƒ‡•ƒ†‡–Šƒ‘Ž‹•Š‡ƒ–‡†—’–‘†‡…‘’‘•‡Ǥ‹Ǧ‡–Š›ŽǦ

–‡”‡’Š–ŠƒŽƒ–‡ ȋȌ ‹• ”‡…‘˜‡”‡† „› –Š‹• ’”‘…‡••Ǥ Š‡ ”‡…‘˜‡”‡†  ‹• †‡Ǧ…‘Ž‘—”‡†ǡ …”›•–ƒŽŽ‹œ‡†ǡ ϐ‹Ž–‡”‡†–‘‘„–ƒ‹’—”‡ǤŠ‡’—”‡‹•…‘˜‡”–‡†‹–‘’—”‡–‡”‡’Š–ŠƒŽ‹…ƒ…‹†ȋȌƒ†‡–Šƒ‘ŽǤ

Š‹•‹•…‘˜‡”–‡†‹–‘„›ƒ††‹–‹‘‘ˆ‡–Š›Ž‡‡‰Ž›…‘Žǡ™Š‹…Š‹•‡’Ž‘›‡†–‘’‘Ž›‡”‹œ‡

”‡•‹Ǥ–Š›Ž‡‡‰Ž›…‘Ž‹•”‡…‘˜‡”‡†ˆ”‘–Š‡’‘Ž›‡”‹œƒ–‹‘’”‘…‡••Ǥ

``,`,,,,,,`,,,`,``,,`,,```,`,`-`-`,,`,,`,`,,` -ISO/TR 16218:2013(E)

Annex B

ȋ‹ˆ‘”ƒ–‹˜‡Ȍ

An example of oil recovery

B.1 Material

›‘”‰ƒ‹…ƒ–‡”‹ƒŽ•‹…Ž—†‹‰’Žƒ•–‹…•ƒ†„‹‘ƒ••Ǧ„ƒ•‡†ƒ–‡”‹ƒŽ•…ƒ„‡—•‡†ˆ‘”‘‹Ž”‡…‘˜‡”›Ǥ•‡†

’ƒ…ƒ‰‹‰‹•ƒ…ƒ†‹†ƒ–‡‘ˆ•–ƒ”–‹‰ƒ–‡”‹ƒŽˆ‘”–Š‡’”‘…‡••ǡ‹ˆ‘Ž›‹–‹•…‘ŽŽ‡…–‡†Ȁ•‘”–‡†Ǥ‘‹‰Ž‡†

ƒ†•Ž‹‰Š–Ž›…‘–ƒ‹ƒ–‡†—•‡†’ƒ…ƒ‰‹‰…ƒƒ’’Ž›ˆ‘”–Š‹•’”‘…‡••Ǥ

–Š‡†‡ǦŽ‡š–”—†‡”ǡ„‹‘ƒ••Ǧ„ƒ•‡†ƒ–‡”‹ƒŽ••—…Šƒ•™‘‘†ǡ’ƒ’‡”ƒ†ϐ‹„”‡ƒ”‡‹…‘”’‘”ƒ–‡†‹–‘–Š‡’”‘…‡••Ǥ

B.2 Process

‹Ž”‡…‘˜‡”›‹•ƒ’”‘…‡••–‘”‡…‘˜‡”Š‹‰Š“—ƒŽ‹–›‘‹ŽȋŠ›†”‘Ǧ…ƒ”„‘‘‹ŽȌˆ”‘—•‡†’ƒ…ƒ‰‹‰„›–”‡ƒ–‡–

ƒ–Š‹‰Š–‡’‡”ƒ–—”‡•ȋ—†‡”‹‡”–…‘†‹–‹‘•Ȍ™‹–Š‘”™‹–Š‘—–…ƒ–ƒŽ›•–•ǤŠ‡”‡ƒ”‡•‡˜‡”ƒŽ’”‘…‡••‡•

‹‰—”‡Ǥͳ

Heating in pyrolysis drum

Used packaging (Source material)

Gas

Pretreatment by de-HCl extruder

Residue

Heat

Gas incineration HCl recover

Agglomerate

Recovered HCl

Product cooling

Energy recovery

High quality oil

Figure B.1 — A typical process of oil recovery system

Š‡—•‡†’ƒ…ƒ‰‹‰‹•ǡƒ–ϐ‹”•–ǡ‹–”‘†—…‡†‹–‘ƒ‡š–”—†‡”–‘”‡‘˜‡…ŠŽ‘”‹‡Ǥ›‹…‹‡”ƒ–‹‘‘ˆ–Š‡

‰‡‡”ƒ–‡†‰ƒ•ǡŽ‹•”‡…‘˜‡”‡†ˆ‘””‡…›…Ž‹‰ǤŠ‡Š‡ƒ–‰‡‡”ƒ–‡†„›‹…‹‡”ƒ–‹‘‹•—–‹Ž‹œ‡†‹–Š‡’”‘…‡••Ǥ

Š‡’Žƒ•–‹…‡Ž–‡š–”—†‡†ˆ”‘–Š‡‡š–”—†‡”‹•‹–”‘†—…‡†‹–‘ƒ’›”‘Ž›•‹•†”—–‘†‡…‘’‘•‡’‘Ž›‡”•Ǥ

Š‡’”‘†—…–•ƒ”‡…‘‘Ž‡†–‘‘„–ƒ‹Š‹‰Š“—ƒŽ‹–›‘‹Žǡ™Š‡”‡ƒ•‰ƒ•…‘’‘‡–•ƒ”‡‡”‰‡†™‹–Š–Š‡‰ƒ•

‰‡‡”ƒ–‡†ˆ”‘–Š‡‡š–”—†‡”ǤŠ‡”‡•‹†—‡‹–Š‡’›”‘Ž›•‹•†”—…ƒŽŽ‡†…Šƒ”‹•—–‹Ž‹œ‡†ˆ‘”‡‡”‰›”‡…‘˜‡”›Ǥ

B.3 Use

Š‡”‡…‘˜‡”‡†Š‹‰Š“—ƒŽ‹–›‘‹Ž…ƒ„‡—•‡†‹–Š‡’Žƒ…‡‘ˆŠ‡ƒ˜›‘‹Žǡƒ•‡‹–Š‡”…Š‡‹…ƒŽˆ‡‡†•–‘…‘”ˆ—‡ŽǤ

ƒ’‘”–‹‘‘ˆ–Š‡—•‡†’ƒ…ƒ‰‹‰‹•…‘•—‡†–‘•—’’Ž›‡‡”‰›ˆ‘”–Š‡’”‘…‡••ǤŠ—•ǡƒŽŽ‘ˆ–Š‡—•‡†’ƒ…ƒ‰‹‰‹•

‡˜‡””‡…‘˜‡”‡†ƒ•‘‹ŽǤŠ‡’”‹‘”‹–›‘ˆ‘‹Ž”‡…‘˜‡”›‹••‡–Ž‘™‡”–Šƒ–Š‡’”‹‘”‹–›ˆ‘”‘”‡‡ˆϐ‹…‹‡–’”‘…‡••‡•Ǥ

Copyright International Organization for Standardization