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Tiêu đề Standard Guide for Three Methods of Assessing Buried Steel Tanks
Trường học ASTM International
Chuyên ngành Corrosion of Metals
Thể loại Standard guide
Năm xuất bản 2016
Thành phố West Conshohocken
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Số trang 10
Dung lượng 188,59 KB

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Designation G158 − 98 (Reapproved 2016) Standard Guide for Three Methods of Assessing Buried Steel Tanks1 This standard is issued under the fixed designation G158; the number immediately following the[.]

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Designation: G15898 (Reapproved 2016)

Standard Guide for

This standard is issued under the fixed designation G158; the number immediately following the designation indicates the year of

original adoption or, in the case of revision, the year of last revision A number in parentheses indicates the year of last reapproval A

superscript epsilon (´) indicates an editorial change since the last revision or reapproval.

INTRODUCTION

The purpose of this guide is to provide three methods of inspecting and assessing buried steel tank(s) for corrosion damage and determining the suitability of these tanks prior to application of

cathodic protection

1 Scope

1.1 This guide covers procedures to be implemented prior to

the application of cathodic protection for evaluating the

suit-ability of a tank for upgrading by cathodic protection alone

1.2 Three procedures are described and identified as

Meth-ods A, B, and C

1.2.1 Method A—Noninvasive with primary emphasis on

statistical and electrochemical analysis of external site

envi-ronment corrosion data

1.2.2 Method B—Invasive ultrasonic thickness testing with

external corrosion evaluation

1.2.3 Method C—Invasive permanently recorded visual

in-spection and evaluation including external corrosion

assess-ment

1.3 This guide presents the methodology and the procedures

utilizing site and tank specific data for determining a tank’s

condition and the suitability for such tanks to be upgraded with

cathodic protection

1.4 The tank’s condition shall be assessed using Method A,

B, or C Prior to assessing the tank, a preliminary site survey

shall be performed pursuant to Section8and the tank shall be

tightness tested pursuant to5.2to establish that the tank is not

leaking

1.5 While this guide provides minimum procedures for

assessing a tank’s condition, this guide does not provide

minimum installation procedures or requirements for upgrades

of the tank by cathodic protection

1.6 The values stated in inch-pound units are to be regarded

as standard The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard

1.7 This standard does not purport to address all of the safety concerns, if any, associated with its use It is the responsibility of the user of this standard to establish appro-priate safety and health practices and determine the applica-bility of regulatory limitations prior to use.

2 Referenced Documents

2.1 The most recent version of the following documents should be consulted as references by those using this guide:

2.2 ASTM Standards:2

D2216Test Methods for Laboratory Determination of Water (Moisture) Content of Soil and Rock by Mass

E114Practice for Ultrasonic Pulse-Echo Straight-Beam Contact Testing

E797Practice for Measuring Thickness by Manual Ultra-sonic Pulse-Echo Contact Method

E1323Guide for Evaluating Laboratory Measurement Prac-tices and the Statistical Analysis of the Resulting Data

E1526Practice for Evaluating the Performance of Release Detection Systems for Underground Storage Tank Sys-tems(Withdrawn 2002)3

G51Test Method for Measuring pH of Soil for Use in Corrosion Testing

G57Test Method for Field Measurement of Soil Resistivity Using the Wenner Four-Electrode Method

1 This guide is under the jurisdiction of ASTM Committee G01 on Corrosion of

Metals and is the direct responsibility of Subcommittee G01.10 on Corrosion in

Soils.

Current edition approved May 1, 2016 Published May 2016 Originally

approved in 1998 Last previous edition approved in 2010 as G158 – 98 (2010).

DOI: 10.1520/G0158-98R16.

2 For referenced ASTM standards, visit the ASTM website, www.astm.org, or

contact ASTM Customer Service at service@astm.org For Annual Book of ASTM

Standards volume information, refer to the standard’s Document Summary page on

the ASTM website.

3 The last approved version of this historical standard is referenced on www.astm.org.

Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959 United States

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2.3 ASNT Standard:4

ASNT SNT-TC-1APersonnel Qualification and

Certifica-tion in Nondestructive Testing

2.4 NACE International Standards:5

RP-0169Standard Recommended Practice-Control on

Ex-ternal Corrosion on Underground or Submerged Metallic

Piping Systems

RP-0187Standard Recommended Practice-Design

Consid-erations for Corrosion Control of Reinforcing Steel in

Concrete

RP-0285 Standard Recommended Practice-Corrosion

Con-trol of Underground Storage Tank Systems by Cathodic

Protection

2.5 Environmental Protection Agency Methods:6

EPA SW 846Test Methods for Evaluating Solid Waste

EPA 371.1Measurement of Sulfate Reducing Bacteria

2.6 National Fire Protection Association (NFPA)7

NFPA 329Recommended Practice for Handling

Under-ground Releases of Flammable and Combustible Liquids

2.7 Underwriters Laboratories Inc.8

UL 58Steel Underground Tanks for Flammable and

Com-bustible Liquids

3 Terminology

3.1 Definitions of Terms Specific to This Standard:

3.1.1 buried—to be placed in the ground and covered with

earth

3.1.2 cathodic protection—an applied technique to prevent

further corrosion of a metal surface by making that surface the

cathode of an electrochemical cell For example, a tank system

can be cathodically protected through the application of either

galvanic anodes or impressed current

3.1.3 corrosion specialist/cathodic protection specialist—a

competent person who by reason of knowledge of the physical

sciences and the principles of engineering and mathematics,

acquired by education and related practical experience, is

qualified to engage in the practice of corrosion control on

buried or submerged metallic piping systems and metallic

tanks Such persons shall be registered professional engineers

or persons recognized as corrosion specialists or cathodic

protection specialists by NACE, if their professional activities

include suitable experiences in external corrosion control on

buried or submerged metallic piping and tanks

3.1.4 corrosion technician—a person possessing basic

knowledge of corrosion and corrosion control, who is capable

of performing routine, well defined work under the supervision

of the corrosion specialist/cathodic protection specialist

3.1.5 invasive procedure—a method of determining the

corrosion status of a tank by assessing the tank from the inside

as part of the upgrade procedure Further, for the purposes of this guide, it does not require manned entry into the tank (See

non-invasive.) 3.1.6 limitations—The user of this guide is encouraged to

review any available third party verification information pro-vided as part of the vendor selection process

3.1.7 noninvasive procedure—a method of determining the

corrosion status of a tank from the characteristics of its surroundings with minimal entry into the tank Further, for the purposes of this guide, it does not require manned entry into

the tank (See invasive.) 3.1.8 pH—the numerical value of the negative logarithm of

the hydrogen ion concentration in moles per litre in an electrolyte

3.1.9 redox potential—potential of platinized platinum

elec-trode in a redox environment (reversible system) The value of redox potential depends on whether the system is in the oxidized, partially oxidized, partially reduced, or reduced state

3.1.10 tank tightness test—a method capable of detecting a

0.1 gal/h leak rate, while accounting for any applicable effects

of thermal expansion or contraction of the product, of vapor pockets, of tank deformation, of evaporation or condensation, and of the location of the water table The method must be capable of detecting a 0.1 gal/h leak rate with a probability of detection of at least 0.95 and a probability of false alarm of at most 0.05 or in accordance with NFPA 329

3.1.11 unconditional probability of corrosion failure—the

probability of corrosion failure which includes a determination

of whether localized, pitting, or general corrosion is occurring

3.1.12 underground storage tank (UST)—any one or

com-bination of tanks (including connected underground piping), the volume of which is 10 % or more beneath the surface of the ground

3.1.13 upgrade—the addition to or retrofit of UST systems

using approaches including, but not limited to, cathodic pro-tection to improve the ability of a UST system to prevent a release

3.1.14 UST—see underground storage tank (see3.1.12)

3.1.15 vendor provided information—The user is referred to

Annex A1for a specific form and format of information which must be provided by a vendor This information consists of historic performance data on a method and is mandated as part

of the guide

4 Significance and Use

4.1 This guide provides three methods for determining the suitability of a buried steel tank to be upgraded with cathodic protection

4.2 This guide may be used to assess any UST, including non-regulated USTs

4.3 This guide provides three alternative methods but does not recommend any specific method or application The responsibility for selection of a method rests with the user

4 Available from The American Society for Nondestructive Testing (ASNT), P.O.

Box 28518, 1711 Arlingate Ln., Columbus, OH 43228-0518.

5 Available from National Association of Corrosion Engineers (NACE), 1440

South Creek Dr., Houston, TX 77084-4906.

6 Available from US Environmental Protection Agency, Office of Underground

Storage Tanks, 401 “M” St SW, Washington, DC 20460.

7 Available from Underwriters Laboratories (UL), Corporate Progress, 333

Pfingsten Rd., Northbrook, IL 60062.

8 Available from National Fire Protection Association (NFPA), 1 Batterymarch

Park, Quincy, MA 02269-9101.

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4.4 This guide has specific requirements for vendor

pro-vided information which should be requested and reviewed by

the user

5 Permits, Plans and Tank Leak Testing

5.1 Prior to engaging in any activities relating to the

alteration, repair, or upgrade of any UST system, consult all

necessary authorities to obtain any required permits

5.2 Tank Leak Testing:

5.2.1 To establish that tanks are not leaking prior to

assessment, they shall be assessed by a leak detection system

This leak detection assessment alone is not sufficient to

determine that a tank is suitable for upgrading with cathodic

protection under this guide

5.2.2 A tightness test or another release detection system in

accordance with NFPA 329 shall be used Any release detection

must be capable of detecting a leak from any portion of the

tank that routinely contains product, and be independently

evaluated and certified in accordance with PracticeE1526 or

the equivalent Leak detection results shall be provided to the

corrosion specialist/cathodic protection specialist

5.2.3 This testing shall be accomplished within six months

prior to performing any of the assessment procedures

6 Required Approvals and Certifications

6.1 The corrosion assessment work carried out under this

guide shall be performed under the responsible direction of a

corrosion specialist/cathodic protection specialist as defined in

3.1.3

6.2 The corrosion specialist/cathodic protection specialist

shall certify to the tank owner or operator that the personnel

performing the assessment work on the tank are knowledgeable

of all the applicable procedures in this guide

6.3 The corrosion specialist/cathodic protection specialist

shall certify to the tank owner or operator that all work was

performed in strict accordance with this guide

7 General Safety Requirements

7.1 All personnel shall comply with applicable federal,

state, and local health and safety codes and regulations

8 Preliminary Site Survey

8.1 A corrosion technician, under the responsible direction

of the corrosion specialist/cathodic protection specialist, shall

obtain tank site specific information as appropriate to the

method of assessment to be used

8.1.1 Facility Information:

8.1.1.1 Address or location, and

8.1.1.2 Name and telephone number of owner and operator

contact personnel

8.1.2 Tank and Piping Details:

8.1.2.1 Number and capacity,

8.1.2.2 Location and dimensions,

8.1.2.3 Age,

8.1.2.4 Material of construction,

8.1.2.5 Electrical isolation,

8.1.2.6 Type of product stored,

8.1.2.7 Names of site contact personnel, 8.1.2.8 Backfill material,

8.1.2.9 Coatings and linings, 8.1.2.10 Leak history, 8.1.2.11 Repair history, 8.1.2.12 Site plans, 8.1.2.13 Installation specifications, 8.1.2.14 Tank excavation liners, and 8.1.2.15 As-built drawings

8.1.3 Information Not in the Immediate Vicinity of the Tanks—The presence of the following items, that are external

to the tank area, shall be investigated and included as appro-priate to the method of assessment of the suitability of tanks for upgrading with cathodic protection:

8.1.3.1 Stray dc current sources, 8.1.3.2 Existing cathodic protection systems, 8.1.3.3 Steel product and vent piping and fittings, and 8.1.3.4 Adjacent subsurface metallic/steel-reinforced con-crete structures

8.2 Preliminary Evaluation—Prior to assessing the tank, a

preliminary site survey must be performed pursuant to Section

8 and a tightness test must be performed pursuant to 5.2 to establish that the tank is not leaking

9 Method A—Noninvasive with Primary Emphasis on Statistical and Electrochemical Analysis of External Site Environment Corrosion Data ( 1 , 2 )

9.1 Field and Laboratory Testing—Noninvasive with Pri-mary Emphasis on Statistical and Electrochemical Analysis of External Site Environment Corrosion Data.

9.1.1 Tests shall be conducted by, or as directed by a corrosion specialist/cathodic protection specialist

9.1.2 Field Testing Procedures—Tests to be performed shall

include, but are not limited to, the following:

9.1.2.1 Stray Currents—Perform tests to detect the presence

of stray currents at each tank site This test shall consist of measuring structure-to-soil potentials at right angles at a minimum of two locations within the tank facilities and observing the measurements for not less than 2 h at a time when such influences are most likely to occur The monitor shall consist of a field data acquisition unit, with a minimum of 10-MΩ input impedance, used in conjunction with a stable reference cell(s) placed in contact with the soil in the vicinity

of the tank The instrument shall measure and store structure-to-electrolyte potential (voltage) data at least every 5 s through-out the entire duration of field investigation at the site or for 2

h, whichever is greater If variations of 650 mV or greater are measured during the test period, make 24-h recording measure-ments to confirm stray current effects

9.1.2.2 Tank Information:

(a) Locate all tanks and confirm materials of construction,

age, capacity, and dimensions Produce detailed site sketches describing the layout of the UST system and above grade pertinent details for each site

(b) Determine the presence and extent of internal corrosion

immediately below the fill riser If the depth of corrosion

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penetration in the tank shell exceeds 50 % of the tank wall

thickness, the UST shall be declared to have failed the test and

the procedure

(c) Determine if the tanks and piping are electrically

continuous

9.1.2.3 Bore Hole Tests:

(a) Determine locations for soil borings in the field Make

two test holes for each tank excavation zone with four or fewer

tanks For tank excavation zones with more than four tanks,

make one additional bore hole for each two additional tanks, or

part thereof Make the tank bore holes at opposite diagonal

ends of the tank excavation zone The tank excavation zone

shall be considered to extend no farther than 4 ft from the

nearest tank Complete the holes to the bottom of the deepest

tank

(b) In each tank bore hole, record measurements as the

boring progresses At 2-ft (0.6-m) intervals, make the

follow-ing tests:

(1) Measure the soil resistivity using the Wenner four pin

method in accordance with Test Methods G57

(2) Make structure-to-soil potential measurements in each

bore hole using a minimum 10-MΩ input impedance digital

voltmeter and a calibrated copper-copper sulfate reference

electrode sensing tip in direct contact with the soil in the bore

hole

(c) Measure the depth of observed, perched, or static water

table in each bore hole, if encountered

(d) In accordance with industry practices, gather one soil

sample each at the top, mid depth, and bottom of each hole

using either a split spoon or core sampling tube and place, seal,

and preserve the soil samples in containers for laboratory

analysis

(e) Backfill each hole and seal with a concrete or asphalt

plug

9.1.2.4 Other Field Considerations—The corrosion

specialist/cathodic protection specialist may also consider, but

not be limited to, performing and evaluating the following

tests:

(a) Current requirement,

(b) Coating resistance, and

(c) Coating efficiency.

9.1.3 Laboratory Testing Procedures—Send soil samples

collected at each site to a qualified soil laboratory where they

shall be tested in accordance with EPA SW 846 GuideE1323,

or other recognized industry test methods The report shall

include the results of all test methods used in the evaluation At

a minimum, obtain the following data:

9.1.3.1 Soil resistivity/conductivity,

9.1.3.2 Moisture content,

9.1.3.3 Soil pH,

9.1.3.4 Soluble chloride ion concentration, and

9.1.3.5 Sulfide ion concentration

9.1.4 The corrosion specialist/cathodic protection specialist

shall also consider, but not be limited to, performing and

evaluating the following tests The report shall include all test

methods used in the evaluation:

9.1.4.1 Redox potential, and

9.1.4.2 Sulfate ion concentration

9.1.4.3 Any other tests required by the external corrosion rate analysis model

9.1.5 Quality Control—One soil sample of every ten

samples analyzed shall be subjected to an independent quality control analysis of all data gathered in9.1.3 If the results of the quality control analysis fail to agree with the original analysis (within limits of experimental accuracy), reanalyze all samples collected since the last successful quality control analysis

9.2 Analysis and Determination of Suitability of a Tank for Upgrading with Cathodic Protection-Noninvasive with Pri-mary Emphasis on Statistical Analysis of External Site Envi-ronment Corrosion Data.

9.2.1 Basis for Analysis—By examining the environment in

the specific vicinity of the tank, a relationship between the aggressiveness of the environment and the rate of corrosion can

be statistically established Base the statistical analysis model used on a sufficient size data base with various factors that are accounted for statistically to reach a confidence level of 0.99 This will achieve consistency and reliability of the results One general form of the multivariate, non-linear regression analysis, which contains the minimum essential variables, is as follows:

E~Age!5 f~R, M, Cl, pH, S, SC, TS, P! (1)

where:

E (Age) = unconditional predicted age to corrosion failure,

Cl = chloride ion concentration,

S = sulfide ion concentration,

SC = stray current magnitude,

TS = tank size, and

P = tank structure to soil potential

9.2.2 Criteria of Acceptance for Upgrading With Cathodic Protection (using RP-0169, RP-0187, and RP-0285)—To be

acceptable as a means of determining the condition of tanks and their suitability for upgrading with cathodic protection, the procedure used shall, at a minimum, meet the following criteria:

9.2.2.1 The procedure shall be based on an evaluation of all

data gathered in situ in each bore hole together with all soil

sample data and the stray dc earth current monitor measure-ments taken at each site

9.2.2.2 The mathematical formulation of the procedure shall conform to accepted physical and electrochemical characteris-tics of the tank corrosion process Independent professional validation of these processes shall be done by an individual or individuals with experience in the relevant scientific or engi-neering disciplines

9.2.2.3 Parameter estimates shall be based on data derived from at least 100 sites where a minimum of 200 tanks were excavated, fully exposed, and evaluated by a qualified corro-sion specialist/cathodic protection specialist Maximum likeli-hood estimation or another procedure that meets the standards

of statistical or electrochemical admissibility shall be required

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Data used in estimation shall contain representative samples of

leaking and non-leaking tanks

9.2.2.4 Models proposed shall be specific as to soil type and

incorporate depth of ground water and rainfall experienced in

the immediate geographical area where testing takes place

9.2.2.5 The standard deviation of the predicted time to

corrosion failure shall not exceed 1.5 years The model shall

generate an unconditional probability of corrosion failure

based upon a comparison of actual tank age to its expected

leak-free life

9.2.3 Report Including Results, Analysis, and

Recommendations—The corrosion specialist/cathodic

protec-tion specialist shall prepare a report including results, analysis,

and recommendations as follows:

9.2.3.1 Base the report conclusions on the expected

leak-free life of a tank at a specific site as determined by the analysis

of the data necessary to determine which tanks are suitable for

upgrading with cathodic protection

9.2.3.2 The report shall provide the expected leak-free life

and present and future probabilities of corrosion failure for all

tanks investigated

9.2.3.3 The report shall include a listing of tanks whose age

is less than the expected leak-free life and for those tanks

where the probability of corrosion perforation is less than 0.05

9.3 Cathodic protection can be applied to those tanks that

have been tested in accordance with Sections8and9and meet

the following criteria:

9.3.1 The tank is confirmed to be leak free in accordance

with5.2

9.3.2 The tank age is less than the expected leak-free life

9.3.3 The probability of corrosion perforation of the tank is

less than 0.05

9.3.4 Either a tank tightness test is conducted between three

and six months after the tank is cathodically protected, or

monthly monitoring with another leak detection system is

implemented within one month after the addition of cathodic

protection Any leak detection system must meet5.2.2

9.4 A form is included inAnnex A1which must be utilized

to report the results of the authenticated vendor provided

information A research report containing examples of actual

authenticated vendor provided information is filed and

avail-able from ASTM.9

10 Method B—Invasive Ultrasonic Thickness Testing

with External Corrosion Evaluation

10.1 Field and Laboratory Testing—Invasive Ultrasonic

Thickness Testing with External Corrosion Evaluation:

10.1.1 Conduct the following procedures when assessing

the suitability of a steel tank for upgrading with cathodic

protection using an invasive method

10.1.2 Conduct tests by, or as directed by, the corrosion

specialist/cathodic protection specialist

10.1.3 Before a tank is suitable for upgrading with cathodic

protection using an invasive approach, the following

site-specific tests shall be conducted for each tank excavation zone

in accordance with industry recognized standard practices: 10.1.3.1 Perform the tests described in9.1.2.1

10.1.3.2 Soil resistivity in accordance with Test Methods

G57 These values shall be measured in the immediate vicinity

of the tank excavation zone and shall, as a minimum, be measured at depths of 5, 71⁄2, 10, 121⁄2, and 15 ft (1.5, 2.3, 3.5, and 5 m)

10.1.3.3 Structure to soil potential in accordance with NACE RP-0285 with at least five such measurements spaced uniformly about each tank excavation zone

10.1.3.4 Soil pH in accordance with Test MethodsG51, soil chlorides and sulfides in accordance with EPA SW 846 uniformly gathered from three locations about each tank excavation zone

10.1.3.5 Electrical continuity/isolation in accordance with NACE RP-0285 of each UST being evaluated

10.1.4 The corrosion specialist/cathodic protection special-ist should also consider, but not be limited to, performing and evaluating the following tests:

10.1.4.1 Redox potential, 10.1.4.2 Current requirement, 10.1.4.3 Coating resistance, 10.1.4.4 Coating efficiency, 10.1.4.5 Wall thickness

10.1.4.6 Soluble chloride ion concentration, 10.1.4.7 Sulfide ion concentration,

10.1.4.8 Sulfate ion concentration, and 10.1.4.9 Any other tests deemed necessary

10.2 Invasive Ultrasonic Thickness Testing with External Corrosion Evaluation:

10.2.1 This subsection provides the general procedure for assessing tanks prior to upgrading with cathodic protection through the use of invasive ultrasonic thickness testing in combination with the leak detection testing in accordance with

5.2and external corrosion evaluation procedures contained in

10.1 This procedure may be conducted using either manually manipulated or computer controlled remote controlled (ro-botic) ultrasonic sensor placement, control and measurement devices which do not require manned entry into the UST

10.2.2 Certification—Corrosion technicians performing

in-vasive ultrasonic thickness testing shall also be certified in accordance with ASNT recommended practice SNT-TC-1A and qualified under similar written practice with the equipment and procedures to be employed

10.2.3 Surface Preparation—In accordance with Practice

E114, the interior surface of the tank to be examined shall be uniform and free of loose scale, loose paint, dirt, or other deposits that affect examination If any such loose scale, loose paint, dirt, or other deposits exist which would prevent accurate ultrasonic thickness measurement of the remaining steel wall, they shall be removed prior to performing these measurements Tightly adhering paint, scale, or bonded coatings do not need to

be removed if they present uniform attenuation characteristics

10.2.4 Calibration—Calibrate the thickness measurement

sensor in accordance with PracticeE797

10.2.5 Couplant—Any couplant used shall be the stored

product or a material compatible with the stored product and

9 Supporting data have been filed at ASTM International Headquarters and may

be obtained by requesting Research Report RR:G01-1019.

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shall be appropriate for the surface finish of the material to be

examined The surface finish and couplant of the reference

standards shall be acoustically similar to those of the tank and

the couplant therein

10.2.6 Ultrasonic Gauging:

10.2.6.1 The invasive ultrasonic inspection shall make

lo-cated wall thickness measurements of at least 15 % of the

entire tank interior surface area excluding man way entries

The thickness measurements shall be uniformly distributed

over the surface of the tank The invasive ultrasonic inspection

equipment shall be capable of accessing at least 95 % of the

tank interior surface area excluding man way entries and other

tank penetration fittings In areas where corrosion damage is

more severe, as determined by the corrosion technician,

additional measurements shall be made as directed by the

corrosion specialist/cathodic protection specialist so as to

provide a sufficient amount of inspection data to accurately

define the extent of corrosion and to ensure an accurate

leak-free life prediction

10.2.6.2 Depending on surface conditions, the minimum

ultrasonic thickness measurement capability may vary from

0.050 to 0.125 in (1.2 to 3.2 mm) The instrumentation should

be able to measure remaining wall thickness of the tank to an

accuracy of 60.010 in (0.25 mm) and to detect a flat bottom

pit of 0.125-in (3.2-mm) diameter

10.2.6.3 The maximum allowable position error in each

wall thickness measurement position location coordinate is

5 % of the maximum tank dimension

10.2.7 Ultrasonic Test Reports—Record the following data

as a minimum for future reference at the time of each

investigation:

10.2.7.1 Operator’s name and certification level,

10.2.7.2 Instrument description including make, model, and

serial number and setup couplant,

10.2.7.3 Instrument calibration certification including date

performed,

10.2.7.4 Cable type and length,

10.2.7.5 Mode of scanning (manual or automatic),

10.2.7.6 Search unit description, such as, type, size,

frequency, special shoes,

10.2.7.7 Reference standards (and calibration data required

to duplicate the examination), and

10.2.7.8 Location data (coordinates) for thickness

measure-ment data points

10.2.8 Invasive ultrasonic wall thickness measurement may

pose certain safety hazards It is the responsibility of the user

of this guide to establish appropriate safety and health practices

and determine the applicability of regulatory limitations prior

to use

10.3 Data Analysis and Determination of Suitability of a

Tank for Upgrading With Cathodic Protection (RP-0169 and

RP-0187) Using Invasive Ultrasonic Thickness Testing and

Evaluation Including External Site Environment Corrosion

Assessment:

10.3.1 This alternative method includes a mathematical

corrosion prediction model and an analytical report The

analytical report contains the tank, soil chemistry (using Guide

E1323), and inspection data The model is then used to

estimate the leak-free life of the tank using the tank information, ultrasonic thickness measurement test data, and soil chemistry data

10.3.2 Prediction Model:

10.3.2.1 Use a prediction model to determine the probability

of an individual tank leak as a result of corrosion It shall yield the years of leak-free life remaining and the probability of a potential leak of the tank in a specific soil condition The model shall be based on tank inspection data collected and shall include all of the site specific parameters listed in 10.1.3.1 – 10.1.3.5and any test(s) performed in10.1.4 The mathematical formulation used in the prediction model shall be based on accepted physical and electrochemical characteristics of the tank corrosion process

10.3.2.2 Consider the tank suitable for upgrading with cathodic protection if there is:

(a) No measured pitting which perforates the tank wall, (b) Ninety-eight percent of all ultrasonic thickness

mea-surements made on the tank shall be greater than or equal to

50 % of the minimum recommended wall thickness as pro-vided in Underwriters Laboratories Standard UL 58 or the documented original tank wall thickness,

(c) The average metal wall thickness of each 1 m2is greater than 85 % of the original wall thickness, and

(d) The results of the prediction model (for example CERL

N 91/18), as determined by the corrosion specialist/cathodic protection specialist, support that cathodic protection is both reasonable and viable

10.3.3 Inspection Report—This report shall summarize all

tank data collected from the inspection and provide results from the prediction model for each tank including recommen-dations with respect to each tank’s suitability for upgrading using cathodic protection The corrosion specialist/cathodic protection specialist shall be responsible for all data analysis and recommendations

10.4 Cathodic protection can be applied to those tanks which have been evaluated using one of the procedures provided for in Sections 8 and 10 and meet the following criteria

10.4.1 Passes all requirements defined in10.3.2.2 10.4.2 Either a tank tightness test is conducted between three and six months after the tank is cathodically protected, or monthly monitoring with another leak detection system is implemented within one month after the addition of cathodic protection Any leak detection system must meet5.2.2 10.5 A form is included in the Annex A1 which must be utilized to report the results of the authenticated vendor provided information A research report containing examples

of actual authenticated vendor provided information is filed and available from ASTM.9

11 Method C—Invasive Permanently Recorded Visual Inspection and Evaluation Including External Corrosion Assessment

11.1 External Corrosion Assessment Data Gathering:

11.1.1 Conduct the following procedures when assessing the suitability of a steel tank for upgrading with cathodic protection using an invasive method

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11.1.2 Conduct tests by, or as directed by a corrosion

specialist/cathodic protection specialist

11.1.3 Before a tank is suitable for upgrading with cathodic

protection using an invasive approach, the following

site-specific tests shall be conducted for each tank excavation zone

in accordance with industry recognized standard practices:

11.1.3.1 Perform tests as described in9.1.2.1

11.1.3.2 Soil resistivity in accordance with Test Methods

G57 These values shall be measured in the immediate vicinity

of the tank excavation zone and shall, as a minimum, be

measured at depths of 5, 71⁄2, 11, 121⁄2, and 15 ft (1.5, 2.3, 3.5,

and 5 m)

11.1.3.3 Structure to soil potential in accordance with

NACE RP-0285 with at least five such measurements spaced

uniformly about each tank excavation zone

11.1.3.4 Soil pH in accordance with Test MethodG51, soil

chlorides and sulfides in accordance with EPA SW 846 and

Guide E1323 uniformly gathered from three locations about

each tank excavation zone

11.1.3.5 Electrical continuity/isolation in accordance with

NACE RP-0285 of each UST being evaluated

11.1.4 The corrosion specialist/cathodic protection

special-ist should also consider, as a minimum but not be limited to,

performing and evaluating the following tests:

11.1.4.1 Redox potential,

11.1.4.2 Current requirement,

11.1.4.3 Coating resistance,

11.1.4.4 Coating efficiency,

11.1.4.5 Wall thickness,

11.1.4.6 Soluble chloride ion concentration,

11.1.4.7 Sulfide ion concentration,

11.1.4.8 Sulfate ion concentration, and

11.1.4.9 Any other tests deemed necessary

11.2 Field Testing Using Invasive Permanently Recorded

Visual Inspection:

11.2.1 This subsection provides the general procedure for

internally visually inspecting, recording and archieving the

results of the visual inspection of USTs without manned

physical entry into the tanks This information is used in

combination with the data obtained from the external testing

procedures defined in11.1.3to assess the tank’s suitability for

upgrading with cathodic protection

11.2.2 The visual inspection is part of a total assessment

procedure that includes leak detection testing in accordance

with 5.2 and external corrosion evaluation as delineated in

11.1 The recorded documentation (for example, photographic

film, digital or analog tape) is archived and is a permanent

record of the visual inspection

11.2.3 Technical Certification—The person performing this

inspection shall be a corrosion technician The corrosion

specialist/cathodic protection specialist shall conduct an

analy-sis of any suspect corrosion activity that may fail a tank

11.2.4 UST Qualification—The field and laboratory testing

(in accordance with 11.1) is completed either prior to or in

conjunction with performing the internal visual tank

inspec-tion In the event these tests reveal any indication of structural

or electrochemical characteristics that are incompatible with

the effective use of cathodic protection, the tank shall be

considered to have failed the test and the internal visual inspection shall be aborted

11.2.5 UST Preparation—Prior to conducting the internal

visual inspection, the tank must be emptied, cleaned, if necessary, and purged

11.2.6 Emptying Tanks—Tanks to be inspected must be

taken out of operation and all liquid product removed that would otherwise preclude accurate visual inspection of the tank Employ applicable safety precautions and procedures

11.2.7 Purging Tanks—Prior to placing any visual

inspection, recording or lighting apparatus within the fill pipe

or tank, the atmosphere within the tank must be purged to avoid any combustible hydrocarbon/air vapor mixture Purging may

be accomplished by pressure feeding a blanket of carbon dioxide or another inert gas into the tank until sufficient air is displaced to render the interior tank atmosphere safe As an alternative to purging by an inert gas, the tank may be freed of flammable vapor mixtures by air purging

11.2.7.1 All instruments used within the tank, including those used for characterization of the atmosphere, must be certified as intrinsically safe for the appropriate class(es), division(s), and group(s) by a competent authority

11.2.8 Cleaning Tanks—Determined by the corrosion

specialist/cathodic protection specialist upon reviewing the visual record, the tank shall be sufficiently free (clean) of sludge, thick oxides, or other dense residual materials as to allow the internal surface of the tank to be evaluated At least

98 % of the interior surface area of the tank must be visible for inspection

11.2.8.1 If the corrosion specialist/cathodic protection spe-cialist determines the interior surfaces were not adequately clean, the corrosion specialist/cathodic protection specialist shall reject the tank for upgrade with cathodic protection until such time the condition has been corrected and the tank re-evaluated

11.2.9 Lighting Equipment—The in-tank visual recording

system shall be equipped with lighting capable of adequately illuminating the interior steel surfaces so that the defect sizes defined in11.2.10.1can be visually observed and permanently recorded

11.2.10 Visual inspection Resolution:

11.2.10.1 The visual inspection method must identify and permanently record the presence of all detectable pits or corrosion by-products tubercles while observing and perma-nently recording the condition of at least 98 % of the tanks’ interior surfaces

11.2.11 Visual Recording—The minimum resolution of the

visual recording system shall be capable of identifying the location and degree of corrosion activity as listed in11.2.10.1 The system shall also permanently embed the time, structure site, UST location, and date of the visual examination in the visual record It shall also provide for permanently recording the observation comments of the visual inspector

11.2.12 Inspection and Recording—After the tank has been

tested and found to be safe in accordance with11.2.7, and the permanent recording apparatus is in place, the inspection shall

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be made by a qualified technician working under the

supervi-sion of the responsible corrosupervi-sion specialist/cathodic protection

specialist in accordance with the following minimum

require-ments:

11.2.12.1 Scan all interior tank surfaces to assess the general

inspection conditions and to ensure the tank is sufficiently

clean to permit effective visual inspection

11.2.12.2 At the start of the recording process, record the

date, time, and all necessary tank identification data including

company name and address, project identification number, tank

size, age and identification number, and corrosion technician’s

name

11.2.12.3 Systematically perform and record the visual

corrosion condition on at least 98 % of the internal tank

surfaces

11.2.12.4 Permanently record in the visual record all

perti-nent or unique observations, corrosion activity or damage, and

location relative to the internal tank surface observed by the

corrosion technician

11.2.12.5 Permanently record a summation commentary of

the corrosion technician

11.2.13 Corrosion Activity—The corrosion technician shall

identify any evidence of corrosion including:

11.2.13.1 Perforations—Water intrusion or other visual

evi-dence

11.2.13.2 Rust Tuberculation—Active dark red/maroon

crust

11.2.13.3 Streaks—Elongated in shape, dark red/black in

color at apex

11.2.13.4 Discoloration—Patches showing dark reddish/

black center, becoming lighter toward the edges, usually

irregularly spaced, 3 to 9 in (7.5 to 23 cm) in diameter

11.2.13.5 Pitting—Black in center-bottom of crater, light

red or bright metal near perimeter

11.2.13.6 Scaling or Delaminations—Typical exfoliation,

no discoloration, layered flakes in small 2 to 4-in (5 to 11-cm)

diameter irregular patches

11.2.13.7 Weld Deterioration—Little discoloration, except

possible black/maroon deposit beneath interface; deterioration

of metal within the weld sometimes with cracks and undercuts

11.2.13.8 Cracks—Usually no discoloration, typically near

welds, openings, fittings, connections, and other stress

concen-tration sites

11.2.14 Passive Corrosion Films:

11.2.14.1 General Overall Rust Film—Light red, pink, or

pink/beige; smooth to slightly pockmarked This is not active

corrosion, but an alpha oxide film that is protective or

passivating

11.3 Data Analysis and Report on Determination of

Suit-ability of a Tank for Upgrading with Cathodic Protection

Using Invasive Visual Inspection with External Corrosion

Evaluation:

11.3.1 The examining corrosion technician may record

comments to aid the corrosion specialist/cathodic protection

specialist in evaluation of the tank’s internal surfaces If no

corrosion or deterioration is evident, the report shall so

indicate

11.3.2 The corrosion specialist/cathodic protection special-ist shall be responsible to view the visual permanent record and make a final determination on the suitability of each tank tested for upgrading

11.3.3 After review of the visual permanent record includ-ing all notations and comments, a report shall be prepared and submitted to the UST owner/operator by the corrosion specialist/cathodic protection specialist including the upgrad-ing suitability determination made for each tank This visual record and report shall be kept on file by the UST owner/ operator as part of the required documentation

11.3.4 Any evidence of a perforation or significant corrosion, as defined in accordance with11.2.13, is confirmed

by the corrosion specialist/cathodic protection specialist, or if the corrosion specialist/cathodic protection specialist’s analy-sis of the site corrosion data as defined in11.1and as evaluated

in11.3.5indicates the tank is not a candidate for upgrading by cathodic protection alone Significant evidence of corrosion exists when the corrosion has advanced enough to compromise the integrity and useful life of the tank

11.3.5 Corrosion Data Evaluation Alternatives for Invasive Visual Inspection Procedure:

11.3.5.1 Prediction Model—Use a prediction model to

de-termine the probability of an individual tank leak as a result of corrosion It shall yield the years of leak-free life remaining and the probability of a potential leak of the tank in a specific soil condition The model shall be based on tank inspection data collected and shall include all of the site specific param-eters listed in 11.1.3 – 11.1.3.5 and any test(s) performed in

11.1.4 The mathematical formulation used in the prediction model shall be based on accepted physical and electrochemical characteristics of the tank corrosion process Consider the tank suitable for upgrading with cathodic protection if the results of

the prediction model (for example, CERL N 91/18) ( 3 ), as

determined by the corrosion specialist/cathodic protection specialist, support that cathodic protection is both reasonable and viable or as detailed in 11.3.5.2

11.3.5.2 Site Specific Value Criteria—Corrosion data for

which tanks shall not be considered suitable for upgrade when

a statistical prediction model as defined in11.3.5.1is not used:

(a) Soil resistivity at the average tank depth less than 700

Ω-cm,

(b) Soil pH less than 4.0, (c) Soluble chloride ion concentration greater than 500

ppm,

(d) A positive sulfide test indicating the presence of

sulfate-reducing bacteria in accordance with EPA SW 846

(e) Average tank-to-soil potential on the UST are more

positive than –300 mV with respect to a saturated copper-copper sulfate electrode

11.4 Requirements for applying cathodic protection to tanks which have been tested in accordance with Sections8 and11

and meet the following criteria:

11.4.1 Those tanks that have been tested, found to be leak free, and found acceptable for upgrading in accordance with Sections 8 and 11 and meet the criteria defined in 11.3.4

together with either11.3.5.1or 11.3.5.2, and

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11.4.2 Either a tank tightness test is conducted between

three and six months after the tank is cathodically protected, or

monthly monitoring with another leak detection system is

implemented within one month after the addition of cathodic

protection Any leak detection system must meet5.2.2

11.5 A form is included inAnnex A1which must be utilized

to report the results of the authenticated vendor provided

information A research report containing examples of actual

authenticated vendor provided information is filed and

avail-able from ASTM.9

12 Keywords

12.1 assessment; cathodic protection; corrosion; criteria; EPA; evaluation; inspection; model; prediction; regulation; rust; statistical; steel; suitability; tank; ultrasonic; underground storage tank; upgrade; UST; video; visual

ANNEX (Mandatory Information) A1 THIRD PARTY VERIFICATION

A1.1 SeeFig A1.1

FIG A1.1 Third Party Verification Form

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REFERENCES (1) Bushman, J., B and Mehalick, T., E “Statistical Analysis of Soil

Characteristics to Predict Mean Time to Corrosion Failure of

Under-ground Metallic Structures,” ASTM STP 1013, ASTM, 1989.

(2) Rogers, W., F “Statistical Prediction of Corrosion Failures,” NACE

International, CORROSION 89, Paper No 596.

(3) Piskin et al, “Leakage Potential of Underground Storage Tanks,” USACERL Technical Report N-91/18, US Army Construction Engi-neering Laboratories, Champaign, IL 61826-9005, June 1991.

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