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In contrast, specific halotolerance of yeast against extracellular NaCl or LiCl is based on the induction of the ENA1/PMR2 gene designated as ENA1 in the following encoding an enzyme of t

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ISC1-encoded inositol phosphosphingolipid phospholipase C

Christian Betz1, Dirk Zajonc1, Matthias Moll2and Eckhart Schweizer1

1

Lehrstuhl fu¨r Biochemie and the2Lehrstuhl fu¨r Anorganische und Allgemeine Chemie, Universita¨t Erlangen-Nu¨rnberg,

Erlangen, Germany

In Saccharomyces cerevisiae, toxic concentrations of Na+

or Li+ions induce the expression of the cation-extrusion

ATPase gene, ENA1 Several well-studied signal

transduc-tion pathways are known correlating high salinity to the

transcriptional activation of ENA1 Nevertheless,

informa-tion on the actual sensing mechanism initiating these

path-ways is limited Here, we report that the ISC1-encoded

phosphosphingolipid-specific phospholipase C appears to be

involved in stimulation of ENA1 expression and,

conse-quently, in mediating Na+ and Li+ tolerance in yeast

Deletion of ISC1 distinctly decreased cellular Na+and Li+

tolerance as growth of the Disc1::HIS5 mutant, DZY1, was

severely impaired by 0.5MNaCl or 0.01M LiCl In

con-trast, K+ tolerance and general osmostress regulation

were unaffected Isc1D mutant growth with 0.9MKCl and

glycerol accumulation in the presence of 0.9M NaCl or 1.5M sorbitol were comparable to that of the wild-type ENA1-lacZ reporter studies suggested that the increased salt sensitivity of the isc1D mutant is related to a significant reduction of Na+/Li+-stimulated ENA1 expression Cor-respondingly, Ena1p-dependent extrusion of Na+/Li+ions was less efficient in the isc1D mutant than in wild-type cells

It is suggested that ISC1-dependent hydrolysis of an unidentified yeast inositol phosphosphingolipid represents

an early event in one of the salt-induced signalling pathways

of ENA1 transcriptional activation

Keywords: salt-stress; signaling; sphingolipids; sphingolipid phospholipase C; yeast

The Saccharomyces cerevisiae gene, ISC1, has recently been

shown to encode an inositol phosphosphingolipid-specific

phospholipase C [1] In vitro, the enzyme exhibits the

characteristics of a Mg2+-dependent neutral (N)

sphing-omyelinase (SMase) and, thus, resembles the most

prom-inent member of the SMase family present in mammalian

cells [2,3] According to current knowledge, sphingomyelin

is absent from yeast and, hence, the physiological substrate

of Isc1p is likely to belong to one of the three major classes

of yeast sphingolipids, i.e inositol phosphorylceramides,

mannositol phosphorylceramides, or mannosyldiinositol

phosphorylceramides [4] In mammalian systems, various

intermediates of sphingolipid metabolism act as mediators

of intracellular signalling pathways [5–8] In particular, the

SMase reaction product, ceramide, has been recognized as

a second messenger being induced by a variety of

extracel-lular stress signals [8,9] Subsequent interaction of ceramide with specific protein kinases, protein phosphatases or proteinases induces signalling cascades which finally affect basic cellular functions such as cell cycle progression, cell growth, differentiation, apoptosis or Ca2+ion homeostasis [8,9] In S cerevisiae, sphingolipids represent 20–30% of cellular phospholipids [4] and, thereby, obviously fulfil an important structural function Besides this, they probably contribute to the signal transduction potential of yeast cells, too [10–15] Their vital function is underlined by the lethality of yeast mutants defective in sphingosine base biosynthesis [16] Although sphingosine base-defective mutants may be partly suppressed by the production of C26-fatty acid-containing glycerolipids, these mutants remain sensitive against heat, osmotic and lowpH stresses [4,5,17] From these results, the involvement of sphingoli-pids in distinct stress response pathways of yeast became quite obvious Each one of various different stress responses appears to have its own specific signalling pathway [5] While heat shock induces the biosynthesis

of trehalose [18,19], high extracellular osmolarity either induces the accumulation of glycerol as a compatible intracellular osmolyte [20–22] or, with toxic concentrations

of Na+or Li+ions, extrusion of these cations by induction and activation of the specific, ATP-driven ion pump Ena1p

is initiated [21,23–26] Both pathways of yeast osmoadap-tation have been intensively studied and many of their details are known Non-specific osmostress is exerted by moderate concentrations of various solutes such as NaCl, KCl or sorbitol and induces the high-osmolarity glycerol (HOG) pathway which rapidly raises the intracellular glycerol concentration up to molar levels [20,21] The

Correspondence to E Schweizer, Lehrstuhl fu¨r Biochemie;

Universita¨t Erlangen, Staudtstrasse 5, D-91058 Erlangen, Germany.

Fax: +49 9131 8528254, Tel.: +49 9131 8528255,

E-mail: eschweiz@biologie.uni-erlangen.de

Abbreviations: (N-)SMase, (neutral)sphingomyelinase; HOG,

high-osmolarity glycerol; BSM, BODIPYFL-C 5

N-(4,4-difluoro-5,7-dimethyl-4-bora-3a,4a-diaza-s-indacene-3-pentanoyl) sphingomyelin;

B-ceramide, BODIPYFL C 5 -ceramide; YPD, yeast extract,

peptone, dextrose; SCD, synthetic complete, dextrose.

Proteins and enzymes: Ena1 (atn1_yeast; EC 3.6.3.7), Isc1 (isc1_yeast;

EC 3.1.4.-), Gpd1 (g3p1_yeast; EC 1.2.1.12), Gpp2 (gpp2_yeast;

EC 3.1.3.-).

(Received 8 May 2002, revised 26 June 2002, accepted 5 July 2002)

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pathway comprises a mitogen-activated protein kinase

cascade which finally initiates transcription of the

glycer-ol-3-phosphate dehydrogenase (GPD1) and

glycerol-3-phosphatase (GPP2) genes [20] In contrast, specific

halotolerance of yeast against extracellular NaCl or LiCl

is based on the induction of the ENA1/PMR2 gene

(designated as ENA1 in the following) encoding an enzyme

of the P-type ATPase family This cation-extrusion pump

promotes the efflux of Na+and Li+from the cell ENA1

expression is controlled by various different signalling

pathways [20–29] Salt-stress-dependent induction of ENA1

involves the Ca2+/calmodulin-activated protein

phospha-tase calcineurin [25], the TOR-GLN3 signalling pathway

[27] and possibly also an additional,

calcineurin-indepen-dent mechanism [24] Besides this, the alkaline response

regulator Rim101p [28] as well as glucose repression and

the HOG pathway contribute to ENA1 expression [20–

22,26,29] While many details, mostly of the downstream

parts of these pathways, have been elucidated, little is

known about the sensing mechanisms and the signalling

molecules involved Since in mammalian systems,

N-SMase has been recognized as a prominent effector of

sphingolipid-dependent stress responses [8,9,30], we were

interested to study whether, in yeast, the N-SMase

homologue, Isc1p, possibly serves as a stress signalling

mediator too Here, we report that ISC1 is required for the

development of yeast halotolerance against Na+and Li+

ions by means of HOG-independent induction of ENA1

expression

E X P E R I M E N T A L P R O C E D U R E S

Yeast strains, plasmids, chemicals and media

The yeast strains used in this study were JS91-15.23 (Mata,

ura3, trp1, his3, can1) and the ISC1 deletion strain DZY1

derived from it (MATa, Disc1::HIS5, ura3, trp1, his3, can1)

The HIS5 insertion cassette used for ISC1 disruption was

isolated, by short flanking homology PCR, from plasmid

pFA6a-HIS3MX containing the Schizosaccharomyces

pombe HIS5gene [31] The cassette exhibits, at both ends,

40 nucleotides of homology to positions 477–517 and 911–

951 of the ISC1 gene, respectively The ENA1 ORF was

isolated by PCR amplification of two adjacent regions of

S cerevisiaechromosomal DNA representing base pairs 1–

1182 and 1129–3273 of the ENA1 DNA sequence The two

fragments were ligated by means of two overlapping,

terminal BamHI sites and subsequently inserted, as a PvuII/

XhoI fragment, between the ADH1 promoter and

termina-tor regions of the multicopy yeast expression vectermina-tor,

pVT100-U [32] The resulting plasmid was pCWB20

Plasmid pDZ6 contained the ISC1 reading frame fused to

the MET25 promoter in the multicopy yeast expression

vector, p425MET25 [33] Plasmid pFR70 containing an

ENA1-lacZ promoter–reporter fusion was obtained from

Prof Rodriguez-Navarro, Madrid, Spain Bacillus cereus

sphingomyelinase (SMase) was purchased from Sigma The

fluorescent probes, BODIPYFL C5-sphingomyelin

(BSM) and BODIPYFL C5-ceramide (B-ceramide) were

from Molecular Probes Inc Complex (YPD) and synthetic

complete (SCD) yeast media as well as the appropriate SCD

omission media were prepared according to standard

protocols [34]

Sphingomyelinase assay The assay followed essentially the procedure described by Ella et al [35] Yeast cells suspended in 1 vol lysis buffer (20 mMTris/HCl pH 7.4, 10% glycerol, 50 mMKCl, 1 mM

dithiothreitol, 1 mMphenylmethanesulfonyl fluoride, 1 lM

pepstatin A, 10 lM leupeptin) were disrupted with glass beads Unbroken cells were removed by 5 min centrifuga-tion at 4000 g Total membranes were collected from the supernatant by centrifugation at 100 000 g for 1 h The fluorescent substrate, BSM, was subsequently used in a semiquantitative SMase assay Briefly, 55 lL of the mem-brane suspension were mixed with 45 lL 10 mMMes/KOH buffer pH 6.0 containing 400 mM KCl, 200 lM BSM,

10 mMMgCl2, 30 mM2-glycerophosphate After 1 h incu-bation at 30C, reaction products were extracted with chloroform/methanol (1 : 1) and separated by TLC on Silica G60 plates (Merck) The plates were developed with chloroform/methanol/water (60 : 35 : 8) and, subsequently, fluorescent spots were visualized and documented by a Fluorescence Binocular (Zeiss, Stemi SV11, 515–565 nm filter) according to the manufacturer’s indications Glycerol determination

Intracellular glycerol was determined enzymatically [36] using a commercial glycerol determination kit (Roche Diagnostics) Briefly, cells from mid-logarithmic phase cultures of wild-type or isc1D strains were transferred, at

an D600of 0.8, from normal YPD media to YPD containing 0.9MNaCl After 2 h growth at 30C, cells were harvested

by centrifugation, washed twice with isotonic saline at 4C and then placed into boiling 0.5M Tris/HCl pH 7.0 for

10 min After removing cell debris by 10 min centrifugation

at 15000 g, the glycerol in the supernatant was determined enzymatically

Measurement of intracellular Na+ and Li+concentrations

Determinations followed essentially the procedure described

by Gaxiola et al [37] In brief, cells were grown in YPD media to the densities indicated for the particular experi-ment After harvesting by centrifugation, cells were washed three times with 1.5M sorbitol For subsequent cell extraction, two alternative methods were used Method A: cells were permeabilized by incubation for 15 min at 95C

Na+and Li+were determined in the cleared extracts using

Na+and Li+specific lamps (L.O.T.-Oriel GmbH, Darms-tadt, Germany) in a Shimadzu AA-6200 atomic absorption flame emission spectrophotometer Method B: cells were washed and lyophilized The dry cells were incinerated at

840C for 6 h The residue was dissolved in 0.1NHCl and atomic absorption measurements were performed as described under method A

R E S U L T S

S cerevisiae ISC1 mutants are sensitive to Na+

and Li+ion stresses According to Sawai et al [1] disruption of the yeast ORF, ISC1, abolishes the in vitro SMase activity of the wild-type

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cell homogenate The characteristics of the Disc1::HIS5

deletion strain, DZY1, which was constructed in this work

are in accordance with these findings (Fig 1) SMase

activity was efficiently restored in isc1D cells upon

transfor-mation with plasmid pDZ6 encoding the intact ISC1 gene

(Fig 1) Comparable growth rates were observed with

wild-type and isc1D cells in normal YPD media not only at 30C

but also at elevated temperature (37C) or lowpH (pH 3.5)

stresses (Fig 2A) However, in the presence of 0.4–0.9M

NaCl, growth of the mutant was differentially reduced

(Fig 2B) and wild-type cells rapidly overgrew the mutants

(Fig 2A) After eight generations in 0.9M NaCl, the

proportion of isc1D cells had dropped to  2% of the

viable cells, which compares to > 80% isc1D cells surviving

in the absence of NaCl under otherwise identical conditions

(Fig 2A) On solid media, the differential sensitivity of

isc1D cells against elevated (0.4–0.5M) NaCl concentration,

was further confirmed and, in addition, a similar toxicity

was established for 0.01MLiCl (Fig 3) In contrast, 0.8M

KCl had no measurable inhibitory effect on isc1D growth

on solid media (Fig 3)

ISC1 functions independently of the HOG-pathway Adaptation of yeast to high salinity is, according to current knowledge, largely based on two different mechanisms, i.e induction of the HOG pathway responding to nonspecific osmostress [20–23], and induction of the ion extrusion pump Ena1p responding to toxic concentrations of Na+and Li+ ions [21,25–29] According to the data shown in Figs 2 and

3, isc1D cells are specifically sensitive to NaCl and LiCl, but tolerate high osmolarity of other solutes such as KCl (Fig 3) or glucose (data not shown) These characteristics argue against the HOG pathway being affected in the isc1D mutant In agreement with this conclusion, cellular glycerol levels increased to comparable levels in wild-type and isc1D cells upon raising the salinity and osmolarity of the media (Table 1) Thus, the HOG signalling pathway responded normally in the mutant not only with 1.5Msorbitol but also with 0.9MNaCl

ISC1 is involved in Na+

and Li+salt-induced expression

ofENA1 Stimulation of ENA1 expression has been recognized as a crucial response of yeast to extracellular high salinity [20– 29] The ENA1 encoded ATPase mediates Na+and Li+ion extrusion from the cell We therefore investigated whether the loss of halotolerance in isc1D cells was due to the failure

of ENA1 induction in the mutant For this, the ENA1-lacZ promoter–reporter construct in plasmid pFR70 was trans-formed into wild-type and isc1D cells The transformants expressing the bacterial lacZ gene under the control of the ENA1 promoter were challenged with 0.8M KCl, 0.8M

NaCl and 0.25M LiCl, respectively In the wild-type transformants, increasing concentrations of NaCl and LiCl caused the expected time- and concentration-dependent, strong induction of b-galactosidase activity (Fig 4) In the isc1D transformants, however, b-galactosidase induction

Fig 1 SMase activity in wild-type (JS91-15.23) and ISC1-disrupted

yeast cells From each strain  550 lg membrane protein w ere applied

to the fluorescent SMase assay as described in Experimental

proce-dures Purified Bacillus cereus SMase (0.1 U) was used in a control

assay The fluorescent sphingomyelin derivative BSM and its SMase

product, B-ceramide were run as references isc1D + pDZ6 w as a

transformant of the isc1D mutant with the ISC1 containing plasmid,

pDZ6.

Fig 2 Differential growth rates of wild-type

and isc1D cells under different stress conditions.

(A) One-to-one mixtures of wild-type

(JS91-15.23) and isc1D cells were inoculated into

SCD media and subsequently incubated under

the following conditions: 30 C (s), 37 C

(.), pH 3.5 (h), with 0.9 M NaCl (d) Both

strains had been precultivated in SCD media

up to mid-log phase At distinct time intervals,

aliquots of each culture were withdrawn and

plated onto SCD media After outgrowth the

cells were replica-plated onto

histidine-omis-sion media The ratio of histidine-positive

isc1D cells to nondisrupted, histidine-requiring

JS91-15.23 cells was then determined for each

sample (B) JS91-15.23 (d) and isc1D (s) cells

were grown separately in YPD media

con-taining 0.4 M NaCl Identical cell counts were

used for inoculation of the two strains.

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under these conditons was either negligible (LiCl) or

significantly ( 70%) lower (Fig 4) With 0.8MKCl, both

the rate and the level of b-galactosidase induction were

comparable in wild-type and isc1D transformants (Fig 4)

Analysis of ENA1 mRNA by Northern blot analyses

provided additional support to these enzymatic measure-ments (data not shown) Specific b-galactosidase inhibition

in ISC1 mutants was excluded as another reporter construct (INO1¢-lacZ) was expressed normally (data not shown) The basal level of ENA1 promoter activity as is observed with 0.8M KCl or w ith NaCl and LiCl in the isc1D mutant probably corresponds to the HOG-dependent portion of ENA1regulation which is apparently unaffected by ISC1 inactivation

In another series of experiments, intracellular sodium and lithium concentrations were determined by atomic absorption spectrometry upon challenging wild-type, isc1D and pCWB20-transformed isc1D cells with 0.8M NaCl and 0.25MLiCl, respectively It is seen that, after 1.5–4 h incubation, the sodium content in ISC1-defective cells was 25–35% above wild-type levels (Fig 5A) Correspondingly, lithium concentrations were 1.3- and 1.8-fold higher in isc1D than in wild-type cells, when these were exposed to LiCl and NaCl stresses, respectively (Fig 5B) These differences were not increased further by more extended stress exposure periods (data not shown) To demonstrate the correlation between Na+and Li+efflux and Ena1p

Fig 3 Effect of ISC1 and ENA1 gene expression on yeast cell growth under various salt stress conditions Wild-type (JS91-15.23) and isc1D cells were transformed with plasmid pCWB20 containing ENA1 under ADH1-promoter control Transformed and non-transformed cells were grown at 30 C on the indicated SCD and YPD solid media for 2 days.

Table 1 Glycerol content of wild-type and isc1D cells upon osmostress

application Wild-type (JS91-15.23) and isc1D cells were grown in YPD

liquid media to mid-logarithmic phase and subsequently transferred to

YPD media supplemented with 1.5 M sorbitol and 0.9 M NaCl,

respectively After 2 h incubation at 30 C, cells were collected by

centrifugation, washed twice with 0.9% NaCl and their glycerol

content was determined as described in Experimental procedures.

Growth

conditions

Glycerol content (g/L) Wild-type isc1D

+ 1.5 M sorbitol 16 15

Fig 4 Induction of ENA1-lacZ reporter expression in ISC1-positive (JS91-15.23, grey) and ISC1-disrupted (black) cells by NaCl, LiCl

or KCl salt stresses Cells were grown in YPD media to an OD 600 of 0.2 (A) and 0.3 (B), respectively, before NaCl, LiCl or KCl were added from appropriate stock solutions (3–6 M ) to give the indicated final concentra-tions Subsequent incubation was at 30 C for 4.5 h (B) or for the varying time periods indicated in (A) After harvesting by centrifu-gation, cells were permeabilized according to Gaxiola et al [37] and b-galactosidase mea-surements were performed as described by Miller [44] Solutions were cleared by centri-fugation before photometric measurement.

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activity, expression of ENA1 was stimulated by

transfor-mation of isc1D cells with pCWB20 On the multicopy

yeast plasmid pCWB20, ENA1 transcription is controlled

by a constitutive yeast promoter (ADH1) and is therefore

independent of salt stress In accordance with these

characteristics and with the presumed function of ENA1,

60–90% lower sodium and lithium levels were observed in

the isc1D/pCWB20 transformants even when compared

with the wild-type (Fig 5) As expected from their

increased ENA1 expression, the pCWB20 transformants

exhibited a distinctly higher salt tolerance than

nontrans-formed cells on NaCl- or LiCl-supplemented solid media

(cf Fig 3)

D I S C U S S I O N

The involvement of sphingolipids in cellular stress

responses appears to be conserved from yeast to

mam-mals [8,9] In mammalian systems, sphingomyelinases and

their product, ceramide, are particularly important

effec-tors not only in these but also in other signalling

pathways [6,7] In the present study, we report that the

ISC1-encoded yeast homolog of mammalian N-SMase is

involved in a cellular stress response, too We observed

that mutational inactivation of ISC1 leads to the loss of

cellular salt tolerance and renders the mutants specifically

sensitive to NaCl or LiCl stresses To our knowledge,

these data provide, for the first time, evidence for an

SMase-like activity participating in a stress signalling

pathway of yeast

A comparable sensitivity of the ISC1 mutant was not

observed to increased KCl concentrations or against

osmostress exerted by 1.5Msorbitol Glycerol production

in response to these conditions of general osmostress was

unimpaired indicating that the HOG signalling pathway

functioned normally in the mutant Similarly, ISC1

mutants were not particularly sensitive to high

tempera-ture or lowpH stresses Thus, ISC1-defective cells obviously exert a specifically increased sensitivity against

Na+ and Li+ toxicity In accordance with the known importance of the cation extrusion pump, Ena1p, for maintaining yeast halotolerance [21,25–28], we found that

in ISC1 null mutants expression of ENA1 was distinctly depressed Evidence for this was derived from differential expression studies with ENA1-b-galactosidase reporter constructs in ISC1-defective and isogenic wild-type cells The failure of ENA1 induction in the ISC1 mutant was not absolute but 60% of the wild-type reporter activity These findings agree with the known complexity of ENA1 regulation Clearly, only one of several possible routes of ENA1 activation is affected in the ISC1 mutants The fact that Ena1p activity is reduced but not absent in ISC1 mutants may be responsible for the only moderate increase in intracellular Na+ and Li+ levels: although they were distinctly higher than those in wild-type cells, the differences observed were not dramatic They never-theless correlate fairly well to the differential growth rates

of wild-type and mutant cells in the presence of 0.4M

NaCl (cf Fig 2B) Taken together, the data reported here suggest that in yeast, the ISC1-encoded sphingolipid phospholipase C makes a remarkable contribution to the

Na+/Li+-dependent induction of ENA1

Ceramide is reported to act, as a mammalian second messenger, on distinct protein kinases and protein phos-phatases which control cellular functions ranging from proliferation and differentiation to growth arrest and apoptosis [8,9] In particular, stimulation of protein phos-phatase PP2A by ceramide is conserved in yeast where it mediates the transient growth arrest upon heat stress [9,10,13–15] The induction of salt resistance being charac-terized by ENA1 activation rather than by cell cycle arrest is expected to followa different mechanism According to current knowledge, a prominent route of ENA1 induc-tion involves the Ca2+/calmodulin-dependent protein

Fig 5 Na + (A) and Li + (B) concentrations

in wild-type (JS91-15.23) and isc1D cells.

(A) Wild-type, isc1D and pCWB20

trans-formed isc1D cells were analysed after having

been exposed to 0.8 M NaCl at 30 C for the

indicated periods of time (B) The three strains

(identical symbols as in A) were incubated for

4 h at 30 C with 0.8 M NaCl and 0.25 M LiCl,

respectively Prior to stress application, cells

had been grow n in YPD media to OD 600 of 0.8

(A) and 0.3 (B) In (B) only Li+

concentra-tions were determined independent of the type

of stress Measurements of intracellular Na +

and Li+concentrations were performed

according to either method A (A) or B (B) as

described in Experimental procedures.

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phosphatase calcineurin [23–25] The target protein of

calcineurin action in yeast is the zinc-finger transcription

factor Crz1p [38,39] Crz1p dephosphorylation initiates its

nuclear import and, subsequently, its binding to the

calcineurin-dependent response element in a variety of

promoters including that of ENA1 As an alternative, a

ceramide-activated phosphatase rather than calcineurin

may be considered to dephosphorylate Crz1p Another

possible mechanism of sphingolipid-dependent ENA1

induction may be connected with the role of sphingolipids

in cellular Ca2+homeostasis [40] For instance, raising the

intracellular Ca2+level is expected to stimulate calcineurin

activity and, thus, ENA1 expression In mammalian cells

various glycerophosphoinositide-specific phospholipases C

function in Ca2+signalling pathways by generating inositol

1,4,5-triphosphate as a second messenger [41] This

messen-ger subsequently releases Ca2+ from intracellular stores

Although a homologue to the respective mammalian

recep-tor is not evident from the yeast genome, an analogous

inositol derivative released by the Isc1p phospholipase C

from an appropriate sphingolipid could fulfil a similar

function As the pathways of sphingolipid metabolism are

highly interconnected, ISC1 and its product, ceramide, must

not be viewed as isolated signalling elements Instead,

ceramide is possibly further metabolized to the true bioactive

effector In this context, a recent report by Birchwood et al

[42] on sphingosine-1-phosphate or related molecules as

stimuli of Ca2+influx and signalling in yeast is of particular

interest The authors report that these compounds

repre-senting intermediates of both sphingolipid biosynthesis and

degradation elevate intracellular Ca2+levels and activate

calcineurin-signalling pathways The transient accumulation

of Ca2+ due to the increase of phyto- and

dihydrosp-hingosine-1-phosphate is well established as a heat shock

response of yeast [12,43] Possibly, a comparable effect is

involved in the salt stress response of yeast

Unlike with heat stress, no alteration of the cellular

ceramide content is observed upon salt stress application to

yeast [5] During heat stress, total ceramides and long-chain

sphingoid base phosphates increase several-fold These

changes are thought to occur as a result of increased

sphingolipid biosynthesis and appear to be required for the

development of thermotolerance rather than for signalling

reactions [5] Due to the abundance and structural

com-plexity of yeast sphingolipids, the breakdown of a single

species or a small percentage of them for the purpose of

signal generation would be difficult to detect Nevertheless,

subtle differences were observed by us (D Zajonc &

E Schweizer, unpublished data) and by Sawai et al [1]

between sphingolipid patterns of wild-type and

ISC1-defective strains Obviously, only a minor fraction of yeast

sphingolipids is susceptible to Isc1p degradation Chemical

characterization of these Isc1p substrates deserves further

investigation

Remarkably, Isc1p activity is detected in extracts of

wild-type yeast even in the absence of salt stress The

activity is not significantly stimulated upon growth in the

presence of 0.8M NaCl (data not shown) Even though

these results need to be reconfirmed once the physiological

substrate of Isc1p is known, the data may indicate that

salt stress-induced activation of Isc1p occurs at a

post-transcriptional level, possibly by its interaction with a

molecule produced further upstream in the signal

trans-duction chain Thus, in vitro and in vivo activities of Isc1p should probably be differentiated, especially as the enzyme

is known to require distinct phospholipid cofactors for full activity [1] Hence, not only the bioactive messenger produced by Isc1p and the mechanism of its action but also the salt-sensing process involving Isc1p activation needs to be studied further

A C K N O W L E D G E M E N T S

This work was supported by the Deutsche Forschungsgemeinschaft and by the Fonds der Chemischen Industrie We thank Prof Alfonso Rodriguez-Navarro (Madrid) for kindly providing plasmid pFR70.

R E F E R E N C E S

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