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Induction of a lacZ reporter gene with any one of the NGG codons at position +2 to +5 does not influence growth of a normal strain, but growth of a strain with a defective peptidyl-tRNA h

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Abortive translation caused by peptidyl-tRNA drop-off

at NGG codons in the early coding region of mRNA

Ernesto I Gonzalez de Valdivia and Leif A Isaksson

Department of Genetics, Microbiology and Toxicology, Stockholm University, Sweden

As an early step during translation initiation in

bac-teria the mRNA is anchored to the 30S ribosomal

sub-unit by base pairing between a sequence close to the

end of the 16S ribosomal RNA and the

Shine–Dal-garno (SD) sequence, a few bases upstream of the

initi-ation codon in the mRNA Even though the SD

sequence increases initiation efficiency, mRNAs that

lack this sequence can be translated [1] albeit at a

lower efficiency [2] In such case the sequence in the

downstream region (DR) immediately following the

initiation codon has a large influence on gene

expres-sion at the translation level [3] This effect was

origin-ally suggested to be the result of an additional

anchoring by base pairing between the DR sequence in

mRNA and 16S rRNA but this model has been

refu-ted experimentally [4,5] Many rare codons are used

within the first 25 codons in Escherichia coli [6]

Clearly, the early coding region in mRNA is important

for gene expression, presumably at the translational level

A closer study of the DR region has revealed that the nature of the +2 codon can affect expression by

up to a factor of 20 A number of codons, but in par-ticular G-rich codons, at this position give low gene expression The codons that follow in the DR have rel-atively similar effects giving normal gene expression with the notable exception of NGG codons (AGG, CGG, UGG and GGG) as these lower gene expression down to 10–20% also if located at positions +3 to +5 The other G-rich codons GGN and GNG (where

N is non-G) do not have this effect in this sequence window At position +7 all G-rich codons, including NGG give normal expression This is also the case if they are placed at +11 [3,7–10] The reduced level of gene expression that is seen for the NGG codons in the early coding region is not the result of lowered

Keywords

abortive translation; NGG codons;

peptidyl-tRNA drop-off; Escherichia coli; early

elongation

Correspondence

L A Isaksson, Department of Genetics,

Microbiology and Toxicology, Stockholm

University, S-106 91 Stockholm, Sweden

Fax: +46 8 15 51 39

Tel: +46 8 16 41 97

E-mail: leif.isaksson@gmt.su.se

Website: http://www.gmt.su.se

(Received 29 June 2005, revised 17 August

2005, accepted 19 August 2005)

doi:10.1111/j.1742-4658.2005.04926.x

In Escherichia coli the codons CGG, AGG, UGG or GGG (NGG codons) but not GGN or GNG (where N is non-G) are associated with low expres-sion of a reporter gene, if located at positions +2 to +5 Induction of a lacZ reporter gene with any one of the NGG codons at position +2 to +5 does not influence growth of a normal strain, but growth of a strain with a defective peptidyl-tRNA hydrolase (Pth) enzyme is inhibited The same codons, if placed at position +7, did not give this effect Other codons, such as CGU and AGA, at location +2 to +5, did not give any growth inhibition of either the wild-type or the mutant strain The inhibi-tory effect on the pth mutant strain by NGG codons at location +5 was suppressed by overexpression of the Pth enzyme from a plasmid However, the overexpression of cognate tRNAs for AGG or GGG did not rescue from the growth inhibition associated with these codons early in the induced model gene The data suggest that the NGG codons trigger pep-tidyl-tRNA drop-off if located at early coding positions in mRNA, thereby strongly reducing gene expression This does not happen if these codons are located further down in the mRNA at position +7, or later

Abbreviations

SD, Shine–Dalgarno; DR, downstream region; Pth, peptidyl-tRNA hydrolase; IPTG, isopropyl thio-b- D -galactoside; Ts, temperature sensitive.

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mRNA levels or secondary structure formation.

Rather, some abortive event seems likely One

possibil-ity would be shifting of the translational reading frame

giving premature termination at some out-of-phase

ter-mination codon However, this explanation does not

seem to be valid Another possibility would be

drop-off of peptidyl-tRNA from the translating ribosome

during early elongation [11] In this case the released

tRNA would be cleaved by the

peptidyl-tRNA hydrolase (Pth) [12], thereby initiating turnover

and re-use of the amino acid residues and the tRNA

moiety

A mutant E coli strain is available that has a heat

sensitive Pth At high temperature this mutant does not

grow because the accumulated peptidyl-tRNA cannot

be degraded [13] This will give shortage of tRNA as a

consequence, which is likely to be one of the reasons

for the heat-sensitive phenotype of the mutant [14]

Increased heat sensitivity of the pth mutant strain

has been used to demonstrate accumulation of

pep-tidyl-tRNA in connection with overexpression of short

mini-genes [15–18] Drop-off at a pair of rare AGA

AGG codons has been demonstrated in a natural gene

and ribosome stalling and drop-off at a pair of

argin-ine codons in mini-genes [19]

In the present study we show that the NGG codons

CGG, AGG, GGG and UGG, when they are

posi-tioned in the early coding region downstream of the

initiation codon in a highly expressed reporter gene,

inhibit growth of a pth thermo-sensitive (Ts) mutant

strain This effect is not seen for other codons or for

the NGG codons if placed at a later position (+7)

The results suggest that low gene expression associated

with NGG in early coding reading in mRNA is the

result of peptidyl-tRNA drop-off from the ribosome

during translation in E coli

Results

Induction of a test gene with an early NGG

codon inhibits growth of a pth(Ts) strain

Codons at position +2, immediately following the

AUG initiation codon, influence gene expression by up

to a factor of 20 Further down at positions +3 to

+5 in the DR this codon influence is less pronounced

with the notable exception of the NGG codons that

lower gene expression to only 10–20% [10] The other

G-rich codons GGN and GNG (where N is non-G),

do not give such low gene expression The low

expres-sion associated with NGG is not seen if the codon is

located further down in the mRNA coding region at

+7 [10]

One possible reason for the low gene expression caused by the early NGG codons could be abortive translation as a result of peptidyl-tRNA drop-off at these codons [13] Such released peptidyl-tRNA is nor-mally hydrolysed by a Pth, thus allowing recycling of both the amino acids and the tRNA A mutant strain MB01 is available with a pth(Ts) (Table 1) In this mutant strain accumulation of peptidyl-tRNA, that cannot be degraded and recycled, leads to inability to grow at high temperature [14] Introduction of plasmid pVH1 with its pth+ gene gives partial complementa-tion of the temperature sensitivity of MB01 (Table 2) This complementation is not complete, probably because of the low copy number of pVH1 [20]

Table 1 Bacterial strains and plasmids.

Relevant characteristics References Strains

MC1061 araD139, D(lacI POZYl) 74, galU,

galK, rpsL, D(ara A BC-leu)7697, hsdR, mcrB, Sm S ,

[44]

XAC D(lacproB), arg E, ara, gyrA, rpoB, thi [43]

MB01 MG1655, zdh-925::Tn10, pth(Ts) This work Plasmids

lacZ pCMS71 Derivative of pCM21 with cloning

cassette, Amp R

[9,10] Protein A¢

pHN109 Derivative of pAB93 with

an internal 2A¢

[30]

Control gene and cloning cassette, Amp R

pEG998 Derivative of pHN109 with Csp45I

restriction site

[10]

Others pUBS250 arg U + (tRNA Arg4 ), Kan R [34] pArgUW argU + (tRNA Arg4 ), argW + (tRNA Arg5 ) Kan R [40]

pJMM19 lysV + (tRNA Lys ), Kan R [20] pMO22 glyU + (tRNA Gly1 ), Tet R [39]

Table 2 Effect of temperature on growth of strain MB01 with a heat sensitive peptidyl-tRNA hydrolase Strains were streaked on Luria–Bertani agar plates with IPTG (1 m M ) (+) or without (–), and incubated at the indicated temperatures.

Strains Plasmid

30 C 37.5 C 43 C 30 C 37.5 C 43 C

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To test for excessive drop-off of peptidyl-tRNA at

certain early codons (including the NGG codons) they

were placed in the 5¢-coding region of a lacZ reporter

gene in a plasmid (Fig 1A) and introduced into the

pth(Ts) mutant strain MB01, with its temperature

sen-sitive Pth (Table 1) Cultures were pregrown at 30C,

followed by dilution into the same medium with or

without isopropyl thio-b-d-galactoside (IPTG; 1 mm)

whereafter growth was continued at 37.5C As shown

in Fig 1, induction of test genes with NGG codons at

positions +2, +3 and +5 inhibits growth of the

pth(Ts) strain This inhibitory effect is not obtained if

the NGG codons are located at +7 or if the test gene

is not induced by IPTG It was noted, but not

ana-lysed further, that cells with the nondrop-off codons

CGU and AGA at position +7 were delayed in

growth in the early growth phase The arginine codons

CGU and AGA at +2, +3 and +5 did not inhibit growth of the strain even in the presence of IPTG induction All of these results suggest that the low gene expression associated with NGG codons in the down-stream region following the initiation codon [9,10], is the result of peptidyl-tRNA drop-off that is excessive enough to inhibit growth of a pth(Ts) mutant strain

Pth enzyme rescues from growth inhibition by +5 NGG codons

As described above, it appeared likely that the inhibi-tory growth effect by early NGG codons in the pth(Ts) mutant MB01 was due to accumulation of peptidyl-tRNA, as the result of an abortive drop-off event MB01 did not grow at 43C and it showed disturbed growth at 37.5C (Table 2) To confirm that the

Fig 1 Plasmid constructs are derivatives of pDA3480 [9,10] The 5¢ end of the transcript is 5¢-AAUUGUGAGCGGAUAACAAUUUCA-CCAGGUAAUAAAUUAAAUAAAAUUUAAAUAUG-3¢ for the gene variants that lack a functional Shine–Dalgarno sequence (SD, underlined) [21] (A) LacZ reporter gene construct pCMS71 was used as a cloning vector for the insertion of different AUG downstream context sequences using the restriction sites SwaI ⁄ SalI and SwaI ⁄ Csp45I The lacZ gene is under control of the trc promoter [9] (B) Protein A¢ reporter gene construct pEG998, earlier denoted pEG1000 [10], was used as cloning vector to subclone different AUG downstream context sequences using the restriction sites SwaI ⁄ SalI and SwaI ⁄ Csp45I.

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disturbed growth was the result of peptidyl-tRNA

accumulation a plasmid (pVH1) containing the pth+

gene was introduced into the pth(Ts) strain,

harbour-ing another compatible plasmid that carries the lacZ

reporter gene with AGG or GGG at position +5

Transformants were streaked on broth plates, with or

without 1 mm IPTG, and incubated at 30C or

37.5C In the absence of a pth+ carrying plasmid,

without IPTG induction, growth of the lacZ variant

with AGG or GGG at position +5 was disturbed at

37.5C (Table 3) In the presence of IPTG growth

inhibition was more severe Co-expression of the

plas-mid pVH1 with its pth+and the plasmid with the test

gene with +5 AGG or GGG protected from the

inhibitory effect by these codons at 37.5C, even in

the presence of IPTG LacZ variants with CGG or

UGG at +5 gave similar growth inhibition as AGG

and GGG (not shown) These results strongly suggest

that growth inhibition by +5 NGG codons at 37.5C

is the result of accumulation of peptidyl-tRNA, caused

by drop-off from the ribosome during translation, and

low activity of Pth in the MB01 mutant strain

Fur-thermore, no codons, including NGG, inhibited

growth of the MB01 strain if placed at +7 (Fig 1D)

even in the presence of IPTG Also these results are

consistent with an earlier report that there is little

influence of +7 codons on gene expression [10,21]

The data presented here suggest that NGG codons at

early coding positions cause growth inhibition of a

pth(Ts) mutant strain as a result of peptidyl-tRNA

drop-off and insufficient Pth activity

Gene expression values in a normal pth+ strain, in

the absence of IPTG induction, are presented as inserts

in Fig 1 These values confirm the previous findings of

low gene expression being associated with early NGG

codons [10,21] They also demonstrate the correlation between a negative effect on gene expression and a strong negative effect on growth of a pth– mutant strain

Overexpression of tRNA has no effect on gene expression or growth inhibition associated with early NGG codons

The MB01 mutant strain is supposed to be growth inhibited at 37.5C because of accumulation of pep-tidyl-tRNA, thus possibly causing decreased turnover and starvation for the tRNA moiety [22] One would therefore expect that overexpression of the correspond-ing tRNA would protect from growth inhibition at 37.5C by the +5 NGG codons, in a similar manner

as does introduction of a plasmid encoding the pth+ gene To test for this possibility a plasmid with +5 AGG in the test gene was combined in the MB01 strain with the plasmid pUBS520 that carries the tRNAArg4 gene, or plasmid pArgUW with the tRNAArg4 (decodes AGA and AGG) and tRNAArg5 (decodes only AGG) genes A plasmid with a +5 GGG construct was combined with the plasmid pMO22 that carries the gene for the cognate tRNAGly1 (decodes only GGG)

Plasmid carrying cells with the different variants of +5 NGG codons were analysed in a similar test as described above for the pth+plasmid However, unlike the pth+ carrying plasmid pVH1, the plasmid pUBS520 (encoding tRNAArg4), pArgUW (encoding tRNAArg4 and tRNAArg5) or plasmid pMO22 (enco-ding tRNAGly1) did not protect cells from the negative effect by the induced test gene, with its +5 NGG codon AGG or GGG, respectively (Table 3) It was Table 3 Complementation of growth inhibition of MB01 by overexpressed genes Plasmids and strains MG16555 or MB01 are described in Table 1 The strains were streaked on Luria–Bertani agar plates with IPTG (1 m M ) (+) or without (–), and incubated at 37.5 C.

IPTG

pEG216 ⁄ pArgUW AGG +5 ⁄ tRNA Arg4; 5

pEG207 ⁄ pMO22 GGG +5 ⁄ tRNA Gly1

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noted that the plasmids encoding tRNAArg4 or

tRNAArg4 and tRNAArg5 were toxic for the MB01

mutant strain, but not for the wild-type strain, even in

the absence of the lacZ variant with its +5 AGG

codon On the contrary, the plasmid that carries the

tRNAGly1 gene did not alone influence growth of the

MB01 mutant strain, nor did it suppress the low gene

expression associated with +5 GGG

The effect on gene expression by an increased

intra-cellular pool of relevant tRNAs was analysed For this

purpose the A¢ reporter system was used (formally

referred to as Z-protein) Fig 2B This reporter system

is carried by a plasmid with the 3A¢ and 2A¢ genes

[10] Both are based on a gene which codes for three

or two, respectively, identical engineered antibody

binding B-domains of protein A from Staphylococcus

aureus Both genes are under separate control of

iden-tical Ptrc promoters and Ttrp terminators The 3A¢

test gene is used to analyse the effects on expression

by base alterations whereas the 2A¢ is kept constant as

an internal control The protein products can be

affin-ity purified in a single step using an IgG–Sepharose

column Gene expression can be estimated by

separ-ation of the two A¢ proteins on gel electrophoresis

Scanning of the protein bands give the relative gene

expression (3A¢ ⁄ 2A¢ ratio)

The question was asked if excess tRNA cognate

to the codon preceding an NGG codon has any

influence on the low gene expression associated with

such codons The lysine codon AAA, that gives high

gene expression if located at position +2, was

cho-sen Plasmid constructs with AAA at +2 and either

one of the NGG codons at +3 (Fig 2B) were

coex-pressed in strain XAC together with another plasmid

(pJMM19) encoding tRNALys The transformants

with their two compatible plasmids were grown

under appropriate double antibiotic selection pressure

and the 3A¢ and 2A¢ protein products were isolated

and quantified by SDS⁄ PAGE Figure 3A shows that

tRNALys overexpression, being cognate to the +2

AAA, did not significantly suppress the low

expres-sion caused by the +3 NGG codons in the 3A¢ test

gene

The question was also asked if excess tRNA,

cog-nate to an early NGG codon, influences gene

expres-sion For this purpose, 3A¢ encoding plasmids with

+2, +3, +4, +5 or +7 AGG, GGG or AGA were

combined with plasmid pUBS250 (encoding tRNAArg4)

or pArgUW (encoding tRNAArg4 and tRNAArg5) or

plasmid pMO22 (encoding tRNAGly1) AAA was used

as +2 codon in the 3A¢ constructs, where applicable,

and it was also analysed at the other positions for

comparison No effect on gene expression by the extra

tRNA supply was seen (Fig 3B) The results suggest that overexpression of the tRNAs for the arginine codon AGG and the glycine codon GGG do not coun-teract the low gene expression caused by these codons

at early positions Thus, low expression by an early AGG and GGG is not suppressible by increased cog-nate tRNA to these respective codons or to the codon that precedes them Both the arginine codons AGG and AGA are decoded by the same tRNAArg4 As shown in Fig 3, in the presence or absence of tRNAArg4, AGA at positions +2, +3, +4, +5 or +7

is associated with high gene expression, thus being very different from the related codon AGG The other NGG codons CGG and UGG were not analysed for the influence of increased concentration of cognate tRNAs

The question remains whether the plasmid associ-ated tRNA genes are expressed in the analysed bac-teria For this reason, the levels of gene expression and tRNA concentration in a wild-type strain was com-pared using a plasmid encoding tRNAArg4 (decoding AGA⁄ AGG) and tRNAArg5 (decoding AGG) and another plasmid with the 3A¢ test gene, using double antibiotic selection As shown in Fig 4, the protein expression value for +5 AGG is 10 times lower than that for +5 AGA, or compared to either codon at position +7 The low expression value for +5 AGG

is not increased despite the fact that the concentration

of the cognate decoding tRNAs is significantly increased in the strain

In summary, the NGG codons CGG, AGG, UGG and GGG are associated with very low gene expression

if placed at positions +2 to +5 This phenomenon is not observed for GGN and GNG (where N is non-G)

or for the other arginine codons CGU, CGC, CGA and AGA [10] For AGG and GGG low expression is found even if the corresponding decoding tRNA

is overexpressed in the cell Peptidyl-tRNA drop-off is suggested to be the reason for the low expression val-ues observed for the analysed codons AGG and GGG

at the early positions +2, +3 or +5 These codons appear not to give any significant drop-off if located at +7 Other analysed codons, including the arginine codons CGU and AGA, do not appear to give any drop-off at any location, as reflected by high expres-sion values and inability to inhibit growth of a pth(Ts) mutant strain

Discussion

The single codons AGG, CGG, UGG and GGG (NGG) at positions +2 to +5 downstream of the initiation codon strongly decrease gene expression at

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the level of translation [9,10,23] The effect is not seen

for the other G-rich codons GGN or GNG (where N

is non-G) or if the NGG codons are placed at the later

positions +7 or +11 The negative effect by NGG

requires that these bases constitute a codon and not

merely an out-of-frame early base sequence in the

mRNA [10] Low gene expression has also been

repor-ted for clusters of two [6,24,25] to five rare codons

[26–29] in the early coding region

Increased mRNA degradation is not likely to

explain the low expression associated with early NGG

codons [9,10,21,27,29,30] Chemical footprinting of

mRNA–ribosome complexes shows that at least 13

and possibly as many as 20 codons of mRNA are cov-ered by a single ribosome [31,32] A second ribosome cannot start translation initiation as long as the first ribosome is still translating any codon in the early region downstream of the initiation codon If the NGG codons in the downstream region are translated slowly down to, and including position +5, this would give extended pausing and thus low gene expression However, pausing at position +7 should also interfere with ribosome loading at the translational start site even if the effect could possibly be smaller Alternat-ively, if the codon is rapidly translated at position +7,

a high gene expression should be the result In this

Fig 2 Inhibition of growth of Pth(Ts)

mutant strain MB01 by peptidyl-tRNA

drop-off at 37.5 C Growth of MB01 with

differ-ent plasmid constructions Open symbols;

noninduced cultures; closed green symbols,

cultures induced with IPTG (1 m M ) Growing

cultures were monitored by measurements

of D 590 as a function of time after the

induc-tion with IPTG at time zero The codons

analysed (CGU, AGA, CGG, AGG, UGG or

GGG) were placed at positions as indicated.

Effects on lacZ gene expression, in the

absence of IPTG induction, by the analysed

codons in strain MC1061 are indicated in

the insert Noninduced b-galactosidase

values are presented as Miller units [45].

(A) Codons at position +2 (B) Codons at

position +3 (D) Codons at position +5.

(C) Codons at position +7.

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case, the question must be raised as to why early

NGG should be decoded faster at position +7 than at

position +5 It appears unlikely that ribosomal

paus-ing at early NGG codons is the reason for the

observed low gene expression

The length of the peptidyl moiety of the

peptidyl-tRNA influences the drop-off process in the case of

very small mini-genes [16,33] Overexpression of

tRNAArg4 and tRNAArg5, giving decoding of both AGA and AGG, has been reported to substantially suppress the low expression of a natural gene with sev-eral consecutive AGA and AGG codons [24,28,34,35] Such overexpression has also been reported to suppress the inhibitory effect on a pth(Ts) mutant strain that is attributed to peptidyl-tRNA drop-off at these codons [19,36]

The codon dependent growth inhibition of the pth mutant strain MB01 described here requires that the test gene is induced by IPTG The resulting growth inhibition can be suppressed by an introduced pth+ gene on a plasmid This finding further supports the model that NGG at early positions gives drop-off and accumulation of peptidyl-tRNA thereby inhibiting growth of MB01, with its Pth deficient enzyme (Fig 1) As the negative effect by NGG codons is not found for position +7, this suggests that a heptamin-opeptidyl-tRNA is stable on the translating ribosome, thus being prevented from drop-off, even if it decodes

an NGG codon (Fig 1D)

Contrary to the observed suppression of AGG dependent growth inhibition by a pth+ gene in strain MB01 we did not obtain such suppression by supply-ing the AGG cognate tRNAArg4or tRNAArg5or both These results are consistent and are obtained using two different plasmids with the tRNAArg4 and tRNAArg5 encoding genes We find that the overex-pressed tRNAArgis toxic to the pth mutant, but not to the wild-type strain We have no satisfactory explan-ation for the inability of overexpressed tRNAArg4and tRNAArg5 to compensate for the deleterious effect by accumulated peptidyl-tRNA that is implied to take place in the pth(Ts) mutant strain Apparently, the rea-son for its growth inhibition is not limiting tRNAArg However, one possibility is that the overexpressed tRNA is undermodified and therefore less efficient in translation [37,38]

A

B

Fig 3 Influence of overexpression of tRNA on gene expression associated with NGG codons Cultivation of cells and induction by IPTG are as described in Material and methods Absence (–) or presence (+) of tRNA is indicated below the figure, from top to bot-tom, with tRNA genes as listed correspondingly in the insert from left to right Protein A¢ values were normalized and are presented

as relative expression where 1.0 stands for 34 ± 0.015 units (3A¢ ⁄ 2A¢ x 100) [46] The standard error of all experiments is ± 0.15

or smaller (A) pJMM19 (encoding tRNA Lys ) influences on expres-sion of the 3A¢ model gene with +3 NGG constructs (B) Influence

on 3A¢ gene expression by pUBS250 (encoding tRNA Arg4 ), pArgUW (encoding tRNA Arg4 and tRNA Arg5 ) and pMO22 (encoding tRNA Gly1 )

as combined with +2, +3, +4, +5 or +7 AGG, GGG, AGA or AAA at each indicated position in the 3A¢ gene.

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Overexpression of certain cognate tRNAs can give

an increased gene expression [20,34,35,39–41] Here, we

have used the 3A¢ reporter gene system to analyse

whe-ther the low gene expression associated with some early

codons could be rescued by overexpression of the

cog-nate tRNA Co-expression of 3A¢ gene constructs with

the lysine codon AAA at +2 together with a tRNALys

encoding plasmid (pJMM19) in the strain, did not

sup-press the low gene exsup-pression caused by any NGG

codon at the following +3 location Similarly, the

coexpression of 3A¢ encoding plasmids with +2, +3,

+4, +5 or +7 AGG, AGA or GGG in the 3A¢ gene

and their respective cognate tRNAs (pUBS250, pAr-gUW or pMO22) did not influence gene expression lev-els Thus, at least for the NGG codons AGG and GGG we fail to demonstrate any compensation of low gene expression by overexpressed tRNA This is true either if the tRNA is cognate to the codon before or to the particular NGG codon itself, as analysed here The low expression values caused by early NGG co-dons are not increased in a strain with an inactive tmRNA system Therefore, tmRNA activity is not the reason for the observed low gene expression by early NGG codon (not shown)

The translational ribosome complex is less stable in the beginning of a translated mRNA than further down [6,27,29] The results presented here suggest an inefficient translational mechanism prone to a codon dependent peptidyl-tRNA drop-off at the very begin-ning of the coding region in mRNA In the case of NGG codons located close to the initiation codon such instability appears to be even more pronounced It could be speculated that during early translation the length of the nascent peptide is too short to reach the protein exit tunnel through the 50S subunit [16,33,42] However, even though we find lowered expression in the cases of the arginine codons CGG and AGG, such effect is not observed for the other analysed arginine codons AGA, CGC, CGA and CGU The amino acid sequence of the nascent peptide is the same in all of these cases This fact eliminates any amino acid contri-bution by the amino acid residues in the nascent pep-tide to the observed low expression values observed for the NGG arginine codons Similar arguments apply

to the glycin codon family with GGG giving low while the others give high expression [10] We are left with a model implying that the codon⁄ anticodon interaction involving NGG codons is intrinsically weak in the early coding region, thus frequently leading to an abortive event like peptidyl-tRNA drop-off

Experimental procedures

Chemicals and kits Chemicals used were of the highest available purity from Sigma-Aldrich Chemie Gmbh (Steinheim, Germany) Restriction enzymes, T4 DNA ligase and T4 kinase were either from New England BioLabs (Ipswich, USA) Invitro-gen (InvitroInvitro-gen AB, Sweden) Plasmids were prepared with GFXTM Micro Plasmid Prep Kit and gel band extractions were prepared with GFXTM PCR and Gel Band Purifica-tion Kit (Amersham Bioscience, Bucks, UK) DNA tem-plates were sequenced by MWG (The Genomic Company, Germany) Total RNA extraction was performed with

Fig 4 tRNA levels and influence of pUBS250 (encoding tRNAArg4)

on expression of the 3 A¢ reporter gene The 3 A¢ gene carries

AGG⁄ AGA at position +5 or +7 as indicated (A) [ 32

P]ATP[cP]-labelled deoxyoligonucleotide probe which is specific for the

tRNA Arg4 isoacceptor was used to identify and quantify the tRNA

using slot blotting (columns 1–4 and 9–12) The tRNA values are

presented as relative expression where 1.0 stands for wild-type

value XAC (data not shown) Protein A¢ values (columns 5–8 and

13–16) were normalized and are presented as relative expression

values, as explained in Fig 3.

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RNeasy Mini Kit (Qiagen, Valencia, CA; Branch Sweden).

Oligonucleotides were labeled using [32P]ATP[cP] from

Amersham Biosciences (Uppsala, Sweden) IgG Sepharose

Fast Flow was from Amersham Biosciences

Electrophor-esis Purity Reagent (30%) (Acrylamide⁄ Bis solution,

29 : 1), Ammonium persulfate and TEMED were from

Bio-Rad Laboratories AB, Sweden

Bacterial strains and plasmids

Escherichia colistrains used in this study are listed Table 1

The pth mutant strain MB01 was used to assay for

pept-idyl-tRNA drop-off in vivo Strain XAC [43] and plasmids

pUBS250 (with tRNAArg4gene), pArgUW (with tRNAArg4

and tRNAArg5 genes) pMO22 (with tRNAGly1 gene) or

pJMM19 (with tRNALys gene) (Table 1) together with the

protein 3 A¢ gene system (Fig 1) was used to analyse for

tRNA influences on gene expression All tRNA encoding

plasmids have different origins of replication and are

com-patible with the lacZ or the 3 A¢ carrying plasmid

Plasmid constructions and DNA sequencing

Plasmids were constructed using standard recombinant

DNA techniques [44] Some of the constructs (Table 1)

have been reported previously [10]

b-Galactosidase assays and growth conditions

Transformants were grown overnight at 37C in minimal

medium [45] supplemented with all amino acids at

recom-mended concentrations [8] and 100 lgÆmL)1 ampicillin

These cultures were used to inoculate fresh medium at

37C Exponentially growing cells (optical density at

590 nm 0.4–0.5) were harvested without IPTG induction

b-Galactosidase activity of the lysed uninduced cells were

determined [9] All measurements were carried out using a

Titer tech iEMS Reader MF (multiscan microplate

photom-eter) and the Genesis computer program (Labsystems)

Peptidyl-tRNA drop-off experiments

MB01 cells with a pCMS71 derived plasmid (Fig 1) were

grown overnight at 30C in M9 medium supplemented

with all the amino acids at recommended concentration

with and 100 lgÆmL)1ampicillin [8,45] Fresh cultures were

grown until D590¼ 0.4 and split into two subcultures with

an D590 ¼ 0.1 in fresh medium One of the two cultures

was inoculated together with IPTG (1 mm) and growth at

37.5C was continued for a further 3.5 h

Protein A¢ assay and growth conditions

Strains with plasmids were cultured overnight at 37C in

M9 medium [45] with all amino acids at recommended

concentrations [8] Antibiotics were added as necessary at

the final concentrations: 100 lgÆmL)1ampicillin, 50 lgÆmL)1 kanamycin and 10 lgÆmL)1tetracycline A 100-fold culture dilution was used as inoculum for growth in the same medium, and growth was followed by spectrophotometer measurements For induction, IPTG (1 mm) was added at the mid-log phase of growth (D590¼ 0.2–0.25) Exponenti-ally growing cells (D590 ¼ 0.5) were cooled and harvested

by centrifugation, followed by re-suspension in 1 mL

10· TST buffer [46] Cells were lysed by incubation at

95C for 10 min, and cell debris was eliminated by centri-fugation Protein A¢ was purified from the supernatant frac-tion using IgG–Sepharose (Pharmacia, Fairfield, CT, USA) mini-columns and a vacuum mini-fold system (Promega, Madison, WI, USA) A¢ proteins were eluted with 0.1 mL 0.5 m HAc at pH 3.2 The eluted protein was dried in a Savant SpeedVac plus SC110A (Telechem International, Inc Sunnyvale, USA) Protein samples were dissolved in sample loading buffer, after denaturation at 95C for

5 min Separation of the A¢ proteins was achieved by SDS⁄ PAGE (12% acrylamide) [44] The bands were quanti-fied by scanning using FujiFilm Image Reader 1000 V1.2 (FujiFilm Life Science, Japan) The protein ratios were obtained by using image gauge 4.0 quantification pro-file⁄ MW, microsoft excel program and extrapolation of plots Protein A¢ values were normalized and are presented

as relative expression where 1.0 stands for 34 ± 0.015 units (3 A¢ ⁄ 2 A¢x100) [46] Each value represents the mean value

of at least three independent measurements

Analysis of tRNA pools of unfractionated RNA immobilized by Northern hybridization slot blotting

Total RNA was extracted using RNeasy Mini Kit protocol

A 5-mL culture in minimal medium, supplemented with all amino acids [8] and the appropriate antibiotic, was induced with 1 mm IPTG at D590 ¼ 0.2 The bacteria (XAC with the appropriate plasmid) were then harvested at an D590¼ 0.5 The extracted total RNA was purified and denatured

in 100 lL with a denaturing solution [50% (v⁄ v) forma-mide, 7% (v⁄ v) formaldehyde, 1· NaCl ⁄ Cit) and incubated

at 68C for 15 min RNA (5 lg, [RNA] ¼ A260nm · dilu-tion · 40 lgÆmL)1) was blotted onto Hybond-XL nylon membrane (Amersham Biosciences) using a manifold apparatus from Hoefer Scientific Total RNA was linked to the Hybond-XL nylon using ultraviolet light for 5 min Oligonucleotides were labelled using [32P]ATP[cP] (Amer-shan Biosciences) and a T4 kinase kit (Invitrogen) To probe the tRNAArg4 the oligo 5¢-GAACCTGCGGCC-CACGACTTAGAA-3¢ was used for hybridization [34] Probes were purified using MicroSpinTM G-25 columns (Amersham Pharmacia Biotech) The transferred RNAs were hybridized overnight (12–14 h, at 42C) to the [32P]ATP[cP] deoxyoligonucleotide probe, which is comple-mentary to the encoding tRNA sequence [44] Filters were

Trang 10

exposed to a phosphorimaging screen, scanned by image

reader V1.8E software (FujiFilm FLA 3000) and saved

using the image gauge V3.45 software (FujiFilm FLA

3000) The tRNA ratios were obtained by using Image

Gauge 4.0 quantification profile⁄ MW, microsoft excel

program and extrapolation of plots, where 1.0 stands for

tRNAArg4for the wild-type strain value Each value

repre-sents the mean of at least three independent measurements

Acknowledgements

We thank Dr Margarete Bucheli-Witschel for her

input at the very beginning of this project We thank

Dr Isabella Moll, Dr Takayoshi Wakagi, Dr Valerie

Heurgue-Hamard and Dr Michael O’Connor for gifts

of plasmids and helpful advice This work was

suppor-ted by a grant from the Swedish Research Council to

L.A Isaksson

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