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the misfolded and partially protein-ase K PK-resistant isoform of the cellular prion pro-tein PrPC] is closely linked to the propagation of infectious prions, but apparently is not suffic

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Molecular basis of cerebral neurodegeneration in prion

diseases

Jo¨rg Tatzelt1and Hermann M Scha¨tzl2

1 Department of Biochemistry, Neurobiochemistry, Ludwig-Maximilians-University Munich, Germany

2 Institute of Virology, Technical University of Munich, Germany

Prion diseases in their ‘classical’ and naturally

occur-ring forms are characterized by both

neurodegenera-tion, with clinical symptoms, and propagation of

infectious prions, the latter giving rise to the typical

transmissibility within and between species [1–5] The

formation of the disease-associated isoform of prion

protein (PrPSc) [i.e the misfolded and partially

protein-ase K (PK)-resistant isoform of the cellular prion

pro-tein (PrPC)] is closely linked to the propagation of

infectious prions, but apparently is not sufficient to

induce neurodegeneration Here, an important role in

mediating the neurodegeneration process is increasing

for PrPC Evidence for this was found in neurografting approaches [6], in conditional prion protein (PrP) knockout studies [7] and in in vivo cross-linking experi-ments of PrPC[8]

Some genetic forms of human prion disease appear less transmissible, or even nontransmissible With one exception this is also true for the transgenic animal mod-els established to mimic genetic prion diseases [1–5] This nontransmissible character is reminiscent of ‘pro-teinopathies’, sometimes linked to PrP overexpression, rather than classical prion diseases, and is in line with the concept of ‘nontransmissible prionopathies’

Keywords

amyloid; neurodegeneration; prion protein;

prion; trafficking; transmissibility

Correspondence

J Tatzelt, Department of Biochemistry,

Ludwig-Maximilians-University Munich,

Schillerstrasse 44, 80336 Munich, Germany

Fax: +49 89 2180 75415

Tel: +49 89 2180 75442

E-mail: joerg.tatzelt@med.uni-muenchen.de

H M Scha¨tzl, Institute of Virology,

Technical University Munich (TUM),

Trogerstraße 30, 81675 Munich, Germany

Fax: +49 89 4140 6823

Tel: +49 89 4140 6820

E-mail: schaetzl@lrz.tum.de

(Received 2 August 2006, revised 30

November 2006, accepted 4 December

2006)

doi:10.1111/j.1742-4658.2007.05633.x

The biochemical nature and the replication of infectious prions have been intensively studied in recent years Much less is known about the cellular events underlying neuronal dysfunction and cell death As the cellular func-tion of the normal cellular isoform of prion protein is not exactly known, the impact of gain of toxic function or loss of function, or a combination

of both, in prion pathology is still controversial There is increasing evi-dence that the normal cellular isoform of the prion protein is a key medi-ator in prion pathology Transgenic models were instrumental in dissecting propagation of prions, disease-associated isoforms of prion protein and amyloid production, and induction of neurodegeneration Four experimen-tal avenues will be discussed here which address scenarios of inappropriate trafficking, folding, or targeting of the prion protein

Abbreviations

Ctm PrP, transmembrane form of PrP with the COOH-terminus in the endoplasmic reticulum lumen; cytoPrP, cytosolic PrP; Dpl, doppel protein; ER, endoplasmic reticulum; HD, hydrophobic domain; Ntm PrP, transmembrane form of PrP with the NH2-terminus in the

endoplasmic reticulum lumen; PK, proteinase K; PrP, prion protein; PrPC, normal cellular isoform of PrP; PrPSc, disease-associated isoform of PrP; secPrP, secretory PrP.

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introduced by C Weissmann [3] Two common phases

in prion diseases can be described In a first phase, with

apparently obligate requirement for PrPC expression,

profound conformational changes give rise to PrP

aggregation and the formation of PrPSc, resulting in

more or less pronounced amyloid formation This is

paralleled by replication of infectious prions and

trans-missibility In a second phase this is transduced into

physiological dysfunction in the central nervous system,

and neuronal damage

On the other hand, transgenic mouse models have

been helpful in revealing that these features can occur

independently There are models available which

des-cribe scenarios for neurodegeneration alone, prion

pro-pagation alone, or a combination of both (Fig 1) In

the following, such in vivo models are described which

address certain aspects of membrane topology, folding,

intracellular targeting and trafficking of PrP The term

‘toxicity’ is used by us here for induction of

neuro-degeneration, and PrPSc is used synonymously for the

pathological form of PrP

Toxicity of transmembrane isoforms

of PrP

The evidence that PrPSc is directly neurotoxic is

con-troversial [6] and has fueled the search for other PrP

conformers involved in pathophysiological scenarios

In the 1980s, it was shown, in cell-free

translation-translocation systems, that PrP can be found in more

than one topologic form [9] The major form is the

fully translocated isoform giving rise to the known,

fully mature, PrP in the secretory pathway, located

finally at the outer leaflet of the plasma membrane by

its GPI-anchor (secPrP) In addition, the existence of

two different transmembrane forms of PrP was verified

[10] One form, termed C-trans transmembrane (CtmPrP), has its COOH-terminus in the endoplasmic reticulum (ER) lumen The other form, termed N-trans transmembrane (NtmPrP), has its NH2-terminus in the

ER lumen Both forms appear to span the membrane

at the same hydrophobic stretch in PrP [in general, res-idues 110–135, previously termed TM1, now referred

to as the hydrophobic domain (HD)] (Fig 2) Interest-ingly, it was shown that during normal biogenesis of PrP, only about two-thirds is expressed as the secre-tory form (secPrP), less than 10% as the CtmPrP and the remainder asNtmPrP Naturally occurring and arti-ficial mutations in the membrane-spanning segment can lead to significantly increased generation of

CtmPrP In addition, several pieces of evidence have linked CtmPrP to neurodegeneration in transgenic mice

P r

P S c

prion propagation prion propagation

P r

P c

neurodegeneration

neurodegeneration

stress sensitive?

Fig 1 Scheme illustrating putative scenarios in PrP pathology In the middle, the ‘classical’ pathway, resulting in neurodegeneration and PrP propagation, is depicted The other pathways are from transgenic mouse models characterized by either PrP-induced neu-rodegeneration or prion propagation A loss of function of PrP C

might result in sensitizing neurons to stress stimuli.

O C O C

S -I P G S

-R E

l p D

O C H

S -I P G

β1 α1 β2 α2 α3

β1 α1 β2 α2 α3

α1 β2 α2 α3

S

-R

E

P r

P c

O C H

S -I P G S

-R E

P r

P F( 32-134)

Fig 2 Structure of PrP c , Dpl, and PrPDF(D32–134) Schematic presentation of the proteins mentioned in the text a, alpha helix; b, beta strand; ER-SS, endoplasmic reticulum signal sequence; GPI-SS, GPI anchor signal sequence; HD, hydrophobic domain (putative transmem-brane domain of Ctm PrP); OR, octarepeat.

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and to some heritable prion diseases (mutation A117V

in the Gerstmann–Stra¨ussler–Scheinker syndrome)

The CtmPrP isoform has been hypothesized to

repre-sent an important intermediate in the pathway of

prion-induced neurodegeneration, by escaping ER resident

quality control mechanisms [10,11] Of note, this takes

place in the absence of generation of ‘classical’

PK-resistant PrPSc and of infectious prions On the other

hand, it was later shown that a prion infection

appar-ently can trigger the generation of ‘toxic’ CtmPrP [11]

This would link transmissible and genetic prion diseases

and provide a common pathway of neurodegeneration

in prion disease Of note, another group has found, in

an additional transgenic model for CtmPrP, that the

neurodegenerative phenotype is strongly dependent on

the co-expression of endogenous wild-type PrP [12]

Toxicity of PrP located in the cytosol

During the initial characterization of the biosynthesis

of PrP, in vitro studies revealed that PrP could, at least

in part, be localized in the cytosolic compartment As

mentioned above, two different transmembrane

topo-logies were also found (NtmPrP and CtmPrP) and the

increased synthesis ofCtmPrP has been shown to

coin-cide with progressive neurodegeneration [10] In these

isoforms, the internal HD (amino acids 112–135) of

PrP serves as a transmembrane domain [13] In a yeast

model the HD interfered with the post-translational

import of PrP into the ER, and as a consequence yeast

growth was impaired and misfolded PrP accumulated

in the cytosol [14] Interestingly, both NtmPrP and

CtmPrP are partly cytosolic proteins Nearly half of the

PrP molecule is exposed to the cytoplasm in the

trans-membrane configuration and could thereby facilitate

‘toxic’ signaling events residing in the cytoplasm

Strong evidence that cytosolic PrP (cytoPrP) is

neu-rotoxic emerged from a transgenic mouse model Mice

expressing a PrP mutant with a deleted N-terminal ER

targeting signal acquired severe ataxia owing to

cere-bellar degeneration and gliosis [15] Cytotoxic effects

of cytoPrP were also observed in some cell culture

models [15–19], whereas in other studies the expression

of cytoPrP seemed not to interfere with cellular

viabil-ity [20,21]

Of interest, a small fraction of wild-type PrP can

also be found in the cytosol of cultured cells [22,23]

and neurons [24] Moreover, some pathogenic

muta-tions linked to Gerstmann–Stra¨ussler–Scheinker

syn-drome in humans, such as Q160Stop and W145Stop,

significantly increase the fraction of cytosolically

locali-zed PrP [25,26] These mutations do not change the

N-terminal ER signal sequence but delete parts of the

highly ordered C-terminal domain, revealing that this region is necessary for the import of PrPCinto the

ER [25]

What is the mechanism of cytoPrP-induced toxicity? The first studies addressing this important issue were recently described By employing cytoPrP transgenic mice [15], it was shown that toxicity correlates with membrane localization of cytoPrP [19] In a different study, apoptotic effects were linked to the association of cytoPrP with Bcl-2, an anti-apoptotic protein localized

at the cytosolic site of ER and mitochondria membranes [17] It also appeared that proteasomal activity and cytosolic chaperones, such as Hsp70 and Hsp40, can modulate the toxic potential of cytoPrP [17] Of note, a variety of previous reports indicated that PrP can inter-act with chaperones, and that chaperones can modulate the formation of misfolded PrP conformers [27] Another important question involves the possible link between the demise of scrapie-infected neurons and the formation of cytosolically localized PrP The first clues from cell culture work show that aggresome formation

in scrapie-infected mouse neuroblastoma (ScN2a) cells induces caspase-3 activation and apoptosis [28]

Toxicity of PrP located at the plasma membrane Spontaneous cerebellar neurodegeneration in certain strains of PRNP0⁄ 0 mice [29] led to the discovery of doppel (Dpl), a protein structurally related to PrPC [30] Under physiological conditions, Dpl seems not to

be expressed in the brain; however, ectopic neuronal expression of Dpl induces Purkinje cell degeneration [31,32] Dpl is complex glycosylated, harbors a GPI-anchor and shows structural homology with the C-terminal globular domain of PrPC, but lacks the N-terminal octarepeats and the internal HD [33] (Fig 2) Interestingly, the expression of PrPDF, a mutant devoid of the octarepeats and the HD (D32– 134), induces cerebellar degeneration similarly to Dpl [32,34,35] The neurotoxic potential of PrP variants was found to correlate with the disruption of the HD, indicating that the deletion of this domain, rather then the absence of the octarepeat region, is linked to the neurotoxic properties of PrPDF The internal HD was identified as an important domain for basolateral sort-ing of PrPC Moreover, Dpl, containing either the whole N-terminal domain of PrPC or the HD only, was sorted basolaterally, indicating that this domain acts as a dominant sorting signal Vice versa, Dpl or PrPC lacking the HD were found mainly at the apical surface of MDCK cells [36] An interesting activity of PrPCemerged from co-expression experiments in trans-genic animals: full-length PrPC can antagonize both

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Dpl- and PrPDF-induced neurodegeneration [32,35].

This effect is difficult to understand in the light of the

differential sorting of PrPC and Dpl However, in

polarized cells expressing Dpl and PrPC, both proteins

are found at the same cellular locale, which could be a

prerequisite for a functional interaction [36]

Several studies have indicated that Dpl or PrPDF

can induce apoptotic cell death [37–39] However, the

major question remains how these molecules, possibly

located at the plasma membrane, can activate

pro-apoptotic signaling pathways In this context it might

be interesting to recall studies addressing the

physiolo-gical role of PrPC They revealed that PrPChas

neuro-protective activity after an ischemic insult [40–43],

supports self-renewal of hematopoietic stem cells and

positively regulates neural precursor proliferation

[44,45] This indicates that the deletion of the internal

HD could change a neuroprotective activity of

wild-type PrP to the pro-apoptotic activity of mutants, such

as PrPDF The HD might directly mediate an

interac-tion of PrPC with accessory proteins, such as

trans-membrane proteins involved in PrP-induced signaling

Alternatively, deletion of the HD could indirectly

affect intermolecular interactions by modulating the

PrPCtertiary or quaternary structure

No central nervous system toxicity of

PrP missing the GPI-anchor

A leading role of neuronally expressed PrPc in

medi-ating neurodegeneration first emerged from

neurograft-ing studies [6] and later was reinforced by a

conditional PrP knockout analysis [7] In line with

these findings, cross-linking studies of PrPC with

monoclonal antibodies in vivo demonstrated the

neuro-toxic signaling potential of PrPC [8] An unexpected

twist came very recently by re-addressing an old

obser-vation In prion-infected cultured mouse cells, it was

found that the absence of the GPI moiety of PrP

redu-ces the formation of PrPSc[46,47] Recently, two lines

of transgenic mice were produced which expressed a

PrP mutant devoid of the GPI-anchor PrPDGPI

[named GPI(–)PrPsen in the mouse study] was

expressed in these mice and, similarly to the findings in

cultured cells, was efficiently secreted [48,49] After

infection with three different prion strains, the

trans-genic mice did not develop clinical symptoms Quite

unexpectedly, however, the brains of these mice

con-tained high prion titers, about 1 : 10 compared with

scrapie-infected wild-type mice Moreover, the amount

of PrPScat 500 days post infection in the

scrapie-infec-ted PrPDGPI mice was higher than in scrapie-infecscrapie-infec-ted

wild-type mice This was reflected by a high load of

amyloid plaques, which are less frequent in PrP wild-type mice Interestingly, the pathological features were most pronounced along blood vessels [48]

In conclusion, although many more PrP plaques and more PK-resistant PrPSc were present than usual, the mice harboured less prion infectivity in the brain and showed no clinical signs How does this all fit together? First, the form of amyloid was different, reflected by a different biophysical behaviour of nonglycosylated PrP apparently highly prone to the formation of higher aggregates It seems to be a common underlying idea in neurodegeneration that amyloid plaques are more an end-product and that smaller units on the road of aggre-gation (‘toxic folding intermediates’) are crucial players Second, the findings could indicate that neurotoxicity of PrPScis linked to its propagation at the plasma mem-brane or along the endocytic pathway There might be

an ‘undesired and deadly’ interaction between PrPScand PrPC, resulting in a ‘false’ or prolonged stimulation of PrPC, thereby transducing a neurotoxic signal via PrPC Alternatively, PrPSc or precursors thereof directly interact with other cell-associated signaling molecules Regardless, the exact mechanism of the study clearly emphasizes a critical role of the GPI anchor of PrP in the pathogenesis of prion diseases

Concluding remarks The puzzle of how infectious prions, PrPSc, and neuro-degeneration are interconnected is still far from being solved Obviously, prion-induced neurodegeneration may require membrane-anchored PrP in neurons, whereas expression of secreted PrPDGPI or PrPC in glia cells can promote the propagation of infectious prions without clinical symptoms, or at least with a significantly delayed onset On the other hand, the des-cribed transgenic mice models revealed neurodegenera-tion induced by aberrant PrP conformers in the absence of prion propagation It will now be important

to show that neurotoxicity induced by alterations in folding or trafficking of PrPC is indeed relevant to neuronal cell death in a prion-diseased brain How-ever, they are valuable models to systematically study pathways induced by neurotoxic protein conforma-tions, a challenging question also in other neurodegen-erative disorders, such as Alzheimer’s, polyglutamine and Parkinson’s disease

Acknowledgements The work of the authors is supported by grants from the

‘Deutsche Forschungsgemeinschaft’, the ‘Bayerisches Staatsministerium fu¨r Wissenschaft, Forschung und

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Kunst’, the ‘Bayerisches Staatsministerium fu¨r

Verbr-aucherschutz’, the ‘Bundesministerium fu¨r Bildung und

Forschung’, and the European Union

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