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Tiêu đề Enhanced sensitivity to hydrogen peroxide-induced apoptosis in Evi1 transformed Rat1 fibroblasts due to repression of carbonic anhydrase III
Tác giả P. Roy, E. Reavey, M. Rayne, S. Roy, M. Abed El Baky, Y. Ishii, C. Bartholomew
Người hướng dẫn C. Bartholomew
Trường học Glasgow Caledonian University
Thể loại báo cáo khoa học
Năm xuất bản 2009
Thành phố Glasgow
Định dạng
Số trang 12
Dung lượng 470,91 KB

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Nội dung

Reporter assays with the rat caIII gene promoter show repressed activity, demonstrating that Evi1 either directly or indi-rectly modulates transcription of this gene in Rat1 cells.. Toge

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apoptosis in Evi1 transformed Rat1 fibroblasts due to

repression of carbonic anhydrase III

P Roy1, E Reavey1, M Rayne1, S Roy1, M Abed El Baky1, Y Ishii2and C Bartholomew1

1 Department of Biological & Biomedical Sciences, Glasgow Caledonian University, City Campus, Glasgow, UK

2 Graduate School of Pharmaceutical Sciences, Kyushu University, Fukuoka, Japan

Introduction

Multiple mechanisms have been proposed for Evi1’s

contribution to cancer progression, including enhanced

cell proliferation, impaired differentiation and evasion

of apoptosis [1] Evasion of apoptosis has been

observed in both haemopoietic and epithelial cells with

a variety of agents and suggests that Evi1 is a survival

factor For example, either deregulated or enforced

expression of Evi1 has been shown to protect HEK293, HEC-1B and Jurkat cells from UV-induced apoptosis [2], U937 cells from tumour necrosis factor-a-induced apoptosis [2], SiHa cells from interferon-a-induced apoptosis [3] and both rat intestinal epithe-lial cells and HT-29 cells from transforming growth factor-b (TGFb)- and paclitaxel-induced apoptosis [4]

Keywords

apoptosis; carbonic anhydrase III; Evi1;

H2O2

Correspondence

C Bartholomew, Department of Biological &

Biomedical Sciences, Glasgow Caledonian

University, City Campus, Cowcaddens

Road, Glasgow G4 OBA, UK

Fax: +44 141 331 3208

Tel: +44 141 331 3213

E-mail: c.bartholomew@gcal.ac.uk

(Received 18 August 2009, revised

9 November 2009, accepted 16 November

2009)

doi:10.1111/j.1742-4658.2009.07496.x

EVI1 is a nuclear zinc finger protein essential to normal development, which participates in acute myeloid leukaemia progression and transforms Rat1 fibroblasts In this study we show that enforced expression of Evi1 in Rat1 fibroblasts protects from paclitaxel-induced apoptosis, consistent with previously published studies Surprisingly, however, these cells show increased sensitivity to hydrogen peroxide (H2O2)-induced apoptosis, dem-onstrated by elevated caspase 3 catalytic activity This effect is caused by a reduction in carbonic anhydrase III (caIII) production caIII transcripts are repressed by 92–97% by Evi1 expression, accompanied by a similar reduc-tion in caIII protein Reporter assays with the rat caIII gene promoter show repressed activity, demonstrating that Evi1 either directly or indi-rectly modulates transcription of this gene in Rat1 cells Targeted knock-down of caIII alone, with Dicer-substrate short inhibitory RNAs, also increases the sensitivity of Rat1 fibroblasts to H2O2, which occurs in the absence of any other changes mediated by Evi1 expression Enforced expression of caIII in Evi1-expressing Rat1 cells reverts the phenotype, restoring H2O2 resistance Together these data show that Evi1 represses transcription of caIII gene expression, leading to increased sensitivity to

H2O2-induced apoptosis in Rat1 cells and might suggest the basis for the development of a novel therapeutic strategy for the treatment of leukae-mias and solid tumours where EVI1 is overexpressed

Abbreviations

AKT, protein kinase B; caIII, carbonic anhydrase III; DCF-DA, 2¢-7¢-dichloroflourescene diacetate; DMEM, Dulbecco’s modified Eagle’s medium; DsiRNA, Dicer-substrate short inhibitory RNA; FACS, fluorescent activated cell sorter; H2O2, hydrogen peroxide;

MTT, 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyl-tetrazolium bromide; PI3K, phosphoinositide-3-kinase; ROS, reactive oxygen species;

RTQ, real-time quantitative; siRNA, short inhibitory RNA; TGFb, transforming growth factor-b.

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Variant forms of Evi1 are also antiapoptotic,

protect-ing murine acute myeloid leukaemia cells that have

been treated with arsenic trioxide [5]: in this case the

agent actually targets degradation of AML1⁄ EVI1 in

order to induce programmed cell death Recent

evi-dence also supports a survival role in nonpathological

conditions, as mice require Evi1 to maintain adequate

numbers of haemopoietic stem cells [6] and this is also

consistent with a more general requirement for Evi1

for cell survival during murine development [7]

Evi1 is a 145 kDa nuclear protein member of the

cys2his2 zinc finger family [8] It possesses multiple

domains that have been identified by both sequence

homology and functional activity, including: two

dis-tinct zinc finger motifs of seven and three repeating

units at the N-terminus and towards the C-terminus,

respectively [8]; a central repressor domain [9] and a

C-terminal acidic domain [8] These domains have been

shown to interact with other molecules, including DNA

[10,11] and proteins [1] and are responsible for

mediat-ing Evi1 inhibition of apoptosis Interactions of various

molecules with these motifs enable Evi1 to impair or

activate particular signalling pathways, including TGFb

[12,13], c-Jun N-terminal kinase (JNK) [2] and

phos-phoinositide-3-kinase⁄ protein kinase B (PI3K ⁄ AKT)

[4] Intervention of critical signalling molecules are the

basis for Evi1-mediated enhanced cell survival

A number of agents have been used to study the

impact of Evi1 on apoptosis in cells, including UV

light, tumour necrosis factor-a, TGFb, interferon-a,

arsenic trioxide and taxol (paclitaxel) Hydrogen

per-oxide (H2O2) also induces apoptosis, but the impact of

Evi1 expression on its apoptotic-inducing capability

has not been investigated previously Either

exoge-nously supplied or endogenous H2O2 generate reactive

oxygen species (ROS), which if unchecked cause

oxida-tive stress, resulting in damaged cellular DNA, lipids

and proteins that interfere with cell function To

com-bat oxidative stress, complex antioxidant defence

mechanisms have evolved to protect cells from

oxidative injury Established antioxidants include the

enzymatic systems catalase, superoxide dismutase,

glu-tathione peroxidases and peroxiredoxin III and

nonen-zymatic systems including vitamins C, E and B2,

coenzyme Q10, glutathione and carotene [14] If the

amount of ROS exceeds the capacity of the

antioxi-dant machinery, then oxidative stress occurs [15]

The enzyme carbonic anhydrase III (caIII) (EC

4.2.1.1) is also thought to protect cellular proteins

from oxidation [16] Carbonic anhydrases are a family

of 15 distinct isozymes that catalyse the reversible

con-version of H2O + CO2 and H++ HCO3) [17] caIII

is unique, very abundant in liver, skeletal muscle and

adipocytes and unlike other members of this family has low hydratase catalytic activity [18] The function

of caIII is unknown, but it is suggested that it has an antioxidant function and it has been shown to protect cells from H2O2-induced apoptosis [19,20]

In this study, we investigated H2O2-induced apoptosis in Rat1 cells expressing an Evi1 transgene Surprisingly, we found that Evi1 expression increases sensitivity to H2O2-mediated apoptosis in complete contrast to the protective effect of other apoptosis-inducing agents Increased sensitivity is primarily due

to the transcriptional downregulation of caIII gene expression mediated by Evi1

Results

Evi1-expressing Rat1 fibroblasts are resistant to taxol-induced apoptosis

Independent, stable populations of Rat1 cells express-ing murine Evi1 were generated by infection with the p50M5.6neo retrovirus (Fig 1A), produced by tran-sient transfection of EcoPak2 cells, and designated 5.61 and 5.62 Empty vector Neo1 and Neo2 cells were similarly created with the p50MX-neo retrovirus Evi1 expression was confirmed by western blot analysis with a-Evi1 (1806), detecting a 145 kDa protein in 5.61 and

o n A

R T L

p50M5.6neo

35 kDa

α-gapdh

A

B

Fig 1 Schematic representation of the murine Evi1-expressing recombinant retroviral vector p50M5.6neo and production of Evi1 in virus-infected Rat1 fibroblasts (A) Viral long terminal repeats (LTR), the murine Evi1 gene, including the N-terminal and C-terminal zinc finger domains (black boxes), repressor domain (grey box) and acidic domain (striped box), the Neo gene (neo) and splice donor (SD) and splice acceptor (SA) sites for the production of

subgenom-ic transcripts for the expression of neo (B) Western blot analysis

of whole cell protein extracts derived from the indicated cell lines and populations using a-Evi1 (1806) and a-gapdh (6C5) antibodies The positions of 145 and 35 kDa Evi1 and gapdh proteins are shown.

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5.62 cells that is absent from Neo1, Neo2 and parental

Rat1 cells (Fig 1B)

Previous studies have shown that Evi1 is a survival

factor, protecting cells from apoptosis induced by a

variety of agents To determine if Evi1 also protects

Rat1 cells from apoptosis, we treated our panel of cell

populations with paclitaxel (taxol) Apoptosis was

monitored by measuring caspase 3 catalytic activity

The results showed that taxol (1 lm, 16 h) induced

sig-nificantly higher caspase 3 catalytic activity in Rat1,

Neo1 and Neo2 cells than in Evi1-expressing 5.61 and

5.62 cells (Fig 2) Taxol induced caspase 3 activity in

all cell populations, but to a much lesser extent in 5.61

and 5.62 cells These data show that Evi1 protects

Rat1 cells from taxol-induced apoptosis, consistent

with previous studies in other cell types

Rat1 fibroblasts expressing Evi1 have increased

sensitivity to H2O2-induced apoptosis

Although previous studies have shown that Evi1

pro-tects cells from a variety of inducers of apoptosis, the

effects of H2O2 have not yet been examined Rat1 cells

and 5.61 cells were exposed to various

concen-trations of H2O2and cell viability monitored by

3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyl-tetrazolium bromide

(MTT) assay The results showed that cell viability

was reduced in a H2O2dose-dependent manner in both

Rat1 and 5.61 cells (Fig 3A) Surprisingly, the

viabil-ity of 5.61 cells was significantly less than Rat1 cells at

each concentration of H2O2(Fig 3A) The viability of

the entire panel of cell populations was examined by

MTT assay following H2O2 (750 lm) treatment and this confirmed that ectopic Evi1 expression decreased survival in Rat1 cells (Fig 3B) This was supported by the dramatic morphological change observed in H2O2 -treated 5.61 cells compared with parental Rat1 or empty vector control Neo cells treated with the same concentration of reagent (Fig 3C)

The morphological changes observed in 5.61 cells treated with H2O2 resembled apoptosis Therefore, we examined caspase 3 activation in cultures of the cell populations The results showed that H2O2 induced caspase 3 catalytic activity in all cell populations exam-ined, but the level of activation was significantly greater in 5.6 cell populations compared with parental Rat1 and vector control cells (Fig 3D)

Evi1 represses expression of the potential antioxidant caIII in Rat1 cells

Previous studies have shown that arsenic trioxide induces apoptosis in leukaemia cells by degrading the Evi1 fusion protein, AML1⁄ EVI1 [5] H2O2-induced Evi1 degradation could reduce cell survival in the pres-ence of this agent Therefore, the stability of Evi1 transgene expression in 5.61 cells was examined by western blot analysis (a-Evi1, 1806) following H2O2 treatment for 4, 10 and 16 h However, the abundance

of Evi1 protein remained unchanged during this time period, confirming that H2O2had no effect on protein stability (Fig 4), eliminating this mechanism

Recently, we used microarray technology to identify Evi1-mediated induction and repression of gene tran-scripts in Rat1 cells (E R Reavey & C Bartholomew, unpublished results) Inspection of these data revealed transcriptional repression of caIII, which encodes a protein that has previously been shown to protect cells from H2O2-induced apoptosis [19,20]

The microarray data were confirmed by real-time quantitative RT-PCR (RTQ-RT-PCR) using total cel-lular RNA from Rat1 and derivative Neo and 5.6 cells These data showed that caIII mRNA transcripts were repressed by 92–97% in 5.61 and 5.62 cells rela-tive to Rat1 and empty vector control cells Neo1 and Neo 2 (Fig 5A) Western blot analysis with a-caIII (E-19) confirmed that caIII protein levels were also dramatically reduced in 5.61 and 5.62 cells (Fig 5B), consistent with the RTQ-RT-PCR data

caIII gene promoter activity is repressed by Evi1

in Rat1 cells

To determine if Evi1-mediated caIII repression occurs

at the level of gene transcription, reporter assays were

160 000

180 000

200 000

***

80 000

100 000

120 000

140 000

0

20 000

40 000

60 000

Fig 2 Histogram showing relative caspase 3 catalytic activity of

the indicated cell lines and populations in the absence (grey

col-umns) or presence of 1 l M paclitaxel for 16 h (black columns) The

columns represent the mean of an experiment performed in

qua-druplicate and error bars the standard deviation ***P £ 0.0002.

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performed A pGL3-basic vector containing )1485 to

+55 of rat caIII gene promoter sequence [21],

desig-nated p-1485⁄ +55 caIII luc, was created (Y Ishii,

unpublished data) and transfected into Rat1, Neo and

5.6 cells, together with the control vector pRLCMV

The activity of p-1485⁄ +55 caIII luc in the various

cell types, normalized for pRLCMV activity, is shown

in Fig 6A The results showed that the caIII gene

promoter had at least 10-fold greater transcriptional

activity in Rat1, Neo1 and Neo2 cells compared with

the Evi1-expressing 5.61 and 5.62 cells In contrast, the

activity of a minimal thymidine kinase gene promoter

construct (pGL2tkluc), normalized for pRLCMV, was

similar in all cell types examined (Fig 6B) These

results show that Evi1 specifically repressed the

transcriptional activity of the caIII gene promoter in

Rat1 cells

caIII knockdown alone enhances H2O2-induced apoptosis in Rat1 cells and enhanced caIII expression is protective

Short inhibitory RNAs (siRNA) were used to deter-mine if repression of caIII gene expression alone

0 20 40 60 80 100 120

Neo 1 Neo 2 5.61 cells 5.62 cells

Neo 1 Neo 2 5.61 cells 5.62 cells

0

20

40

60

80

100

120

UT 100 150 200 250 500 750

H2O2 (µM)

Rat1 Neo2 5.61 cells

750 M

H2O2

Untreated

0

20 000

40 000

60 000

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100 000

120 000

140 000

Rat1 Neo1 Neo2

5.61 cells 5.62 cells

Rat1 Neo1 Neo2

5.61 cells 5.62 cells Relative caspase 3 activity (luminescence, RLU)

**

***

C

D

Fig 3 Cell viability and caspase 3 catalytic activity of cell lines and populations following 16 h treatment with H2O2 (A) Histogram of the percentage viability (MTT assay) of untreated cells (UT) and cells treated with the indicated concentration of H2O2for 16 h Grey columns are Rat1 cells and black columns are 5.61 cells The columns represent the mean of an experiment performed in quadruplicate and error bars the standard deviation (B) Histogram of the percentage viability (MTT assay) of the indicated untreated (black columns) and 16 h of

750 l M H2O2treated (grey columns) cell lines and populations The columns represent the mean of an experiment performed in quadrupli-cate and error bars the standard deviation **P £ 0.002 (C) Photographs showing the morphology of either untreated or treated (16 h

750 l M H 2 O 2 ) indicated cell lines and populations (D) Histogram showing relative caspase 3 catalytic activity of the indicated cell lines and populations in the absence (grey columns) or presence of 750 l M H2O2for 16 h (black columns) The columns represent the mean of an experiment performed in quadruplicate and error bars the standard deviation ***P < 0.0001.

UT 4 h 10 h 16 h UT 4 h 10 h 16 h

5.61 cells Neo1

α-Evi1 α-gapdh

145 kDa

35 kDa

Fig 4 Western blot analysis of whole cell protein extracts derived from Neo1 and 5.61 cell populations following treatment for 0 (UT),

4, 10 and 16 h with 750 l M H2O2using a-Evi1 (1806) and a-gapdh (6C5) antibodies The positions of 145 kDa Evi1 and 35 kDa gapdh proteins are shown.

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tizes Rat1 cells to H2O2 Both RTQ-RT-PCR and

wes-tern blot analysis (a-caIII) were used to identify an

effective Dicer-substrate siRNA (DsiRNA) that

inhib-ited both caIII mRNA gene transcripts (98%

reduc-tion, Fig 7A, 10 nm siRNA1) and caIII protein

(Fig 7B, 10 nm siRNA1) when transfected into Rat1

cells A control, nonspecific DsiRNA had no effect on

either caIII mRNA or caIII protein when transfected

into Rat1 cells at the same concentration (Fig 7A,B,

Non sp siRNA)

The effect of caIII siRNA1 on H2O2 sensitivity in

transfected Rat1 cells was then investigated by

moni-toring caspase 3 catalytic activity siRNA1 transfected

Rat1 cells treated with 750 lm H2O2 for 16 h had at

least double the caspase 3 activity observed with

750 lm H2O2-treated untransfected and nonspecific

DsiRNA transfected Rat1 control cells (Fig 7C) caIII

knockdown with a second distinct siRNA (siRNA3)

produced the same phenotype (Fig S1) The results

show that H2O2induced caspase 3 catalytic activity in

all cells, but the level of activation was significantly

greater in Rat1 cells transfected with a caIII-specific

siRNA (Fig 7C) Furthermore, caIII knockdown only

sensitized Rat1 cells to H2O2 treatment and had no effect upon apoptosis induced by treatment with taxol (Fig S2)

caIII expression was restored in 5.61 cells to deter-mine if the sensitivity to H2O2 treatment could be reverted Rat1 cells were transiently transfected with a caIII expression vector (pRC-sport 6caIII), which sig-nificantly increased cellular levels of the caIII protein (Fig 8A) The increased levels of caIII protein in 5.61 cells protected them from H2O2 treatment, compared with untreated or empty vector control transfected cells, as determined by measuring caspase 3 catalytic activity (Fig 8B)

Finally, we measured intracellular levels of ROS to determine if the basal oxidized state varied between Rat1 and 5.61 cells Cells labelled with 2¢-7¢-dichloro-flourescene diacetate (DCF-DA) were examined by fluorescent automatic cell sorter (FACS) The results

2.00

***

1.20

1.60

0.40

0.80

0.00

Neo1 Neo2 5.61 cells 5.62 cells

Rat1 Neo1 Neo2 5.61 cells

α-caIII α-gapdh

35 kDa

27 kDa

A

B

Fig 5 caIII gene expression in Rat1 cells and derivative cell

popu-lations (A) Histogram of caIII mRNA levels normalized for gapdh

mRNA relative to normalized caIII mRNA in Rat1 cells, determined

by RTQ-RT-PCR The columns are the mean of an experiment

per-formed in quadruplicate and the error bars the standard deviation.

(B) Western blot analysis of whole cell protein extracts using a-caIII

(E-19) and a-gapdh (6C5) antibodies The positions of 27 kDa caIII

and 35 kDa gapdh proteins are shown ***P < 0.0001.

B A

Fig 6 Reporter assays showing the activity of the caIII and mini-mal herpes simplex virus thymidine kinase (HSV tk) gene promot-ers in Rat1 and derivative cells (A) Histogram of caIII gene promoter firefly luciferase reporter activity (p-1485 ⁄ +55 caIII luc) normalized for cytomegalovirus (CMV) immediate early enhancer ⁄ promoter renilla luciferase reporter activity (pRLCMV) The columns are the mean of an experiment performed in quadruplicate and error bars the standard deviation ***P < 0.0001 (B) Histogram of HSV tk gene promoter firefly luciferase reporter activity (pGL2tkluc) normalized for pRLCMV The columns are the mean of an experi-ment performed in quadruplicate and error bars the standard deviation.

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showed that the mean fluorescence of 5.61 cells was

significantly higher than that observed in Rat1 and

Neo1 cells (Fig 9) This shows that ROS were elevated

in 5.61 cells, consistent with the observed reduction in caIII expression

Discussion

We show here for the first time that ectopic expression

of Evi1 sensitizes Rat1 cells to H2O2-induced apopto-sis This represents the first description that Evi1 can actually stimulate cell death Previous studies with a variety of agents have shown that Evi1 protects cells from apoptosis and functions as a survival factor, pro-viding one of multiple suggested roles that contribute

to the development and progression of leukaemia Consistent with this view, we also show that Evi1 pro-tects Rat1 cells from apoptosis induced by at least one

of these agents (taxol) and therefore probably also acts

as a survival factor in these cells Evi1-mediated pro-tection from taxol-induced apoptosis in rat intestinal epithelial cells and colon cancer cells (HT-29) is due to

UT Non sp siRNA siRNA

α-caIII α-gapdh

35 kDa

27 kDa

0

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1.2

1.4

**

Non sp siRNA 1

siRNA

0

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200 000

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UT Non sp

siRNA

siRNA 1

UT

750 µ M

***

A

B

C

Fig 7 DsiRNA-mediated knockdown of caIII mRNA and protein

and enhanced caspase 3 catalytic activity in Rat1 cells (A)

Histo-gram of caIII mRNA levels normalized for gapdh mRNA relative to

normalized caIII mRNA in untreated Rat1 cells, determined by

QRT-PCR in Rat1 cells transfected for 48 h with 10 n M of either a

non-specific siRNA (Non sp siRNA) or a caIII-non-specific siRNA (siRNA

10 n M ) The columns are the mean of an experiment performed in

quadruplicate and the error bars the standard deviation.

**P £ 0.0041 (B) Western blot analysis of whole cell extracts

derived from Rat1 cells, transfected as described in (A), with a-caIII

(E-19) and a-gapdh (6C5) antibodies The positions of 27 kDa caIII

and 35 kDa gapdh proteins are shown (C) Relative caspase 3

cata-lytic activity in Rat1 cells transfected as described in (A), either

treated (black columns) or untreated (grey columns) with 750 l M

H2O2for 16 h The columns are the mean of an experiment

per-formed in quadruplicate and error bars the standard deviation.

***P < 0.0001.

α-caIII α-gapdh

35 kDa

27 kDa

1400 000

1600 000

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1200 000

***

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***

0

B A

Fig 8 5.61 cell protection from H2O2-induced caspase 3 catalytic activity by ectopic expression of caIII (A) Western blot analysis of whole cell extracts derived from untransfected 5.61 cells (UT), empty vector transfected 5.61 cells (pRC CMV) and caIII expres-sion vector transfected cells (pRC-sport6caIII) with a-caIII (E-19) and a-gapdh (6C5) antibodies The positions of 27 kDa caIII and

35 kDa gapdh proteins are shown (B) Relative caspase 3 catalytic activity in untransfected 5.61 cells (grey columns) and 5.61 cells transfected with pRC CMV (white columns) or pRC-sport6caIII (black columns) with (H 2 O 2 ) or without (UT) 750 l M H 2 O 2 treat-ment ***P £ 0.0007.

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stimulation of PI3K and its downstream effector AKT

[4] The same mechanism probably also operates in

Rat1 cells, but was not examined in this study

Sensitization to H2O2-induced apoptosis, determined

by caspase 3 catalytic activity, was seen in both

Evi1-expressing Rat1 cells (5.6 cells) and in caIII knockdown

Rat1 cells Furthermore, Evi1-expressing Rat1 cells had

a 90% reduction in caIII gene transcripts and protein

Together, these results confirm that Evi1-mediated

stim-ulation of H2O2-induced cell death is due to the reduc-tion in cellular levels of the caIII protein

The results presented here suggest that caIII protects Rat1 cells from H2O2-derived ROS and therefore acts

as an antioxidant However, the biological activity of caIII is an enigma Unlike other products of this gene family, caIII has very low catalytic activity and so it is unlikely that it functions in hydrating carbon dioxide [18] Furthermore, knockout mice, deficient in caIII, have normal growth, development and lifespan under laboratory conditions, suggesting that the protein is not essential [22] However, several recent observations suggest that caIII is an important antioxidant, consis-tent with the observations here caIII is highly abun-dant in skeletal muscle, a tissue of high oxygen consumption and antioxidant activity Microarray analysis of skeletal muscle of wild-type and caIII-defi-cient knockout mice revealed that caIII has a possible role in the glutathione-mediated antioxidative system [23] This is supported by biochemical evidence show-ing that caIII undergoes rapid reversible S-glutathiola-tion or irreversible oxidation in mildly and exhaustively stressed muscle, respectively [23]: in the presence of glutathione, glutathione peroxidases restore reversibly S-glutathiolated caIII This mechanism would explain both the protective effect of ectopic caIII expression observed in NIH3T3 cells [20] and the increased sensitivity of caIII knockdown Rat1 or Evi1-expressing Rat1 cells exposed to H2O2

Several possibilities exist to explain the caIII repres-sion effect observed in the present study Abundant caIII gene transcripts and protein occur in Rat1 cells, which, like all fibroblasts examined (C Bartholomew, unpublished results), normally express low levels of endogenous evi1 Therefore, caIII gene expression and protein production normally occur efficiently in the presence of evi1 in Rat1 cells The simplest explanation

is that merely elevated cellular levels of Evi1 are suffi-cient to repress caIII transcription Consistent with this, previous studies have shown that the abundance

of Evi1 is crucial to 32Dcl3 granulocyte differentiation [24], suggesting that differential changes in gene expression must occur that are dependent on the quan-tity of cellular levels of the Evi1 protein However, other possibilities exist Multiple naturally occurring evi1 isoforms occur and it might be that it is the relative increase in the abundance of the Evi1 full-length form [25] in Rat1 cells (5.6 cells), observed here, that signifi-cantly represses caIII gene expression It is possible that only some isoforms of Evi1 repress caIII expression, whereas perhaps other forms either have no effect or the opposite effect to the full-length form Some studies have shown that the MDS1⁄ EVI1 isoform has

Rat1 MFI –250

ROS levels

Neo1 MFI –144

ROS levels

5.61 cells MFI –905

ROS levels

10 0 10 1 10 2 10 3 10 4

10 0 10 1 10 2

FL1-H

FL1-H

10 3 10 4

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M1

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M1

Fig 9 Histogram of fluorescence intensity (x-axis) versus cell

num-ber (y-axis) of indicated DCF-DA-labelled cells analysed by FACS.

The mean fluorescence intensity (MFI) for the region designated

M1 is shown for each cell type.

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the opposite effect of the full-length form For example,

it is reported that the MDS1⁄ EVI1 isoform enhances

the growth inhibitory effects of TGFb [26], whereas the

full-length form blocks this response [12]

caIII is a very abundant protein, particularly in liver,

muscle and adipocytes However, very little is known

about its transcriptional regulation Transcription of the

rat caIII gene is inhibited by the aryl hydrocarbon

recep-tor ligand 3-methylchlanthrene in hepatocytes and in

the livers of rats fed an ethanol-supplemented diet

[21,27] Human CAIII mRNA is induced in muscle of

athletes training under hypoxic conditions [28] One

study has been conducted with the caIII gene promoter,

with a preliminary analysis of an active 2.8 kb human

CAIII gene promoter in myogenic cells and a significant

loss of activity upon deletion to)715 bp [29]

Reporter assays with the caIII gene promoter

()1485 ⁄ +55) showed that this region contains strong

promoter activity in Rat1 cells, consistent with a

previ-ous analysis of the human promoter [29] This region

also has the cis-regulatory elements necessary for

Evi1-mediated transcriptional repression

Evi1-mediated repression could be caused by binding

directly to promoter sequences Previous studies with

artificial promoter reporter constructs have shown that

Evi1 can function as a DNA-binding transcriptional

repressor protein [9] Evi1 binds several corepressor

molecules, CtBP, the histone methyltransferase

SUV39H1 and the histone deacetylase HDAC1

[30–32], each of which mediates transcriptional

repres-sion However, to date no genes that are direct targets

for transcriptional repression have been identified

Furthermore, very few genes have been identified that

are directly regulated and induced by Evi1; GATA2

being the best characterized [6,33] Inspection of the

)1485 ⁄ +55 rat nucleotide sequence for Evi1

protein-binding sites with matinspector software revealed

mul-tiple potential sites This suggests that caIII may be a

direct target for Evi1-mediated transcriptional

repres-sion, although binding and biological activity of any of

these motifs require experimental investigation

Alternatively, repression of caIII gene expression

could be indirect Evi1 has been shown to interact with a

number of transcription factors, including PU.1,

RUNX1, GATA1, E2F1 and SMAD3 [12,34–37] and

signalling molecules such as JNK and PI3K⁄ AKT [2,4]

to inhibit their biological activities Therefore, it remains

possible that Evi1 might repress caIII gene expression

by interacting with a transcription factor or by

inhibit-ing a signallinhibit-ing pathway that is normally required for

the high level of expression observed in Rat1 cells

Inspection of the caIII )1485 ⁄ +55 promoter region

with matinspector software showed several potential

binding sites for E2F family proteins, but not for any of the other transcription factors Evi1 has been shown to interact with The precise mechanism by which Evi1 represses caIII gene expression awaits a more detailed analysis of the)1485 ⁄ +55 gene promoter region These data show that Evi1 represses transcription of caIII in Rat1 cells (5.6 cells) and as a consequence these cells are vulnerable to oxidative stress This raises the possibility that Evi1 regulates caIII in other cell types and if the caIII protein is an important antioxidant, then they too would be vulnerable to oxidative stress

EVI1 is overexpressed in some human neoplasias, including acute myeloid leukaemias [38] and hepatocel-lular carcinoma [4] CAIII is also very abundant in nor-mal liver and presumably is an important antioxidant in this tissue Interestingly, CAIII expression is reduced in human hepatocellular carcinoma [39], although it is not known which tumours overexpress EVI1 EVI1 might

be responsible for CAIII repression in some cases and perhaps different mechanisms operate in others CAIII expression in haemopoietic cells and leukaemia cells has not been described There is some evidence that CAIII might operate as an antioxidant in erythrocytes in cer-tain anaemias [40], suggesting that it might be important

in protecting haemopoietic cells from oxidative stress It would be interesting to assess the expression level of CAIII in normal haemopoetic cells and leukaemia cells

to determine if it is reduced in these neoplasias and if levels are inversely proportional to EVI1 expression If this is the case, then tumours overexpressing EVI1 might

be vulnerable to therapeutic agents that induce oxidative stress

Materials and methods

Preparation of plasmid DNA Plasmids p50MX-neo, p50M5.6neo, pGL2tkluc, pBluescript KSII, pCMVcar3 (I.M.A.G.E Id 4195712) and pRLCMV have all been described previously [9] and were obtained from Promega UK (Southampton, UK), Stratagene (La Jolla, CA, USA) and Source Bioscience, geneservice (Cam-bridge, UK) The construction of pGL3-caIII ()1485 ⁄ +55) has not been published (Y Ishii, unpublished data) Plas-mid DNAs were prepared by affinity chromatography using NucleobondPC500EF gravity flow columns according to the manufacturer’s instructions (Macherey-Nagal, Du¨ren, Germany)

Cell culture Rat1 and EcoPak2 cells were cultured in complete medium comprising Dulbecco’s modified Eagle’s medium (DMEM,

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Lonza Group, Basel, Switzerland, BE12-604F)

supple-mented with 5% newborn calf serum (Sigma-Aldrich,

Poole, UK, N4637) or 10% fetal calf serum (Lonza

Group, DE14-801F), respectively, and 2.5 mm glutamine,

50 lgÆmL)1 penicillin, 50 unitsÆmL)1 streptomycin (Lonza

Group, BE17-605E and BE17-603E), 37C, 5% CO2 For

retrovirus production, EcoPak2 cells (Clontech-Takara Bio

Europe, Saint-Germain-en-Laye, France) were plated on

collagen (Sigma-Aldrich, C38671) coated dishes and

tran-siently transfected with either p50M5.6-neo or p50MX-neo

using the calcium phosphate coprecipitate method described

previously [41] Virus was harvested and used to infect

Rat1 fibroblasts, as described previously [9]; infected cells

were selected in complete medium supplemented with

50 lgÆmL)1 G418 (Invitrogen, Paisley, UK) For paclitaxel

and H2O2treatment, cells were incubated in complete

med-ium supplemented with either 1 lm paclitaxel

(Sigma-Aldrich, T7191) or 100–750 lm H2O2 (Sigma-Aldrich,

21676) for 16 h

Western blotting

Protein extracts, SDS⁄ PAGE and western blotting were

performed as described previously [9] with either a-caIII

(Santa Cruz Biotechnology, Santa Cruz, CA, USA, E-19),

a-Evi1 (1806) or a-gapdh (Fitzgerald Industries, North

Acton, MA, USA, 6C5) and diluted 1⁄ 200 or 1 ⁄ 5000 (1806

and 6C5) Appropriate horseradish peroxidase-conjugated

anti-goat (Sigma-Aldrich, A5420), anti-rabbit

(Sigma-Aldrich, A9169) or anti-mouse (Sigma-(Sigma-Aldrich, A9044) IgG

secondary antibodies were used at 1⁄ 5000 dilutions and

detection was performed by enhanced chemiluminescence

(Pierce, Rockford, IL, USA, 32209)

DNA-mediated transfection and reporter assays

Rat1 cells and derivatives were transfected using Fugene6

(Roche Diagnostics, Mannheim, Germany, 11815091001)

For reporter assays, cells were transfected with recombinant

pGL3-caIII ()1485 ⁄ +55) and pRLCMV plasmid DNAs

Constant DNA concentrations were maintained with

pBlue-script KSII Cells (5· 103

) were incubated with a 1 : 6 ratio DNA : FuGENE6, prepared as described by the

manufac-turer, in 96-well plates (Costar, New York, NY, USA,

3917) for 48 h Cells were lysed, and luciferase activity

determined using the dual-luciferase reporter assay system

(Promega, TM046) in a Fluostar OPTIMA luminometer

(BMG LABTECH, Offenburg, Germany)

Oligonucleotides

Gene-specific oligonucleotides were designed using primer

expresssoftware version 3.0 (Applied Biosystems),

synthe-sized and supplied by Eurogentec (Seraing, Belgium):

5¢ rat caIII: ccgggactattggacctacca 3¢ rat caIII: cagtagcagccacacaatgca 5¢ HEX, 3¢ TAMRA rat caIII probe: cttcaccacgccaccctgc gag

5¢ rat gapdh: gggcagcccagaacatca 3¢ rat gapdh: ccgttcagctctgggatgac 5¢ 6-FAM, 3¢ TAMRA rat gapdh probe: ccctgcatccactgg tgctgcc

Preparation of total cellular RNA, cDNA synthesis and RTQ-RT-PCR

RNA was prepared from semiconfluent cultures of cells using the Trizol method (Invitrogen, 1559-026) Total cellular RNA (1 lg) was used to synthesize cDNA with Supermix III first-strand strand synthesis for QPCR according to the man-ufacturer’s instructions (Invitrogen, 11752) Five per cent of the cDNA reaction was used for RTQ-PCR using the ABso-lute QPCR mix (ABgene, Epsom, UK, AB-4136), gene-spe-cific oligonucleotide primers and dual-labelled probes, 95C,

15 min followed by 40 cycles 95C, 30 s, 60 C, 30 s in an OPTICON 2 DNA engine (MJ Research, Watertown, MA, USA)

The efficiency of the RTQ-PCR reactions was calculated using the formula efficiency =)1 + 10()1 ⁄ slope) against the standard curve of each assay over a gradient of template concentration with each gene The efficiencies for caIII and gapdhprimers⁄ probes were 90 and 101%, respectively Rela-tive expression levels between caIII and gapdh were deter-mined using the arithmetic comparative 2)DDCt method [42] and were determined relative to caIII in Rat1 cells (calibrator)

Caspase 3 assay Cells were incubated in 96-well dishes (Costar 3917), trea-ted with various agents and apoptosis determined using the Caspase 3⁄ 7-Glo assay according to the manufacturer’s instructions (Promega, G8090), measuring luminescence with a Fluostar OPTIMA luminometer (BMG LABTECH)

MTT assays MTT assays were performed on cells grown in 96-well tissue culture plates following treatment with H2O2 Cells were treated with 500 lgÆmL)1MTT (Sigma-Aldrich, M5655) in complete medium, 37C, 5% CO2, 1 h The medium was removed and replaced with 100 lL dimethylsulfoxide (Sigma-Aldrich, 472301) and absorbance measured at

570 nm using an MRX plate reader (Dynatech Laboratories, Guernsey Channel Island, UK) The final absorbance was determined by subtracting the absorbance of treated wells lacking cells The formazan concentration was determined using the formula: c (formazan concentration; lm) = A (absorbance)⁄ e (extinction coefficient) 1 (path length)

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Knockdown of rat caIII

Rat caIII knockdown was achieved in Rat1 cells using

Tri-FECTa DsiRNA Kit RNC.RNAI.NO19292.9 (Integrated

DNA Technologies, Leuven, Belgium) SiRNA1 (5¢-CCA

UUGAACUGCAUACUAAAGACAT-3¢, 5¢-AUGUCUU

UAGUAUGCAGUUCAAUGGGU-3¢) was found to be

the most effective and used for these studies The control

DsiRNA sequence used was (5¢-CUUCCUCUCUUUCUC

UCCCUUGUGA-3¢, 5¢ UCACAAGGGAGAGAAAGA

GAGGAAGGA-3¢) In total, 1 · 105 Rat1 cells per well

were seeded in a 12-well tissue culture plate in compete

medium and incubated, 37C, 5% CO2 Twenty-four hours

later the medium was removed and replaced with 600 lL

compete medium After 1 h, 1.5 lL Silentfect (BioRad,

Hercules, CA, USA, 170-3360) in 50 lL DMEM was mixed

with 50 lL DMEM containing DsiRNA and added to the

cells, giving a final DsiRNA concentration of 10 nm The

cells were incubated, 37C, 5% CO2, for 48 h prior to

isolation of whole cell protein extracts or treatment with

H2O2or 24 h for isolation of total cellular RNA

ROS assay

The ROS assay was performed by labelling cells with

DCF-DA [43] Cells grown in complete medium were

labelled for 30 min with 20 lm DCF-DA (Sigma-Aldrich,

35845), 37C, 5% CO2 The cells were trypsinized, pelleted

and washed three times with ice-cold phosphate-buffered

saline (Lonza Group, BE17-516F), then analysed for

fluorescence by FACS (FACSCaliber, Becton Dickinson,

Oxford, UK)

Acknowledgements

This work was funded by a Glasgow Caledonian

University PhD studentship and Overseas Research

Student Award Scheme (PR) and in part by the

Leukaemia Research Fund (CB, 08018)

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