Photo chapter opener 14 Liquid oxygen poured into the space between the poles of a strong magnet remains there until it boils away Copyright © Houghton Mifflin Company All rights reserved 14a–1 Figure[.]
Trang 1Copyright © Houghton Mifflin
Company All rights reserved
14a–1
Figure 14.1: (a) Lewis structure of the methane molecule (b) the tetrahedral molecular geometry
of the methane molecule.
Trang 2Copyright © Houghton Mifflin
Company All rights reserved
14a–2
Figure 14.2: valence orbitals on a free
carbon atom
Trang 3Copyright © Houghton Mifflin
Company All rights reserved
14a–3
Figure 14.3: native 2s and three 2p atomic orbitals
characteristic of a free carbon atome are combined to
form a new set of four sp3 orbitals.
Trang 4Copyright © Houghton Mifflin
Company All rights reserved
14a–4
Figure 14.5: Energy-level diagram showing
the formation of four sp3 orbitals
Trang 5Copyright © Houghton Mifflin
Company All rights reserved
14a–5
Figure 14.7: The nitrogen atom in ammonia
is sp3 hybridized.
Trang 6Copyright © Houghton Mifflin
Company All rights reserved
14a–6
Figure 14.8: The hybridization of the s, p x, and
p y atomic orbitals results in the formation of three
sp2 orbitals centered in the xy plane.
Trang 7Copyright © Houghton Mifflin
Company All rights reserved
14a–7
Figure 14.9: An orbital energy-level diagram
for sp2 hybridization:
Trang 8Copyright © Houghton Mifflin
Company All rights reserved
14a–8
Figure 14.13: (a) The orbitals used to form the bonds in
ethylene (b) The Lewis structure for ethylene.
Trang 9Copyright © Houghton Mifflin
Company All rights reserved
14a–9
Figure 14.14: When one s orbital and one
p orbital are hybridized, a set of two sp
orbitals oriented at 180 degrees results.
Trang 10Copyright © Houghton Mifflin
Company All rights reserved
14a–10
Figure 14.16: orbital energy level diagram for the formation of sp hybrid orbitals of carbon.
Trang 11Copyright © Houghton Mifflin
Company All rights reserved
14a–11
Figure 14.19: (a) Orbitals predicted by the LE model to describe (b) The Lewis structure for carbon dioxide
Trang 12Copyright © Houghton Mifflin
Company All rights reserved
14a–12
Figure 14.20: (a) An sp hybridized nitrogen atom
(b) The s bond in the N 2 molecule (c) the two p bonds
in N 2 are formed when
Trang 13Copyright © Houghton Mifflin
Company All rights reserved
14a–13
Figure 14.21: A set of dsp3 hybrid orbitals
on a phosphorous atom
Trang 14Copyright © Houghton Mifflin
Company All rights reserved
14a–14
Figure 14.22: The orbitals used to form the
bonds in the PCL5 molecule
Trang 15Copyright © Houghton Mifflin
Company All rights reserved
14a–15
Figure 14.23: An octahedral set of d2sp3
orbitals on a sulfur atom