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Sebastes schlegelii – environmental adaptation of thehatching enzyme and evolutionary aspects of formation of the pseudogene Mari Kawaguchi1, Masahiro Nakagawa2, Tsutomu Noda3, Norio Yos

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Sebastes schlegelii – environmental adaptation of the

hatching enzyme and evolutionary aspects of formation of the pseudogene

Mari Kawaguchi1, Masahiro Nakagawa2, Tsutomu Noda3, Norio Yoshizaki4, Junya Hiroi5, Mutsumi Nishida6, Ichiro Iuchi1and Shigeki Yasumasu1

1 Life Science Institute, Sophia University, Tokyo, Japan

2 National Center for Stock Enhancement, Fisheries Research Agency, Goto Station, Nagasaki, Japan

3 National Center for Stock Enhancement, Fisheries Research Agency, Miyako Station, Iwate, Japan

4 Department of Animal Resource Production, United Graduate School of Agricultural Science, Gifu University, Japan

5 Department of Anatomy, St Marianna University School of Medicine, Kawasaki, Japan

6 Ocean Research Institute, University of Tokyo, Japan

At the time of hatching of oviparous fish embryos, the

hatching enzyme is secreted from hatching gland cells

of the embryos to digest the egg envelope (chorion) [1–

3] The hatching enzyme cDNAs have been cloned

from embryos of various oviparous fish species, such

as medaka (Oryzias latipes) [4], zebrafish (Danio rerio) [5], masu salmon (Oncorhynchus masou) [5], yellow-tailed damsel (Chrysiptera parasema) [6], Japanese eel

Keywords

aberrant splicing; adaptation; astacin family

metalloprotease; hatching enzyme;

pseudogene

Correspondence

S Yasumasu, Life Science Institute, Sophia

University, 7-1 Kioi-cho, Chiyoda-ku, Tokyo

102-8554, Japan

Fax: +81 3 3238 3393

Tel: +81 3 3238 4263

E-mail: s-yasuma@hoffman.cc.sophia.ac.jp

Database

The nucleotide sequence data have been

submitted to the DDBJ ⁄ EMBL ⁄ GenBank

nucleotide sequence databases under the

accession numbers AB353099–AB353111

(Received 17 February 2008, revised 25

March 2008, accepted 1 April 2008)

doi:10.1111/j.1742-4658.2008.06427.x

The hatching enzyme of oviparous euteleostean fishes consists of two metalloproteases: high choriolytic enzyme (HCE) and low choriolytic enzyme (LCE) They cooperatively digest the egg envelope (chorion) at the time of embryo hatching In the present study, we investigated the hatching

of embryos of the ovoviviparous black rockfish Sebastes schlegelii The chorion-swelling activity, HCE-like activity, was found in the ovarian fluid carrying the embryos immediately before the hatching stage Two kinds of HCE were partially purified from the fluid, and the relative molecular masses of them matched well with those deduced from two HCE cDNAs, respectively, by MALDI-TOF MS analysis On the other hand, LCE cDNAs were cloned; however, the ORF was not complete These results suggest that the hatching enzyme is also present in ovoviviparous fish, but

is composed of only HCE, which is different from the situation in other oviparous euteleostean fishes The expression of the HCE gene was quite weak when compared with that of the other teleostean fishes Considering that the black rockfish chorion is thin and fragile, such a small amount of enzyme would be enough to digest the chorion The black rockfish hatch-ing enzyme is considered to be well adapted to the natural hatchhatch-ing envi-ronment of black rockfish embryos In addition, five aberrant spliced LCE cDNAs were cloned Several nucleotide substitutions were found in the splice site consensus sequences of the LCE gene, suggesting that the prod-ucts alternatively spliced from the LCE gene are generated by the muta-tions in intronic regions responsible for splicing

Abbreviations

DIG, digoxigenin; Ga, Gasterosteus aculeatus; HCE, high choriolytic enzyme; Hh, Helicolenus hilgendorfi; LCE, low choriolytic enzyme; MCA, 7-amino-4-methylcoumarin; MYA, million years ago; Sg, Setarches guentheri; Ss, Sebastes schlegelii.

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(Anguilla japonica) [7], Fundulus heteroclitus [8], ayu

(Plecoglossus altivelis altivelis) [9] and fugu

(Taki-fugu rubripes) [10] Among them, the medaka enzymes

have been studied comprehensively The hatching

enzyme is composed of two proteases: high choriolytic

enzyme (HCE, choriolysin H, EC 3.4.24.67) and low

choriolytic enzyme (LCE, choriolysin L, EC 3.4.24.66)

They cooperatively digest the chorion; HCE swells the

chorion by its limited proteolytic action, and then

LCE digests the swollen chorion completely [11–13]

They act at the same time, and efficient, complete

digestion was observed at natural hatching Both

enzymes belong to the astacin family of

metallo-proteases [14]

Unlike oviparous fish embryos, ovoviviparous fish

embryos grow and hatch within the maternal body

and are then delivered from the body At the time of

ovoviviparous fish hatching, it has been unclear

whether the hatching enzyme is secreted from hatching

gland cells to digest the chorion In this study, we

observed the embryo hatching of the ovoviviparous

black rockfish Sebastes schlegelii, which is a member

of the Scorpaeniformes within the Euteleostei [15] The

hatching enzyme was identified from ovarian fluids of

the black rockfish, and the cDNAs and the genes for

the hatching enzyme were cloned from the embryos

Results

Detection of metalloprotease activity in ovarian

fluid

We expected that enzymes secreted from ovoviviparous

fish embryos (hatching enzymes) would be present in

the ovarian fluid after the embryos hatched Ovarian

fluid was collected from the ovarian cavity, and its

proteolytic activity was examined using several

sub-strates added in isotonic saline (0.128 m NaCl, similar

to the natural hatching environment of embryos in the

ovarian cavity) The teleostean hatching enzymes are

generally known to belong to the astacin family of

metalloproteases, and they are inactivated by a

chelating reagent such as EDTA Enzyme activities

were determined with or without EDTA

First, the caseinolytic activity of ovarian fluid was

examined The ovarian fluid was prepared from female

fish carrying embryos at the following stages: stages of

late blastula (stage 11), 22–23 somites (optic cups,

stage 20), auditory placodes (stage 21), 26–27 somites

(pectoral fins, stage 24), pigmentation of retina

(stage 25), openings of mouth and anus (stage 28),

pig-mentation of peritoneal wall (stage 29), depletion of

yolk (stage 30), immediately before hatching (stage 31),

and after embryo delivery [16] As shown in Fig 1A, constant activities were observed in the ovarian fluids carrying stage 11 to stage 30 embryos (stage 11 to stage 30 ovarian fluid) The activity was sharply increased in the stage 31 ovarian fluid, and disap-peared from the fluid after embryo delivery The activi-ties in stage 11 to stage 30 ovarian fluid were not inhibited by EDTA, but the activity in stage 31 ovar-ian fluid dropped to about a half because of EDTA Although some proteases are present in ovarian fluid carrying embryos throughout all developmental stages, the stage 31 ovarian fluid is suggested to contain metalloprotease(s)

Next, the substrate specificity of the enzyme activity was examined using Suc-Leu-Leu-Val-Tyr-7-amino-4-methylcoumarin (MCA) and Suc-Ala-Pro-Ala-MCA as substrates; these are the best substrates for medaka HCE [12] and Fundulus HCE [8], respectively Fig-ure 1B shows the change in MCA-peptide-cleaving activity of the ovarian fluid towards Suc-Leu-Leu-Val-Tyr-MCA Little or no activity was observed in stage 11 to stage 30 ovarian fluid The activity was sharply increased in the stage 31 fluid, and was not detected in the ovarian fluid after embryo delivery The activity in the stage 31 fluid was strongly inhibited

by EDTA The activity towards Suc-Ala-Pro-Ala-MCA in stage 31 ovarian fluid was about 30 times less than that towards Suc-Leu-Leu-Val-Tyr-MCA The changes in the activities throughout development were the same as those towards Suc-Leu-Leu-Val-Tyr-MCA These results suggest that the

metallo-Fig 1 Caseinolytic activity (A) and Suc-Leu-Leu-Val-Tyr-MCA-cleav-ing activity (B) of ovarian fluid carrySuc-Leu-Leu-Val-Tyr-MCA-cleav-ing embryos at various develop-mental stages (from stage 11 to stage 31) and after embryo delivery, D Black circles and white squares indicate the activities

of the fluid preincubated without and with 20 m M EDTA, respec-tively Caseinolytic and MCA-cleaving activities are expressed as

DA 280 30 min)1and nmolÆmin)1, respectively.

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protease with the substrate specificity similar to that of

known HCEs is present specifically in the stage 31

ovarian fluid

Choriolytic activity in stage 31 ovarian fluid and

morphological changes of the chorion

As stage 31 of black rockfish embryos is the stage

immediately before hatching, it is conceivable that

metalloprotease(s) present in the stage 31 ovarian fluid

are the hatching enzyme(s) of black rockfish When the

stage 31 ovarian fluid was incubated with chorion

frag-ments, the amount of liberated peptides was increased

up to 30 min and became constant thereafter

(Fig 2A) Most of the peptides were not liberated after

the treatment with EDTA, suggesting that metallopro-tease efficiently digesting the chorion is present in the stage 31 ovarian fluid After 30 min of incubation, the chorion was swollen (Fig 2D), and the thickness of the chorion was increased about four times when com-pared with that of the control chorion (Fig 2B,C) Eighty minutes later, the inner layer of the chorion was completely digested, and the thin outer layer remained undigested (Fig 2E)

The fine structure of the black rockfish chorion before

or after incubation with ovarian fluid was observed with

an electron microscope The control chorion was com-posed of a thick inner layer and a thin outer layer The inner layer seems to be composed of two layers, which are morphologically distinct (Fig 3A) No significant change of the chorion was observed after the incubation with stage 24 ovarian fluid (data not shown) On the other hand, stage 31 ovarian fluid swelled both of the inner layers of the isolated chorion (Fig 3B), and fine fibrillar structures were observed in the outer region of the inner layer (Fig 3C) This structural change was similar to that of the chorion isolated from stage 31 embryos (Fig 3D) The chorion-digesting property of the stage 31 ovarian fluid was similar to that of HCEs that have been previously reported in medaka and Fund-ulus [8,13] This observation suggests that an HCE-like activity, rather than an LCE-like activity, exists in stage 31 ovarian fluid

Identification of HCE from stage 31 ovarian fluid The protease(s) in stage 31 ovarian fluid was par-tially purified by successive HPLC steps through a gel

Fig 2 (A) Time course of chorion solubilization by stage 31 ovarian

fluid Black circles and white squares indicate the activities of the

fluid preincubated without and with 20 m M EDTA, respectively The

activity is expressed as the value of DA 595 Black rockfish chorion

isolated from stage 11 embryos was incubated for 0 min (B, C),

30 min (D) and 80 min (E) Scale bars: 100 lm Arrows indicate

thickness of chorion.

Fig 3 Electron microscopic observation of morphological change

of the chorion by stage 31 ovarian fluid The chorion isolated from stage 11 embryos was incubated with only the buffer (A) and with stage 31 ovarian fluid (B) (C) High magnification of the part shown

in the box in (B) The bar indicates the outer layer (D) The chorion isolated from a stage 31 embryo Scale bars: 1 lm (A, B, D) and 0.5 lm (C).

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filtration column, S-Sepharose column and Source 15S

column Figure 4 shows the chromatogram of the

Source 15S column Most of the proteins were

adsorbed to the column, and the proteolytic activity

was eluted as two peaks just after a large protein peak

Then, the fraction containing the two peaks was

sub-jected to reversed-phase column chromatography The

five protein peaks thus obtained were analyzed by

SDS⁄ PAGE The major peak, containing a 23 kDa

protein, the molecular mass of which was anticipated

to be the molecular mass of other euteleostean HCEs,

was subjected to MALDI-TOF MS analysis (Fig 4)

The values (m⁄ z 22 789.68 and 23 075.27) were almost

identical to the relative molecular masses calculated

from two black rockfish HCE cDNAs (SsHCE1,

Mr= 22 584; SsHCE2, Mr= 23 056) cloned in the

present study (described later) These results strongly

suggest that the chorion-swelling activity in the

stage 31 ovarian fluid is responsible for the action of

HCEs, the genes of which are orthologous to those of

other euteleostean HCEs

Cloning of black rockfish hatching enzyme

cDNAs

It has been suggested that both HCE and LCE genes

are present in euteleostean fishes [10] However, only

HCE was identified in stage 31 ovarian fluid Whether

black rockfish possess both the HCE and LCE genes

or not remains unclear First, we performed cloning of

hatching enzyme cDNAs by RT-PCR and RACE PCR

from the RNA of black rockfish embryos As a result,

the 1009 bp and 1088 bp cDNAs were cloned from black rockfish embryos Figure 5 shows the phyloge-netic tree constructed from the previously cloned hatching enzyme cDNAs of fishes belonging to the Elopomorpha (Japanese eel) and the Euteleostei (medaka, Fundulus, fugu, and Tetraodon), together with the cDNAs cloned in the present study The tree clearly shows that euteleostean hatching enzymes are divided into HCE and LCE clades with high probabil-ity (92% for the maximum likelihood tree, 100% for the neighbor-joining tree, and 100% for the Bayesian tree) On the basis of the tree, the two cloned cDNAs were named black rockfish Seb schlegelii HCEs, SsHCE1 and SsHCE2

Fig 4 Elution pattern of cation exchange Source 15S

chromatogra-phy with a linear gradient from 0 to 1 M NaCl Solid line,

absor-bance at 280 nm; dashed line, Suc-Leu-Leu-Val-Tyr-MCA-cleaving

activity shown as nmolÆmin)1 The inset shows the MALDI-TOF MS

spectrum obtained from the major peak by RP-HPLC with the

range of m ⁄ z values from 21 716 to 24 768 Ions at m ⁄ z 22 789.68

and 23 075.27 were identified as the black rockfish HCE.

Fig 5 A 55% majority rule consensus phylogenetic tree structed by the maximum likelihood method The tree was con-structed using nucleotide sequences at the mature enzyme portion

of hatching enzymes of arowana (AwHE, AB276000), bony tongue (BtHE, AB360712), Japanese eel (EHE, AB071423–9), Fundulus (FHCE, AB210813; and FLCE, AB210814), medaka (MHCE, M96170; and MLCE, M96169), Tetraodon (TnHCE, AB246043; and TnLCE, AB246044), fugu (FgHCE, AB246041; and FgLCE, AB246042), stickleback (GaHCE, AB353108–9; and GaLCE, AB353110), Set guentheri (SgHCE, AB353105–6; and SgLCE, AB353107), H hilgendorfi (HhHCE, AB353102–3; and HhLCE, AB353104), and black rockfish (SsHCE, AB353099–100; and wSsLCE, AB353101) Numbers at the nodes indicate bootstrap val-ues for the maximum likelihood tree and neighbor-joining tree, and Bayesian posterior probabilities, shown as percentages.

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To obtain evolutionary information, we amplified

HCE genes from genomic DNAs of Helicolenus

hil-gendorfi and Setarches guentheri, which belong to the

same subfamily (Sebastinae) as that of black rockfish

[15] From both the species, SsHCE1 and SsHCE2

or-thologs (HhHCE1 and HhHCE2 for H hilgendorfi,

and SgHCE1 and SgHCE2 for Set guentheri) were

cloned (Fig 5) HCE (GaHCE1 and GaHCE2)

cDNAs were also cloned from the stickleback

Gaster-osteus aculeatus, belonging to the Gasterosteiformes

[15], which is an order different from the

Scorpaenifor-mes Both the orders belong to the same series, the Percomorpha

The amino acid sequences of HCEs deduced from the newly cloned cDNAs are shown in Fig 6A All

of them possessed two active site consensus sequences of the astacin family proteases: HExxHxx-GFxHExxRxDR (zinc-binding site) and SxMHY (methionine turn) [17–19] In addition, six cysteines, which are present in all of the previously cloned fish hatching enzymes [9], were conserved among them

Fig 6 (A) A multiple alignment of amino acid sequences of hatching enzymes White and black triangles indicate putative signal sequence cleavage sites and N-terminals of mature enzymes, respectively Arrows indicate intron insertion sites of LCE genes Identical residues are boxed Dashes represent gaps Two active site consensus sequences of the astacin family protease are given in dark (zinc-binding site) and light (methionine turn) gray boxes, and conserved cysteine residues are in black boxes (B) Exon–intron structures of black rockfish (wSsLCE), H hilgendorfi (HhLCE), Set guentheri (SgLCE) and stickleback (GaLCE) LCE and HCE genes The exons and introns are indicated

by boxes and solid lines, respectively Numbers in parentheses indicate intron phases.

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The gene structures of all the HCE genes were

deter-mined to be intron-less (Fig 6B), which is

characteris-tic of HCE genes [10] Southern blot analysis showed

that the SsHCE1 probe hybridized with at least four

EcoRI fragments of 4.4, 3.8, 3.4 and 3.2 kbp of black

rockfish genomic DNA (Fig 7A), indicating that the

black rockfish HCE gene is a multicopy gene, like

other euteleostean HCE genes examined so far [10]

As no LCE cDNA fragments were obtained from

the black rockfish by the above strategy, we employed

another strategy: that is, primers were generated from

the sequence of stickleback LCE (GaLCE) cDNA Six

different-size cDNAs (600–2 kbp) were cloned from

black rockfish embryos, and five of the six were the

transcripts that would be formed by abnormal splicing

(see later) The other one (929 bp, SsLCE1) was well

aligned with other known LCE cDNAs, but its ORF

was incomplete Thus, the black rockfish LCE gene is

transcribed, but the gene is not translated into a

func-tional protein The LCE gene is predicted to be a

pseudogene We named it black rockfish pseudo-LCE

gene (wSsLCE) These results support the finding from

the protein level experiment that only HCE activity,

not the cooperative activity of HCE and LCE, is

pres-ent in stage 31 ovarian fluid

LCE genes were cloned from H hilgendorfi

(HhLCE) and Set guentheri (SgLCE) Their ORFs

were predicted to be complete Figure 8 shows

nucle-otide and deduced amino acid sequences of

wSsLCE1 and HhLCE cDNAs The identity of the

nucleotide sequences of the ORF between them was

wSsLCE1 cDNA possessed a pretermination stop

codon due to nucleotide substitution of 262G to

262T, and a frameshift mutation due to one nucleo-tide deletion (288delA) (Fig 8)

The gene structure of wSsLCE was determined using the nucleotide sequence of wSsLCE1 cDNA The wSsLCE gene was composed of eight exons and seven introns; its structure, including the positions of exon– intron boundaries and intron phases, was the same as that of other euteleostean LCE genes (Fig 6B) [10] Southern blot analysis was performed using genomic DNA digested with BamHI, HindIII, ScaI and BglII The wSsLCE1 DNA probe hybridized with a single fragment in each digest (Fig 7B), suggesting that the wSsLCE gene is a single-copy gene, like other euteleos-tean LCE genes examined so far [10]

As described above, in addition to wSsLCE1 cDNA, five different-size cDNAs were cloned from black rock-fish embryos using primers designed from the 5¢-UTR and 3¢-UTR for wSsLCE1 cDNA The wSsLCE2 (724 bp) and wSsLCE3 (606 bp) cDNAs were shorter than wSsLCE1 cDNA (870 bp), whereas wSsLCE4 (1033 bp), wSsLCE5 (2036 bp) and wSsLCE6 (1852 bp) cDNAs were longer than wSsLCE1 cDNA (Fig 9A) wSsLCE2 and wSsLCE3 cDNAs lacked the entire region of exon 4 (146 bp) and exon 4⁄ 5 (264 bp)

of the wSsLCE gene, respectively Considering that the wSsLCE gene is a single-copy gene, wSsLCE2 and wSsLCE3 cDNAs are predicted to be the products resulting from exon skipping by aberrant splicing As the pretermination stop codon and the nucleotide dele-tion are present in exon 4, wSsLCE2 and wSsLCE3 cDNAs have complete ORFs However, their trans-lated products lack the N-terminal region of the mature enzyme encoded by exon 4, and are considered

to be nonfunctional On the other hand, wSsLCE4 and wSsLCE5 cDNAs possessed the entire intron 1 (163 bp) and intron 5 (1166 bp) sequences, respec-tively, showing cancellation of splicing of intron 1 and intron 5, respectively wSsLCE6 cDNA was 184 bp shorter than wSsLCE5 cDNA, due to partial deletion

of exon 5 and partial inclusion of intron 5 wSsLCE6 cDNA is considered to be the transcript that appears

as a result of imprecise splicing

As shown in Fig 9B, intron regions including the 5¢-splicing boundary of intron 5 also showed the simi-larity among the black rockfish, H hilgendorfi and Set guentheri When we focused on the 5¢-splicing con-sensus sequence (gtragt) [20], we found a G to A sub-stitution in the +5 site of the wSsLCE gene (gtragt to gtgaat), whereas those of the HhLCE and SgLCE genes were well conserved An experiment has demon-strated that +5 site mutation causes the exon skipping [21] These results suggest that the mutation found in the wSsLCE gene probably results in intron 5 being

Fig 7 Southern blot analysis of SsHCE1 (A) and wSsLCE (B)

genes The restriction enzymes are shown at the top Numbers on

the left refer to the positions of size markers.

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retained by the cancellation of splicing, as seen in

wSsLCE5 cDNA, and in the exon deletion, as seen in

wSsLCE3 cDNA (Fig 9A)

Half of the wSsLCE cDNAs cloned in the present

study had one nucleotide deletion (73delG) located at

the 5¢-end of exon 2 (Fig 8) The region including the

exon–intron boundary between intron 1 and exon 2

was amplified by PCR from the genomic DNA

Sequence analysis revealed that the gene is

heterozy-gous, and that a nucleotide substitution-destroying

splicing acceptor consensus sequence (AG to AA;

Fig 9B) is present in one of the alleleic wSsLCE genes

One of the alleles used the original AG acceptor

sequence, and the other mutated allele used a

pseudo-AG acceptor sequence by shifting one nucleotide to

the 3¢-site; that is, )1A in the intronic sequence and

73G in the exonic sequence were used as the acceptor

sites The occurrence of 73delG in wSsLCE cDNA can

be explained if the 73G was spliced out for use as a

pseudo-AG acceptor sequence (Fig 9B) The substi-tution might also cause the intron 1 retention, as seen

in wSsLCE4 cDNA (Fig 9A)

Expression of black rockfish hatching enzyme genes

First, the gene expression of SsHCE and wSsLCE was analyzed by northern blot analysis An SsHCE1 DNA probe was used for detecting the HCE transcript This probe probably detects both the SsHCE1 and SsHCE2 transcripts, because of their high level of similarity (88%) The hybridization of this probe with 10 lg of total RNA did not show any signal This amount of RNA, 10 lg, is known to be enough for detecting the HCE transcripts of medaka and Fundulus [8,22] The result suggests that the expression of SsHCE genes is much weaker than that in other fish species, and there-fore, poly(A)-rich RNA purified from 100 lg of total

Fig 8 Nucleotide and predicted amino acid sequences of wSsLCE1 and HhLCE Arrows indicate intron insertion sites with intron numbers Boxes indicate mutation sites found in the wSsLCE gene as described in the text.

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RNA was employed The SsHCE1 probe hybridized

with about 1 kb of transcript; this size was consistent

with that of the cDNAs The transcripts were detected

in stage 17⁄ 18 embryos, decreased in amount towards

stage 25, and disappeared thereafter (Fig 10A) We

failed to detect the positive signal of the wSsLCE gene

transcript by northern blot analysis

Next, gene expression was determined by RT-PCR

(Fig 10B) After 28 cycles of PCR, sufficient

expres-sion of the SsHCE1 and SsHCE2 genes was

detected, and the band intensity of SsHCE2

tran-scripts was about half that of SsHCE1 For the

wSsLCE gene, the 33 cycles of RT-PCR gave these

bands at about 700 bp, 800 bp, 1 kbp, and 1.2 kbp,

corresponding to wSsLCE3, wSsLCE2, wSsLCE1 and

wSsLCE4 cDNAs, respectively The expression

pat-tern of the wSsLCE gene through the developmental

stages was similar to that of the SsHCE genes, but

the expression was much weaker than that of the SsHCE genes

As shown in Fig 11, whole-mount in situ hybrid-ization using an antisense RNA probe for the SsHCE1 gene revealed a distribution of cells express-ing SsHCE transcripts in developexpress-ing black rockfish embryos It is well known that the fish hatching gland cells differentiate at the anterior end of the hypoblast layer, called the pillow, in the late gastrula embryos, and until hatching, the gland cells migrate

to the final destination in a species-dependent man-ner [5,22] In stage 17 embryos of the black rockfish, positive cells were first observed along the edge of the anterior head These cells seem to make a start

in migration from the pillow (Fig 11A) From stage 18 to stage 22, the cells migrated posteriorly (Fig 11B), and they were finally distributed widely

in the epidermis of both lateral sides of the head

Fig 9 (A) A schematic representation of the splicing variants of the wSsLCE gene The black triangle indicates putative N-terminals of mature enzymes The structures of the normally spliced form (wSsLCE1) and the alternatively spliced forms (wSsLCE2–6) are shown wSsLCE2, wSsLCE3, wSsLCE4, wSsLCE5 and wSsLCE6 have an exon 4 deletion, an exon 4 and 5 deletion, an intron 1 inclusion, an intron 5 inclusion, and partial deletion of exon 5 and partial inclusion of intron 5, respectively (B) Nucleotide mutations found on the splice site con-sensus sequence at intron 5 and intron 1 The upper part gives a comparison of the exon–intron boundary between exon 5 and intron 5 among the wSsLCE, HhLCE and SgLCE genes The consensus sequence of splicing donor site is shown at the top The lower part is an electropherogram of the PCR product around the boundary between intron 1 and exon 2 The splicing acceptor consensus sequence and pseudo-AG consensus sequence are indicated by red boxes on the upper and lower lines, respectively, together with each cDNA product The regions of the exon and intron are indicated by upper-case and lower-case letters, respectively.

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(Fig 11C,D) In stage 24 and stage 25 embryos, the

signals in positive cells became weak and their

num-bers were decreased No signals were observed in

stage 29 and stage 31 embryos and posthatching fry, and nor were signals from sense RNA observed in any embryos

Fig 10 Expression analysis of the SsHCE1, SsHCE2 and wSsLCE genes (A) Northern blot analysis of expression of the SsHCE gene during development Arrowheads indi-cate the positions of 28S and 18S rRNA (B) RT-PCR analysis of SsHCE1, SsHCE2 and wSsLCE during development b-Actin was used as a control PCR cycles were 28 for SsHCE1 and SsHCE2, 33 for wSsLCE, and

24 for b-actin Developmental stages are shown at the top Fry, posthatching embryos The 200 bp (SsHCE1, SsHCE2, and wSsLCE) and 100 bp (b-actin) ladder markers are shown in the left lane.

Fig 11 Whole-mount in situ hybridization

of SsHCE gene during the development of black rockfish embryos The SsHCE1 RNA probe was hybridized with stage 17 (A), stage 18 (B), stage 22 (C, D), stage 24 (E) and stage 25 (F) embryos (A, B) Dorsal views of head regions Upper, the anterior-most (C, E, F) Lateral views Upper, dorsal (D) Dorsal view of the head region Right, the anterior-most Yolk was removed from stage 22 embryos (C, D) Scale bars:

200 lm (G) Average number of hatching gland cells per embryo The values are expressed as the mean of five embryos Error bars indicate the standard deviation.

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Throughout the developmental stages, the total

number of SsHCE-expressing cells per embryo seemed

to be less than in other fishes The number of hatching

gland cells in hybridized embryos was counted, and

the average number per embryo was determined at

each developmental stage (Fig 11G) In stage 17 and

stage 22 embryos, about 100 cells were observed, and

the number was decreased to about one-half at

stage 24, to about one-quarter at stage 25, and to zero

at stage 29 These results were consistent with the

developmental expression profile obtained by northern

blot analysis In comparison, we counted the numbers

of hatching gland cells of rainbow trout, ayu or loach

embryos at the middle to late stages of somitogenesis

There were about 3000 (loach), 2000 (rainbow trout)

and 1000 (ayu) per embryo Thus, black rockfish

hatching gland cells were about 10–30 times fewer in

number than those of other fish species Summing up

the results, the black rockfish hatching enzyme gene is

actively expressed, but its expression stops at the

ear-lier stages In addition, the expression level is

consid-ered to be suppressed to a greater extent than in other

fishes

Discussion

We investigated the hatching of an ovoviviparous

black rockfish The EDTA-sensitive protease activity

with a substrate specificity similar to that of known

HCEs was detected in the ovarian fluid carrying

embryos immediately before hatching stage (stage 31)

Furthermore, the protease was found to swell the inner

layer of the egg envelope (chorion) and to release some

water-soluble peptides from the chorion HCE, one of

the euteleostean hatching enzymes, is well known to

swell the chorion by its proteolytic action The

prote-ases in the stage 31 ovarian fluid were partially

puri-fied, and a proteolytically active fraction containing

proteins had a molecular mass corresponding to the

cloned SsHCE1 and SsHCE2 cDNAs according to

MALDI-TOF MS analysis Therefore, these results

strongly suggest that HCEs are secreted from black

rockfish embryos immediately before the hatching

stage This is the first demonstration of hatching

enzymes in ovoviviparous fish

At the natural hatching of medaka and Fundulus

embryos, the chorion is efficiently solubilized, and no

swelling of the chorion has been observed, due to the

concurrent and cooperative action of LCE and HCE

[8,13] The morphological change of the chorion

observed in black rockfish embryos implies that its

chorion digestion mechanism is different from that of

other euteleostean fishes In addition, the present study

revealed that HCE cDNAs were cloned and their gene expression was observed specifically in the hatching gland cells of embryos, whereas the LCE gene was pseudogenized These results suggest that the chorion digestion at black rockfish hatching is performed by HCE alone The intact chorion of the black rockfish was thin and fragile when compared with the medaka and Fundulus chorions (Fig 2B), and had about one-fourth the thickness of the medaka chorion [23] According to in vitro experiments, the chorion was completely digested by a long period of incubation (80 min) with stage 31 ovarian fluid Considering that the hatching enzyme stays with the chorion for a long time in the ovarian cavity, HCE alone would be suffi-cient for chorion digestion

The northern blot analysis and in situ hybridization experiment showed that expression of the HCE gene was suppressed to a very low extent when compared with that of other euteleostean HCE genes In addi-tion, the hatching enzyme synthesis of the black rock-fish ceased around the middle of somitogenesis, whereas that of other teleostean fishes, such as medaka, zebrafish, Japanese eel and ayu, could be detected at stages from the beginning of its expression

to immediately before hatching [5,7,9,22] These results imply that the black rockfish embryo synthesizes an amount sufficient for, but limited to, chorion digestion Such an amount would not be harmful for embryos,

as embryos might be damaged by a long period of incubation with a high concentration of the protease Thus, the hatching enzyme system in oviparous fish embryos is conserved in the ovoviviparous black rockfish, with adaptations to their specific hatching environment

According to the teleostean phylogenetic tree pro-posed by Nelson, the ovoviviparous black rockfish and oviparous H hilgendorfi belong to the same tribe (Sebastinae) but different genera, and oviparous Set guentheri belongs to the same subfamily (Sebasti-nae) but a different tribe [15] The mitochondrial DNA-based phylogenetic tree indicates that the genus Helicolenus is sister to Sebastes, which includes the black rockfish [24] The nucleotide sequences of black rockfish hatching enzyme cDNAs indicated high simi-larity (93% and 97% for HCE1 and HCE2, respec-tively, and 95% for LCE) to those of H hilgendorfi, and the phylogenetic analysis (Fig 5) agreed well with the mitochondrial phylogenetic tree Despite this phy-logenetically close relationship, the LCE genes of

H hilgendorfi and Set guentheri had complete ORFs, whereas that of the black rockfish was incomplete The Sebastesfossils can be traced back to the late Miocene (about 6–10 million years ago, MYA) [25] This time

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