1-M0DAU Platin cung nhu plurcchat cua no dual' Ling dung lam xuc 1~1c rho nhicu qua umh long hop trong phong thi nghiern va tmng cong nghicp hoa dau ... Thuc chat cua nhicu YU{1trinh xuc
Trang 1T I1P chi Hila hoc, T. 45 (2), T, 176 - 180,2007
TONG HQP VA CAU TRUC CUA MQT SO PHUC CHAT
TRANS-DICLORO(5AFROL)(AMIN THdM)PLATIN(II)
Dell 1'00 SO(11/ 8-6-2006
NGUYEN THI THANH CHI, TRAN THj DA, vuQUANG NHV, NGUYEN HOU DINH
1'rut'IJlg Da hoc Sa pliant lid N~;I
SUMMARY
Four complexes of plutintun!II) il/ell/dilig trans-/PI( Sa})( o-toludineK'U (1'n. IUII/s-/PI( SII})( p lull/dillejCl,l (1'2 i trans-/Pt( Sa})( o-anisidinc JCI,} (!'3) lruIiS-/!'I( Suf)( p-unisi.tinciCU(P~ihave been synthesised The structure of the coniplcxes have been dctcrminded by elemental analysis, molar conducsivitv JR Raman, electronic and /H-NMR spectra studies.
1-M0DAU Platin cung nhu plurcchat cua no dual' Ling
dung lam xuc 1~1c rho nhicu qua umh long hop
trong phong thi nghiern va tmng cong nghicp
hoa dau [1] Thuc chat cua nhicu YU{1trinh xuc
tac do Hi du tao phirc chat irung gian gilra olefin
lPt(olefin)(amin)CU cHi dual' nghicn cuu nhieu
[2, 3] Tuy nhicn voi phoi ur olefin thicn nhieu
thi hau nhu can chua duoc nghicncuu
Trong cac bai baa uircc 14, 5 j, chung toi da
thOng baa djeu kicn tong hap va xac dinh cau
true cua plurc chat KlPt(safrol)CI,j, trong do
safrol la mot aryl olefin thien nhicn (thanh phan
chinh cua iinh dau xa xi) Tiel' theo, trong bai
bao nay chung ioi trinh bay ket qua: tong hap
cau true, tinh chat ella mot so plurc chat
1I"UIlS-diclororsafrohtamin thomjplatintl l) Safrol duoc
viet tat la Sal'
II -THUC' N(JllI(,M
1 Tong hop cae phue
- Tong hap po: Pht(c podual' tclng htip thea
phuong phap motiltrong tai Ilcu [41
'!'rlng hap 1'1 P2 P3, 1'4: Cho til til I, I
176
mrnol dung dich amin vao dung dich bao hoa cua I mmol PO Khuay dung dich ph an ling 6 nhiet do phong, sau khoang 5 gio thu dual' kct
iua Rua ket tua liin hrot bang dung dich IICI O,lN, nuoc va ruou lanh San pham dual' ket tinh lai trung hen hop nrou-mroc
- H~Hn luoug PI va iuroc ket tinh dU0C xac dinh bang phuong phap trong luang tai Khoa IIoa hoc, Truong DH Su phan: IIa Noi site ky
dual' thuc hien voi ban mong Silufol-UV 254 cua Tiel' Khac trong he giiti hap axcton/axit nitric = 10: I hien vet bang hoi iot DO dim dien phan tu' do tren may III 88119 N cua My. I'ho Raman ghi trcn may Micro Raman LABRAM trong vung III4000 - 100 cm', buc xa kich thich 632,8 run til laser hcli-neon Phrl IR duoc ghi trcn may IMPAC- 410-NICOLET trong vung
4000 - 400 ernI mau do 0 dang vien nen voi
KBr Ph" IIl-NMR cua cac phuc chat dual' do
tren may Brucker ADVANCE (500 MHz) tai Vicn l loa hoc thuoc Vien Khoa hoc va Ccll1g
ngh<; Yi¢t Nam, tat ea cae pink chat dul,tc do
Hong dung [11(1i MeOD vai chal chuan lit TMS
111-KfiT QUA VAnIAo LUI\N
V iec lC>ng hlJp phuc chat dau